WO2023025242A1 - 钢制薄壁拼焊件的制造方法及使用该拼焊件制备的热冲压部件 - Google Patents
钢制薄壁拼焊件的制造方法及使用该拼焊件制备的热冲压部件 Download PDFInfo
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- WO2023025242A1 WO2023025242A1 PCT/CN2022/114784 CN2022114784W WO2023025242A1 WO 2023025242 A1 WO2023025242 A1 WO 2023025242A1 CN 2022114784 W CN2022114784 W CN 2022114784W WO 2023025242 A1 WO2023025242 A1 WO 2023025242A1
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- welded
- welding
- hot stamping
- steel plate
- tailor
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 244
- 239000010959 steel Substances 0.000 title claims abstract description 244
- 238000000034 method Methods 0.000 title claims abstract description 81
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 39
- 238000003466 welding Methods 0.000 claims abstract description 302
- 239000000203 mixture Substances 0.000 claims abstract description 107
- 238000000576 coating method Methods 0.000 claims abstract description 73
- 239000011248 coating agent Substances 0.000 claims abstract description 67
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 63
- 230000008569 process Effects 0.000 claims abstract description 61
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 49
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 44
- 229910000734 martensite Inorganic materials 0.000 claims abstract description 42
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910000765 intermetallic Inorganic materials 0.000 claims abstract description 18
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 16
- 210000001503 joint Anatomy 0.000 claims description 64
- 229910052757 nitrogen Inorganic materials 0.000 claims description 27
- 229910052748 manganese Inorganic materials 0.000 claims description 24
- 239000012535 impurity Substances 0.000 claims description 20
- 229910052759 nickel Inorganic materials 0.000 claims description 19
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 18
- 238000011049 filling Methods 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- 239000000945 filler Substances 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 229910052717 sulfur Inorganic materials 0.000 claims description 10
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 230000000717 retained effect Effects 0.000 claims description 8
- 230000001681 protective effect Effects 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- 238000010791 quenching Methods 0.000 claims description 6
- 230000000171 quenching effect Effects 0.000 claims description 6
- 229910052720 vanadium Inorganic materials 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- KCZFLPPCFOHPNI-UHFFFAOYSA-N alumane;iron Chemical compound [AlH3].[Fe] KCZFLPPCFOHPNI-UHFFFAOYSA-N 0.000 abstract description 10
- 239000007789 gas Substances 0.000 description 63
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 26
- 239000011572 manganese Substances 0.000 description 25
- 239000003344 environmental pollutant Substances 0.000 description 23
- 239000003921 oil Substances 0.000 description 23
- 231100000719 pollutant Toxicity 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
- 229910052786 argon Inorganic materials 0.000 description 22
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000010953 base metal Substances 0.000 description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
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- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910015372 FeAl Inorganic materials 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
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- 238000005728 strengthening Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- PIMDXYQKECXXRT-UHFFFAOYSA-M N.[O-2].[OH-].O.[Al+3] Chemical compound N.[O-2].[OH-].O.[Al+3] PIMDXYQKECXXRT-UHFFFAOYSA-M 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000009916 joint effect Effects 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000005480 shot peening Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/346—Working by laser beam, e.g. welding, cutting or boring in combination with welding or cutting covered by groups B23K5/00 - B23K25/00, e.g. in combination with resistance welding
- B23K26/348—Working by laser beam, e.g. welding, cutting or boring in combination with welding or cutting covered by groups B23K5/00 - B23K25/00, e.g. in combination with resistance welding in combination with arc heating, e.g. TIG [tungsten inert gas], MIG [metal inert gas] or plasma welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/21—Bonding by welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/21—Bonding by welding
- B23K26/211—Bonding by welding with interposition of special material to facilitate connection of the parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/21—Bonding by welding
- B23K26/24—Seam welding
- B23K26/26—Seam welding of rectilinear seams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/20—Bonding
- B23K26/32—Bonding taking account of the properties of the material involved
- B23K26/323—Bonding taking account of the properties of the material involved involving parts made of dissimilar metallic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/60—Preliminary treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/16—Arc welding or cutting making use of shielding gas
- B23K9/173—Arc welding or cutting making use of shielding gas and of a consumable electrode
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/23—Arc welding or cutting taking account of the properties of the materials to be welded
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/235—Preliminary treatment
Definitions
- the invention relates to a manufacturing method of a welded part, in particular to a manufacturing method of a steel thin-walled tailor welded part and a hot stamping part prepared by using the tailored welded part.
- Tailored weldment is to weld together several steel plates of the same/different material, same/different thickness or same/different coating to meet the different requirements of parts for material properties.
- the hot stamping process of tailor-welded parts can reduce the weight of the car body, improve the assembly accuracy and simplify the assembly steps. At the same time, it can take into account the advantages of hot stamping and further improve the formability of the steel plate.
- the hot stamping products formed by tailor-welded parts have the characteristics of high strength, complex shape, good formability, high dimensional accuracy and small springback.
- Steel for hot stamping can be divided into bare plate and coated steel plate according to the state of the surface.
- the surface of bare steel is prone to oxidation at high temperature and forms scale.
- the scale is squeezed Pressed into the steel, forming surface defects, which greatly affects its performance.
- the hot stamping steel plate with coating can save the shot peening after hot stamping while protecting the steel plate from oxidation. Therefore, the coated steel plate Hot-stamped steel sheets have received more and more attention.
- Chinese patent CN101426612A discloses "method for manufacturing welded parts with good mechanical properties from rolled coated sheet”. This method solves the problem that the strength and elongation of the weld seam are not up to standard due to the melting of aluminum into the molten pool, but the coating needs to be ablated before welding the steel plate, which increases equipment investment and reduces production efficiency.
- Cikon patent CN102985216A discloses "arc/laser hybrid welding method for aluminum-coated steel parts with nitrogen and/or oxygen-containing gas".
- arc+laser hybrid welding is used for welding aluminum-coated parts, and the shielding gas is added with additional gas nitrogen.
- additional gas nitrogen the volume content of the additional gas is 1-20%
- the function of the additional gas is to capture aluminum to form Al 2 O 3 or AlN compounds, to avoid the formation of ferrite or other harmful intermetallic compounds
- the formed aluminum oxide or nitrogen Aluminum oxide floats on the surface of the molten pool, thus preventing aluminum from dissolving in the welded pool (paragraph 0015), and the weld structure is a full martensitic structure.
- Chinese patent CN108025400A discloses "laser welding method for producing semi-finished plates from hardenable steel with aluminum-based or aluminum-silicon-based coating", which is tailored for differential strength hot stamping steel plates, and the final weld structure obtained is full horse Body organization.
- Chinese patent CN201380027064.4 discloses "metal sheet with welding notches and its forming method".
- it is difficult to control the depth of coating removal because if the coating removal is not complete, it will be similar to the method disclosed in Chinese patent CN101426612A; if the coating removal depth is too large, it will be Damage to the steel substrate is equivalent to the thinning of the material in disguise, and the performance of the joint after welding will inevitably decrease; in addition, the control of the removal width of the coating is also a problem.
- the removal width is narrower than the weld seam, the coating elements will melt into the molten pool during welding, which will reduce the performance of the weld seam; if the removal width is wider than the weld seam, there will be no coating protection in the welding heat-affected zone, which will affect the corrosion resistance of the joint.
- Cid patent CN104023899A discloses "tailored welded parts and its manufacturing method, and hot stamping parts using tailored welded parts", which uses welding wires with higher carbon and manganese content than the base metal to weld aluminum or aluminum alloy clad plates; although The problem of weld performance is solved, but the weld structure of the weld is completely transformed into martensite during hot stamping, and the carbon and manganese contents in the welding wire are 0.1-0.8wt.% and 1.5-7.0wt.% higher than the base metal respectively .
- the content of carbon, manganese and other elements in hot stamping steel itself is very high, so the welding wire disclosed in the patent is a high-carbon and high-manganese welding wire, and the manufacturing difficulty of the welding wire is high.
- Chinese patent CN111230301A discloses the "manufacturing method of steel thin-walled welding and other strong parts with aluminum or aluminum alloy coating".
- the welded joints obtained by this method can only reach the level of 1500MPa.
- the welded joints of hot stamping parts are subject to quasi-static stretching because the strength of the weld is lower than that of the base material, resulting in weld fracture , the depot cannot be used.
- the purpose of the present invention is to provide a manufacturing method of steel thin-walled tailor-welded parts and hot stamping parts prepared by using the tailored welded parts, so as to solve the problem that the welded parts are welded after hot stamping due to the plating layer melting into the molten pool during the tailor-welded process.
- the quasi-static tensile fracture position of the welded joint of the hot stamping part obtained by using the tailor-welded part is located in the base metal, the elongation of the joint is greater than 4%, and the weld strength is greater than the tensile strength of the low-strength base metal; welding
- the strain rate of the joint is 40-800/s, its tensile fracture strain value is greater than 0.08, which better meets the application requirements in the field of automobile production.
- a manufacturing method of steel thin-walled tailor-welded parts comprising the steps of:
- the steel plates to be welded include a substrate and an aluminum or aluminum alloy coating on at least one surface thereof, and the coating includes a The contacted intermetallic compound alloy layer and the metal alloy layer thereon, the coating of the steel plate to be welded is not removed or thinned;
- the welding speed in laser wire-filled welding is 40-120mm/s, and the wire-feeding speed is 2-8m/min;
- the welding speed of MAG welding is 300-800mm/min
- the welding speed of laser MAG hybrid welding is 40 ⁇ 150mm/s, and the wire feeding speed is 2 ⁇ 10m/min;
- the protective gas is Ar+15 ⁇ 80vol.%CO 2 +1 ⁇ 10vol.%N 2 , and the flow rate of the protective gas is 10 ⁇ 25L/min;
- the composition of the welding wire for welding includes C, Mn, and Ni austenite stabilizing elements, the content of the three elements in the welding wire composition is subtracted from the content of the corresponding element in the steel plate A to be welded, and the obtained difference is expressed by ⁇ C, ⁇ Mn and ⁇ Ni represent;
- the steel plate to be welded A is one of the two steel plates to be welded with the same strength level, or the steel plate to be welded with a lower strength level among the two steel plates to be welded with different strength levels;
- the tensile strength of steel plate A to be welded is ⁇ 900MPa, ⁇ C: -0.05 ⁇ 0.09wt.%, ⁇ Mn: -0.5wt.% ⁇ 1.4wt.%, ⁇ Ni: 0 ⁇ 4.0wt.%; or
- the tensile strength of steel plate A to be welded is ⁇ 1700MPa, ⁇ C: -0.26 ⁇ -0.15wt.%, ⁇ Mn: -1.4 ⁇ 0.7wt.%, ⁇ Ni: 2.26 ⁇ 4.0wt%;
- the weld structure of the tailored weldment is martensite + 1-15vol.% ferrite dispersedly distributed + 0-5vol.% retained austenite; the content of free aluminum in the weld is 0.1-4.0wt.%. .
- the CO 2 content in the protective gas is 15-50 vol.%.
- the N 2 content in the protective gas is 2-4 vol.%.
- the welding current of the MAG welding or laser MAG hybrid welding is 110-130A, and the welding voltage is 18-25V.
- the welding current of the MAG welding or laser MAG hybrid welding is 110-125A, and the welding voltage is 18-25V.
- the welding speed of laser MAG hybrid welding is 60-150 mm/s, and the wire feeding speed is 4-10 m/min.
- the defocus amount in the laser wire-fill welding or laser MAG composite welding process is -10-10mm, and the laser power control range is 3-8kW.
- the defocus amount is -8-8mm, and the laser power control range is 4-8kW.
- the minimum diameter of the laser spot output by the laser processing head is 0.3-1.6 mm.
- those skilled in the art can select relevant parameters according to the actual situation, so as to ensure that the minimum spot diameter output by the laser processing head is 0.3-1.6 mm.
- the ratio of the focal length of the focusing mirror to the focal length of the collimating mirror can be set to 0.75 ⁇ 4.0
- the Rayleigh Length is 1.249 ⁇ 44.955
- the diameter of the laser transmission fiber is 0.2 ⁇ 0.8mm
- the Focusing Angle is 2.3 ⁇ 18.4 Grad.
- the welding is laser wire-filled welding
- the welding speed is 40-120mm/s
- the wire-feeding speed is 2-8m/min
- the defocus is -8-8mm
- the laser power control range is 4 ⁇ 8kW.
- the welding is MAG welding
- the welding speed is 400-800mm/min
- the welding current is 110-125A
- the welding voltage is 18-25V.
- the welding is laser MAG hybrid welding
- the welding speed is 60-150mm/s
- the wire feeding speed is 4-10m/min
- the defocus is -10-10mm
- the laser power control range is 3 ⁇ 8kW
- welding current is 110 ⁇ 130A
- welding voltage is 18 ⁇ 25V.
- the diameter of the welding wire is 1.0-1.6 mm.
- the thickness of the substrate is 0.5-3mm.
- the coating is an aluminum alloy coating
- the composition of the aluminum alloy coating is: Si: 5-11%, Fe: 0-4%, and the balance is Al and other unavoidable impurities.
- the composition of the aluminum alloy coating is: Si: 8.5-10.5%, Fe: 1.5-2.5%, and the balance is Al and other unavoidable impurities.
- the tensile strength of the steel plate A to be welded is ⁇ 900MPa, and its component weight percentage is: C: 0.06-0.1%, 0 ⁇ Si ⁇ 0.1%, Mn: 0.5-1.0%, P ⁇ 0.03%, S ⁇ 0.01%, Al ⁇ 0.1%, 0 ⁇ Cr ⁇ 0.1%, 0 ⁇ Ti ⁇ 0.05%, and the rest are Fe and other unavoidable impurities.
- the tensile strength of the steel plate A to be welded is greater than or equal to 900MPa and less than 1300MPa, and its composition weight percentage is: C: 0.06-0.15%, Si: 0.3-1.0%, Mn: 0.5-2.5%, P ⁇ 0.10% , S ⁇ 0.05%, Al: 0.02 ⁇ 0.30%, Cr: 0.05 ⁇ 0.5%, Nb: 0.02 ⁇ 0.20%, V ⁇ 0.15%, Ti: 0.01 ⁇ 0.10%, Mo ⁇ 0.5%, Ni ⁇ 0.5%, B : 0.001 to 0.01%, the balance being Fe and other unavoidable impurities.
- the tensile strength of the steel plate A to be welded is greater than or equal to 1300MPa and less than 1700MPa, and its composition weight percentage is: C: 0.2-0.3%, Si: 0.1-0.5%, Mn: 0.5-2.5%, P ⁇ 0.015% , S ⁇ 0.05%, Al ⁇ 0.1%, Ti ⁇ 0.2%, B: 0.0005 ⁇ 0.08%, Cr: 0.01 ⁇ 1%, Ni ⁇ 0.24%, and the balance is Fe and other unavoidable impurities.
- the tensile strength of the steel plate A to be welded is ⁇ 1700 MPa, and its composition by weight percentage is: C: 0.30-0.39%, Si: 0.05-0.6%, Mn: 0.5-2.5%, P ⁇ 0.015%, S ⁇ 0.01%, Al: 0.01 ⁇ 0.07%, Cr ⁇ 1.0%, Nb ⁇ 0.08%, V ⁇ 0.1%, Ti: 0.01 ⁇ 0.12%, Mo: 0.01 ⁇ 0.5%, Ni ⁇ 0.25%, B: 0.0001 ⁇ 0.005 %, N ⁇ 0.006%, and the balance is Fe and other unavoidable impurities.
- the composition of the welding wire is: C: 0.05-0.15%, Mn: 0.5-1.9%, Ni: 0-4%, and the balance is Fe and other unavoidable impurities.
- the content of Ni in the welding wire is 0.5-4%. It should be understood that the selection of C, Mn and Ni content in the welding wire needs to meet the requirements mentioned above.
- the invention includes the steel thin-walled tailor-welded parts obtained by the above-mentioned manufacturing method.
- the present invention provides a steel thin-walled tailor welded part, which is welded by two steel plates to be welded with the same or different strength levels, the steel plates to be welded include a base body and aluminum on at least one surface thereof Or an aluminum alloy coating, the coating includes an intermetallic compound alloy layer in contact with the substrate and a metal alloy layer thereon, and the weld structure of the steel thin-walled tailor-welded part is martensite +1-15vol. % diffusely distributed ferrite + 0-5vol.% retained austenite, and the content of free aluminum in the weld is 0.1-4.0wt.%.
- the thickness of the substrate is 0.5-3mm.
- the coating is an aluminum alloy coating
- the composition of the aluminum alloy coating is: Si: 5-11%, Fe: 0-4%, and the balance is Al and other unavoidable impurities.
- the composition of the aluminum alloy coating is: Si: 8.5-10.5%, Fe: 1.5-2.5%, and the balance is Al and other unavoidable impurities.
- the two steel plates to be welded are each independently selected from the following steel plates:
- the composition weight percentage is: C: 0.06 ⁇ 0.1%, 0 ⁇ Si ⁇ 0.1%, Mn: 0.5 ⁇ 1.0%, P ⁇ 0.03%, S ⁇ 0.01%, Al ⁇ 0.1%, 0 ⁇ Cr ⁇ 0.1%, 0 ⁇ Ti ⁇ 0.05%, the rest are Fe and other unavoidable impurities;
- the composition weight percentage is: C: 0.06-0.15%, Si: 0.3-1.0%, Mn: 0.5-2.5%, P ⁇ 0.10%, S ⁇ 0.05%, Al: 0.02 ⁇ 0.30%, Cr: 0.05 ⁇ 0.5%, Nb: 0.02 ⁇ 0.20%, V ⁇ 0.15%, Ti: 0.01 ⁇ 0.10%, Mo ⁇ 0.5%, Ni ⁇ 0.5%, B: 0.001 ⁇ 0.01%, balance For Fe and other unavoidable impurities;
- the composition weight percentage is: C: 0.2-0.3%, Si: 0.1-0.5%, Mn: 0.5-2.5%, P ⁇ 0.015%, S ⁇ 0.05%, Al ⁇ 0.1%, Ti ⁇ 0.2%, B: 0.0005 ⁇ 0.08%, Cr: 0.01 ⁇ 1%, Ni ⁇ 0.24%, the balance is Fe and other unavoidable impurities; and
- Steel plate with tensile strength ⁇ 1700MPa its composition by weight percentage is: C: 0.30 ⁇ 0.39%, Si: 0.05 ⁇ 0.6%, Mn: 0.5 ⁇ 2.5%, P ⁇ 0.015%, S ⁇ 0.01%, Al: 0.01 ⁇ 0.07%, Cr ⁇ 1.0%, Nb ⁇ 0.08%, V ⁇ 0.1%, Ti: 0.01 ⁇ 0.12%, Mo: 0.01 ⁇ 0.5%, Ni ⁇ 0.25%, B: 0.0001 ⁇ 0.005%, N ⁇ 0.006%, remainder The amount is Fe and other unavoidable impurities.
- the present invention also provides a hot stamping part prepared from the steel thin-walled tailor-welded parts obtained by the above manufacturing method, the weld seam structure of the hot stamping part is martensite + 0.1-10vol.% ferrite dispersedly distributed , the quasi-static tensile fracture position of the hot stamping part is the base material, and the elongation of the joint is not less than 4%; when the strain rate of the welded joint is 40-800/s, the tensile fracture strain value of the welded joint is greater than 0.08.
- the ferrite content in the weld structure of the hot stamping part of the present invention is 0.5-5 vol.%.
- the ferrite in the weld microstructure of the hot stamping part of the present invention is needle-shaped.
- the strain rate of the welded joint of the hot stamping part of the present invention is 40-800/s
- the tensile fracture strain value of the welded joint is greater than 0.09.
- iron-aluminum intermetallic compound and massive ferrite there is no iron-aluminum intermetallic compound and massive ferrite in the weld structure of the hot stamping part of the present invention.
- the present invention also provides a hot stamping part, the welding seam structure of the hot stamping part is martensite + 0.1-10vol.% ferrite dispersedly distributed, the quasi-static tensile fracture position of the hot stamping part is the base material, and the joint is extended The rate is not less than 4%; when the strain rate of the welded joint is 40-800/s, the tensile fracture strain value of the welded joint is greater than 0.08.
- the hot stamping parts are prepared by using the thin-walled steel tailor-welded parts of the present invention, or by using the thin-walled steel tailor-welded parts obtained by the manufacturing method described in the present invention.
- the ferrite content in the weld structure of the hot stamping part of the present invention is 0.5-5 vol.%.
- the ferrite in the weld microstructure of the hot stamping part of the present invention is needle-shaped.
- the strain rate of the welded joint of the hot stamping part of the present invention is 40-800/s
- the tensile fracture strain value of the welded joint is greater than 0.09.
- iron-aluminum intermetallic compound and massive ferrite there is no iron-aluminum intermetallic compound and massive ferrite in the weld structure of the hot stamping part of the present invention.
- the present invention also provides a method for preparing a hot stamping part, which includes the step of performing hot stamping and quenching on the steel thin-walled tailor welded part of the present invention.
- the tailor welded blank is subjected to hot stamping and quenching, the heating temperature is 920-950° C., the heating time is 3-6 minutes, and the pressure is maintained in the water-passing mold for 8-20 seconds.
- the method includes the step of manufacturing thin-walled tailor-welded steel parts by using the method for manufacturing thin-walled tailored welded parts made of steel according to any embodiment herein, and the manufactured thin-walled tailored welded steel parts The step of performing hot stamping and quenching.
- the weld seam structure of the hot stamping part is martensite + 0.1-10vol.% ferrite dispersedly distributed
- the quasi-static tensile fracture position of the welded joint of the hot stamping part is the base material
- the elongation of the joint is not low
- the strain rate of the welded joint is 40-800/s
- the tensile fracture strain value of the welded joint is greater than 0.08.
- the ferrite content in the weld structure of the hot stamping part is 0.5-5 vol.%.
- the ferrite in the weld structure of the hot stamping part is needle-shaped.
- the strain rate of the welded joint of the hot stamping part is 40-800/s
- the tensile fracture strain value of the welded joint is greater than 0.09.
- At least one surface of the substrate to be welded in the present invention has a coating on at least one surface.
- the coating on the area to be welded on the steel plate to be welded is not removed or thinned. Due to the existence of the aluminum-containing coating, the coating melts The molten pool forms brittle and hard intermetallic compounds (Fe 3 Al, Fe 2 Al 5 , FeAl 3 ) and excessive ferrite, which reduces the strength and ductility of welded joints after hot stamping and cannot be used.
- the amount of free aluminum in the weld should be controlled during the welding process to avoid the formation of iron-aluminum intermetallic compounds in the weld and the formation of an appropriate amount of ferrite.
- the ternary shielding gas mixed with argon, carbon dioxide and nitrogen is used in the welding process.
- the volume content of N2 is 1-10%.
- N2 can transfer nitrogen element to the weld.
- Al and N in the molten pool react, The formed AlN is dispersed in the molten pool with the violent stirring of the molten pool, and will be used as secondary phase particles to improve the strength of the weld after hot stamping; on the other hand, the free Al in the molten pool combines with N to form AlN, which controls the melting
- the concentration of free Al in the pool can prevent the precipitation of excessive ferrite, and also avoid the absence of ferrite in the weld at room temperature.
- the proportion of N2 in the shielding gas should not be too high, otherwise the ductility of the welded joint will be reduced, and nitrogen pores will also be caused.
- the volume content of CO2 is 15-80%.
- CO2 enhances the activity of the protective gas in the welding zone, which is beneficial to increase the penetration rate of the plate and the fluidity of the liquid metal, improve the composition uniformity of the molten pool metal, and avoid aluminum elements segregation, to ensure that the composition of the weld is uniform, to avoid the strip structure due to uneven composition, especially to avoid the large ferrite formed by the aggregation of aluminum, to ensure that the ferrite is dispersed in the weld, so that the weld The performance is stable.
- the welding wire used in the welding process contains carbon, manganese, nickel and other elements that expand the austenite phase zone. Control the difference between the element content of carbon, manganese and nickel in the weld and the steel plate to be welded.
- these three elements are elements that expand the austenite phase region, compressing the high-temperature ferrite region to prevent Excess ferrite is precipitated in the weld seam before the hot stamping die is closed to increase the strength of the weld seam; on the other hand, the martensite transformation temperature of the weld seam can be reduced to ensure the martensite transformation rate.
- Carbon is an important constituent element of welding wire, which affects the machinability of welding wire and the carbon equivalent of weld.
- the austenite stability of the weld decreases, and it is difficult to ensure the strength of the weld; when the carbon content is too high, the manufacturability of the welding wire decreases, and the plasticity and toughness of the weld decrease.
- the content of C in the welding wire may be 0.05-0.15%.
- manganese can improve the austenite stability of the weld, shift the C curve to the right, and reduce the critical cooling rate of martensite. If the manganese content is too high, the manufacturability of the welding wire will be affected, and the plasticity and toughness of the weld will decrease. If the Mn content is too low, the hardenability of the weld is reduced and the strengthening effect is weakened.
- the content of Mn in the welding wire can be 0.5-1.9%.
- nickel can increase the stability of austenite in the weld, reduce the critical Ms point temperature, and improve the hardenability, strength and toughness of the weld. If the nickel content is too high, the production cost of the welding wire will increase, and the residual austenite after hot stamping of the weld seam will increase, which will affect the strength of the weld seam; the nickel content of the welding wire can be adjusted according to the strength level of the plate to be welded to ensure that the weld seam toughness needs.
- the content of Ni in the welding wire may be 0-4%, such as 0.5-4%.
- the composition of the welding wire for welding is changed based on the composition of the steel plate to be welded at the low-strength steel level.
- the composition of the welding wire can be changed accordingly, and the composition of the corresponding weld must also change.
- the structure of the weld seam is the same, but the mechanical properties of the weld seam are different, so as to meet the performance requirements of the automobile industry for tailor-welded blanks with different strengths.
- the present invention further controls welding speed and wire feeding speed, and changes the ratio of deposited metal (weld metal formed after welding wire is melted) in the weld, although the steel plate to be welded contains aluminum or aluminum Alloy coating, but the concentration of aluminum element melted into the weld of tailor welded parts can be controlled.
- the concentration of free aluminum in the weld seam of the tailored weldment is controlled at 0.1-4.0wt.% through the joint action of the shielding gas, the composition of the welding wire and the welding process.
- Al is an element that promotes the formation of ferrite. If the free Al in the weld is reduced, the ability of ferrite formation will be weakened.
- the content of free Al in the weld should be controlled at 0.1-4.0wt.%. On the one hand, it can avoid It prevents excessive ferrite from being formed in the weld and ensures the strength of the weld; on the other hand, it can avoid the formation of iron-aluminum intermetallic compounds in the weld, and keep an appropriate amount of ferrite in the weld to ensure that tailor welding at room temperature
- the weld structure of the workpiece is martensite + 1-15vol.% ferrite dispersedly distributed + 0-5vol.% retained austenite.
- the focus is on regulating the weld structure of the tailor-welded parts, mainly regulating the quantity and shape of ferrite, avoiding the formation of iron-aluminum intermetallic compounds and massive ferrite during the welding process, and finally obtaining
- the weld structure of tailor-welded parts is martensite + 1-15vol.% dispersed ferrite + 0-5vol.% residual austenite.
- a proper amount of diffusely distributed ferrite in the weld of the part is kept below, and the weld structure of the finally obtained hot stamping part is martensite + 0.1-10vol.% ferrite dispersedly distributed.
- the welding seam structure of the hot stamping part of the present invention is martensite + 0.1-10vol.% ferrite dispersedly distributed, which improves the high-speed tensile performance of the welded joint, and when the strain rate is 40-800/s, the fracture strain value of the welded joint Greater than 0.08.
- the weld seam structure of traditional hot stamping parts is single martensite. When the strain rate is 40/s, the fracture strain value of the welded joint is about 0.07; when the strain rate is 800/s, the fracture strain value of the welded joint is about 0.058. Therefore, It can be seen that the high-speed tensile fracture strain value of the hot stamping part of the present invention is significantly improved.
- the welded joint with martensite + dispersed acicular ferrite can provide more coordinated deformation opportunities for martensite when subjected to external force compared with the welded joint with single martensite.
- the substructure of martensite is mainly dislocation, and the existence of ferrite will greatly reduce the dislocation density of martensite in the weld structure compared with that of single martensite; dislocation accumulation is easy Microcracks are formed, so the risk of forming microcracks in welded joints with martensite + diffusely distributed acicular ferrite is greatly reduced compared with welded joints with single martensite; even if microcracks are formed Cracks, dispersed ferrite can also hinder the further growth and expansion of micro-cracks, so that the welded joint structure is martensite + diffusely distributed acicular ferrite than the weld structure is a single martensite. Welded joints of astenite exhibit better deformability, especially during high-speed tensioning.
- the invention adopts hot stamping steel plate with aluminum or aluminum alloy coating for tailor welding, controls the welding speed and wire feeding speed by adjusting the welding wire composition, and uses ternary shielding gas as the shielding gas to reduce the amount of free aluminum in the weld seam of tailor welded parts , the content of free aluminum in the weld is controlled at 0.1-4.0wt.%.
- it avoids excessive ferrite in the weld and ensures the strength and toughness of the weld; on the other hand, it can avoid the formation of iron-aluminum metal in the weld inter-compound, and keep a proper amount of ferrite in the weld.
- CO 2 in the shielding gas can avoid the segregation of aluminum elements, ensure the uniform composition of the weld, and avoid the formation of large ferrite due to aluminum aggregation.
- the performance is more stable.
- the obtained tailor-welded parts are hot stamped parts prepared by hot stamping. Due to the presence of AlN in the weld, the weld strength is further improved, and the quasi-static tensile fracture position of the welded joint is the base material, indicating that the weld strength is greater than that of the base metal. Meet the requirements of the automotive production field.
- the present invention ensures that the weld structure of the tailored weldment is martensite + 1-15 vol. % dispersedly distributed ferrite + 0-5 vol. %retained austenite; in this way, martensite + 0.1-10vol.% dispersed ferrite is formed in the weld structure of the hot stamping parts obtained after hot stamping of tailor welded parts, and the weld structure is full martensite Compared with the hot stamping parts of the body, the high-speed tensile performance of the welded joints of the hot stamping parts of the present invention is significantly improved, and when the strain rate is 40-800/s, the fracture strain value of the welded joints is greater than 0.08.
- thermoformed parts prepared by the tailor-welded parts obtained by the technical solution of the present invention have better high-speed deformation ability under the premise of ensuring quasi-static mechanical properties, absorb more energy during collisions, and have higher collision safety.
- Fig. 1 is a schematic diagram of tailor welding with laser filler wire in Embodiment 1 of the present invention.
- Fig. 2 is a curve diagram of quasi-static tensile properties of welded joints of hot stamping parts obtained in Example 1 of the present invention.
- Fig. 3 is a diagram of quasi-static tensile sample fracture positions of welded joints of hot stamping parts obtained in Example 1 of the present invention.
- Fig. 4 is a metallographic diagram of a welded joint of a hot stamping part obtained in Example 1 of the present invention.
- Fig. 5 is the hardness distribution of the welded joint of the hot stamping part obtained in Example 1 of the present invention.
- the laser filler wire tailor welding of the present invention uses the laser beam 40 to melt the welding wire 30 and the steel plate to be welded 10 and the steel plate to be welded 20 to realize tailor welding;
- the steel plate to be welded 10 includes a steel matrix 11 and the coatings 12 and 12' on the base.
- the steel plate 20 to be welded includes a steel base 21 and coatings 22 and 22' on the base.
- the coatings are aluminum or aluminum alloy coatings.
- Table 1 shows the composition of the steel plate 10 to be welded
- Table 2 shows the composition of the steel plate 20 to be welded
- Table 3 shows the composition of the welding wire of the present invention
- Table 4 shows the quasi-static tension of the welded joint of the hot stamping part Performance
- Table 5 shows the high-speed tensile properties of welded joints of hot stamping parts.
- the manufacturing method of steel thin-walled tailor-welded parts according to the present invention comprises the following steps:
- the two steel plates to be welded are welded by laser wire filler welding, MAG welding or laser MAG composite welding.
- Examples 1-21 and comparative examples 1-2 relate to the weight percentages of Si and Fe components in the aluminum alloy coating of the steel plate to be welded, as shown in Table 1 and Table 2, and the balance is Al and other unavoidable impurities;
- the strength levels 500MPa, 1000MPa, 1500MPa and 1800MPa involved in Examples 1-21 and Comparative Examples 1-2 refer to the tensile strength levels of the steel plates to be welded after hot stamping.
- the tensile strength (tested according to ISO 6892 standard) ranges corresponding to these four strength levels are: 500MPa grade is 400-750MPa, 1000MPa grade is 1000-1300MPa, 1500MPa grade is 1300-1700MPa, 1800MPa grade is 1700-2150MPa.
- the wire feeding speed is 4m/min
- the wire diameter is 1.2mm
- the shielding gas is 48vol.%Ar+50vol.% CO2 +2vol.% N2
- the gas flow rate is 15L/min.
- the heating temperature is 945°C
- the heating time is 4 minutes
- the pressure is maintained in the water-passing mold for 10 seconds.
- the tailor-welded blank is first austenitized, and the atoms in the coating and the steel expand each other during this heating period, so that the original coating is completely transformed into an intermetallic compound layer, and the thickness of this layer is thicker than that of the original coating. .
- this layer has the characteristics of high melting point and high hardness, which prevents the substrate from being oxidized and decarburized during the heating stage and holding pressure stage.
- the tailor welded blank undergoes martensitic transformation.
- the metallographic photo of the joint is shown in Figure 4.
- the weld structure is martensite + 4.9vol.% diffusely distributed acicular ferrite, and no iron-aluminum intermetallic compound and massive ferrite are seen.
- the hardness of the joint is shown in Figure 5. From Figure 5, it can be seen that the hardness consistency between the weld of the hot stamping part and the base metal is good.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the wire feeding speed is 2m/min
- the wire diameter is 1.0mm
- the shielding gas is 81vol.%Ar+15vol.% CO2 +4vol.% N2
- the gas flow rate is 10L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the following process is used for laser wire-filled tailor welding, using the welding wire of the present invention (see Table 3 for the welding wire composition), 0.5mm is reserved for the spliced plate gap, the welding power is 7kW, the welding speed is 50mm/s, and the defocus amount is -10mm , the wire feeding speed is 8m/min, the wire diameter is 1.2mm, the shielding gas is 10vol.%Ar+80vol.%CO 2 +10vol.%N 2 , and the gas flow rate is 25L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- Use the following process to carry out laser wire-filling tailor welding, using the welding wire of the present invention see Table 3 for the welding wire composition), reserve 0.1mm for the spliced plate gap, welding power 5kW, welding speed 120mm/s, defocus amount -5mm , the wire feeding speed is 7m/min, the wire diameter is 1.0mm, the shielding gas is 40vol.%Ar+50vol.%CO 2 +10vol.%N 2 , and the gas flow rate is 22L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the following process is used for laser wire-filling tailor welding, using the welding wire of the present invention (see Table 3 for the welding wire composition), 0.3mm is reserved for the gap between the spliced plates, the welding power is 8kW, the welding speed is 100mm/s, and the defocus amount is -8mm , the wire feeding speed is 6m/min, the wire diameter is 1.2mm, the shielding gas is 46vol.%Ar+50vol.%CO 2 +4vol.%N 2 , and the gas flow rate is 19L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- Use the following process to carry out laser wire-filling tailor welding, using the welding wire described in the present invention see Table 3 for the welding wire composition), reserve 0.3mm for the splicing plate gap, welding power 5kW, welding speed 90mm/s, defocus amount -6mm , the wire feeding speed is 5m/min, the wire diameter is 1.2mm, the shielding gas is 83vol.%Ar+15vol.%CO 2 +2vol.%N 2 , and the gas flow rate is 21L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the following process is used for laser wire-filling tailor welding, using the welding wire of the present invention (see Table 3 for the welding wire composition), 0.4mm is reserved for the gap between the spliced plates, the welding power is 8kW, the welding speed is 100mm/s, and the defocus is 3mm.
- the wire feeding speed is 3m/min
- the wire diameter is 1.6mm
- the shielding gas is 81vol.%Ar+18vol.% CO2 +1vol.% N2
- the gas flow rate is 23L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- Table 3 for the welding wire composition
- the welding power is 8kW
- the welding speed is 88mm/s
- the defocus amount is -3mm
- the wire feeding speed is 5m/min
- the wire diameter is 1.2mm
- the shielding gas is 74vol.%Ar+16vol.%CO 2 +10vol.%N 2
- the gas flow rate is 18L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- Use the following process to carry out laser wire-filling tailor welding adopt the welding wire of the present invention (see Table 3 for the welding wire composition), reserve 0.4mm for the gap between spliced plates, weld power 5.5kW, welding speed 80mm/s, defocus amount- 6mm, the wire feeding speed is 5.5m/min, the wire diameter is 1.2mm, the shielding gas is 58vol.%Ar+40vol.%CO 2 +2vol.%N 2 , and the gas flow rate is 17L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- Use the following process to carry out laser wire-filling tailor welding adopt the welding wire of the present invention (see Table 3 for the welding wire composition), reserve 0.35mm for the spliced plate gap, weld power 7.5kW, welding speed 110mm/s, defocus amount- 7.5mm, wire feeding speed 7.5m/min, wire diameter 1.4mm, shielding gas 51vol.%Ar+45vol.%CO 2 +4vol.%N 2 , gas flow 19L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the following process is used for laser wire-filling tailor welding, using the welding wire of the present invention (see Table 3 for the welding wire composition), 0.25mm is reserved for the spliced plate gap, the welding power is 6.5kW, the welding speed is 85mm/s, and the defocus amount is - 5.5mm, wire feeding speed 5.5m/min, wire diameter 1.2mm, shielding gas 65vol.%Ar+30vol.%CO 2 +5vol.%N 2 , gas flow 12L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- Adopt the following process to carry out laser wire filling tailor welding adopt the welding wire of the present invention (the welding wire composition is shown in Table 3), reserve 0.3mm for the spliced plate gap, welding power 7.5kW, welding speed 105mm/s, defocus amount- 4.5mm, wire feeding speed 8m/min, wire diameter 1.0mm, shielding gas 59vol.%Ar+35vol.%CO 2 +6vol.%N 2 , gas flow 14L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the following process is used to carry out laser filler wire tailor welding, using the welding wire of the present invention (the welding wire composition is shown in Table 3), the spliced plate gap is reserved for 0.35mm, the welding power is 4.5kW, the welding speed is 65mm/s, and the defocus amount is - 7mm, wire feeding speed 4.5m/min, wire diameter 1.2mm, shielding gas 67vol.%Ar+25vol.%CO 2 +8vol.%N 2 , gas flow rate 11L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the following process is used to carry out laser filler wire tailor welding, using the welding wire of the present invention (see Table 3 for the welding wire composition), 0.2mm is reserved for the spliced plate gap, the welding power is 5.5kW, the welding speed is 70mm/s, and the defocus amount is - 6.5mm, wire feeding speed 5m/min, wire diameter 1.2mm, shielding gas 73vol.%Ar+20vol.%CO 2 +7vol.%N 2 , gas flow 16L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- Adopt the following process to carry out arc tailor welding with active gas shielding of molten electrode adopt the welding wire according to the present invention (see Table 3 for the welding wire composition), reserve 0.4mm in the splicing plate gap; the welding current is 110A, the welding voltage is 22V, and the welding speed 500mm/min, the wire diameter is 1.2mm, the shielding gas is 76vol.%Ar+20vol.%CO 2 +4vol.%N 2 , and the gas flow rate is 13L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the following process is used for laser wire-filling tailor welding, using the welding wire of the present invention (see Table 3 for the welding wire composition), 0.3mm is reserved for the spliced plate gap, the welding power is 4kW, the welding speed is 60mm/s, and the defocus amount is -6.5 mm, the wire feeding speed is 4m/min, the wire diameter is 1.2mm, the shielding gas is 56vol.%Ar+35vol.%CO 2 +9vol.%N 2 , and the gas flow rate is 20L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the following process is used to carry out laser MAG composite tailor welding, using the welding wire according to the present invention (see Table 3 for the welding wire composition), welding power 3kW, welding speed 80mm/s, 0.3mm gap reserved for spliced plates, and defocus amount 2mm;
- the current of the MAG heat source is 120A, the voltage is 20V;
- the wire feeding speed is 6m/min, the wire diameter is 1.2mm;
- the shielding gas is 78vol.%Ar+20vol.%CO 2 +2vol.%N 2 , and the gas flow rate is 24L/min .
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the following process is used for laser wire-filling tailor welding, using the welding wire of the present invention (see Table 3 for the welding wire composition), 0.1mm is reserved for the spliced plate gap, the welding power is 5kW, the welding speed is 85mm/s, and the defocus amount is -8.5 mm, the wire feeding speed is 6m/min, the wire diameter is 1.0mm, the shielding gas is 40vol.%Ar+50vol.%CO 2 +10vol.%N 2 , and the gas flow rate is 25L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- Table 3 for the welding wire composition
- welding power is 5kW
- welding speed is 83mm/s
- defocus is -6mm
- the wire feeding speed is 7m/min
- the wire diameter is 1.2mm
- the shielding gas is 40vol.%Ar+50vol.%CO 2 +10vol.%N 2
- the gas flow rate is 19L/min.
- Example 2 After welding, the same hot stamping process as in Example 1 is used for hot stamping.
- the quasi-static tensile properties of welded joints of hot stamping parts are shown in Table 4.
- the high-speed tensile properties of welded joints of hot stamping parts are shown in Table 5.
- the weld microstructure of hot stamping parts obtained by ablation welding is full martensite.
- the high-speed tensile test results of the prepared tailor-welded hot stamping parts are shown in Table 5, and the test was carried out with reference to the standard ISO/DIS 26203-2.
- Table 5 The results of the high-speed tensile test of the welded joint are shown in Table 5, and the test was carried out with reference to the standard ISO/DIS 26203-2.
- the quasi-static tensile fracture position of the welded joint of the hot stamping part obtained by the present invention is the base material, indicating that the strength of the weld seam is greater than that of the low-strength base material, which meets the requirements in the field of automobile production.
- the high-speed tensile properties of the welded joints are significantly improved, and the fracture strain value of the welded joints is greater than 0.09 when the strain rate is 40-800/s.
- thermoformed parts prepared by the tailor-welded parts obtained by the technical solution of the present invention have better high-speed deformation ability under the premise of ensuring quasi-static mechanical properties, absorb more energy during collisions, and have higher collision safety.
- Example 1 0.15 1.2 4
- Example 2 0.13 1.1 2.5
- Example 3 0.15 1.9 4
- Example 4 0.09 1.1 3.2
- Example 5 0.14 1.9 3.1
- Example 6 0.1 1.2 0.5 Example 7 0.09 1.9 4
- Example 8 0.08 1.2 1.5
- Example 9 0.15 1.8 2
- Example 10 0.14 1.6 2.4
- Example 11 0.05 1.9 4
- Example 12 0.15 0.5 1.2
- Example 13 0.15 0.5 2.6
- Example 14 0.08 1.3
- Example 15 0.12 1.9 1.8
- Example 16 0.13 1.2 2.5
- Example 17 0.12 1.6 3.2
- Example 18 0.13 1.7 1
- Example 19 0.15 0.7 0
- Example 20 0.05 1.7 0.7
- Example 21 0.13 1.38 3.0 Comparative example 1 - - - Comparative example 2 0.09 2.7 1.5
- the weld structure of the tailored weldment obtained in Examples 1-21 is martensite + 1-15vol.% acicular ferrite dispersedly distributed + 0-5vol.% retained austenite, and the concentration of free aluminum in the weld is 0.1 ⁇ 4.0wt.%.
- Tailored welded parts are hot stamped parts obtained by hot stamping forming process, so that a proper amount of dispersed ferrite in the weld seam of the hot stamped part is retained below, and the weld seam of the hot stamped part finally obtained
- the structure is martensite + 0.1-10vol.% diffusely distributed acicular ferrite, iron-free aluminum intermetallic compound and massive ferrite.
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Abstract
Description
C | Mn | Ni | |
实施例1 | 0.15 | 1.2 | 4 |
实施例2 | 0.13 | 1.1 | 2.5 |
实施例3 | 0.15 | 1.9 | 4 |
实施例4 | 0.09 | 1.1 | 3.2 |
实施例5 | 0.14 | 1.9 | 3.1 |
实施例6 | 0.1 | 1.2 | 0.5 |
实施例7 | 0.09 | 1.9 | 4 |
实施例8 | 0.08 | 1.2 | 1.5 |
实施例9 | 0.15 | 1.8 | 2 |
实施例10 | 0.14 | 1.6 | 2.4 |
实施例11 | 0.05 | 1.9 | 4 |
实施例12 | 0.15 | 0.5 | 1.2 |
实施例13 | 0.15 | 0.5 | 2.6 |
实施例14 | 0.08 | 1.3 | 1.3 |
实施例15 | 0.12 | 1.9 | 1.8 |
实施例16 | 0.13 | 1.2 | 2.5 |
实施例17 | 0.12 | 1.6 | 3.2 |
实施例18 | 0.13 | 1.7 | 1 |
实施例19 | 0.15 | 0.7 | 0 |
实施例20 | 0.05 | 1.7 | 0.7 |
实施例21 | 0.13 | 1.38 | 3.0 |
对比例1 | - | - | - |
对比例2 | 0.09 | 2.7 | 1.5 |
Claims (15)
- 一种钢制薄壁拼焊件的制造方法,其特征是,包括如下步骤:1)钢板焊前准备取两块强度级别相同或不同的待焊接钢板,焊前对待焊接钢板进行表面清洁,所述待焊接钢板包括基体及其至少一个表面上有铝或铝合金镀层,所述镀层包括与所述基体接触的金属间化合物合金层及其上的金属合金层,所述待焊接钢板的镀层不做去除或减薄处理;2)焊接预置对接间隙将待焊接钢板的对接间隙预置为0.1~0.5mm;3)焊接采用激光填丝焊、MAG焊或激光MAG复合焊进行焊接;其中,激光填丝焊中焊接速度为40~120mm/s,送丝速度为2~8m/min;MAG焊的焊接速度为300~800mm/min;激光MAG复合焊的焊接速度为60~150mm/s,送丝速度为4~10m/min;保护气体为Ar+15~80vol.%CO 2+1~10vol.%N 2,保护气体流量为10~25L/min;焊接用焊丝的成分中C、Mn、Ni的含量减去待焊接钢板A中对应元素的含量,所得差值△C、△Mn、△Ni满足以下要求:待焊接钢板A的抗拉强度<900MPa,△C:-0.05~0.09wt.%,△Mn:-0.5~1.4wt.%,△Ni:0~4.0wt.%;或900MPa≤待焊接钢板A的抗拉强度<1300MPa,△C:-0.1~0.09wt.%,△Mn:-2~1.4wt.%,△Ni:0~4.0wt%;或1300MPa≤待焊接钢板A的抗拉强度<1700MPa,△C:-0.21~-0.05wt.%,△Mn:-1.4~1.4wt.%,△Ni:1.76~4.0wt%;或待焊接钢板A的抗拉强度≥1700MPa,△C:-0.26~-0.15wt.%,△Mn:-1.4~0.7wt.%,△Ni:2.26~4.0wt%;其中,所述待焊接钢板A为强度级别相同的两块待焊接钢板中的其中之一,或强度级别不同的两块待焊接钢板中强度级别较低的待焊接钢板;其中,所述拼焊件的焊缝组织为马氏体+1~15vol.%弥散分布的铁素体+0~5vol.%残余奥氏体;焊缝中的游离铝含量为0.1~4.0wt.%。
- 如权利要求1所述的钢制薄壁拼焊件的制造方法,其特征是,步骤3)中,所述保护气体中CO 2含量为15~50vol.%。
- 如权利要求1或2所述的钢制薄壁拼焊件的制造方法,其特征是,步骤3)中,所述保护气体中N 2含量为2~4vol.%。
- 如权利要求1所述的钢制薄壁拼焊件的制造方法,其特征是,所述MAG焊或激光MAG复合焊的焊接电流为110~130A,焊接电压为18~25V。
- 如权利要求1所述的钢制薄壁拼焊件的制造方法,其特征是,所述激光填丝焊或激光MAG复合焊工艺中离焦量为-10~10mm,激光功率控制范围3~8kW;优选的,所述激光填丝焊或激光MAG复合焊工艺中,激光加工头输出的最小光斑直径为0.3~1.6mm。
- 如权利要求1所述的钢制薄壁拼焊件的制造方法,其特征是,所述镀层为铝合金镀层,所述铝合金镀层的成分按重量百分比为:Si:5~11%,Fe:0~4%,其余量为Al及其它不可避免的杂质。
- 如权利要求1所述的钢制薄壁拼焊件的制造方法,其特征是,所述待焊接钢板A的抗拉强度<900MPa,其成分重量百分比为:C:0.06~0.1%,0<Si≤0.1%,Mn:0.5~1.0%,P<0.03%,S<0.01%,Al<0.1%,0<Cr≤0.1%,0<Ti≤0.05%,其余为Fe及其它不可避免的杂质;或所述待焊接钢板A的抗拉强度大于等于900MPa小于1300MPa,其成分重量百分比为:C:0.06~0.15%,Si:0.3~1.0%,Mn:0.5~2.5%,P≤0.10%,S≤0.05%,Al:0.02~0.30%,Cr:0.05~0.5%,Nb:0.02~0.20%,V≤0.15%,Ti:0.01~0.10%,Mo≤0.5%,Ni≤0.5%,B:0.001~0.01%,余量为Fe及其它不可避免的杂质;或所述待焊接钢板A的抗拉强度大于等于1300MPa小于1700MPa,其成分重量百分比为:C:0.2~0.3%,Si:0.1~0.5%,Mn:0.5~2.5%,P<0.015%,S<0.05%, Al<0.1%,Ti<0.2%,B:0.0005~0.08%,Cr:0.01~1%,Ni≤0.24%,余量为Fe及其它不可避免的杂质;或所述待焊接钢板A的抗拉强度≥1700MPa,其成分重量百分比为:C:0.30~0.39%,Si:0.05~0.6%,Mn:0.5~2.5%,P≤0.015%,S≤0.01%,Al:0.01~0.07%,Cr≤1.0%,Nb≤0.08%,V≤0.1%,Ti:0.01~0.12%,Mo:0.01~0.5%,Ni<0.25%,B:0.0001~0.005%,N≤0.006%,余量为Fe及其它不可避免的杂质。
- 如权利要求1所述的钢制薄壁拼焊件的制造方法,其特征是,所述焊丝的成分按重量百分百为:C:0.05~0.15%,Mn:0.5~1.9%,Ni:0~4%、优选0.5~4%,余量为Fe及其它不可避免的杂质。
- 一种钢制薄壁拼焊件,其由两块强度级别相同或不同的待焊接钢板焊接而成,所述待焊接钢板包括基体及其至少一个表面上有铝或铝合金镀层,所述镀层包括与所述基体接触的金属间化合物合金层及其上的金属合金层,所述钢制薄壁拼焊件的焊缝组织为马氏体+1~15vol.%弥散分布的铁素体+0~5vol.%残余奥氏体,焊缝中的游离铝含量为0.1~4.0wt.%;优选地,所述制薄壁拼焊件采用权利要求1-8中任一项所述的方法制备得到。
- 一种热冲压部件,其特征是,所述热冲压部件的焊缝组织为马氏体+0.1~10vol.%弥散分布的铁素体,焊接接头准静态拉伸断裂位置为母材,接头延伸率不低于4%;焊接接头在应变速率为40~800/s时,焊接接头拉伸断裂应变值大于0.08。
- 如权利要求10所述的热冲压部件,其特征是,所述热冲压部件采用权利要求1-8中任一项所述的制造方法获得的钢制薄壁拼焊件制备得到,或采用权利要求9所述的钢制薄壁拼焊件制备得到。
- 如权利要求10所述的热冲压部件,其特征是,所述热冲压部件的焊缝组织中铁素体含量为0.5~5vol.%;和/或所述热冲压部件的焊缝组织中铁素体呈针状。
- 如权利要求10所述的热冲压部件,其特征是,所述热冲压部件的焊接接头在应变速率为40~800/s时,焊接接头拉伸断裂应变值大于0.09。
- 一种制造热冲压部件的方法,其特征是,该方法包括采用权利要求1-8中任一项所述的制造钢制薄壁拼焊件的方法制造钢制薄壁拼焊件的步骤,以及对所制造得到的钢制薄壁拼焊件进行热冲压淬火的步骤。
- 如权利要求14所述的方法,其特征是,所述热冲压淬火中,加热温度为920~950℃,加热时间为3~6分钟,在通水模具中保压8~20秒钟。
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