WO2022198374A1 - 显示基板及其制备方法、显示装置、彩膜基板 - Google Patents
显示基板及其制备方法、显示装置、彩膜基板 Download PDFInfo
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Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/8791—Arrangements for improving contrast, e.g. preventing reflection of ambient light
- H10K59/8792—Arrangements for improving contrast, e.g. preventing reflection of ambient light comprising light absorbing layers, e.g. black layers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/1201—Manufacture or treatment
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- G—PHYSICS
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- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/201—Filters in the form of arrays
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/38—Devices specially adapted for multicolour light emission comprising colour filters or colour changing media [CCM]
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
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Definitions
- This article relates to, but is not limited to, the field of display technology, especially a display substrate and its manufacturing method, a display device, and a color filter substrate.
- OLED Organic Light Emitting Diode
- TFT Thin Film Transistor
- Embodiments of the present disclosure provide a display substrate and a method for manufacturing the same, a display device, and a color filter substrate.
- an embodiment of the present disclosure provides a display substrate, comprising: a base substrate, a display structure layer disposed on the base substrate, and a light adjustment layer disposed on a light exit side of the display structure layer.
- the display structure layer includes a plurality of sub-pixels; the orthographic projection of the light-adjusting layer on the base substrate does not overlap with the opening regions of the plurality of sub-pixels; the light-adjusting layer is configured to adjust the distance from the display The outgoing direction of at least one color light emitted from the structural layer.
- the display structure layer further includes: a color filter layer on the light-emitting side of the plurality of sub-pixels.
- the color filter layer includes a black matrix and a plurality of periodically arranged color filter units, and the black matrix is located between adjacent color filter units.
- the light adjustment layer is located on a side of the black matrix away from the base substrate.
- the orthographic projection of the black matrix on the base substrate covers the orthographic projection of the light modulation layer on the base substrate.
- the light adjustment layer includes at least one light adjustment part located on at least one side of the at least one color filter unit.
- the luminance ratios of different colors of light of the display substrate at a target viewing angle are adjusted by at least one of the following: the distance from the light adjustment part to the corresponding sub-pixel, the first degree of the light adjustment part a length, the second length of the light adjustment part.
- the first length is a dimension of the light adjusting portion along a first direction, and the first direction is perpendicular to the plane where the display substrate is located.
- the second length is the dimension of the light adjusting part along a second direction, the second direction being parallel to the plane of the display substrate and intersecting with the center line of the sub-pixel corresponding to the light adjusting part.
- the second length of the light adjustment portion is greater than or equal to the critical width D
- d 0 is the vertical distance from the light adjusting part to the center line of the corresponding sub-pixel
- ⁇ is the oblique viewing angle
- n 1 is the refractive index of the first medium
- n 2 is the refractive index of the light adjusting part.
- the vertical distance d 0 a 1 /2+d from the light adjustment part to the center line of the corresponding sub-pixel
- a 1 is the size of the sub-pixel corresponding to the light adjustment part
- d is The distance from the light adjusting part to the corresponding sub-pixel, wherein d is greater than 0 and less than the difference between the distance between adjacent sub-pixels and the second length of the light adjusting part between the adjacent sub-pixels.
- the cross section of the light adjustment part in a plane passing through the center line of the sub-pixel corresponding to the light adjustment part and perpendicular to the base substrate, is rectangular, or the light adjustment part
- the second length of the bottom portion of the portion is greater than the second length of the top portion.
- the color filter layer includes: a first color filter unit, a second color filter unit and a third color filter unit which are periodically arranged.
- the light adjustment layer includes at least one of the following: a first light adjustment part located on the side of the first color filter unit away from the second color filter unit; a fourth light adjusting part on the side of the light unit, a second light adjusting part on the side of the second color filter unit close to the first color filter unit, and a second light adjusting part on the side of the second color filter unit close to the third color filter unit The third light adjustment part on one side of the light unit.
- the second light adjusting part and the fourth light adjusting part are integrally formed.
- the second length of the integrated structure formed by the second light adjusting part and the fourth light adjusting part is greater than or equal to the critical width of the second light adjusting part and the fourth light adjusting part the largest of the critical widths.
- the second length is the dimension of the light adjustment part along a second direction, the second direction is parallel to the plane where the display substrate is located, and intersects the center line of the sub-pixel corresponding to the light adjustment part.
- the first color filter unit is a red filter unit
- the second color filter unit is a green filter unit
- the third color filter unit is a blue filter unit .
- the first light adjustment part and the fourth light adjustment part are configured to adjust the exit direction of the first color light emitted from the first color filter unit; the second light adjustment part and the third light adjustment part are configured as The exit direction of the second color light exiting from the second color filter unit is adjusted.
- the first length of the first light adjustment part and the fourth light adjustment part is greater than or equal to the first length of the second light adjustment part, and is greater than or equal to the first length of the third light adjustment part.
- the first length is a dimension of the light adjusting portion along a first direction, and the first direction is perpendicular to the plane where the display substrate is located.
- the first length of the first light adjustment part and the fourth light adjustment part is about 0.7 micrometers to 1.2 micrometers, and the first length of the second light adjustment part is about 0.1 micrometers to 0.5 micrometers ⁇ m, the first length of the third light adjustment part is about 0.01 ⁇ m to 0.3 ⁇ m.
- the second lengths of the first light adjusting portion, the second light adjusting portion, the third light adjusting portion, and the fourth light adjusting portion are substantially the same.
- the second length is the dimension of the light adjusting portion along a second direction, the second direction being parallel to the plane of the display substrate and intersecting with the center line of the sub-pixel corresponding to the light adjusting portion.
- the material of the light adjustment layer is a negative refractive index material.
- the sub-pixel includes a light-emitting element and a driving circuit for driving the light-emitting element to emit light.
- the light-emitting element comprises: a first electrode, a second electrode and an organic light-emitting layer arranged between the first electrode and the second electrode, the first electrode is located on the side of the second electrode close to the base substrate . There is an inclination angle between the plane where the first electrode is located and the plane where the base substrate is located.
- an embodiment of the present disclosure provides a display device including the above-mentioned display substrate.
- an embodiment of the present disclosure provides a method for preparing a display substrate, which is used for preparing the above-mentioned display substrate.
- the preparation method includes: forming a display structure layer on a base substrate; and forming a light adjustment layer on the light emitting side of the display structure layer.
- the display structure layer includes a plurality of sub-pixels. The orthographic projection of the light adjustment layer on the base substrate does not overlap with the opening areas of the plurality of sub-pixels; the light adjustment layer is configured to adjust the exit direction of at least one color light emitted from the display structure layer .
- an embodiment of the present disclosure provides a color filter substrate, including: a substrate, a color filter layer disposed on the substrate, and a light adjustment layer.
- the color filter layer includes a black matrix and a plurality of color filter units arranged periodically, and the light adjustment layer is disposed on the side of the black matrix away from the substrate; the light adjustment layer is configured to adjust from The outgoing direction of at least one color light emitted from the color filter layer.
- 1 is a schematic diagram of a spectrum of a display substrate at a viewing angle of 0° and a viewing angle of 60°;
- FIG. 2 is a schematic diagram of a display substrate with a yellowish color cast at an oblique viewing angle
- FIG. 3 is a schematic plan view of a plurality of sub-pixels in a display area according to at least one embodiment of the present disclosure
- FIG. 4 is a schematic diagram of a partial structure of a display substrate according to at least one embodiment of the disclosure.
- FIG. 5 is a schematic structural diagram of a display substrate according to at least one embodiment of the disclosure.
- Fig. 6 is the characteristic schematic diagram of light refraction material
- FIG. 7A and 7B are schematic diagrams showing the relationship between the first length and the second length of the light adjusting portion according to at least one embodiment of the present disclosure
- FIG. 8 is another schematic structural diagram of a display substrate according to at least one embodiment of the disclosure.
- FIG. 9 is a schematic diagram of the light intensity control of the light adjustment layer at different viewing angles according to at least one embodiment of the present disclosure.
- FIG. 10 is a schematic diagram illustrating the effect of improving color shift of the display substrate at an oblique viewing angle according to at least one embodiment of the present disclosure
- FIG. 11 is a schematic diagram of luminance attenuation of a display substrate according to at least one embodiment of the disclosure.
- FIG. 12 is another schematic structural diagram of a display substrate according to at least one embodiment of the disclosure.
- 13 to 15 are three-dimensional and cross-sectional structural schematic diagrams of a light adjusting portion of at least one embodiment of the disclosure.
- 16 is another schematic structural diagram of a display substrate according to at least one embodiment of the disclosure.
- 17 is a schematic diagram of a display device according to at least one embodiment of the disclosure.
- FIG. 18 is a schematic diagram of a color filter substrate according to at least one embodiment of the disclosure.
- ordinal numbers such as “first”, “second”, and “third” are set to avoid confusion of constituent elements, rather than to limit the quantity.
- "Plurality” in this disclosure includes two and the quantity of two or more.
- the terms “installed”, “connected” and “connected” should be construed broadly unless otherwise expressly specified and limited. For example, it may be a fixed connection, or a detachable connection, or an integral connection; it may be a mechanical connection, or an electrical connection; it may be a direct connection, or an indirect connection through an intermediate piece, or an internal communication between two elements.
- installed should be construed broadly unless otherwise expressly specified and limited. For example, it may be a fixed connection, or a detachable connection, or an integral connection; it may be a mechanical connection, or an electrical connection; it may be a direct connection, or an indirect connection through an intermediate piece, or an internal communication between two elements.
- a transistor refers to an element including at least three terminals of a gate electrode, a drain electrode, and a source electrode.
- a transistor has a channel region between a drain electrode (drain electrode terminal, drain region, or drain electrode) and a source electrode (source electrode terminal, source region, or source electrode), and current can flow through the drain electrode, the channel region, and the source electrode .
- the channel region refers to a region through which current mainly flows.
- the functions of the "source electrode” and the “drain electrode” may be interchanged when using transistors of opposite polarities or when the direction of the current changes during circuit operation. Therefore, in the present disclosure, “source electrode” and “drain electrode” may be interchanged with each other.
- electrically connected includes the case where constituent elements are connected together by elements having some electrical function.
- the "element having a certain electrical effect” is not particularly limited as long as it can transmit and receive electrical signals between the connected constituent elements.
- Examples of “elements having some electrical function” include not only electrodes and wirings, but also switching elements such as transistors, resistors, inductors, capacitors, other elements having one or more functions, and the like.
- parallel refers to a state in which the angle formed by two straight lines is -10° or more and 10° or less, and thus can include a state in which the angle is -5° or more and 5° or less.
- perpendicular refers to a state in which the angle formed by two straight lines is 80° or more and 100° or less, and therefore can include a state in which an angle of 85° or more and 95° or less is included.
- film and “layer” are interchangeable.
- conductive layer may be replaced by “conductive film” in some cases.
- insulating film may be replaced with “insulating layer” in some cases.
- OLED display substrates use the microcavity effect to improve the luminous efficiency and color purity of displayed images.
- the microcavity effect is that the light emitted from the organic light-emitting layer (EL, Electro-Luminescence) is repeatedly and selectively reflected between specific layers, and transmits through the first electrode layer or the second electrode layer with increased optical intensity, thereby Improve the brightness and color purity of the final output light.
- EL organic light-emitting layer
- the light in the OLED display substrate undergoes interference superposition and interference cancellation, which will cause the OLED display substrate to have a problem of viewing angle polarization.
- FIG. 1 is a schematic diagram of the spectrum of a display substrate at a viewing angle of 0° (ie, a front viewing angle) and a viewing angle of 60°. As shown in FIG. 1 , the RGB spectral light intensity at a viewing angle of 60° is reduced compared to the red-green-blue (RGB) spectral light intensity at a viewing angle of 0°.
- RGB red-green-blue
- the intensities of red light and blue light decrease rapidly, and the RGB spectrum at a viewing angle of 60° is blue-shifted compared to the RGB spectrum at a normal viewing angle, which makes the brightness ratio of RGB synthesized white light different at a viewing angle of 60°
- the brightness ratio of the RGB synthesized white light at a positive viewing angle shows that the image quality of the OLED display substrate is abnormal at a viewing angle of 60°, and there is an abnormal state of blue or yellow.
- FIG. 2 is a schematic diagram of a display substrate having a yellowish color cast at an oblique viewing angle (ie, a viewing angle other than 0°).
- Figure 2 shows the CIE1931 chromaticity diagram.
- the X-axis chromaticity coordinates represent the proportion of the red primary color
- the Y-axis chromaticity coordinates represent the proportion of the green primary color.
- the synthesized white light corresponds to point S1 under a frontal viewing angle
- the synthesized white light corresponds to point S2 under an oblique viewing angle (eg, a viewing angle greater than 60°). It can be seen from FIG. 2 that, compared with the case of the frontal viewing angle, the display substrate has a yellowing phenomenon under the oblique viewing angle.
- At least one embodiment of the present disclosure provides a display substrate, comprising: a base substrate, a display structure layer disposed on the base substrate, and a light adjustment layer disposed on a light exit side of the display structure layer.
- the display structure layer includes a plurality of sub-pixels. The orthographic projection of the light adjustment layer on the base substrate does not overlap with the opening regions of the plurality of sub-pixels.
- the light adjustment layer is configured to adjust the exit direction of at least one color light exiting from the display structure layer.
- the light-adjusting layer provided on the light-emitting side of the display structure layer can adjust the output direction of at least one color light, and by changing the light path, the light intensity of different colors of light entering the human eye can be adjusted, Further, the viewing angle deviation existing in the display substrate is improved.
- the light adjustment layer is configured to adjust the exit direction of at least one of the following colors of light emitted from the display structure layer: red light, green light, blue light.
- the light adjustment layer only adjusts the exit direction of red light, or only adjusts the exit direction of green light, or only adjusts the exit direction of blue light, or adjusts the exit direction of at least two colors of red, green and blue light.
- this embodiment does not limit this.
- the display structure layer further includes: a color filter layer on the light-emitting side of the plurality of sub-pixels.
- the color filter layer includes a black matrix and a plurality of periodically arranged color filter units, and the black matrix is located between adjacent color filter units.
- the light adjustment layer is located on the side of the black matrix away from the base substrate.
- a plurality of color filter units may correspond to a plurality of sub-pixels one-to-one.
- the orthographic projection of the color filter unit on the base substrate covers the opening area of the corresponding sub-pixel.
- the orthographic projection of the black matrix on the base substrate covers the orthographic projection of the light adjustment layer on the base substrate.
- the orthographic projection of the color filter unit on the base substrate does not overlap with the orthographic projection of the light adjustment layer on the base substrate.
- the display substrate may be a display substrate of a COE (CF on Encapsulation, a color filter layer is formed on a thin film encapsulated organic electroluminescent device) structure.
- COE CF on Encapsulation, a color filter layer is formed on a thin film encapsulated organic electroluminescent device
- the light adjustment layer includes at least one light adjustment part located on at least one side of the at least one color filter unit.
- the at least one light adjustment part may be disposed on the periphery of the at least one color filter unit, for example, the light adjustment part may be located on one side of the color filter unit, or on opposite sides, or around the color filter unit.
- the light adjustment layer includes a plurality of light adjustment parts, and the plurality of light adjustment parts may be independent of each other, or a part of the light adjustment parts may be connected with each other to form an integrated structure, or all the light adjustment parts may be connected with each other to form an integrated structure.
- this embodiment does not limit this.
- the ratio of brightness of light of different colors of the display substrate at a target viewing angle can be adjusted by at least one of the following: the distance from the light adjustment part to the corresponding sub-pixel, the first length of the light adjustment part, the light adjustment the second length of the section.
- the first length is the dimension of the light adjusting portion along the first direction, and the first direction is perpendicular to the plane where the display substrate is located.
- the second length is the dimension of the light adjustment part along the second direction, the second direction is parallel to the plane of the display substrate and intersects the center line of the sub-pixel corresponding to the light adjustment part.
- the first length may be referred to as thickness or height
- the second length may be referred to as width.
- the distance from the light adjustment part to the corresponding sub-pixel may be the vertical distance from the edge of the light adjustment part close to the corresponding sub pixel to the edge of the opening area of the sub pixel close to the light adjustment part.
- the brightness ratio of the light of different colors of the display substrate under the target viewing angle can be adjusted by adjusting the distance from the light adjusting part to the corresponding sub-pixel, so as to improve the viewing angle deviation.
- the RGB luminance ratio under the viewing angle bias is adjusted to the optimal luminance ratio under the target viewing angle.
- the dimensions (including the first length and the second length) of the different light adjusting parts may be the same. However, this embodiment does not limit this.
- the brightness ratio of the light of different colors of the display substrate under the target viewing angle can be adjusted, so as to improve the viewing angle deviation.
- the second length of the light adjustment part is determined according to the vertical distance from the light adjustment part to the center line of the corresponding sub-pixel and the target viewing angle; the second length of the light adjustment part is determined according to the RGB brightness ratio under the viewing angle bias and the optimal brightness ratio as the adjustment target Adjustment factors for light of different colors, and based on the adjustment factors, determine the first length of the light adjustment portion, so as to achieve the optimal brightness ratio under the target viewing angle.
- the brightness ratio of different colors of light of the display substrate under the target viewing angle can be adjusted, thereby improving the viewing angle partial.
- the second length of the light adjusting part is determined according to the vertical distance from the light adjusting part to the center line of the corresponding sub-pixel and the target viewing angle;
- the optimal brightness ratio of the target is determined, and the adjustment factors of different colors of light are determined, and based on the adjustment factors, the first length of the light adjustment part is determined, so as to achieve the optimal brightness ratio under the left target viewing angle.
- the dimensions of the remaining light adjustment parts are set to be the same as those of the aforementioned light adjustment parts (including the first length and the second length). By adjusting the distances from the remaining light adjustment parts to the corresponding sub-pixels, the RGB luminance ratio under the right viewing angle is adjusted to the optimal luminance ratio under the target viewing angle.
- the second length of the light adjustment portion is greater than or equal to the critical width D
- d 0 is the vertical distance from the light adjustment part to the center line of the corresponding sub-pixel
- ⁇ is the oblique viewing angle
- n 1 is the refractive index of the first medium
- n 2 is the refractive index of the light adjustment part.
- the first medium is a medium through which light passes before entering the light adjustment part.
- the vertical distance d 0 a 1 /2+d from the light adjusting part to the center line of the corresponding sub-pixel
- a 1 is the size of the sub-pixel corresponding to the light adjusting part
- d is the distance between the light adjusting part and the corresponding sub-pixel.
- the distance between the corresponding sub-pixels, d is greater than 0 and smaller than the difference between the distance between adjacent sub-pixels and the second length of the light adjustment portion between the adjacent sub-pixels.
- the size of the sub-pixel corresponding to the light adjustment part may refer to the size of the opening area of the sub-pixel corresponding to the light adjustment part.
- the cross section of the light adjustment part in a plane passing through the center line of the sub-pixel corresponding to the light adjustment part and perpendicular to the base substrate, the cross section of the light adjustment part is rectangular, or the bottom of the light adjustment part has a rectangular shape.
- the second length is greater than the second length of the top.
- the cross section of the light adjustment part is rectangular, the height of the light adjustment part may be less than or equal to h 0 , and the width may be greater than or equal to D.
- the cross-section of the light-adjusting portion may be non-rectangular, wherein the second length of the bottom of the light-adjusting portion is greater than the second length of the top, and the second length of the portion between the bottom and the top may vary, eg, Gradually decrease, first decrease and then increase, etc.
- the cross-section of the light adjusting portion may be a trapezoid, a triangle, or a structure having an arc top surface (eg, the top surface is convex or concave).
- the maximum height of the light adjustment portion may be less than or equal to h 0
- the minimum width of the light adjustment portion may be greater than or equal to D.
- the height of the trapezoid may be less than or equal to h 0 , and the length of the upper base (ie, the second length of the top) of the trapezoid may be greater than or equal to D.
- the cross section of the light adjusting part is a triangle
- the maximum height of the triangle may be less than or equal to h 0
- the minimum width may be greater than or equal to D.
- this embodiment does not limit this.
- the color filter layer may include: a first color filter unit, a second color filter unit, and a third color filter unit that are periodically arranged.
- the light adjustment layer may include at least one of the following: a first light adjustment part located on a side of the first color filter unit away from the second color filter unit, a first light adjustment part located on a side of the first color filter unit close to the second color filter unit a fourth light adjustment part, a second light adjustment part located on the side of the second color filter unit close to the first color filter unit, and a third light adjustment part located on the side of the second color filter unit close to the third color filter unit department.
- this embodiment does not limit this.
- the second light adjusting part and the fourth light adjusting part may be an integral structure. Wherein, the second light adjusting part and the fourth light adjusting part are both located between the first color filter unit and the second color filter unit. However, this embodiment does not limit this.
- the second length of the integrated structure formed by the second light adjusting part and the fourth light adjusting part is greater than or equal to the largest of the critical width of the second light adjusting part and the critical width of the fourth light adjusting part By.
- the critical width of the second light adjusting portion is greater than the critical width of the fourth light adjusting portion
- the second length of the integrated structure formed by the second light adjusting portion and the fourth light adjusting portion is greater than or equal to the critical width of the second light adjusting portion width.
- this embodiment does not limit this.
- the first color filter unit is a red filter unit
- the second color filter unit is a green filter unit
- the third color filter unit is a blue filter unit.
- the first light adjusting part and the fourth light adjusting part are configured to adjust the exit direction of the first color light emitted from the first color filter unit; the second light adjusting part and the third light adjusting part are configured to adjust the light from the second color filter unit.
- the first length of the first light adjustment part and the fourth adjustment part is greater than or equal to the first length of the second light adjustment part, and is greater than or equal to the first length of the third light adjustment part.
- the first length of the light adjusting portion that adjusts the exit direction of the first color light is greater than or equal to the light adjusting portion that adjusts the exit direction of the second color light.
- the first light adjustment part and the fourth light adjustment part are located on opposite sides of the first color filter unit, and the second light adjustment part and the third light adjustment part are located on opposite sides of the second color filter unit .
- this embodiment does not limit this.
- the first length of the first light adjustment portion and the fourth light adjustment portion are about 0.7 to 1.2 microns
- the first length of the second light adjustment portion is about 0.1 to 0.5 microns
- the third light adjustment portion has a first length of about 0.1 to 0.5 microns.
- the first length of the light adjustment portion is about 0.01 to 0.3 microns.
- the light adjustment layer provided by this exemplary embodiment can improve the color shift when the oblique viewing angle is greater than or equal to 60°.
- the second lengths of the first light adjusting portion, the second light adjusting portion, the third light adjusting portion, and the fourth light adjusting portion are substantially the same.
- this embodiment does not limit this.
- the second lengths of the first light adjusting portion, the second light adjusting portion, the third light adjusting portion, and the fourth light adjusting portion may be different from each other, or partially the same.
- the second lengths of the different light adjustment parts need to be greater than or equal to the corresponding critical widths.
- the material of the light adjustment layer is a negative refractive index material.
- the material of the light adjustment layer may include at least one of the following: a photonic crystal material, a bi-medium negative refraction material. However, this embodiment does not limit this.
- a sub-pixel includes a light-emitting element and a driving circuit that drives the light-emitting element to emit light.
- the light-emitting element includes: a first electrode, a second electrode and an organic light-emitting layer arranged between the first electrode and the second electrode, the first electrode is located on the side of the second electrode close to the base substrate; the plane where the first electrode is located is connected to the substrate There is an inclination angle between the planes where the base substrate is located. In some examples, the inclination angles between the plane where the first electrodes of different sub-pixels are located and the plane where the base substrate is located are different.
- the orthographic projection of the light adjustment portion corresponding to the sub-pixel on the base substrate may be located on the side of the inclination angle of the first electrode facing the sub-pixel.
- the right side of the first electrode of the sub-pixel is raised so that an inclined angle is formed between the plane where the first electrode is located and the plane where the base substrate is located, and the orthographic projection of the light adjustment portion corresponding to the sub-pixel on the substrate substrate may be located to the left of the sub-pixel.
- this embodiment does not limit this.
- the display substrate of the present exemplary embodiment can improve the large variation of the monochromatic ratio of synthesized white light at different viewing angles due to the inclined angle of the first electrode, resulting in asymmetric luminance attenuation (L-Decay) in the positive and negative viewing angles. , thereby improving the viewing role bias caused by it.
- the display substrate of the present embodiment will be illustrated below through a plurality of examples.
- the display substrate is an OLED display substrate with a top emission structure as an example for description. Wherein, the light emitting side of the display structure layer is away from the base substrate.
- the display substrate may be an OLED display substrate of a bottom emission structure. Wherein, the light emitting side of the display structure layer is close to the base substrate.
- the display substrate may include a display area and a non-display area around the display area. Multiple pixel units can be regularly arranged in the display area. At least one of the plurality of pixel units includes a plurality of sub-pixels, for example, may include: a first sub-pixel emitting light of a first color, a second sub-pixel emitting light of a second color, and a third sub-pixel emitting light of a third color . However, this embodiment does not limit this. For example, at least one pixel unit may include a red sub-pixel, a green sub-pixel, a blue sub-pixel, and a white sub-pixel.
- At least one sub-pixel includes a light-emitting element and a pixel driving circuit for driving the light-emitting element to emit light.
- the pixel driving circuit in at least one sub-pixel is respectively connected with the scanning signal line, the data signal line and the light-emitting signal line, and the pixel driving circuit is configured to receive the data voltage transmitted by the data signal line under the control of the scanning signal line and the light-emitting signal line , and output the corresponding current to the corresponding light-emitting element.
- the light-emitting element in at least one sub-pixel is connected to the corresponding pixel driving circuit, and the light-emitting element is configured to emit light with corresponding brightness in response to the current output by the pixel driving circuit of the sub-pixel.
- FIG. 3 is a schematic plan view of a plurality of sub-pixels in a display area according to at least one embodiment of the present disclosure.
- a plurality of sub-pixels in the display area may be arranged in the following manner: one first sub-pixel P1, two second sub-pixels P2 and one first sub-pixel P2 on each row
- the repeating unit of the three sub-pixels P3 is arranged, and the two second sub-pixels P2 in the repeating unit are arranged along the column direction.
- the first sub-pixel P1 emits light of the first color
- the second sub-pixel P2 emits light of the second color
- the third sub-pixel P3 emits light of the third color.
- the spacing in the row direction of the sub-pixels emitting the same color light may be approximately equal to 1 to 2 times the width of the sub-pixels, eg, 1.5 times.
- the two second sub-pixels P2 may be pentagons (eg, rounded pentagons), the two second sub-pixels P2 are symmetrical with each other, and the symmetry axis is parallel to the row direction.
- the first subpixel P1 and the third subpixel P3 are respectively hexagonal (eg, rounded hexagons).
- the length of the first subpixel P1 in the column direction may be greater than the length of the third subpixel P3 in the column direction, and the length of the third subpixel P3 in the column direction may be greater than the length of the second subpixel P2 in the column direction.
- the first subpixel P1 may be a red (R) subpixel
- the second subpixel P2 may be a green (G) subpixel
- the third subpixel P3 may be a blue (B) subpixel.
- the first color light may be red light
- the second color light may be green light
- the third color light may be blue light.
- the three sub-pixels of one pixel unit are arranged in a pattern.
- this embodiment does not limit the shape and arrangement of the plurality of sub-pixels in the display area.
- the sub-pixels may be rectangular, diamond, pentagon or hexagonal.
- the three sub-pixels can be arranged horizontally or vertically; when a pixel unit includes four sub-pixels, the four sub-pixels can be arranged horizontally, vertically or squarely.
- FIG. 4 is a schematic diagram of a partial structure of a display substrate according to at least one embodiment of the present disclosure.
- FIG. 4 illustrates by taking a repeating unit of the display area as an example, and a color filter layer is provided on the light-emitting side of the sub-pixel.
- the color filter layer includes: a black matrix 501 and a first color filter unit 502a, a second color filter unit 502b and a third color filter unit 502c which are periodically arranged.
- the black matrix 501 is located between adjacent color filter units.
- the first color filter unit 502a is located on the light-emitting side of the first sub-pixel P1, and the orthographic projection of the first color filter unit 502a on the base substrate covers the opening area of the first sub-pixel P1.
- the second color filter unit 502b is located on the light-emitting side of the second sub-pixel P2, and the orthographic projection of the second color filter unit 502b on the base substrate covers the opening area of the second sub-pixel P2.
- the third color filter unit 502c is located on the light-emitting side of the third sub-pixel P3, and the orthographic projection of the third color filter unit 502c on the base substrate covers the opening area of the third sub-pixel P3.
- At least one sub-pixel includes an open area and a non-open area surrounding the open area.
- the opening area of the sub-pixel is configured for display and is not blocked by the black matrix 501 ; the non-opening area surrounds the opening area and is blocked by the black matrix 501 and is not displayed.
- the first color filter unit 502a is a red filter unit
- the second color filter unit 502b is a green filter unit
- the third color filter unit 502c is a blue filter unit.
- a light adjustment layer is provided on the side of the black matrix 501 away from the base substrate.
- the orthographic projection of the black matrix 501 on the base substrate covers the orthographic projection of the light adjustment layer on the base substrate.
- the orthographic projection of the light adjustment layer on the base substrate does not overlap with the orthographic projection of the color filter unit on the base substrate.
- the orthographic projection of the light adjustment layer on the base substrate does not overlap with the opening regions of the plurality of sub-pixels. In other words, the light adjustment layer will not block the opening area of the sub-pixel.
- the light adjustment layer includes a plurality of light adjustment parts, such as a first light adjustment part 601 , a second light adjustment part 602 and a third light adjustment part 603 .
- the first light adjustment part 601 is located on the side of the first color filter unit 502a away from the adjacent second color filter unit 502b, and the second light adjustment part 602 is located between the first color filter unit 502a and the adjacent second color filter unit 502b. Between the filter units 502b, the third light adjustment part 603 is located between the second color filter unit 502b and the adjacent third color filter unit 502c.
- the first light adjusting part 601 is configured to adjust the exit direction of the first color light emitted from the first color filter unit 502a
- the second light adjusting part 602 and the third light adjusting part 603 are configured to adjust the light from the second color filter unit 502a.
- the emission direction of the second color light emitted by the light unit 502b is configured to adjust the light from the second color filter unit 502a.
- the present embodiment does not limit the number and arrangement positions of the light adjustment parts of the light adjustment layer.
- the light adjusting part may be provided only on the periphery of the first color filter unit 502a (eg, one side, or opposite sides, or all around the first color filter unit 502a) to adjust the light from the first color filter unit 502a.
- the light adjustment part may be provided only on the periphery of the second color filter unit 502b (for example, one side, or opposite sides or around the second color filter unit 502b) , to adjust the exit direction of the second color light emitted from the second color filter unit 502b; Opposite sides or four sides) are provided with light adjustment parts to adjust the exit direction of the third color light emitted from the third color filter unit 502c; Adjust the output direction of the light emitted from the corresponding color filter unit.
- the light adjustment part of the light adjustment layer may have a unitary structure.
- the second light adjusting portion 602 of two adjacent second color filter units 502b on the side close to the first color filter unit 502a may have an integrated structure
- two adjacent second color filter units 502b may have an integrated structure
- the third light adjusting part 603 of the 502b on the side close to the third color filter unit 502c may have an integrated structure.
- all of the light-modulating portions in the light-modulating layer may be independent of each other.
- the light adjustment parts corresponding to different color filter units are independent from each other and not connected.
- At least one light adjustment part of the light adjustment layer may be a strip-like structure.
- the extending direction of the light adjustment part may be perpendicular to the sub-pixel row direction and parallel to the sub-pixel column direction.
- the extension length of the light adjustment part in the column direction of the sub-pixels may be greater than the length of the opening region of the corresponding sub-pixels in the column direction.
- the extension length of the first light adjusting part 601 along the sub-pixel column direction is greater than the length of the opening region of the first sub-pixel P1 along the column direction, and also greater than the length of the first color filter unit 502a along the sub-pixel column direction.
- the respective extension lengths of the second light adjusting portion 602 and the third light adjusting portion 603 along the sub-pixel column direction are greater than the length of the opening region of the second sub-pixel P2 along the column direction, and are also greater than the second color filter unit 502b along the sub-pixel column. the length of the direction.
- this embodiment does not limit this.
- the extension length of the at least one light adjustment part in the column direction of the sub-pixels may be equal to or smaller than the length of the opening area of the corresponding sub-pixel in the column direction.
- the extending direction of the light adjusting portion may be perpendicular to the sub-pixel column direction and parallel to the sub-pixel row direction.
- FIG. 5 is a schematic structural diagram of a display substrate according to at least one embodiment of the disclosure.
- FIG. 5 is a schematic partial cross-sectional view along the R-R direction in FIG. 4 .
- the display substrate in a plane perpendicular to the display substrate, includes: a base substrate 101 , a display structure layer disposed on the base substrate 101 , a display structure layer located away from the substrate The encapsulation layer 104 on the side of the base substrate 101, the color filter layer 105 and the light adjustment layer 106 on the side of the encapsulation layer 104 away from the base substrate 101, the flat layer 107 and the cover on the side of the light adjustment layer 106 away from the base substrate 101 layer 108.
- the display substrate may include other film layers, such as spacer columns and the like. However, this embodiment does not limit this.
- the base substrate 101 may be a flexible substrate or a rigid substrate.
- the display structure layer includes: a driving structure layer 102 disposed on the base substrate 101 , and a light emitting structure layer 103 located on the side of the driving structure layer 102 away from the base substrate 101 .
- the driving structure layer 102 includes a plurality of pixel driving circuits. At least one pixel drive circuit includes a plurality of transistors and at least one storage capacitor.
- the pixel driving circuit may be a 3T1C, 4T1C, 5T1C, 5T2C, 6T1C or 7T1C structure.
- FIG. 5 takes one transistor 211 and one storage capacitor 210 included in each sub-pixel as an example for illustration.
- the driving structure layer 102 includes: a semiconductor layer, a first gate metal layer, a second gate metal layer, and a source-drain metal layer, which are sequentially disposed on the base substrate 101 .
- a first insulating layer 201 is arranged between the semiconductor layer and the base substrate 101
- a second insulating layer 202 is arranged between the semiconductor layer and the first gate metal layer
- a second insulating layer 202 is arranged between the first gate metal layer and the second gate metal layer.
- a fourth insulating layer 204 is provided between the third insulating layer 203 , the second gate metal layer and the source-drain metal layer
- a fifth insulating layer 205 is provided on the side of the source-drain metal layer away from the base substrate 101 .
- the semiconductor layer at least includes the active layer of the transistor 211, the first gate metal layer at least includes the gate electrode of the transistor 211 and the first capacitor electrode of the storage capacitor 210, the second gate metal layer at least includes the second capacitor electrode of the storage capacitor 210, the source
- the drain metal layer includes at least the source electrode and the drain electrode of the transistor 211 .
- the first to fourth insulating layers 201 to 204 may be inorganic insulating layers, and the fifth insulating layer 205 may be an organic insulating layer. However, this embodiment does not limit this.
- the light emitting structure layer 103 includes a plurality of light emitting elements.
- the light emitting structure layer 103 may include: a pixel definition layer 302, a first electrode layer, a second electrode layer, and an organic light emitting layer disposed between the first electrode layer and the second electrode layer.
- the first electrode layer is located on the side of the second electrode layer close to the base substrate 101 .
- the first electrode layer includes a plurality of first electrodes (eg, first electrodes 301 a , 301 b and 301 c ), and the second electrode layer includes a second electrode 304 .
- the first electrode may be a reflective electrode
- the second electrode may be a transparent electrode or a transflective electrode. As shown in FIG.
- the light-emitting element of the first sub-pixel includes a first electrode 301a, a second electrode 304, and an organic light-emitting layer 303a located between the first electrode 301a and the second electrode 304;
- the light-emitting element of the second sub-pixel may be including a first electrode 301b, a second electrode 304, and an organic light-emitting layer 303b located between the first electrode 301b and the second electrode 304;
- the light-emitting element of the third sub-pixel may include a first electrode 301c, a second electrode 304 and an organic light-emitting layer 303b located between the first electrode 301b and the second electrode 304;
- the organic light-emitting layer 303c between the first electrode 301c and the second electrode 304.
- the light-emitting element of the first sub-pixel is used as an example for description.
- the first electrode 301a of the light-emitting element of the first sub-pixel is connected to the drain electrode of the corresponding transistor 211 of the pixel driving circuit through a via hole.
- the pixel definition layer 302 has a plurality of pixel definition layer openings.
- Each pixel definition layer opening exposes at least part of the corresponding first electrode 301a
- the organic light emitting layer 303a is disposed on the side of the first electrode 301a away from the base substrate 101, and is in contact with the first electrode 301a through the pixel definition layer opening
- the second electrode 304 is disposed on the side of the organic light-emitting layer 303a away from the base substrate 101, and is in contact with the organic light-emitting layer 303a.
- the organic light emitting layer 303a in the opening of the pixel definition layer emits light of the first color under the driving of the first electrode 301a and the second electrode 304 .
- the organic light-emitting layer 303b in the opening of the pixel definition layer emits light of the second color under the driving of the first electrode 301b and the second electrode 304
- the organic light-emitting layer 303c in the opening of the pixel definition layer is driven by the first electrode 301b and the second electrode 304.
- the third color light is emitted under the driving of the electrode 304 .
- the orthographic projection of the opening of the pixel definition layer on the base substrate 101 includes the orthographic projection of the opening region of the sub-pixel on the base substrate 101 .
- the organic light-emitting layer may include a stacked hole injection layer (HIL, Hole Injection Layer), a hole transport layer (HTL, Hole Transport Layer), an electron blocking layer (EBL, Electron Block Layer) , Emission Layer (EML, Emitting Layer), Hole Block Layer (HBL, Hole Block Layer), Electron Transport Layer (ETL, Electron Transport Layer) and Electron Injection Layer (EIL, Electron Injection Layer).
- HIL Hole Injection Layer
- HTL Hole Injection Layer
- HTL Hole Transport Layer
- EBL Electron Block Layer
- Emission Layer Emission Layer
- HBL Hole Block Layer
- ETL Electron Transport Layer
- EIL Electron Injection Layer
- the hole injection layer and electron injection layer of all subpixels may be a common layer connected together
- the hole transport layer and electron transport layer of all subpixels may be a common layer connected together
- all subpixels may be a common layer connected together.
- the hole blocking layer can be a common layer connected together, the light-emitting layer and the electron blocking layer of adjacent sub-pixels can have a small amount of overlap, or can be isolated, the hole blocking layer can be a common layer connected together .
- this embodiment does not limit this.
- the encapsulation layer 104 may include a stacked first encapsulation layer, a second encapsulation layer, and a third encapsulation layer.
- the first encapsulation layer and the third encapsulation layer can be made of inorganic materials, and the second encapsulation layer can be made of organic materials. However, this embodiment does not limit this.
- the cross-sections of the first light adjustment part 601 , the second light adjustment part 602 and the third light adjustment part 603 of the light adjustment layer 106 can all be rectangles, for example, the cross-sections of the three are rectangles with different sizes.
- this embodiment does not limit this.
- the cross-sectional dimensions of the different light adjusting parts may be the same; or, the cross-sectional shapes of the different light adjusting parts may be different.
- the light adjustment layer 106 may adopt a negative refractive index material, that is, a material with a refractive index less than zero.
- the material of the light adjustment layer 106 may include at least one of the following: a photonic crystal material, a dual-dielectric negative refractive index material (eg, modified polyimide).
- FIG. 6 is a schematic diagram of the characteristics of the photorefractive material.
- FIG. 6( a ) is a schematic diagram of the refraction of light by a general material
- FIG. 6( b ) is a schematic diagram of the refraction of light by a negative refractive index material.
- n 0 represents the refractive index of a general material
- n 2 represents the refractive index of a negative refractive index material
- n 1 represents the refractive index of air.
- the negative refractive index material has the property that the incident light and the refracted light are located on the same side of the interface normal. After the light passes through the negative refractive index material, the path of the light changes, and it exits on the same side as the incident direction with respect to the interface normal.
- the light adjustment layer is designed by utilizing the properties of the negative refractive index material, so that the light path emitted from the color filter layer can be changed, so as to improve the viewing angle polarization existing in the display substrate.
- FIG. 7A and 7B are schematic diagrams showing the relationship between the first length and the second length of the light adjusting portion according to at least one embodiment of the present disclosure.
- FIG. 7A and FIG. 7B are partial schematic views that pass through the center line of the sub-pixel corresponding to the light adjustment part and are perpendicular to the plane of the base substrate.
- the incident light of the light adjusting portion can be made to propagate along the first path I.
- the first length is the dimension of the light adjustment part along the first direction
- the second length is the dimension of the light adjustment part along the second direction.
- the first direction is perpendicular to the plane where the display substrate is located, and the first length may be referred to as the thickness or height of the light adjustment portion.
- the second direction is parallel to the plane where the display substrate is located, and may intersect with the center line of the sub-pixel corresponding to the light adjustment portion.
- the second length may be referred to as the width of the light adjustment portion.
- vv' represents the interface normal of the light incident from the first medium to the light adjustment part 603; ss' represents the interface normal of the light incident from the light adjustment part 603 to the first medium; oo' represents the light incident from the light adjustment part 603 to the black The interface normal of matrix 501.
- the third light adjusting portion 603 with a rectangular cross-section shown in FIG. 5 is used as an example for description. According to Figure 7A, the following relationship can be obtained:
- Equation 1 Equation 2 Equation 3 Equation 4
- the thickness h 0 of the light adjusting portion 603 has a correlation with the oblique viewing angle ⁇ and the vertical distance d 0 from the light adjusting portion 603 to the center line of the corresponding sub-pixel.
- the critical width D of the light adjusting part 603 and the oblique viewing angle ⁇ , the vertical distance d 0 from the light adjusting part 603 to the center line of the corresponding sub-pixel, the refractive index n 2 of the light adjusting part 603 , and the first medium has a correlation.
- the light adjustment part 603 is used to change the light path, which can adjust the light color with excessive brightness ratio in the RGB composite white light, thereby improving the viewing angle deviation of the display substrate.
- the light exit path will propagate along the second path II. Since the width d1 of the light adjusting portion 603 is smaller than the critical width D, the light does not reach the interface between the light adjusting portion 603 and the black matrix 501 and is refracted twice, and the light propagates along the second path II, that is, the initial propagation direction. Under such conditions, the light adjustment section 603 cannot change the light path.
- the width d 1 of the light adjustment portion of the light adjustment layer needs to be designed to be greater than or equal to the critical width D.
- the direction of the oblique viewing angle can be adjusted.
- the light intensity of at least one color light entering the human eye thereby improving the viewing angle deviation of the display substrate.
- FIG. 8 is another schematic structural diagram of a display substrate according to at least one embodiment of the disclosure.
- the display substrate in a plane perpendicular to the base substrate, the display substrate includes: a base substrate 101 , a display structure layer disposed on the base substrate 101 , a display structure layer located away from the display structure layer
- the display structure layer includes: a driving structure layer 102 disposed on the base substrate 101 , and a light emitting structure layer 103 located on a side of the driving structure layer 102 away from the base substrate 101 .
- the driving structure layer 102 includes: a semiconductor layer, a first gate metal layer, a second gate metal layer and a source-drain metal layer which are sequentially arranged on the base substrate 101 .
- the first electrode since there are traces of the source-drain metal layer under the light-emitting element, and via holes are provided in the fifth insulating layer 205 to realize the connection between the first electrode and the corresponding pixel driving circuit, the first electrode will be uneven, and there are Inclined, that is, there is an inclined angle between the first electrode and the plane where the base substrate 101 is located.
- the inclination angle of the first electrode ie, the angle between the plane where the first electrode is located and the plane where the base substrate is located
- the RGB brightness ratio of the synthetic white light is adjusted to the optimal brightness ratio to effectively improve the viewing angle.
- n k ⁇ (where k is an integer, d 1 is the optical path, here is the width of the light adjustment part, ⁇ is the wavelength, and n is the light adjustment part Refractive index), it can be seen that since different colors of light enter the same medium and propagate differently, and the ratios that need to be adjusted to synthesize different light colors of white light are also different, therefore, the corresponding adjustment of the output direction of different colors of light of the light adjustment part There will be differences in thickness and width d1 .
- the light adjustment layer 106 includes: a first light adjustment part 601 and a fourth light adjustment part 604 located on opposite sides of the first color filter unit 502a, and a second light adjustment part 604 located on opposite sides of the first color filter unit 502a
- the second light adjusting part 602 and the third light adjusting part 603 on opposite sides of the color filter unit 502b.
- the second light adjusting part 602 and the fourth light adjusting part 604 are located between the first color filter unit 502a and the second color filter unit 502b, the second light adjusting part 602 is close to the second color filter unit 502b, the fourth light The adjusting part 604 is close to the first color filter unit 502a.
- the third light adjustment part 603 is located between the second color filter unit 502b and the third color filter unit 502c.
- the first color filter unit 502a is a red filter unit
- the second color filter unit 502b is a green filter unit
- the third color filter unit 502c is a blue filter unit.
- the light adjustment layer 106 can be used to adjust the outgoing directions of the red light and the green light at the same time, so as to adjust the light intensity of the red light and the green light entering the human eye under an oblique viewing angle.
- FIG. 9 is a schematic diagram of the light intensity control of the light adjustment layer at different viewing angles according to at least one embodiment of the present disclosure. As shown in FIG. 9 , through the adjustment of the light adjustment layer 106 , the light intensity at a smaller viewing angle can be made larger, and when the viewing angle is greater than 30°, the light intensity gradually weakens as the viewing angle increases.
- FIG. 10 is a schematic diagram illustrating an effect of improving color shift of a display substrate at an oblique viewing angle according to at least one embodiment of the present disclosure.
- the synthesized white light corresponds to point S1 under the frontal viewing angle, the synthesized white light corresponding to the S2 point under the oblique viewing angle for the display substrate without the light adjustment layer, and the S3 point corresponding to the synthesized white light of the display substrate provided in this embodiment under the oblique viewing angle .
- the RGB luminance ratio under the oblique viewing angle can reach the ratio under the normal viewing angle to synthesize white light, thereby improving the yellowing of the oblique viewing angle.
- the display substrate exhibits yellowing at a viewing angle of 70°, the left viewing angle RGB luminance ratio is 3.3:6.1:0.6, and the right viewing angle RGB luminance ratio is 3.2:6.1:0.7
- the differentiated design of the light adjustment portion of the light adjustment layer of the display substrate to improve the above situation will be described.
- the oblique viewing angle is ⁇
- the sub-pixel size is a 1 ⁇ m (um)
- the distance between adjacent sub-pixels is b 1 um
- the refractive index of the light adjustment layer to the light beam is n 2
- the distance from the light adjustment part to the sub-pixel is d um
- the center line of the first sub-pixel for example, the red sub-pixel
- d 0 (a 1 /2+d)um.
- the size of the second sub-pixel (eg, green sub-pixel) is about 5um, the distance between adjacent sub-pixels is 8um, the refractive index of the light adjustment layer relative to the green light is n 2G , and the distance from the light adjustment part to the second sub-pixel is about 1um .
- the adjustment factor for the brightness of the red light and the green light may be determined based on the actual brightness ratio of RGB to be adjusted, the optimal brightness ratio to be adjusted, and a brightness adjustment algorithm. This embodiment does not limit the implementation of the brightness adjustment algorithm.
- the first light adjustment part 601 is arranged at the left side of the first subpixel at a distance of 2um from the first subpixel, and the first light adjustment part 601 is arranged at the right side of the first subpixel at a distance of 2um from the first subpixel.
- Four light adjustment parts 604 .
- the thickness of the first light adjustment part 601 is about 1.15um and the width is about 5um; the thickness of the fourth light adjustment part 604 is about 0.87um and the width is about 5um.
- the first light adjusting part 601 can adjust the red light brightness by 45% in the viewing angle range of 70° to 90°
- the fourth light adjusting part 604 can adjust the red light brightness by 34% in the viewing angle range from 70° to 90°.
- a second light adjusting part 602 is provided on the left side of the second sub-pixel at a distance of 1 um from the second sub-pixel
- a third light adjusting part 603 is provided on the right side of the second sub-pixel at a distance of 1 um from the second sub-pixel.
- the thickness of the second light adjusting part 602 is about 0.52um and the width is about 5um; the thickness of the third light adjusting part 603 is about 0.39um and the width is about 5um.
- the second light adjusting part 602 can adjust the green light brightness to decrease by 41% within the viewing angle range of 70° to 90°
- the third light adjusting part 603 can adjust the green light luminance to decrease 31% within the viewing angle range of 70° to 90°.
- the RGB luminance ratio of the left and right sides at a viewing angle of 70° can be adjusted to 3:6:1, thereby improving the color shift and yellowing of the display substrate at a viewing angle of 70°.
- the widths of the first light adjusting part 601 to the fourth light adjusting part 604 may all be 5um, so as to simplify the process. However, this embodiment does not limit this.
- the widths of the first light adjusting portion 601 and the fourth light adjusting portion 604 may be greater than or equal to 4.54um, and the widths of the second light adjusting portion 602 and the third light adjusting portion 603 may be greater than or equal to 1.82um.
- This example can eliminate the yellowing phenomenon of color cast for a viewing angle of 60°, and can significantly reduce the yellowing phenomenon of color cast at a viewing angle of 70° and 80°.
- the thickness of the light adjustment part corresponding to the first sub-pixel is the largest value and minimum width, and the maximum thickness and minimum width of the light adjustment portion corresponding to the second sub-pixel.
- the first subpixel can be determined according to the adjustment factor of the brightness of the red light and the green light on the left, the maximum thickness of the light adjustment portion corresponding to the first subpixel, and the maximum thickness of the light adjustment portion corresponding to the second subpixel
- the width of the first light adjustment portion 601 on the left side of the first subpixel and the width of the second subpixel can be determined.
- the width and thickness of the fourth light adjusting part 604 on the right side of the first sub-pixel can be designed to be the same as those of the first light adjusting part 601 , respectively.
- the width and thickness are the same, and the width and thickness of the third light adjusting part 603 on the right side of the second sub-pixel can be designed to be the same as the width and thickness of the second light adjusting part 602 , respectively.
- the attenuation of the right red light is adjusted by adjusting the distance from the fourth light adjusting part 604 to the first subpixel, and the right green light is adjusted by adjusting the distance from the third light adjusting part 603 to the second subpixel.
- the degree of light attenuation to adjust the right RGB brightness ratio to the best brightness ratio does not limit this.
- the sizes of the first light adjusting part 601 , the second light adjusting part 602 , the third light adjusting part 603 and the fourth light adjusting part 604 may be the same, wherein the cross-sectional shapes of the four light adjusting parts Can be the same, can have the same width and the same thickness.
- the attenuation degree of the red light on the left side can be adjusted by adjusting the distance from the first light adjusting part 601 to the first sub-pixel, and the right side can be adjusted by adjusting the distance between the fourth light adjusting part 604 and the first sub-pixel
- the attenuation degree of red light is adjusted by adjusting the distance from the second light adjustment part 602 to the second sub-pixel to adjust the attenuation degree of the green light on the left side
- the distance from the third light adjustment part 603 to the second sub-pixel is adjusted to adjust the right side
- the attenuation level of the filter to adjust both the right RGB luminance ratio and the left RGB luminance ratio to the optimal luminance ratio.
- this embodiment does not limit this.
- FIG. 11 is a schematic diagram of luminance attenuation of a display substrate according to at least one embodiment of the disclosure.
- FIG. 11( a ) is a schematic diagram showing the luminance attenuation of the display substrate in which the first electrode is inclined and the light adjustment layer is not provided.
- FIG. 11( b ) is a schematic diagram of luminance attenuation of the display substrate shown in FIG. 8 .
- the highest point of the bright spot of the display substrate is at a position of 4° in the negative direction, and the brightness attenuation is asymmetric, the attenuation in the positive direction is faster, and the brightness attenuation deviates in both directions, and the brightness attenuation in the positive and negative 30°
- the deviation is about 12%, and the deviation at plus or minus 45° is about 10%.
- the display substrate of the present exemplary embodiment can improve the brightness attenuation deviation existing in the positive and negative viewing angle directions by providing the light adjustment layer.
- the light intensity attenuation on both sides of the RGB sub-pixels can be regulated with the change of viewing angle by differentially designing the light adjustment parts on both sides of the first color filter unit and the second color filter unit. degree, thereby improving the visual role bias.
- FIG. 12 is another schematic structural diagram of a display substrate according to at least one embodiment of the disclosure.
- the second light adjusting part 602 and the fourth light adjusting part 604 between the first color filter unit 502a and the second color filter unit 502b may be an integral structure.
- the thickness of the integrated structure of the fourth light adjusting part 604 and the second light adjusting part 602 on the side close to the first color filter unit 502 a is greater than the thickness of the side close to the second color filter unit 502 b.
- the top surface of the second light adjusting part 602 and the side surface close to the second color filter unit 502b are connected by an inclined surface. Based on the example of the embodiment shown in FIG.
- the thickness of the second light adjusting part 602 on the side close to the first color filter unit 502a is about 0.87um
- the thickness of the second light adjusting part 602 on the side close to the second color filter unit 502b is about 0.87um.
- the thickness is about 0.52um.
- this embodiment does not limit this.
- the light path is changed by arranging a light adjustment layer, so as to adjust the light intensity of light of different colors entering the human eye under oblique viewing angles, readjust the RGB brightness ratio, and improve the viewing angle deviation of the display substrate.
- FIG. 13 to 15 are schematic diagrams of three-dimensional and cross-sectional structures of a light adjusting portion of at least one embodiment of the present disclosure.
- Fig. 13(a), Fig. 14(a) and Fig. 15(a) are schematic diagrams of the three-dimensional structure of the light adjustment part
- Fig. 13(b), Fig. 14(b) and Fig. 15(b) are the light adjustment Sectional schematic diagram of the part.
- the light adjusting portion may be a strip-like structure having different cross-sectional shapes.
- the cross section of the light adjusting portion may be a trapezoid. As shown in FIG. 14( a ) and FIG. 14( b ), the cross section of the light adjusting portion may be triangular. As shown in FIG. 15( a ) and FIG. 15( b ), the cross section of the light adjusting portion may be in a shape having a rectangular bottom and an arc top surface. Wherein, the top surface may be a convex surface. However, this embodiment does not limit this. For example, the top surface of the light adjustment part may be concave.
- the thickness of the light adjusting portion may be less than or equal to h 0 , and the thickness of the light adjusting portion may be less than or equal to h 0 .
- the width may be greater than or equal to the critical width D.
- the thickness of the light adjusting portion with a trapezoidal cross-section may be less than or equal to h 0
- the length of the upper base may be greater than or equal to the critical width D.
- the maximum thickness of the light adjusting portion with a triangular cross-section may be less than or equal to h 0 , and the length of the lower base may be greater than the critical width D.
- the maximum thickness of the light adjusting portion having an arc top shape in cross section may be less than or equal to h 0 , and the minimum width may be greater than or equal to the critical width D.
- this embodiment does not limit this.
- the structure of the display substrate according to the embodiment of the present disclosure will be described below with reference to FIG. 8 through an example of a manufacturing process of the display substrate.
- the "patterning process" referred to in the present disclosure includes processes such as depositing film layers, coating photoresist, mask exposure, developing, etching and stripping photoresist.
- Deposition can be selected from any one or more of sputtering, evaporation and chemical vapor deposition
- coating can be selected from any one or more of spray coating and spin coating
- etching can be selected from dry etching. and any one or more of wet engraving.
- “Film” refers to a layer of thin film made by depositing or coating a certain material on a substrate.
- the “film” can also be referred to as a "layer”.
- the "film” needs a patterning process in the whole production process, it is called a “film” before the patterning process, and a “layer” after the patterning process.
- the “layer” after the patterning process contains at least one "pattern”.
- a and B are arranged in the same layer means that A and B are simultaneously formed through the same patterning process.
- the same layer does not always mean that the thickness of the layer or the height of the layer is the same in the cross-sectional view.
- the projection of A includes the projection of B means that the projection of B falls within the projection range of A, or the projection of A covers the projection of B.
- the preparation process of the display substrate of this embodiment may include the following steps (1) to (6).
- a flexible display substrate with a top emission structure is taken as an example for description.
- the base substrate 101 may be a rigid substrate, such as a quartz substrate, or a glass substrate, or may be a flexible substrate, such as an organic resin substrate. However, this embodiment does not limit this.
- the driver structure layer 102 includes a plurality of driver circuits, each driver circuit including a plurality of transistors and at least one storage capacitor, eg, a 2T1C, 3T1C, or 7T1C design.
- each driver circuit including a plurality of transistors and at least one storage capacitor, eg, a 2T1C, 3T1C, or 7T1C design.
- FIG. 8 three sub-pixels are taken as an example for illustration, and the pixel driving circuit of each sub-pixel is illustrated by only one transistor 211 and one storage capacitor 210 as an example.
- the preparation process of the driving structure layer 102 may refer to the following description.
- the manufacturing process of the pixel driving circuit of the first sub-pixel is taken as an example for description.
- a first insulating film and a semiconductor film are sequentially deposited on the base substrate 101 , and the semiconductor film is patterned through a patterning process to form a first insulating layer 201 covering the entire base substrate 101 and a semiconductor film disposed on the first insulating layer 201
- the layer pattern, the semiconductor layer pattern at least includes the active layer of the transistor 211 .
- a second insulating film and a first metal film are sequentially deposited, and the first metal film is patterned through a patterning process to form a second insulating layer 202 covering the semiconductor layer pattern, and a first gate disposed on the second insulating layer 202
- the metal layer pattern, the first gate metal layer pattern at least includes the gate electrode of the transistor 211 and the first capacitor electrode of the storage capacitor 210 .
- the second gate metal layer pattern includes at least a second capacitor electrode of the storage capacitor 210 , and the position of the second capacitor electrode corresponds to the position of the first capacitor electrode.
- a fourth insulating film is deposited, and the fourth insulating film is patterned by a patterning process to form a pattern of a fourth insulating layer 204 covering the second gate metal layer, and at least two first via holes are opened on the fourth insulating layer 204, The fourth insulating layer 204, the third insulating layer 203 and the second insulating layer 202 in the two first via holes are etched away, exposing the surface of the active layer.
- a third metal film is deposited, and the third metal film is patterned by a patterning process, and a source-drain metal layer pattern is formed on the fourth insulating layer 204 , and the source-drain metal layer at least includes the source electrode and the drain electrode of the transistor 211 .
- the source electrode and the drain electrode may be connected to the active layer through the first via holes, respectively.
- a fifth insulating film is coated on the base substrate 101 on which the aforementioned pattern is formed to form a fifth insulating layer 205 covering the entire base substrate 101 , and the fifth insulating layer 205 is formed on the fifth insulating layer 205 by masking, exposing and developing processes.
- a plurality of second vias are formed.
- the fifth insulating layer 205 in the plurality of second via holes is developed to expose the surface of the drain electrode of the transistor 211 of the pixel driving circuit of the first sub-pixel and the leakage current of the corresponding transistor of the pixel driving circuit of the second sub-pixel respectively.
- the active layer, the gate electrode, the source electrode and the drain electrode can form a transistor 211
- the first capacitor electrode and the second capacitor electrode can form a storage capacitor 210 .
- the pixel driving circuit of the second sub-pixel and the pixel driving circuit of the third sub-pixel can be formed simultaneously.
- the first insulating layer 201 , the second insulating layer 202 , the third insulating layer 203 and the fourth insulating layer 204 are silicon oxide (SiOx), silicon nitride (SiNx) and silicon oxynitride ( Any one or more of SiON), which may be a single layer, a multi-layer or a composite layer.
- the first insulating layer 201 is called a buffer layer, which is used to improve the water and oxygen resistance of the base substrate; the second insulating layer 202 and the third insulating layer 203 are called gate insulating (GI, Gate Insulator) layers;
- the fourth insulating layer 204 is called an Interlayer Dielectric (ILD, Interlayer Dielectric) layer.
- ILD Interlayer Dielectric
- the fifth insulating layer 205 may be an organic material such as polyimide, acrylic or polyethylene terephthalate.
- the fifth insulating layer 205 is called a planarization (PLN, Planarization) layer.
- the first metal thin film, the second metal thin film and the third metal thin film are made of metal materials such as any one or more of silver (Ag), copper (Cu), aluminum (Al), titanium (Ti) and molybdenum (Mo).
- Various, or alloy materials of the above metals such as aluminum neodymium alloy (AlNd) or molybdenum niobium alloy (MoNb), can be a single-layer structure, or a multi-layer composite structure, such as Ti/Al/Ti and the like.
- the semiconductor film adopts amorphous indium gallium zinc oxide (a-IGZO), zinc oxynitride (ZnON), indium zinc tin oxide (IZTO), amorphous silicon (a-Si), polycrystalline silicon (p-Si), hexathiophene , polythiophene and other materials, that is, the present disclosure is applicable to transistors manufactured based on oxide technology, silicon technology and organic matter technology.
- a-IGZO amorphous indium gallium zinc oxide
- ZnON zinc oxynitride
- IZTO indium zinc tin oxide
- a-Si amorphous silicon
- p-Si polycrystalline silicon
- hexathiophene polythiophene and other materials
- a light-emitting element is formed on the base substrate on which the pattern is formed.
- a conductive thin film is deposited on the base substrate 101 on which the aforementioned patterns are formed, and the conductive thin film is patterned through a patterning process to form a first electrode layer pattern.
- the first electrode layer includes a plurality of first electrodes.
- the first electrode is a reflective anode. As shown in FIG.
- the first electrode 301a of the first sub-pixel is connected to the drain electrode of the transistor 211 through the second via hole, and the first electrode 301b of the second sub-pixel is driven to the pixel of the second sub-pixel through the second via hole
- the drain electrode of the corresponding transistor of the circuit is connected, and the first electrode 301c of the third sub-pixel is connected to the drain electrode of the corresponding transistor of the pixel driving circuit of the third sub-pixel through the second via hole.
- the first electrode may employ a metallic material, such as any one or more of magnesium (Mg), silver (Ag), copper (Cu), aluminum (Al), titanium (Ti), and molybdenum (Mo).
- a metallic material such as any one or more of magnesium (Mg), silver (Ag), copper (Cu), aluminum (Al), titanium (Ti), and molybdenum (Mo).
- Various, or alloy materials of the above metals such as aluminum neodymium alloy (AlNd) or molybdenum niobium alloy (MoNb) can be a single-layer structure, or a multi-layer composite structure, such as Ti/Al/Ti, etc., or, a metal and Stacked structures formed of transparent conductive materials, such as reflective materials such as ITO/Ag/ITO, Mo/AlNd/ITO, etc.
- a pixel definition film is coated on the base substrate 101 forming the aforementioned pattern, and a pixel definition layer (PDL, Pixel Definition Layer) pattern is formed by masking, exposing, and developing processes.
- the pixel definition layer 302 in the display area includes a plurality of pixel definition layer openings, and the pixel definition layer in the plurality of pixel definition layer openings is developed to expose at least the first electrode 301a of the first sub-pixel respectively. Part of the surface, at least part of the surface of the first electrode 301b of the second subpixel, and at least part of the surface of the first electrode 301c of the third subpixel.
- the pixel definition layer 302 may employ polyimide, acrylic, polyethylene terephthalate, or the like.
- a thin film of an organic material is coated on the base substrate 101 on which the aforementioned pattern is formed, and a spacer column pattern is formed by masking, exposing, and developing processes.
- the spacer posts can act as a support layer configured to support a Fine Metal Mask (FMM, Fine Metal Mask) during the evaporation process.
- FMM Fine Metal Mask
- an organic light-emitting layer and a second electrode are sequentially formed on the base substrate 101 on which the aforementioned patterns are formed.
- the second electrode is a transparent cathode.
- the light-emitting element can emit light from the side away from the base substrate 101 through the transparent cathode to realize top emission.
- the organic light emitting layer of the light emitting element includes a hole injection layer, a hole transport layer, an electron blocking layer, a light emitting layer, a hole blocking layer, an electron transport layer, and an electron injection layer.
- a hole injection layer, a hole transport layer and an electron blocking layer are sequentially formed by vapor deposition on the base substrate 101 on which the aforementioned patterns are formed by using an open mask.
- the thickness of the hole injection layer is about 0 to 20 nm
- the thickness of the hole transport layer is about 70 to 200 nm
- the thickness of the electron blocking layer is about 10 to 70 nm.
- FMM is used to sequentially evaporate to form light-emitting layers of different colors, such as a blue light-emitting layer, a green light-emitting layer and a red light-emitting layer.
- the thickness of the light emitting layer is about 10 nm to 50 nm.
- a hole blocking layer, an electron transport layer and an electron injection layer are formed by successive evaporation using an open mask.
- the thickness of the hole blocking layer is about 0 to 20 nm
- the thickness of the electron transport layer is about 10 to 50 nm
- the thickness of the resistance injection layer is about 0 to 5 nm.
- this embodiment does not limit this.
- the organic light-emitting layer is formed in the sub-pixel region to realize the connection between the organic light-emitting layer and the first electrode.
- the second electrode 304 is formed on the pixel defining layer 302 and connected to the organic light emitting layer.
- the second electrode may be made of any one or more of magnesium (Mg), silver (Ag), aluminum (Al), or any one or more of the aforementioned metals alloys, or using transparent conductive materials, such as indium tin oxide (ITO), or a multi-layer composite structure of metals and transparent conductive materials.
- Mg magnesium
- Ag silver
- Al aluminum
- ITO indium tin oxide
- the ratio of magnesium to silver of the second electrode may be about 1:9 to 8:2.
- the thickness of the second electrode may be about 5 nm to 30 nm. However, this embodiment does not limit this.
- a light coupling layer may be formed on the side of the second electrode 304 away from the base substrate 101 , and the light coupling layer may be a common layer of a plurality of sub-pixels.
- the light coupling layer can cooperate with the transparent cathode to increase the light output.
- the material of the light coupling layer can be a semiconductor material. However, this embodiment does not limit this.
- an encapsulation layer 104 is formed on the base substrate 101 on which the aforementioned patterns are formed, and the encapsulation layer 104 may include a stacked first encapsulation layer, a second encapsulation layer, and a third encapsulation layer.
- the first encapsulation layer is made of inorganic material and covers the second electrode 304 in the display area.
- the second encapsulation layer adopts an organic material.
- the third encapsulation layer is made of inorganic material and covers the first encapsulation layer and the second encapsulation layer.
- the encapsulation layer may adopt a five-layer structure of inorganic/organic/inorganic/organic/inorganic.
- a black matrix, a light adjustment layer and a color filter unit are sequentially formed.
- a black pigment or a black chrome (Cr) film is coated on the surface of the encapsulation layer 104 , and the black pigment or black chrome film is patterned through a patterning process to form a black matrix 501 on the encapsulation layer 104 .
- the black matrix 501 has a plurality of openings, and the black matrix in the plurality of openings is removed to expose the opening regions of the plurality of sub-pixels.
- a light adjusting material is coated on the surface of the black matrix 501, and a light adjusting layer 106 is formed on the black matrix 501 through a process of masking, exposing and developing.
- the light modulating material may be a negative refractive index material, eg, a photonic crystal material, a bi-dielectric negative refractive index material. Then, a plurality of first color filter units (eg, red filter units), a plurality of second color filter units (eg, green filter units), and a plurality of third color filter units (eg, blue filter units) are sequentially formed color filter unit). Taking the formation of a red filter unit as an example, red resin is firstly coated on the encapsulation layer 104 on which the black matrix 501 and the light adjustment layer 106 have been formed, and after baking and curing, the red filter unit is formed by exposing and developing through a mask.
- red resin is firstly coated on the encapsulation layer 104 on which the black matrix 501 and the light adjustment layer 106 have been formed, and after baking and curing, the red filter unit is formed by exposing and developing through a mask.
- the formation process of the green filter unit and the blue filter unit is similar, so it will not be repeated here.
- the light adjustment layer is formed between the formation of the color filter unit, which can avoid the influence of the preparation process of the light adjustment layer on the color filter unit.
- a flat layer 107 and a cover layer 108 are sequentially formed.
- the outgoing directions of light of different colors can be adjusted, so as to improve the viewing angle polarization of the display substrate.
- the structure of the display substrate and the manufacturing process of the display substrate according to the embodiments of the present disclosure are merely illustrative. In some exemplary embodiments, corresponding structures may be changed and patterning processes may be increased or decreased according to actual needs.
- the display substrate may be a display substrate of a bottom emission structure.
- the display structure layer may include two source-drain metal layers.
- the color filter unit can be prepared first, and then the light adjustment layer can be formed.
- this embodiment does not limit this.
- FIG. 16 is another schematic structural diagram of a display substrate according to at least one embodiment of the disclosure.
- the display substrate in a plane perpendicular to the display substrate, the display substrate includes: a base substrate 101 , a display structure layer sequentially arranged on the base substrate 101 , an encapsulation layer 104 , a light adjustment layer 106 , a flat layer 107 and Polarizer 109.
- the display structure layer includes a driving structure layer 102 and a light emitting structure layer 103 sequentially disposed on the base substrate 101 .
- the light adjustment layer 106 is located on the encapsulation layer 104, and is configured to adjust the exit directions of light of different colors emitted from the sub-pixels.
- the light adjustment layer 106 may include a plurality of light adjustment parts, eg, the first light adjustment part 601 to the fourth light adjustment part 604 .
- the first light adjusting part 601 and the fourth light adjusting part 604 are configured to adjust the output direction of the red light emitted by the red sub-pixels
- the second light adjusting part 602 and the third light adjusting part 603 are configured to adjust the green sub-pixels The direction of the green light emitted by the pixel.
- this embodiment does not limit this.
- At least one embodiment of the present disclosure further provides a method for fabricating a display substrate, which is used to fabricate the display substrate described in the above embodiments.
- the preparation method of this embodiment includes: forming a display structure layer on a base substrate; and forming a light adjustment layer on the light emitting side of the display structure layer.
- the display structure layer includes a plurality of sub-pixels. The orthographic projection of the light adjustment layer on the base substrate does not overlap with the opening regions of the plurality of sub-pixels; the light adjustment layer is configured to adjust the exit direction of at least one color light emitted from the display structure layer.
- FIG. 17 is a schematic diagram of a display device according to at least one embodiment of the disclosure.
- this embodiment provides a display device 91 including: a display substrate 910 .
- the display substrate 910 is the display substrate provided in the foregoing embodiments.
- the display substrate 910 may be an OLED display substrate.
- the display device 91 can be: OLED display device, mobile phone, tablet computer, TV, monitor, notebook computer, digital photo frame, navigator, vehicle display, watch, wristband, etc. any product or component with display function. However, this embodiment does not limit this.
- FIG. 18 is a schematic diagram of a color filter substrate according to at least one embodiment of the disclosure.
- the color filter substrate in a plane perpendicular to the color filter substrate, includes: a substrate 10 , a color filter layer 11 and a light adjustment layer 16 disposed on the substrate 10 , and a color filter layer 16 located on the light adjustment layer 16 away from the substrate 10 .
- side flat layer 12 and cover layer 13 The color filter layer 11 includes a black matrix 21 and a plurality of color filter units arranged periodically, such as a first color filter unit 22a, a second color filter unit 22b and a third color filter unit 22c.
- the light adjustment layer 16 is provided on the black matrix 21 .
- the orthographic projection of the light adjustment layer 16 on the substrate 10 is located within the orthographic projection of the black matrix 21 on the substrate 10 and does not overlap with the orthographic projection of the color filter unit on the substrate 10 .
- the light adjustment layer 16 is configured to adjust the emission direction of at least one color light emitted from the color filter layer 11 .
- the light adjustment layer 16 may include a first light adjustment part 601 , a second light adjustment part 602 , a third light adjustment part 603 and a fourth light adjustment part 604 .
- the first light adjusting part 601 and the fourth light adjusting part 604 are located on opposite sides of the first color filter unit 22a, and are configured to adjust the exit direction of the first color light emitted by the first color filter unit 22a.
- the second light adjusting part 602 and the third light adjusting part 603 are located on opposite sides of the second color filter unit 22b, and are configured to adjust the exit direction of the second color light emitted by the second color filter unit 22b.
- the first color filter unit 22a is a red filter unit
- the second color filter unit 22b is a green filter unit
- the third color filter unit 22c is a blue filter unit.
- this embodiment does not limit this.
- the color filter substrate of this embodiment may be disposed on the light emitting side of the OLED display substrate.
- the color filter substrate of this embodiment can be arranged in a cell with the array substrate to form a display panel.
- this embodiment does not limit this.
- the color filter substrate provided in this embodiment can use the light adjustment layer to adjust the outgoing directions of light of different colors, thereby improving the display viewing angle polarization.
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Abstract
Description
Claims (20)
- 一种显示基板,包括:衬底基板、设置在所述衬底基板上的显示结构层、以及设置在所述显示结构层的出光侧的光调节层;所述显示结构层包括多个子像素;所述光调节层在所述衬底基板上的正投影与所述多个子像素的开口区域没有交叠;所述光调节层配置为调节从所述显示结构层射出的至少一种颜色光的出射方向。
- 根据权利要求1所述的显示基板,其中,所述显示结构层还包括:位于所述多个子像素的出光侧的彩色滤光层;所述彩色滤光层包括黑矩阵和周期性排布的多个彩色滤光单元,所述黑矩阵位于相邻彩色滤光单元之间;所述光调节层位于所述黑矩阵远离所述衬底基板的一侧。
- 根据权利要求2所述的显示基板,其中,所述黑矩阵在所述衬底基板上的正投影覆盖所述光调节层在所述衬底基板上的正投影。
- 根据权利要求2或3所述的显示基板,其中,所述光调节层包括至少一个光调节部,所述光调节部位于至少一个彩色滤光单元的至少一侧。
- 根据权利要求4所述的显示基板,其中,所述显示基板在目标视角下的不同颜色光的亮度比例通过以下至少一项调节:所述光调节部到对应的子像素的距离、所述光调节部的第一长度、所述光调节部的第二长度;所述第一长度为所述光调节部沿第一方向的尺寸,所述第一方向垂直于所述显示基板所在平面;所述第二长度为所述光调节部沿第二方向的尺寸,所述第二方向平行于所述显示基板所在平面,且与所述光调节部对应的子像素的中心线相交。
- 根据权利要求5所述的显示基板,其中,所述光调节部的第一长度小于或等于h 0,h 0=d 0/tanθ,其中,d 0为所述光调节部至对应的子像素的中心线的垂直距离,θ为斜视角角度。
- 根据权利要求6或7所述的显示基板,其中,所述光调节部至对应的子像素的中心线的垂直距离d 0=a 1/2+d,a 1为所述光调节部对应的子像素尺寸,d为所述光调节部到对应的子像素的距离,其中,d大于0且小于相邻子像素的间距与所述相邻子像素之间的光调节部的第二长度的差值。
- 根据权利要求5所述的显示基板,其中,在经过所述光调节部对应的子像素的中心线且垂直于所述衬底基板的平面内,所述光调节部的截面呈矩形,或者,所述光调节部的底部的第二长度大于顶部的第二长度。
- 根据权利要求2或3所述的显示基板,其中,所述彩色滤光层包括:周期性排布的第一彩色滤光单元、第二彩色滤光单元和第三彩色滤光单元;所述光调节层包括以下至少之一:位于所述第一彩色滤光单元远离第二彩色滤光单元一侧的第一光调节部、位于所述第一彩色滤光单元靠近第二彩色滤光单元一侧的第四光调节部、位于所述第二彩色滤光单元靠近第一彩色滤光单元一侧的第二光调节部、位于所述第二彩色滤光单元靠近第三彩色滤光单元一侧的第三光调节部。
- 根据权利要求10所述的显示基板,其中,所述第二光调节部与第四光调节部为一体结构。
- 根据权利要求11所述的显示基板,其中,所述第二光调节部和第四光调节部形成的一体结构的第二长度大于或等于所述第二光调节部的临界宽度和所述第四光调节部的临界宽度中的最大者;所述第二长度为光调节部沿第二方向的尺寸,所述第二方向平行于所述显示基板所在平面,且与光调节部对应的子像素的中心线相交。
- 根据权利要求10至12中任一项所述的显示基板,其中,所述第一彩色滤光单元为红色滤光单元,所述第二彩色滤光单元为绿色滤光单元,所 述第三彩色滤光单元为蓝色滤光单元;所述第一光调节部和第四光调节部配置为调节从所述第一彩色滤光单元射出的第一颜色光的出射方向;所述第二光调节部和第三光调节部配置为调节从所述第二彩色滤光单元射出的第二颜色光的出射方向;所述第一光调节部和第四光调节部的第一长度大于或等于所述第二光调节部的第一长度,且大于或等于所述第三光调节部的第一长度;所述第一长度为光调节部沿第一方向的尺寸,所述第一方向垂直于所述显示基板所在平面。
- 根据权利要求13所述的显示基板,其中,所述第一光调节部和第四光调节部的第一长度约为0.7微米至1.2微米,所述第二光调节部的第一长度约为0.1微米至0.5微米,所述第三光调节部的第一长度约为0.01微米至0.3微米。
- 根据权利要求13所述的显示基板,其中,所述第一光调节部、第二光调节部、第三光调节部和第四光调节部的第二长度大致相同;所述第二长度为光调节部沿第二方向的尺寸,所述第二方向平行于所述显示基板所在平面,且与所述光调节部对应的子像素的中心线相交。
- 根据权利要求1至15中任一项所述的显示基板,其中,所述光调节层的材料为负折射率材料。
- 根据权利要求1至16中任一项所述的显示基板,其中,所述子像素包括:发光元件和驱动所述发光元件发光的驱动电路;所述发光元件包括:第一电极、第二电极以及设置在所述第一电极和第二电极之间的有机发光层,所述第一电极位于第二电极靠近所述衬底基板的一侧;所述第一电极所在平面与所述衬底基板所在平面之间存在倾斜角度。
- 一种显示装置,包括如权利要求1至17中任一项所述的显示基板。
- 一种显示基板的制备方法,用于制备如权利要求1至17中任一项所述的显示基板,所述制备方法,包括:在衬底基板上形成显示结构层,所述显示结构层包括多个子像素;在所述显示结构层的出光侧形成光调节层;所述光调节层在所述衬底基 板上的正投影与多个子像素的开口区域没有交叠;所述光调节层配置为调节从所述显示结构层射出的至少一种颜色光的出射方向。
- 一种彩膜基板,包括:基底、设置在所述基底上的彩色滤光层、以及光调节层;所述彩色滤光层包括黑矩阵和周期性排布的多个彩色滤光单元,所述光调节层设置在所述黑矩阵远离所述基底的一侧;所述光调节层配置为调节从所述彩色滤光层射出的至少一种颜色光的出射方向。
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Publication number | Priority date | Publication date | Assignee | Title |
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US20150085384A1 (en) * | 2013-09-24 | 2015-03-26 | Samsung Display Co., Ltd. | Display apparatus |
CN107255885A (zh) * | 2017-08-16 | 2017-10-17 | 京东方科技集团股份有限公司 | 显示面板及其制造方法 |
CN108919402A (zh) * | 2018-07-24 | 2018-11-30 | 京东方科技集团股份有限公司 | 彩色滤光基板及其制作方法、显示装置 |
CN110707146A (zh) * | 2019-11-22 | 2020-01-17 | 京东方科技集团股份有限公司 | 盖板、有机发光显示面板、显示装置 |
CN111668384A (zh) * | 2020-05-06 | 2020-09-15 | 湖北长江新型显示产业创新中心有限公司 | 一种显示面板及其制作方法和显示装置 |
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Publication number | Priority date | Publication date | Assignee | Title |
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US20150085384A1 (en) * | 2013-09-24 | 2015-03-26 | Samsung Display Co., Ltd. | Display apparatus |
CN107255885A (zh) * | 2017-08-16 | 2017-10-17 | 京东方科技集团股份有限公司 | 显示面板及其制造方法 |
CN108919402A (zh) * | 2018-07-24 | 2018-11-30 | 京东方科技集团股份有限公司 | 彩色滤光基板及其制作方法、显示装置 |
CN110707146A (zh) * | 2019-11-22 | 2020-01-17 | 京东方科技集团股份有限公司 | 盖板、有机发光显示面板、显示装置 |
CN111668384A (zh) * | 2020-05-06 | 2020-09-15 | 湖北长江新型显示产业创新中心有限公司 | 一种显示面板及其制作方法和显示装置 |
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