WO2022186564A1 - 화재 방지 성능이 향상된 배터리 모듈 - Google Patents
화재 방지 성능이 향상된 배터리 모듈 Download PDFInfo
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- WO2022186564A1 WO2022186564A1 PCT/KR2022/002831 KR2022002831W WO2022186564A1 WO 2022186564 A1 WO2022186564 A1 WO 2022186564A1 KR 2022002831 W KR2022002831 W KR 2022002831W WO 2022186564 A1 WO2022186564 A1 WO 2022186564A1
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- Prior art keywords
- battery
- battery module
- present
- module
- trap
- Prior art date
Links
- 230000002265 prevention Effects 0.000 title 1
- 238000004146 energy storage Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 4
- 239000007789 gas Substances 0.000 description 33
- 230000000903 blocking effect Effects 0.000 description 18
- 238000007789 sealing Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- 239000011148 porous material Substances 0.000 description 13
- 238000004880 explosion Methods 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000002457 bidirectional effect Effects 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000008279 sol Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/30—Arrangements for facilitating escape of gases
- H01M50/383—Flame arresting or ignition-preventing means
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
- H01M50/207—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
- H01M50/211—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for pouch cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/233—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by physical properties of casings or racks, e.g. dimensions
- H01M50/24—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by physical properties of casings or racks, e.g. dimensions adapted for protecting batteries from their environment, e.g. from corrosion
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/251—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders specially adapted for stationary devices, e.g. power plant buffering or backup power supplies
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/267—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders having means for adapting to batteries or cells of different types or different sizes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/502—Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing
- H01M50/507—Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing comprising an arrangement of two or more busbars within a container structure, e.g. busbar modules
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2200/00—Safety devices for primary or secondary batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/10—Batteries in stationary systems, e.g. emergency power source in plant
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a battery, and more particularly, to a battery module capable of effectively preventing the occurrence or spread of fire, and a battery pack and an energy storage system including the same.
- Currently commercialized secondary batteries include a nickel cadmium battery, a nickel hydrogen battery, a nickel zinc battery, and a lithium secondary battery.
- the lithium secondary battery is attracting attention because of the advantages of free charge/discharge, a very low self-discharge rate, and a high energy density because the memory effect hardly occurs compared to a nickel-based secondary battery.
- the secondary battery may be used alone, but in general, a plurality of secondary batteries are electrically connected to each other in series and/or in parallel in many cases.
- a plurality of secondary batteries may be accommodated in one module case while being electrically connected to each other to constitute one battery module.
- the battery module may be used alone or two or more may be electrically connected to each other in series and/or parallel to constitute a higher level device such as a battery pack.
- an energy storage system for storing the generated power is receiving more attention.
- ESS energy storage system
- a battery pack may typically include a large number of battery modules. And, in order to increase the energy density, a plurality of battery modules are often configured in a dense form in a very narrow space.
- a thermal propagation situation may occur in one battery module, and a situation in which a high-temperature gas is discharged from at least one battery cell (secondary battery) may occur.
- high-temperature sparks may be ejected when the gas is discharged, and the sparks may include active materials or molten aluminum particles that are desorbed from electrodes inside the battery cell.
- a flare or the like may occur in some battery cells. If such sparks or flares leak to the outside of the battery module, a fire may occur in the battery pack.
- the present invention has been devised to solve the above problems, and a battery module configured to effectively suppress fire even if sparks or flares are generated inside due to thermal runaway, etc., a battery pack including the same, and energy storage
- the purpose is to provide a system, etc.
- a battery module comprising: a cell assembly including a plurality of secondary batteries stacked on each other; and a module case having a lower plate, a side plate, and an upper plate to form an inner space to accommodate the cell assembly, and having a trap part concave outwardly on at least a portion of an inner surface of the side plate.
- the cell assembly may be configured in a form in which a plurality of pouch-type secondary batteries are stacked in a vertical direction in a lying state.
- electrode leads of the pouch-type secondary battery may be positioned in the front and rear directions of the module case, and the module case may be configured such that at least one side of the front and rear is opened.
- the battery module according to the present invention may further include a bus bar assembly positioned in the open portion of the module case and configured to be coupled to the electrode lead.
- the module case may be configured such that when gas is generated from the cell assembly, the generated gas is discharged to at least one side of a front and a rear side.
- the trap part may be formed in at least a front-rear central portion of the side plate.
- the trap portion may be formed such that the depth of the concave portion becomes deeper as at least a portion of the portion moves forward or rearward.
- the module case may further include a protrusion formed to protrude in a central direction at at least one end of the trap unit.
- At least one end of the trap part may be concave in the front-rear direction.
- a battery pack according to another aspect of the present invention for achieving the above object includes the battery module according to the present invention.
- an energy storage system for achieving the above object includes a battery module according to the present invention.
- the occurrence of fire in the battery module can be effectively prevented.
- the spark, etc. from flowing out while easily discharging the gas to the outside of the battery module. Accordingly, it is possible to prevent explosion of the battery module and fundamentally prevent a fire from occurring outside the battery module.
- the present invention may have various other effects, which will be described in each embodiment, or the corresponding description will be omitted for effects that can be easily inferred by those skilled in the art.
- FIG. 1 is a perspective view schematically showing the configuration of a battery module according to an embodiment of the present invention.
- FIG. 2 is an exploded perspective view of a partial configuration of FIG. 1 .
- FIG. 3 is a view of the configuration of a battery module according to an embodiment of the present invention as viewed from above.
- FIG. 4 is a diagram schematically illustrating a spark trap effect when a spark is generated in some secondary batteries in a battery module according to an embodiment of the present invention.
- FIG. 5 is a perspective view showing a cell assembly separated from the battery module according to an embodiment of the present invention.
- FIG. 6 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention.
- FIG. 7 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention.
- FIG. 8 is an enlarged view of a portion E1 of FIG. 7 .
- FIG. 9 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention.
- FIG. 10 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention.
- 11 and 12 are top views schematically illustrating the configuration of a battery module according to still another exemplary embodiment of the present invention.
- FIG. 13 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention.
- FIG. 14 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention.
- 15 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention.
- FIG. 16 is an enlarged view of a portion A6 of FIG. 15 .
- FIG. 1 is a perspective view schematically showing a configuration of a battery module according to an embodiment of the present invention
- FIG. 2 is an exploded perspective view of a part of the configuration of FIG. 1 .
- the battery module according to the present invention includes a cell assembly 100 and a module case 200 .
- the cell assembly 100 may include a plurality of secondary batteries 110 (battery cells).
- the secondary battery 110 may include an electrode assembly, an electrolyte, and a battery case.
- the secondary battery 110 provided in the cell assembly 100 may be a pouch-type secondary battery 110 .
- other types of the secondary battery 110 such as a cylindrical battery or a prismatic battery, may also be employed in the cell assembly 100 of the present invention.
- the plurality of secondary batteries 110 may form the cell assembly 100 in a stacked form.
- the plurality of secondary batteries 110 may be stacked in the vertical direction (the Z-axis direction of the drawing).
- Each pouch-type secondary battery 110 may include an electrode lead 111 , and the electrode lead 111 may be located at both ends or at one end of each secondary battery 110 .
- the secondary battery 110 in which the electrode lead 111 protrudes in both directions may be referred to as a bidirectional cell, and the secondary battery in which the electrode lead 111 protrudes in one direction may be referred to as a unidirectional cell.
- the electrode leads 111 may be positioned at both ends in the Y-axis direction.
- the secondary battery 110 of the battery module according to the present invention may have a shape in which the electrode lead 111 is positioned only at one end in the Y-axis direction, for example, at an end in the +Y-axis direction.
- the present invention is not limited by the specific type or shape of the secondary battery 110 , and various secondary batteries 110 known at the time of filing of the present invention may be employed in the cell assembly 100 of the present invention. In this specification, a case where the secondary battery 110 is a bidirectional cell will be mainly described.
- the module case 200 may have an empty space formed therein to accommodate the cell assembly 100 . Furthermore, the module case 200 may include a lower plate 210 , a side plate 220 , and an upper plate 230 as shown in the drawings.
- the module case 200 may be manufactured in a form in which at least some plates are integrated, or may be configured in a form coupled to each other by a fastening method such as bolts or welding.
- the lower plate 210 and the side plate 220 may be manufactured integrally with each other to form a lower case.
- the lower plate 210 , the side plate 220 , and the upper plate 230 may define an inner space, and the cell assembly 100 may be accommodated in the inner space.
- the lower plate 210 and the side plate 220 may be formed in a U-shape or a box shape to constitute a lower case.
- the upper plate 230 may be coupled to the upper open end of the lower case to cover the upper end of the cell assembly 100 .
- the upper plate 230 may be configured in a shape in which both ends are bent, but may be formed in various other shapes and configured to be coupled to the side plate 220 .
- the module case 200 may be formed in the form of a mono frame in which the lower plate 210 , the side plate 220 , and the upper plate 230 are integrated.
- the module case 200 may include a trap unit 221 .
- the trap part 221 may be formed on the inner surface of the side plate 220 , in particular, the side plate 220 .
- the trap unit 221 may be configured to be concavely formed in an outward direction from at least a portion of the inner surface of the side plate 220 . This will be further described with reference to FIG. 3 .
- FIG. 3 is a view of the configuration of a battery module according to an embodiment of the present invention as viewed from above.
- FIG. 3 may be referred to as a view of the battery module of FIGS. 1 and 2 as viewed from the top in a state in which the upper plate 230 is removed.
- the side plate 220 of the module case 200 may include a left plate 220L and a right plate 220R.
- the left plate 220L and the right plate 220R are positioned at both ends in the X-axis direction with respect to the cell assembly 100 in the drawing.
- the side plate 220 may include a trap portion 221 having an inner surface concave outwardly, as in the portion indicated by a circle in FIG. 3 .
- the outward direction may refer to a direction opposite to the direction in which the battery cells are positioned, that is, an outer direction of the battery module.
- FIG. 1 to 3 the configuration of FIG.
- the left plate 220L may include a trap portion 221 concave in the left direction (+X-axis direction), as indicated by arrows on a part of the inner surface.
- the right plate 220R may include a trap part 221 concave in the right direction (-X-axis direction), as indicated by arrows on the inner surface of the right side plate 220R.
- a direction toward the center of the battery module for example, a direction in which the cell assembly 100 is positioned, is indicated as an inner direction, and a direction toward the outside of the battery module is indicated as an outer direction.
- the trap part 221 can be considered to be concave when the inner surface of the side plate 220 is referenced, and to form the concave portion, the outer surface may be convex. That is, as shown in FIGS. 1 to 3 , the side plate 220 may have an inner surface concave and an outer surface protruding outward to form the trap portion 221 . However, when the side plate 220 is formed in a thick form, the outer surface may be formed in a form in which the outer surface does not protrude outward.
- the trap unit 221 formed in the module case 200 it is possible to effectively prevent high-temperature sparks or flares from flowing out to the outside of the module case 200. have. This will be described in more detail with reference to FIG. 4 .
- FIG. 4 is a diagram schematically illustrating a trap effect of a spark when a spark is generated in some secondary batteries 110 in the battery module according to an embodiment of the present invention.
- the ejected spark may be trapped by the trap portion 221 of the side plate 220 . That is, the spark ejected from the secondary battery 110 may be discharged into the inner space of the module case 200 , and the trap unit 221 is present in the inner space of the module case 200 .
- the spark may be introduced into the concave portion of the trap portion 221 and move along the concave shape, and the movement may be blocked at the end of the concave portion.
- the spark in the trap part 221 moves as indicated by an arrow in FIG. 4 , and then at the horizontal ends of the trap part 221 as indicated by A1 and A1', the movement is blocked or moved.
- the direction can be switched.
- the trap unit 221 may allow sparks generated inside the module case 200 to be confined in a concave space therein. Therefore, sparks and the like may not be discharged to the outside of the module case 200 . According to this implementation effect, sparks and the like are prevented from contacting oxygen existing outside the module case 200, thereby reducing the risk of fire.
- the cell assembly 100 may be configured in a form in which a plurality of pouch-type secondary batteries 110 are stacked in a vertical direction in a lying state. This will be described in more detail with reference to FIG. 5 .
- FIG. 5 is a perspective view showing the cell assembly 100 separated from the battery module according to an embodiment of the present invention.
- the secondary battery 110 included in the cell assembly 100 is a pouch-type secondary battery 110 and may be disposed in a lying state.
- the pouch-type secondary battery 110 may be formed to have approximately two wide surfaces, and may be disposed in a laid-down form such that the two wide surfaces face upward and downward directions.
- the X-Y plane of FIG. 5 may form the same plane as the lower plate 210 of the module case 200.
- the secondary batteries 110 of the laid-down form may be stacked and disposed in the vertical direction (the Z-axis direction of the drawing) so that the upper surface and the lower surface face each other.
- the sealing parts of all secondary batteries 110 may be configured to face the trap part 221 of the side plate 220 . Therefore, no matter what kind of secondary battery 110 a spark is discharged, the discharged spark may be configured to be confined by the trap unit 221 .
- sparks are formed in any of the secondary batteries 110 stacked in the vertical direction and are discharged in the directions indicated by arrows A2 and A2 ′, even if the sparks are discharged. may be directed toward the trap portion 221 of the side plate 220 . Accordingly, with respect to all the stacked secondary batteries 110 , the trap unit 221 may respond when sparks are ejected.
- the cell assembly 100 may be configured such that the electrode leads 111 of the pouch-type secondary battery 110 are positioned in the front and rear directions of the module case 200 .
- the electrode lead 111 is forward (+Y-axis direction) or rearward (- Y-axis direction) may be configured to face.
- the module case 200 may be configured such that at least one side of the front and rear is opened.
- the module case 200 may include a front plate 240 and a rear plate 250 .
- the front plate 240 may be configured such that a portion thereof is opened, such as the portion indicated by O1.
- the rear plate 250 may be configured such that a portion thereof is open, such as a portion indicated by O2.
- the gas when the spark is ejected from the cell assembly 100 together with the gas, the gas is smoothly discharged to the outside of the module case 200, while the spark is discharged to the outside of the module case 200 can be suppressed
- the gas when gas and sparks are discharged in the A2 and A2' directions, the gas is not greatly restricted by the trap unit 221's flow as a gas, and the front opening part (O1) or the rear opening (O2) can be discharged. Accordingly, even when gas is generated from the cell assembly 100 , the internal pressure of the module case 200 is prevented from increasing to a certain level or more, so that the explosion of the battery module can be suppressed.
- sparks and the like may contain particles or substances such as solid or liquid, gel or sol state. may impede its movement. Therefore, according to this configuration of the present invention, the effect of preventing both the explosion of the battery module and external leakage such as sparks can be achieved.
- the trap part 221 for blocking the spark in the module case 200 is provided on the side plate 220, and the opening parts O1 and O2 from which the gas is discharged are the module case 200 .
- the trap part 221 may be located anteriorly and/or posteriorly of
- the trap part 221 may be positioned to face a side of the sealing part of the secondary battery 110 on which the electrode lead 111 is not positioned.
- the openings O1 and O2 may be positioned to face the side surface where the electrode lead 111 is positioned among the sealing parts of the secondary battery 110 .
- a portion where the gas is discharged by explosion is mainly a portion where the electrode lead 111 is not located. That is, in the configuration of FIG. 4 , when the secondary battery 110 explodes, the explosion site is highly likely to be a sealing portion at both ends in the ⁇ X-axis direction (left and right ends), and a sealing portion at both ends in the ⁇ Y-axis direction (both front and rear ends). Explosions may not easily occur in
- the pouch-type secondary battery 110 may be formed in a substantially rectangular shape when viewed from the top in a lying state.
- the pouch-type secondary battery 110 may be configured in a form in which four sealing parts surround the periphery of the receiving part, and the left and right sealing parts (wing parts) where the electrode leads 111 are not located are the electrode leads 111 . ) is often formed longer than the front and rear sealing portions (terrace portions) where they are located.
- the trap unit 221 may be present at the gas and spark ejection portion.
- the spark may inevitably pass through the trap portion 221 before heading toward the openings O1 and O2. Therefore, the movement of the spark can be suppressed by the trap portion 221 as shown in FIG. 4 . Accordingly, according to the embodiment, the spark discharge blocking effect of the trap unit 221 may be further improved.
- each pouch-type secondary battery 110 of the cell assembly 100 are shown in an upwardly folded form. According to this configuration, the volume of the cell assembly 100 can be reduced.
- this is only an example, and the present invention is not necessarily limited to this form.
- the battery module according to the present invention may further include a bus bar assembly 300 as shown in FIGS. 1 and 2 .
- the bus bar assembly 300 may be located in the openings O1 and O2 of the module case 200 .
- the electrode leads 111 of the cell assembly 100 may be positioned in the openings O1 and O2 of the module case 200 .
- the bus bar assembly 300 may be configured to be coupled to the electrode lead 111 of the cell assembly 100 .
- the electrode leads 111 are positioned at both ends in the Y-axis direction, and the module case 200 may be configured such that both ends in the Y-axis direction are opened in response thereto.
- the bus bar assembly 300 may be coupled to the open portions O1 and O2.
- the module case 200 may be configured to open only in the +Y-axis direction.
- the module case 200 may be configured to be sealed except for an open portion to which the bus bar assembly 300 is coupled. Accordingly, when gas is generated inside the module case 200 , the generated gas may be discharged only to the side where the bus bar assembly 300 is located.
- the bus bar assembly 300 may be configured to be positioned on at least one side of the module case 200 , for example, both front and rear ends of the module case 200 (both ends in the Y-axis direction in FIG. 2 ). have.
- the bus bar assembly 300 may include a module bus bar 310 and a bus bar housing 320 .
- the module bus bar 310 may be made of an electrically conductive material, for example, a metal material such as copper or nickel.
- the module bus bar 310 may be configured to be electrically connected to the electrode lead 111 of the cell assembly 100 .
- the module bus bar 310 may be welded or bolted in direct contact with the electrode lead 111 .
- the module bus bar 310 may electrically connect between the electrode leads 111 or transmit voltage information sensed from the electrode leads 111 to an external control unit, for example, a Battery Management System (BMS). have.
- BMS Battery Management System
- the bus bar housing 320 may be configured such that the module bus bar 310 can be seated therein.
- the bus bar housing 320 may have a shape corresponding to the surface of the module bus bar 310 , for example, a planar portion as a seating part so that the module bus bar 310 is mounted.
- the bus bar housing 320 may support the module bus bar 310 so that the seated module bus bar 310 can stably maintain its position.
- the bus bar housing 320 may be coupled and fixed to the module bus bar 310 using various fastening methods such as bolts, rivets, fusion, insertion, and adhesion.
- the bus bar housing 320 may be made of an electrically insulating material such as plastic (polymer) so as not to be electrically connected to the module bus bar 310 .
- the bus bar housing 320 may be coupled and fixed to the module case 200 , in particular, the front plate 240 or the rear plate 250 .
- the coupling method between the bus bar housing 320 and the module case 200 may be implemented in various forms such as bolts, rivets, fusion, insertion, and adhesion.
- a slot 321 may be formed so that the electrode lead 111 passes therethrough.
- the module bus bar 310 is seated on the outer surface of the bus bar housing 320 , and the electrode lead 111 penetrates the slot 321 from the inside of the bus bar housing 320 . After that, it may be in contact with the outer surface of the module bus bar 310 located outside.
- the slot 321 may be formed in a shape corresponding to the shape of the electrode lead 111 so that the electrode lead 111 can easily pass therethrough.
- the slot 321 as shown in the drawing, may be formed in a form that is elongated in the left-right direction (X-axis direction of the drawing).
- a plurality of such slots 321 may be formed in the bus bar housing 320 .
- a plurality of electrode leads 111 may exist in the vertical direction. Accordingly, as shown in FIG. 2 , a plurality of slots 321 may also be disposed to be spaced apart by a predetermined distance in the vertical direction.
- the slot 321 may serve to penetrate the electrode lead 111 and support the electrode lead 111 , and may additionally serve to discharge the vent gas.
- the other part of the module case 200 may be configured in an almost sealed form.
- the gas may increase the pressure inside the battery module.
- the slot 321 since an empty gap is formed around the periphery through which the electrode lead 111 has passed, the gas inside the battery module may be discharged to the outside through the slot 321 .
- sparks or flares other than gas may be prevented from being discharged to the outside by the trap unit 221 , as described above.
- the module case 200 may be configured such that when gas is generated from the cell assembly 100, the generated gas is discharged to at least one side of the front and the rear. .
- the portion from which the gas is discharged to the outside of the module case 200 may be a slot 321 of the bus bar assembly.
- the trap unit 221 may be formed on the side plate 220 of the module case 200 . That is, the trap unit 221 may be formed on the left plate 220L and the right plate 220R of the module case 200 .
- the gas and sparks discharged from the cell assembly 100 may pass through the trap unit 221 before being discharged to the outside of the module case 200 . Accordingly, while the gas in the gas state is smoothly discharged to the outside of the module case 200 , the spark in the non-gas state may be prevented from being discharged to the outside of the module case 200 by the trap unit 221 .
- the trap part 221 may be formed in at least a central portion in the front-rear direction of the side plate 220 . This will be described in more detail with reference to FIG. 6 .
- FIG. 6 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention.
- the front-rear direction of the side plate 220 may be referred to as a ⁇ Y-axis direction.
- a center line in the front-rear direction with respect to the side plate 220 may be referred to as a line A3-A3'.
- the trap unit 221 may be configured to be formed at least on the line A3-A3'.
- the trap unit 221 may be configured to extend in the front-rear direction with respect to the line A3-A3'. That is, in the configuration of FIG. 6 , the trap unit 221 may be configured to extend in the +Y-axis direction and the -Y-axis direction based on the front-rear center line A3-A3'. In this case, the trap part 221 may be positioned to face the side sealing part of each of the plurality of pouch-type secondary batteries 110 , that is, the central part of the wing part.
- the explosion point is highly likely to be the central portion of the wing portion having a relatively long length among the sealing portions. Therefore, according to the embodiment, when sparks or flares are ejected from the cell assembly 100 , the ejected sparks or flares can be directly introduced into the trap unit 221 .
- the trap part 221 may extend from the central portion of the side plate 220 in the front-rear direction (Y-axis direction) to a portion where the terrace portion S2 is located.
- the pouch-type secondary battery 110 provided in the cell assembly 100 includes a housing R in which the electrode assembly is accommodated, and a sealing in which the upper pouch and the lower pouch are fused. It can be divided into part (S).
- the sealing part (S) may include a wing part (S1) and a terrace part (S2), and may be configured to surround the receiving part (R).
- the trap unit 221 extends in the front-rear direction from the central portion (line A3-A3') of the side plate 220 to the portion where the terrace portion S2 of the pouch-type secondary battery 110 is located, Or it can be extended beyond that. That is, the trap unit 221 is configured to extend at least to the end of the storage unit R of the pouch-type secondary battery 110 , like the portions indicated by lines A4-A4' and A5-A5' in FIG. 6 . can be
- the trap portion 221 can be positioned to face the entire wing portion S1 of the pouch-type secondary battery 110 . That is, the trap portion 221 of the side plate 220 may cover the entire wing portion S1 of the pouch-type secondary battery 110 provided in the cell assembly 100 . Therefore, even if sparks or flares are ejected from the wing part S1 of any pouch-type secondary battery 110 , the movement blocking effect by the trap part 221 can be reliably ensured.
- the trap portion 221 may be formed such that the depth of the concave portion increases as at least a portion of it moves forward or rearward. This will be described in more detail with reference to FIGS. 7 and 8 .
- FIG. 7 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention. Also, FIG. 8 is an enlarged view of a portion E1 of FIG. 7 .
- the present embodiment will be mainly described with respect to parts that are different from the previous embodiment, and detailed descriptions of parts to which the description of the previous embodiment can be applied in the same or similar manner will be omitted.
- the trap part 221 is located on the front side (right side of FIG. 7) with respect to the front-rear center line (line A3-A3') of the side plate 220, the front ( +Y-axis direction) may be configured such that the depth of the concave portion becomes deeper.
- the trap portion 221, the portion located on the rear side (left side of FIG. 7) with respect to the front-rear center line (line A3-A3') of the side plate 220, the rear (-Y-axis direction) It may be configured such that the depth of the concave portion becomes deeper as it faces.
- an inclined surface may be formed on the inner surface of the trap unit 221 .
- the inclined surface in the portion located on the front side of the trap unit 221, the inclined surface is formed in such a way that the depth becomes deeper as it goes toward the front (+Y-axis direction).
- the inclined surface in the portion located on the rear side of the trap unit 221, the inclined surface may be formed in such a way that the depth becomes deeper as it goes toward the rear (-Y-axis direction).
- sparks ejected from the wing portion of the secondary battery 110 may move in the front-rear direction ( ⁇ Y-axis direction) along the inclined surfaces D1 , D1 ′, D2 , and D2 ′ of the trap unit 221 . Then, when it reaches the front-rear end of the trap part 221 , it cannot move any more at portions indicated by E1 , E1 ′, E2 , and E2 ′, and the movement direction may be changed. In this case, the moving direction may be bent at an angle greater than 90°.
- the angle itself near the edges of the front and rear ends E1, E1', E2, and E2' of the trap part 221 constitutes an acute angle.
- this may be said to be an angle greater than 90°. That is, looking at (a) of FIG. 8 , sparks, etc., first move in the direction of arrow F1 in the trap part 221 , then collide with the end of the trap part 221 , and the direction is changed, and the direction is changed as shown by arrow F2. direction can be moved. And, if the center points of the arrows F1 and F2 are the same, it is as shown in (b) of FIG. 8 . In this case, the angle ⁇ formed by the arrows F1 and F2 may be an obtuse angle greater than 90°.
- the outer surface is shown to be inclined to correspond to the inclined shape of the inner surface, but the present invention is not necessarily limited to this form. That is, while the inner surface of the side plate 220 is inclined, the outer surface may be configured to be flat. However, as shown in FIG. 7 , when the outer surface is formed to be inclined, when the side plate 220 is viewed from the outside, it can be seen that the central portion is concave in the inner direction. At this time, when a plurality of battery modules are stacked in a horizontal direction, the concave portion of the outer side of the side plate 220 may be used as a space between the battery modules as a flow path through which cooling air or the like flows.
- the trap unit 221 may be configured such that irregularities are formed on the inner surface. This will be described in more detail with reference to FIG. 9 .
- FIG. 9 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention. Also with reference to FIG. 9, the parts with differences from the previous embodiment will be mainly described.
- the trap part 221 may be configured in a shape having irregularities by forming a plurality of grooves concave in the outward direction on the inner surface.
- the trap part 221 is configured in a form in which a plurality of grooves are formed on the front side and a plurality of grooves are also formed on the rear side based on the front-rear center line (line A3-A3') of the side plate 220 .
- the movement of sparks and the like may be prevented by the irregularities formed on the inner surface of the trap unit 221 , that is, the plurality of grooves G. Therefore, it can be further suppressed that sparks are discharged to the outside through the openings O1 and O2 of the module case 200 .
- each of the grooves G may be formed such that the depth of the concave portion increases in the front-rear direction with respect to the front-rear center line A3-A3'. That is, the plurality of grooves G formed in the trap portion 221, as indicated by D3 in FIG. 9 , each have inclined surfaces, and these inclined surfaces D3 have a greater depth in the front-back direction, which is the gas flow direction. It can be configured in a deep form.
- the movement direction of the spark or the like for each groove can be switched to an angle (obtuse angle) greater than a right angle. Accordingly, the effect of suppressing movement of sparks by the trap unit 221 may be further improved.
- the present invention is limited to this embodiment it is not
- the plurality of grooves G described in FIG. 9 may be formed in each of the inclined surfaces D1, D1', D2, and D2', as shown in FIG. 7 .
- the spark blocking effect due to the inclined surface of the trap unit 221 itself and the spark blocking effect due to the unevenness are summed, and the effect may be further increased.
- module case 200 may further include a protrusion formed to protrude in a central direction at at least one end of the trap unit 221 . This will be described in more detail with reference to FIG. 10 .
- FIG. 10 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention. Also with reference to FIG. 10, parts with differences from the previous embodiment will be mainly described.
- the module case 200 may further include a protrusion 222 at the front end and/or the rear end of the trap unit 221 .
- the protrusion 222 may be configured to protrude from the side plate 220 of the module case 200 toward the inside of the trap unit 221 .
- the protrusion 222 is configured to protrude in the front side direction (+Y axis direction), It may be configured to partially cover the rear end.
- sparks introduced into the trap part 221 may be switched in the opposite direction from the end side of the trap part 221 . Therefore, in this case, sparks and the like can be made to stay in the trap unit 221 , and thus, a trap effect of sparks generated by the trap unit 221 can be further improved.
- At least one end of the trap part 221 may be concave in the front-rear direction. This will be described in more detail with reference to FIGS. 11 and 12 .
- FIG. 11 and 12 are top views schematically illustrating the configuration of a battery module according to still another exemplary embodiment of the present invention.
- the present embodiments will also be mainly described with respect to parts that are different from the previous embodiments.
- the trap part 221 is formed on the side plate 220 of the module case 200 , and the front-back direction (Y-axis direction) side end of the trap part 221 is further in the front-back direction. may be concave.
- the front end of the trap unit 221 may be more concave in the forward lateral direction (+Y-axis direction), such as the portion indicated by H1 ′, such that a groove is provided in the front.
- the rear end of the trap part 221 may be formed to be more concave in the rear lateral direction (-Y-axis direction) as indicated by H1 to provide a rear groove.
- inclined surfaces may be formed on the front and rear ends of the trap part 221 .
- the front end of the trap part 221 may be more concave in the front lateral direction (+Y-axis direction), like the portion indicated by H2 ′, such that a groove is provided in the front.
- the rear end of the trap part 221 may be formed to be more concave in the rear lateral direction (-Y-axis direction), as indicated by H2 , to provide a rear groove.
- the trap portion 221 in order to provide grooves (concave portions) at the front and rear ends of the trap portion 221 , the trap portion 221 may be formed in a more concave shape in the front and rear directions. have.
- the effect of preventing sparks or flares by the trap unit 221 can be more stably secured.
- the sparks or flares move in the front-rear direction, and are difficult to flow out of the internal space of the trap unit 221 by the recesses located at the front and rear ends.
- spark particles or the like may be inserted into grooves provided on the front and rear ends of the trap part. Therefore, in this case, the effect of preventing the discharge of sparks and flares by the trap unit 221 may be further improved.
- FIG. 13 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention.
- the present embodiment will also be mainly described with respect to parts that are different from the previous embodiment.
- the battery module according to the present invention may further include a mesh member 400 .
- the mesh member 400 may be configured in a form in which a plurality of holes are formed.
- the mesh member 400 may be configured in a form in which a plurality of holes are provided in a plate-shaped member.
- the mesh member 400 may be configured in a form such as a mesh in which different wires are orthogonal to each other. In this case, the mesh member 400 may be easily manufactured, and a large number of holes may be formed while reducing the size of the holes.
- the mesh member 400 may be configured to be introduced into the inner space of the trap unit 221 .
- the mesh member 400 may be disposed so that holes are formed in the front and rear directions.
- the mesh member 400 may be disposed at both ends of the trap unit 221 in the front-rear direction.
- the movement of sparks or flares by the mesh member 400 can be further blocked. That is, when the spark or flare together with the gas moves in the front-rear direction in the inner space of the trap unit 221 and reaches the mesh member 400 , the gas in a gaseous state can easily pass through the mesh, but the spark or flare Included particles and the like may be filtered by the mesh member 400 . Therefore, in this case, the effect of preventing external emission of sparks or flares can be further improved.
- FIG. 14 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention.
- the present embodiment will also be mainly described with respect to parts that are different from the previous embodiment.
- the battery module according to the present invention may further include a pore member 500 .
- the pore member 500 may be configured in a form in which a plurality of pores are retained. In particular, these internal pores may be configured to communicate with the outside. That is, the pores held in the pore member 500 may be called empty spaces filled with only gas, and these pores may be configured to communicate with the outside, not in a closed form.
- the porous member 500 may be configured in a form in which a plurality of wires, particularly a plurality of wires made of a material such as metal or polymer, are entangled with each other.
- the pore member 500 may be configured to be inserted into the internal space of the trap unit 221 .
- FIG. 15 is a top view schematically showing the configuration of a battery module according to another embodiment of the present invention. Also, Fig. 16 is an enlarged view of a portion A6 in Fig. 15 .
- the present embodiment will also be mainly described with respect to parts that are different from the previous embodiment.
- a plurality of blocking protrusions P may be formed on the inner surface of the trap unit 221 .
- the blocking protrusion P is formed to protrude from the inner surface of the side plate 220 in the direction (X-axis direction) toward the cell assembly 100 .
- the blocking protrusion (P) is provided with an empty space therein, and this empty space is configured to be in an open state in the front-rear direction, particularly in the direction toward the front-rear center line (A3-A3' line) of the side plate 220 can be
- the inner space of the blocking protrusion P may be configured to be in a closed state toward the front and rear both ends of the side plate 220 .
- the right portion of the blocking protrusion P in the drawing may be referred to as a direction (+Y-axis direction) toward the front-rear center line (A3-A3' line).
- the left portion of the blocking protrusion P may be referred to as a direction toward the rear end (-Y-axis direction).
- the right portion of the blocking protrusion P may be opened, and the left portion of the blocking protrusion P may be configured in a closed form.
- the plurality of blocking projections (P) formed on the inner surface of the trap portion 221 external discharge such as sparks or flares can be more reliably blocked.
- sparks or flares moving forward or backward along the inner surface of the trap unit 221 are introduced into the inner space of the blocking protrusion P. The movement is blocked and the direction can be changed. Therefore, in this case, the effect of preventing movement of sparks or flares can be further improved.
- the battery pack according to the present invention may include a plurality of the above-described battery modules according to the present invention.
- the battery pack according to the present invention includes, in addition to the battery module, various other components, such as BMS, bus bar, pack case, relay, current sensor, etc. known at the time of filing of the present invention. may include more.
- the energy storage system according to the present invention may include one or more battery modules according to the present invention.
- a plurality of battery modules according to the present invention may be included in a form electrically connected to each other.
- a plurality of battery modules according to the present invention may constitute one battery pack, and the energy storage system may be configured in such a way that a plurality of such battery packs are included.
- the energy storage system according to the present invention may further include other various components of the energy storage system known at the time of filing of the present invention.
- such an energy storage system can be used in various places or devices, such as a smart grid system or an electric charging station.
- 220L Left plate
- 220R Right plate
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Mounting, Suspending (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
Description
Claims (11)
- 상호 적층된 다수의 이차 전지를 구비하는 셀 어셈블리; 및상기 셀 어셈블리를 수용하도록, 하부 플레이트, 측부 플레이트 및 상부 플레이트를 구비하여 내부 공간을 형성하며, 상기 측부 플레이트의 내면 중 적어도 일부에 외측 방향으로 오목하게 형성된 트랩부를 구비하는 모듈 케이스를 포함하는 것을 특징으로 하는 배터리 모듈.
- 제1항에 있어서,상기 셀 어셈블리는, 다수의 파우치형 이차 전지가 눕혀진 상태에서 상하 방향으로 적층된 형태로 구성된 것을 특징으로 하는 배터리 모듈.
- 제2항에 있어서,상기 셀 어셈블리는, 상기 파우치형 이차 전지의 전극 리드가 상기 모듈 케이스의 전후 방향에 위치하며,상기 모듈 케이스는, 전방 및 후방 중 적어도 일측이 개방되도록 구성된 것을 특징으로 하는 배터리 모듈.
- 제3항에 있어서,상기 모듈 케이스의 개방부에 위치하며, 상기 전극 리드와 결합되도록 구성된 버스바 어셈블리를 더 포함하는 것을 특징으로 하는 배터리 모듈.
- 제1항에 있어서,상기 모듈 케이스는, 상기 셀 어셈블리로부터 가스 발생 시, 발생된 가스가 전방 및 후방 중 적어도 일측으로 배출되도록 구성된 것을 특징으로 하는 배터리 모듈.
- 제1항에 있어서,상기 트랩부는, 상기 측부 플레이트에서 적어도 전후 방향 중앙 부분에 형성된 것을 특징으로 하는 배터리 모듈.
- 제1항에 있어서,상기 트랩부는, 적어도 일부분이 전방 또는 후방으로 갈수록 오목한 부분의 깊이가 더 깊어지도록 형성된 것을 특징으로 하는 배터리 모듈.
- 제1항에 있어서,상기 모듈 케이스는, 상기 트랩부의 적어도 일 단부에 중앙 방향으로 돌출되게 형성된 돌출부를 더 구비하는 것을 특징으로 하는 배터리 모듈.
- 제1항에 있어서,상기 트랩부는, 적어도 일 단부가 전후 방향으로 오목하게 형성된 것을 특징으로 하는 배터리 모듈.
- 제1항 내지 제9항 중 어느 한 항에 따른 배터리 모듈을 다수 포함하는 배터리 팩.
- 제1항 내지 제9항 중 어느 한 항에 따른 배터리 모듈을 포함하는 에너지 저장 시스템.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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EP22763547.1A EP4207465A4 (en) | 2021-03-04 | 2022-02-25 | BATTERY MODULE WITH IMPROVED FIRE PREVENTION PERFORMANCE |
AU2022229167A AU2022229167A1 (en) | 2021-03-04 | 2022-02-25 | Battery module with improved fire protection performance |
US18/024,639 US20230361422A1 (en) | 2021-03-04 | 2022-02-25 | Battery module with improved fire protection performance |
CN202280006388.9A CN116075970A (zh) | 2021-03-04 | 2022-02-25 | 具有改进的火灾保护性能的电池模块 |
JP2023514130A JP2023540724A (ja) | 2021-03-04 | 2022-02-25 | 火事防止性能が向上したバッテリーモジュール |
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KR10-2021-0029058 | 2021-03-04 | ||
KR1020210029058A KR20220125086A (ko) | 2021-03-04 | 2021-03-04 | 화재 방지 성능이 향상된 배터리 모듈 |
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US (1) | US20230361422A1 (ko) |
EP (1) | EP4207465A4 (ko) |
JP (1) | JP2023540724A (ko) |
KR (1) | KR20220125086A (ko) |
CN (1) | CN116075970A (ko) |
AU (1) | AU2022229167A1 (ko) |
WO (1) | WO2022186564A1 (ko) |
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- 2021-03-04 KR KR1020210029058A patent/KR20220125086A/ko active Search and Examination
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- 2022-02-25 EP EP22763547.1A patent/EP4207465A4/en active Pending
- 2022-02-25 WO PCT/KR2022/002831 patent/WO2022186564A1/ko active Application Filing
- 2022-02-25 CN CN202280006388.9A patent/CN116075970A/zh active Pending
- 2022-02-25 AU AU2022229167A patent/AU2022229167A1/en active Pending
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Also Published As
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AU2022229167A1 (en) | 2023-05-04 |
EP4207465A4 (en) | 2024-07-31 |
EP4207465A1 (en) | 2023-07-05 |
KR20220125086A (ko) | 2022-09-14 |
US20230361422A1 (en) | 2023-11-09 |
CN116075970A (zh) | 2023-05-05 |
JP2023540724A (ja) | 2023-09-26 |
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