WO2022087756A1 - Iniciador electrónico programable no explosivo para tronadura de roca, y proceso de testeo y reacción exotérmica del iniciador - Google Patents
Iniciador electrónico programable no explosivo para tronadura de roca, y proceso de testeo y reacción exotérmica del iniciador Download PDFInfo
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- WO2022087756A1 WO2022087756A1 PCT/CL2020/050144 CL2020050144W WO2022087756A1 WO 2022087756 A1 WO2022087756 A1 WO 2022087756A1 CL 2020050144 W CL2020050144 W CL 2020050144W WO 2022087756 A1 WO2022087756 A1 WO 2022087756A1
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- Prior art keywords
- microprocessor
- explosive
- capacitor
- initiator
- electronic initiator
- Prior art date
Links
- 239000003999 initiator Substances 0.000 title claims abstract description 108
- 239000002360 explosive Substances 0.000 title claims abstract description 95
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- 238000005422 blasting Methods 0.000 title abstract description 19
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- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 2
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- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
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- MHWLNQBTOIYJJP-UHFFFAOYSA-N mercury difulminate Chemical compound [O-][N+]#C[Hg]C#[N+][O-] MHWLNQBTOIYJJP-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B3/00—Blasting cartridges, i.e. case and explosive
- F42B3/10—Initiators therefor
- F42B3/12—Bridge initiators
- F42B3/121—Initiators with incorporated integrated circuit
- F42B3/122—Programmable electronic delay initiators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B3/00—Blasting cartridges, i.e. case and explosive
- F42B3/10—Initiators therefor
- F42B3/12—Bridge initiators
- F42B3/124—Bridge initiators characterised by the configuration or material of the bridge
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B3/00—Blasting cartridges, i.e. case and explosive
- F42B3/10—Initiators therefor
- F42B3/12—Bridge initiators
- F42B3/125—Bridge initiators characterised by the configuration of the bridge initiator case
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B3/00—Blasting cartridges, i.e. case and explosive
- F42B3/10—Initiators therefor
- F42B3/12—Bridge initiators
- F42B3/128—Bridge initiators characterised by the composition of the pyrotechnic material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42D—BLASTING
- F42D1/00—Blasting methods or apparatus, e.g. loading or tamping
- F42D1/04—Arrangements for ignition
- F42D1/045—Arrangements for electric ignition
- F42D1/05—Electric circuits for blasting
- F42D1/055—Electric circuits for blasting specially adapted for firing multiple charges with a time delay
Definitions
- the purpose of this development is to provide a non-explosive (explosive) programmable electronic initiator for a rapidly expanding metallic mixture (such as plasma and/or explosives of different categories), which seeks to provide a solution to the following technical problems existing in the rock fragmentation; reach the high temperature necessary to activate a rapidly expanding metallic mixture with a very low voltage requirement; improve the rates of non-activated loads (shots left) with an effective test system; provide work continuity, increase productivity and safety in processes related to rock fragmentation with a programmed delay system in each initiator.
- a non-explosive (explosive) programmable electronic initiator for a rapidly expanding metallic mixture (such as plasma and/or explosives of different categories), which seeks to provide a solution to the following technical problems existing in the rock fragmentation; reach the high temperature necessary to activate a rapidly expanding metallic mixture with a very low voltage requirement; improve the rates of non-activated loads (shots left) with an effective test system; provide work continuity, increase productivity and safety in processes related to rock fragmentation with a programme
- Another initiation system is the safety fuse or slow fuse. This consists of black powder wrapped in textile threads, with a braider, later it was waterproofed with a layer of asphalt covered in turn, with a new textile or wax layer. From 1936 to date, detonating cord is used, which is a flexible and waterproof rope that houses an explosive inside, originally trinitrotoluene (TNT) and penthrite.
- TNT trinitrotoluene
- the massive application of explosives in the more than 140 years of history of the industry, has been due to its low cost and accessibility.
- the explosive technology used consists of the use of a blasting agent, "Anfo" (from the English Ammonium Nitrate - Fuel Oil), a mixture of ammonium nitrate and oil suitable for not producing toxic gases and has adequate power depending on the type. of rock to fragment.
- a technical problem with rock blasting is its effect on nearby rock, as it can lead to intense fragmentation and disruption of the surrounding rock integrity if the blasting or drilling systems are incorrect. The damage would be greater if the blast energy was transmitted to a more remote area, destabilizing the mine structures.
- the results of a blast depend on factors such as: the type of rock, the stress regime, the structural geology and the presence of water.
- appropriate measures to minimize the damage caused by a blast are: an appropriate choice of explosive, the use of perimeter blasting techniques, such as pre-division blasting (parallel and very close holes that define the perimeter of the excavation), decoupling charges (the diameter of the explosive is smaller than that of the blasthole), retardation time and stop holes.
- Some references regarding developments of electronic detonators can be the European patent DE 102005052578.4 where a method and a system for assigning a delay time to an electronic delay detonator are described, where the detonator includes an information register (24), in which the desired delay time value is written, supplied by the controller, where later, during a predetermined period of time (t), the content of the information register (24) is repetitively added to a counter register (26), where the content is accumulated, where after a division of the content of the counter register through the calibration time, the content of the counter register (26) is subsequently counted backwards using the same oscillator (18) that has controlled the accumulation process.
- the present invention allows the value of the delay time supplied by the controller to be adhered exactly, using a low precision oscillator (18) and without feedback from the detonator (12) to the controller.
- a detonator that includes a high voltage switch, an initiator and an initiation pellet, where the detonator also includes a low voltage detonation group to high voltage connected to the switch and the primer in such a way that the detonator includes a high voltage power source and a primer in an integrated package.
- the trigger can also include power and communications, a microprocessor, tracking and/or location technologies, such as rfid, gps, etc. and a starting pellet of an explosive or a combination of explosives.
- the combination explosive pellet has a first explosive having a first impact energy and a secondary high explosive in the starting pellet having a second impact energy greater than the impact energy of the first explosive.
- patents EP1105693 / WO0009967 can be mentioned where a method and an apparatus are presented to establish a blasting arrangement by loading at least one detonator in each one of a plurality of blast holes, placing explosive material in each blast hole, connecting to a trunk line to a control unit having a power source incapable of firing the detonators, sequentially connecting the detonators, by means of the respective bypass lines, to the trunk line and leaving each detonator connected to the trunk line.
- the apparatus includes means for receiving and storing in memory means identity data of each detonator, means for generating a signal to test the integrity of the detonator/trunk line connection and the functionality of the detonator, and being able to assign a delay of predetermined time for each detonator to be stored in memory.
- an explosive detonating system is presented to detonate an explosive charge with which it is, during use, arranged in a detonating relationship
- the detonating system comprising a detonator, including a detonator capsule: a detonation circuit within the detonator capsule, the detonation circuit comprising a conductive path: an initiator head within the detonator capsule, the initiator head comprising at least two spatially separated conductive electrodes and a resistive bridge that bridges the space between the electrodes, the initiator head being integrated with the detonation circuit in such a way that the conductive path passes along both the electrodes and the resistive bridge; a chargeable voltage source discharged within the detonator capsule, the chargeable voltage source being integrated with the detonation circuit and being electrically responsive to a charge property which is included in a charge signal which is, in use, communicated
- patent US6173651 B1 where a detonators control method equipped with an electronic ignition module is presented.
- Each module is associated with specific parameters including at least one identification parameter and burst delay time, and includes a trigger capacitor and a rudimentary internal clock.
- the modules are capable of establishing a dialogue with a trip control unit equipped with a reference time base.
- the identification parameters are stored in the modules by means of a programming unit; specific parameters are stored in the shot control unit; for each successive module, its internal clock is calibrated by the trigger control unit and the associated delay time is sent to the module; the modules are commanded to charge the firing capacitors and a firing command is sent to the modules by the firing control unit, triggering an eventual reset of the internal clocks as well as a firing sequence.
- a second US patent, US4674047 A1 discloses a detonation system for use with electrical power supply having a user operable firing console for selectively transmitting unit identification information, firing delay time information and selections from a set of commands including Exit, Delay, Trip (Time), Abort, Power On (Arm), Entry, and Store.
- the console displays the responses or digested information of the electrical delay detonators' responses to commands.
- Detonators have an explosive, a capacitor to store energy from the supply to activate the explosive, a circuit to charge the capacitor from the supply and transfer the energy from the capacitor to the explosive in response to the first and second signals generated in response to the commands.
- Each detonator can be programmed with a unique identification number and delay time. The time base of each detonator can be compensated in such a way as to avoid errors in the time base to achieve the correct delay.
- the security code circuits and software are described in such a way that each detonator can only be activated by authorized users.
- the fast-expanding metallic mixture corresponds to a chemical mixture composed of metal salts and powders, available in multiple formulas on the market, according to the following examples:
- thermochemical reaction A formula, like the one identified in Formula 1 above, subjected to temperatures of 1,500°C (Note that the ignition temperature varies according to the mixture ratios of metal salt and powder in each Formula), triggers the following thermochemical reaction of its components:
- the metal salt allows the oxidation of metal powder, the heat generated in the oxidation process of extremely high temperatures (3,000°C - 30,000°C) is generated instantly, releasing a large amount of thermal energy, converting iron products (Fe) and manganese oxide (Mn 3 O 4 ) in rapidly expanding vaporized gases; the vaporized expanded product it changes to the solid state and thus the expansion reaction stops.
- the release of expansive energy is what finally allows the rock to fracture due to the high pressures reached (5,000 - 20,000 Atm).
- metal nitrates are the most preferable, however, a rapidly expanding metal mixture can also be composed of other metal salts such as: metal oxides, metal hydroxides, metal carbonates, sulfates and perchlorates metallic. Said metal salt can be used alone or in combinations thereof.
- the metal nitrates can be additionally added with at least one metal salt selected from metal oxides, metal hydroxides, metal sulphates and perchlorates, to control the temperature required for the initiation of oxidation and the period of time required for oxidation.
- the metal powder is preferably selected from the group consisting of aluminum powder (Al), sodium powder (Na), potassium powder (K), lithium powder (Li), magnesium (Mg) powder, calcium (Ca) powder, Manganese (Mn) powder, Bath Powder (Ba), Chromium (Cr) powder, Silicon (Si) powder, and combinations thereof.
- the proportions used to compose the mixture of metal salts and the metal powder are defined according to the ratio of the amounts of oxygen generated by the metal salts and the amounts of oxygen required for the oxidation of the metal powder. This ratio of generation versus requirement provides a ratio based on molecular weights calculated from chemical formulas.
- composition, function and preparation process of a rapidly expanding metallic mixture is not the object of this document, however, there are different documents or patents, in the public domain with the information.
- the high temperature condition required to trigger the oxidation reaction of a rapidly expanding metal mixture can be achieved by various methods.
- one of the most widely used methods currently consists of the one described in patent EP 1 306 642 B1, in which a capsule structure is provided for a rapidly expanding metallic mixture, in which the heat of arc discharge high voltage (which generates temperatures of thousands of degrees), is used as a heat source.
- the capsule for a rapidly expanding metallic mixture comprises an external casing made of an insulating material, with the rapidly expanding mixture contained in the external casing, and two supply bars of energy coming out from both ends of the outer casing.
- Two main firing electrodes are provided to induce arc discharge at the inner ends of the two power supply bars.
- the two main firing electrodes induce an arc discharge between them when high voltage is applied to them.
- a high voltage of 2 kV or more is applied to the two power bars, an arc discharge is induced between two drive electrodes, instantly generating a high temperature of about 2,000°C or more at the positions around the drive electrodes.
- positive and negative activation The voltage requirement varies depending on the distance of the electrodes, i.e.
- the disadvantages of this method lie mainly in the high voltage requirement necessary to achieve the high temperature that triggers the chemical reaction and the lack of a testing system that allows reducing or eliminating the existence of non-activated capsules.
- patent EP 1 306 642 B1 could be reduced in projects that require a large volume of non-explosive fragmentation, because the high voltage required for the activation of the necessary chemical reaction would be a limitation for the number of capsules in the field. .
- the high voltage required for the activation of the necessary chemical reaction would be a limitation for the number of capsules in the field.
- the present development is related to a non-explosive programmable electronic initiator, whose purpose is to activate the chemical reaction of a rapidly expanding metallic mixture with a temperature greater than 1,000 °C; whose main characteristics are: a low voltage requirement (less than 35 V), which allows a large number of capsules in the mesh to be fragmented (greater than 400 capsules); a delay system (from 1 to 64,000 milliseconds), which allows greater precision and fragmentation control; a testing system that allows validating the circuit prior to ignition, which eliminates the existence of non-activated capsules.
- fast-expanding metallic mixtures unlike other analogous products, do not have any explosive component.
- its use allows obtaining similar results and with important advantages such as, reduction significant risk of handling and transport, due to the great stability of the chemical mixture against shocks, friction, pressure and high temperatures significant reduction in risks of occupational accidents; operational continuity due to the fact that the evacuation of people and equipment is minimal in a radius close to the blasting area; lower environmental impact due to minimal levels of vibration, noise, shrapnel and no toxic gases.
- a particular problem with rock blasting is its effect on nearby rock, as it can lead to intense fragmentation and disruption of the surrounding rock integrity if the blasting or drilling systems are incorrect.
- One of the measures used to minimize the environmental impact generated by high vibrations and improve the safety of field work is the delay time in blasting.
- each initiator has a programmable delay system, which allows the required delay period to be programmed in advance and individually according to the blasting schedule.
- Each Non-Explosive Programmable Electronic Initiator [07] can be programmed with a delay time in a range between 1 millisecond and 64,000 milliseconds.
- Some electronic initiators for explosives have a programmable delay time, such is the case of patent US 6 173 651 (14,000 milliseconds, being patent EP 1105693 B1, WO 0009967 A1 (according to patent 3,000 milliseconds, without However, according to the data sheet 30,000 milliseconds) whose initiators have the longest delay time known to date.
- a fundamental characteristic of the present development consists in delivering the necessary voltage for the activation of one (or more) Non-Explosive Programmable Electronic Initiator [07] for a rapidly expanding metallic mixture.
- a voltage between 24V and 35V is required.
- the same voltage is required: 24V and 35V.
- the voltage requirement does not vary either by distance between activation electrodes, or by electronic initiator units arranged on the line. This is because the connection of each Non-Explosive Programmable Electronic Initiator [07] to the line is in parallel.
- each initiator requires 2,000V or more.
- this patent indicates different voltage requirements depending on the distance between the activation electrodes; when the activation electrodes are separated by 200mm or more, the voltage requirement for activation is between 6,000V and 7,000V; when the activation electrodes are separated by 100mm or more, the voltage requirement for activation is between 3,000V and 4,000V. Because the connection of the initiators to the line is in sign, the applied voltage is divided into the number of initiators that the line has, so the voltage requirement of each initiator arranged in a blast increases the total voltage requirement. .
- the required high temperature (1,000 °C or more) is reached through the controlled discharge of Capacitor C7 [21] in the filament [30], which produces its incandescence for the necessary period, reaching the temperature required for the activation of the first rapidly expanding metallic mixture [13], which fulfills the role of non-explosive tallow.
- the necessary temperature is reached (1,200 °C or more) for the activation of the second fast-expanding metallic mixture [15].
- the process requires, among other things, the presence of a supervisor throughout the operation, ensuring the clearance of the compromised area, removing workers and equipment not related to the operation, and using the minimum necessary personnel for this activity, thus reducing the number exposed to highly critical conditions.
- the frequency change verification is essential to ensure the correct state prior to the activation of the "sleep" functionality of Microprocessor IC1 [07], which is directly related to the low voltage requirement and the reach of the maximum delay time of 64,000 milliseconds.
- Delay The concept of delay or delay time in the present development refers to the assignment of a countdown delay period measured in milliseconds (ms) that determine the ignition sequence in a blast. Each trigger is assigned a predefined period of time (between 1 and 64,000 milliseconds).
- Missed shots The concept of missed shots for the present development refers to the complete or partial ignition failure of one (or more) capsule included in the ignition sequence in a blast. It is an undesirable consequence of high risk, in which remains of the product that can be activated by any mechanical effect during the excavation, milling or crushing stages of the mining process.
- Microprocessor The concept of microprocessor used for this development refers to the set of integrated electronic circuits that carry out the instructions and tasks involved in information processing.
- the present development requires a Microprocessor that has the following characteristics: serial communication, low power consumption (preferably but not restricted to 20 nA in sleep mode), internal precision oscillator (preferably but not restricted to 31 KHz at 32 MHz), feasibility of integrating an external low-frequency oscillator (preferably but not restricted to 32 KHz), memory capacity (preferably but not restricted to EEPROM 256 bytes, SRAM 256 bytes) and sufficient input and output ports to perform the functions that are required (at least 8).
- the Microchip PIC16LF1824/1828 model has been defined as a feasible Microprocessor of uses for the execution of the commands and programs required in the present development.
- Communication protocol it is a system of rules that allow two or more entities of a communication system to communicate with each other to transmit information. For the present development, it refers to the form of bidirectional communication between the Command Team [01] and the Non-Explosive Electronic Initiator(s) [07] that maintains the transmission of information and the necessary voltage for the operation of the Electronic Initiator(s). NO Explosives [07] and that can occur under the language of transmission of bits per second through voltage pulses.
- Eilamento For the present development it refers to a filament of a thickness, length and materiality that achieves a balance between capacitance and resistance of the filament to have a point between not being cut and reaching the necessary temperature, by way of example and without restricting the scope of this term, a tungsten filament with a purity that varies between 99.90% and 99.99%, preferably 99.93%, 99.95% and 99.97%, in a spiral format with a length that varies between 1 and 3 mm, preferably 2 mm, 2.2 mm, 2.5 mm, with a diameter in the range between 0.01 mm and 0.1 mm, preferably 0.01 mm, 0.02 mm , 0.03 mm and with a resistance between 2.5 and 4.5 ohms, preferably 3 ohms, 3.2 ohms, 3.5 ohms, 3.6 ohms, 3.7 ohms, 3.8 ohms and 3.9 ohms.
- Plasma for the present development, plasma is considered as a mixture of rapidly expanding metal salts that, when initiated, produces an exothermic reaction of high temperature, in a confined space. It is a very stable substance, as it does not react to high temperatures, shocks, friction and high pressures. The reaction starts at high temperatures, over 1,000°C.
- a Command Unit (Console or Master) [01] is required, with the ability to convert serial communication into a communication protocol based on Voltage Modulation [03] through a Line of Communication and Power (parallel lines) [02A and 02B], a connector [04] that connects said parallel lines with the (or) Non-Explosive Programmable Electronic Initiator [07] ( Figure 1 A and 1 B) and a Reader device.
- RFID card (Logger) [06].
- Command Unit [01] Other general requirements for the operation of the Command Unit [01] consist of, but are not limited to: external power source (preferably 24V to 36V battery), microprocessor, Micro SD card, Bluetooth system, RFID Reader [06], wireless transmission and screen with keypad.
- external power source preferably 24V to 36V battery
- microprocessor preferably 24V to 36V battery
- Micro SD card preferably 24V to 36V battery
- Bluetooth system preferably 24V to 36V battery
- RFID Reader [06] wireless transmission and screen with keypad.
- a Communication and Power Line [02A and 02B] is required, made up of two parallel copper cables, each of them with a diameter greater than 0.5 millimeters in diameter, whose resistance is less than 36 ohms per kilometer.
- These cables fulfill an essential role, and when used in accordance with the instructions in table I, they allow to ensure both the reliability in the transmission of Voltage Modulation [03] and communication protocol ( Figure 2), as well as the power received by each Non-Explosive Programmable Electronic Initiator [07], Table I: Electrical Conductor Resistance
- Formula 1 2Fe(NO 3 ) 2 +12Mn ; Patent N° 10-0213577 Formula 2: Fe(NO 3 ) 2 +3CuO+6AI ; Patent No. 10-0213577
- the present development consists of a Non-Explosive Programmable Electronic Initiator [07], composed of a capsule with two types of fast-expanding metallic mixture [13] and [15] that allows it to be attached to a container tube or sleeve [16]. and a seal plug [17] (Figure 3); and that, once it receives the Voltage Modulation [03] and the communication protocol ( Figure 2), by means of commands, the functions that allow reaching the high temperatures required to start the chemical reaction are activated, using a low voltage requirement. (less than 35V), with a delay system (from 1 ms to 64,000 ms), and with a testing system that allows validating the circuit prior to ignition.
- Each Non-Explosive Programmable Electronic Initiator [07] has a unique and unrepeatable identification (ID), which is recorded at the factory and coincides with the internal code of the external RFID card [05].
- ID unique and unrepeatable identification
- the Command Unit [01] captures said ID through the serial port via bluetooth through the RFID reader unit (Logger) [06] ( Figure 1) and stores it on the MicroSD card belonging to the Command Unit [01 ]. The data remains available for later use in certain processes.
- the Non-Explosive Programmable Electronic Initiator [07] has a Microprocessor IC1 [28] ( Figure 4), with an Internal Oscillator and a non-volatile EEPROM memory [35] ( Figure 5).
- the Voltage Modulation [03] ( Figure 2) sent consists of a constant square wave with an amplitude defined between 24V and 35V ( Figure 2A) and a period of 4.0 ms. The high bit of 4 milliseconds and the low bit of 0.2 milliseconds allow a constant voltage to be maintained ( Figure 2A).
- the data is sent at a communication speed equivalent to 2400 bauds from the Command Unit [01] through the Communication and Power Line [02A and 02B] and are received by the Non-Explosive Programmable Electronic Initiator [07] ( Figure 2C).
- the data is sent through the Communication and Power Line [02A and 02B] from the Non-Explosive Programmable Electronic Initiator [07] and is received by the Command Unit [01] ( Figure 2B).
- the sending of data from the Non-Explosive Programmable Electronic Initiator [07] to the Command Unit [01] is determined by a bit of 25 us (microseconds), equivalent to 40,000 bauds; data transmission (one byte) is done on the low bit of the communication line.
- the input of the Non-Explosive Programmable Electronic Initiator [07], comprises a diode D1 and a Voltage Rectifier D2 [18] ( Figure 4), which are connected to the Communication and Power Line [02A and 02B].
- Diode D1 suppresses transient currents and prevents current leakage.
- the D2 Voltage Rectifier with voltage inputs between 24V and 35V, transforms alternating current (AC) into direct current (DC) ( Figure 4).
- a Voltage Regulator IC2 [20] receives the voltage from 24V to 35V and the rectified current (DC). This Voltage Regulator IC2 regulates the initial voltage to 5V ( Figure 4).
- two voltage dividing resistors R1 and R2 [24] are connected to the system input of the Programmable Electronic Non-Explosive Initiator [07]. , which lower the voltage from 24V-35V to 5V, thus adjusting to the operating level of Microprocessor IC1 [28].
- R1 operates with a resistance between 90 and 170 Kohm, preferably 110 Kohm, preferably 120 Kohm and preferably 130 Kohm
- R2 operates with a resistance between 15 Kohm and 25 Kohm, preferably 110 Kohm, preferably 120 Kohm and preferably 130 Kohm
- the square wave with the data is then transmitted from the Command Unit [01] to the INT/IO PORT input pin [41] ( Figure 7) of the Microprocessor IC1 [28], being converted into bytes using an algorithm.
- the Microprocessor IC1 [28] through the transmission block EUSART [28E] ( Figure 4) pin TX [43] ( Figure 9) transmits the output data.
- the output data is inserted through a transistor T1 and two resistors R3 and R4 [23] in the Communication and Power Line [02A and 02B],
- the response data is then sent to the Command Unit [01] for its processing ( Figure 2B).
- diodes D4 and D5 [19] are connected to the 5V voltage input. In this stage of the circuit, the 5V input voltage is reduced to 3.6V, necessary for the operation of the Microprocessor IC1 [28]. Diodes D4 and D5 [19] suppress transient currents and prevent current leakage.
- Capacitor C4 [19] is an energy reservoir that is kept continuously charged. It is essential to point out that this device will be the power source for Microprocessor IC1 [28] and will keep it active for up to 64,000 milliseconds, once the Communication and Power Line [02A and 02B] is interrupted. The discharge time of this capacitor must be greater than the programmed delay time; This point is addressed in greater depth when the operation of the External Oscillator [25] ( Figure 4) and OSC [36] ( Figure 6) are described.
- the Filament [30] is a Tungsten spiral with a length that varies between 1 and 3 mm, preferably 2 mm, 2.2 mm, 2.5 mm, with a diameter ranging between 0.01 mm and 0.1 mm.
- mm preferably 0.01 mm, 0.02 mm, 0.03 mm and with a resistance ranging from 2.5 to 4.5 ohms, preferably 3 ohms, 3.2 ohms, 3.5 ohms, 3 .6 ohm, 3.7 ohm, 3.8 ohm and 3.9 ohm.
- a transistor T4 [22] (figure 4) connected to a series resistor R12 (current limiter), which in turn is connected to ground (Vss or GND), maintains the Filament [30] and the Capacitor C7 [21] with a voltage lower than 1 V.
- the Transistor T4 [22] through a command (Command 5), is deactivated so that it is start the charging process of Capacitor C7 [21], prior to the trip.
- this Transistor T4 [22] discharges Capacitor C7 [21] to ground (Vss or GND), reducing the voltage of Capacitor C7 [21] to a value lower than 1 V and preventing the Filament [30] from having the necessary voltage to ignite and activate the rapidly expanding metallic mixture.
- the Filament [30] is connected to a Capacitor C7 [21] (initial charge 0V) and to the transistor T2 [27].
- the Trigger Command (Command 7) is activated, the I/O PORT C5 pin [28B] ( Figure 4) activates the transistor T2 [27] for the discharge of the Capacitor C7 [21] in the Filament [30], causing its incandescence.
- Resistor R9 [21] limits the input current to a value that ranges between 2 and 3 milliamperes, this allows a slow charge of Capacitor C7 [21 ] and a minimum current consumption. Diode D3 [21] prevents current leakage from Capacitor C7 [21],
- the Test System is fed by the data from the sensor configured on the ADC/AN pin [42] ( Figure 8). The data obtained are analyzed by internal algorithm of the Microprocessor IC1 [28].
- the Operation Test System is activated in Command 3 (described later) and is made up of the following tests:
- Capacitor C7 [21] Initial Status Verification: o
- a transistor T4 [22] Figure 4
- a resistor R12 [22] is activated to connect the positive output of capacitor C7 [21] to ground ( Vss or GND) and keeps the capacitor charge at a voltage lower than 1V.
- the verification of the initial state of the capacitor C7 [21] consists in measuring the voltage of the capacitor C7 through the sensor [28C].
- the sensor reads the data regarding the voltage of the Capacitor C7 [21] and stores it in a variable of 10 bits in the Microprocessor IC1 [28] equivalent to a certain amount of 1024 parts.
- the initial voltage is in a range between 24V and 35V, one part is equivalent to a range between 0.023V and 0.034V; then a range between 30 and 43 parts is equivalent to a voltage of less than 1V.
- the reading after this milestone must be less than 1 V.
- a reading greater than this value means defective Capacitor C7 [21] or defective Transistor T4 [22].
- Capacitor C7 Voltage [21] ⁇ 800 parts implies the Unused Initiator.
- Programmed Delay Verification o
- Data regarding the programmed delay is sent from the Command Unit [01] to the Programmable Non-Explosive Electronic Initiator [07] and stored in the EEPROM memory.
- the Non-Explosive Programmable Electronic Initiator [07] through an algorithm, verifies that the data sent by the Command Unit [01] is equal to the data received by the Microprocessor IC1 [28].
- the Microprocessor IC1 [28] sends a response to the Command Unit [01].
- the programmed response time is 150 milliseconds.
- Scheduled Response Time > 150 milliseconds implies a Communication Error.
- the response data referring to the delay is identical to the data sent by the Command Unit [01], it receives an acknowledgment code (ACK).
- ACK acknowledgment code
- External Oscillator Status Verification [25] and Frequency Change for sleep mode o
- the External Oscillator [25] is activated and the emitted beats per second are read. These pulsations must coincide with the frequency of 32 KHz.
- the Command Unit [01] receives an error code.
- Microprocessor IC1 [28] which has an internal oscillator preferably of 16 MHz [28A] ( Figure 4) although it does not exclude alternatives with higher frequency, has an approximate power consumption of 2 mA (milliamps).
- Figure 6 is a detailed representation of the dynamics that is generated in the Clock Source Block [28A] belonging to Figure 4.
- the present development contemplates a 32 kHz External Oscillator Q1 [25] ( Figure 4) connected to Microprocessor IC1 [28], whose objective is to reduce energy consumption, lowering the system frequency from 16 MHz to 32 KHz.
- the Filament [30] ( Figure 4) is made up of Tungsten wire in the shape of a spiral with a length that varies between 1 and 3 mm, preferably 2 mm, 2.2 mm, 2.5 mm, with a diameter of a range between 0.01 mm and 0.1 mm, preferably 0.01, 0.02, 0.03 and with a resistance ranging between 2.5 and 4.5 ohms, preferably 3 ohms, 3.2 ohm, 3.5 ohm, 3.6 ohm, 3.7 ohm, 3.8 ohm and 3.9 ohm.
- the TIMER1 [37] ( Figure 6) of the Microprocessor IC1 [28] can read the pulsations emitted by it and associate by means of a algorithm its equivalence in time.
- the delay time is defined in the field and before the execution of the shot (Fire).
- the defined delay time is programmed in the Non-Explosive Programmable Electronic Initiator [07] through the Control Unit [01 ].
- the data related to the programmed delay time is stored in the non-volatile EEPROM memory of the Microprocessor IC1 [28] of each Non-Explosive Programmable Electronic Initiator [07],
- the delay time of each Non-Explosive Programmable Electronic Initiator [07] is limited by three characteristics associated with different functionalities.
- the capacitor C4 [19] ( Figure 4) fulfills the role of external battery of the Microprocessor IC1 [28] after the line cut; the charge autonomy of Capacitor C4 [19], is decisive for the maximum period of operation of Microprocessor IC1 [28] once the “Fire” command (Command 7) is activated and the Communication and Power Line is cut [ 02A and 02B],
- the 32 kHz External Oscillator Q1 [25] emits 32,000 pulses per second, these are counted by TIMER1 [37] ( Figure 6) of Microprocessor IC1 [28]. It is these pulsations that, by means of an algorithm, their equivalence in time allows a countdown to reach the programmed delay time.
- Microprocessor IC1 [28] has a sleep mode function “sleep”, which is activated by an instruction.
- sleep mode function “sleep”, which is activated by an instruction.
- the TIMER1 oscillator of Microprocessor IC1 [37] is not affected and the peripherals that operate from it can continue to work in sleep ( Figure 6); the existence of an External Oscillator Q1 [25], allows to use the “sleep” function of Microprocessor IC1 [28] and substantially lower its energy consumption; Note that the “sleep” function, although it is true that it could be activated with the internal oscillator of Microprocessor IC1 [28], the energy consumption associated with this form would be 600 nA. Using the External Oscillator Q1 [25] and having activated the “sleep” functionality, this consumption is 20nA.
- each Non-Explosive Programmable Electronic Initiator [07] is limited to a range between 1 and 64,000 milliseconds.
- the activation of Fire causes the following actions: a) All the interruptions of the Microprocessor IC1 [28] are disconnected to avoid an early awakening of the dormant function “sleep”. b) The load of Capacitor C7 [21] is disconnected, so that it maintains its maximum load while Microprocessor IC1 [28] is in "sleep" mode and TIMER1 counts down. c) Information related to the delay time stored in the non-volatile EEPROM memory of Microprocessor IC1 [28] is retrieved and the programmed delay time is loaded into the TIMER1 counter (Command 2). d) The “sleep” function of Microprocessor IC1 [28] is enabled and only TIMER1 functions to start the countdown of the delay time. e) The delay time countdown starts.
- Capacitor C7 [21] is enabled, at that moment Transistor T2 (NPN) [27] with its Resistor R8 [27] is enabled to discharge all the energy accumulated in Capacitor C7 [ 21] on the Filament [30] ( Figure 4).
- Non-Explosive Programmable Electronic Initiator [07] carries out the processes described below:
- Process 1 The input voltage (24V to 35V) of the Non-Explosive Programmable Electronic Initiator [07] is rectified by means of two capacitors, C1 and C2 [18], a diode D1 and a rectifier bridge D2 [18].
- Capacitor C3 keeps the input voltage stable (24V and 35V).
- the Voltage Regulator IC2 lowers the input voltage (24V and 35V) to 5V, input voltage for diodes D4 and D5 [19].
- Process 3 The data enters the Non-Explosive Programmable Electronic Initiator [07] through resistors R1 and R2 [24] ( Figure 04). These resistors filter (separate) the byte frame associated with the incoming data and reduce its input voltage (between 24V and 35V) to the level required by Microprocessor IC1 [28] (between 3.3V and 5.0V).
- Process 4 Two diodes D4 and D5 [19] are placed on the voltage input line to the Microprocessor IC1 [28], these components regulate the voltage to the voltage required by the Microprocessor IC1 [28] (3.6V) and stop current loss. Also in the voltage input line to Microprocessor IC1 [28], a 470 uF Capacitor C4 [19] is placed, which keeps the input voltage stable (3.6V). Capacitor C4 [19] also fulfills the role of energy accumulator.
- Process 5 Microprocessor IC1 [28] has a PIN configured as a sensor. The sensor is connected to two resistors R6 and R7 [26], which fulfill the role of voltage divider, between Capacitor C7 [21], Filament [30] and ground (VSS).
- the sensor [28C] ( Figure 4) reads the data resulting from the verification regarding the continuity of the Filament [30] (Command 3).
- the resistance value is expected to be between 2.5 and 4.5 ohms.
- the sensor of the Microprocessor IC1 [28] reads the state of the initial charge of the Capacitor C7 [21].
- the first sample taken is expected to be of a value less than 1 V (Command 3).
- Microprocessor IC1 [28] deactivates Transistor T4 [22], activates the PIN connected to Transistor T3 [29] through Resistors R10 and R5 [29], This allows to start charging Capacitor C7 [21], The charging process of Capacitor C7 [21] is programmed for 30 seconds.
- Process 7 The Microprocessor sensor IC1 [28] records charging voltage data every 30 milliseconds during the 30 seconds of charging of Capacitor C7 [28]. The generated data is stored in a non-volatile EEPROM memory of the Microprocessor IC1 [28]. The data will be processed via Command 3, indicated later.
- Process 8 Capacitor C7 [21] is connected to the rectified power line (Process 1). Resistor R9 [21] and diode D3 [21] limit the system load. A slow charge of Capacitor C7 [21 ] (30 sec) and a current consumption between 2 and 3 milliamps is generated.
- Process 9 Connected to Microprocessor IC1 [28], External Oscillator Q1 [25] and Capacitors C5 and C6 [25] keep the 32 Khz oscillation stable.
- Process 11 The Microprocessor IC1 [28] activates the transistor T2 [27] through the Resistor R8 [27], the discharge of the Capacitor C7 [21] occurs through the Filament [30], producing incandescence in the Filament [30].
- Process 13 The exothermic reaction of the activation of the Rapid Expansion Metallic Mix [13] allows reaching the temperature of 1,200 C and activates the Rapid Expansion Metallic Mix [15].
- Command 1 Records in the non-volatile EEPROM memory of Microprocessor IC1 [28] the ID, RFID identification code [05], uniquely and unrepeatablely identifying a Non-Explosive Programmable Electronic Initiator [07].
- Command 2 Records in the non-volatile EEPROM memory of Microprocessor IC1 [28] the programmed delay time, which varies between 1 millisecond and 64,000 milliseconds.
- Command 3 Query ID. It diagnoses the current functionality, excluding Command 7 (Trip).
- Diagnosis 1 Through an algorithm, the response time of the Programmable Non-Explosive Electronic Initiator [07] is checked. In the event that said response time exceeds a programmed time limit (100 milliseconds), it responds with an error code.
- Diagnosis 3 Using a sensor, it is verified that the Filament [30] has continuity between 2.5 and 4.5 ohms. In the case of failure, it responds with an error code. In case of error, transistor T4 [22] is activated and forces the discharge to ground (Vss or GND) of capacitor C7 [21],
- Diagnosis 4 Through an algorithm, the data associated with the programmed delay stored in the non-volatile EEPROM memory of Microprocessor IC1 [28] is retrieved. It is verified that this data coincides with the data related to the programmed delay time sent by the Command Unit [01]. In the case of failure, it responds with an error code.
- Diagnosis 5 Through an algorithm, the data associated with the frequency of the External Oscillator [25], stored in the non-volatile EEPROM memory of the Microprocessor IC1 [28] at system startup, is recovered. In the event that the register indicates an error, the transistor T4 [22] is activated and forces the discharge to ground (Vss or GND) of the capacitor C7 [21],
- Command 4 Allows changing the location of one (or more) Non-Explosive Programmable Electronic Initiator [07], Allows modifying the delay assignment of one (or more) Non-Explosive Programmable Electronic Initiator [07], Allows manual reprogramming of one (or more) Non-Explosive Programmable Electronic Initiator [07],
- Command 5 Preparation before the shot. Disables Transistor T4 [22] to exit ground state. Enables Transistor T3 [29] to proceed with the charge of Capacitor C7 [21] in a period of time of 30 seconds; reads and stores the charging data of Capacitor C7 [21] every 30 milliseconds during the 30 seconds of charging. Stored data is available for reading in a variable of the Microprocessor IC1 [28]. It disables the internal oscillator (16 Mhz) of Microprocessor IC1 [28] and enables the External Oscillator [25] (32 KHz).
- Command 6 Safety measure in case of any failure. In the case of failure in Command 5, it responds with an error code, Transistor T4 [22] is activated, connecting Capacitor C7 [21] to ground and proceeding to its discharge.
- Command 7 Fire. Disables external Microprocessor interrupts [28]. It disables the charge of Capacitor C7 [21 ], TIMER1 is loaded with the data related to the delay time. Activates “sleep” function of Microprocessor IC1 [21], Enables countdown of the assigned delay time of the Programmable Non-Explosive Electronic Initiator [07], Once the countdown assigned to the programmed delay time has finished, activates Capacitor C7 [21 ]. Activates output I/O PORT C5 [40] ( Figure 7) of Microprocessor IC1 [28] and Transistor T2 [27],
- I/O port input via interrupt (INT), for data processing (28D Figure 4)
- FIG. 1A shows the disposition of the elements of the present system using a single parallel Communication and Power line [02A and 02B] for a single Non-Explosive Programmable Electronic Initiator [ 07] and an RFID reader that reads the unique ID code of the Non-Explosive Programmable Electronic Initiator [07].
- Scheme B or figure B shows the present system using a single parallel Communication and Power line [02A and 02B] for four or more Non-Explosive Programmable Electronic Initiators [07],
- This figure represents three schemes A, B and C, which represent voltage waves, where figure 2A, upper, shows the beginning of the bidirectional communication, where the Voltage Modulation [03] sent, consists of a constant square wave with a amplitude defined between 24V and 35V and a period of 4.0 ms. The high bit of 4 milliseconds and the low bit of 0.2 milliseconds allow a constant voltage to be maintained.
- Figures 2B and 2C show diagrams showing the details of a bidirectional communication protocol with a transmission speed of 2,400 bits per second that is used in the Communication and Power Line [02A and 02B],
- FIG. 7 shows a scheme of how the square wave with the data is transmitted from the Command Unit [01] to the INT/IO PORT input pin [41] and IO output ports [28B] (for charging Capacitor C7 [38 ], for discharge of Capacitor C7 [39], for firing and discharge of Capacitor C7 in Filament [30] [40]) ( Figure 4) of Microprocessor IC1 [28], converting it into bytes using an algorithm.
- figure 7 refers to the PINS CO, C3, C5 of the microcontroller IC1 of figure 4.
- Figure 8 :
- This figure presents a schematic of the analog information received by the Microprocessor IC1 [28] through the ADC/AN pin [42] ( Figure 4) [28C] where it is converted to digital for sensor reading.
- FIG. 4 presents a schematic of how the Microprocessor IC1 [28], through the USART pin TX transmission block [43] ( Figure 4) [28E], transmits the output data, where the output data is inserted through a transistor T1 and two resistors R3 and R4 [23] in the Communication and Power Line [02A and 02B],
- ⁇ (T) ⁇ or (1 + ⁇ ( ⁇ T)) (Equation No.1)
- ⁇ (T) Resistivity of a metal as a function of a temperature differential.
- ⁇ o Initial resistivity of the metal.
- ⁇ Temperature Coefficient per degree centigrade of the metal.
- ⁇ T Temperature differential ( Final T - Initial T).
- R(T) Resistance of the metal to a temperature variation
- T F Temperature variation with respect to the initial
- T F ((R F / RO) - 1 )/ ⁇ + T O (Equation No.4)
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Abstract
Description
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Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
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EP20958925.8A EP4239278A1 (en) | 2020-10-29 | 2020-10-29 | Programmable non-explosive electronic initiator for rock blasting, and exothermic reaction and testing process of the initiator |
PCT/CL2020/050144 WO2022087756A1 (es) | 2020-10-29 | 2020-10-29 | Iniciador electrónico programable no explosivo para tronadura de roca, y proceso de testeo y reacción exotérmica del iniciador |
CA3196525A CA3196525A1 (en) | 2020-10-29 | 2020-10-29 | Programmable non-explosive electronic initiator for rock blasting, and exothermic reaction and testing process of the initiator |
US18/251,225 US20230408230A1 (en) | 2020-10-29 | 2020-10-29 | Non-explosive programmable electronic initiation system for rock blasting |
PE2023001499A PE20240936A1 (es) | 2020-10-29 | 2020-10-29 | Sistema de iniciacion electronico programable no explosivo para tronadura de roca |
AU2020474620A AU2020474620A1 (en) | 2020-10-29 | 2020-10-29 | Non-explosive programmable electronic initiation system for rock blasting |
CL2023001058A CL2023001058A1 (es) | 2020-10-29 | 2023-04-12 | Sistema de iniciación electrónico programable no explosivo para tronadura de roca |
CONC2023/0004958A CO2023004958A2 (es) | 2020-10-29 | 2023-04-20 | Iniciador electrónico programable no explosivo para tronadura de roca, y proceso de testeo y reacción exotérmica del iniciador |
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PCT/CL2020/050144 WO2022087756A1 (es) | 2020-10-29 | 2020-10-29 | Iniciador electrónico programable no explosivo para tronadura de roca, y proceso de testeo y reacción exotérmica del iniciador |
Country Status (8)
Country | Link |
---|---|
US (1) | US20230408230A1 (es) |
EP (1) | EP4239278A1 (es) |
AU (1) | AU2020474620A1 (es) |
CA (1) | CA3196525A1 (es) |
CL (1) | CL2023001058A1 (es) |
CO (1) | CO2023004958A2 (es) |
PE (1) | PE20240936A1 (es) |
WO (1) | WO2022087756A1 (es) |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4674047A (en) | 1984-01-31 | 1987-06-16 | The Curators Of The University Of Missouri | Integrated detonator delay circuits and firing console |
US5171935A (en) | 1992-11-05 | 1992-12-15 | The Ensign-Bickford Company | Low-energy blasting initiation system method and surface connection thereof |
KR100213577B1 (ko) | 1997-06-10 | 1999-08-02 | 김창선 | 급팽창 금속 혼합물 |
WO2000009967A1 (en) | 1998-08-13 | 2000-02-24 | Expert Explosives (Proprietary) Limited | Blasting arrangement |
US6173651B1 (en) | 1996-05-24 | 2001-01-16 | Davey Bickford | Method of detonator control with electronic ignition module, coded blast controlling unit and ignition module for its implementation |
US20050034624A1 (en) * | 2003-07-15 | 2005-02-17 | Special Devices, Inc. | Firing-readiness diagnostic of a pyrotechnic device such as an electronic detonator |
EP1306642B1 (en) | 2001-10-23 | 2006-03-08 | Chang Sun Kim | Blasting cartridge for a rapidly expanding metallic mixture |
EP2678633A1 (en) | 2011-02-21 | 2014-01-01 | Ael Mining Services Limited | Detonation of explosives |
US8746144B2 (en) | 2008-10-24 | 2014-06-10 | Battelle Memorial Institute | Electronic detonator system |
CA2802888C (en) * | 2010-06-18 | 2018-08-21 | Battelle Memorial Institute | Non-energetics based detonator |
US20180371859A1 (en) * | 2015-12-09 | 2018-12-27 | Interwell P&A As | Ignitor, system and method of electrical ignition of exothermic mixture |
-
2020
- 2020-10-29 EP EP20958925.8A patent/EP4239278A1/en active Pending
- 2020-10-29 AU AU2020474620A patent/AU2020474620A1/en active Pending
- 2020-10-29 WO PCT/CL2020/050144 patent/WO2022087756A1/es unknown
- 2020-10-29 CA CA3196525A patent/CA3196525A1/en active Pending
- 2020-10-29 PE PE2023001499A patent/PE20240936A1/es unknown
- 2020-10-29 US US18/251,225 patent/US20230408230A1/en active Pending
-
2023
- 2023-04-12 CL CL2023001058A patent/CL2023001058A1/es unknown
- 2023-04-20 CO CONC2023/0004958A patent/CO2023004958A2/es unknown
Patent Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4674047A (en) | 1984-01-31 | 1987-06-16 | The Curators Of The University Of Missouri | Integrated detonator delay circuits and firing console |
US5171935A (en) | 1992-11-05 | 1992-12-15 | The Ensign-Bickford Company | Low-energy blasting initiation system method and surface connection thereof |
US6173651B1 (en) | 1996-05-24 | 2001-01-16 | Davey Bickford | Method of detonator control with electronic ignition module, coded blast controlling unit and ignition module for its implementation |
KR100213577B1 (ko) | 1997-06-10 | 1999-08-02 | 김창선 | 급팽창 금속 혼합물 |
EP1105693B1 (en) | 1998-08-13 | 2007-07-11 | Orica Explosives Technology Pty Ltd | Blasting arrangement |
EP1105693A1 (en) | 1998-08-13 | 2001-06-13 | Expert Explosives (Proprietary) Limited | Blasting arrangement |
WO2000009967A1 (en) | 1998-08-13 | 2000-02-24 | Expert Explosives (Proprietary) Limited | Blasting arrangement |
CA2339167C (en) | 1998-08-13 | 2008-01-22 | Expert Explosives (Proprietary) Limited | Blasting arrangement |
EP1306642B1 (en) | 2001-10-23 | 2006-03-08 | Chang Sun Kim | Blasting cartridge for a rapidly expanding metallic mixture |
US20050034624A1 (en) * | 2003-07-15 | 2005-02-17 | Special Devices, Inc. | Firing-readiness diagnostic of a pyrotechnic device such as an electronic detonator |
US8746144B2 (en) | 2008-10-24 | 2014-06-10 | Battelle Memorial Institute | Electronic detonator system |
EP3051248B1 (en) * | 2008-10-24 | 2018-02-28 | Battelle Memorial Institute | Electronic detonator system |
CA2802888C (en) * | 2010-06-18 | 2018-08-21 | Battelle Memorial Institute | Non-energetics based detonator |
EP2678633A1 (en) | 2011-02-21 | 2014-01-01 | Ael Mining Services Limited | Detonation of explosives |
ES2540573T3 (es) | 2011-02-21 | 2015-07-10 | Ael Mining Services Limited | Detonación de explosivos |
US20180371859A1 (en) * | 2015-12-09 | 2018-12-27 | Interwell P&A As | Ignitor, system and method of electrical ignition of exothermic mixture |
Also Published As
Publication number | Publication date |
---|---|
CO2023004958A2 (es) | 2023-05-08 |
PE20240936A1 (es) | 2024-05-06 |
AU2020474620A1 (en) | 2023-06-15 |
CA3196525A1 (en) | 2022-05-05 |
EP4239278A1 (en) | 2023-09-06 |
CL2023001058A1 (es) | 2023-08-04 |
US20230408230A1 (en) | 2023-12-21 |
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