WO2021082279A1 - 一种钻井水基泥浆干化剂 - Google Patents
一种钻井水基泥浆干化剂 Download PDFInfo
- Publication number
- WO2021082279A1 WO2021082279A1 PCT/CN2020/000263 CN2020000263W WO2021082279A1 WO 2021082279 A1 WO2021082279 A1 WO 2021082279A1 CN 2020000263 W CN2020000263 W CN 2020000263W WO 2021082279 A1 WO2021082279 A1 WO 2021082279A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- based mud
- drilling water
- drying agent
- drilling
- water
- Prior art date
Links
- 238000005553 drilling Methods 0.000 title claims abstract description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 239000002274 desiccant Substances 0.000 title claims abstract description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 18
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000292 calcium oxide Substances 0.000 claims abstract description 17
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 16
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 15
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 15
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 15
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 15
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 15
- 235000012255 calcium oxide Nutrition 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 229920000768 polyamine Polymers 0.000 claims description 4
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 claims 1
- 235000019402 calcium peroxide Nutrition 0.000 claims 1
- 238000003672 processing method Methods 0.000 claims 1
- XUIMIQQOPSSXEZ-IGMARMGPSA-N silicon-28 atom Chemical compound [28Si] XUIMIQQOPSSXEZ-IGMARMGPSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 8
- 238000002386 leaching Methods 0.000 abstract description 7
- 239000002910 solid waste Substances 0.000 abstract description 7
- 238000012360 testing method Methods 0.000 abstract description 5
- 239000002699 waste material Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000002351 wastewater Substances 0.000 abstract description 3
- 238000010276 construction Methods 0.000 abstract description 2
- 239000007790 solid phase Substances 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 6
- 230000008569 process Effects 0.000 description 4
- 239000010865 sewage Substances 0.000 description 4
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
- C02F11/148—Combined use of inorganic and organic substances, being added in the same treatment step
Definitions
- the embodiment of the present invention relates to the technical field of drilling waste fluid treatment, in particular to a drilling water-based mud drying agent.
- Drilling water-based mud is one of the main wastes. It is mainly a multi-phase stable colloidal suspension system containing clay, various chemical treatment agents, sewage, slop oil and drill cuttings, and contains certain heavy metals such as mercury and copper. , Arsenic, chromium, zinc, lead and barite, etc.
- water-based drilling mud is generally processed by filter press or other methods to separate the solid and liquid.
- the separated liquid needs to be treated twice to meet the discharge standard. This method has the disadvantages of complex technology and high cost.
- the embodiment of the present invention provides a drilling water-based mud drying agent.
- the drilling water-based mud drying agent is used to treat drilling water-based mud and has the advantages of simple process and low cost, so as to solve the complex process of the existing method. , High-cost defects.
- the embodiments of the present invention provide a drilling water-based mud drying agent
- the drilling water-based mud drying agent includes polyaluminum chloride, calcium oxide, silicon dioxide, carboxymethyl Base cellulose, curing agent.
- polyaluminum chloride is a cationic inorganic polymer flocculant with polyhydroxy and polynuclear complexes.
- Polyaluminum chloride undergoes hydrolysis under the action of water, and is accompanied by a series of aggregation, adsorption, precipitation, etc. Physical and chemical processes can effectively remove heavy metal ions contained in sewage.
- calcium oxide is alkaline and is used to adjust the pH. It can also remove heavy metal ions in the sewage to generate incompatible hydroxides.
- silica is used as the core of flocculation.
- carboxymethyl cellulose is a carboxymethyl group substitution product of cellulose. When used in sewage treatment, it has good adsorption and removal performance for heavy metal ions.
- the curing agent can accelerate the drying of the drilling water-based mud.
- the drilling water-based mud drying agent includes polyaluminum chloride 20-35%, calcium oxide 20-35%, silicon dioxide 25-35%, carboxymethyl cellulose 10 -25%, curing agent 10-20%.
- the curing agent includes an aliphatic polyamine.
- the aliphatic polyamine includes aliphatic polyamines such as diethylenetriamine, triethylenetetramine, and tetraethylenepentamine.
- the drilling water-based mud drying agent includes 25% polyaluminum chloride, 25% calcium oxide, 28% silicon dioxide, 12% carboxymethyl cellulose, and 10% curing agent. .
- the preparation method of the drilling water-based mud drying agent includes the following steps: mixing polyaluminum chloride, calcium oxide, silicon dioxide, carboxymethyl cellulose and curing agent.
- the embodiments of the present invention provide a method for processing water-based drilling mud.
- the method includes the following steps: adding the above-mentioned drying agent for drilling water-based mud to the water-based drilling mud; Stir and let it stand.
- the added amount of the drilling water-based mud drying agent is 5-10% of the weight of the drilling water-based mud.
- the drilling water-based mud drying agent of the present invention includes polyaluminum chloride, calcium oxide, silicon dioxide, carboxymethyl cellulose, and curing agent.
- polyaluminum chloride When added to the drilling water-based mud, a series of complex problems can occur with the mud. Physical and chemical reactions make the harmful components in the mud, such as heavy metals, polymers and oils, enclosed in it, thereby reducing its fluid loss and preventing heavy metals and polymers from spreading to the environment.
- the solid waste leachate of the drilling water-based mud meets the discharge standard of the maximum allowable discharge concentration standard limit in Table 1 of the "Integrated Wastewater Discharge Standard" GB8978-1996.
- the invention rapidly dries the drilling water-based mud into a solid phase by adding a desiccant, without the liquid part, omits the treatment of the liquid part, and has the advantages of simple and fast construction, good treatment effect, low environmental impact and the like.
- the drilling water-based mud drying agent of this embodiment by weight percentage, includes polyaluminum chloride 22%, calcium oxide 20%, silicon dioxide 35%, carboxymethyl cellulose 11%, and curing agent 12% .
- the curing agent is diethylene triamine.
- the preparation method of the above-mentioned drilling water-based mud drying agent includes the following steps:
- Example 2-5 The preparation method of Example 2-5 is the same as that of Example 1.
- the drilling water-based mud drying agent of this embodiment includes polyaluminum chloride 25%, calcium oxide 25%, silicon dioxide 28%, carboxymethyl cellulose 12%, and curing agent 10% .
- the curing agent is triethylenetetramine.
- the drilling water-based mud drying agent of this embodiment includes 30% polyaluminum chloride, 23% calcium oxide, 26% silicon dioxide, 10% carboxymethyl cellulose, and 11% curing agent in terms of weight percentage. .
- the curing agent is diethylene triamine.
- the drilling water-based mud drying agent of this embodiment includes 23% polyaluminum chloride, 28% calcium oxide, 26% silicon dioxide, 13% carboxymethyl cellulose, and 10% curing agent in terms of weight percentage. .
- the curing agent is tetraethylenepentamine.
- the drilling water-based mud drying agent of this embodiment includes 28% polyaluminum chloride, 20% calcium oxide, 25% silicon dioxide, 14% carboxymethyl cellulose, and 13% curing agent in terms of weight percentage. .
- the curing agent is tetraethylenepentamine.
- Preparation of leaching solution simulating natural processes, using pure water as the leaching agent to extract harmful substances, specifically, using the HJ557-2010 solid waste leaching toxicity leaching method (horizontal shaking method) to obtain the leaching solution.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Treatment Of Sludge (AREA)
Abstract
Description
Claims (8)
- 一种钻井水基泥浆干化剂,其特征在于,所述钻井水基泥浆干化剂包括聚合氯化铝、氧化钙、二氧化硅、羧甲基纤维素、固化剂。
- 根据权利要求1所述的钻井水基泥浆干化剂,其特征在于,按重量百分含量计,所述钻井水基泥浆干化剂包括聚合氯化铝20-35%、氧化钙20-35%、二氧化硅25-35%、羧甲基纤维素10-25%、固化剂10-20%。
- 根据权利要求1所述的钻井水基泥浆干化剂,其特征在于,按重量百分含量计,所述钻井水基泥浆干化剂包括聚合氯化铝25%、氧化钙25%、二氧化硅28%、羧甲基纤维素12%、固化剂10%。
- 根据权利要求1所述的钻井水基泥浆干化剂,其特征在于,所述固化剂为脂肪族多胺。
- 根据权利要求1所述的钻井水基泥浆干化剂,其特征在于,所述钻井水基泥浆干化剂的制备方法包括以下步骤:将聚合氯化铝、氧化钙、二氧化硅、羧甲基纤维素和固化剂混匀即可。
- 一种钻井水基泥浆的处理方法,其特征在于,所述方法包括以下步骤:向钻井水基泥浆中添加如权利要求1所述的钻井水基泥浆干化剂,搅拌,静置即可。
- 根据权利要求6所述的钻井水基泥浆的处理方法,其特征在于,所述钻井水基泥浆干化剂的添加量为钻井水基泥浆重量的5-10%。
- 根据权利要求6所述的钻井水基泥浆的处理方法,其特征在于,静置36~48小时。
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CN201911061366.9 | 2019-11-01 | ||
CN201911061366.9A CN110903016A (zh) | 2019-11-01 | 2019-11-01 | 一种钻井水基泥浆干化剂 |
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PCT/CN2020/000263 WO2021082279A1 (zh) | 2019-11-01 | 2020-10-30 | 一种钻井水基泥浆干化剂 |
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WO (1) | WO2021082279A1 (zh) |
Families Citing this family (1)
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CN110903016A (zh) * | 2019-11-01 | 2020-03-24 | 四川格英达环保科技有限公司 | 一种钻井水基泥浆干化剂 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1597579A (zh) * | 2004-08-04 | 2005-03-23 | 胜利油田华胜环保产业有限责任公司 | 钻井废弃泥浆无害化处理剂及废弃泥浆处理工艺 |
CN103524015A (zh) * | 2013-10-22 | 2014-01-22 | 秦广山 | 一种泥浆固化剂及其制备方法 |
CN105107824A (zh) * | 2015-09-10 | 2015-12-02 | 北京融达建业建筑工程技术有限公司 | 一种油气田钻井废弃物无害化处理方法 |
CN105907383A (zh) * | 2016-05-11 | 2016-08-31 | 西南石油大学 | 一种水基钻井废水处理后再配制钻井液的方法 |
WO2016167751A1 (en) * | 2015-04-14 | 2016-10-20 | Halliburton Energy Services, Inc. | Methods of cleaning invert emulsion drilling fluids |
CN109705827A (zh) * | 2017-10-25 | 2019-05-03 | 中国石油化工股份有限公司 | 石油钻井用堵漏承压剂及其制备方法 |
CN110903016A (zh) * | 2019-11-01 | 2020-03-24 | 四川格英达环保科技有限公司 | 一种钻井水基泥浆干化剂 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7503143B2 (en) * | 2002-10-15 | 2009-03-17 | Encap Llc. | PAM carrier |
CN100471585C (zh) * | 2006-07-03 | 2009-03-25 | 张明罡 | 石油钻井废弃泥浆固化剂及其使用方法 |
CN102485666A (zh) * | 2010-12-02 | 2012-06-06 | 陕西昊鼎德鑫环保科技有限公司 | 废弃钻井泥浆原位无害化处理工艺方法 |
CN102815851A (zh) * | 2012-08-07 | 2012-12-12 | 上海交大辛德环保有限公司 | 一种深度污泥干化调理***及方法 |
CN104297101B (zh) * | 2014-09-26 | 2017-01-25 | 承德石油高等专科学校 | 钻井用泥浆密度测量仪及其制备方法 |
CN104529283B (zh) * | 2014-12-15 | 2016-08-24 | 上海三瑞高分子材料有限公司 | 一种油田废弃钻井泥浆固化材料 |
CN105347761A (zh) * | 2015-10-26 | 2016-02-24 | 中国建筑材料科学研究总院 | 一种快速防腐修补砂浆及其制备方法与应用 |
CN105754495B (zh) * | 2016-03-16 | 2019-04-23 | 江苏文昌新材料科技有限公司 | 高强度桥面防水粘结剂及其制备方法 |
CN106348569A (zh) * | 2016-10-18 | 2017-01-25 | 四川铁科新型建材有限公司 | 一种低掺量泥浆固化剂组合物及其制备方法、应用方法 |
CN106630536A (zh) * | 2016-12-30 | 2017-05-10 | 李沛然 | 一种钻井废弃物干化剂及其使用方法 |
CN106630545B (zh) * | 2017-02-06 | 2020-02-21 | 天津市环境保护技术开发中心设计所 | 含油污泥的干化处理方法 |
CN108623233B (zh) * | 2018-05-23 | 2021-11-12 | 成都恩承科技股份有限公司 | 一种用于磺化钻井岩屑处理的固化剂及其应用 |
CN108997713B (zh) * | 2018-06-28 | 2020-12-11 | 广州均实复合材料科技有限公司 | 一种耐压透水性多孔材料及其制备方法 |
CN109293052A (zh) * | 2018-10-23 | 2019-02-01 | 天津大港油田滨港集团博弘石油化工有限公司 | 一种水基废弃钻井液破胶体系及其制备方法 |
CN109574597A (zh) * | 2019-01-21 | 2019-04-05 | 广西利赛科资源综合利用科技有限公司 | 一种用于固化/稳定化含重金属固体废物的塑性混凝土及其制备方法 |
CN110003864A (zh) * | 2019-04-03 | 2019-07-12 | 新疆格瑞迪斯石油技术股份有限公司 | 一种钻井液内堵漏封堵剂及其制备方法 |
-
2019
- 2019-11-01 CN CN201911061366.9A patent/CN110903016A/zh active Pending
-
2020
- 2020-10-30 WO PCT/CN2020/000263 patent/WO2021082279A1/zh active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1597579A (zh) * | 2004-08-04 | 2005-03-23 | 胜利油田华胜环保产业有限责任公司 | 钻井废弃泥浆无害化处理剂及废弃泥浆处理工艺 |
CN103524015A (zh) * | 2013-10-22 | 2014-01-22 | 秦广山 | 一种泥浆固化剂及其制备方法 |
WO2016167751A1 (en) * | 2015-04-14 | 2016-10-20 | Halliburton Energy Services, Inc. | Methods of cleaning invert emulsion drilling fluids |
CN105107824A (zh) * | 2015-09-10 | 2015-12-02 | 北京融达建业建筑工程技术有限公司 | 一种油气田钻井废弃物无害化处理方法 |
CN105907383A (zh) * | 2016-05-11 | 2016-08-31 | 西南石油大学 | 一种水基钻井废水处理后再配制钻井液的方法 |
CN109705827A (zh) * | 2017-10-25 | 2019-05-03 | 中国石油化工股份有限公司 | 石油钻井用堵漏承压剂及其制备方法 |
CN110903016A (zh) * | 2019-11-01 | 2020-03-24 | 四川格英达环保科技有限公司 | 一种钻井水基泥浆干化剂 |
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