WO2020251573A1 - Composition and method for preparing corrosion resistant multifunctional coatings - Google Patents
Composition and method for preparing corrosion resistant multifunctional coatings Download PDFInfo
- Publication number
- WO2020251573A1 WO2020251573A1 PCT/US2019/036858 US2019036858W WO2020251573A1 WO 2020251573 A1 WO2020251573 A1 WO 2020251573A1 US 2019036858 W US2019036858 W US 2019036858W WO 2020251573 A1 WO2020251573 A1 WO 2020251573A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coating
- corrosion
- oleo
- applicator
- nickel
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 121
- 238000005260 corrosion Methods 0.000 title claims abstract description 71
- 230000007797 corrosion Effects 0.000 title claims abstract description 71
- 238000000034 method Methods 0.000 title claims description 33
- 239000000203 mixture Substances 0.000 title description 11
- 239000011248 coating agent Substances 0.000 claims abstract description 100
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 44
- 239000000956 alloy Substances 0.000 claims abstract description 44
- 239000002131 composite material Substances 0.000 claims abstract description 43
- 238000004140 cleaning Methods 0.000 claims abstract description 7
- 239000002105 nanoparticle Substances 0.000 claims description 38
- 229910052751 metal Inorganic materials 0.000 claims description 25
- 239000002184 metal Substances 0.000 claims description 25
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- -1 nickel-phosphorous Chemical compound 0.000 claims description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 14
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- 238000007747 plating Methods 0.000 claims description 12
- 239000004593 Epoxy Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 238000009713 electroplating Methods 0.000 claims description 9
- 239000011159 matrix material Substances 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000919 ceramic Substances 0.000 claims description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 150000001412 amines Chemical group 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 238000005530 etching Methods 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 238000007772 electroless plating Methods 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- CPRNWMZKNOIIML-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctylphosphonic acid Chemical compound OP(O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CPRNWMZKNOIIML-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims description 4
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- QDWJUBJKEHXSMT-UHFFFAOYSA-N boranylidynenickel Chemical compound [Ni]#B QDWJUBJKEHXSMT-UHFFFAOYSA-N 0.000 claims description 4
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 4
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 229920002313 fluoropolymer Polymers 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- FPLYNRPOIZEADP-UHFFFAOYSA-N octylsilane Chemical compound CCCCCCCC[SiH3] FPLYNRPOIZEADP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- 150000004756 silanes Chemical class 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 229940035339 tri-chlor Drugs 0.000 claims description 4
- AVXLXFZNRNUCRP-UHFFFAOYSA-N trichloro(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)silane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)[Si](Cl)(Cl)Cl AVXLXFZNRNUCRP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000758 substrate Substances 0.000 abstract description 14
- 230000002209 hydrophobic effect Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 20
- 239000003792 electrolyte Substances 0.000 description 16
- 239000007784 solid electrolyte Substances 0.000 description 16
- 239000007787 solid Substances 0.000 description 11
- 239000010959 steel Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- 125000000524 functional group Chemical group 0.000 description 8
- 239000002243 precursor Substances 0.000 description 7
- 239000002609 medium Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 5
- 235000009508 confectionery Nutrition 0.000 description 5
- 238000010276 construction Methods 0.000 description 4
- 239000006181 electrochemical material Substances 0.000 description 4
- 229920005596 polymer binder Polymers 0.000 description 4
- 239000002491 polymer binding agent Substances 0.000 description 4
- 238000005422 blasting Methods 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000005553 drilling Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- VNZQQAVATKSIBR-UHFFFAOYSA-L copper;octanoate Chemical compound [Cu+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O VNZQQAVATKSIBR-UHFFFAOYSA-L 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005363 electrowinning Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 229910021555 Chromium Chloride Inorganic materials 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- 238000007743 anodising Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000000010 aprotic solvent Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000002355 dual-layer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000000866 electrolytic etching Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 229910021652 non-ferrous alloy Inorganic materials 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- XCZXGTMEAKBVPV-UHFFFAOYSA-N trimethylgallium Chemical compound C[Ga](C)C XCZXGTMEAKBVPV-UHFFFAOYSA-N 0.000 description 1
- IBEFSUTVZWZJEL-UHFFFAOYSA-N trimethylindium Chemical compound C[In](C)C IBEFSUTVZWZJEL-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1689—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/04—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F17/00—Multi-step processes for surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by subclass C21D or C22F or class C25
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/04—Electroplating with moving electrodes
- C25D5/06—Brush or pad plating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
- C09K2208/20—Hydrogen sulfide elimination
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
- C09K2208/32—Anticorrosion additives
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/38—Electroplating: Baths therefor from solutions of copper
Definitions
- the application relates generally to surface treatments and coatings to prevent scale build up and H2S and C02-induced corrosion and provide sweet gas and sour gas resistance and water/oil repellency.
- Sour gas is any gas, but often natural gas, containing significant amounts of ThS.
- ThS ThS
- Corrosion resistant alloy coatings are difficult to apply on the interior of pipelines and in inaccessible areas and the process is not scalable.
- Existing corrosion resistant coating technology lacks EbS and CO2 corrosion resistance.
- Most of the commercial solutions are based on a polymer or composite coating to prevent corrosion and H2S/CO2 attack but they provide minimal protection once the coating is damaged.
- the use of polymer-based coatings only provides a temporary resistance to these gases which is not maintained at high pressure and temperature.
- a novel corrosion resistant coating can sustain corrosion-resistance in high temperature, high pressure, corrosive, sweet or sour gas environments.
- the high-water repellency also assists in improving scale resistance and other beneficial results.
- This coating may include a base metallic corrosion resistant layer containing nickel, chromium, cobalt and/or any other corrosion resistant alloys and a top layer of polymer composite coating capable of providing a low surface energy to reduce drag in multiphase flow regimes.
- the coating is useful for oil and gas drilling and exploration, as well as for marine, aviation, automobile, electronics, domestic, construction, and transportation applications, etc.
- Benefits of the new coating include durable corrosion resistance for metal surfaces, easy application on intricate components and hard-to-reach areas, especially in pipeline, pump, and valve interiors, improved ThS and CO2 resistance, and durable performance at high pressure and high temperature.
- the coating involves a thin layer of corrosion resistant alloy coating applied to the surface using, for example, electroless, brush plating or electroplating approaches, followed by application of a composite coating of nanoparticle-embedded perfluorinated polymer that is resistant to water/oil and impermeable/inert to sweet and sour gases.
- corrosion resistant alloy coating is described in detail later.
- the top coating of the new multifunctional coating is omniphobic and may consist of fluorinated nanoparticles (such as fluorinated silica nanoparticles) in a known commercial polymer.
- Functional groups such as hydroxyl, epoxy, acrylic, amines etc may be applied to the corrosion-resistant alloy before application of the top coating to improve durability.
- Each layer has its own function- the inner, first alloy coating prevents sour gas attack, while the top composite layer functions as an oil and water repellant.
- the top layer can break down at high temperatures and pressures, leaving the surface below it exposed to the
- the multifunctional coating provides simple, scalable dual layer surface protection of H2S resistance and water and oil repellency.
- the corrosion resistant alloy layer may be used alone with sufficient strength to provide substantial corrosion protection.
- a new multifunctional coating method in embodiments includes the steps of cleaning a surface, applying a layer of corrosion-resistant alloy coating to the surface, and applying an oleo- hydrophobic composite coating over the corrosion-resistant alloy coating. In some embodiments the method also includes modifying and functionalizing the layer of corrosion-resistant alloy coating by chemical and/or electrochemical etching and attachment of functional groups, prior to application of the oleo-hydrophobic composite coating.
- the functional groups in various embodiments are hydroxyl, epoxy, acrylic, or amine functional groups.
- the surface cleaning in various embodiments includes shot blasting and/or acid/base washing.
- the corrosion-resistant alloy in various embodiments is applied by at least one of electroless plating, brush plating, and electroplating.
- the oleo-hydrophobic composite coating in some embodiments includes corrosion- resistant nanoparticles embedded in perfluorinated and/or fluorinated polymer.
- the surface in some embodiments is a metal surface, and in some embodiments part of a heat exchanger. In some embodiments the heat exchanger is located in a power plant.
- the corrosion-resistant alloy in some embodiments includes at least one of nickel, nickel- phosphorous, nickel-cobalt, nickel-boron, nickel-PTFE, and chromium.
- the oleo-hydrophobic composite coating in some embodiments includes ceramic nanoparticles embedded in a coating matrix.
- the ceramic nanoparticles in some embodiments include at least one of silica, alumina, titania, and ceria nanoparticles.
- nanoparticles in some embodiments are functionalized by attaching at least one of perfluoro octyl trichloro silane, perfluoro octyl phosphonic acid, perfluoro polyhedral oligomeric silsesquioxanes (POSS), trichloro octa decyl, trichlor octyl silane, perfluorosiloxane,
- PES perfluoro polyhedral oligomeric silsesquioxanes
- fluorohydrocarbon fluorinated silane, fluorinated acid, amine, phosphoric acid, alcohol, acrylates, epoxy, ester, ethers, sulfonate, and/or fluorinated or non-fluorinated monomers.
- the oleo-hydrophobic composite coating in some embodiments includes metallic nanoparticles embedded in the coating matrix.
- the metallic nanoparticles in some embodiments include at least one of nickel, copper, and iron nanoparticles.
- the oleo-hydrophobic composite coating in some embodiments includes perfluorinated polymers.
- a new applicator for applying a multifunctional coating to a metal surface applies the multifunctional coating according to a method involving cleaning a surface, applying a layer of corrosion-resistant alloy coating to the surface, and applying an oleo-hydrophobic composite coating over the corrosion-resistant alloy coating.
- the applicator contains the oleo-hydrophobic composite coating.
- the oleo-hydrophobic composite coating in some embodiments includes metallic nanoparticles embedded in a coating matrix.
- the method also includes modifying and functionalizing the layer of corrosion-resistant alloy coating by chemical and/or electrochemical etching and attachment of functional groups, prior to application of the oleo-hydrophobic composite coating.
- the functional groups in various embodiments are hydroxyl, epoxy, acrylic, or amine functional groups.
- the surface cleaning in various embodiments includes shot blasting and/or acid/base washing.
- the corrosion-resistant alloy in various embodiments is applied by at least one of electroless plating, brush plating, and electroplating.
- the oleo-hydrophobic composite coating in some embodiments includes corrosion-resistant nanoparticles embedded in perfluorinated and/or fluorinated polymer.
- the surface in some embodiments is a metal surface, and in some embodiments part of a heat exchanger. In some embodiments the heat exchanger is located in a power plant.
- the corrosion- resistant alloy in some embodiments includes at least one of nickel, nickel-phosphorous, nickel- cobalt, nickel -boron, nickel -PTFE, and chromium.
- the oleo-hydrophobic composite coating in some embodiments includes ceramic nanoparticles embedded in a coating matrix.
- the ceramic nanoparticles in some embodiments include at least one of silica, alumina, titania, and ceria nanoparticles.
- nanoparticles in some embodiments are functionalized by attaching at least one of perfluoro octyl trichloro silane, perfluoro octyl phosphonic acid, perfluoro polyhedral oligomeric silsesquioxanes (POSS), trichloro octa decyl, trichlor octyl silane, perfluorosiloxane,
- PES perfluoro polyhedral oligomeric silsesquioxanes
- fluorohydrocarbon fluorinated silane, fluorinated acid, amine, phosphoric acid, alcohol, acrylates, epoxy, ester, ethers, sulfonate, and/or fluorinated or non-fluorinated monomers.
- the oleo-hydrophobic composite coating in some embodiments includes metallic nanoparticles embedded in the coating matrix.
- the metallic nanoparticles in some embodiments include at least one of nickel, copper, and iron nanoparticles.
- the oleo-hydrophobic composite coating in some embodiments includes perfluorinated polymers.
- the applicator contains the corrosion-resistant alloy coating.
- a new or existing oil and gas pipe has an inner surface with a multifunctional coating applied to the inside surface, which includes an inner oleo-hydrophobic composite coating, beneath the inner oleo-hydrophobic composite coating a corrosion-resistant alloy coating, and beneath the corrosion-resistant alloy coating untreated pipe material.
- Multifunctional corrosion resistant coatings can also be applied to metallic surfaces (e.g. aluminum, copper, and/or chromium-based alloys) other than steel or stainless-steel alloys.
- metallic surfaces e.g. aluminum, copper, and/or chromium-based alloys
- FIG. l is a flowchart of a corrosion resistant multifunctional coating process, in an embodiment.
- FIGS. 2A-2E are schematics illustrating the changes occurring on a metal surface during a corrosion resistant multifunctional coating process, in an embodiment.
- FIG. 2F is a detail view of area A of FIG. 2E.
- FIG. 3 A-F are schematics illustrating the changes occurring on a metal surface during a corrosion resistant multifunctional coating process, in another embodiment.
- FIG. 3G is a detail view of area B of FIG. 3F.
- FIGS. 4A-C are a series of images showing a steel sample undergoing a corrosion resistant multifunctional coating process, in an embodiment.
- FIGS. 5 A-5B illustrate a method of applying a corrosion resistant alloy coating.
- FIG. l is a flowchart of a corrosion resistant multifunctional coating process, in an embodiment.
- the surface to be coated is cleaned 100, for example by shot blasting, acid/base washing, and/or other known techniques.
- a corrosion-resistant alloy coating is applied 102, for example using a technique such as electroless plating, brush plating,
- the corrosion-resistant alloy coating is modified and functionalized 104 using chemical and/or electrochemical etching and functional group attachment.
- a multifunctional oil/water repellant polymer composite coating is applied 106, for example corrosion-resistant nanoparticles embedded in perfluorinated polymer.
- FIGS. 2A-F are schematics illustrating the changes occurring on a metal surface 200 during a corrosion resistant multifunctional coating process, in an embodiment.
- a metal surface 200 as shown I FIG. 2A
- first that surface is cleaned 201, leaving a clean top surface 202 of the metal as shown in FIG. 2B for application of the coating.
- the corrosion resistant alloy is deposited 203 onto the clean top surface, resulting in a metal surface having a top layer of corrosion-resistant alloy 204 as shown in FIG. 2C.
- a multifunctional composite oleo-hydrophobic coating 206 is applied 207 to the corrosion-resistant alloy layer, forming the final top layer on the surface as shown in FIG. 2D.
- the final surface comprises a bottom layer of unchanged metal 200, a middle layer of corrosion-resistant alloy coating 204, and a top layer of multifunctional composite oleo-hydrophobic coating 206 as shown in FIG. 2E and detail FIG.
- FIGS. 3 A-G are schematics illustrating the changes occurring on a metal surface 200 during a corrosion resistant multifunctional coating process, in an embodiment. This schematic is similar to FIGS. 2A-F, but with the addition of a functional group attachment step shown in FIG. 3D, in which functional groups 205 are attached to the corrosion-resistant alloy as a nanoparticle coating prior to application of the multifunctional composite oleo-hydrophobic coating 206 as shown in FIG. 3E for enhanced adhesion and durability.
- FIGS. 4A-C are a series of images showing a steel sample undergoing a corrosion resistant multifunctional coating process, in an embodiment. First FIG. 4A shows a bare steel sample 400 two inches in width. Next, FIG.
- FIG. 4B shows the steel after an electroless nickel deposition has been performed on it, giving it a top layer of corrosion-resistant nickel alloy 402.
- FIG. 4C shows the steel sample with a top layer of corrosion-resistant composite coating 404 after a multifunctional composite oleo-hydrophobic coating has been applied.
- the coatings described herein may be applied to various metal surfaces in industrial environments, including, but not limited to, geometrically complex surfaces located in inaccessible or hard-to-reach areas. Such surfaces include, purely as a non limiting example, the interior and exterior surfaces of heat exchangers inside power plants. It should further be appreciated that one or more methods may be used to apply the coatings that embody the invention to a given surface, such as, for example, spraying, brushing, and the like.
- One good method of applying the corrosion resistant alloy coating is a brush plating process that involves packaging ionic and/or nonionic electrolytes, such as a copper
- electroplating solution in moldable solid form, eliminating the need for electrolyte recirculation or dipping of the brush plating wand in the electrolyte solution.
- electrolyte in a solid form, there is no need for liquid electrolytes to be used in the brush plating process. Water is sprayed on to the electrode to maintain conductivity.
- a solid electrolyte having precursor, binder and medium in solid or semisolid form and a tool having the product combined in an electrode/electrolyte assembly for electrochemical treatment of a substrate may be used.
- the solid electrolyte may include metal salts,
- the binder may include polymers polyethylene oxide, polyvinyl pyrolidone, silicones, inorganic binders, silicate, and surfactants or cetyltrimethyl ammonium bromide.
- the medium may include aqueous or non-aqueous solvent, ionic liquid or aprotic solvent.
- the solid electrolyte is a moldable or conformable solid or semisolid in moldable form.
- the electrode may be a conducting metallic or nonmetallic wire, rods, tube foil, plate, sheet, foam or mesh and further has a DC power connection to the electrode. A handle is connected to the electrode. A DC power connection also is connected to the substrate.
- the solid electrolyte material is an electroplating, electropolishing, electrowinning, electroetching or anodizing electrochemical, and the electrochemical treatment includes electroplating, electropolishing, electrowinning, electrochemical etching or anodization.
- the invention provides an ionic or nonionic electrolyte in a moldable solid or semisolid form.
- the ionic or nonionic electrolyte is a mixture of precursor, binder and medium.
- the solid electrode is formed with a mixture of electrochemical material and binder.
- the solid electrolyte may be attached to an electrode, a DC connector applied to the electrode and a handle provided on the electrode. A DC connector is applied to a substrate and the substrate is wetted with solvent. Holding the electrode and solid electrolyte with the handle and moving the solid electrolyte in contact with the wetted surface of the substrate completes the process.
- the wetting may involve spraying a solvent mist on the substrate.
- the precursor may be a metal salt, copper chloride, chromium chloride, nickel sulfate, organic compounds, pyridine, pyrrole, aniline, organometallic compounds, trimethylgallium, trimethylindium or trimethylaluminum, as examples.
- the solid electrolyte precursor and the precursors are transferred from the solid electrolyte to a surface of the substrate by using the handle to move the solid electrolyte over the surface of the substrate when the surface or the electrolyte is slightly wetted with solvent.
- a solid electrolyte containing high concentration of metal may be used which can release metal ions upon rubbing and applying electrical potential between electrode and the substrate only when the electrolyte is sufficiently hydrated. It is possible to store sufficient quantities of metal ions in the form of electrolyte and to deliver them to the necessary location as desired during the plating process.
- the solid electrolyte can be attached to the existing wand and can be covered with the cloth and brush plating, which can be performed similar to existing practices.
- Figs 5A and 5B commercial copper surfactant solution containing nearly 10wt% of copper octanoate is used without any purification.
- a known amount of a polymer binder polyethylene oxide
- copper octanoate solution in water for 30 minutes.
- the homogenized solution is poured in to plastic 2"x2"x2" cube molds and dried in a vacuum oven at 80°C for two days.
- the fabricated solid copper electrolyte polymer 1 is used for brush plating copper on steel coupons 3.
- a DC potential is applied between the steel plate 3 and a copper wand, i.e., brushing electrode 4 covered with the solid copper electrolyte 1 as shown in FIGS. 5A and 5B.
- the copper electrolyte 1 is hydrated occasionally with few drops (l-2mL) of water to maintain electrical conductivity. Alternatively, a mist of water is sprayed on the substrate. Copper is deposited on the steel plate 3 by brushing the copper electrolyte 1 over the steel plate 3.
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Abstract
Description
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Priority Applications (4)
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EP19933017.6A EP3983579A4 (en) | 2019-06-12 | 2019-06-12 | Composition and method for preparing corrosion resistant multifunctional coatings |
PCT/US2019/036858 WO2020251573A1 (en) | 2019-06-12 | 2019-06-12 | Composition and method for preparing corrosion resistant multifunctional coatings |
KR1020227000092A KR20220020330A (en) | 2019-06-12 | 2019-06-12 | Composition and manufacturing method of corrosion-resistant multifunctional paint |
JP2021573340A JP7457039B2 (en) | 2019-06-12 | 2019-06-12 | Method of applying multifunctional coatings to metal surfaces and applicators for applying multifunctional coatings to metal surfaces |
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PCT/US2019/036858 WO2020251573A1 (en) | 2019-06-12 | 2019-06-12 | Composition and method for preparing corrosion resistant multifunctional coatings |
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JP (1) | JP7457039B2 (en) |
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CN113416990A (en) * | 2021-08-23 | 2021-09-21 | 胜利油田胜鑫防腐有限责任公司 | Preparation process of metal coating anti-corrosion pipe |
CN115012008A (en) * | 2022-03-31 | 2022-09-06 | 九牧厨卫股份有限公司 | Environment-friendly composite coating layer capable of improving adhesive force and preparation method thereof |
US11835307B2 (en) | 2019-04-12 | 2023-12-05 | Rheem Manufacturing Company | Applying coatings to the interior surfaces of heat exchangers |
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EP3983579A1 (en) | 2022-04-20 |
EP3983579A4 (en) | 2023-04-05 |
JP7457039B2 (en) | 2024-03-27 |
JP2022541375A (en) | 2022-09-26 |
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