WO2020245251A3 - Multilayer polyproplyene film - Google Patents

Multilayer polyproplyene film Download PDF

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Publication number
WO2020245251A3
WO2020245251A3 PCT/EP2020/065445 EP2020065445W WO2020245251A3 WO 2020245251 A3 WO2020245251 A3 WO 2020245251A3 EP 2020065445 W EP2020065445 W EP 2020065445W WO 2020245251 A3 WO2020245251 A3 WO 2020245251A3
Authority
WO
WIPO (PCT)
Prior art keywords
content
ethylene
multilayer
film
multilayer film
Prior art date
Application number
PCT/EP2020/065445
Other languages
French (fr)
Other versions
WO2020245251A2 (en
Inventor
Jingbo Wang
Markus Gahleitner
Klaus Bernreitner
Pauli Leskinen
Manfred Gruenberger
Original Assignee
Borealis Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Ag filed Critical Borealis Ag
Priority to EP20729757.3A priority Critical patent/EP3980473A2/en
Priority to US17/595,840 priority patent/US11752743B2/en
Priority to CN202080039583.2A priority patent/CN113924211B/en
Publication of WO2020245251A2 publication Critical patent/WO2020245251A2/en
Publication of WO2020245251A3 publication Critical patent/WO2020245251A3/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • C08L23/142Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • B32B2250/246All polymers belonging to those covered by groups B32B27/32 and B32B27/30
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00Resin or rubber layer containing a blend of at least two different polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2274/00Thermoplastic elastomer material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/02Open containers
    • B32B2439/06Bags, sacks, sachets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/40Closed containers
    • B32B2439/46Bags
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/80Medical packaging
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/07Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/02Heterophasic composition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

Multilayer film comprising at least a skin layer, a core layer and an inner layer,whereby the inner layer comprises a single site catalyst derived (SSC) random propylene ethylene copolymer having - a melting temperature (Tm) from 120°C to 144°C, - a content of units derived from ethylene in an amount of 1.5 to 6.0 wt.-%, - the melting temperature (Tm) fulfilling the following equation Tm < 156 °C – [5.2 x C2 content in wt.-%] °C wherein C2 content stands for the content of units derived from ethylene; and - a xylene cold soluble content (ISO 16152, 1st ED, 2005-07-01; 25°C) of preferably below 30 wt.-% wherein the multilayer film is free of phthalic acid esters as well as decomposition products thereof.
PCT/EP2020/065445 2019-06-05 2020-06-04 Multilayer polyproplyene film WO2020245251A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP20729757.3A EP3980473A2 (en) 2019-06-05 2020-06-04 Multilayer polyproplyene film
US17/595,840 US11752743B2 (en) 2019-06-05 2020-06-04 Multilayer polypropylene film
CN202080039583.2A CN113924211B (en) 2019-06-05 2020-06-04 Multilayer polypropylene film

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP19178413 2019-06-05
EP19178413.1 2019-06-05

Publications (2)

Publication Number Publication Date
WO2020245251A2 WO2020245251A2 (en) 2020-12-10
WO2020245251A3 true WO2020245251A3 (en) 2021-01-14

Family

ID=66770338

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2020/065445 WO2020245251A2 (en) 2019-06-05 2020-06-04 Multilayer polyproplyene film

Country Status (4)

Country Link
US (1) US11752743B2 (en)
EP (1) EP3980473A2 (en)
CN (1) CN113924211B (en)
WO (1) WO2020245251A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3826844B1 (en) 2018-07-23 2022-12-21 Borealis AG Multilayer polypropylene film
EP4141068B1 (en) 2021-08-31 2024-05-29 Borealis AG A homopolymer-random copolymer blend having a beneficial balance of optical and mechanical properties
WO2023247227A1 (en) * 2022-06-20 2023-12-28 Basell Poliolefine Italia S.R.L. Multilayer film
WO2024102116A1 (en) * 2022-11-08 2024-05-16 Amcor Flexibles North America, Inc. Polypropylene blends for thermoforming

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001042009A1 (en) * 1999-12-11 2001-06-14 Fresenius Kabi Deutschland Gmbh Autoclavable pvc-free multilayer film to be especially used for packing liquid, medicinal products, method for producing the same and the use thereof
JP2007245490A (en) * 2006-03-15 2007-09-27 Intermedic Co Ltd Multilayer film and soft bag for medical treatment
WO2013144061A1 (en) * 2012-03-29 2013-10-03 Borealis Ag Unoriented film based on soft polypropylene
DE202013103803U1 (en) * 2013-08-22 2014-11-24 Kobusch-Sengewald Gmbh Multilayer film

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JP2001245490A (en) 2000-02-28 2001-09-07 Bunka Shutter Co Ltd Opening and closing body controller
US7537829B2 (en) 2001-02-22 2009-05-26 Exxonmobil Oil Corporation Multi-layer films having improved sealing properties
EP2355927B1 (en) 2008-11-07 2015-03-04 Borealis AG Solid catalyst composition
WO2010052263A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
EP2361267B1 (en) 2008-11-07 2015-03-04 Borealis AG Process to prepare a solid catalyst composition
KR101091527B1 (en) 2009-04-06 2011-12-13 제이더블유생명과학 주식회사 Multilayer Film For Medical Use And the Use thereof
KR101091528B1 (en) 2009-04-06 2011-12-13 제이더블유생명과학 주식회사 Multilayer Film For Medical Use And the Use thereof
ES2525554T3 (en) 2010-07-13 2014-12-26 Borealis Ag Catalyst component
ES2643158T3 (en) 2011-07-08 2017-11-21 Borealis Ag Catalysts
EP2548920B1 (en) 2011-07-15 2017-10-11 Borealis AG Unoriented film
EP2610272B1 (en) 2011-12-30 2017-05-10 Borealis AG Catalyst component
EP2610270B1 (en) 2011-12-30 2015-10-07 Borealis AG Catalyst component
ES2727405T3 (en) 2011-12-30 2019-10-16 Borealis Ag Preparation of phthalate free ZN PP catalysts
JP6151438B2 (en) * 2013-05-08 2017-06-21 ボレアリス・アクチェンゲゼルシャフトBorealis Ag Multilayer polymer film
EP2829558B1 (en) 2013-07-24 2016-12-14 Borealis AG Process
EP3119816B2 (en) * 2014-03-21 2023-02-22 Borealis AG Heterophasic propylene copolymer with high melting point
US9401350B1 (en) 2015-07-29 2016-07-26 Qualcomm Incorporated Package-on-package (POP) structure including multiple dies
EP3246358A1 (en) * 2016-05-18 2017-11-22 Borealis AG Soft and transparent propylene copolymers

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001042009A1 (en) * 1999-12-11 2001-06-14 Fresenius Kabi Deutschland Gmbh Autoclavable pvc-free multilayer film to be especially used for packing liquid, medicinal products, method for producing the same and the use thereof
JP2007245490A (en) * 2006-03-15 2007-09-27 Intermedic Co Ltd Multilayer film and soft bag for medical treatment
WO2013144061A1 (en) * 2012-03-29 2013-10-03 Borealis Ag Unoriented film based on soft polypropylene
DE202013103803U1 (en) * 2013-08-22 2014-11-24 Kobusch-Sengewald Gmbh Multilayer film

Also Published As

Publication number Publication date
CN113924211B (en) 2023-09-22
WO2020245251A2 (en) 2020-12-10
CN113924211A (en) 2022-01-11
US20220258457A1 (en) 2022-08-18
EP3980473A2 (en) 2022-04-13
US11752743B2 (en) 2023-09-12

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