WO2020143134A1 - Recycled paper and manufacturing method thereof - Google Patents

Recycled paper and manufacturing method thereof Download PDF

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Publication number
WO2020143134A1
WO2020143134A1 PCT/CN2019/084933 CN2019084933W WO2020143134A1 WO 2020143134 A1 WO2020143134 A1 WO 2020143134A1 CN 2019084933 W CN2019084933 W CN 2019084933W WO 2020143134 A1 WO2020143134 A1 WO 2020143134A1
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WO
WIPO (PCT)
Prior art keywords
paper
crushing
flocculent
deinking
assembly
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PCT/CN2019/084933
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French (fr)
Chinese (zh)
Inventor
齐元胜
高溯
周航
季茂林
张哲欣
魏腾跃
于洪萱
Original Assignee
北京印刷学院
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Application filed by 北京印刷学院 filed Critical 北京印刷学院
Publication of WO2020143134A1 publication Critical patent/WO2020143134A1/en

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/64Paper recycling

Definitions

  • the invention belongs to the technical field of papermaking production, and relates to a papermaking method, in particular to a method of using waste to make paper.
  • the traditional paper manufacturing industry is still crushing the recovered waste paper, and then adding a large amount of water and chemical reagents to soak the waste paper, re-pulp, deink, and finally make various paper products .
  • the current waste paper recycling is still mainly to send the waste paper to the paper mill for reuse, and the current paper mill still has greater pollution to the surrounding environment. Even if reagents are added to the sewage to neutralize it, It will inevitably cause damage to the natural environment and cannot achieve or achieve "zero" pollution.
  • the waste paper crushing and deinking machine is crushed into flocculent dry fibers and the waste paper ink is removed at the same time, and no moisture and chemical reagents are added during the process of preparing the flocculent fibers. Due to the different morphology of the substance, in this form, the ink present in the waste paper exists at a very low content and is broken up. Only a certain proportion of starch glue needs to be added to bind, suppress, and dry the flocculent dry fiber In the process of drying, etc., the conventional paper that can be used can be made to avoid environmental pollution and achieve "zero" pollution and "zero" emissions.
  • the recycled paper prepared by the present invention has better water retention, moldability and higher toughness, and the method of the present invention is a papermaking process without waste water generation.
  • the papermaking method of the present invention is green, Environmental protection.
  • the purpose of the present invention is to provide a kind of recycled paper and its preparation method in view of the existing preparation method of using waste paper to prepare recycled paper and the technical problem of preparing recycled paper.
  • the method of the present invention is a new type of anhydrous papermaking method to discard paper As raw materials, the ink of the waste paper is removed at the same time of crushing, and the flocculent dry fiber to remove the ink is prepared and mixed with the adhesive to make a new paper.
  • the method of the present invention provides a new papermaking idea and solves the papermaking Due to the problems of water pollution and waste paper waste in the industry, the waste paper raw materials of the present invention have a wide range of sources, the prepared paper is cheap, the preparation time is less, the waste paper can be reused, the use of tree materials is reduced, and environmental protection is convenient. A small amount of water is used in the production of various paper products, which reduces the series of heavy pollution processes such as beating and waste disposal of traditional papermaking, and realizes the true green printing, clean papermaking, and pollution-free papermaking process and process effects.
  • one aspect of the present invention provides a papermaking method, including the following steps:
  • the length of the flocculent dry fiber in step 1) is ⁇ 1.0 mm, preferably 1.0-1.2 mm.
  • the deinking treatment is carried out at the same time as the waste paper is crushed to prepare the flocculent dry fiber from which the ink is removed.
  • the pulverization and deinking treatment is to pulverize waste paper into flocculent dry fibers, and at the same time pulverize, remove the ink from the waste paper to produce flocculent dry fibers from which printing ink has been removed.
  • the crushing and deinking process is performed on the waste paper by using a crushing and deinking machine.
  • the crushing and deinking machine includes: a housing; a coarse crushing component installed on the housing for cutting waste paper into the housing; mounted on the housing and below the coarse crushing component A paper-washing assembly for preventing clogging of the coarse crushing device; a crushing and de-inking assembly installed on the casing and located below the paper-washing assembly for crushing the paper pieces into flocculent scraps and separating the scraps and the ink on the scraps ;
  • the collecting assembly installed on the casing and located below the crushing and deinking device has a filter screen for filtering the flocculent paper dust and a screen for screening the flocculent paper dust located below the filter screen.
  • the coarse crushing assembly includes: at least two rotating shafts which are rotatably mounted on the casing and extend in the horizontal direction; a plurality of paper cutting blades installed at intervals along the axial direction of the rotating shaft; wherein, two adjacent rotating shafts The cutting blades are misaligned.
  • the coarse crushing module crushes the waste paper into shredded paper pieces having a size of (1-5) mm ⁇ (1-5) mm, and the size of the shredded paper pieces is preferably 5 mm ⁇ 5 mm.
  • the punching assembly includes at least one pair of nozzles disposed on both sides of the casing.
  • the crushing and deinking assembly includes: a pair of rotors installed side by side on the casing and having a central axis perpendicular to the central axis of the rotating shaft; a ring provided on the outer wall of each rotor for crushing the paper sheet Multiple rows of hammers formed into flocculent scraps; a rotary drive mechanism connected to a pair of rotors to drive a pair of rotors to rotate at a high speed in order to separate the flocculent scraps and the ink on the scraps.
  • the multiple rows of hammers on the rotor respectively include a plurality of hammers arranged at intervals along the axial direction of the rotor, and the hammers on the pair of rotors are arranged in a misaligned manner.
  • the hammer is a T-shaped hammer.
  • the T-shaped hammer piece includes a radial segment extending in the radial direction of the rotor and a tangential segment extending in the tangential direction of the rotor, and the inner end of the radial segment is fixedly mounted on the outer wall of the rotor.
  • the radial section and the tangential section of the T-shaped hammer have the same shape and size.
  • the gap between two adjacent rows of T-shaped hammer pieces arranged on one rotor in the axial direction of the rotor is 0.8-1.2 cm, preferably 1.0 cm.
  • the width of the radial section of the T-shaped hammer piece in the axial direction of the rotor is 0.6-1.5 cm, preferably 1.2 cm.
  • the gap between the ends of the pair of rotors opposite the hammers there is a gap of 0.2-0.4cm, preferably 0.2mm, between the ends of the pair of rotors opposite the hammers, (usually the hammers are staggered, regardless of the gap, but the paper is flammable, the opposite hammers There is a certain gap between them), that is, the gap between the ends of the tangential section of the hammer is 0.2-0.4cm, preferably 0.2mm (usually the hammers are staggered, the gap is not considered, but the paper is flammable) , There is a certain gap between the opposite hammers).
  • the rotational speed of the control rotor during the crushing and deinking process is ⁇ 3000 rpm, preferably ⁇ 7000 rpm, and more preferably 7000-15000 rpm.
  • the pore size of the filter screen of the collecting component is 14-16 mesh; the pore size of the screen is 16-20 mesh, preferably 16 mesh.
  • the collecting assembly further includes: a pipe located below the screen of the crushing and deinking assembly, and a blower connected to the viewpoint for discharging the filtered flocculent paper dust.
  • it also includes a material guide assembly mounted on the casing and located between the coarse crushing assembly and the crushing deinking assembly.
  • the material guide assembly includes a triangular plate or an inverted V-shaped flap with its top hinged to the casing, and a hinged edge of the triangular plate or inverted V-shaped flap for hinged with the casing
  • the extending direction of is parallel to the direction of the central axis of the rotor of the crushing and deinking assembly.
  • the paper cutting blade of the coarse crushing assembly and the inner wall of the cabinet are respectively coated with an antistatic coating for preventing static electricity.
  • the adhesive for papermaking mentioned in step 2) is starch glue, preferably glutinous rice glue.
  • the adhesive solution for papermaking is prepared according to the following method: starch glue is added to distilled water and stirred evenly, wherein the mass ratio of starch glue to distilled water is 1:14-20, preferably 1:16 .
  • the mass ratio of the flocculent dry fiber to the adhesive solution for papermaking is 100:0.5-1.2, preferably 100:1.
  • the pressing process in step 3) is divided into two rollings, the first rolling is to produce a paper roughness 1.2-1.8 times thicker than the finished paper thickness, preferably a paper roughness 1.5 times thick;
  • the second rolling is to roll the rough paper after the first rolling into a semi-finished paper with a moisture content of 10-15%.
  • two sets of rollers are used for the two rollings.
  • the gap between the first group of rollers during the first rolling process is 1.2-1.8 times the thickness of the resulting paper, preferably 1.5 times.
  • the drying process is to dry the pressed paper semi-finished product to a moisture content of 7%-8%.
  • the drying process is selected to be a vacuum drying process, in which the drying temperature is controlled to be 40-50°C; the degree of vacuum is -0.0075 to -0.1 MPa.
  • the drying treatment selects atmospheric pressure drying, wherein the drying temperature is 110°C-150°C, preferably 120°C.
  • UV drying is selected for the drying process.
  • the present invention has the following advantages and benefits:
  • the method for preparing recycled paper of the present invention breaks the tradition, directly crushes waste paper materials into flocculent form, and completes deinking treatment in the crushing process. It is an innovative application that has never been used in the field of recycled paper preparation. , So that no deinking of water is needed in the papermaking process, no pollution to the environment, and the waste papermaking process is simplified.
  • the method of the present invention eliminates the effect of the residual ink on the waste paper on the quality of the recycled paper, and no waste pulp waste will be generated in the papermaking process Liquid, and improve the quality of recycled paper, in line with China's green production road to protect the environment.
  • a crushing and deinking machine is used to crush the paper into flocculent paper dust, and the ink on the paper is detached from the paper fiber, so that there is no need to use warm water to soak the paper dust and add chemicals to perform the deinking process. No pollution to the environment due to waste liquid.
  • the present invention uses a deinking crusher to crush waste paper. Its T-shaped hammers ease the speed of air circulation in the casing, reduce the impact on light and fine flocculent paper scraps, and improve the crushing efficiency.
  • the method for preparing recycled paper of the present invention can recycle and remanufacture waste paper in situ, which consumes less time and has a lower price. It can reuse waste paper and reduce the use of tree materials. It is environmentally friendly and convenient, and the process of manufacturing recycled paper For waterless recycled paper, a series of heavy pollution processes such as beating and waste disposal of traditional papermaking are reduced, green printing is achieved, papermaking is clean, it is beneficial to protect the ecological environment, and the papermaking process is reduced.
  • the papermaking process of the present invention eliminates the use of water, omits the beating process, and achieves zero pollution and zero emissions; and the prepared recycled paper can be used to manufacture cardboard and carton; packaging paper bags; newsprint and other products.
  • the recycled paper of the present invention is made from waste paper, in which 80% of the raw materials come from recycled waste paper. Since there is no need to add any whitening agent, fluorescent agent and other chemicals in the process of manufacturing recycled paper, it can more show the true color of the paper, and because the recycled paper produced is not reflective, it is more conducive to protecting eyesight. In addition, no deinking treatment is needed for water in the manufacturing process, reducing the generation of waste liquid, reducing environmental pollution, and reducing the consumption of trees, which is conducive to the protection of the ecological environment.
  • Figure 1 is a process flow diagram of the preparation of recycled paper of the present invention
  • FIG. 2 is a schematic structural view of a crushing and deinking machine of the present invention
  • FIG. 3 is a schematic diagram of the relative position of the cutting blades on the two rotating shafts of the crushing and deinking machine of the present invention
  • FIG. 4 is a schematic view of the nozzle of the crushing and deinking machine of the present invention installed on the casing;
  • FIG. 5 is a schematic structural view of a pair of rotors of the crushing and deinking machine of the present invention and the rotors provided with hammers;
  • FIG. 6 is another schematic structural view of the crushing and deinking machine of the present invention.
  • FIG. 7 is a flow chart of the crushing and deinking process of waste paper by using the crushing and deinking machine of the present invention.
  • the materials, reagents, equipment, and instruments used in the following examples can be obtained from commercial sources.
  • the waste paper comes from a waste paper recycling station.
  • the preparation process of recycled paper of the present invention firstly, the collected waste paper is crushed and deinked by a crushing and deinking machine, and the flocculent dry fiber is prepared by filtration and sieving, and then the papermaking is sprayed into the flocculent dry fiber Using an adhesive, a flocculent fiber-adhesive mixture is prepared; then the flocculent fiber-adhesive mixture is sequentially rolled and dried to obtain a recycled paper.
  • the crushing and deinking machine of the present invention includes: a casing; a coarse pulverizing assembly 1 installed on the casing for cutting waste paper into the casing; mounted on the casing and located in the coarse Punching assembly 4 below the crushing assembly 1 for preventing the clogging of the coarse crushing assembly 1; installed on the cabinet and below the punching assembly 4 for crushing the paper pieces into flocculent scraps and separating the scraps and scraps
  • the crushing and deinking assembly 7 of the ink; the receiving assembly 10 installed on the casing and located below the crushing and deinking assembly 7, has a filter screen 9 for filtering the flocculent paper dust and a filter screen for filtering the floc under the filter screen ⁇ Screen ⁇ 11.
  • the casing includes: a coarse crushing chamber casing, which is a cylindrical upper cylindrical casing 13, and a paper inlet for waste paper is opened at an upper portion thereof; a crushing and deinking chamber casing includes: The upper narrow, lower wide upper conical shell 14 connected to the bottom of the cylindrical shell 13, the lower cylindrical shell 15 whose top is connected to the bottom of the upper conical shell 14, the top thereof and the bottom of the lower cylindrical shell 15 Connected upper wide and lower narrow lower conical shell 16, wherein the pipe 12 of the receiving device 10 is connected to the bottom of the lower conical shell 16, in design, it can be set at the outlet of the lower cylindrical shell 15 Open or close the outlet baffle (not shown).
  • the coarse crushing assembly 1 is installed in the upper cylindrical casing 13 of the casing, which includes: at least two rotating shafts 2 which are rotatably installed in the upper cylindrical casing 13 and extend in the horizontal direction; A plurality of paper cutting blades 3 on the rotating shaft; among them, the paper cutting blades on the two adjacent rotating shafts are arranged in a misaligned manner.
  • it also includes a driving mechanism installed in the upper cylindrical housing and connected to the rotating shaft for driving the rotating shaft to rotate.
  • the driving mechanism may use a motor to drive a gear set mechanism or other mechanisms in the prior art, which is not correct here. Its structure is described.
  • rotating shafts there may be two or more rotating shafts installed in the upper cylindrical housing 13.
  • two parallel rotating shafts 2 that are parallel to each other are used as an example to describe the structure.
  • a plurality of cutting blades 3 are installed on the two rotating shafts 2 at intervals (in FIG. 2, five cutting blades are installed on one rotating shaft and four cutting blades are installed on the other rotating shaft), and the cutting blades 3 are round Disc-shaped, the outer edges are provided with cutting teeth along the circumferential direction, as shown in Figure 3, and the center distance between the cutting blades on the two rotating shafts is smaller than the diameter of the outermost edges of the two cutting blades.
  • the paper cutting blades on the two rotating shafts are misaligned along the axial direction of the respective rotating shafts, that is, from the axial view of a pair of rotating shafts, the The cutting blade on one shaft is located between the two cutting blades on the other shaft.
  • a coarse crushing assembly 1 is provided below the feed opening of the upper cylindrical housing 13, and when waste paper (ie, waste paper) is thrown in through the feed opening, the waste paper will be shredded under the action of the cutting blade of the coarse crushing assembly
  • the paper sheet ((1-5) mm ⁇ (1-5) mm, preferably 5 mm ⁇ 5 mm) is advantageous for the next crushing of the paper sheet by the crushing and deinking device 7 to improve production efficiency.
  • a punching assembly 4 for preventing clogging of the coarse crushing assembly is provided below the coarse crushing assembly.
  • At least one pair of spray heads 42 on both sides of the inner wall of the upper cylindrical housing, and the air outlets of the pair of spray heads are arranged to face each other obliquely upward, and are respectively aligned with the two rotating shafts or the positions between the two rotating shafts, as shown in FIG. 2.
  • the spray head 42 is made of a material with elasticity, and the spray head shell 41 is clamped on the outside, and the spray head shell is installed on the inner wall of the upper cylindrical shell by bolts, and the air inlet of the spray head is provided on the upper cylindrical shell
  • the air outlet of the small hair dryer (including motor and fan blade) is connected.
  • the blower is energized, and its motor drives the fan blades to generate a certain intensity of airflow.
  • the airflow enters through the air inlet of the nozzle and is blown out diagonally upward from the air outlet, so that Cut into pieces of paper to prevent the cutting blade from clogging.
  • the paper sheet cut by the coarse crushing assembly falls down into the shell of the crushing and deinking assembly under the action of gravity, so that the crushing and deinking assembly 7 can perform secondary crushing treatment on the paper sheet And deinking treatment.
  • a part of the crushing and deinking assembly 7 is placed in the upper conical shell 14 and the other part is placed in the lower cylindrical shell 15 to facilitate the overall reception of the paper pieces falling down from the upper cylindrical shell to fully prevent paper The piece clogs the upper cylindrical housing.
  • the crushing and deinking assembly 7 includes: a pair of rotors 8 installed side by side at a horizontal position where the upper conical housing 14 and the lower cylindrical housing 15 are connected, and the central axis of the rotor 8 is different from the central axis of the rotating shaft 2
  • the surface is vertical; the multiple rows of hammers 6 that are placed on the outer wall of each rotor to crush the paper into flocculent scraps; connected to a pair of rotors respectively to drive a pair of rotors to rotate at a high speed to separate the flocculent scraps and A rotary drive mechanism for ink on paper scraps (not shown in the figure).
  • the rotary drive mechanism can use a prior-art rotary mechanism, such as a motor-driven mechanism, to transmit its output power to a pair of rotors, respectively.
  • the rotors rotate toward each other, for example, the rotor on the left in FIG. 2 rotates clockwise, and the rotor on the right rotates counterclockwise, so that the hammer 6 crushes the paper into fluffy paper dust.
  • each row of hammers includes a plurality of spaced apart along the axial direction of the rotor Hammer.
  • the hammers on a pair of rotors are misaligned, and there is a gap between the ends of opposite rotors on a pair of rotors, as shown in Figure 5, that is, the sum of the distances from the end faces of the hammers of the two rotors to the axis is less than two
  • the distance between the axes of the two rotors prevents the two rotors from vibrating during the high-speed rotation and crushing of the paper.
  • the hammers on the pair of rotors will cause mechanical collisions, and the ends of the pair of rotors opposite the hammers There is a gap of 0.2-0.4cm, preferably 0.2mm, (usually the hammers are staggered, regardless of the hammer head gap, but the paper is flammable, and there is a certain gap between the hammer heads), that is, the relative hammer
  • the gap between the ends of the tangential section is 0.2-0.4cm, preferably 0.2mm (usually the hammers are staggered, regardless of the gap, but the paper is flammable, and there is a certain gap between the hammers).
  • the hammer adopts T-shaped hammer, which includes a radial segment extending in the radial direction of the rotor and a tangential segment extending in the tangential direction of the rotor.
  • the inner end of the radial segment is fixedly installed on the outer wall of the rotor.
  • the center and diameter of the tangential segment Connect to the outer end of the segment.
  • the use of a pair of rotors to drive the T-shaped hammer blades to rotate at high speed can crush the waste paper strips into deinked flocculent paper scraps, alleviating the speed of air circulation in the crushing and deinking chamber, and reducing the impact on light and fine paper scraps. Improving crushing efficiency, greatly improving production efficiency, improving product quality, and breaking the traditional waste paper recycling method are innovative applications that have never been used in the field of shredders or even waste paper recycling.
  • the distance between two adjacent hammers on the same rotor in the axial direction is 0.8-1.2 cm, preferably 1 cm.
  • the radial section of the T-shaped hammer piece has the same shape and size as the tangential section; and the width of the radial section of the T-shaped hammer piece in the axial direction of the rotor is 0.6-1.5 cm, preferably 1.2 cm.
  • the rotation speed of the rotor is ⁇ 3000 rpm, preferably ⁇ 7000 rpm, and more preferably 7000-15000 rpm.
  • the rotating mechanism of the crushing and deinking component 7 drives the rotor and the T-shaped hammer to rotate and cut the paper at high speed, and the paper is crushed by the high speed impact of the hammer and the paper
  • the flakes are crushed into flocculent scraps (size range ⁇ 1.0mm, preferably 1.1-1.2mm)
  • the ink on the waste paper strip is peeled off under the impact of the T-shaped hammer, and the rotor and T-shaped hammer are high-speed Under the action of rotating centrifugal force, the ink is separated from the paper (rotor speed ⁇ 3000rpm).
  • the centrifugal force is thrown on the inner wall of the upper conical shell, the lower cylindrical shell or remains on the T-shaped hammer, and the paper scraps fall down under the action of gravity.
  • the flocculent dry fiber material ie, flocculent scraps
  • the baffle plate is opened, and the scraps are collected and discharged through the collecting assembly 10, and thrown to the upper conical shell
  • the ink on the inner wall of the body and the lower cylindrical shell can be periodically processed manually.
  • paper beating is used for deinking.
  • the present invention uses a crushing deinking section to directly process waste paper into deinked flocculent scraps, eliminating the need for paper beating, thereby reducing the use of waste paper
  • the papermaking process steps are carried out, and because there is no paper beating process, a large amount of waste pulp and waste liquid will not be generated, thereby avoiding pollution to the environment.
  • a material guide assembly 5 for guiding the falling direction of the paper sheet is provided.
  • the material guide assembly 5 includes its top and the upper cylindrical shell and/or upper cone
  • the inverted V-shaped baffle of the reversed V-shaped baffle (as shown in FIG. 2) is hinged, and the extending direction of the hinged edge of the inverted V-shaped baffle used to be hinged with the housing and the rotor of the crushing deinking assembly The direction of the central axis is parallel.
  • the inverted V-shaped baffle is installed directly above the pair of rotors, and the paper after primary crushing by the coarse crushing assembly is guided along the slope of the inverted V-shaped plate into the crushing deinking chamber to avoid crushing falling between the pair of rotors Vacuum zone, which improves crushing efficiency.
  • the material guide assembly 5 of the present invention may also adopt a triangular plate. As shown in FIG. 6, the top of the triangular plate is hinged with the upper cylindrical shell and/or the upper conical shell. Similarly, the hinged edge of the triangular plate is used to hinge with the shell. The extending direction is parallel to the central axis direction of the rotor of the crushing deinking assembly.
  • the bottom plate opposite to the top can also destroy the annular throwing ring formed by the paper under the action of the rotor, preventing paper or paper scraps and hammers
  • the pieces produce opposite movement, which improves the hammer's impact on the paper or paper scraps, and is more conducive to the separation of the ink on the paper or paper scraps.
  • the crushed and deinked paper dust from the crushing and deinking assembly 7 falls down and is collected and discharged by the collecting assembly 10.
  • the receiving assembly includes: a screen 9 installed in the lower cylindrical housing 15 and below the pair of rotors 8; a screen 11 below the screen 9 for screening paper dust; and a paper dust for deinking Discharged duct 12; a blower (not shown in the figure) connected to the duct 12 for discharging the paper dust that has fallen out after screening.
  • the filter screen 9 is an arc filter screen with an arc shape adapted to the outer contours of the pair of rotors 8, the periphery of the filter screen is fixed to the inner wall of the lower cylindrical housing 15, and the filter 9 is filtered and crushed and deinked by the crushing and deinking assembly
  • the resulting flocculent paper dust causes paper dust with a size smaller than or equal to the mesh diameter to fall through the filter onto the screen, and paper dust with a size larger than the diameter of the filter mesh is repeated by a pair of rotors and T-shaped hammers on the rotor Crushing, in the process of crushing the paper strip, the filter screen also plays the role of rubbing and shearing the paper strip, the pore size of the filter screen is 14-16 mesh; at the same time, it is necessary to control the tangential section of the hammer on the rotor and the filter screen
  • the gap between them is ⁇ 8mm, preferably 6-8mm, further preferably 8mm), the paper is lighter and not easy to fall during the crushing
  • the screen is fixed to the connection between the lower cylindrical shell 15 and the lower conical shell 16, and the screen aperture is 16-20 mesh.
  • the aperture of the screen it should be selected according to the actual situation to prevent the flocculent scraps of paper strips from clogging the screen.
  • a baffle plate is provided below the crushing and deinking chamber, the baffle plate can be placed above the screen, under the filter screen, or the baffle plate can be placed under the screen. After the paper pieces are crushed, the baffle is opened to allow the paper scraps to fall down into the lower conical shell 16, and the paper scraps are drawn away through the duct 12 under the action of a blower (not shown) To complete the layout.
  • the cutting blade of the coarse crushing component and the inner wall of the cabinet can be coated with anti-static fluorine coating to prevent static electricity, so as to prevent paper pieces or paper scraps from sticking to the inner wall of the cabinet and minimize the paper Material sticky phenomenon.
  • wear-resistant materials can also be coated on the inner wall of the cabinet to reduce the noise when the equipment is working.
  • spraying papermaking adhesive sizing treatment, rolling treatment, and drying treatment can be carried out by spraying, rolling, and drying methods in the prior art, so each treatment is not carried out here. Methods and steps are described in detail.
  • the recovered waste paper (such as waste office paper) is put between the two rotating shafts through the feed inlet, and the waste paper is cut into shredded paper pieces through a plurality of cutting blades arranged on a pair of rotating shafts,
  • the size of the shredded paper is ((1-5) mm ⁇ (1-5) mm).
  • the paper cutting blade is cleaned by the paper punching assembly located below the coarse crushing assembly to prevent the cutting blade from being blocked by the small pieces of paper.
  • the shredded paper pieces processed by the coarse crushing assembly drop into the crushing deinking assembly under the action of gravity, and then crushed and deinked again by the crushing deinking assembly.
  • the rotor and the T-shaped hammer (the hammer is the blade) , T-shaped) high-speed rotation cutting paper, through the high-speed impact of the hammer and the paper to crush the paper into flocculent scraps (ie flocculent dry fiber material), while separating the ink from the paper.
  • the paper dust that has been crushed and deinked by the rotor and T-shaped hammer is filtered through a filter screen. After the screen is sieved, the flocculent dry fibers with a length of 1.0mm to 1.2mm are collected to prepare deinked flocculent dry fibers; crushed- When a certain amount of flocculent dry fiber material accumulates after deinking, it passes through the screen and enters the lower conical shell (that is, storage bin) under the action of the blower, and is discharged through the pipeline for further processing.
  • the lower conical shell that is, storage bin
  • the fiber-adhesive mixture is rolled twice, the first rolling process is rough pressing, so that it initially takes the form of paper and slightly removes water, and the rolling thickness during the first rolling process is the thickness of the paper 1.2-1.8 times (preferably 1.5 times); the second rolling treatment is squeezing to obtain semi-finished paper with a moisture content of 10-15%, at this time the semi-finished paper is dark white.
  • the surface of the roller is coated with tetrafluoroethylene coating to prevent sticking.
  • Drying the semi-finished recycled paper usually by high temperature drying, vacuum drying, UV photothermal drying, etc., to obtain finished recycled paper.
  • the raw material used in the recycled paper of the present invention is waste paper. After being crushed and deinked by the crushing and deinking machine of the present invention, a 16-20 mesh screen is also used to sieve the crushed paper scraps and collect 1.0mm-1.2 mm-length flocculent inkless dry fiber. It reduces the use of tree materials and helps protect the ecological environment.
  • the formed flocculent dry fiber can be used in the manufacture of daily office paper: using related equipment to crush the waste paper into flocculent dry fiber, and spray-type glue to bond, and then realize anhydrous papermaking. This papermaking technology uses waste paper that has been used in the production process, which reduces the use of tree materials and is beneficial to the protection of the ecological environment.
  • Drying treatment of paper semi-finished products can remove three types of water from paper, one is free water, one is water in fiber tube, and the other is combined water. Rolling treatment can remove part of free water and fiber tube The remaining water is completed by drying.
  • the waste paper from the feed port of the recycled paper crushing and deinking machine and carry out preliminary crushing in the coarse crushing unit of the crushing and deinking machine to make the size 5mm ⁇ 5mm (usually (1-5)mm ⁇ (1- 5) mm) shredded paper, then enter the crushing and deinking assembly under the action of gravity, cut the shredded paper under the high-speed rotation of the rotor and T-shaped hammer, and crush the paper into a high-speed impact of the hammer and the paper Flocculent paper dust (i.e., flocculent dry fiber material), at the same time, the ink is separated from the paper sheet, and deinking treatment is carried out, in which the rotor speed is controlled to 8000rpm (usually ⁇ 7000rpm, preferably 7000-15000rpm); The gap between two adjacent rows of T-shaped hammer pieces in the axial direction is 1.0cm (usually 0.8-1.2cm); the radial section of the T-shaped hammer piece has the same shape and size as the radial
  • the gap between the tangential section of the hammers on the rotor and the filter screen needs to be controlled to 8mm (usually (Less than 8mm, preferably 6-8mm), the paper is light and not easy to fall, in the crushing process.
  • the filter screen has a pore size of 14-16 mesh
  • a screen with a pore size of 16 mesh usually 16-20 mesh
  • the flocculent paper dust is sieved to obtain a length of 1.0-1.2 mm (usually the length of the flocculent dry fiber ⁇ 1.0mm, preferably 1.0-1.2mm), the flocculent dry fiber of the waste paper, used;
  • flocculent dry fiber has a good capture of the water-starch glue mist system used in the anhydrous papermaking process.
  • 1.0mm is the lower limit of the waste paper fiber bonding length, because the focus of the flocculent dry fiber is on the flocculent, that is, there are many soft hairs on the main fiber, which can capture the misty tiny colloidal particles, based on the principle of surface area effect (The more the same volume of material is dispersed, the greater the surface area), the smaller the flocculent dry fiber, the better the capture of colloidal particles, so 1.0mm-1.2mm length of fiber is used.
  • glutinous rice glue to distilled water and stir until the final formation of a stable and stable paper-making adhesive solution (ie glutinous rice glue-water mixture) without obvious lumps, in which the quality of glutinous rice glue and water
  • the ratio is 1:16 (usually 1:14-20) and then the paper-made adhesive solution is poured into the atomization bottle and set aside.
  • Glutinous rice glue belongs to starch glue, and starch is divided into two types, amylose and amylopectin.
  • amylose the higher the content of amylopectin, the stronger the viscosity, and the stickiness in glutinous rice glue
  • amylose content is above 90%, the highest content in natural starch-like gums, and environmentally friendly.
  • glutinous rice glue is used as an example for description, and other starch adhesives such as corn glue and other solid glues are suitable for the present invention.
  • the flocculent waste paper dry fiber sieved through the screen of the crushing and deinking section is transported to the atomizing chamber through a conveyor belt, and the atomized papermaking adhesive solution (glutinous rice glue) is sprayed into the flocculent dry fiber in the atomizing chamber -Water mixture), spray sizing, the mass ratio of flocculent dry fiber to glutinous rice glue-water mixture is 100:1 (usually 100:0.5-1.2), the paper will be lifted by misty glutinous rice glue-water mixture
  • the fiber tape falls and mixes with the paper dry fiber until a paste-like paper fiber-adhesive mixture is formed.
  • the paste paper fiber-adhesive mixture is transported between two sets of rollers through a conveyor belt, and is subjected to two rolling treatments. After the two rollers are rolled, the first roller is used for preliminary paste Press to make it take the form of paper and remove water slightly.
  • the gap of the first set of rollers is 1.5 (usually 1.2-1.8 times) the thickness of the resulting paper, and the thickness of the paper is 1.5 (usually 1.2-1.8) times thick.
  • the second group of rolling rollers is precision pressing, that is, the second group of rolling rollers is used for the second rolling of the rough pressed paper blanks to obtain paper semi-finished products with a moisture content of 10-15%.
  • the pressing process is divided into two rolling processes.
  • the first rolling process is rough pressing, which means that the paste is initially pressed to make it take the form of paper and remove water slightly, and the gap between the rollers is 1.5 of the thickness of the resulting paper (usually (1.2-1.8 times) times; two times of rolling and compacting to obtain semi-finished paper with a moisture content of 10-15%, at this time the semi-finished paper is dark white.
  • the surface of the conveyor belt and roller is coated with tetrafluoroethylene coating to prevent sticking.
  • the dark white semi-finished paper is transported to the drying section through the conveyor belt of the conveying section for vacuum drying, the drying temperature is 40-50°C, the vacuum degree is controlled to -0.0075 ⁇ -0.1MPa during the drying process, and the drying time is 15s-20s.
  • Drying treatment In addition to vacuum drying treatment, other conventional drying methods, such as atmospheric high temperature drying, UV photothermal drying, etc., are suitable for the present invention.
  • the sizing treatment, pressing treatment and drying treatment of the present invention can adopt the methods of sizing, pressing and drying treatment currently known in the art, respectively, which are all applicable to the present invention.
  • the brightness of the recycled paper is measured according to the national standard "Determination of the Blue Light Diffuse Reflectance Factor D65 for Paper, Paperboard and Pulp (GB/T 7974-2013) (Diffuse/Vertical Method, Outdoor Daylight Conditions)" method;
  • the horizontal folding endurance of recycled paper is measured according to the national standard "Determination of folding endurance of paper and paperboard GB/T 457-2008";
  • the tightness of recycled paper usually refers to the quality of 1 cubic meter of paper or cardboard, also known as the apparent density; the specific measurement method is as follows: randomly select ten papers from the prepared paper and use an electric thickness gauge to measure the thickness of each paper Record with numbers; measure the corresponding mass of each paper with an electronic balance; then. According to the standard surface area of the prepared paper, divide the mass of the paper by the product of the thickness of the corresponding paper and the surface area and obtain the average of the tightness of the paper. Value, the measurement results are shown in Table 1;
  • the tensile strength of the recycled paper is measured by a tensile strength testing machine.
  • the tensile strength tester stretches the specimen of the specified size to break under the condition of constant speed loading and measures its tensile strength. Record the maximum elongation at break and calculate the tensile (tensile) strength. The measurement results are shown in Table 1;
  • the surface strength of the recycled paper is determined by the IGT printing suitability tester and wax stick, according to the drawing speed measurement method and the wax stick method.
  • the thickness of the recycled paper was measured using an electric thickness gauge, and the measurement results are shown in Table 1.

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Abstract

A manufacturing method of recycled paper comprises: simultaneously shredding and de-inking waste paper, and forming de-inked dry flocculent fiber; spraying a liquid papermaking adhesive; and sequentially performing pressing and drying operations.

Description

一种再生纸及其制备方法Recycled paper and preparation method thereof 技术领域Technical field
本发明属于造纸生产技术领域,涉及一种造纸方法,特别涉及一种利用废弃物进行造纸的方法。The invention belongs to the technical field of papermaking production, and relates to a papermaking method, in particular to a method of using waste to make paper.
背景技术Background technique
据调查的得知现在传统制造纸制品的行业依旧是把回收的废纸进行粉碎,然后加入大量的水以及化学试剂对废纸进行浸涨后重新打浆,脱墨,最终制成各种纸制品。根据查阅相关资料,现在的废纸回收还是主要把废纸送到造纸厂进行再利用,且现在的造纸厂依旧对附近的环境有较大的污染,纵使在污水中加入了试剂中和,却不可避免的会对自然环境造成伤害,不能达到或实现“零”污染。According to the investigation, it is learned that the traditional paper manufacturing industry is still crushing the recovered waste paper, and then adding a large amount of water and chemical reagents to soak the waste paper, re-pulp, deink, and finally make various paper products . According to the relevant information, the current waste paper recycling is still mainly to send the waste paper to the paper mill for reuse, and the current paper mill still has greater pollution to the surrounding environment. Even if reagents are added to the sewage to neutralize it, It will inevitably cause damage to the natural environment and cannot achieve or achieve "zero" pollution.
而本发明是将废纸粉碎脱墨机粉碎成絮状干纤维的同时脱除废纸油墨,制备絮状纤维的过程中不需要添加任何的水分以及化学试剂。由于物质的形态不同,在该形态下,废纸中存在的油墨以极低的含量存在,并被打散,只需要加入一定配比的淀粉胶对絮状干纤维进行粘结、压制、烘干等过程,就可以制成可供使用的常规用纸,避免环境污染,实现环境“零”污染,“零”排放。In the present invention, the waste paper crushing and deinking machine is crushed into flocculent dry fibers and the waste paper ink is removed at the same time, and no moisture and chemical reagents are added during the process of preparing the flocculent fibers. Due to the different morphology of the substance, in this form, the ink present in the waste paper exists at a very low content and is broken up. Only a certain proportion of starch glue needs to be added to bind, suppress, and dry the flocculent dry fiber In the process of drying, etc., the conventional paper that can be used can be made to avoid environmental pollution and achieve "zero" pollution and "zero" emissions.
本发明制备的再生纸相对于传统的造纸方法制备的纸张具有更好的保水性,可塑造性以及更高的韧性,而且本发明方法为无废水产生的造纸流程,本发明的造纸方法绿色、环保。Compared with the paper prepared by the traditional papermaking method, the recycled paper prepared by the present invention has better water retention, moldability and higher toughness, and the method of the present invention is a papermaking process without waste water generation. The papermaking method of the present invention is green, Environmental protection.
发明内容Summary of the invention
本发明的目的是针对现有利用废纸制备再生纸的制备方法和制备再生纸存在的技术问题,提供一种再生纸及其制备方法,本发明方法为新型的无水造纸方法,以废弃纸张为原料,粉碎的同时脱除废纸的油墨,制成去除油墨的絮状干纤维后与胶黏剂混合,制成新的纸张,本发明方法提供了一种新的造纸思路,解决了造纸行业 水污染和废纸浪费的问题,本发明的废纸原料来源广泛,制备的纸张价格低廉,制备耗时少,废纸可以重复利用,减少了树木材料的使用,环保便捷。生产各种纸制品的过程中使用少量水,减少了传统造纸的打浆,排废等一系列重污染过程,实现了真正意义上的绿色印刷,清洁造纸,无污造纸的工艺流程和工艺效果。The purpose of the present invention is to provide a kind of recycled paper and its preparation method in view of the existing preparation method of using waste paper to prepare recycled paper and the technical problem of preparing recycled paper. The method of the present invention is a new type of anhydrous papermaking method to discard paper As raw materials, the ink of the waste paper is removed at the same time of crushing, and the flocculent dry fiber to remove the ink is prepared and mixed with the adhesive to make a new paper. The method of the present invention provides a new papermaking idea and solves the papermaking Due to the problems of water pollution and waste paper waste in the industry, the waste paper raw materials of the present invention have a wide range of sources, the prepared paper is cheap, the preparation time is less, the waste paper can be reused, the use of tree materials is reduced, and environmental protection is convenient. A small amount of water is used in the production of various paper products, which reduces the series of heavy pollution processes such as beating and waste disposal of traditional papermaking, and realizes the true green printing, clean papermaking, and pollution-free papermaking process and process effects.
为实现本发明的目的,本发明一方面提供一种造纸方法,包括如下步骤:In order to achieve the purpose of the present invention, one aspect of the present invention provides a papermaking method, including the following steps:
1)将废弃纸张同时进行粉碎、脱墨处理,制成去除印刷油墨的絮状干纤维;1) The waste paper is crushed and deinked at the same time to make flocculent dry fiber to remove printing ink;
2)向絮状干纤维中喷洒造纸用胶黏剂溶液,制成纸纤维-胶黏剂混合物;2) Spray the papermaking adhesive solution into the flocculent dry fiber to make a paper fiber-adhesive mixture;
3)对纸纤维-胶黏剂混合物依次进行压制处理和干燥处理,即得。3) Pressing and drying the paper fiber-adhesive mixture in sequence, that's it.
其中,步骤1)中所述絮状干纤维的长度≥1.0mm,优选为1.0-1.2mm。Wherein, the length of the flocculent dry fiber in step 1) is ≥ 1.0 mm, preferably 1.0-1.2 mm.
其中,在废弃纸张粉碎的同时进行脱墨处理,制得去除油墨的絮状干纤维。Among them, the deinking treatment is carried out at the same time as the waste paper is crushed to prepare the flocculent dry fiber from which the ink is removed.
特别是,所述粉碎脱墨处理为将废弃纸张粉碎成絮状干纤维,在粉碎的同时将废弃纸张的油墨脱除,制得去除了印刷油墨的絮状干纤维。In particular, the pulverization and deinking treatment is to pulverize waste paper into flocculent dry fibers, and at the same time pulverize, remove the ink from the waste paper to produce flocculent dry fibers from which printing ink has been removed.
其中,采用粉碎脱墨机对废弃纸张进行所述的粉碎、脱墨处理。Among them, the crushing and deinking process is performed on the waste paper by using a crushing and deinking machine.
特别是,所述粉碎脱墨机包括:机壳;安装在机壳上的用于将进入机壳内的废纸切割成纸片的粗粉碎组件;安装在机壳上且位于粗粉碎组件下方的用于防止粗粉碎装置堵塞的冲纸组件;安装在机壳上且位于冲纸组件下方的用于将纸片粉碎成絮状纸屑并分离纸屑及纸屑上的油墨的粉碎脱墨组件;安装在机壳上且位于粉碎脱墨装置下方的收料组件,具有用于过滤絮状纸屑的滤网和位于滤网下方的用于筛分絮状纸屑的筛网。In particular, the crushing and deinking machine includes: a housing; a coarse crushing component installed on the housing for cutting waste paper into the housing; mounted on the housing and below the coarse crushing component A paper-washing assembly for preventing clogging of the coarse crushing device; a crushing and de-inking assembly installed on the casing and located below the paper-washing assembly for crushing the paper pieces into flocculent scraps and separating the scraps and the ink on the scraps ; The collecting assembly installed on the casing and located below the crushing and deinking device has a filter screen for filtering the flocculent paper dust and a screen for screening the flocculent paper dust located below the filter screen.
其中,所述粗粉碎组件包括:转动安装于所述机壳上且沿水平方向延伸的至少两根转轴;沿转轴的轴向间隔安装的多个切纸刀片;其中,相邻两根转轴上的切纸刀片错位设置。Wherein, the coarse crushing assembly includes: at least two rotating shafts which are rotatably mounted on the casing and extend in the horizontal direction; a plurality of paper cutting blades installed at intervals along the axial direction of the rotating shaft; wherein, two adjacent rotating shafts The cutting blades are misaligned.
特别是,粗粉碎组件将废纸粉碎成尺寸为(1-5)mm×(1-5)mm的碎纸片,碎纸片的尺寸优选为5mm×5mm。In particular, the coarse crushing module crushes the waste paper into shredded paper pieces having a size of (1-5) mm×(1-5) mm, and the size of the shredded paper pieces is preferably 5 mm×5 mm.
其中,所述冲纸组件包括设置于所述机壳两侧的至少一对喷头。Wherein, the punching assembly includes at least one pair of nozzles disposed on both sides of the casing.
其中,所述粉碎脱墨组件包括:并排安装在所述机壳上且中心轴与所述转轴中心轴方向垂直的一对转子;环设于每个转子外壁的用于将所述纸片粉碎成絮状纸屑的多排锤片;与一对转子分别连接的用于驱动一对转子相向高速旋转以便分离絮状纸屑及纸屑上的油墨的旋转驱动机构。Wherein, the crushing and deinking assembly includes: a pair of rotors installed side by side on the casing and having a central axis perpendicular to the central axis of the rotating shaft; a ring provided on the outer wall of each rotor for crushing the paper sheet Multiple rows of hammers formed into flocculent scraps; a rotary drive mechanism connected to a pair of rotors to drive a pair of rotors to rotate at a high speed in order to separate the flocculent scraps and the ink on the scraps.
特别是,所述转子上的多排锤片分别包括沿转子的轴向间隔设置的多个锤片,且一对转子上的锤片错位设置。In particular, the multiple rows of hammers on the rotor respectively include a plurality of hammers arranged at intervals along the axial direction of the rotor, and the hammers on the pair of rotors are arranged in a misaligned manner.
尤其是,所述锤片为T形锤片。In particular, the hammer is a T-shaped hammer.
特别是,所述T形锤片包括沿所述转子的径向延伸的径向段和沿所述转子的切向延伸的切向段,径向段的内端固定安装于所述转子外壁。In particular, the T-shaped hammer piece includes a radial segment extending in the radial direction of the rotor and a tangential segment extending in the tangential direction of the rotor, and the inner end of the radial segment is fixedly mounted on the outer wall of the rotor.
尤其是,所述T型锤片的径向段与切向段的形状、尺寸相同。In particular, the radial section and the tangential section of the T-shaped hammer have the same shape and size.
特别是,一个转子上沿转子轴向排列的相邻两排T型锤片件的间隙为0.8-1.2cm,优选为1.0cm。In particular, the gap between two adjacent rows of T-shaped hammer pieces arranged on one rotor in the axial direction of the rotor is 0.8-1.2 cm, preferably 1.0 cm.
尤其是,所述T型锤片径向段沿转子轴向方向的宽度为0.6-1.5cm,优选为1.2cm。In particular, the width of the radial section of the T-shaped hammer piece in the axial direction of the rotor is 0.6-1.5 cm, preferably 1.2 cm.
特别是,一对转子上相对锤片的端头之间具有间隙为0.2-0.4cm,优选0.2mm,(通常为锤片为交错排列,不考虑间隙,但是纸张是易燃物,相对锤片间留有一定的间隙),即相对锤片的切向段端头之间的间隙为0.2-0.4cm,优选0.2mm(通常为锤片为交错排列,不考虑间隙,但是纸张是易燃物,相对锤片间留有一定的间隙)。In particular, there is a gap of 0.2-0.4cm, preferably 0.2mm, between the ends of the pair of rotors opposite the hammers, (usually the hammers are staggered, regardless of the gap, but the paper is flammable, the opposite hammers There is a certain gap between them), that is, the gap between the ends of the tangential section of the hammer is 0.2-0.4cm, preferably 0.2mm (usually the hammers are staggered, the gap is not considered, but the paper is flammable) , There is a certain gap between the opposite hammers).
特别是,粉碎脱墨处理过程中控制转子的转速≥3000rpm,优选为≥7000rpm,进一步优选为7000-15000rpm。In particular, the rotational speed of the control rotor during the crushing and deinking process is ≥3000 rpm, preferably ≥7000 rpm, and more preferably 7000-15000 rpm.
其中,所述收料组件的滤网的孔径为14-16目;所述筛网的孔径为16-20目,优选为16目。Wherein, the pore size of the filter screen of the collecting component is 14-16 mesh; the pore size of the screen is 16-20 mesh, preferably 16 mesh.
特别是,所述收料组件还包括:位于所述粉碎脱墨组件筛网下方的管道,和与与所述观点连接的用于将过滤后的絮状纸屑排出的鼓风机。In particular, the collecting assembly further includes: a pipe located below the screen of the crushing and deinking assembly, and a blower connected to the viewpoint for discharging the filtered flocculent paper dust.
特别是,还包括安装于所述机壳上且位于所述粗粉碎组件与所述粉碎脱墨组件之间的导料导向组件。In particular, it also includes a material guide assembly mounted on the casing and located between the coarse crushing assembly and the crushing deinking assembly.
尤其是,所述导料导向组件包括其顶部与所述机壳铰接的三角板或呈倒V形的倒V形挡片,且三角板或倒V形挡片的用于与机壳铰接的铰接边的延伸方向与所述粉碎脱墨组件的转子的中心轴方向平行。In particular, the material guide assembly includes a triangular plate or an inverted V-shaped flap with its top hinged to the casing, and a hinged edge of the triangular plate or inverted V-shaped flap for hinged with the casing The extending direction of is parallel to the direction of the central axis of the rotor of the crushing and deinking assembly.
特别是,所述粗粉碎组件的切纸刀片及所述机壳内壁分别涂覆有用于防止静电的防静电涂层。In particular, the paper cutting blade of the coarse crushing assembly and the inner wall of the cabinet are respectively coated with an antistatic coating for preventing static electricity.
其中,步骤2)中所述造纸用胶黏剂选择淀粉胶,优选为糯米胶。Wherein, the adhesive for papermaking mentioned in step 2) is starch glue, preferably glutinous rice glue.
特别是,所述造纸用胶黏剂溶液按照如下方法制备而成:将淀粉胶加入到蒸馏 水中,搅拌均匀,其中淀粉胶与蒸馏水的质量之比为1:14-20,优选为1:16。In particular, the adhesive solution for papermaking is prepared according to the following method: starch glue is added to distilled water and stirred evenly, wherein the mass ratio of starch glue to distilled water is 1:14-20, preferably 1:16 .
特别是,所述絮状干纤维与造纸用胶黏剂溶液的质量之比为100:0.5-1.2,优选为100:1。In particular, the mass ratio of the flocculent dry fiber to the adhesive solution for papermaking is 100:0.5-1.2, preferably 100:1.
其中,步骤3)中所述压制处理分为两次碾压,第一次碾压制成厚度为纸张成品厚度的1.2-1.8倍的纸张粗坯,优选为1.5倍厚度的纸张粗坯;第二次碾压为将经过第一次碾压的纸张粗坯碾压成水分含量为10-15%的纸张半成品。Wherein, the pressing process in step 3) is divided into two rollings, the first rolling is to produce a paper roughness 1.2-1.8 times thicker than the finished paper thickness, preferably a paper roughness 1.5 times thick; The second rolling is to roll the rough paper after the first rolling into a semi-finished paper with a moisture content of 10-15%.
特别是,采用2组碾压辊进行所述的两次碾压。In particular, two sets of rollers are used for the two rollings.
尤其是,第一次碾压过程中第一组碾压辊间的间隙为所得纸张厚度的1.2-1.8倍,优选为1.5倍。In particular, the gap between the first group of rollers during the first rolling process is 1.2-1.8 times the thickness of the resulting paper, preferably 1.5 times.
其中,所述干燥处理为将压制处理的纸张半成品干燥至含水率为7%-8%。Wherein, the drying process is to dry the pressed paper semi-finished product to a moisture content of 7%-8%.
特别是,所述干燥处理选择真空干燥处理,其中控制干燥温度为40-50℃;真空度为-0.0075~-0.1MPa。In particular, the drying process is selected to be a vacuum drying process, in which the drying temperature is controlled to be 40-50°C; the degree of vacuum is -0.0075 to -0.1 MPa.
特别是,所述干燥处理选择常压干燥,其中干燥温度为110℃—150℃,优选为120℃。In particular, the drying treatment selects atmospheric pressure drying, wherein the drying temperature is 110°C-150°C, preferably 120°C.
特别是,所述干燥处理选择UV光热干燥。In particular, UV drying is selected for the drying process.
与现有技术相比,本发明具有如下优点和好处:Compared with the prior art, the present invention has the following advantages and benefits:
1、本发明的再生纸制备方法,打破传统,直接将废弃纸张类物质粉碎成絮状,并在粉碎的过程中完成脱墨处理,是利用废纸制备再生纸领域不曾有过的创新性应用,使得造纸过程中无需用水脱墨,不会对环境产生污染,且简化废纸造纸工艺。1. The method for preparing recycled paper of the present invention breaks the tradition, directly crushes waste paper materials into flocculent form, and completes deinking treatment in the crushing process. It is an innovative application that has never been used in the field of recycled paper preparation. , So that no deinking of water is needed in the papermaking process, no pollution to the environment, and the waste papermaking process is simplified.
2、相比于现有技术中的废纸温水浸涨后被重新打成纸浆,采用本发明方法消除了废纸残存油墨对再生纸质量的影响,在造纸过程中既不会产生废浆废液,又提高再生纸质量,符合我国保护环境的绿色生产之路。2. Compared with the waste paper in the prior art which is swollen with warm water and then re-beated into pulp, the method of the present invention eliminates the effect of the residual ink on the waste paper on the quality of the recycled paper, and no waste pulp waste will be generated in the papermaking process Liquid, and improve the quality of recycled paper, in line with China's green production road to protect the environment.
3、本发明中使用粉碎脱墨机将纸片粉碎成絮状纸屑,并使纸张上的油墨与纸纤维脱离,从而不需采用温水浸泡纸屑添加化学药剂以进行脱墨处理的工序,从而不会因废液对环境造成污染。3. In the present invention, a crushing and deinking machine is used to crush the paper into flocculent paper dust, and the ink on the paper is detached from the paper fiber, so that there is no need to use warm water to soak the paper dust and add chemicals to perform the deinking process. No pollution to the environment due to waste liquid.
4、本发明使用脱墨粉碎机粉碎废纸,其T形锤片缓解了机壳内空气环流的速度,减小了对轻细絮状纸屑的影响,提高了粉碎效率。4. The present invention uses a deinking crusher to crush waste paper. Its T-shaped hammers ease the speed of air circulation in the casing, reduce the impact on light and fine flocculent paper scraps, and improve the crushing efficiency.
5、本发明的再生纸制备方法,可对废纸原地回收与再制造,耗时少,价格低, 可以重复利用废纸,减少对树木材料的使用,环保便捷,且制造再生纸的过程为无水再生纸,减少了传统造纸的打浆、排废等一系列重污染过程,实现了绿色印刷,清洁造纸,利于保护生态环境,且减化造纸工艺流程。5. The method for preparing recycled paper of the present invention can recycle and remanufacture waste paper in situ, which consumes less time and has a lower price. It can reuse waste paper and reduce the use of tree materials. It is environmentally friendly and convenient, and the process of manufacturing recycled paper For waterless recycled paper, a series of heavy pollution processes such as beating and waste disposal of traditional papermaking are reduced, green printing is achieved, papermaking is clean, it is beneficial to protect the ecological environment, and the papermaking process is reduced.
6、本发明造纸过程中杜绝了水的使用,省略了打浆过程,实现了零污染和零排放;而且制备的再生纸可用来制造纸板和纸箱;包装纸袋;新闻用纸等产品。6. The papermaking process of the present invention eliminates the use of water, omits the beating process, and achieves zero pollution and zero emissions; and the prepared recycled paper can be used to manufacture cardboard and carton; packaging paper bags; newsprint and other products.
7、本发明的再生纸由废纸制作,其中原料的80%来源于回收的废纸。由于在制造再生纸的过程中不需添加任何增白剂、荧光剂等化学品,所以可更显现出纸张的本色,且由于制作的再生纸不反光,更有利于保护视力。另外,在制造过程中不需用水进行脱墨处理,减少废液的产生,减少对环境的污染,也降低了对树木的消耗,有利于生态环境的保护。7. The recycled paper of the present invention is made from waste paper, in which 80% of the raw materials come from recycled waste paper. Since there is no need to add any whitening agent, fluorescent agent and other chemicals in the process of manufacturing recycled paper, it can more show the true color of the paper, and because the recycled paper produced is not reflective, it is more conducive to protecting eyesight. In addition, no deinking treatment is needed for water in the manufacturing process, reducing the generation of waste liquid, reducing environmental pollution, and reducing the consumption of trees, which is conducive to the protection of the ecological environment.
附图说明BRIEF DESCRIPTION
图1为本发明再生纸制备的工艺流程图;Figure 1 is a process flow diagram of the preparation of recycled paper of the present invention;
图2为本发明的粉碎脱墨机的一种结构示意图;2 is a schematic structural view of a crushing and deinking machine of the present invention;
图3为本发明的粉碎脱墨机的两根转轴上切纸刀片的相对位置示意图;3 is a schematic diagram of the relative position of the cutting blades on the two rotating shafts of the crushing and deinking machine of the present invention;
图4是本发明的粉碎脱墨机的喷头安装于机壳上的示意图;4 is a schematic view of the nozzle of the crushing and deinking machine of the present invention installed on the casing;
图5是本发明的粉碎脱墨机的一对转子及转子上设置锤片的结构示意图;5 is a schematic structural view of a pair of rotors of the crushing and deinking machine of the present invention and the rotors provided with hammers;
图6是本发明的粉碎脱墨机的另一种结构示意图;6 is another schematic structural view of the crushing and deinking machine of the present invention;
图7为采用本发明粉碎脱墨机对废纸进行粉碎-脱墨处理的流程图。7 is a flow chart of the crushing and deinking process of waste paper by using the crushing and deinking machine of the present invention.
具体实施方式detailed description
下面结合附图和具体实施方式对本发明作进一步详细的描述,本发明的优点和特点将会随着描述而更为清楚。但这些实施例仅是范例性的,并不对本发明的范围构成任何限制。本领域技术人员应该理解的是,本发明的实施方式不限于此,在不偏离本发明的精神和范围下可以对本发明技术方案的细节和形式进行修改或替换,但这些修改和替换均落入本发明的保护范围内。The present invention will be described in further detail with reference to the accompanying drawings and specific embodiments. The advantages and features of the present invention will become more clear as the description proceeds. However, these examples are only exemplary and do not limit the scope of the present invention. Those skilled in the art should understand that the embodiments of the present invention are not limited to this, and the details and forms of the technical solutions of the present invention can be modified or replaced without departing from the spirit and scope of the present invention, but these modifications and replacements all fall within Within the protection scope of the present invention.
下述实施例中所使用的实验方法如无特殊说明,均为常规方法。Unless otherwise specified, the experimental methods used in the following examples are conventional methods.
下述实施例中所用的材料、试剂、设备、仪器等,如无特殊说明,均可从商业途径得到。本发明实施例中废纸来源于废纸回收站。Unless otherwise specified, the materials, reagents, equipment, and instruments used in the following examples can be obtained from commercial sources. In the embodiment of the present invention, the waste paper comes from a waste paper recycling station.
如图1,本发明再生纸制备流程:首先将收集的废弃纸张用粉碎脱墨机进行粉碎和脱墨处理,经过过滤和筛分制得絮状干纤维,接着向絮状干纤维中喷洒造纸用胶黏剂,制得絮状纤维-胶黏剂混合物;然后对絮状纤维-胶黏剂混合物依次进行碾压处理和干燥处理,制得再生纸。As shown in Figure 1, the preparation process of recycled paper of the present invention: firstly, the collected waste paper is crushed and deinked by a crushing and deinking machine, and the flocculent dry fiber is prepared by filtration and sieving, and then the papermaking is sprayed into the flocculent dry fiber Using an adhesive, a flocculent fiber-adhesive mixture is prepared; then the flocculent fiber-adhesive mixture is sequentially rolled and dried to obtain a recycled paper.
如图2,本发明的粉碎脱墨机包括:机壳;安装在机壳上的用于将进入机壳内的废纸切割成纸片的粗粉碎组件1;安装在机壳上且位于粗粉碎组件1下方的用于防止粗粉碎组件1堵塞的冲纸组件4;安装在机壳上且位于冲纸组件4下方的用于将纸片粉碎成絮状纸屑并分离纸屑及纸屑上的油墨的粉碎脱墨组件7;安装在机壳上且位于粉碎脱墨组件7下方的收料组件10,具有用于过滤絮状纸屑的滤网9和位于滤网下方的用于筛分絮状纸屑的筛网11。As shown in FIG. 2, the crushing and deinking machine of the present invention includes: a casing; a coarse pulverizing assembly 1 installed on the casing for cutting waste paper into the casing; mounted on the casing and located in the coarse Punching assembly 4 below the crushing assembly 1 for preventing the clogging of the coarse crushing assembly 1; installed on the cabinet and below the punching assembly 4 for crushing the paper pieces into flocculent scraps and separating the scraps and scraps The crushing and deinking assembly 7 of the ink; the receiving assembly 10 installed on the casing and located below the crushing and deinking assembly 7, has a filter screen 9 for filtering the flocculent paper dust and a filter screen for filtering the floc under the filter screen状纸碎的Screen网 11.
其中,机壳包括:粗粉碎室壳体,为呈筒状的上筒形壳体13,其上部开设有用于供废纸进入的进纸口;粉碎脱墨室壳体,包括:其顶部与筒形壳体13底部连接的上窄、下宽的上锥形壳体14、其顶部与上锥形壳体14底部连接的下筒形壳体15、其顶部与下筒形壳体15底部连接的上宽、下窄的下锥形壳体16,其中,收料装置10的管道12与下锥形壳体16的底部连接,设计时,可在下筒形壳体15的出口处设置可打开或关闭出口的挡料板(图中未示出)。Among them, the casing includes: a coarse crushing chamber casing, which is a cylindrical upper cylindrical casing 13, and a paper inlet for waste paper is opened at an upper portion thereof; a crushing and deinking chamber casing includes: The upper narrow, lower wide upper conical shell 14 connected to the bottom of the cylindrical shell 13, the lower cylindrical shell 15 whose top is connected to the bottom of the upper conical shell 14, the top thereof and the bottom of the lower cylindrical shell 15 Connected upper wide and lower narrow lower conical shell 16, wherein the pipe 12 of the receiving device 10 is connected to the bottom of the lower conical shell 16, in design, it can be set at the outlet of the lower cylindrical shell 15 Open or close the outlet baffle (not shown).
粗粉碎组件1安装在机壳的上筒形壳体13内,其包括:转动安装于上筒形壳体13内且沿水平方向延伸的至少两根转轴2;沿转轴的轴向间隔安装在转轴上的多个切纸刀片3;其中,相邻两根转轴上的切纸刀片错位设置。此外,还包括安装在上筒形壳体内的与转轴连接的用于驱动转轴旋转的驱动机构,该驱动机构可以采用电机驱动齿轮组的机构,也可以采用现有技术的其它机构,在此不对其结构进行描述。The coarse crushing assembly 1 is installed in the upper cylindrical casing 13 of the casing, which includes: at least two rotating shafts 2 which are rotatably installed in the upper cylindrical casing 13 and extend in the horizontal direction; A plurality of paper cutting blades 3 on the rotating shaft; among them, the paper cutting blades on the two adjacent rotating shafts are arranged in a misaligned manner. In addition, it also includes a driving mechanism installed in the upper cylindrical housing and connected to the rotating shaft for driving the rotating shaft to rotate. The driving mechanism may use a motor to drive a gear set mechanism or other mechanisms in the prior art, which is not correct here. Its structure is described.
应用时,在上筒形壳体13内安装的转轴可以为两根,也可以为多根,本发明具体实施方式中以采用互相平行的两根转轴2为例对结构进行说明。In application, there may be two or more rotating shafts installed in the upper cylindrical housing 13. In the specific embodiment of the present invention, two parallel rotating shafts 2 that are parallel to each other are used as an example to describe the structure.
两根转轴2上分别间隔安装有多个切纸刀片3(图2中,一根转轴上安装5个切纸刀片,另一根转轴上安装4个切纸刀片),切纸刀片3呈圆盘形,外边缘沿周向均设切齿,如图3所示,且两根转轴上的切纸刀片之间的中心距小于两个切纸刀片最外缘的直径。装配时,为避免两根转轴上的切纸刀片发生干涉,两根转轴上的切纸刀片沿各自转轴的轴向错位设置,即,从一对转轴的轴向来看,两根转轴中的一根转轴上的切纸刀片位于另一根转轴的两个切纸刀片之间。A plurality of cutting blades 3 are installed on the two rotating shafts 2 at intervals (in FIG. 2, five cutting blades are installed on one rotating shaft and four cutting blades are installed on the other rotating shaft), and the cutting blades 3 are round Disc-shaped, the outer edges are provided with cutting teeth along the circumferential direction, as shown in Figure 3, and the center distance between the cutting blades on the two rotating shafts is smaller than the diameter of the outermost edges of the two cutting blades. When assembling, in order to avoid the interference of the paper cutting blades on the two rotating shafts, the paper cutting blades on the two rotating shafts are misaligned along the axial direction of the respective rotating shafts, that is, from the axial view of a pair of rotating shafts, the The cutting blade on one shaft is located between the two cutting blades on the other shaft.
在上筒形壳体13的进料口下方设置粗粉碎组件1,当废弃纸张(即废纸)由进料口投入后,在粗粉碎组件切纸刀片的作用下废纸将被切成碎纸片((1-5)mm×(1-5)mm,优选为5mm×5mm),从而利于接下来通过粉碎脱墨装置7对纸片进行二次粉碎处理,提高生产效率。A coarse crushing assembly 1 is provided below the feed opening of the upper cylindrical housing 13, and when waste paper (ie, waste paper) is thrown in through the feed opening, the waste paper will be shredded under the action of the cutting blade of the coarse crushing assembly The paper sheet ((1-5) mm×(1-5) mm, preferably 5 mm×5 mm) is advantageous for the next crushing of the paper sheet by the crushing and deinking device 7 to improve production efficiency.
当通过切纸刀片将废纸切割成纸片后,为防止切成的纸片堵塞切纸刀片,在粗粉碎组件下方设置用于防止粗粉碎组件堵塞的冲纸组件4,冲纸组件包括设置于上筒形壳体内壁两侧的至少一对喷头42,且一对喷头的出风口倾斜向上相对设置,分别对准两根转轴或两根转轴之间的位置,如图2。After the waste paper is cut into pieces by the cutting blade, in order to prevent the cut pieces of paper from clogging the cutting blade, a punching assembly 4 for preventing clogging of the coarse crushing assembly is provided below the coarse crushing assembly. At least one pair of spray heads 42 on both sides of the inner wall of the upper cylindrical housing, and the air outlets of the pair of spray heads are arranged to face each other obliquely upward, and are respectively aligned with the two rotating shafts or the positions between the two rotating shafts, as shown in FIG. 2.
如图4,喷头42由带有弹性的材料制成,外面卡装有喷头壳41,喷头壳通过螺栓安装于上筒形壳体的内壁,喷头的进风口与设于上筒形壳体上的小型吹风机(包括电动机和风叶)的出风口连通。在粗粉碎组件将废纸切成纸片后,使吹风机通电,其电动机带动风叶旋转产生一定强度的气流,气流经由喷头的进风口进入、再由出风口斜向上吹出,从而通过气流吹起切成的纸片,防止切纸刀片堵塞。As shown in FIG. 4, the spray head 42 is made of a material with elasticity, and the spray head shell 41 is clamped on the outside, and the spray head shell is installed on the inner wall of the upper cylindrical shell by bolts, and the air inlet of the spray head is provided on the upper cylindrical shell The air outlet of the small hair dryer (including motor and fan blade) is connected. After the coarse crushing component cuts the waste paper into paper pieces, the blower is energized, and its motor drives the fan blades to generate a certain intensity of airflow. The airflow enters through the air inlet of the nozzle and is blown out diagonally upward from the air outlet, so that Cut into pieces of paper to prevent the cutting blade from clogging.
被粗粉碎组件切成的纸片在重力作用下在上筒形壳体内向下掉落至粉碎脱墨组件的壳体内,以便通过其内的粉碎脱墨组件7对纸片进行二次粉碎处理及脱墨处理。The paper sheet cut by the coarse crushing assembly falls down into the shell of the crushing and deinking assembly under the action of gravity, so that the crushing and deinking assembly 7 can perform secondary crushing treatment on the paper sheet And deinking treatment.
其中,粉碎脱墨组件7的一部分安置于上锥形壳体14内、另一部分安置于下筒形壳体15内,便于全面接收上筒形壳体向下掉落的纸片,充分防止纸片堵塞上筒形壳体。Among them, a part of the crushing and deinking assembly 7 is placed in the upper conical shell 14 and the other part is placed in the lower cylindrical shell 15 to facilitate the overall reception of the paper pieces falling down from the upper cylindrical shell to fully prevent paper The piece clogs the upper cylindrical housing.
如图2,粉碎脱墨组件7包括:并排安装在上锥形壳体14和下筒形壳体15连接的水平位置处的一对转子8,转子8的中心轴与转轴2的中心轴异面垂直;环设于每个转子外壁的用于将纸片粉碎成絮状纸屑的多排锤片6;与一对转子分别连接的用于驱动一对转子相向高速旋转以便分离絮状纸屑及纸屑上的油墨的旋转驱动机构(图中未示出),该旋转驱动机构可以采用现有技术的旋转机构,如电机驱动的机构,将其输出动力分别传递给一对转子,使一对转子相向旋转,例如使图2中的位于左边的转子顺时针方向旋转,使位于右边的转子逆时针方向旋转,从而通过锤片6将纸片粉碎成絮状纸屑。As shown in FIG. 2, the crushing and deinking assembly 7 includes: a pair of rotors 8 installed side by side at a horizontal position where the upper conical housing 14 and the lower cylindrical housing 15 are connected, and the central axis of the rotor 8 is different from the central axis of the rotating shaft 2 The surface is vertical; the multiple rows of hammers 6 that are placed on the outer wall of each rotor to crush the paper into flocculent scraps; connected to a pair of rotors respectively to drive a pair of rotors to rotate at a high speed to separate the flocculent scraps and A rotary drive mechanism for ink on paper scraps (not shown in the figure). The rotary drive mechanism can use a prior-art rotary mechanism, such as a motor-driven mechanism, to transmit its output power to a pair of rotors, respectively. The rotors rotate toward each other, for example, the rotor on the left in FIG. 2 rotates clockwise, and the rotor on the right rotates counterclockwise, so that the hammer 6 crushes the paper into fluffy paper dust.
如图2、4,本发明实施例中转子的外壁沿周向固定安装有多排锤片(本实施例为四排锤片),每排锤片包括沿转子的轴向间隔设置的多个锤片。一对转子上的锤片错位设置,且一对转子上相对锤片的端头之间具有间隙,如图5,即两个转子的锤 片的锤头端面到轴心的距离之和小于两个转子的轴心之间的距离,防止两个转子在高速旋转粉碎纸片的过程中可能发生振动,一对转子上的锤片会产生机械碰撞,一对转子上相对锤片的端头之间具有间隙为0.2-0.4cm,优选0.2mm,(通常为锤片为交错排列,不考虑锤头间隙,但是纸张是易燃物,相对锤头间留有一定的间隙),即相对锤片的切向段端头之间的间隙为0.2-0.4cm,优选0.2mm(通常为锤片为交错排列,不考虑间隙,但是纸张是易燃物,相对锤头间留有一定的间隙)。As shown in Figures 2 and 4, multiple rows of hammers are fixedly installed on the outer wall of the rotor in the embodiment of the present invention (four rows of hammers in this embodiment), each row of hammers includes a plurality of spaced apart along the axial direction of the rotor Hammer. The hammers on a pair of rotors are misaligned, and there is a gap between the ends of opposite rotors on a pair of rotors, as shown in Figure 5, that is, the sum of the distances from the end faces of the hammers of the two rotors to the axis is less than two The distance between the axes of the two rotors prevents the two rotors from vibrating during the high-speed rotation and crushing of the paper. The hammers on the pair of rotors will cause mechanical collisions, and the ends of the pair of rotors opposite the hammers There is a gap of 0.2-0.4cm, preferably 0.2mm, (usually the hammers are staggered, regardless of the hammer head gap, but the paper is flammable, and there is a certain gap between the hammer heads), that is, the relative hammer The gap between the ends of the tangential section is 0.2-0.4cm, preferably 0.2mm (usually the hammers are staggered, regardless of the gap, but the paper is flammable, and there is a certain gap between the hammers).
锤片采用T形锤片,包括沿转子的径向延伸的径向段和沿转子的切向延伸的切向段,径向段的内端固定安装于转子外壁,切向段的中心与径向段的外端固定连接。采用T形锤片,在粉碎纸片的过程中可以减少形成的絮状纸屑的外漏,从而防止絮状纸屑对转子、电机等造成损害。并且,采用一对转子带动T形锤片高速旋转,可将废纸条粉碎成脱墨的絮状纸屑,缓解了粉碎脱墨室内空气环流的速度,减小了对轻细纸屑的影响,提高粉碎效率,极大地提高生产效率,提高产品质量,打破传统废纸回收方法,是在粉碎机领域甚至废纸再利用领域不曾有过的创新性应用。The hammer adopts T-shaped hammer, which includes a radial segment extending in the radial direction of the rotor and a tangential segment extending in the tangential direction of the rotor. The inner end of the radial segment is fixedly installed on the outer wall of the rotor. The center and diameter of the tangential segment Connect to the outer end of the segment. The use of T-shaped hammer blades can reduce the leakage of the formed flocculent scraps in the process of crushing the papers, thereby preventing the flocculent scraps from damaging the rotor and the motor. In addition, the use of a pair of rotors to drive the T-shaped hammer blades to rotate at high speed can crush the waste paper strips into deinked flocculent paper scraps, alleviating the speed of air circulation in the crushing and deinking chamber, and reducing the impact on light and fine paper scraps. Improving crushing efficiency, greatly improving production efficiency, improving product quality, and breaking the traditional waste paper recycling method are innovative applications that have never been used in the field of shredders or even waste paper recycling.
同一转子上沿轴向的相邻两个锤片之间的间距为0.8-1.2cm,优选为1cm。T型锤片的径向段与切向段的形状、尺寸相同;并且T型锤片径向段沿转子轴向方向的宽度为0.6-1.5cm,优选为1.2cm。转子的转速≥3000rpm,优选为≥7000rpm,进一步优选为7000-15000rpm。The distance between two adjacent hammers on the same rotor in the axial direction is 0.8-1.2 cm, preferably 1 cm. The radial section of the T-shaped hammer piece has the same shape and size as the tangential section; and the width of the radial section of the T-shaped hammer piece in the axial direction of the rotor is 0.6-1.5 cm, preferably 1.2 cm. The rotation speed of the rotor is ≥3000 rpm, preferably ≥7000 rpm, and more preferably 7000-15000 rpm.
经粗粉碎组件粉碎后的废纸碎片流入到粉碎脱墨组件后,粉碎脱墨组件7的旋转机构带动转子和T形锤片高速转动切割纸片,通过锤片与纸片的高速撞击将纸片粉碎成絮状纸屑(尺寸范围≥1.0mm,优选为1.1-1.2mm),与此同时,废纸条上的油墨在T形锤片的击打下被剥离,在转子与T形锤片高速转动的离心力的作用下,油墨实现与纸张的分离(转子的转速≥3000rpm)。由于油墨自身的质量大于纸屑的质量而在离心力作用被甩在上锥形壳体、下筒形壳体的内壁上或残留在T形锤片上,纸屑在重力作用下向下掉落。当掉落至下筒形壳体15内的絮状干纤维物质(即絮状纸屑)积累一定量时,挡料板打开,纸屑经由收料组件10收集及排出,而甩至上锥形壳体、下筒形壳体的内壁上的油墨可采用人工定期处理。After the waste paper fragments crushed by the coarse crushing component flow into the crushing and deinking component, the rotating mechanism of the crushing and deinking component 7 drives the rotor and the T-shaped hammer to rotate and cut the paper at high speed, and the paper is crushed by the high speed impact of the hammer and the paper The flakes are crushed into flocculent scraps (size range ≥ 1.0mm, preferably 1.1-1.2mm), at the same time, the ink on the waste paper strip is peeled off under the impact of the T-shaped hammer, and the rotor and T-shaped hammer are high-speed Under the action of rotating centrifugal force, the ink is separated from the paper (rotor speed ≥3000rpm). Because the mass of the ink itself is greater than the mass of the paper scraps, the centrifugal force is thrown on the inner wall of the upper conical shell, the lower cylindrical shell or remains on the T-shaped hammer, and the paper scraps fall down under the action of gravity. When the flocculent dry fiber material (ie, flocculent scraps) dropped into the lower cylindrical housing 15 accumulates a certain amount, the baffle plate is opened, and the scraps are collected and discharged through the collecting assembly 10, and thrown to the upper conical shell The ink on the inner wall of the body and the lower cylindrical shell can be periodically processed manually.
而现有的废纸回收利用处理过程中,采用纸张打浆进行脱墨,本发明采用粉碎脱墨部,直接将废纸处理成脱墨的絮状纸屑,无需进行纸张打浆,从而减少利用废纸进行造纸的工艺步骤,且由于无纸张打浆过程,不会产生大量废浆废液,避免对 环境造成的污染。In the existing waste paper recycling process, paper beating is used for deinking. The present invention uses a crushing deinking section to directly process waste paper into deinked flocculent scraps, eliminating the need for paper beating, thereby reducing the use of waste paper The papermaking process steps are carried out, and because there is no paper beating process, a large amount of waste pulp and waste liquid will not be generated, thereby avoiding pollution to the environment.
由于两个转子高速旋转粉碎纸片,在一对转子的相对T形锤片之间会形成没有挤压力作用的粉碎真空区,而为防止从粗粉碎室掉落的纸片掉入粉碎真空区内,在粗粉碎室与粉碎脱墨室之间设置有用于引导纸片掉落方向的导料导向组件5,该导料导向组件5包括其顶部与上筒形壳体和/或上锥形壳体铰接的呈倒V形的倒V形挡片(如图2所示),且倒V形挡片的用于与壳体铰接的铰接边的延伸方向与粉碎脱墨组件的转子的中心轴方向平行。Because the two rotors rotate to crush the paper at high speed, a crushing vacuum area without squeezing force will be formed between the opposing T-shaped hammers of a pair of rotors, and in order to prevent the paper falling from the coarse crushing chamber from falling into the crushing vacuum In the area, between the coarse crushing chamber and the crushing deinking chamber, a material guide assembly 5 for guiding the falling direction of the paper sheet is provided. The material guide assembly 5 includes its top and the upper cylindrical shell and/or upper cone The inverted V-shaped baffle of the reversed V-shaped baffle (as shown in FIG. 2) is hinged, and the extending direction of the hinged edge of the inverted V-shaped baffle used to be hinged with the housing and the rotor of the crushing deinking assembly The direction of the central axis is parallel.
倒V形挡片安装在一对转子正上方,经粗粉碎组件初碎后的纸片被引导着沿着倒V形板的斜坡进入粉碎脱墨室,避免落入一对转子之间的粉碎真空区,从而提高粉碎效率。The inverted V-shaped baffle is installed directly above the pair of rotors, and the paper after primary crushing by the coarse crushing assembly is guided along the slope of the inverted V-shaped plate into the crushing deinking chamber to avoid crushing falling between the pair of rotors Vacuum zone, which improves crushing efficiency.
本发明的导料导向组件5还可以采用三角板,如图6,三角板的顶部与上筒形壳体和/或上锥形壳体铰接,同样,三角板的用于与壳体铰接的铰接边的延伸方向与粉碎脱墨组件的转子的中心轴方向平行。The material guide assembly 5 of the present invention may also adopt a triangular plate. As shown in FIG. 6, the top of the triangular plate is hinged with the upper cylindrical shell and/or the upper conical shell. Similarly, the hinged edge of the triangular plate is used to hinge with the shell. The extending direction is parallel to the central axis direction of the rotor of the crushing deinking assembly.
采用三角板,除了可以引导纸片掉落至粉碎脱墨室内的方向外,其与顶部相对的底板还可以破坏纸片在转子作用下所形成的环形抛料环,防止纸片或纸屑与锤片产生相向运动,提高锤片对纸片或纸屑的打击效果,更利于纸片或纸屑上的油墨与纸张脱离。The use of a triangular plate, in addition to guiding the paper to the direction of crushing and deinking chamber, the bottom plate opposite to the top can also destroy the annular throwing ring formed by the paper under the action of the rotor, preventing paper or paper scraps and hammers The pieces produce opposite movement, which improves the hammer's impact on the paper or paper scraps, and is more conducive to the separation of the ink on the paper or paper scraps.
被粉碎脱墨组件7粉碎脱墨后的纸屑向下掉落,由收料组件10收集及排出。收料组件包括:安装在下筒形壳体15内且位于一对转子8下方的滤网9;位于滤网9下方的用于筛选纸屑的筛网11;用于将脱墨后的纸屑排出的管道12;与管道12连接的用于将筛选后掉落的纸屑排出的鼓风机(图中未示出)。The crushed and deinked paper dust from the crushing and deinking assembly 7 falls down and is collected and discharged by the collecting assembly 10. The receiving assembly includes: a screen 9 installed in the lower cylindrical housing 15 and below the pair of rotors 8; a screen 11 below the screen 9 for screening paper dust; and a paper dust for deinking Discharged duct 12; a blower (not shown in the figure) connected to the duct 12 for discharging the paper dust that has fallen out after screening.
滤网9为具有与一对转子8外轮廓相适配弧形的弧形滤网,滤网周边固定于下筒形壳体15的内壁,通过滤网9过滤由粉碎脱墨组件粉碎脱墨后形成的絮状纸屑,使尺寸小于或等于网孔直径的纸屑透过滤网下落至筛网上,而尺寸大于滤网网孔直径的纸屑被一对转子及转子上的T形锤片重复粉碎,在粉碎纸条的过程中,滤网也起到对纸条搓擦、剪切的作用,滤网的孔径为14-16目;同时需要控制转子上锤片的切向段与滤网之间的间隙为≤8mm,优选为6-8mm,进一步优选为8mm),纸张较轻,不易下落,在粉碎过程中。The filter screen 9 is an arc filter screen with an arc shape adapted to the outer contours of the pair of rotors 8, the periphery of the filter screen is fixed to the inner wall of the lower cylindrical housing 15, and the filter 9 is filtered and crushed and deinked by the crushing and deinking assembly The resulting flocculent paper dust causes paper dust with a size smaller than or equal to the mesh diameter to fall through the filter onto the screen, and paper dust with a size larger than the diameter of the filter mesh is repeated by a pair of rotors and T-shaped hammers on the rotor Crushing, in the process of crushing the paper strip, the filter screen also plays the role of rubbing and shearing the paper strip, the pore size of the filter screen is 14-16 mesh; at the same time, it is necessary to control the tangential section of the hammer on the rotor and the filter screen The gap between them is ≤8mm, preferably 6-8mm, further preferably 8mm), the paper is lighter and not easy to fall during the crushing process.
筛网固定于下筒形壳体15与下锥形壳体16的连接处,筛网孔径为16-20目。 选取筛网的孔径时,应根据实际情况选取,以防止纸条碎成的絮状纸屑堵塞筛孔。若粉碎脱墨室下方设置挡板,则挡板可安置于筛网的上方、滤网的下方,或者,挡板可安置于筛网的下方。当纸片被粉碎完成后,将挡板打开,使纸屑向下掉落到下锥形壳体16内,并在鼓风机(图中未示出)的作用下将纸屑通过管道12抽走以完成排料。The screen is fixed to the connection between the lower cylindrical shell 15 and the lower conical shell 16, and the screen aperture is 16-20 mesh. When selecting the aperture of the screen, it should be selected according to the actual situation to prevent the flocculent scraps of paper strips from clogging the screen. If a baffle plate is provided below the crushing and deinking chamber, the baffle plate can be placed above the screen, under the filter screen, or the baffle plate can be placed under the screen. After the paper pieces are crushed, the baffle is opened to allow the paper scraps to fall down into the lower conical shell 16, and the paper scraps are drawn away through the duct 12 under the action of a blower (not shown) To complete the layout.
设计时,粗粉碎组件的切纸刀片及机壳的内壁可以分别涂覆有用于防止静电的防静电氟涂层,以免纸片或纸屑粘覆于机壳内壁,最大限度地减小了纸料粘黏现象。此外,还可以在机壳内壁涂敷耐磨材料以降低设备工作时的噪音。During design, the cutting blade of the coarse crushing component and the inner wall of the cabinet can be coated with anti-static fluorine coating to prevent static electricity, so as to prevent paper pieces or paper scraps from sticking to the inner wall of the cabinet and minimize the paper Material sticky phenomenon. In addition, wear-resistant materials can also be coated on the inner wall of the cabinet to reduce the noise when the equipment is working.
需要说明的是,在造纸过程中喷洒造纸用胶黏剂施胶处理、碾压处理、烘干处理分别可采用现有技术中喷胶、碾压、烘干方法进行,故在此不对各处理方法、步骤进行详细描述。It should be noted that in the papermaking process, spraying papermaking adhesive sizing treatment, rolling treatment, and drying treatment can be carried out by spraying, rolling, and drying methods in the prior art, so each treatment is not carried out here. Methods and steps are described in detail.
使用粉碎脱墨机粉碎脱墨处理废纸制造再生纸的工作过程如下:The process of using a crushing and deinking machine to crush and deinking waste paper to make recycled paper is as follows:
1、废纸粉碎-脱墨处理1. Waste paper crushing-deinking treatment
如图7,将回收的废纸(如废旧办公用纸)经由进料口投入至两根转轴之间,通过一对转轴上错位安置的多个切纸刀片将废纸切成碎纸片,其中碎纸片的尺寸为((1-5)mm×(1-5)mm)。As shown in Figure 7, the recovered waste paper (such as waste office paper) is put between the two rotating shafts through the feed inlet, and the waste paper is cut into shredded paper pieces through a plurality of cutting blades arranged on a pair of rotating shafts, The size of the shredded paper is ((1-5) mm×(1-5) mm).
当废纸被切成若干细小纸片后,通过位于粗粉碎组件下方的冲纸组件对切纸刀片进行清理,以防止切纸刀片被细小纸片堵塞。After the waste paper is cut into several small pieces of paper, the paper cutting blade is cleaned by the paper punching assembly located below the coarse crushing assembly to prevent the cutting blade from being blocked by the small pieces of paper.
被粗粉碎组件处理的碎纸片在重力作用下掉落至粉碎脱墨组件内,通过粉碎脱墨组件进行再次粉碎与脱墨处理,处理过程中,转子和T形锤片(锤片即刀片,呈T形)高速转动切割纸片,通过锤片与纸片的高速撞击将纸片粉碎成絮状纸屑(即絮状干纤维物质),同时将油墨与纸片分离。The shredded paper pieces processed by the coarse crushing assembly drop into the crushing deinking assembly under the action of gravity, and then crushed and deinked again by the crushing deinking assembly. During the process, the rotor and the T-shaped hammer (the hammer is the blade) , T-shaped) high-speed rotation cutting paper, through the high-speed impact of the hammer and the paper to crush the paper into flocculent scraps (ie flocculent dry fiber material), while separating the ink from the paper.
经转子、T形锤片粉碎和脱墨处理的纸屑经过滤网过滤,筛网筛分后,收集1.0mm到1.2mm长度的絮状干纤维,制得脱墨絮状干纤维;粉碎-脱墨处理后的絮状干纤维物质积累一定量时,在鼓风机的作用下穿过筛网进入下锥形壳体(即存储仓)内,并通过管道排出,以对其进行下一步处理。The paper dust that has been crushed and deinked by the rotor and T-shaped hammer is filtered through a filter screen. After the screen is sieved, the flocculent dry fibers with a length of 1.0mm to 1.2mm are collected to prepare deinked flocculent dry fibers; crushed- When a certain amount of flocculent dry fiber material accumulates after deinking, it passes through the screen and enters the lower conical shell (that is, storage bin) under the action of the blower, and is discharged through the pipeline for further processing.
2、施胶处理2. Sizing treatment
向脱墨后的絮状干纤维中喷洒雾化的造纸用胶黏剂,并混合均匀,制成纤维- 胶黏剂混合物;Spray the atomized paper-making adhesive on the de-flocked dry fibers and mix them evenly to make a fiber-adhesive mixture;
3、压制处理3. Suppression processing
对纤维-胶黏剂混合物进行两次碾压处理,第一次碾压处理为粗压,使其初具纸张形态且微除水,第一次碾压处理过程中碾压厚度为纸张厚度的1.2-1.8倍(优选为1.5倍);第二碾压处理为精压,获得水分含量为10-15%的半成品纸,此时半成品纸张为暗白色。碾压过程中碾压滚筒的表面上涂装四氟乙烯涂料,防止粘粘。The fiber-adhesive mixture is rolled twice, the first rolling process is rough pressing, so that it initially takes the form of paper and slightly removes water, and the rolling thickness during the first rolling process is the thickness of the paper 1.2-1.8 times (preferably 1.5 times); the second rolling treatment is squeezing to obtain semi-finished paper with a moisture content of 10-15%, at this time the semi-finished paper is dark white. During the rolling process, the surface of the roller is coated with tetrafluoroethylene coating to prevent sticking.
4、烘干处理4. Drying treatment
将再生纸半成品进行烘干处理,通常采用高温干燥、真空干燥、UV光热干燥等方式进行烘干处理,获得再生纸成品。Drying the semi-finished recycled paper, usually by high temperature drying, vacuum drying, UV photothermal drying, etc., to obtain finished recycled paper.
本领域中现有的已知的纸张碾压处理方法均适用于本发明;用于纸张干燥的方式均适用于本发明。The paper rolling treatment methods known in the art are all applicable to the present invention; the methods used for drying the paper are all applicable to the present invention.
本发明的再生纸使用的原料为废弃纸张,采用本发明的粉碎脱墨机粉碎、脱墨处理之后还采用了16-20目的筛网对粉碎的纸屑进行筛分处理,收集1.0mm-1.2mm长度的絮状无油墨的干纤维。它降低了树木材料的使用,有利于保护生态环境。成型的絮状干纤维可应用于制造日常办公用纸:采用相关设备将废纸碎成絮状干纤维,喷雾状胶加以粘结,进而实现无水造纸。此造纸技术在制作过程中利用的是已经被使用的废纸,降低了树木材料的使用,有利于保护生态环境。The raw material used in the recycled paper of the present invention is waste paper. After being crushed and deinked by the crushing and deinking machine of the present invention, a 16-20 mesh screen is also used to sieve the crushed paper scraps and collect 1.0mm-1.2 mm-length flocculent inkless dry fiber. It reduces the use of tree materials and helps protect the ecological environment. The formed flocculent dry fiber can be used in the manufacture of daily office paper: using related equipment to crush the waste paper into flocculent dry fiber, and spray-type glue to bond, and then realize anhydrous papermaking. This papermaking technology uses waste paper that has been used in the production process, which reduces the use of tree materials and is beneficial to the protection of the ecological environment.
纸张半成品的干燥处理,去除纸张中的水分主要有三种水,一种是游离水,一种是纤维管中的水,还一种是结合水,碾压处理可以去掉部分游离水和纤维管中的水,剩下的水分通过烘干完成。Drying treatment of paper semi-finished products can remove three types of water from paper, one is free water, one is water in fiber tube, and the other is combined water. Rolling treatment can remove part of free water and fiber tube The remaining water is completed by drying.
实施例1Example 1
1、制备絮状干纤维1. Preparation of flocculent dry fiber
将废纸由再生纸粉碎脱墨机的进料口投入,在粉碎脱墨机的粗粉碎组件内进行初步粉碎,制成尺寸为5mm×5mm(通常为(1-5)mm×(1-5)mm)的碎纸片,接着在重力作用下进入粉碎脱墨组件,在转子和T型锤片的高速转动下切割碎纸片,通过锤片与纸片的高速撞击将纸片粉碎成絮状纸屑(即絮状干纤维物质),同时将油墨与纸片分离,进行脱墨处理,其中,控制转子的转速为8000rpm(通常≥7000rpm,优 选为7000-15000rpm);同一转子上沿转子轴向方向的相邻两排T型锤片件的间隙为1.0cm(通常为0.8-1.2cm);T型锤片的径向段与径向段的形状、尺寸相同,径向段沿着转子轴向方向的宽度为1.2cm(通常为0.6-1.5cm);一对转子上相对锤片的端头之间具有间隙为0.2cm(通常为0.2-0.4cm,通常由于锤片为交错排列,不考虑间隙,但是纸张是易燃物,相对锤片间留有一定的间隙),即相对锤片的切向段端头之间的间隙为0.2cm(通常为0.2-0.4cm,通常由于锤片为交错排列,不考虑间隙,但是纸张是易燃物,相对锤片间留有一定的间隙),同时需要控制转子上锤片的切向段与滤网之间的间隙为8mm(通常小于8mm,优选为6-8mm),纸张较轻,不易下落,在粉碎过程中。Put the waste paper from the feed port of the recycled paper crushing and deinking machine, and carry out preliminary crushing in the coarse crushing unit of the crushing and deinking machine to make the size 5mm×5mm (usually (1-5)mm×(1- 5) mm) shredded paper, then enter the crushing and deinking assembly under the action of gravity, cut the shredded paper under the high-speed rotation of the rotor and T-shaped hammer, and crush the paper into a high-speed impact of the hammer and the paper Flocculent paper dust (i.e., flocculent dry fiber material), at the same time, the ink is separated from the paper sheet, and deinking treatment is carried out, in which the rotor speed is controlled to 8000rpm (usually ≥7000rpm, preferably 7000-15000rpm); The gap between two adjacent rows of T-shaped hammer pieces in the axial direction is 1.0cm (usually 0.8-1.2cm); the radial section of the T-shaped hammer piece has the same shape and size as the radial section, and the radial section is along The width of the rotor in the axial direction is 1.2cm (usually 0.6-1.5cm); the gap between the ends of the pair of rotors on the opposite hammers is 0.2cm (usually 0.2-0.4cm, usually because the hammers are staggered) , The gap is not considered, but the paper is flammable, and there is a certain gap between the opposite hammers), that is, the gap between the ends of the tangential segments of the opposite hammers is 0.2cm (usually 0.2-0.4cm, usually because of The hammers are staggered and the gap is not considered, but the paper is flammable, and there is a certain gap between the hammers. At the same time, the gap between the tangential section of the hammers on the rotor and the filter screen needs to be controlled to 8mm (usually (Less than 8mm, preferably 6-8mm), the paper is light and not easy to fall, in the crushing process.
然后经过滤网(滤网孔径为14-16目)过滤,接着过孔径为16目(通常为16-20目)的筛网,对絮状纸屑进行筛分处理,制得长度为1.0-1.2mm(通常絮状干纤维的长度≥1.0mm,优选为1.0-1.2mm)的絮状废纸干纤维,备用;It is then filtered through a filter screen (the filter screen has a pore size of 14-16 mesh), then passes through a screen with a pore size of 16 mesh (usually 16-20 mesh), and the flocculent paper dust is sieved to obtain a length of 1.0-1.2 mm (usually the length of the flocculent dry fiber ≥ 1.0mm, preferably 1.0-1.2mm), the flocculent dry fiber of the waste paper, used;
絮状干纤维的好处在于对无水造纸流程中采用的水-淀粉胶雾状体系捕捉性良好。1.0mm是废纸纤维粘结长度的下限,因为絮状干纤维的重点在絮状上面,即在主干纤维上有很多软毛,可以对雾状的微小胶粒进行捕捉,基于表面积效应的原理(相同体积物质越分散,表面积越大),絮状干纤维越小,对胶粒捕捉性越好,所以采用1.0mm-1.2mm长度的纤维。The advantage of flocculent dry fiber is that it has a good capture of the water-starch glue mist system used in the anhydrous papermaking process. 1.0mm is the lower limit of the waste paper fiber bonding length, because the focus of the flocculent dry fiber is on the flocculent, that is, there are many soft hairs on the main fiber, which can capture the misty tiny colloidal particles, based on the principle of surface area effect (The more the same volume of material is dispersed, the greater the surface area), the smaller the flocculent dry fiber, the better the capture of colloidal particles, so 1.0mm-1.2mm length of fiber is used.
2、制备胶黏剂溶液2. Preparation of adhesive solution
将糯米胶加入到蒸馏水中,边加边搅拌,直至最终形成无明显块状物且形态均一、稳定的造纸用胶黏剂溶液(即糯米胶-水混合物),其中,糯米胶与水的质量之比为1:16(通常为1:14-20)然后将造纸用胶黏剂溶液倒入雾化瓶内,备用。Add glutinous rice glue to distilled water and stir until the final formation of a stable and stable paper-making adhesive solution (ie glutinous rice glue-water mixture) without obvious lumps, in which the quality of glutinous rice glue and water The ratio is 1:16 (usually 1:14-20) and then the paper-made adhesive solution is poured into the atomization bottle and set aside.
糯米胶属于淀粉胶,淀粉又分为两类,直链淀粉与支链淀粉,对于某一类淀粉胶来讲,支链淀粉的含量越高,其粘性就越强,而糯米胶中的支链淀粉含量在90%以上,在自然类淀粉胶中含量最高,且又环保。Glutinous rice glue belongs to starch glue, and starch is divided into two types, amylose and amylopectin. For a certain type of starch glue, the higher the content of amylopectin, the stronger the viscosity, and the stickiness in glutinous rice glue The amylose content is above 90%, the highest content in natural starch-like gums, and environmentally friendly.
本发明实施例中的仅仅以糯米胶为例进行说明,其他淀粉类胶黏剂如玉米胶等固态胶均适用于本发明。In the embodiment of the present invention, only glutinous rice glue is used as an example for description, and other starch adhesives such as corn glue and other solid glues are suitable for the present invention.
3、施胶处理3. Sizing treatment
将经过粉碎脱墨部的筛网筛分得到的絮状废纸干纤维通过传送带输送至雾化室,在雾化室内向絮状干纤维中喷洒雾化的造纸用胶黏剂溶液(糯米胶-水混合物), 进行喷雾施胶,絮状干纤维与糯米胶-水混合物的质量之比为100:1(通常为100:0.5-1.2),雾状糯米胶-水混合物将扬起的纸纤维带落,与纸张干纤维发生混合作用,直至形成膏状的纸纤维-胶黏剂混合物。The flocculent waste paper dry fiber sieved through the screen of the crushing and deinking section is transported to the atomizing chamber through a conveyor belt, and the atomized papermaking adhesive solution (glutinous rice glue) is sprayed into the flocculent dry fiber in the atomizing chamber -Water mixture), spray sizing, the mass ratio of flocculent dry fiber to glutinous rice glue-water mixture is 100:1 (usually 100:0.5-1.2), the paper will be lifted by misty glutinous rice glue-water mixture The fiber tape falls and mixes with the paper dry fiber until a paste-like paper fiber-adhesive mixture is formed.
4、压制处理4. Suppression processing
膏状纸纤维-胶黏剂混合物通过传送带输送至两组碾压滚筒之间,进行两次碾压处理,经过两组碾压滚筒的碾压,第一组碾压滚筒对膏状物进行初步的压制,使其初具纸张形态且微除水,第一组滚筒间隙为所得纸张厚度的1.5(通常为1.2-1.8倍)倍,压制成厚度为1.5(通常为1.2-1.8)倍的纸张粗坯;第二组碾压滚筒为精压,即采用第二组碾压滚筒对经粗压后的纸张粗坯进行第二次碾压,获得水分含量为10-15%的纸张半成品。The paste paper fiber-adhesive mixture is transported between two sets of rollers through a conveyor belt, and is subjected to two rolling treatments. After the two rollers are rolled, the first roller is used for preliminary paste Press to make it take the form of paper and remove water slightly. The gap of the first set of rollers is 1.5 (usually 1.2-1.8 times) the thickness of the resulting paper, and the thickness of the paper is 1.5 (usually 1.2-1.8) times thick. The second group of rolling rollers is precision pressing, that is, the second group of rolling rollers is used for the second rolling of the rough pressed paper blanks to obtain paper semi-finished products with a moisture content of 10-15%.
压制处理分为两个碾压过程,第一遍碾压为粗压,即对膏状物进行初步的压制,使其初具纸张形态且微除水,滚筒间隙为所得纸张厚度的1.5(通常为1.2-1.8倍)倍;二遍碾压进行精压,获得水分含量为10-15%的半成品纸,此时半成品纸张为暗白色。传送带、滚筒的表面上涂装四氟乙烯涂料,防止粘粘。The pressing process is divided into two rolling processes. The first rolling process is rough pressing, which means that the paste is initially pressed to make it take the form of paper and remove water slightly, and the gap between the rollers is 1.5 of the thickness of the resulting paper (usually (1.2-1.8 times) times; two times of rolling and compacting to obtain semi-finished paper with a moisture content of 10-15%, at this time the semi-finished paper is dark white. The surface of the conveyor belt and roller is coated with tetrafluoroethylene coating to prevent sticking.
5、干燥处理5. Drying treatment
将暗白色的半成品纸通过传送部的传送带输送至烘干部,进行真空干燥,烘干温度为40-50℃,烘干过程中控制真空度为-0.0075~-0.1MPa,干燥15s-20s。The dark white semi-finished paper is transported to the drying section through the conveyor belt of the conveying section for vacuum drying, the drying temperature is 40-50°C, the vacuum degree is controlled to -0.0075~-0.1MPa during the drying process, and the drying time is 15s-20s.
在运转时为连续干燥,一个运行周期在5-7min,一个周期能干燥15-20张再生纸,直至纸张颜色为亮白色,关闭干燥机,纸张制备完成。It is continuous drying during operation, with an operating cycle of 5-7min and a cycle of 15-20 sheets of recycled paper until the paper color is bright white. Turn off the dryer and the paper preparation is completed.
干燥处理除了真空干燥处理之外,其他常规干燥方法,例如常压高温干燥、UV光热干燥等均适用于本发明。Drying treatment In addition to vacuum drying treatment, other conventional drying methods, such as atmospheric high temperature drying, UV photothermal drying, etc., are suitable for the present invention.
本发明的施胶处理、压制处理、干燥处理可以分别采用本领域中现有已知的施胶、压制、干燥处理的方法均适用于本发明。The sizing treatment, pressing treatment and drying treatment of the present invention can adopt the methods of sizing, pressing and drying treatment currently known in the art, respectively, which are all applicable to the present invention.
制备的再生纸的亮度、平滑度、横向耐折度分别按照国标方法进行测定,测定结果如表1,其中:The brightness, smoothness and transverse folding resistance of the prepared recycled paper were measured according to the national standard method. The measurement results are shown in Table 1, where:
再生纸的亮度按照国家标准《GB/T 7974-2013纸、纸板和纸浆蓝光漫反射因数D65亮度的测定(漫射/垂直法,室外日光条件)》方法进行测定;The brightness of the recycled paper is measured according to the national standard "Determination of the Blue Light Diffuse Reflectance Factor D65 for Paper, Paperboard and Pulp (GB/T 7974-2013) (Diffuse/Vertical Method, Outdoor Daylight Conditions)" method;
再生纸的平滑度按照国家标准《GB/T 456-2002纸和纸板平滑度的测定(别克法)》方法进行测定;The smoothness of recycled paper is measured according to the national standard "Determination of Smoothness of Paper and Paperboard (GB/T 456-2002) (Buick Method)";
再生纸的横向耐折度按照国家标准《GB/T 457-2008纸和纸板耐折度的测定》方法进行测定;The horizontal folding endurance of recycled paper is measured according to the national standard "Determination of folding endurance of paper and paperboard GB/T 457-2008";
再生纸的紧度通常指1立方米的纸或纸板的质量,又称表观密度;具体测方法如下:从制备的纸张中随机抽选十张纸,使用电动厚度仪测量每张纸的厚度并编号记录;用电子天平测出每张纸相对应的质量;然后.按照制备纸张的标准表面积,用纸张的质量除以对应纸张的厚度与表面积的乘积得到的纸张的紧度,并求平均值,测定结果如表1;The tightness of recycled paper usually refers to the quality of 1 cubic meter of paper or cardboard, also known as the apparent density; the specific measurement method is as follows: randomly select ten papers from the prepared paper and use an electric thickness gauge to measure the thickness of each paper Record with numbers; measure the corresponding mass of each paper with an electronic balance; then. According to the standard surface area of the prepared paper, divide the mass of the paper by the product of the thickness of the corresponding paper and the surface area and obtain the average of the tightness of the paper. Value, the measurement results are shown in Table 1;
再生纸的抗拉(张)强度,采用抗张强度试验机进行测定,抗张强度试验仪在恒速加荷的条件下,将规定尺寸的试样拉伸至断裂,测量其抗张力,同时记录断裂时的最大伸长率,计算抗拉(张)强度,测定结果如表1;The tensile strength of the recycled paper is measured by a tensile strength testing machine. The tensile strength tester stretches the specimen of the specified size to break under the condition of constant speed loading and measures its tensile strength. Record the maximum elongation at break and calculate the tensile (tensile) strength. The measurement results are shown in Table 1;
再生纸的表面强度采用IGT印刷适性仪、蜡棒,按照拉毛速度测定法和蜡棒法测定,测定结果如表1;The surface strength of the recycled paper is determined by the IGT printing suitability tester and wax stick, according to the drawing speed measurement method and the wax stick method.
再生纸的厚度采用电动厚度测定仪进行测定,测定结果如表1。The thickness of the recycled paper was measured using an electric thickness gauge, and the measurement results are shown in Table 1.
表1制备的再生纸的性能检测结果Table 1 Performance test results of prepared recycled paper
指标名称Indicator name 标准规定standard regulation 测定结果The measurement results
白度(%)≥Whiteness (%) ≥ 70.070.0 71.271.2
平滑度(正反面均)(S)≥Smoothness (both positive and negative) (S) ≥ 2020 21.6221.62
紧度(g/cm 3) Tightness (g/cm 3 ) 0.80±0.100.80±0.10 0.8020.802
厚度(mm)Thickness (mm) 0.09±0.0050.09±0.005 0.0930.093

Claims (10)

  1. 一种再生纸的制备方法,其特征是,包括如下步骤:A method for preparing recycled paper is characterized by the following steps:
    1)将废弃纸张同时进行粉碎、脱墨处理,制成去除印刷油墨的絮状干纤维;1) The waste paper is crushed and deinked at the same time to make flocculent dry fiber to remove printing ink;
    2)向絮状干纤维中喷洒造纸用胶黏剂溶液,制成纸纤维-胶黏剂混合物;2) Spray the papermaking adhesive solution into the flocculent dry fiber to make a paper fiber-adhesive mixture;
    3)对纸纤维-胶黏剂混合物依次进行压制处理和干燥处理,即得。3) Pressing and drying the paper fiber-adhesive mixture in sequence, that's it.
  2. 如权利要求1所述的制备方法,其特征是,步骤1)中所述絮状干纤维的长度≥1.0mm。The preparation method according to claim 1, wherein the length of the flocculent dry fiber in step 1) is ≥ 1.0 mm.
  3. 如权利要求1或2所述的制备方法,其特征是,采用粉碎脱墨机对废弃纸张进行所述的粉碎、脱墨处理,其中,所述粉碎脱墨机包括:机壳;安装在机壳上的用于将进入机壳内的废纸切割成纸片的粗粉碎组件;安装在机壳上且位于粗粉碎组件下方的用于防止粗粉碎装置堵塞的冲纸组件;安装在机壳上且位于冲纸组件下方的用于将纸片粉碎成絮状纸屑并分离纸屑及纸屑上的油墨的粉碎脱墨组件;安装在机壳上且位于粉碎脱墨装置下方的收料组件,具有用于过滤絮状纸屑的滤网和位于滤网下方的用于筛分絮状纸屑的筛网。The preparation method according to claim 1 or 2, wherein the crushing and deinking treatment is performed on the waste paper by using a crushing and deinking machine, wherein the crushing and deinking machine includes: a casing; Coarse crushing assembly on the casing for cutting waste paper into the casing; paper punching assembly installed on the casing and located below the coarse crushing assembly to prevent clogging of the coarse crushing device; installed on the casing A crushing and deinking assembly on the lower part of the punching assembly for crushing the paper into flocculent scraps and separating the scraps and the ink on the scraps; a collecting assembly installed on the cabinet and below the crushing and deinking device It has a filter screen for filtering the flocculent paper dust and a screen for screening the flocculent paper dust under the filter screen.
  4. 如权利要求3所述的制备方法,其特征是,所述粉碎脱墨组件包括:并排安装在所述机壳上且中心轴与所述转轴中心轴方向垂直的一对转子;环设于每个转子外壁的用于将所述纸片粉碎成絮状纸屑的多排锤片;与一对转子分别连接的用于驱动一对转子相向高速旋转以便分离絮状纸屑及纸屑上的油墨的旋转驱动机构。The preparation method according to claim 3, wherein the crushing and deinking assembly comprises: a pair of rotors mounted side by side on the casing with a center axis perpendicular to the center axis of the rotating shaft; A plurality of rows of hammers on the outer wall of each rotor for crushing the paper into flocculent scraps; connected to a pair of rotors for driving a pair of rotors to rotate at a high speed to separate the flocculent scraps and the ink on the scraps Rotary drive mechanism.
  5. 如权利要求3或4所述的制备方法,其特征是,所述转子上的多排锤片分别包括沿转子的轴向间隔设置的多个锤片,且一对转子上的锤片错位设置。The preparation method according to claim 3 or 4, characterized in that the multiple rows of hammers on the rotor respectively include a plurality of hammers arranged at intervals along the axial direction of the rotor, and the hammers on a pair of rotors are arranged out of position .
  6. 如权利要求5所述的制备方法,其特征是,一个转子上沿转子轴向排列的相邻两排锤片之间的间距为2-5cm。The preparation method according to claim 5, wherein the distance between two adjacent rows of hammers arranged on the axis of the rotor is 2-5 cm.
  7. 如权利要求3或4所述的制备方法,其特征是,粉碎脱墨处理过程中控制转子的转速≥3000rpm。The preparation method according to claim 3 or 4, wherein the rotation speed of the rotor is controlled to be ≥3000 rpm during the crushing and deinking process.
  8. 如权利要求1或2所述的制备方法,其特征是,步骤2)中所述造纸用胶黏剂选择淀粉胶。The preparation method according to claim 1 or 2, wherein the adhesive for papermaking in step 2) is starch glue.
  9. 如权利要求1或2所述的制备方法,其特征是,步骤2)中所述絮状干纤维与造纸用胶黏剂溶液的质量之比为100:0.5-1.2。The preparation method according to claim 1 or 2, wherein the mass ratio of the flocculent dry fiber to the adhesive solution for papermaking in step 2) is 100: 0.5-1.2.
  10. 如权利要求1或2所述的制备方法,其特征是,步骤3)中所述压制处理分为两次碾压,第一次碾压制成厚度为纸张成品厚度的1.2-1.8倍的纸张粗坯;第二次碾压为将经过第一次碾压的纸张粗坯碾压成水分含量为10-15%的纸张半成品。The preparation method according to claim 1 or 2, characterized in that, in step 3), the pressing process is divided into two rollings, and the first rolling is made into paper with a thickness 1.2-1.8 times the thickness of the finished paper Rough blank; The second rolling is to roll the rough blank of the paper after the first rolling into a semi-finished paper with a moisture content of 10-15%.
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2830477Y (en) * 2005-03-30 2006-10-25 杨宗霖 Fiber reduction deinking machine
CN101190419A (en) * 2006-11-21 2008-06-04 姜新民 Birotor beater disintegrating machine
CN201406604Y (en) * 2009-05-11 2010-02-17 孙首中 Mechanical deinking pulper
CN202377039U (en) * 2011-12-23 2012-08-15 江阴市鑫达药化机械制造有限公司 Hammerhead type crushing machine
CN108714841A (en) * 2018-06-22 2018-10-30 四川大学 A kind of device for paper machinery deinking
CN108866823A (en) * 2014-02-14 2018-11-23 精工爱普生株式会社 Sheet producing device, raw material fiber decomposition device
CN109537363A (en) * 2019-01-11 2019-03-29 北京印刷学院 A kind of recycled writing paper and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014208922A (en) * 2013-03-27 2014-11-06 セイコーエプソン株式会社 Apparatus for manufacturing sheet and method for manufacturing sheet
CN206157451U (en) * 2016-10-31 2017-05-10 李璇 High -efficient environmental protection paper machine of domestic water conservation of official working
CN106337308A (en) * 2016-10-31 2017-01-18 李璇 Water-saving, high-efficiency and environment-friendly paper machine for office and home use
CN109024026B (en) * 2018-09-25 2021-02-05 北京服装学院 High-density plate prepared from recycled waste paper and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2830477Y (en) * 2005-03-30 2006-10-25 杨宗霖 Fiber reduction deinking machine
CN101190419A (en) * 2006-11-21 2008-06-04 姜新民 Birotor beater disintegrating machine
CN201406604Y (en) * 2009-05-11 2010-02-17 孙首中 Mechanical deinking pulper
CN202377039U (en) * 2011-12-23 2012-08-15 江阴市鑫达药化机械制造有限公司 Hammerhead type crushing machine
CN108866823A (en) * 2014-02-14 2018-11-23 精工爱普生株式会社 Sheet producing device, raw material fiber decomposition device
CN108714841A (en) * 2018-06-22 2018-10-30 四川大学 A kind of device for paper machinery deinking
CN109537363A (en) * 2019-01-11 2019-03-29 北京印刷学院 A kind of recycled writing paper and preparation method thereof

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