WO2020128209A1 - Pneumatique pour camionnette optimise - Google Patents
Pneumatique pour camionnette optimise Download PDFInfo
- Publication number
- WO2020128209A1 WO2020128209A1 PCT/FR2019/052943 FR2019052943W WO2020128209A1 WO 2020128209 A1 WO2020128209 A1 WO 2020128209A1 FR 2019052943 W FR2019052943 W FR 2019052943W WO 2020128209 A1 WO2020128209 A1 WO 2020128209A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- equal
- tread
- tire
- radially
- layer
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/03—Tread patterns
- B60C11/0327—Tread patterns characterised by special properties of the tread pattern
- B60C11/033—Tread patterns characterised by special properties of the tread pattern by the void or net-to-gross ratios of the patterns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0041—Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers
- B60C11/005—Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers with cap and base layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/24—Wear-indicating arrangements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/18—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers
- B60C9/20—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers built-up from rubberised plies each having all cords arranged substantially parallel
- B60C2009/2012—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers built-up from rubberised plies each having all cords arranged substantially parallel with particular configuration of the belt cords in the respective belt layers
- B60C2009/2016—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers built-up from rubberised plies each having all cords arranged substantially parallel with particular configuration of the belt cords in the respective belt layers comprising cords at an angle of 10 to 30 degrees to the circumferential direction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
- B60C9/18—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers
- B60C9/20—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers built-up from rubberised plies each having all cords arranged substantially parallel
- B60C9/22—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers built-up from rubberised plies each having all cords arranged substantially parallel the plies being arranged with all cords disposed along the circumference of the tyre
- B60C2009/2214—Structure or arrangement of belts or breakers, crown-reinforcing or cushioning layers built-up from rubberised plies each having all cords arranged substantially parallel the plies being arranged with all cords disposed along the circumference of the tyre characterised by the materials of the zero degree ply cords
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0008—Tyre tread bands; Tread patterns; Anti-skid inserts characterised by the tread rubber
- B60C2011/0016—Physical properties or dimensions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0008—Tyre tread bands; Tread patterns; Anti-skid inserts characterised by the tread rubber
- B60C2011/0016—Physical properties or dimensions
- B60C2011/0025—Modulus or tan delta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C13/00—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof
- B60C2013/005—Physical properties of the sidewall rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C13/00—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof
- B60C2013/005—Physical properties of the sidewall rubber
- B60C2013/007—Thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C13/00—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof
- B60C13/04—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof having annular inlays or covers, e.g. white sidewalls
- B60C2013/045—Tyre sidewalls; Protecting, decorating, marking, or the like, thereof having annular inlays or covers, e.g. white sidewalls comprising different sidewall rubber layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C2200/00—Tyres specially adapted for particular applications
- B60C2200/06—Tyres specially adapted for particular applications for heavy duty vehicles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Definitions
- the invention relates to a radial tire intended to equip a transport vehicle, usually called a van.
- the tire area more particularly concerned is that of tires, the nominal pressure of which is at least equal to 4 bar and at most equal to 6 bar, for a load index at least equal to 110 and at most equal to 121 , within the meaning of the European Tire and Rim Technical Organization or “ETRTO” standard.
- the diameter at seat D defining the diameter of the tire mounting rim, is at least equal to 14 inches, and at most equal to 19 inches.
- the main dimensions of these applications are: 225/70 R15C 112 / 110S, 225/65 R16C 112 / 110R, 235/65 R16C 115 / 113R, 205/75 R16C 110 / 108R, 195/75 R16C 110 / 108R, 225 / 75 R16C 121 / 120R, 215/75 R16C 116 / 114R, 215/75 R16C 113/11 IR, 235/65 R16C 121 / 119R.
- the invention is applicable to them as well as to the other dimensions of this type of application.
- circumferential directions XX ', axial YY' and radial ZZ ' respectively designate a direction tangent to the running surface of the tire according to the direction of rotation of the tire, a direction parallel to the tire rotation axis and a direction perpendicular to the tire rotation axis.
- radially interior respectively “radially exterior” is meant “closer to the axis of rotation of the tire”, respectively “further from the axis of rotation of the tire”.
- axially interior is meant “closer to the equatorial plane of the tire”, respectively “further from the equatorial plane of the tire", the equatorial plane XZ of the tire being the plane passing through the middle of the tire rolling surface and perpendicular to the axis of rotation of the tire.
- a tire comprises a tread, intended to come into contact with the ground via a rolling surface, and connected via two sidewalls with two beads, ensuring the connection mechanical between the tire and the rim on which it is mounted.
- a radial tire comprises a reinforcing reinforcement, comprising a crown reinforcement, radially internal to the tread, and a carcass reinforcement, generally radially inside the crown reinforcement.
- the tread comprises raised elements separated from each other by recesses.
- the arrangement of the raised elements and the recesses constitutes the tread pattern.
- the raised elements extend radially outward from a bottom surface to the running surface.
- the radial distance between the bottom surface and the running surface is called the radial height of the elements in relief and for the maximum radial height, generally measured at the equatorial plane, tread height Hs.
- the proportion of hollows in relation to the elements in relief is defined by a rate
- TEV volume notch equal to the ratio between the total volume of the hollows and the sum of the respective total volumes of the hollows and the elements in relief.
- the total volume of the recesses is the sum of the elementary volumes of the recesses having, typically, an axial width at least equal to 1 mm, that is to say of the recesses which are not simple incisions.
- the volume measurements are carried out by profile surveys of the tread of the new tire, for example, by laser.
- the profile of the tread has an axial width equal to the axial width of the tread surface in contact with the ground, when the tire, mounted on its nominal rim, is inflated to its nominal pressure and subjected to its nominal load, said nominal conditions being defined by the ETRTO standard.
- the raised elements, in new condition generally have a tread height Hs of between 9.5 and 11 mm and the rate of notching TEV volume is around 18%.
- main hollows each having an average width at least equal to 6 mm and having a total volume Vcp.
- main recesses have, in particular, the function of storing water in the contact area between the tread and the ground and of discharging it out of the contact area in order to ensure the performance of hydroplaning.
- the speed index is high and therefore the risk of aquaplaning must be taken into account in design.
- the rate of volume notching is specific, overall lower than that of passenger vehicles and overall higher than that of heavy goods vehicles.
- main hollows are qualified as substantially circumferential, or longitudinal hollows, when their mean line forms with the circumferential direction XX ’of the tire an angle at most equal to 45 °. They are qualified as substantially axial, or transverse hollows, when their mean line forms with the direction.
- circumferential XX ’of the tire an angle at least equal to 45 °.
- the tread comprises at least one polymeric material of the elastomeric blend type, that is to say a polymeric material obtained by mixing at least one elastomer, at least one reinforcing filler and a system. of crosslinking. Most often, the tread is formed by a unique elastomeric mixture.
- a usual physical characteristic of an elastomeric mixture is its glass transition temperature Tg, temperature at which the elastomeric mixture passes from a deformable rubbery state to a rigid glassy state.
- the glass transition temperature Tg of an elastomeric mixture is generally determined when measuring the dynamic properties of the elastomeric mixture, on a viscoanalyzer for example of the Metravib VA4000 type, according to standard ASTM D 5992-96.
- the dynamic properties are measured on a sample of vulcanized elastomeric mixture, that is to say baked up to a conversion rate of at least 90%, the sample having the shape of a cylindrical test piece having a thickness equal to 2 mm and a section equal to 78.5 mm 2 .
- the response of the sample of elastomeric mixture to a sinusoidal stress in alternating single shear is recorded, having a peak-peak amplitude equal to 0.7 MPa and a frequency equal to 10 Hz.
- a temperature scan is carried out at rising speed at a constant temperature of + 1.5 ° C / min.
- the results exploited are generally the complex dynamic shear modulus G *, comprising an elastic part G 'and a viscous part G ”, and the dynamic loss tgô, equal to the ratio G” / G'.
- the glass transition temperature Tg is the temperature at which the dynamic loss tgô reaches a maximum during the temperature sweep.
- the mechanical behavior of an elastomeric mixture can be characterized, statically, by its Shore A hardness, measured in accordance with DIN 53505 or ASTM 2240 standards, and, in dynamics, by its complex dynamic shear modulus G *, such as previously defined, at a given temperature, typically at 23 ° C.
- the heat dissipation, or hysteresis, of an elastomeric mixture can be characterized, statically, by its loss at 60 ° C, which is a loss of energy at 60 ° C, measured by rebound at imposed energy measured at sixth shock and whose value, expressed in%, is the ratio between the difference between the energy supplied and the energy restored and the energy supplied. It can also be characterized, in dynamics, by its dynamic loss tgô, as previously defined, at a given temperature, typically at 23 ° C.
- the material of the tread of a light truck tire of the reference state of the art is an elastomeric mixture having a glass transition temperature Tg equal to -23 ° C, a Shore A hardness of 68 and plus and a dynamic loss tgô at 23 ° C of approximately 0.30.
- the crown reinforcement radially inside the tread and more often, radially outside the carcass reinforcement, comprises, radially from the outside inwards, a hooping reinforcement comprising at least one hooping layer and a working reinforcement comprising at least three working layers.
- the crown reinforcement has the function of resuming both the mechanical inflation stresses generated by the inflation pressure of the tire and transmitted by the carcass reinforcement and the mechanical rolling stresses generated by the rolling tire on a ground and transmitted by the tread.
- the specific purpose of the working reinforcement is to impart rigidity to the tire in the circumferential, axial and radial directions and, in particular, in road holding.
- the presence of three working layers makes it possible to protect the tire against shocks and the oxidation of the most radially inner working layers which are the most stressed in tension, the most radially outer working layer acting as a protective layer.
- the hooping frame has a specific function to provide additional circumferential rigidity relative to the working reinforcement, in order to limit the radial deformations of the tire.
- the hooping frame for a tire for a van, most often comprises a single layer of hooping.
- a hooping layer comprises reinforcements generally made of textile, for example of aliphatic polyamide such as nylon, coated in an elastomeric mixture and parallel to each other.
- the reinforcements form, with the circumferential direction XX ’of the tire, an angle AF, measured in the equatorial plane XZ of the tire, at most equal to 5 °, in absolute value.
- the working frame for a van tire with this load index, usually comprises three working layers, radially superimposed, comprising metal reinforcements coated in an elastomeric mixture, mutually parallel in each layer.
- the two most radially inner working layers are crossed, forming, with the circumferential direction XX ’of the tire, angles (ATI, AT2), measured in the equatorial plane XZ of the
- the most radially outer layer forms, with the circumferential direction XX ′ of the tire, an angle (AT3), measured in the equatorial plane XZ of the tire, the value of which is substantially equal, apart from variations in manufacturing and measurement, to the nearest value of the angle (AT2) formed by the working layer which is adjacent to it.
- This arrangement is favorable to corrosion resistance.
- the metal reinforcements of the working layers are cables formed by an assembly of metal wires.
- the metal reinforcements used for the prior art pick-up tire, taken as a reference is a cable 4.32 constituted by a twisted assembly of four metal wires each having a diameter equal to 0.32 mm.
- the carcass reinforcement comprises at least one carcass layer comprising reinforcements usually made of textile material, coated in an elastomeric material and parallel to each other.
- the reinforcements of a carcass layer form, with the circumferential direction XX 'of the tire, an angle AC at least equal to 85 ° and at most equal 95 °.
- Textile materials commonly used for reinforcing a carcass layer, for a Prior art light truck tires are a polyester such as a polyethylene terephthalate (PET) or an aromatic polyamide, such as aramid.
- a carcass layer can be turned over or not turned over.
- a carcass layer is said to be inverted, when it comprises a main part, connecting the two beads of the tire to each other, and is wound, in each bead, from the inside to the outside of the tire around a circumferential reinforcement or rod, to form a reversal having a free end.
- a carcass layer is not turned over, when it consists only of a main part, connecting the two beads together, without wrapping around a rod.
- the main performances targeted for a van tire are, in a non-exhaustive manner, the longitudinal and transverse adhesions on wet ground and on dry ground, the behavior, in particular at low transverse acceleration, the wear and the rolling resistance. .
- the inventors have given themselves the objective of improving, compared to a van tire of the state of the art as previously described, the compromise between rolling resistance and antagonistic performance such as the various types of 'grip (longitudinal / transverse, on dry / wet ground) or, and wear.
- a tire for a transport vehicle whose nominal pressure is at least equal to 4 bar and at most equal to 6 bar, for a load index at least equal to 110 and at most equal to 121 comprising:
- a tread intended to come into contact with a ground by means of a tread surface and comprising elements in relief extending radially outward from a bottom surface to the rolling surface on a maximum radial height Hs, the sculpture height Hs being at least equal to 6.5 mm and at most equal to 11 mm, the tread comprising at least one wear indicator,
- the elements in relief (22) having a total volume Vp and being separated by recesses having a total volume Vc .
- a part of the hollows being main hollows, each having an average width at least equal to 6 mm and all of the main hollows having a total volume Vcp,
- TEV volume notching rate defined as the ratio between the total volume Vc of the hollows and the sum of the total volume Vc of the hollows and the total volume Vp of the elements in relief, at least equal to 18% and at most equal to 23%
- the tread further comprising at least one elastomeric mixture having a glass transition temperature Tg, a Shore A hardness and a dynamic loss tgô at 23 ° C., the at least one elastomeric mixture of the tread having a temperature of glass transition Tg at least equal to -30 ° C and at most equal to -18 ° C,
- an intermediate layer radially internal to the tread further comprising at least one elastomeric mixture having a dynamic loss tgôa at 23 ° C,
- a hooping reinforcement radially internal to the intermediate layer, comprising at least one hooping layer comprising textile reinforcements coated in an elastomeric mixture, parallel to each other and forming, with a direction
- -a working frame radially inside the hooping frame, comprising at least three working layers, radially superimposed, comprising metal reinforcements coated in an elastomeric mixture, mutually parallel in each layer and crossed from one layer to the following, training, with management
- a carcass reinforcement comprising at least one carcass layer and at most two carcass layers, each carcass layer comprising textile reinforcements coated in an elastomeric material, parallel to each other and forming, with the circumferential direction XX ′ of the tire, a angle AC at least equal to 85 ° and at most equal 95 °,
- the at least one elastomeric mixture of the tread has a Shore A hardness at least equal to 55 and at most equal to 66 and a dynamic loss tgô at 23 ° C at least equal to 0.15 and at most equal to 0.29, and comprises a modified diene elastomer comprising at least one functional group comprising a silicon atom, the latter being located within the main chain of the elastomer including the chain ends,
- the elastomeric mixture of the intermediate layer having a dynamic loss tgôa at 23 ° C at most equal to the dynamic loss tgô of the elastomeric mixture or mixtures constituting the tread, the axial thickness Epf being at least equal to 3mm and at most equal to 7mm.
- An elastomeric tread mixture with low hysteresis contributes to low rolling resistance, this effect being reinforced by the limited radial height of the raised tread elements. Furthermore, in this type of application, it is necessary to achieve the desired performance to have an intermediate layer under the tread, the dynamic loss of which is also low and at most equal to that of the elastomeric mixture or mixtures included in the band. and intended to be in contact with the road surface during normal use of the tire on a vehicle.
- an elastomeric tread mixture with reduced hardness therefore rather softer all, makes it possible to increase the grip on wet ground but degrades the behavior.
- the negative impact of the soft elastomeric mixture on the behavior is at least partially offset by the compromise between the radial height of the raised tread elements and the properties of the materials.
- the glass transition temperature Tg a wide range of values makes it possible to adjust the compromise between rolling resistance and grip on wet ground: a rather low glass transition temperature Tg is favorable for rolling resistance performance, while a rather high glass transition temperature Tg is favorable for grip.
- a low tread height of the order of 8 mm associated with a low glass transition temperature Tg will allow maximum rolling resistance performance without degrading the grip.
- a tread height around 10 mm associated with a low glass transition temperature Tg will allow very good rolling resistance performance while improving grip and wear if the associated material allows it.
- the elastomeric mixture or mixtures of the tread have a glass transition temperature Tg at least equal to -30 ° C and at most equal to -18 ° C.
- This range of glass transition temperature values Tg achieves a satisfactory compromise between rolling resistance and grip on wet surfaces, with the particular operating point of light truck tires.
- the glass transition temperature Tg is high enough to be favorable for wet grip but low enough, which is favorable for the rolling resistance, pressures and operating loads of these tires.
- a total volume Vcp of all of the main hollows adapted to the pressure of these tires contributes to good grip on wet ground, in particular with a high water level, thanks to its storage effect and d evacuation of water.
- a preferred embodiment is the combination of a material whose glass transition temperature Tg is at most equal to -21 ° c and at least equal to -18 ° C and sculpture heights between 8 and 10 mm to find an optimal balance between rolling resistance and wear performance.
- a preferred embodiment is the combination of a material whose glass transition temperature Tg is at most equal to -30 ° C and at least equal to - 24 ° C and a sculpture height at least equal to 7 and 8.5 mm to make a
- the modified diene elastomeric mixture comprises 100 phr (parts per cent of elastomer) of an elastomer matrix comprising a modified diene elastomer.
- a diene elastomer is a homopolymer or a copolymer, derived at least in part from diene monomers, that is to say from monomers carrying two carbon-carbon double bonds, conjugated or not.
- the elastomeric mixture comprises the diene elastomer modified at a rate at least equal to 20 phr.
- the chemical composition of the elastomeric mixture of the tread according to the invention contributes to an improvement in the rolling resistance and / or wear and / or grip on wet ground or a shift in the compromise between these performances. .
- the functional group comprising a silicon atom is located at one end of the main chain of T elastomer.
- the functional group comprises a silanol function.
- the silicon atom of the functional group is substituted by at least one alkoxy function, optionally totally or partially hydrolyzed to hydroxyl.
- the functional group is located in the main elastomer chain, it will then be said that the diene elastomer is coupled or even functionalized in the middle of the chain.
- the silicon atom of the functional group then links the two branches of the main chain of the diene elastomer.
- the silicon atom of the functional group is substituted by at least one alkoxy function, optionally totally or partially hydrolyzed to hydroxyl.
- the functional group comprises a silanol function at the chain end
- the functional group can be a silanol function or else a polysiloxane group having a silanol end.
- Corresponding modified diene elastomers are described in particular in documents EP 0 778 311 A1, WO 2011/042507 Al.
- the silicon atom of the functional group is substituted by at least one alkoxy function, optionally totally or partially hydrolyzed to hydroxyl
- the silicon atom can also be substituted , directly or via a divalent hydrocarbon radical, by at least one other function comprising at least one heteroatom chosen from N, S, O, P.
- the silicon atom is substituted by at least one other function via a divalent hydrocarbon radical, more preferably a linear Cl-Cl 8 aliphatic radical.
- the other function is preferably a tertiary amine, more preferably a diethylamino- or dimethylamino- group.
- the alkoxy function is preferably methoxy, ethoxy, butoxy or propoxy. Modified diene elastomers corresponding to these variants are described in particular in documents WO 2009/133068 A1, WO 2015/018743 A1.
- the modification of the diene elastomer by at least one functional group comprising a silicon atom does not exclude another modification of the elastomer, for example at the chain end by an amine function introduced during the initiation of polymerization, as described in WO 2015/018774 A1, WO 2015/018772 A1.
- the modified diene elastomer according to the invention is a 1,3-butadiene polymer, more preferably a copolymer of 1,3-butadiene and styrene (SBR)
- SBR styrene
- Modified diene elastomer according to the invention can be, according to different variants, used alone in the elastomeric mixture or in blending with at least one other diene elastomer conventionally used in tires, whether it is star-shaped, coupled, functionalized by example with tin or silicon, or not.
- the elastomeric mixture of the tread according to the invention comprises a plasticizing resin of the thermoplastic resin type at a rate at least equal to 20 phr.
- the carcass reinforcement can be made up of an inverted and engaged carcass layer.
- the reversal of the carcass layer starts again from each bead, crosses the sidewalls of the tire towards the top. If the free end of the carcass layer is axially internal to the axial end of one of the layers of the crown reinforcement, it is said to be engaged.
- This solution is particularly advantageous in the use of light truck tires to resist internal pressure and optimize the mass of the tire.
- the carcass reinforcement consists of two carcass layers to improve the impact resistance against sidewalks while facilitating manufacture compared to other solutions.
- the volume entablature TEV volume of the tread is at least equal to 18% and at most equal to 23%. This range of entablature rate values ensures good adhesion performance on wet ground, thanks to a tread notch rate high enough to compensate for a limited tread height.
- the TEV volume notching rate of the tread is at least equal to 19% and at most equal to 22%.
- the main recesses are oriented in the circumferential direction, preferably, the tread comprises at least 3 at most 4 circumferential main recesses.
- the tread comprises recesses, forming an angle with the longitudinal direction at least equal to 40 ° with the longitudinal axis XX ', having a variable width and an average value at most equal to 2 mm .
- the average width at most equal to 2 mm allows these recesses to close in the passage of contact with the running surface and to maintain, despite these recesses, a rigidity of the tread favorable to rolling resistance.
- the variable nature of this thickness makes it possible to increase this effect.
- the most axially outside point of the hooping layer is axially outside at the most axially outside point of the most radially outside working layer.
- This architecture is favorable to the stiffening of the structure and therefore to the behavior.
- the textile reinforcements of the at least one hooping layer of the hooping frame comprise an aromatic polyamide, such as aramid.
- Aramid has a high extension module and therefore low deformability, which is favorable for a hooping function of the tire.
- the textile reinforcements of the at least one hooping layer of the hooping frame comprise a combination of an aromatic polyamide, such as aramid , and an aliphatic polyamide, such as nylon.
- Such reinforcements are also called hybrid reinforcements and have the advantage of having a mechanical behavior in extension known as “bi-module”, characterized by a low extension module, that of nylon, and therefore great deformability, for small elongations, and a high extension module and therefore lower deformability, for large elongations.
- the textile reinforcements of the at least one hooping layer of the hooping frame comprise a combination of an aromatic polyamide, such as aramid, and a polyester, such as polyethylene terephthalate (PET).
- aromatic polyamide such as aramid
- PET polyethylene terephthalate
- Such reinforcements are also hybrid reinforcements which have the same advantages as those described above.
- This variant is very favorable to rolling resistance because it reduces the average hysteresis of the crown block while ensuring that only a material designed for this use is in contact with the road surface.
- the intermediate layer is profiled at its axial ends and of an average radial thickness at least equal to 3 mm and at most equal to 5 mm.
- This progressive thickness of the intermediate layer allows axial management of the stiffnesses of the tread.
- the intermediate layer is of maximum thickness and this thickness can be variable to decrease under the main hollows and increase or not under elements in relief of the tread axially offset from the plane Ecuador. It is preferred that the thickness decreases progressively and continuously at the ends of the intermediate layer in order to compensate for the loss of rigidity of the working layers due to the edge effects of their own axial ends.
- a thickness of between 3 and 5 mm is preferred.
- the intermediate layer consists of an elastomeric mixture of a dynamic loss tgôa at 23 ° C at least equal to 0.05 and at most equal to 0.15.
- FIG. 1 a figure of a perspective section of a tire according to the invention, not shown to scale and described below.
- FIG. 1 represents a meridian section in perspective, in a meridian plane YZ, of a tire for a van vehicle according to the invention.
- the tire comprises, most radially on the outside, a tread 2, intended to come into contact with a ground via a tread surface 21 and comprising raised elements 22 extending radially towards the exterior from a bottom surface 23 to the rolling surface 21 over a tread height Hs of the tire, at least equal to 6.5 mm and at most equal to 11 mm.
- the elements in relief 22 have a total volume Vp and are separated by recesses 24 having a total volume Vc.
- Part of the recesses 24 are main recesses, each having an average width at least equal to 6 mm and all of the main recesses having a total volume Vcp.
- the tread 2 has a volume notching rate TEV, defined as the ratio between the total volume Vc of the recesses 24 and the sum of the total volume Vc of the recesses 24 and the total volume Vp of the elements in relief 22, at least equal at 18% and at most equal to 23%.
- the tread 2 consists of a modified diene elastomer comprising at least one functional group comprising a silicon atom, the latter being located within the main chain of the elastomer including the chain ends.
- This elastomeric mixture has a glass transition temperature Tg at least equal to -30 ° C and at most equal to -18 ° C, a Shore A hardness at least equal to 55 and at most equal to 66 and a dynamic loss tgô to 23 ° C at least equal to 0.15 and at most equal to 0.29.
- the tire also comprises an intermediate layer 6 comprising an elastomeric mixture and positioned radially inside the tread 2 and whose dynamic loss tgôa at 23 ° C at least equal to 0.05 and at most equal to 0.15 and at more equal to the dynamic loss tgô at 23 ° C of the tread material (s).
- the tire also comprises a hooping reinforcement 3, radially internal to the intermediate layer 6 and comprising a hooping layer 31, a working reinforcement 4, radially inside the hooping reinforcement 3 and comprising two working layers (41, 42) radially superposed, and, finally, a carcass reinforcement 5 comprising a carcass layer 51.
- the hooping layer 31 comprises textile reinforcements 311 coated in an elastomeric mixture, parallel to each other and forming, with a direction
- the three working layers (41, 42, 43) each include metallic reinforcements (411, 421, 431) coated in an elastomeric mixture, mutually parallel in each layer.
- the two most radially inner layers are crossed, and their metallic reinforcements form, with the circumferential direction XX 'of the tire, an angle (ATI, AT2), measured in the equatorial plane XZ of the tire, the absolute value of which is at least equal at 23 ° and at most equal to 30 °.
- the metal reinforcements of the most radially outer working layer (43) form, with the circumferential direction XX ’of the tire, an angle (AT3), measured in the equatorial plane XZ of the tire, the value of which is
- the carcass layer 51 comprises textile reinforcements 511 coated in an elastomeric material, parallel to each other and forming, with the circumferential direction XX 'of the tire, an angle AC at least equal to 85 ° and at most equal 95 °.
- the invention has been more particularly studied for a light truck tire of size 235 / 65R16, with a nominal pressure of 4.75b and a load index 115.
- a reference tire Ref has been compared with two tires Inv1 and Inv2 according to the invention.
- the tread of the reference tire Ref comprises elements in relief extending radially over a tread height Hs equal to 10 mm.
- the TEV volume notching rate of the tread is 19%.
- the elastomeric mixture of the tread has a glass transition temperature Tg equal to -23 ° C, a Shore A hardness equal to 68 and a dynamic loss tgô at 23 ° C equal to 0.29.
- the reference tire Ref does not include an intermediate layer radially inside the tread.
- the hooping frame comprises a layer of hooping of which the textile reinforcements are made of nylon 140/2 title (assembly of 2 additional fibers of 140 tex each, 1 tex being the mass in g of 1000 m of thread) and distributed in the hooping layer with a density of 98 threads / dm.
- the working frame includes three radially superimposed working layers.
- the metallic reinforcements of formula 4.32 twisted assembly of four metallic wires each having a diameter equal to 0.32 mm) of the radially innermost working layer and of the radially outermost working layer are distributed at a pitch equal to 1.4 mm and form, with management
- the carcass reinforcement is made up of two carcass layers, the textile reinforcements of which are made of polyethylene terephthalate (PET) of 144/2 titer (assembly of 2 surpluses of 144 tex each), with a twist of 420 turns / m and distributed in the carcass layer with a density of 104 threads / dm.
- PET polyethylene terephthalate
- the tread of the tire according to the Invl invention comprises elements in relief extending radially over a tread height Hs equal to 8.6 mm.
- the TEV volume notching rate of the tread is 21%.
- the elastomeric mixture of the tread has a glass transition temperature Tg equal to -20 ° C, a Shore A hardness equal to 64 and a dynamic loss tgô at 23 ° C equal to 0.27.
- the tire according to the invention also comprises an intermediate layer, radially inside the tread and radially outside the hooping reinforcement, constituted by an elastomeric mixture having a dynamic loss tgô at 23 ° C equal to 0.14.
- the hoop reinforcement and the working and carcass layers are not modified between the reference tire Ref and the
- the tread of the tire according to the invention Inv2 comprises elements in relief extending radially over a tread height Hs equal to 8.2 mm.
- the TEV volume notching rate of the tread is 21%.
- the elastomeric mixture of the tread has a glass transition temperature Tg equal to -28 ° C, a Shore A hardness equal to 64 and a dynamic loss tgô at 23 ° C equal to 0.21.
- the tire according to the invention further comprises an intermediate layer, radially inside the tread and radially outside the hooping reinforcement, constituted by an elastomeric mixture having a dynamic loss tgô at 23 ° C equal to 0.11.
- the hoop reinforcement and the working and carcass layers are not modified between the reference tire Ref and the
- the tread of the reference tire Ref does not comprise a modified diene elastomer comprising at least one functional group, it is a conventional elastomeric mixture for this type of application.
- the tire treads according to the invention Invl and Inv2 comprise a modified diene elastomer comprising at least one functional group comprising a silicon atom, the latter being situated at the end of the chain.
- the tire Invl according to the invention has a reduction in rolling resistance of 1.3 kg / t, with performance in longitudinal grip at least equivalent, improved on wet ground and a gain in wear of 10%.
- the Inv2 and Ref tires were subjected to various tests and comparative measurements. The results, presented below, are expressed respectively for Inv2 with respect to Ref (reference or base 100):
- the tire Inv2 according to the invention exhibits adhesion performance
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Tires In General (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR112021011042-9A BR112021011042A2 (pt) | 2018-12-19 | 2019-12-05 | Pneumático para caminhonete otimizado |
EP19870042.9A EP3898271B1 (fr) | 2018-12-19 | 2019-12-05 | Pneumatique pour camionnette optimise |
CN201980082894.4A CN113195244B (zh) | 2018-12-19 | 2019-12-05 | 优化的货车轮胎 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FRFR1873272 | 2018-12-19 | ||
FR1873272A FR3090476A3 (fr) | 2018-12-19 | 2018-12-19 | Pneumatique pour camionnette optimisé |
FRFR1900826 | 2019-01-30 | ||
FR1900826A FR3090477A1 (fr) | 2018-12-19 | 2019-01-30 | Pneumatique pour camionnette optimisé |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2020128209A1 true WO2020128209A1 (fr) | 2020-06-25 |
Family
ID=70108161
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2019/052943 WO2020128209A1 (fr) | 2018-12-19 | 2019-12-05 | Pneumatique pour camionnette optimise |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2020128209A1 (fr) |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0778311A1 (fr) | 1995-11-07 | 1997-06-11 | COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN-MICHELIN & CIE | Composition de caoutchouc à base de silice et de polymère diénique fonctionnalisé ayant une fonction silanol terminale |
WO2009133068A1 (fr) | 2008-04-29 | 2009-11-05 | Societe De Technologie Michelin | Melange elastomerique comprenant majoritairement un elastomere dienique couple par un groupe amino-alcoxysilane, composition de caoutchouc le comprenant et leurs procedes d'obtention |
WO2011042507A1 (fr) | 2009-10-08 | 2011-04-14 | Societe De Technologie Michelin | Elastomere dienique fonctionnalise et composition de caoutchouc le contenant. |
WO2015018772A1 (fr) | 2013-08-09 | 2015-02-12 | Compagnie Generale Des Etablissements Michelin | Elastomère diénique modifié comprenant un élastomère diénique couplé par un composé aminoalcoxysilane et fonctionnalisé amine en extrémité de chaîne et composition de caoutchouc le comprenant |
WO2015018774A1 (fr) | 2013-08-09 | 2015-02-12 | Compagnie Generale Des Etablissements Michelin | Elastomère diénique couplé possédant une fonction silanol en milieu de chaîne et fonctionnalisé amine en extrémité de chaîne et composition de caoutchouc le comprenant |
WO2015018743A1 (fr) | 2013-08-08 | 2015-02-12 | Compagnie Generale Des Etablissements Michelin | Elastomère diénique modifié, son procédé de synthèse et composition de caoutchouc le comprenant |
FR3041568A1 (fr) * | 2015-09-30 | 2017-03-31 | Michelin & Cie | Pneumatique pour vehicule de tourisme |
WO2018172695A1 (fr) * | 2017-03-23 | 2018-09-27 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour véhicule de tourisme |
WO2018178568A1 (fr) * | 2017-03-30 | 2018-10-04 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour véhicule de tourisme |
WO2018185436A1 (fr) * | 2017-04-04 | 2018-10-11 | Compagnie Generale Des Etablissements Michelin | Pneu a performances ameliorees |
-
2019
- 2019-12-05 WO PCT/FR2019/052943 patent/WO2020128209A1/fr unknown
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0778311A1 (fr) | 1995-11-07 | 1997-06-11 | COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN-MICHELIN & CIE | Composition de caoutchouc à base de silice et de polymère diénique fonctionnalisé ayant une fonction silanol terminale |
WO2009133068A1 (fr) | 2008-04-29 | 2009-11-05 | Societe De Technologie Michelin | Melange elastomerique comprenant majoritairement un elastomere dienique couple par un groupe amino-alcoxysilane, composition de caoutchouc le comprenant et leurs procedes d'obtention |
WO2011042507A1 (fr) | 2009-10-08 | 2011-04-14 | Societe De Technologie Michelin | Elastomere dienique fonctionnalise et composition de caoutchouc le contenant. |
WO2015018743A1 (fr) | 2013-08-08 | 2015-02-12 | Compagnie Generale Des Etablissements Michelin | Elastomère diénique modifié, son procédé de synthèse et composition de caoutchouc le comprenant |
WO2015018772A1 (fr) | 2013-08-09 | 2015-02-12 | Compagnie Generale Des Etablissements Michelin | Elastomère diénique modifié comprenant un élastomère diénique couplé par un composé aminoalcoxysilane et fonctionnalisé amine en extrémité de chaîne et composition de caoutchouc le comprenant |
WO2015018774A1 (fr) | 2013-08-09 | 2015-02-12 | Compagnie Generale Des Etablissements Michelin | Elastomère diénique couplé possédant une fonction silanol en milieu de chaîne et fonctionnalisé amine en extrémité de chaîne et composition de caoutchouc le comprenant |
FR3041568A1 (fr) * | 2015-09-30 | 2017-03-31 | Michelin & Cie | Pneumatique pour vehicule de tourisme |
WO2018172695A1 (fr) * | 2017-03-23 | 2018-09-27 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour véhicule de tourisme |
WO2018178568A1 (fr) * | 2017-03-30 | 2018-10-04 | Compagnie Generale Des Etablissements Michelin | Pneumatique pour véhicule de tourisme |
WO2018185436A1 (fr) * | 2017-04-04 | 2018-10-11 | Compagnie Generale Des Etablissements Michelin | Pneu a performances ameliorees |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3356161B1 (fr) | Pneumatique pour vehicule de tourisme | |
EP3600917B1 (fr) | Pneumatique pour véhicule de tourisme | |
EP3600915B1 (fr) | Pneumatique pour véhicule de tourisme | |
EP3727894B1 (fr) | Pneu pour poids lourd ameliore en endurance | |
EP3713776B1 (fr) | Pneumatique pour vehicule de tourisme | |
EP4178809A1 (fr) | Pneumatique presentant des proprietes de resistance au roulement ameliorees | |
EP3713777B1 (fr) | Pneumatique pour vehicule de tourisme | |
EP3898271B1 (fr) | Pneumatique pour camionnette optimise | |
WO2017103458A1 (fr) | Pneumatique présentant des propriétés d'usure et de résistance au roulement améliorées | |
EP3898269B1 (fr) | Pneumatique pour camionnette optimise | |
EP3898270B1 (fr) | Pneumatique pour camionnette optimise | |
WO2020128209A1 (fr) | Pneumatique pour camionnette optimise | |
WO2019102150A1 (fr) | Pneumatique pour vehicule de tourisme | |
WO2020128207A1 (fr) | Pneumatique pour camionnette optimise | |
WO2020128208A1 (fr) | Pneumatique pour camionnette optimise | |
FR2953460A1 (fr) | Bourrelet de pneumatique pour vehicule lourd de type genie civil | |
WO2017174904A1 (fr) | Armature de carcasse de pneumatique pour véhicule a deux roues | |
EP4237261A1 (fr) | Pneumatique avec une bande de roulement comportant des rainures circonférentielles renforcées | |
WO2017103456A1 (fr) | Pneumatique presentant des proprietes d'usure et de resistance au roulement ameliorees | |
WO2022123131A1 (fr) | Pneumatique comportant une bande de roulement comportant au moins une couche d'elements de renforcement textiles | |
WO2022084607A1 (fr) | Pneumatique comportant une bande de roulement constituee de plusieurs melanges elastomeriques | |
EP3621825A1 (fr) | Pneumatique à architecture et bande de roulement optimisées |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 19870042 Country of ref document: EP Kind code of ref document: A1 |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112021011042 Country of ref document: BR |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2019870042 Country of ref document: EP Effective date: 20210719 |
|
ENP | Entry into the national phase |
Ref document number: 112021011042 Country of ref document: BR Kind code of ref document: A2 Effective date: 20210608 |