WO2020126773A1

WO2020126773A1 - Composition for dyeing keratin fibers comprising at least one silicone acrylic copolymer, at least one silicone resin and at least one pigment

Info

Publication number: WO2020126773A1
Application number: PCT/EP2019/084769
Authority: WO
Inventors: Alexis LIARD
Original assignee: L'oreal
Priority date: 2018-12-20
Filing date: 2019-12-11
Publication date: 2020-06-25
Also published as: FR3090368B1; FR3090368A1

Abstract

Composition for dyeing keratin fibers comprising at least one silicone acrylic copolymer, at least one silicone resin and at least one pigment A composition for treating human keratin fibers such as the hair is described and comprises at least one silicone acrylic copolymer, at least one silicone resin and at least one pigment. The present invention also relates to a process for treating human keratin fibers such as the hair, comprising the application to the keratin fibers of a composition as defined previously. The present invention also relates to a process for treating human keratin fibers such as the hair comprising the application to the keratin fibers of a dye composition as described previously, and the application to the dyed keratin fibers of a makeup-removing composition comprising at least one hydrocarbon-based oil.

Description

Title: Composition for dyeing keratin fibers comprising at least one silicone acrylic copolymer, at least one silicone resin and at least one pigment

Technical field

[0001] A subject of the present invention is a composition for treating human keratin fibers such as the hair, comprising at least one silicone acrylic copolymer, at least one silicone resin and at least one pigment.

[0002] A subject of the present invention is also a process for treating keratin fibers such as the hair, comprising the application to the keratin fibers of a dye composition comprising at least one silicone acrylic copolymer, at least one silicone resin and at least one pigment, and the application to the dyed keratin fibers of a makeup-removing composition comprising at least one hydrocarbon-based oil.

[0003] In the field of dyeing keratin fibers, in particular human keratin fibers, it is already known practice to dye keratin fibers via various techniques using direct dyes or pigments for non-permanent dyeing, or dye precursors for permanent dyeing.

[0004] There are essentially three types of process for dyeing the hair:

[0005] a)“permanent” dyeing, the function of which is to afford a substantial modification to the natural color and which uses oxidation dyes which penetrate into the hair fiber and forms the dye via an oxidative condensation process;

[0006] b) non-permanent, semi-permanent or direct dyeing, which does not use the oxidative condensation process and withstands four or five shampoo washes; it consists in dyeing keratin fibers with dye compositions containing direct dyes. These dyes are colored and coloring molecules that have affinity for keratin fibers;

[0007] c) temporary dyeing, which gives rise to a modification of the natural color of the head of hair that remains from one shampoo wash to the next, and which serves to enhance or correct a shade that has already been obtained. It may also be likened to a“makeup” process.

[0008] For this last type of dyeing, it is known practice to use colored polymers formed by grafting one or more dyes of azo, triphenylmethane, azine, indoamine or anthraquinone nature onto a polymer chain. These colored polymers are not entirely satisfactory, especially as regards the homogeneity of the coloring obtained and its resistance, not to mention the problems associated with their manufacture and especially with their reproducibility. [0009] Another dyeing method consists in using pigments. Specifically, the use of pigment on the surface of keratin fibers generally makes it possible to obtain visible colorings on dark hair, since the surface pigment masks the natural color of the fiber. The use of pigment for dyeing keratin fibers is described, for example, in patent application FR 2 741 530, which recommends using, for the temporary dyeing of keratin fibers, a composition comprising at least one dispersion of film-forming polymer particles comprising at least one acid function and at least one pigment dispersed in the continuous phase of said dispersion. The colorings obtained via this dyeing method have the drawback of having a low resistance to shampoo washes.

[0010] In addition, compositions for temporarily dyeing the hair may also lead to a hair feel that is uncosmetic and/or not natural; the hair thus dyed may in particular lack softness and/or suppleness and/or strand separation.

[0011] Furthermore, the application of a dye composition comprising pigments to keratin fibers is often followed by a step of applying heat to the keratin fibers using a straightening iron, for example at a temperature of between 120°C and 220°C. This step of applying heat using a straightening iron is restrictive for users and can damage the keratin fibers.

[0012] In addition, there are no effective makeup-removing compositions for removing this type of temporary dye composition when it is persistent with respect to shampoo washes.

[0013] Therefore, there remains a need to obtain a composition for dyeing keratin fibers, in particular the hair, which has the advantage of obtaining a homogeneous and smooth colored coating on the hair, and also hair with complete strand separation, while forming a coating that is persistent with respect to shampoo washes and to the various attacking factors to which hair may be subjected without damage to the hair, without requiring a step of applying heat using a straightening iron, and which is easily removed, that is to say eliminated.

[0014] Thus, the objective of the present invention is to develop a composition for dyeing keratin fibers, in particular the hair, which has the advantage of obtaining a homogeneous and smooth colored coating on the hair, and also hair with complete strand separation, while forming a coating that is persistent with respect to shampoo washes and to the various attacking factors to which hair may be subjected without damage to the hair, without requiring a step of applying heat using a straightening iron, and which is easily removed.

Summary of the invention

[0015] This objective is achieved with the present invention, a subject of which is a composition for treating human keratin fibers such as the hair, comprising: a) at least one silicone acrylic copolymer comprising at least the following units:

- a polydimethylsiloxane (PDMS) unit comprising at least two polymerizable radical groups chosen from an acrylic or methacrylic group having from 1 to 6 carbon atoms,

- an alkyl acrylate or methacrylate unit, b) at least one silicone resin, and

c) at least one pigment.

[0016] A subject of the present invention is also a process for dyeing human keratin fibers such as the hair, comprising the application to said fibers of a composition as defined above.

[0017] The present invention also relates to a process for treating human keratin fibers such as the hair, comprising the following steps:

a) applying to the keratin fibers a dye composition as defined above, and

b) applying to the dyed keratin fibers a makeup-removing composition comprising at least one hydrocarbon-based oil.

[0018] The present invention also relates to a kit for treating keratin fibers such as the hair, comprising a dye composition as defined above, and a makeup-removing composition as defined above.

[0019] A subject of the invention is also the use of the composition as defined above, for the cosmetic treatment of, in particular for dyeing, keratin fibers, in particular human keratin fibers such as the hair.

[0020] Through the use of this composition, colored coatings are obtained on the hair that make it possible to obtain a coloring that is visible on all types of hair in a manner that is persistent with respect to shampoo washes, while preserving the physical qualities of the keratin fibers. Such a coating may be resistant to the external attacking factors to which the hair may be subjected, such as blow-drying and perspiration.

[0021] The colored coatings obtained are persistent with respect to shampoo washes and also with respect to external attacking factors without requiring the application of heat to the hair by means of a straightening iron. In general, the application of heat to the hair by means of a straightening iron is carried out at a temperature of between 120°C and 220°C.

[0022] Moreover, this composition makes it possible to obtain perfectly separated hairs, which can be styled without problem and from which makeup can be easily removed either immediately after the application of the dye composition or after a certain amount of time, i.e. a few days to a few weeks, after the application of the dye composition. [0023] The term“ hair with strand separation” is intended to mean hair which, after application of the composition and drying, is not stuck together (or of which all the strands are separated from each other) and thus does not form clumps of hair.

[0024] For the purposes of the present invention, the term“ coloring that is persistent with respect to a shampoo wash” is intended to mean that the coloring obtained remains after one shampoo wash, preferably after 3 shampoo washes, more preferentially after 5 shampoo washes, more preferentially still after 10 shampoo washes.

[0025] The expression“ comprising a” should be understood as meaning“comprising at least one”, unless otherwise specified.

[0026] The expression“ at least one” is intended to mean“one or more”.

[0027] The invention is not limited to the examples illustrated. The features of the various examples may notably be combined within variants which are not illustrated.

[0028] The composition for treating human keratin fibers according to the invention is preferably a composition for dyeing human keratin fibers such as the hair.

Silicone acrylic copolymer

[0029] The composition according to the invention comprises at least one silicone acrylic

copolymer comprising at least the following units:

- an alkyl acrylate or methacrylate unit.

[0030] Preferably, the copolymer according to the invention is water insoluble. For the purposes of the present invention, the term“water insoluble” is intended to mean a compound that is insoluble in water at ordinary temperature (25°C) and at atmospheric pressure (760 mmHg or 1.013 x 10⁵ Pa). Preferably, the copolymer according to the invention has a solubility in water of less than 5%, better still less than 1% and even more preferentially less than 0.1%.

[0031] An“alkyl acrylate or methacrylate unit” is intended to mean a unit derived from an alkyl acrylate or methacrylate monomer.

[0032] The term“polydimethylsiloxanes” (also abbreviated as PDMSs) is intended to denote, in accordance with what is generally accepted, any organosilicon polymer or oligomer of linear structure, of variable molecular weight, obtained by polymerization and/or polycondensation of suitably functionalized silanes, and constituted essentially of a repetition of main units wherein the silicon atoms are linked together via oxygen atoms (siloxane bond-Si-O-Si-), comprising methyl radicals directly linked via a carbon atom to said silicon atoms. [0033] The PDMS chains which can be used to obtain the copolymer used according to the invention comprise at least two polymerizable radical groups, preferably located on at least one of the ends of the chain, that is to say that the PDMS can, for example, have a polymerizable radical group on each of the two ends of the chain.

[0034] A polymerizable radical group is understood to mean a radical capable of polymerizing with other polymerizable radical groups or monomers.

[0035] An“end of the chain” is intended to mean the terminal group of the polydimethylsiloxanes unit consisting of dimethylsiloxane group, the polydimethylsiloxanes unit comprising two ends, each having a terminal group such as dimethylsiloxane group.

[0036] Preferably, the polydimethylsiloxane unit comprises at least one polymerizable radical group on each of the two ends of the chain.

[0037] Preferably, the polymerizable radical group is an acrylic or methacrylic group having from 1 to 6 carbon atoms, more preferentially a C¾ = CH - CO - O - Ri- group, wherein Ri represents an alkyl radical comprising from 1 to 3 carbon atoms.

[0038] The copolymers used in the composition are generally obtained according to the usual methods of polymerization and grafting, for example by radical polymerization (A) of a polyalkylsiloxane comprising at least two polymerizable radical groups (preferably one polymerizable radical group on each of the two ends of the chain) and (B) of at least one acrylic or methacrylic monomer, such as acrylic acid, methacrylic acid or an ester thereof, as described, for example, in the documents US-A-5 061 481 and US-A-5 219 560.

[0039] Preferably, the composition comprises at least one silicone acrylic copolymer, comprising at least the following units:

- a polydimethylsiloxane (PDMS) unit comprising at least two polymerizable radical groups chosen from an acrylic or methacrylic group having from 1 to 6 carbon atoms, and

- an alkyl acrylate or methacrylate unit, the alkyl radical comprising from 1 to 30 carbon atoms, preferentially from 1 to 22 carbon atoms, better still 1 to 10 carbon atoms, and more preferentially 2 to 6 carbon atoms.

[0040] More particularly, the silicone acrylic copolymer comprises at least the following units:

- a polydimethylsiloxane (PDMS) unit comprising at least two polymerizable radical groups chosen from a C¾ = CH - CO - O - Ri- group, wherein Ri represents an alkyl radical comprising from 1 to 3 carbon atoms; and

- a C1-C30, preferably C1-C22, preferentially C1-C10 and better still C2-C6 alkyl acrylate or methacrylate unit. [0041] Even more particularly, the composition according to the invention comprises at least one silicone acrylic copolymer comprising at least the following units:

- a polydimethylsiloxane (PDMS) unit comprising at least two polymerizable radical groups chosen from a CEE = CH - CO - O - Ri- group, wherein Ri represents an alkyl radical comprising from 1 to 3 carbon atoms; and

- a C1-C22, preferably C1-C10 and better still C2-C6 alkyl acrylate or methacrylate unit.

[0042] More particularly still, the silicone acrylic copolymer according to the invention is a copolymer with the INCI name isobutyl methacrylate/bis-hydroxypropyl dimethicone acrylate copolymer, such as for example the compound sold by Grant Industries under the name Granacrysil BMAS.

[0043] It is an isobutyl methacrylate/bis-hydroxypropyl dimethicone acrylate copolymer in solution in isododecane.

[0044] The silicone acrylic copolymer(s) may be present in a total amount ranging from 1% to 50% by weight, preferably from 2% to 40% by weight, more preferentially from 3% to 30% by weight and better still from 5% to 20% by weight relative to the total weight of the composition.

Silicone resin

[0045] The composition according to the invention comprises at least one silicone resin.

[0046] More generally, the term“resin” is intended to mean a compound of which the structure is three-dimensional.“Silicone resins” are also referred to as“siloxane resins”. Thus, for the purposes of the present invention, a polydimethylsiloxane is not a silicone resin.

[0047] The silicone resin(s) according to the invention can be chosen from silicone resins having a molecular weight of between 300 and 100 000 g/mol, preferably between 300 and 50 000 g/mol, more preferentially between 300 and 30 000 g/mol. The term“molecular weight” is intended to mean average molecular weight (Mw).

[0048] The nomenclature of silicone resins (also known as siloxane resins) is known under the name “MDTQ”, the resin being described as a function of the various siloxane monomer units it comprises, each of the letters“MDTQ” characterizing a type of unit.

[0049] The letter M represents the monofunctional unit of formula RlR2R3SiOi_/2, the silicon atom being bonded to only one oxygen atom in the polymer comprising this unit.

[0050] The letter D means a difunctional unit RIR2S1O2/2 wherein the silicon atom is bonded to two oxygen atoms. [0051] The letter T represents a trifunctional unit of formula R1 S1O3_/2.

[0052] Such resins are described, for example, in the Encyclopedia of Polymer Science and Engineering, vol. 15, John Wiley and Sons, New York, (1989), pp. 265-270, and US 2 676 182, US

3 627 851, US 3 772 247, US 5 248 739 or else US 5 082 706, US 5 319 040, US 5 302 685 and US

4 935 484.

[0053] In the units M, D and T defined previously, R, namely Rl, R2 and R3, represents a hydrocarbon-based radical (especially alkyl) containing from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or a hydroxyl group.

[0054] Finally, the letter Q means a tetrafunctional unit S1O4/2 wherein the silicon atom is bonded to four oxygen atoms, which are themselves bonded to the rest of the polymer.

[0055] Various silicone resins with different properties may be obtained from these different units, the properties of these polymers varying as a function of the type of monomer (or unit), the nature and number of the radical R, the length of the polymer chain, the degree of branching and the size of the side chains.

[0056] As silicone resins that may be used in the compositions according to the invention, use may be made, for example, of silicone resins of MQ type, of T type or of MQT type.

[0057] MQ resins:

[0058] As examples of silicone resins of MQ type, mention may be made of the alkyl siloxysilicates of formula [(Rl)₃Si0i_/2]_x(Si0₂)y (MQ units) wherein x and y are integers ranging from 50 to 80, and such that the group Rl represents a radical as defined previously, and is preferably an alkyl group containing from 1 to 8 carbon atoms or a hydroxyl group, preferably a methyl group.

[0059] As examples of solid silicone resins of MQ type of trimethyl siloxysilicate type, mention may be made of those sold under the reference SR1000®, E 1 170-002® or SS 4230® by the company General Electric, under the reference TMS 803®, WACKER 803® and 804® by the company Wacker, under the name“KF-7312J®” by the company Shin-Etsu,“DC 749®”,“DC 593®” by the company Dow Coming, under the name Silsoft 74 by the company Momentive Performance Materials.

[0060] As silicone resins comprising MQ siloxysilicate units, mention may also be made of phenylalkylsiloxysilicate resins, such as phenylpropyldimethylsiloxysilicate (Silshine 151® sold by the company General Electric). The preparation of such resins is described especially in patent US 5 817 302.

[0061] T resins: [0062] Examples of silicone resins of type T that may be mentioned include the polysilsesquioxanes of formula (RSi03_/2)x (T units) wherein x is greater than 100 and such that the group R is an alkyl group containing from 1 to 10 carbon atoms, said polysilsesquioxanes also possibly comprising Si- OH end groups.

[0063] Polymethylsilsesquioxane resins that may preferably be used are those wherein R

represents a methyl group, for instance those sold:

- by the company Wacker under the reference Resin MK®, such as Belsil PMS MK®: polymer comprising CH₃S1O_3/2 repeating units (T units), which may also comprise up to 1% by weight of (CH₃)₂Si0_2/2 units (D units) and having an average molecular weight of about 10 000 g/mol, or

- by the company Shin-Etsu under the references KR 220L®, which are composed of T units of formula CH3S1O3/2 and contain Si-OH (silanol) end groups, under the reference KR- 242A®, which comprise 98% of T units and 2% of dimethyl D units and contain Si-OH end groups, or else under the reference KR 251®, comprising 88% of T units and 12% of dimethyl D units and contain Si-OH end groups, or

- by the company Grant Industries under the name Granresin PMSQ ID containing 80% of polymethylsilsesquioxane in isododecane.

[0064] MQT resins:

[0065] Resins comprising MQT units that are especially known are those mentioned in US 5 110 890.

[0066] A preferred form of resins of MQT type are MQT-propyl (also known as MQTpr) resins. Such resins that may be used in the compositions according to the invention are especially the resins described and prepared in patent application WO 2005/075 542, the content of which is incorporated herein by reference.

[0067] The MQ-T-propyl resin preferably comprises the following units:

(I) (Rl₃SlOi/₂)a

(II) (R2₂Si0_2/2)b

(iii) (R3Si03_/2)_c and

(iv) (Si0_4/2)d

[0068] With Rl, R2 and R3 independently representing a hydrocarbon-based radical (especially alkyl) containing from 1 to 10 carbon atoms, a phenyl group, a phenylalkyl group or a hydroxyl group and preferably an alkyl radical containing from 1 to 8 carbon atoms or a phenyl group, a, b, c and d being mole fractions,

a being between 0.05 and 0.5,

b being between 0 and 0.3,

c being greater than zero,

d being between 0.05 and 0.6,

a + b + c + d = l,

on condition that more than 40 mol% of the groups R3 of the siloxane resin are propyl groups.

[0069] Preferably, the siloxane resin comprises the units:

(l) (Rl₃SlOi/₂)a

(iii) (R3Si0_3/2)_c and

(iv) (Si0_4/2)d

With R1 and R3 independently representing an alkyl group containing from 1 to 8 carbon atoms, R1 preferably being a methyl group and R3 preferably being a propyl group,

a being between 0.05 and 0.5 and preferably between 0.15 and 0.4,

c being greater than zero, preferably between 0.15 and 0.4,

d being between 0.05 and 0.6, preferably between 0.2 and 0.6 or alternatively between 0.2 and 0.55,

a + b + c + d = 1, and a, b, c and d being mole fractions,

[0070] The siloxane resins that may be used according to the invention may be obtained via a process comprising the reaction of:

A) an MQ resin comprising at least 80 mol% of units (Rl₃SiOi_/2)_a and (SiC>4_/2)_d,

R1 representing an alkyl group containing from 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group,

a and d being greater than zero,

the ratio a/d being between 0.5 and 1.5; and

B) a T-propyl resin comprising at least 80 mol% of units (R3Si0_3/2)_c, R3 representing an alkyl group containing from 1 to 8 carbon atoms, an aryl group, a carbinol group or an amino group,

c being greater than zero,

on condition that at least 40 mol% of the groups R3 are propyl groups,

wherein the weight ratio A/B is between 95/5 and 15/85 and preferably the weight ratio A/B is 30/70.

[0071] Advantageously, the weight ratio A/B is between 95/5 and 15/85. Preferably, the ratio A/B is less than or equal to 70/30. These preferred ratios have proven to afford comfortable deposits.

[0072] Preferably, the composition according to the invention comprises, as silicone resin, at least one silicone resin of type T, better still a silicone resin of polysilsesquioxane type of formula (RSiC>3_/2)_x wherein x is greater than 100 and the R group is an alkyl group having from 1 to 10 carbon atoms, more preferentially at least one silicone resin of polymethylsilsesquioxane type.

[0073] According to one preferred embodiment of the invention, the silicone resin is present in the composition in a content ranging from 0.01% to 10% by weight, preferably ranging from 0.05% to 5% by weight and more preferentially ranging from 0.05% to 3% by weight, relative to the total weight of the composition.

Pigment

[0074] The composition according to the invention comprises at least one pigment.

[0075] The term“pigment” is intended to mean white or colored particles of any shape, which are insoluble in the composition wherein they are present.

[0076] The pigments that may be used are especially chosen from the organic and/or mineral pigments known in the art, notably those described in Kirk-Othmer’s Encyclopedia of Chemical Technology and in Ullmann’s Encyclopedia of Industrial Chemistry.

[0077] They may be natural, of natural origin, or non-natural.

[0078] These pigments may be in pigment powder or paste form. They may be coated or uncoated.

[0079] The pigments may be chosen, for example, from mineral pigments, organic pigments, lakes, pigments with special effects such as nacres or glitter flakes, and mixtures thereof.

[0080] The pigment may be a mineral pigment. The term“mineral pigment” is intended to mean any pigment that satisfies the definition in Ullmann’s encyclopedia in the chapter on inorganic pigments. Among the mineral pigments that are useful in the present invention, mention may be made of ochres such as red ochre (clay (in particular kaolinite) and iron hydroxide (for example hematite)), brown ochre (clay (in particular kaolinite) and limonite), yellow ochre (clay (in particular kaolinite) and goethite); titanium dioxide, optionally surface treated; zirconium oxide or cerium oxide; zinc oxide, iron oxide (black, yellow or red) or chromium oxide; manganese violet, ultramarine blue, chromium hydrate and ferric blue; metal powders such as aluminum powder or copper powder.

[0081] Mention may also be made of alkaline-earth metal carbonates (such as calcium carbonate or magnesium carbonate), silicon dioxide, quartz and any other compound used as inert fdler in cosmetic compositions, provided that these compounds contribute color or whiteness to the composition under the conditions under which they are employed.

[0082] The pigment may be an organic pigment. The term“organic pigment” is intended to mean any pigment that satisfies the definition in Ullmann’s Encyclopedia in the chapter on organic pigments.

[0083] The organic pigment may especially be chosen from nitroso, nitro, azo, xanthene, pyrene, quinoline, anthraquinone, triphenylmethane, fluorane, phthalocyanine, metal-complex, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, indigo, thioindigo, dioxazine, triphenylmethane and quinophthalone compounds.

[0084] Use may also be made of any mineral or organic compound that is insoluble in the composition and standard in the cosmetics field, provided that these compounds contribute color or whiteness to the composition under the conditions under which they are employed, for example guanine, which, according to the refractive index of the composition, is a pigment.

[0085] In particular, the white or colored organic pigments may be chosen from carmine, carbon black, aniline black, azo yellow, quinacridone, phthalocyanine blue, the blue pigments codified in the Color Index under the references Cl 42090, 69800, 69825, 74100, 74160, the yellow pigments codified in the Color Index under the references Cl 11680, 11710, 19140, 20040, 21100, 21108, 47000, 47005, the green pigments codified in the Color Index under the references Cl 61565, 61570, 74260, the orange pigments codified in the Color Index under the references Cl 11725, 45370, 71105, the red pigments codified in the Color Index under the references Cl 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 26100, 45380, 45410, 58000, 73360, 73915, 75470, the pigments obtained by oxidative polymerization of indole or phenol derivatives as described in patent FR 2 679 771.

[0086] Examples that may also be mentioned include pigment pastes of organic pigment, such as the products sold by the company Hoechst under the names:

[0087] - Cosmenyl Yellow IOG: Yellow 3 pigment (Cl 11710);

[0088] - Cosmenyl Yellow G: Yellow 1 pigment (Cl 11680);

[0089] - Cosmenyl Orange GR: Orange 43 pigment (Cl 71105); [0090] - Cosmenyl Red R: Red 4 pigment (Cl 12085);

[0091] - Carmine Cosmenyl FB: Red 5 pigment (Cl 12490);

[0092] - Cosmenyl Violet RL: Violet 23 pigment (Cl 51319);

[0093] - Cosmenyl Blue A2R: Blue 15.1 pigment (Cl 74160);

[0094] - Cosmenyl Green GG: Green 7 pigment (Cl 74260);

[0095] - Cosmenyl Black R: Black 7 pigment (Cl 77266).

[0096] The pigments in accordance with the invention may also be in the form of composite pigments, as described in patent EP 1 184 426. These composite pigments may be composed notably of particles comprising a mineral core, at least one binder, for attaching the organic pigments to the core, and at least one organic pigment which at least partially covers the core.

[0097] The organic pigment may also be a lake. The term“lake” is intended to mean dyes adsorbed onto insoluble particles, the assembly thus obtained remaining insoluble during use.

[0098] The mineral substrates onto which the dyes are adsorbed are, for example, alumina, silica, calcium sodium borosilicate or calcium aluminum borosilicate and aluminum.

[0099] Among the dyes, mention may be made of carminic acid. Mention may also be made of the dyes known under the following names: D&C Red 21 (Cl 45 380), D&C Orange 5 (Cl 45 370), D&C Red 27 (Cl 45 410), D&C Orange 10 (Cl 45 425), D&C Red 3 (Cl 45 430), D&C Red 4 (Cl 15 510), D&C Red 33 (Cl 17 200), D&C Yellow 5 (Cl 19 140), D&C Yellow 6 (Cl 15 985), D&C Green (Cl 61 570), D&C Yellow 10 (Cl 77 002), D&C Green 3 (Cl 42 053), D&C Blue 1 (Cl 42 090).

[00100] An example of a lake that may be mentioned is the product known under the following name :

D&C Red 7 (Cl 15 850: 1).

[00101] The pigment may also be a pigment with special effects. The term“pigments with special effects” is intended to mean pigments that generally create a colored appearance (characterized by a certain shade, a certain vivacity and a certain level of luminance) that is non-uniform and that changes as a function of the conditions of observation (light, temperature, angles of observation, etc.). They thereby contrast with colored pigments, which afford a conventional opaque, semitransparent or transparent, uniform color.

[00102] Several types of pigment with special effects exist: those with a low refractive index, such as fluorescent or photochromic pigments, and those with a higher refractive index, such as nacres, interference pigments or glitter flakes.

[00103] Examples of pigments with special effects that may be mentioned include nacreous pigments such as mica coated with titanium or with bismuth oxychloride, colored nacreous pigments such as mica coated with titanium and iron oxides, mica coated with iron oxide, mica coated with titanium and especially with ferric blue or with chromium oxide, mica coated with titanium and with an organic pigment as defined above, and also nacreous pigments based on bismuth oxychloride. Nacreous pigments that may be mentioned include the Cellini nacres sold by Engelhard (mica-TiCE-lake), Prestige sold by Eckart (mica-TiCE), Prestige Bronze sold by Eckart (mica-Fe203), and Colorona sold by Merck (mica-TiCE-F e2CE) .

[00104] Mention may also be made of the gold-colored nacres sold especially by Engelhard under the name Brilliant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne); the bronze nacres sold especially by Merck under the name Bronze fine (17384) (Colorona) and Bronze (17353) (Colorona) and by Engelhard under the name Super bronze (Cloisonne); the orange nacres sold especially by Engelhard under the name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by Merck under the name Passion orange (Colorona) and Matte orange (17449) (Microna); the brown-colored nacres sold especially by Engelhard under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite); the nacres with a coppery glint sold especially by Engelhard under the name Copper 340A (Timica); the nacres with a red glint sold especially by Merck under the name Sienna fine (17386) (Colorona); the nacres with a yellow glint sold especially by Engelhard under the name Yellow (4502) (Chromalite); the red- colored nacres with a gold glint sold especially by Engelhard under the name Sunstone GO 12 (Gemtone); the pink nacres sold especially by Engelhard under the name Tan opale G005 (Gemtone); the black nacres with a gold glint sold especially by Engelhard under the name Nu antique bronze 240 AB (Timica), the blue nacres sold especially by Merck under the name Matte blue (17433) (Microna), the white nacres with a silvery glint sold especially by Merck under the name Xirona Silver, and the golden- green pink-orange nacres sold especially by Merck under the name Indian summer (Xirona), and mixtures thereof.

[00105] Still as examples of nacres, mention may also be made of particles comprising a borosilicate substrate coated with titanium oxide.

[00106] Particles comprising a glass substrate coated with titanium oxide are sold in particular under the name Metashine MC1080RY by the company Toyal.

[00107] Finally, as examples of nacres, mention may also be made of polyethylene terephthalate glitter flakes, in particular those sold by the company Meadowbrook Inventions under the name Silver IP 0.004X0.004 (silver glitter flakes). It is also possible to envision multilayer pigments based on synthetic substrates, such as alumina, silica, calcium sodium borosilicate or calcium aluminum borosilicate, and aluminum.

[00108] The pigments with special effects may also be chosen from reflective particles, i.e. especially from particles of which the size, structure, especially the thickness of the layer(s) of which they are made and their physical and chemical natures, and the surface finish, allow them to reflect incident light. This reflection may, where appropriate, have an intensity sufficient to create at the surface of the composition or of the mixture, when it is applied to the support to be made up, highlight points that are visible to the naked eye, i.e. more luminous points that contrast with their environment by appearing to sparkle.

[00109] The reflective particles may be selected so as not to significantly alter the coloring effect generated by the coloring agents with which they are combined, and more particularly so as to optimize this effect in terms of color rendition. They may more particularly have a yellow, pink, red, bronze, orange, brown, gold and/or coppery color or glint.

[00110] These particles may have varied forms and may especially be in platelet or globular form, in particular in spherical form.

[00111] Irrespective of their form, the reflective particles may or may not have a multilayer structure, and, in the case of a multilayer structure, may have, for example, at least one layer of uniform thickness, especially of a reflective material.

[00112] When the reflective particles do not have a multilayer structure, they may be composed, for example, of metal oxides, especially titanium or iron oxides obtained synthetically.

[00113] When the reflective particles have a multilayer structure, they may comprise, for example, a natural or synthetic substrate, especially a synthetic substrate at least partially coated with at least one layer of a reflective material, especially of at least one metal or metallic material. The substrate may be made of one or more organic and/or mineral materials.

[00114] More particularly, it may be chosen from glasses, ceramics, graphite, metal oxides, aluminas, silicas, silicates, especially aluminosilicates and borosilicates, and synthetic mica, and mixtures thereof, this list not being limiting.

[00115] The reflective material may comprise a layer of metal or of a metallic material.

[00116] Reflective particles are described especially in JP-A-09188830, JP-A-10158450, JP-A- 10158541, JP-A-07258460 and JP-A-05017710.

[00117] Still as an example of reflective particles including a mineral substrate coated with a layer of metal, mention may also be made of particles including a silver-coated borosilicate substrate.

[00118] Particles with a silver-coated glass substrate, in the form of platelets, are sold under the name Microglass Metashine REFSX 2025 PS by the company Toyal. Particles with a glass substrate coated with nickel/chromium/molybdenum alloy are sold under the names Crystal Star GF 550 and GF 2525 by this same company. [00119] Use may also be made of particles comprising a metal substrate, such as silver, aluminum, iron, chromium, nickel, molybdenum, gold, copper, zinc, tin, magnesium, steel, bronze or titanium, said substrate being coated with at least one layer of at least one metal oxide, such as titanium oxide, aluminum oxide, iron oxide, cerium oxide, chromium oxide, silicon oxides and mixtures thereof.

[00120] Examples that may be mentioned include aluminum powder, bronze powder or copper powder coated with SiCh sold under the name Visionaire by Eckart.

[00121] Mention may also be made of pigments with an interference effect which are not attached to a substrate, such as liquid crystals (Helicones HC from Wacker) or interference holographic glitter flakes (Geometric Pigments or Spectra f/x from Spectratek). Pigments with special effects also comprise fluorescent pigments, whether these are substances that are fluorescent in daylight or that produce an ultraviolet fluorescence, phosphorescent pigments, photochromic pigments, thermochromic pigments and quantum dots, sold, for example, by the company Quantum Dots Corporation.

[00122] Quantum dots are luminescent semiconductor nanoparticles that are capable of emitting, under light excitation, radiation with a wavelength of between 400 nm and 700 nm. These nanoparticles are known from the literature. In particular, they may be synthesized according to the processes described, for example, in US 6 225 198 or US 5 990 479, in the publications cited therein and also in the following publications: Dabboussi B.O. et ah,“(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites”, Journal of Physical Chemistry B, vol. 101, 1997, pages 9463-9475, and Peng, Xiaogang et ak,“Epitaxial growth of highly luminescent CdSe/CdS core/shell nanocrystals with photostability and electronic accessibility”, Journal of the American Chemical Society, vol. 119, No. 30, pages 7019-7029.

[00123] The variety of pigments that may be used in the present invention makes it possible to obtain a wide range of colors, and also particular optical effects such as metallic effects or interference effects.

[00124] The size of the pigment used in the composition according to the present invention is generally between 10 nm and 200 pm, preferably between 20 nm and 80 pm and more preferably between 30 nm and 50 pm.

[00125] The pigments may be dispersed in the product by means of a dispersant.

[00126] The dispersant serves to protect the dispersed particles against agglomeration or flocculation thereof. This dispersant may be a surfactant, an oligomer, a polymer or a mixture of several thereof, bearing one or more functionalities with strong affinity for the surface of the particles to be dispersed. In particular, they may become physically or chemically attached to the surface of the pigments. These dispersants also contain at least one functional group that is compatible with or soluble in the continuous medium. In particular, 12-hydroxystearic acid esters in particular and Cs to C20 fatty acid esters of polyols such as glycerol or diglycerol are used, such as poly( 12-hydroxystearic acid) stearate with a molecular weight of approximately 750 g/mol, such as the product sold under the name Solsperse 21 000 by Avecia, polyglyceryl-2 dipolyhydroxystearate (CTFA name) sold under the reference Dehymyls PGPH by Henkel, or else polyhydroxystearic acid such as the product sold under the reference Arlacel PI 00 by Uniqema, and mixtures thereof.

[00127] As other dispersants that may be used in the compositions of the invention, mention may be made of quaternary ammonium derivatives of poly condensed fatty acids, for instance Solsperse 17 000 sold by Avecia, and polydimethylsiloxane/oxypropylene mixtures such as those sold by Dow Coming under the references DC2-5185 and DC2-5225 C.

[00128] The pigments used in the composition may be surface-treated with an organic agent.

[00129] Thus, the pigments that have been surface-treated beforehand, which are useful in the context of the invention, are pigments that have totally or partially undergone a surface treatment of chemical, electronic, electrochemical, mechanochemical or mechanical nature, with an organic agent such as those described especially in Cosmetics and Toiletries, February 1990, Vol. 105, pages 53-64, before being dispersed in the composition in accordance with the invention. These organic agents may be chosen, for example, from waxes, for example camauba wax and beeswax; fatty acids, fatty alcohols and derivatives thereof, such as stearic acid, hydroxystearic acid, stearyl alcohol, hydroxystearyl alcohol and lauric acid and derivatives thereof; anionic surfactants; lecithins; sodium, potassium, magnesium, iron, titanium, zinc or aluminum salts of fatty acids, for example aluminum stearate or laurate; metal alkoxides; polyethylene; (meth)acrylic polymers, for example polymethyl methacrylates; polymers and copolymers containing acrylate units; alkanolamines; silicone compounds, for example silicones, in particular polydimethylsiloxanes; organofluorine compounds, for example perfluoroalkyl ethers; fluorosilicone compounds.

[00130] The surface-treated pigments that are useful in the composition may also have been treated with a mixture of these compounds and/or may have undergone several surface treatments.

[00131] The surface-treated pigments that are useful in the context of the present invention may be prepared according to surface-treatment techniques that are well known to those skilled in the art, or may be commercially available as is.

[00132] Preferably, the surface-treated pigments are coated with an organic layer.

[00133] The organic agent with which the pigments are treated may be deposited on the pigments by solvent evaporation, chemical reaction between the molecules of the surface agent or creation of a covalent bond between the surface agent and the pigments.

[00134] The surface treatment may thus be performed, for example, by chemical reaction of a surface agent with the surface of the pigments and creation of a covalent bond between the surface agent and the pigments or the fdlers. This method is notably described in patent US 4 578 266. [00135] An organic agent covalently bonded to the pigments will preferably be used.

[00136] The agent for the surface treatment may represent from 0.1 % to 50% by weight of the total weight of the surface-treated pigment, preferably from 0.5% to 30% by weight and even more preferentially from 1% to 20% by weight of the total weight of the surface-treated pigment.

[00137] Preferably, the surface treatments of the pigments are chosen from the following treatments:

- a PEG-silicone treatment, for instance the AQ surface treatment sold by LCW;

- a methicone treatment, for instance the SI surface treatment sold by LCW;

- a dimethicone treatment, for instance the Covasil 3.05 surface treatment sold by LCW;

- a dimethicone/trimethyl siloxysilicate treatment, for instance the Covasil 4.05 surface treatment sold by LCW;

- a magnesium myristate treatment, for instance the MM surface treatment sold by LCW;

- an aluminum dimyristate treatment, such as the MI surface treatment sold by Miyoshi;

- a perfluoropolymethylisopropyl ether treatment, for instance the LHC surface treatment sold by LCW;

- an isostearyl sebacate treatment, for instance the HS surface treatment sold by Miyoshi;

- a perfluoroalkyl phosphate treatment, for instance the PL surface treatment sold by Daito;

- an acrylate/dimethicone copolymer and perfluoroalkyl phosphate treatment, for instance the PSA surface treatment sold by Daito;

- a polymethylhydrosiloxane/perfluoroalkyl phosphate treatment, for instance the PS01 surface treatment sold by Daito;

- an acrylate/dimethicone copolymer treatment, for instance the ASC surface treatment sold by Daito;

- an isopropyl titanium triisostearate treatment, for instance the ITT surface treatment sold by Daito;

- an acrylate copolymer treatment, for instance the APD surface treatment sold by Daito;

- a perfluoroalkyl phosphate/isopropyl titanium triisostearate treatment, for instance the PL + ITT surface treatment sold by Daito.

[00138] According to one particular embodiment of the invention, the dispersant is present with organic or mineral pigments in submicron-sized particulate form in the dye composition. [00139] The term“submicron” is understood to mean pigments having a particulate size that has been micronized by a micronization method and having a mean particle size of less than a micrometer (pm), in particular between 0.1 and 0.9 pm, and preferably between 0.2 and 0.6 pm.

[00140] According to one embodiment, the dispersant and the pigment or pigments are present in an amount (dispersantpigment) of between 0.5: 1 and 2: 1, particularly between 0.75: 1 and 1.5: 1 or better still between 0.8: 1 and 1.2: 1.

[00141] According to one particular embodiment, the dispersant is suitable for dispersing the pigments and is compatible with a condensation-curable formulation.

[00142] The term“compatible” is understood to mean, for example, that said dispersant is miscible in the oily phase of the composition or of the dispersion containing the pigment(s), and it does not retard or reduce the curing. The dispersant is preferably cationic.

[00143] The dispersant(s) may therefore have a silicone backbone, such as silicone polyether and dispersants of aminosilicone type. Among the suitable dispersants, mention may be made of:

aminosilicones, i.e. silicones comprising one or more amino groups such as those sold under the names and references: BYK LPX 21879 by BYK, GP-4, GP-6, GP-344, GP-851, GP-965, GP-967 and GP-988-1, sold by Genesee Polymers,

silicone acrylates such as Tego ® RC 902, Tego ® RC 922, Tego ® RC 1041, and Tego ® RC 1043, sold by Evonik,

polydimethylsiloxane (PDMS) silicones with carboxyl groups such as X- 22162 and X-22370 by Shin-Etsu, epoxy silicones such as GP-29, GP-32, GP-502, GP-504, GP-514, GP-607, GP-682, and GP-695 by Genesee Polymers, or Tego ® RC 1401, Tego ® RC 1403, Tego ® RC 1412 by Evonik.

[00144] According to one particular embodiment, the dispersant(s) is (are) of aminosilicone type and are positively charged.

[00145] Preferably, the pigment(s) is (are) chosen from mineral, mixed mineral-organic or organic pigments.

[00146] In one variant of the invention, the pigment(s) according to the invention are organic pigments, preferentially organic pigments, surface-treated with an organic agent chosen from silicone compounds, in particular polydimethylsiloxane s. In another variant of the invention, the pigment(s) according to the invention are mineral pigments.

[00147] The total amount of pigment(s) may range from 0.01% to 30% by weight, more particularly from 0.05% to 20% by weight, preferably from 0.1% to 15% by weight and preferably from 1% to 10% by weight relative to the total weight of the composition. [00148] The composition according to the invention may comprise water, present in a content ranging from 0% to 40% by weight, more preferentially from 0% to 25% by weight, relative to the weight of the composition.

[00149] The composition according to the invention may comprise less than 2% by weight of water or even less than 0.5% by weight of water, relative to the total weight of the composition.

[00150] Preferably, the composition does not comprise any water.

Oils

[00151] The composition may comprise one or more oil(s).

[00152] Preferably, the composition comprises one or more oil(s) chosen from alkanes.

[00153] The term“oil” is intended to mean a fatty substance that is liquid at ambient temperature (25°C) and at atmospheric pressure (760 mmHg or 1.013 x l0⁵ Pa).

[00154] The oil can be volatile or nonvolatile.

[00155] The term“volatile oil” is intended to mean an oil that can evaporate on contact with the skin in less than one hour, at ambient temperature and atmospheric pressure. The volatile oil is a cosmetic volatile oil, which is liquid at ambient temperature. More specifically, a volatile oil has an evaporation rate of between 0.01 and 200 mg/cm²/min, limits included (see protocol for measuring the evaporation rate indicated in the text below).

[00156] The term“nonvolatile oil” is intended to mean an oil that remains on the skin or the keratin fiber at ambient temperature and atmospheric pressure. More specifically, a nonvolatile oil has an evaporation rate of strictly less than 0.01 mg/cm²/min (see protocol for measuring the evaporation rate indicated in the text below).

[00157] Preferably, the composition comprises one or more oil(s) chosen from G,-C i alkanes and/or mixtures thereof.

[00158] As regards the G-Gr_> alkanes, they may be linear or branched, and possibly cyclic.

[00159] Mention may in particular be made of branched G-C i alkanes, such as CVGr_> isoalkanes (also known as isoparaffins), isododecane, isodecane or isohexadecane, and for example the oils sold under the Isopar or Permethyl trade names, and mixtures thereof.

[00160] Mention may also be made of linear alkanes, preferably of plant origin, comprising from 7 to 15 carbon atoms, in particular from 9 to 14 carbon atoms and more particularly from 11 to 13 carbon atoms.

[00161] As examples of linear alkanes that are suitable for the invention, mention may be made of n- heptane (C7), n-octane (C8), n-nonane (C9), n-decane (CIO), n-undecane (Cl l), n-dodecane (C12), n- tridecane (C13), n-tetradecane (C14) and n-pentadecane (C15), and mixtures thereof, and in particular the mixture of n-undecane (C 11) and n-tridecane (C13) described in Example 1 of patent application WO 2008/155 059 by the company Cognis.

[00162] Mention may also be made of n-dodecane (C12) and n-tetradecane (C14) sold by Sasol under the references, respectively, Parafol 12-97 and Parafol 14-97, and also mixtures thereof.

[00163] As examples of alkanes that are suitable for the invention, mention may be made of the alkanes described in patent applications WO 2007/068 371 and WO 2008/155 059. These alkanes are obtained from fatty alcohols, which are themselves obtained from coconut oil or palm oil.

[00164] According to one particular embodiment, the composition comprises isododecane. Such a compound is, for example, the isododecane sold under the reference Isododecane by Ineos.

[00165] Preferably, the composition according to the invention comprises one or more oil(s) chosen from C₈-Ci₆ alkanes, more preferentially from isododecane, isohexadecane, tetradecane and/or mixtures thereof.

[00166] Preferably, the composition comprises isododecane.

[00167] The composition according to the invention may comprise one or more oils present in a total amount of between 10% and 99% by weight, preferably between 20% and 95% by weight and better still between 30% and 90% by weight, relative to the total weight of the composition.

[00168] The composition according to the invention may also contain at least one agent customarily used in cosmetics, for example chosen from reducing agents, thickeners, softeners, antifoams, moisturizers, UV-screening agents, peptizers, solubilizers, fragrances, anionic, cationic, nonionic or amphoteric surfactants, proteins, vitamins, cationic polymers, silicone polymers other than the silicon acrylic polymers described above.

[00169] The dye composition according to the invention may especially be in the form of a suspension, a dispersion, a gel, an emulsion, especially an oil-in-water (O/W) or water-in-oil (W/O) emulsion, or a multiple (W/O/W or polyol/O/W or O/W/O) emulsion, in the form of a cream, a mousse, a stick, a dispersion of vesicles, especially of ionic or nonionic lipids, or a two-phase or multi-phase lotion.

[00170] A person skilled in the art may select the appropriate presentation form, and also the method for preparing it, on the basis of his general knowledge, taking into account firstly the nature of the constituents used, especially their solubility in the support, and secondly the intended application of the composition.

Process for dyeing and removing makeup from and/or cleansing keratin fibers [00171] The present invention relates to a process for treating human keratin fibers such as the hair comprising a step of applying to the keratin fibers a dye composition as described above, and a step of applying to the dyed keratin fibers a makeup-removing composition comprising at least one hydrocarbon-based oil.

[00172] Preferably, the process for treating human keratin fibers such as the hair relates to a process for treating the hair comprising a step of applying to the hair a dye composition as described above, and a step of applying to the dyed hair a makeup-removing composition as described above.

[00173] The dye composition corresponds to the composition for treating human keratin fibers such as the hair, described above.

Makeup-removing composition

[00174] The makeup-removing composition may be in the form of an emulsion, a microemulsion, a two-phase composition or an anhydrous composition.

[00175] The term“anhydrous composition” is intended to mean a composition which contains less than 2% by weight of water, or even less than 0.5% of water relative to the total weight of the composition, or in particular a composition free of water, the water not being added during the preparation of the composition but corresponding to the residual water provided by the mixed ingredients.

[00176] When the composition according to the invention is an emulsion, a microemulsion or a two- phase composition, it comprises an aqueous phase and an oily phase. The emulsions or microemulsions, on the one hand, and the two-phase compositions on the other hand, according to the invention are distinguished by the fact that the two-phase compositions are constituted of two phases which, at rest, are visibly distinct from one another other instead of being emulsified in one another.

[00177] When the composition is in the form of an emulsion, it may be a water-in-oil (W/O) or oil- in-water (O/W) emulsion, or a multiple (W/O/W or O/W/O) emulsion.

[00178] “Microemulsion” denotes a thermodynamically stable isotropic single liquid phase containing a ternary system having three components comprising an oily component, an aqueous component and a surfactant. In the present context, the term“microemulsion” denotes a“microemulsion in the narrow sense”, i.e. a thermodynamically stable isotropic single liquid phase.

[00179] The microemulsion may be of O/W (oil-in- water) type wherein the oil is solubilized by micelles, a microemulsion of W/O (water-in-oil) type wherein the water is solubilized by reverse micelles, or a bicontinuous microemulsion wherein the number of associations of surfactant molecules tends to infinity such that the aqueous phase and the oily phase both have a continuous structure. [00180] The microemulsion may have a dispersed phase with a number-average diameter of 100 nm or less, preferably 50 nm or less and more preferably 20 nm or less, measured by laser particle size analysis.

[00181] Preferably, the makeup-removing composition according to the invention is in the form of a water-in-oil emulsion or a water-in-oil microemulsion.

[00182] More preferentially, the makeup-removing composition according to the invention is in the form of a water-in-oil microemulsion.

Oily phase

[00183] Preferably, the makeup -removing composition comprises an oily phase.

[00184] The content of oily phase in the makeup-removing composition varies according to the formulation of the makeup composition (emulsion, microemulsion, anhydrous, etc.).

[00185] The oily phase comprises at least one hydrocarbon-based oil and may further comprise one or more fatty substances other than the hydrocarbon-based oils as described below.

Hydrocarbon-based oil

[00186] The makeup-removing composition according to the invention comprises at least one hydrocarbon-based oil. Preferably, the oily phase of the makeup-removing composition comprises at least one hydrocarbon-based oil.

[00187] The term“oil” is intended to mean a fatty substance that is liquid at ambient temperature (25°C) and at atmospheric pressure (760 mmHg or 1.013 x 10⁵ Pa).

[00188] The term“fatty substance” is intended to mean an organic compound that is insoluble in water at ordinary temperature (25 °C) and at atmospheric pressure (760 mmHg or 1 .013 1 (f Pa) (solubility of less than 5%, preferably of less than 1% and even more preferentially of less than 0.1%). They bear in their structure at least one hydrocarbon-based chain comprising at least 6 carbon atoms or a sequence of at least two siloxane groups. In addition, the fatty substances are generally soluble in organic solvents under the same temperature and pressure conditions, for instance chloroform, dichloromethane, carbon tetrachloride, ethanol, benzene, toluene, tetrahydrofuran (THF), liquid petroleum jelly or decamethylcyclopentasiloxane.

[00189] The term“hydrocarbon-based oil” is intended to mean an oil formed essentially from, or even constituted of, carbon and hydrogen atoms, and optionally oxygen and nitrogen atoms, and not containing any silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and/or amide groups. [00190] Mention may be made of volatile hydrocarbon-based oils and nonvolatile hydrocarbon-based oils. Preferably, the makeup-removing composition comprises at least one nonvolatile hydrocarbon- based oil.

[00191] The term“nonvolatile oil” is intended to mean an oil that remains on the skin or the keratin fiber at ambient temperature and atmospheric pressure. More precisely, a nonvolatile oil has an evaporation rate strictly less than 0.01 mg/cm²/min.

[00192] To measure this evaporation rate, 15 g of oil or of oil mixture to be tested are placed in a crystallizing dish 7 cm in diameter, which is placed on a balance in a large chamber of about 0.3 m³ that is temperature regulated, at a temperature of 25°C, and hygrometry regulated, at a relative humidity of 50%. The liquid is allowed to evaporate freely, without stirring it, while providing ventilation by means of a fan (Papst-Motoren, reference 8550 N, rotating at 2700 rpm) placed in a vertical position above the crystallizing dish containing said oil or said mixture, the blades being directed toward the crystallizing dish, 20 cm away from the bottom of the crystallizing dish. The weight of oil remaining in the crystallizing dish is measured at regular intervals. The evaporation rates are expressed in mg of oil evaporated per unit of area (cm²) and per unit of time (minutes).

[00193] The nonvolatile hydrocarbon-based oils that are suitable for the present invention may be chosen in particular from:

- hydrocarbon-based oils of plant origin, such as triglycerides constituted of fatty acid esters of glycerol, the fatty acids of which may have chain lengths ranging from C4 to C28, these fatty acids possibly being linear or branched, and saturated or unsaturated; these oils are in particular wheatgerm oil, sunflower oil, beauty-leaf oil, grapeseed oil, sesame oil, com oil, apricot oil, castor oil, shea oil, avocado oil, olive oil, soybean oil, sweet almond oil, rapeseed oil, cottonseed oil, hazelnut oil, macadamia oil, jojoba oil, palm oil, alfalfa oil, poppy oil, pumpkin oil, sesame oil, marrow oil, rapeseed oil, blackcurrant oil, evening primrose oil, millet oil, barley oil, quinoa oil, rye oil, safflower oil, candlenut oil, passion flower oil and musk rose oil; or alternatively caprylic/capric acid triglycerides such as those sold by the company Stearineries Dubois or those sold under the names Miglyol 810®, 812® and 818® by the company Sasol;

- synthetic ethers containing from 10 to 40 carbon atoms;

- linear or branched hydrocarbons, of mineral or synthetic origin, such as petroleum jelly, polybutenes, polydecenes and squalane;

synthetic esters and/or ethers such as the oils of formula R1COOR2 and/or R1OR2 wherein Ri represents the residue of a linear or branched fatty acid comprising from 1 to 40 carbon atoms and R2 represents a hydrocarbon chain, in particular a branched hydrocarbon chain containing from 1 to 40 carbon atoms, on condition that the total number of carbons of Ri + R₂ is > 10, such as for example purcellin oil (cetostearyl octanoate), isopropyl myristate, isopropyl palmitate, butyl stearate, C12 to C15 alkyl benzoate, hexyl laurate, diisopropyl adipate, isononyl isononanoate, 2- ethylhexyl palmitate, 2-hexyldecyl laurate, 2-octyldecyl palmitate, 2-octyldodecyl myristate or lactate, 2-diethylhexyl succinate, isostearyl isostearate, octanoates, decanoates or ricinoleates of alcohols or of polyalcohols, such as propylene glycol dioctanoate; hydroxylated esters such as isostearyl lactate and diisostearyl malate; lanolic acid, oleic acid, lauric acid or stearic acid esters; glyceryl or diglyceryl triisostearate; and pentaerythritol esters;

- fatty alcohols that are liquid at ambient temperature, containing a branched and/or unsaturated carbon chain having from 12 to 26 carbon atoms, for instance cetanol, octyldodecanol, stearyl alcohol, linoleyl alcohol, linolenyl alcohol, isostearyl alcohol, oleyl alcohol, 2-hexyldecanol, 2- butyloctanol or 2-undecylpentadecanol;

- fatty acids such as myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid and isostearic acid; and

- mixtures thereof.

[00194] Preferably, the makeup-removing composition according to the invention comprises a total content of nonvolatile hydrocarbon-based oil(s) ranging from 10% to 95% by weight, preferably from 20% to 80% by weight, and preferentially from 30% to 70% by weight, relative to the total weight of the makeup-removing composition.

[00195] The term“volatile oil” is intended to mean an oil that can evaporate on contact with the skin in less than one hour, at ambient temperature and atmospheric pressure. The volatile oil is a cosmetic volatile oil, which is liquid at ambient temperature. More specifically, a volatile oil has an evaporation rate of between 0.01 and 200 mg/cm²/min, limits included (see protocol for measuring the evaporation rate above).

[00196] The volatile hydrocarbon-based oils suitable for the invention may be chosen from hydrocarbon-based oils having from 7 to 16 carbon atoms. The volatile hydrocarbon-based oils may be chosen from branched alkanes and linear alkanes.

[00197] Volatile hydrocarbon-based oils having from 7 to 16 carbon atoms that may especially be mentioned include branched CVC 1 alkanes, for instance CVC 1 isoalkanes (also known as isoparaffins), isododecane, isodecane, isohexadecane and, for example, the oils sold under the trade name Isopar or Permethyl, branched CVCV esters, for instance isohexyl neopentanoate, and mixtures thereof. Preferably, the volatile hydrocarbon-based oil having from 7 to 16 carbon atoms is chosen from isododecane, isodecane and isohexadecane, and mixtures thereof, and is especially isododecane. [00198] As volatile hydrocarbon-based oils that may be used for the purposes of the present invention, mention may be made of linear alkanes, preferably of plant origin, comprising from 7 to 15 carbon atoms, in particular from 9 to 14 carbon atoms and more particularly from 11 to 13 carbon atoms.

[00199] As examples of linear alkanes that are suitable for the invention, mention may be made of n- heptane (C7), n-octane (C8), n-nonane (C9), n-decane (CIO), n-undecane (Cl l), n-dodecane (C12), n- tridecane (C13), n-tetradecane (C14) and -pentadecane (C15), and mixtures thereof, and in particular the mixture of n-undecane (Cl l) and n-tridecane (C13) described in Example 1 of patent application WO 2008/155 059 by the company Cognis. Mention may also be made of n-dodecane (C12) and n- tetradecane (C14) sold by Sasol under the references, respectively, Parafol 12-97 and Parafol 14-97, and also mixtures thereof.

[00200] In this case, the makeup-removing composition according to the invention comprises a total content of volatile hydrocarbon-based oil(s) ranging from 0.1% to 10% by weight and better still from 0.5% to 5% by weight, relative to the total weight of the makeup-removing composition.

[00201] The hydrocarbon-based oil(s) according to the invention may also be defined according to their molecular weight and their solubility parameter 5a.

[00202] Preferably, a hydrocarbon-based oil according to the invention has a molecular weight of less than or equal to 400 g/mol and a solubility parameter 5a ranging from 2 to 15 J^{0 5}/cm^{1 5}.

[00203] The definition and calculation of the solubility parameters in the Hansen three-dimensional solubility space are described in the article by C.M. Hansen: “The three-dimensional solubility parameters”, J. Paint Technol. 39, 105 (1967).

[00204] According to this Hansen space:

- 5d characterizes the London dispersion forces derived from the formation of dipoles induced during molecular impacts;

- dr characterizes the Debye interaction forces between permanent dipoles and also the Keesom interaction forces between induced dipoles and permanent dipoles;

- 5h characterizes the specific interaction forces (such as hydrogen bonding, acid/base, donor/acceptor, etc.); and

- 5a is determined by the equation

[00205] [Math. 1]

Sa = (5p² + oh²)¹'²

[00206] The parameters 5d, dr, dΐi and da are expressed in (J/cm³)^1/2. [00207] The total solubility parameter d according to the Hansen solubility space is defined in the article“Solubility parameter values” by Eric A. Grulke in the book“Polymer Handbook”, 3rd Edition, Chapter VII, pages 519-559, by the relationship:

[00208] [Math.2] d = (Set² + 6p²+51i^I)^lfl

[00209] Among the hydrocarbon-based oils having a molecular weight of less than or equal to 400 g/mol and a solubility parameter 5a ranging from 2 to 15 J⁰⁵/cm¹⁵, mention may be made of dicaprylyl ether (5a = 3.45 J⁰⁵/cm¹⁵), 2-ethylhexyl palmitate (5a = 4.2 J⁰⁵/cm¹⁵), cetyl 2-ethylhexanoate (5a = 4.2 J° cm¹⁵), octyldodecyl neopentanoate (5a = 4.2 f' Vcm¹"). isostearyl neopentanoate (5a = 4.3 J° ^/cm¹⁵), isostearyl benzoate (5a = 4.4 J⁰⁵/cm¹⁵), tridecyl isononanoate (5a = 4.4 J⁰⁵/cm¹⁵), isopropyl stearate (5a = 4.5 J⁰⁵/cm¹⁵), isopropyl isostearate (5a = 4.5 J⁰⁵/cm¹⁵), isopropyl palmitate (5a = 4.7 J⁰⁵/cm¹⁵), isononyl isononanoate (5a = 4.87 J⁰⁵/cm¹⁵), C12-15 alkyl benzoate (5a = 4.9 J⁰⁵/cm¹⁵), isopropyl myristate (5a = 5.0 J⁰⁵/cm¹⁵), 2-ethylhexyl 2-ethylhexanoate (5a = 5.2 J⁰⁵/cm¹⁵), isodecyl neopentanoate (5a = 5.3 J⁰⁵/cm¹⁵), 2-ethylhexyl benzoate (5a = 5.9 J⁰⁵/cm¹⁵), caprylyl carbonate (5a = 6.0 J⁰⁵/cm¹⁵) sold under the name Cetiol CC by Cognis, dioctyl (2-ethylhexyl) carbonate (5a = 6.0 J⁰⁵/cm¹⁵), diethylhexyl adipate (5a = 6.2 J⁰⁵/cm¹⁵), octadecyl 5-oxo-L-prolinate (5a = 6.2 J⁰⁵/cm¹⁵), propylene glycol dipelargonate (5a = 6.4 J⁰⁵/cm¹⁵), neopentyl glycol dicaprate (5a = 6.4 J⁰⁵/cm¹⁵), dicaprylyl maleate (5a = 6.6 J⁰⁵/cm¹⁵), propylene glycol dioctanoate (5a = 6.7 J⁰⁵/cm¹⁵), dodecyl 1- butyl-5-oxopyrrolidine-3-carboxylate (5a = 7.1 f' Vcm¹").2,4-methyl-l,5-pentanediol dineopentanoate (5a = 7.3 J⁰⁵/cm¹⁵), 2-octyldodecanol (5a = 7.7 J⁰⁵/cm¹⁵), isostearyl alcohol (5a =8.1 J⁰⁵/cm¹⁵), oleyl alcohol (5a = 8.2 J⁰⁵/cm¹⁵), diisopropyl adipate (5a = 8.31 J⁰⁵/cm¹⁵), diisobutyl adipate (5a = 8.31 J⁰⁵/cm¹⁵), hexyldecanol (5a = 8.6 J⁰⁵/cm¹⁵), propan-2-yl 1 -(2-ethylhexyl) -5 -oxopyrrolidine-3 - carboxylate (5a =8.6 J⁰⁵/cm¹⁵), propylene glycol monoisostearate (5a =8.7 J⁰⁵/cm¹⁵), isostearyl lactate (5a = 8.7 J0.5/cml.5), butyl 1 -butyl-5 -oxopyrrolidine-3 -carboxylate (5a = 9.4 f' Vcm¹").2-butyloctanol (5a = 9.8 J⁰⁵/cm¹⁵), C12-C13 alkyl lactate (5a = 10.1 J⁰⁵/cm¹⁵), dimethyl isosorbide (5a = 10.76 J⁰⁵/cm¹⁵), tributyl citrate (5a = 11.41 J⁰⁵/cm¹⁵), triethyl citrate (5a =13.7 J⁰⁵/cm¹⁵), phenylethyl alcohol (5a = 14.0 J⁰⁵/cm¹⁵), PEG-8 (polyethylene glycol containing 8 ethylene glycol units) (5a = 14.8 J° cm¹⁵), and mixtures thereof.

[00210] According to one preferred embodiment, the makeup-removing composition comprises at least one hydrocarbon-based oil having a molecular weight of less than or equal to 400 g/mol and a solubility parameter 5a ranging from 2 to 15 J⁰7cm' \ said oil preferably being chosen from synthetic ethers and esters, and preferably from isopropyl myristate (5a = 5.0 J⁰⁵/cm¹⁵), dicaprylyl ether (5a = 3.45 J^/cm¹·⁵), isononyl isononanoate (5a = 4.87 f' Vcm¹')- isodecyl neopentanoate (5a = 5.3 f' Vcm¹')- diisobutyl adipate (5a = 8.31 J⁰⁵/cm¹⁵), diisopropyl adipate (5a = 8.31 J⁰⁵/cm¹⁵), dimethylisosorbide (5a = 10.76 J^/cm^1·5), tributyl citrate (5a = 11.41 f' Vcm¹')- and mixtures thereof. [00211] Preferably, the makeup-removing composition comprises at least one hydrocarbon-based oil chosen from synthetic esters of formula R1COOR2 wherein Ri represents the residue of a fatty acid comprising from 8 to 29 carbon atoms and R2 represents a branched or unbranched hydrocarbon chain, containing from 3 to 30 carbon atoms, and mixtures thereof.

[00212] More preferentially, the hydrocarbon-based oil(s) are chosen from isopropyl myristate, isononyl isononanoate, and mixtures thereof.

[00213] Preferably, the hydrocarbon-based oil(s) is (are) present in a total content ranging from 10% to 95% by weight, preferably from 20% to 80% by weight, and more preferentially from 30% to 70% by weight, relative to the total weight of the makeup-removing composition.

[00214] The oily phase is present in a content of between 0.1% and 80% by weight, preferably between 1% and 70% by weight, relative to the total weight of the makeup-removing composition.

Aqueous phase

[00215] Preferably, the makeup -removing composition comprises an aqueous phase.

[00216] The aqueous phase comprises water. It may also comprise at least one water-soluble organic solvent.

[00217] The term“water-soluble organic solvent” is intended to mean an organic solvent that is miscible with water at 25 °C.

[00218] Among the water-soluble organic solvents that may be used in the makeup -removing composition, mention may be made especially of monoalcohols having from 1 to 5 carbon atoms such as ethanol, isopropanol and butanol, and glycols having from 2 to 8 carbon atoms such as ethylene glycol, propylene glycol, 1,3 -butylene glycol and dipropylene glycol.

[00219] Preferably, the aqueous phase (water and optionally the water-miscible solvent) is then present in the makeup-removing composition in a content ranging from 0.5% to 20% by weight, relative to the total weight of the makeup-removing composition, more preferentially ranging from 1% to 17% by weight, and better still from 5% to 15% by weight, relative to the total weight of the makeup- removing composition.

[00220] When the makeup -removing composition according to the invention comprises water, the water content preferably varies from 0.5% to 30% by weight, preferentially from 1% to 20% by weight and better still from 2% to 10% by weight, relative to the total weight of the makeup-removing composition.

Surfactants

[00221] The makeup-removing composition may comprise one or more surfactants. [00222] The surfactant may be chosen from nonionic surfactants, anionic surfactants, amphoteric or zwitterionic surfactants, and mixtures thereof.

[00223] Mention may be made, as surfactants that can be used in the makeup-removing

composition according to the invention:

[00224] among the nonionic surfactants, of:

- glycerol ethers which are preferably oxyalkylenated, oxyethylenated and/or

oxypropylenated, which may comprise from 10 to 150 oxy ethylene and/or oxypropylene units;

- oxyalkylenated alcohols, in particular oxyethylenated and/or oxypropylenated alcohols, which may comprise from 2 to 150 oxyethylene and/or oxypropylene units, preferably from 5 to 100 oxyethylene units, in particular ethoxylated C8-C24 and preferably C12-C18 fatty alcohols such as ethoxylated stearyl alcohol comprising 20 oxyethylene units (CTFA name: Steareth-20) such as Brij 78 sold by the company Uniqema, or ethoxylated cetearyl alcohol comprising 30 oxyethylene units (CTFA name: Ceteareth-30) and the mixture of C12-C15 fatty alcohols comprising 7 oxyethylene units (CTFA name: Cl 2- 15 Pareth-7), for instance the product sold under the name Neodol 25-7® by Shell Chemicals;

- esters of a fatty acid, especially a C8-C24 and preferably C16-C22 fatty acid, and of polyethylene glycol (or PEG) (which may comprise from 10 to 150 oxyethylene units), such as PEG- 50 stearate and PEG-40 monostearate sold under the name Myq 52P® by the company Uniqema;

- esters of a fatty acid, especially a C8-C24 and preferably C16-C22 fatty acid, and of glycerol ethers which are preferably oxyalkylenated, oxyethylenated and/or oxypropylenated (which may comprise from 10 to 150 oxyethylene and/or oxypropylene units), for instance polyoxyethylenated glyceryl monostearate comprising 200 oxyethylene units, sold under the name Simulsol 220 TM® by the company SEPPIC; polyoxyethylenated glyceryl stearate comprising 30 oxyethylene units, for instance the product Tagat S® sold by the company Goldschmidt, polyoxyethylenated glyceryl oleate comprising 30 oxyethylene units, for instance the product Tagat O® sold by the company

Goldschmidt, polyoxyethylenated glyceryl cocoate comprising 30 oxyethylene units, for instance the product Varionic LI 13® sold by the company Sherex, polyoxyethylenated glyceryl isostearate comprising 30 oxyethylene units, for instance the product Tagat L® sold by the company

Goldschmidt, and polyoxyethylenated glyceryl laurate comprising 30 oxyethylene units, for instance the product Tagat I® from the company Goldschmidt;

- esters of a fatty acid, especially a C8-C24 and preferably C16-C22 fatty acid, and of sorbitol ethers which are preferably oxyalkylenated, oxyethylenated and/or oxypropylenated (which may comprise from 2 to 150 oxyethylene and/or oxypropylene units), for instance the polysorbate 60 sold under the name Tween 60® by the company Uniqema or the polysorbate 21 sold under the name Tween 21-LQ® by the company Croda;

- and mixture(s) thereof;

[00225] among the anionic surfactants, of:

- alkyl phosphates;

- alkyl sulfates, and in particular alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates and monoglyceride sulfates;

- alkyl sulfonates, alkylamide sulfonates, alkylaryl sulfonates, a-olefm sulfonates, paraffin sulfonates;

- alkyl sulfosuccinates, alkyl ether sulfosuccinates and alkylamide sulfosuccinates;

- alkyl sulfosuccinamates;

- alkyl sulfoacetates;

- acyl sarcosinates, acyl glutamates, acyl isethionates, N-acyl taurates and acyl lactylates;

- alkylpolyglycoside carboxylic esters, such as alkylglucoside citrates, alkylpolyglycoside tartrates, alkylpolyglycoside sulfosuccinates or alkylpolyglycoside sulfosuccinamates; and

- fatty acids, and salts thereof, in particular oleic acid, ricinoleic acid, palmitic acid or stearic acid salts, coconut oil or hydrogenated coconut oil acids;

- alkyl-D-galactoside uronic acids and salts thereof, polyoxyalkylenated (G-Gfialkyl ether carboxylic acids, polyoxyalkylenated (G-Gfialkylaryl ether carboxylic acids, polyoxyalkylenated (G-Gr [alkylamido ether carboxylic acids and salts thereof, in particular those containing from 2 to 50 alkylene oxide and in particular ethylene oxide groups;

- and mixtures thereof; preferably from fatty acid salts;

[00226] among amphoteric or zwitterionic surfactants, of:

- alkylamphoacetates such as N-disodium N-cocoyl-N-carboxymethoxyethyl-N- carboxymethylethylenediamine (CTFA name: Disodium cocoamphodiacetate) sold as an aqueous saline solution under the name Miranol C2M Cone NP by the company Rhodia Chimie; N-sodium N- cocoyl-N-hydroxyethyl-N-carboxymethylethylenediamine (CTFA name: sodium cocamphoacetate); cocamides, for instance the mixture of coconut acid ethanolamides (CTFA name: Cocamide DEA).

[00227] Preferably, the surfactant(s) are chosen from nonionic surfactants. [00228] Preferably, the nonionic surfactant(s) are chosen from esters of a C8-C24 and preferably C _K,- C22 fatty acid, and of sorbitol ethers which are preferably oxyalkylenated, oxyethylenated and/or oxypropylenated .

[00229] Preferably, the makeup-removing composition comprises at least one nonionic surfactant chosen from esters of a fatty acid, especially a C8-C24 and preferably C16-C22 fatty acid, and of preferably oxyalkylenated, oxyethylenated and/or oxypropylenated sorbitol ethers.

[00230] Preferably, when the makeup -removing composition comprises one or more surfactants, the total amount of surfactant(s) ranges from 1% to 50% by weight, more preferentially from 5% to 45% by weight and better still from 10% to 35% by weight, relative to the total weight of the makeup-removing composition.

Additives

[00231] The makeup-removing composition may also contain any adjuvant or additive usually used.

[00232] Among the additives that may be contained in the makeup-removing composition, mention may be made in particular of preservatives, antioxidants, fragrances, mattifying fdlers, cosmetic active agents, thickeners, lipophilic or hydrophilic polymers and sequestrants.

[00233] The application of the dye composition to the keratin fibers such as the hair is carried out before the application of the makeup-removing composition.

[00234] The dye composition according to the invention may be used on wet or dry keratin fibers, and also on any type of fair or dark, natural or dyed, permanent- waved, bleached or straightened fibers.

[00235] According to a particular embodiment of the process of the invention, the fibers are washed before application of the dye composition described above.

[00236] The application of the dye composition to the keratin fibers may be carried out by any conventional means, in particular using a comb, a fine brush, a coarse brush or with the fingers.

[00237] The dyeing process, i.e. application of the dye composition to the keratin fibers, is generally carried out at ambient temperature (between 15 and 25 °C).

[00238] The process according to the invention may comprise a step of applying heat to the dyed keratin fibers using a heating tool, the heating tool preferably not being a straightening iron.

[00239] The heat application step of the process of the invention may be carried out using a hood or a hairdryer.

[00240] When the process of the invention implements a step of applying heat to the keratin fibers, the step of applying heat to the keratin fibers takes place after the application of the dye composition to the keratin fibers. [00241] The step of applying heat to the keratin fibers may be performed after the application of the dye composition and before the application of the makeup-removing composition to the keratin fibers.

[00242] Preferably, the step of applying heat to the keratin fibers using a hood or a hairdryer is carried out at a temperature ranging from 30°C to 110°C, preferentially from 40°C to 90°C and more preferentially from 50°C to 80°C.

[00243] During the step of applying heat to the keratin fibers, a mechanical action may be exerted on the locks, such as combing, brushing or running the fingers through.

[00244] Preferably, if the fibers are dried, they are dried, in addition to a supply of heat, with a flow of air. This flow of air during drying makes it possible to improve the strand separation of the coating.

[00245] The makeup-removing composition is applied to dyed keratin fibers by the dye composition as defined above.

[00246] The application of the makeup-removing composition can be carried out on dry dyed keratin fibers or wet dyed keratin fibers and also on all types of fibers.

[00247] The makeup-removing process is generally carried out at ambient temperature (between 15°C and 25°C).

[00248] The application of the makeup -removing composition may be carried out immediately after the application of the dye composition (i.e. a few minutes to a few hours after the application of the dye composition), or in the days or weeks following the application of the dye composition.

[00249] The makeup-removing composition may be applied with the aid of any suitable support, which is especially capable of absorbing it, for example a fibrous makeup -removing disk, for example a woven or nonwoven fabric, cotton wool, a flocked film, a sponge, a wipe, or a twisted or injection- molded mascara application brush.

[00250] The makeup-removing composition may be contained in a container and taken up gradually each time makeup is removed. As a variant, the makeup -removing composition impregnates the support used for removing makeup, the support possibly being packaged, in this case, for example in leaktight packaging.

[00251] After the makeup-removing composition has been used, the keratin fibers may not be rinsed. As a variant, they may be rinsed. The rinsing may be performed, for example, with running water, without addition of a soap.

[00252] The present invention will now be described more specifically by means of examples, which do not in any way limit the scope of the invention. However, the examples make it possible to support specific characteristics, variants and preferred embodiments of the invention. Example

[00253] Example 1 :

[00254] Dye composition: Compositions (g /100 g)

[00255] [Table 1]

[00256] (1) sold under the trade name Granacrysil BMAS by the company Grant Industries

(2) sold under the name Granresin PMSQ-ID by the company Grant Industries

[00257] Protocol:

[00258] The dye composition A is applied to locks of natural hair containing 90% white hairs in a proportion of 0.5 g of composition per gram of lock.

[00259] The locks of hair are then combed and dried with a hair dryer.

[00260] The hair is dyed uniformly and intensely.

[00261] The hair thus dyed is then subjected to a test of several repeated shampoo washes so as to evaluate the resistance (persistence) of the coloring obtained with respect to shampoo washes.

[00262] Shampoo wash protocol:

[00263] The locks are washed with standard shampoo (Gamier Ultra Doux) respectively at T = 0 (i.e. immediately after the application of the dye composition to the keratin fibers).

[00264] The locks of hair are then rinsed, combed and dried with a hair dryer.

[00265] The next shampoo wash is then performed on the locks obtained after the application of the hairdryer.

[00266] Results: [00267] The persistence of the color of the locks was evaluated in the CIE L*a*b* system, using a Minolta Spectrophotometer CM3600D colorimeter.

[00268] In this L*a*b* system, L* represents the intensity of the color, a* indicates the green/red color axis and b* the blue/yellow color axis.

[00269] The persistence of the coloring is evaluated by the color difference DE between the dyed locks before shampooing, then after having undergone 3, 5 and 10 shampoo washes according to the protocol described above. The lower the value of DE, the more the color is persistent with respect to shampoo washes.

[00270] [Table 2]

[00271] The hair has a natural feel and the strands of hair may be separated with the fingers or by using a comb and/or a brush.

[00272] The locks of hair dyed with the dye composition A according to the invention and washed with three, five or ten shampoo washes without application of heat using a straightening iron exhibit low DE values.

[00273] Thus, the colored coating of the keratin fibers from the composition according to the invention is persistent with respect to shampoo washes even in the absence of the application of heat using straightening iron. Indeed, the locks of hair dyed with the composition according to the invention and washed with three, five or ten shampoo washes without application of heat using a straightening iron exhibit good color persistence.

[00274] The composition according to the invention is also less restrictive to apply to the hair for users because a step of applying heat using a straightening iron is not necessary.

[00275] Makeup-removing composition: Compositions (g /100 g)

[00276] [Table 3]

[00277] Protocol:

[00278] The locks of hair dyed by the dye composition A are treated with the makeup-removing composition B once the dyed locks are dry to the touch, in a proportion of 0.5 g of composition B per gram of lock.

[00279] The locks of hair dyed by the dye composition A are rinsed with the makeup-removing composition B three times in succession. Between each application of the makeup-removing composition, the locks are rinsed with water.

[00280] After the three applications of the makeup-removing composition, the locks are placed on absorbent paper and dried with a hair dryer.

[00281] Results:

[00282] As the number of washes with the makeup-removing composition increases, the hair is rapidly bleached.

[00283] Example 2:

[00284] Compositions (g /100 g)

[00285] [Table 4]

[00286] (1) sold under the trade name Granacrysil BMAS by the company Grant Industries

[00287] Protocol:

[00288] The comparative composition C and the composition A according to the invention (described in example 1) are respectively applied to locks of natural hair containing 90% white hairs in a proportion of 0.5 g of composition per gram of lock.

[00289] The locks of hair are then combed and dried with a hair dryer.

[00290] The hair is dyed uniformly and intensely.

[00291] The hair thus dyed is then subjected to a test of several repeated shampoo washes so as to evaluate the resistance (persistence) of the coloring obtained with respect to shampoo washes, as described in example 1.

[00292] Results:

[00293] The persistence of the color of the locks was evaluated in the CIE L*a*b* system, using a Minolta Spectrophotometer CM3600D colorimeter.

[00294] In this L*a*b* system, L* represents the intensity of the color, a* indicates the green/red color axis and b* the blue/yellow color axis.

[00295] The persistence of the coloring is evaluated by the color difference DE between the dyed locks before shampooing, then after having undergone 5 shampoo washes according to the protocol described above. The lower the value of DE, the more the color is persistent with respect to shampoo washes.

[00296] [Table 5]

[00297] The locks of hair dyed with the comparative composition C and washed with five shampoo washes exhibit a higher DE value than locks of hair dyed with the composition A according to the invention.

[00298] Thus, the colored coating of the keratin fibers from the comparative composition which does not comprise silicone resin is less persistent with respect to shampoo washes than the composition according to the invention which comprises silicone resin.

Claims

[Claim 1] A composition for treating human keratin fibers such as the hair, comprising: a) at least one silicone acrylic copolymer comprising at least the following units:

- an alkyl acrylate or methacrylate unit, b) at least one silicone resin, and c) at least one pigment.

[Claim 2] The composition as claimed in claim 1, characterized in that the silicone acrylic

copolymer comprises at least the following units:

[Claim 3] The composition as claimed in any one of the preceding claims, characterized in that the silicone acrylic copolymer comprises at least the following units:

- a C1-C30, preferably C1-C22, preferentially C1-C10 and better still C2-C6 alkyl acrylate or methacrylate unit.

[Claim 4] The composition as claimed in any one of the preceding claims, characterized in that the silicone acrylic copolymer comprises at least the following units:

- a C1-C22, preferentially C1-C10 and better still C2-C6 alkyl acrylate or methacrylate unit.

[Claim 5] The composition as claimed in any one of the preceding claims, characterized in that the silicone acrylic copolymer(s) is (are) present in a total amount ranging from 1% to 50% by weight, preferably from 2% to 40% by weight, more preferentially from 3% to 30% by weight and better still from 5% to 20% by weight, relative to the total weight of the composition.

[Claim 6] The composition as claimed in any one of the preceding claims, characterized in that the silicone resin is a silicone resin of type T, better still a silicone resin of polysilsesquioxane type of formula (RSi03_/2)x wherein x is greater than 100 and the R group is an alkyl group having from 1 to 10 carbon atoms, and more preferentially at least one silicone resin of polymethylsilsesquioxane type.

[Claim 7] The composition as claimed in any one of the preceding claims, characterized in that the silicone resin is present in the composition in an amount ranging from 0.01% to 10% by weight, preferably from 0.05% to 5% by weight and more preferentially from 0.05% to 3% by weight, relative to the total weight of the composition.

[Claim 8] The composition as claimed in any one of the preceding claims, characterized in that the composition comprises one or more oil(s), preferably one or more oil(s) chosen from CVC i alkanes, more preferentially from isododecane, isohexadecane, tetradecane and/or mixtures thereof.

[Claim 9] A process for the cosmetic treatment of, in particular for dyeing, human keratin fibers such as the hair, wherein the composition as defined in any one of claims 1 to 8 is applied to said fibers.

[Claim 10] A process for treating human keratin fibers such as the hair, comprising the following steps:

a) applying to the keratin fibers a dye composition as defined in any one of claims 1 to

8, and

[Claim 11] The process as claimed in claim 10, characterized in that the makeup-removing composition comprises at least one nonvolatile hydrocarbon-based oil.

[Claim 12] The process as claimed in either one of claims 10 and 11, characterized in that the hydrocarbon-based oil(s) is (are) chosen from synthetic esters of formulae R1COOR2 wherein Ri represents the residue of a fatty acid comprising from 8 to 29 carbon atoms, and R2 represents a branched or unbranched hydrocarbon chain containing from 3 to 30 carbon atoms, and mixtures thereof.

[Claim 13] The process as claimed in any one of claims 10 to 12, characterized in that the hydrocarbon-based oil(s) is (are) chosen from isopropyl myristate, isononyl isononanoate and/or mixtures thereof.

[Claim 14] The process as claimed in any one of claims 10 to 13, characterized in that the hydrocarbon-based oil(s) is (are) present in a total content ranging from 10% to 95% by weight, preferably from 20% to 80% by weight and more preferentially from 30% to 70% by weight, relative to the total weight of the makeup-removing composition.

[Claim 15] The process as claimed in any one of claims 10 to 14, characterized in that the makeup- removing composition comprises at least one nonionic surfactant, preferably chosen from esters of a C8-C24, preferably C16-C22, fatty acid, and of preferably oxyalkylenated, oxyethylenated and/or oxypropylenated sorbitol ethers.

[Claim 16] The process as claimed in any one of claims 10 to 15, characterized in that the application of the dye composition to the keratin fibers is carried out before the application of the makeup-removing composition.

[Claim 17] A kit for treating keratin fibers such as the hair, comprising:

- a dye composition as defined according to any one of claims 1 to 8, and

- a makeup-removing composition as defined according to any one of claims 10 to 15. [Claim 18] The use of the composition as defined according to any one of claims 1 to 8, for the cosmetic treatment of, in particular dyeing, keratin fibers, in particular human keratin fibers such as the hair.