WO2020071324A1 - Dispositif de génération de dioxyde de chlore - Google Patents

Dispositif de génération de dioxyde de chlore

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Publication number
WO2020071324A1
WO2020071324A1 PCT/JP2019/038549 JP2019038549W WO2020071324A1 WO 2020071324 A1 WO2020071324 A1 WO 2020071324A1 JP 2019038549 W JP2019038549 W JP 2019038549W WO 2020071324 A1 WO2020071324 A1 WO 2020071324A1
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WO
WIPO (PCT)
Prior art keywords
chlorine dioxide
chlorite
outer container
component
dioxide generator
Prior art date
Application number
PCT/JP2019/038549
Other languages
English (en)
Japanese (ja)
Inventor
奥山麻依子
米田裕治
Original Assignee
大幸薬品株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 大幸薬品株式会社 filed Critical 大幸薬品株式会社
Priority to CN201980062472.0A priority Critical patent/CN112739644A/zh
Priority to KR1020217012208A priority patent/KR20210062679A/ko
Priority to JP2020550425A priority patent/JP7412772B2/ja
Publication of WO2020071324A1 publication Critical patent/WO2020071324A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B11/00—Oxides or oxyacids of halogens; Salts thereof
    • C01B11/02—Oxides of chlorine
    • C01B11/022—Chlorine dioxide (ClO2)
    • C01B11/023—Preparation from chlorites or chlorates
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
    • A61L9/12—Apparatus, e.g. holders, therefor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B11/00—Oxides or oxyacids of halogens; Salts thereof
    • C01B11/02—Oxides of chlorine

Definitions

  • the present invention relates to a chlorine dioxide generator that generates chlorine dioxide gas by reacting chlorite as a first component and a second component that reacts with the chlorite to generate chlorine dioxide gas. .
  • Patent Document 1 Conventionally, there has been known an instrument or an apparatus for reacting a chlorite solution with an acidic substance to generate chlorine dioxide gas (for example, Patent Document 1).
  • the present invention has been made in view of the above circumstances, and has as its object to reduce the size of a device, to allow the source of chlorine dioxide gas to be safely carried (portable), and to quickly remove a large amount of chlorine dioxide gas.
  • An object of the present invention is to provide a chlorine dioxide generator capable of generating chlorine dioxide.
  • the first feature configuration of the chlorine dioxide generator according to the present invention for achieving the above object is a chlorite as a first component, and a second component that reacts with the chlorite to generate chlorine dioxide gas.
  • a chlorine dioxide generator that reacts with components to generate chlorine dioxide gas
  • an outer container that is deformable by applying an external force and is configured to be capable of draining a liquid, and is housed inside the outer container.
  • the chlorine dioxide generator can be configured by enclosing the outer container containing the inner container and the solid composition in the bag-like body, the device can be downsized.
  • the bag-like body contains the solid composition containing the second component and the outer container, the solid composition containing the second component and the aqueous chlorite solution are not contacted. Can be stored in a state. In this state, by applying an external force to the outer container to deform it, the easily breakable inner container housed therein can be easily broken. At this time, the aqueous chlorite solution flows out of the inner container into the outer container. Since the outer container is configured to drain the liquid, the aqueous chlorite solution is discharged from the outer container and comes into contact with the solid composition containing the second component, thereby generating chlorine dioxide gas. The chlorine dioxide gas generated in the bag-like body is released to the outside of the bag-like body from a ventilation part having air permeability.
  • the concentration of chlorine dioxide gas in the fumigation chamber increases, and chlorine dioxide treatment (bacteria / fungus sterilization processing, virus inactivation processing, Pest control, etc.) for a predetermined period of time.
  • the chlorine dioxide gas at this time can be generated in a large amount and quickly. That is, after a large amount of chlorine dioxide gas is generated in a short time, the amount of chlorine dioxide gas generated decreases after a while. Therefore, the fumigation processing time (evacuation time for a person) of the space in the fumigation room can be shortened, and a person can immediately enter the fumigation room after ventilation.
  • the reason why a large amount of chlorine dioxide gas is generated temporarily is that the second component is contained in the solid composition, so that free water in the reaction system can be reduced. . That is, the second component can be reacted in a state that is higher than the apparent concentration of the second component in the solid composition. As a result, the contact area (reaction opportunity) between chlorite and the second component is increased, and the reaction rate is increased. As a result, the reaction becomes dramatic and the chlorine dioxide gas is generated transiently (rapidly). Can be
  • the bag-like body can release the chlorine dioxide gas from the ventilating part having air permeability.
  • the second characteristic configuration of the chlorine dioxide generator according to the present invention is to react a chlorite as a first component with a second component that generates chlorine dioxide gas by reacting with the chlorite.
  • the outer container is deformable by applying an external force, and is configured to be capable of discharging liquid, and is contained inside the outer container, and the second component is An easily breakable inner container sealed with an aqueous solution, and a bag-like body containing the chlorite-containing solid composition and the outer container, and having a vent portion having air permeability. is there.
  • the chlorine dioxide generator can be configured by enclosing the outer container containing the inner container and the solid composition in the bag-like body, the device can be downsized.
  • the bag-shaped body contains the solid composition containing chlorite and the outer container
  • the solid composition containing chlorite and the aqueous solution of the second component are used. It can be stored in a non-contact state. In this state, by applying an external force to the outer container to deform it, the easily breakable inner container housed therein can be easily broken. At this time, the aqueous solution of the second component flows out of the inner container into the outer container. Since the outer container is configured to drain the liquid, the aqueous solution of the second component is discharged from the outer container and comes into contact with the solid composition containing chlorite, thereby generating chlorine dioxide gas. The chlorine dioxide gas generated in the bag-like body is released to the outside of the bag-like body from a ventilation part having air permeability.
  • the bag-like body can release the chlorine dioxide gas from the ventilating part having air permeability.
  • a third characteristic configuration of the chlorine dioxide generator according to the present invention resides in that the bag-like body is formed in a rectangular shape in a top view, and the ventilation portion is formed in a planar shape.
  • the ventilation portion can be formed on at least one side of the back surface of the bag.
  • chlorine dioxide generated inside the bag-like body can be released from at least one entire surface of the bag-like body, so that a large amount of chlorine dioxide gas generated is quickly released to the outside of the bag-like body. be able to.
  • a fourth characteristic configuration of the chlorine dioxide generator according to the present invention is that the ventilation section is formed by processing a synthetic resin material into a nonwoven fabric.
  • the ventilation section can be made gas-permeable and liquid-impermeable.
  • a fifth feature of the chlorine dioxide generator according to the present invention is that the solid composition contains a porous substance as a carrier.
  • the porous substance serves as a carrier for supporting the first component or the second component, the first component or the second component can be stably held inside the bag.
  • a sixth characteristic configuration of the chlorine dioxide generator according to the present invention resides in that the solid composition is granulated.
  • the solid composition can easily move freely inside the bag-shaped body. Therefore, for example, when the chlorite aqueous solution is in contact with the solid composition containing the second component, if the solid composition is allowed to move freely, for example, by moving the bag-like body left and right, The reaction between the aqueous acid salt solution and the second component is performed efficiently, and chlorine dioxide gas can be generated according to the theoretical value of the reaction.
  • a seventh characteristic configuration of the chlorine dioxide generator according to the present invention is that the outer container and the inner container are configured in a tubular shape, and the outer container has outer container lids at both ends, and each of the two ends of the inner container is provided. Are provided in contact with and supported by the respective inner surfaces of the outer container lids provided at both ends of the outer container.
  • both ends of the inner container can be held between the pair of outer container lids, it is possible to prevent the inner container from moving inside the outer container.
  • the eighth feature of the chlorine dioxide generator according to the present invention resides in that the second component is an acidic substance.
  • the chlorite reacts with the acidic substance to easily generate chlorine dioxide gas. Can be done.
  • a ninth characteristic configuration of the chlorine dioxide generator according to the present invention is that the acidic substance is sulfuric acid and the chlorite is sodium chlorite or potassium chlorite.
  • sulfuric acid as an acidic substance has excellent storage stability, does not generate corrosive gas, and does not change in concentration even after being supported on a porous substance, so that it is excellent in handling. Further, since sodium chlorite or potassium chlorite as chlorite is easily available, the present invention can be easily implemented.
  • a tenth feature of the chlorine dioxide generator according to the present invention is that the concentration of the acidic substance is 30% by weight or less and the concentration of the chlorite is 0.1 to 30% by weight.
  • the concentration of the acidic substance exceeds 30% by weight, the viscosity of the solution becomes high and it becomes difficult to disperse, and the dispersion of the prepared acidic substance becomes unfavorable.
  • the concentration of chlorite is less than 0.1% by weight, there is a possibility that a problem of insufficient chlorite in the generation of chlorine dioxide gas may occur.
  • the problem that the chlorate is saturated and crystals are easily precipitated may occur. Therefore, considering safety, stability, chlorine dioxide gas generation efficiency, and the like, the content is preferably 0.1 to 30% by weight.
  • the chlorine dioxide generator according to the present invention generates chlorine dioxide gas by reacting chlorite as a first component with a second component that reacts with the chlorite to generate chlorine dioxide gas. .
  • the chlorine dioxide generator X of the present invention is deformable by applying an external force and accommodates an outer container 10 configured to be capable of draining a liquid and an inside of the outer container 10. And a bag containing the easily breakable inner container 20 in which the chlorite aqueous solution 1 is sealed, the solid composition 30 containing the second component 2 and the outer container 10, and provided with a vent portion 41 having air permeability. And a state body 40.
  • the second component may be any substance that generates chlorine dioxide gas by reacting with chlorite, such as an acidic substance, or chlorine dioxide by reacting alone with chlorite without containing an acidic substance. Can be generated.
  • the second component 2 is an acidic substance will be described. It is preferable that the acidic substance be an acidic substance that shows acidity by being dissolved in water.
  • the outer container 10 can be deformed by applying an external force, and may have any mode as long as it has a space in which the inner container 20 can be accommodated.
  • a flexible material is exemplified.
  • the term "flexibility" as used herein means a material that can be easily deformed by being curved, for example, in an arc shape when an external force is applied, and easily return to an original shape when the applied force is released.
  • Specific examples of the flexible resin material include polyethylene, polypropylene, and silicon.
  • Examples of the shape of the outer container 10 include a tubular shape (test tubular shape), a stick shape, a bag shape, and a box shape, but the shape is not limited thereto.
  • the outer container 10 is formed in a bag shape
  • the inner container 20 is housed inside the bag-shaped outer container 10.
  • the bag-shaped outer container 10 may be pressed and deformed to such an extent that the inner container 20 is broken.
  • the outer container 10 has a tubular shape will be described.
  • the outer container 10 is configured to be able to drain the liquid.
  • an outer container lid 11 having a plurality of small openings 11a (for example, five openings having a diameter of 2 mm) is provided at both ends of the outer container 10. That is, the liquid can be drained through the opening 11a formed in the outer container lid 11.
  • each of both ends of the inner container 20 is supported by being in contact with the inner surface of each of the outer container lids 11 provided at both ends of the outer container 10. Good to do.
  • both ends of the inner container 20 can be held by being sandwiched between the pair of outer container lids 11, the inner container 20 can be prevented from moving inside the outer container 10.
  • the inner container 20 is a container that can seal the chlorite aqueous solution 1 and is easily broken.
  • the term “easy destruction” as used herein refers to a property that can be easily broken or cracked by applying a force from the outside to deform or bend (or to bend). It must not be damaged by shaking or light impact during storage. Examples of easily breakable enclosures include glass ampules and relatively thin plastic containers. When a plastic container is used as the easily breakable inner container 20, a fragile portion is artificially provided in the container in advance, and a force is applied from the outside to bend (or attempt to bend), so that the fragile portion is bent. It can also be configured to crack or crack (break).
  • the shape of the inner container 20 is exemplified by a tube (test tube), a stick, a bag, a box, and the like, but is not limited thereto. In the present embodiment, a case where the shape of the inner container 20 is tubular will be described.
  • the bag-shaped body 40 is provided with a ventilation part 41 having air permeability.
  • a description will be given of a mode in which the bag-shaped body 40 is formed in a rectangular shape in a top view, and the ventilation section 41 is formed in a planar shape.
  • the present invention is not limited thereto.
  • the ventilation part 41 can be formed on at least one side of the back surface of the bag-shaped body 40.
  • At least one of the front and back surfaces of the bag 40 is gas-permeable and liquid-impermeable. That is, the bag-shaped body 40 may have a gas-liquid and liquid-impermeable front surface and a gas-liquid impermeable back surface, or a gas-liquid impermeable surface and a gas-permeable and liquid impermeable back surface. Both the front and back surfaces may be gas-permeable and liquid-impermeable. At this time, the bag-shaped body 40 may be in a mode in which at least one of the front and back surfaces is translucent. The peripheral portion 40a of the bag-like body 40 may be bonded by heat sealing, ultrasonic sealing, an adhesive or the like.
  • the ventilation portion 41 provided on the front or back surface may be formed by processing a synthetic resin material into a nonwoven fabric.
  • a nonwoven fabric for example, a sheet of high-density polyethylene nonwoven fabric can be used, but the present invention is not limited to this.
  • the nonwoven fabric for example, Exepol (registered trademark, manufactured by Mitsubishi Chemical Corporation), Tyvek (registered trademark, manufactured by Dupont), Gore-Tex (registered trademark, manufactured by WL Gore & Associates) and the like can be used. It is not limited to this.
  • acrylonitrile styrene (AS) resin acrylonitrile butadiene styrene (ABS) resin, ethylene vinyl alcohol (EVOH) resin, vinyl chloride resin, polyethylene resin
  • AS acrylonitrile styrene
  • ABS acrylonitrile butadiene styrene
  • EVOH ethylene vinyl alcohol
  • vinyl chloride resin vinyl chloride resin
  • polyethylene resin a sheet made of a synthetic resin material such as a polypropylene resin or a polyolefin resin can be used, but is not limited thereto.
  • the chlorite used in the present invention includes, for example, alkali metal chlorite and alkaline earth metal chlorite.
  • alkali metal chlorite include sodium chlorite, potassium chlorite, and lithium chlorite.
  • alkaline earth metal chlorite include calcium chlorite, magnesium chlorite, and sodium chlorite. Barium chlorate. Of these, sodium chlorite and potassium chlorite are preferred, and sodium chlorite is most preferred, in terms of availability.
  • One of these alkali chlorites may be used alone, or two or more thereof may be used in combination.
  • the proportion of chlorite in the aqueous chlorite solution is preferably 0.1% by weight to 30% by weight. If the amount is less than 0.1% by weight, there may be a problem that chlorite is insufficient in generating chlorine dioxide gas. If the amount exceeds 30% by weight, chlorite is saturated and crystals are formed. There is a possibility that a problem of easy precipitation may occur. In consideration of safety, stability, generation efficiency of chlorine dioxide gas, and the like, 15% by weight to 25% by weight is preferable, and a more preferable range is 20% by weight to 25% by weight.
  • Examples of the acidic substance that can be used in the present invention include inorganic acids and organic acids and salts thereof.For example, hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, boric acid, metaphosphoric acid, pyrophosphoric acid, inorganic acids such as sulfamic acid, formic acid, Acetic acid, propionic acid, butyric acid, lactic acid, pyruvic acid, citric acid, malic acid, tartaric acid, gluconic acid, glycolic acid, fumaric acid, malonic acid, maleic acid, oxalic acid, succinic acid, acrylic acid, crotonic acid, oxalic acid, Organic acids, such as glutaric acid, and salts thereof are mentioned.
  • inorganic acids such as sulfamic acid, formic acid, Acetic acid, propionic acid, butyric acid, lactic acid, pyruvic acid, citric acid, malic acid, tartaric acid, gluconic acid, glyco
  • the salt of an inorganic acid examples include a salt of dihydrogen phosphate (a sodium salt and a potassium salt, the same applies hereinafter), and a mixture of a dihydrogen phosphate and a monohydrogen phosphate.
  • sulfuric acid it is preferable to use sulfuric acid because it has excellent storage stability, does not generate corrosive gas, and does not cause a change in concentration even after being supported (impregnated) on a porous substance.
  • the concentration of sulfuric acid the final concentration of the sulfuric acid contained in the solid composition 30 is preferably 30% by weight or less, and more preferably 10% by weight or less from the viewpoint of safety.
  • the acidic substance one type may be used alone, or two or more types may be used in combination.
  • the solid composition 30 may be in a form containing a second component (acidic substance), and for example, may be in the form of a crystal of an acidic substance or a porous substance containing an acidic substance.
  • a second component acidic substance
  • the solid composition 30 includes a porous substance as a carrier will be described. That is, the above-mentioned "solid composition 30 containing the second component 2" is a porous substance containing an acidic substance which becomes acidic when dissolved in water.
  • the solid composition 30 is preferably in the form of particles. By making the solid composition 30 granular, the solid composition 30 can easily move freely inside the bag-like body 40. Therefore, when the aqueous chlorite solution is in contact with the solid composition 30 containing the second component (acidic substance), the solid composition 30 can move freely, for example, by moving the bag-shaped body 40 left and right. By doing so, the reaction between the aqueous chlorite solution and the acidic substance is efficiently performed, and it is possible to generate chlorine dioxide gas according to the theoretical value of the reaction.
  • porous material for example, a porous material or a baked aggregate can be used, but is not limited thereto.
  • the porous material include porous silica, sepiolite, montmorillonite, diatomaceous earth, talc, zeolite, activated clay, molecular sieve, and activated alumina.
  • porous silica because it is easily available, has excellent porosity (the porous space is wide), and easily contains an acidic substance or chlorite.
  • the specific surface area of such porous silica is not particularly limited.
  • the fired aggregate for example, bones, shells, and corals of animals (including mammals, fish, and birds) that have been fired to obtain crushed pieces, particles, or powder can be used.
  • the particle size of such a porous substance is preferably, for example, about 0.05 to 10 mm. Further, it is preferable to select a porous substance having a water adsorption amount of 5% or more at room temperature. In addition, it is preferable to select a porous substance having a repose angle of 50 ° or less, preferably 45 ° or less, more preferably 40 ° or less, and still more preferably 30 ° or less.
  • the repose angle of Carract Q-10 (manufactured by Fuji Silysia Chemical Ltd.), which is a kind of porous silica, has a particle size of 1.7-4.0 mm: 19 °, 75-500 ⁇ m: 23 °, and Carract G
  • the angle of repose of -10 (manufactured by Fuji Silysia Chemical Ltd.) has a particle size of 0.35-1.7 mm: 35 °.
  • the easily deformable inner container 20 housed therein can be easily broken by applying an external force to the outer container 10 to deform it.
  • the aqueous chlorite solution flows out of the inner container 20 into the outer container 10.
  • the outer container 10 is configured to be able to drain the liquid through the opening 11a, the aqueous chlorite solution is discharged from the outer container 10 and comes into contact with the solid composition 30 containing an acidic substance (second component).
  • an acidic substance (second component) As a result, chlorine dioxide gas is generated.
  • the chlorine dioxide gas generated in the bag-like body 40 is released to the outside of the bag-like body 40 from the ventilation part 41 having air permeability.
  • the place (fumigation place) where the chlorine dioxide generator X of the present invention is used is not particularly limited.
  • it is used in general homes (living rooms, entrances, restrooms, kitchens, etc.), for industrial use (for factories), hospitals, and hospitals. It can be used in various situations, such as medical sites such as clinics and nursing homes, and public facilities such as schools, station buildings, and public toilets. Further, it can be used not only in a relatively large space such as an indoor space where people can live, but also in a narrow space such as a refrigerator, a clog box, and a car (car, bus, train).
  • the size of the applicable space of the generator of the present invention is not particularly limited, but is preferably a closed space.
  • chlorine dioxide gas has a very high solubility
  • a porous material such as zeolite or silica gel is used as a carrier in order to reduce free water in the reaction system as much as possible when reacting.
  • the reaction rate of acidic substances such as sulfuric acid and chlorite can be increased, and the amount of dissolved chlorine dioxide gas can be reduced. Therefore, it is possible to substantially generate the chlorine dioxide gas at a high concentration in a short period (transient).
  • the chlorine dioxide generator X of the present invention a large amount of chlorine dioxide gas can be quickly generated. Therefore, the fumigation processing time (evacuation time for a person) of the space in the fumigation room can be shortened, and a person can immediately enter the fumigation room after ventilation.
  • the chlorine dioxide generator X of another embodiment can be deformed by applying an external force, and the outer container 10 is configured to be able to drain the liquid, and is housed inside the outer container 10, A bag containing an easily destructible inner container 20 sealed with an aqueous solution of the component (acidic substance), a chlorite-containing solid composition 30 and an outer container 10, and provided with a ventilating part 41 having air permeability. And a body 40.
  • the easily deformable inner container 20 housed therein can be easily broken by applying an external force to the outer container 10 to deform it.
  • the aqueous solution of the acidic substance flows out of the inner container 20 into the outer container 10.
  • the outer container 10 is configured to be able to drain the liquid through the opening 11a, the aqueous solution of the acidic substance is discharged from the outer container 10 and comes into contact with the solid composition 30 containing chlorite.
  • Chlorine dioxide gas is generated.
  • the chlorine dioxide gas generated in the bag-like body 40 is released to the outside of the bag-like body 40 from the ventilation part 41 having air permeability.
  • the above-described acidic substance can be used.
  • sulfuric acid used as the acidic substance
  • the concentration of the aqueous solution is preferably 30% by weight or less.
  • the final concentration of chlorite contained in the solid composition 30 is preferably 30% by weight or less, and more preferably 20 to 25% by weight. It is preferable from the viewpoints of properties and the generation efficiency of chlorine dioxide gas.
  • Chlorine dioxide was generated using the chlorine dioxide generator X of the present invention, and the amount of generated chlorine dioxide gas was determined.
  • the chlorine dioxide generator X includes a polypropylene resin tube (outer container 10: ⁇ 20, total length 150 mm) that can be deformed by applying an external force, and a cylindrical glass ampule (inner container 20: ⁇ 8) sealed with an aqueous solution of sodium chlorite.
  • Caractact Q-10 particle size 1.7-4.0 mm, manufactured by Fuji Silysia Chemical Ltd.
  • solid composition 30 impregnated with sulfuric acid as an acidic substance by a conventionally known method, and a resin cylinder.
  • nonwoven bag bag-like body 40: 120 mm ⁇ 200 mm
  • outer container lids 11 each having five openings 11a each having a diameter of 2 mm were mounted.
  • the nonwoven fabric bag (bag-like body 40) uses a sheet made of Tyvek (registered trademark, manufactured by DuPont) on the front surface and a vinyl chloride resin on the back surface, and heat seals both so that the seal width of the peripheral portion 40a is 10 mm. did.
  • the amount of sodium chlorite contained in the aqueous solution of sodium chlorite was 890 mg
  • the amount of sulfuric acid contained in the solid composition 30 was 260 mg
  • the theoretical value of chlorine dioxide gas generated was 330 mg.
  • a chlorine dioxide gas was generated by contacting an aqueous solution of sodium chlorate with silica gel impregnated with sulfuric acid (solid composition 30).
  • the chlorine dioxide generator X in which chlorine dioxide gas is generated is immediately placed in a container 51 made of vinyl chloride, and the chlorine dioxide is added to an aqueous solution (200 mL) of potassium iodide contained in another container 52. The gas was dissolved to collect chlorine dioxide gas. The collection was completed at a predetermined time after the start of the reaction, and the amount of the collected chlorine dioxide gas was determined by the following titration method. The results are shown in Table 1 and FIG.
  • Example 2 In the chlorine dioxide generator X of Example 1, the amount of sodium chlorite contained in the aqueous sodium chlorite solution was variously changed to 400 to 1200 mg, and the amount of sulfuric acid contained in the solid composition 30 was varied to 115 to 350 mg. The changed gas was used to generate chlorine dioxide, and the gas amount of the collected chlorine dioxide was determined. The results are shown in Table 2 and FIG.
  • the amount of chlorine dioxide gas collected increases linearly as the amount of sodium chlorite contained in the aqueous sodium chlorite solution increases.
  • the reaction efficiency was almost 100%, it was recognized that chlorine dioxide gas was generated efficiently according to the theoretical value. Therefore, in the chlorine dioxide generator X of the present invention, it was recognized that the amount of chlorine dioxide gas to be generated can be easily adjusted by adjusting the amount of sodium chlorite contained in the aqueous solution of sodium chlorite.
  • the present invention relates to a chlorine dioxide generator that generates chlorine dioxide gas by reacting chlorite as a first component and a second component that reacts with the chlorite to generate chlorine dioxide gas. Available.
  • Chlorine dioxide generator 1 Chlorite aqueous solution 2
  • Second component 10 Outer vessel 11
  • Outer vessel lid 20 Inner vessel 30
  • Solid composition 40 Bag-shaped body 41 Ventilation section

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
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  • Inorganic Chemistry (AREA)
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  • General Life Sciences & Earth Sciences (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)

Abstract

L'invention concerne un dispositif de génération de dioxyde de chlore X qui génère du dioxyde de chlore gazeux par réaction de chlorite servant de premier composant avec un second composant (2) qui génère du dioxyde de chlore gazeux par réaction avec le chlorite. Ledit dispositif comprend: un récipient externe (10) qui est configuré de façon à être déformable en raison d'une force externe qui lui est appliquée et de telle sorte qu'un liquide peut être drainé; un récipient interne cassable (20) qui est logé à l'intérieur du récipient externe (10) et qui scelle une solution aqueuse de chlorite (1); et un corps de type sac (40) qui reçoit une composition solide (30) contenant le second composant (2) et le récipient externe (10) et qui a une partie perméable à l'air (41) qui a une perméabilité à l'air.
PCT/JP2019/038549 2018-10-01 2019-09-30 Dispositif de génération de dioxyde de chlore WO2020071324A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201980062472.0A CN112739644A (zh) 2018-10-01 2019-09-30 二氧化氯发生装置
KR1020217012208A KR20210062679A (ko) 2018-10-01 2019-09-30 이산화염소 발생 장치
JP2020550425A JP7412772B2 (ja) 2018-10-01 2019-09-30 二酸化塩素発生装置

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2018-186772 2018-10-01
JP2018186772 2018-10-01

Publications (1)

Publication Number Publication Date
WO2020071324A1 true WO2020071324A1 (fr) 2020-04-09

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JP2006335447A (ja) * 2005-06-03 2006-12-14 Daisen Sangyo Kk ガス発散袋状体
JP2011230956A (ja) * 2010-04-27 2011-11-17 Taiko Pharmaceutical Co Ltd スティック状の二酸化塩素発生装置
WO2012128022A1 (fr) * 2011-03-23 2012-09-27 大幸薬品株式会社 Générateur de dioxyde de chlore
US20160101978A1 (en) * 2014-10-13 2016-04-14 Purgofarm Co, Ltd. ClO2 EMISSION APPARATUS AND ClO2 GENERATOR
JP2017202346A (ja) * 2017-07-31 2017-11-16 有限会社クリーンケア 二酸化塩素発生剤

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US20040062680A1 (en) * 2002-09-30 2004-04-01 Bernard Technologies, Inc. Apparatus and method for generation of chlorine dioxide gas
JP2007145654A (ja) 2005-11-29 2007-06-14 Daisen Sangyo Kk 二酸化塩素ガス発生装置

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US20040241065A1 (en) * 2002-09-30 2004-12-02 Bernard Technologies, Inc. Apparatus and kit for generation of chlorine dioxide gas
JP2006335447A (ja) * 2005-06-03 2006-12-14 Daisen Sangyo Kk ガス発散袋状体
JP2011230956A (ja) * 2010-04-27 2011-11-17 Taiko Pharmaceutical Co Ltd スティック状の二酸化塩素発生装置
WO2012128022A1 (fr) * 2011-03-23 2012-09-27 大幸薬品株式会社 Générateur de dioxyde de chlore
US20160101978A1 (en) * 2014-10-13 2016-04-14 Purgofarm Co, Ltd. ClO2 EMISSION APPARATUS AND ClO2 GENERATOR
JP2017202346A (ja) * 2017-07-31 2017-11-16 有限会社クリーンケア 二酸化塩素発生剤

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JP7412772B2 (ja) 2024-01-15
KR20210062679A (ko) 2021-05-31

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