WO2020069734A1

WO2020069734A1 - Coated metal sheet, method to provide such a coated metal sheet, and hot dip galvanizing device to manufacture such a coated metal sheet

Info

Publication number: WO2020069734A1
Application number: PCT/EP2018/076874
Authority: WO
Inventors: Edgar Matthijs TOOSE; Henrique DUARTE ALVARENGA
Original assignee: Tata Steel Ijmuiden B.V.
Priority date: 2018-10-02
Filing date: 2018-10-02
Publication date: 2020-04-09
Also published as: EP3861146A1

Abstract

Method of providing a coating on a metal sheet, wherein a cold rolled metal sheet is subjected to a hot dip galvanizing operation to provide a metal coating on the metal sheet, which hot dip galvanizing operation comprises guiding the metal sheet through a liquid bath of the metal coating with at least one stabilization roll provided at a predefined depth (Depth) below surface level of the liquid bath, and wiping the metal coating that is provided on the metal sheet with at least one gas knife having an outlet to project wiping gas on the metal coating on the metal sheet that passes along the gas knife, wherein a distance (D) of the at least one gas knife to the passing metal sheet and a height (H) of the at least one gas knife above the liquid bath of the metal coating are selected at values so as to satisfy a formula X <= (Wsa - 0.1395) / 0.0016, wherein X = D*ln(H*Depth) and wherein Wsa is selected at a value representing a targeted maximum waviness.

Description

COATED METAL SHEET, METHOD TO PROVIDE SUCH A COATED METAL SHEET, AND HOT DIP GALVANIZING DEVICE TO MANUFACTURE SUCH A COATED METAL SHEET

The invention relates primarily to a method of providing a coating on a metal sheet, wherein a cold rolled metal sheet is subjected to a hot dip galvanizing operation to provide a metal coating on the metal sheet, which hot dip galvanizing operation comprises guiding the metal sheet through a liquid bath of the metal coating with at least one stabilization roll, wherein each stabilization roll is entirely provided below a predefined depth level below surface level of the liquid bath, and wiping the metal coating that is provided on the metal sheet with at least one gas knife having an outlet to project wiping gas on the metal coating that is provided on the metal sheet that passes along the gas knife.

Such a method of providing a coating on a metal sheet is widely known throughout the iron and steel industry; an exemplary publication showing such a method is GB 2517622.

A problem also acknowledged in GB 2517622 is the waviness of the coated metal sheet, which causes that after providing the coated metal sheet with a film of paint its outer appearance can be less than optimal. One known problem is the appearance of orange skin which is particularly undesirable for outside body parts of automobiles.

GB 2517622 does not particularly provide a workable solution for this problem, for one thing since its disclosure is obscure in relation to the waviness measure it applies.

It is an object of the invention to solve this long existing problem and to provide a workable solution for it. In this connection throughout this application waviness of the coated metal sheet is defined by the measure Wsa (pm) as published by the Deutsche Industry Norm publication SEP 1941 : 2012-05 entitled (in German): Messung des Welligkeitskennwertes Wsa (1-5) an kaltgewaltzten Flacherzeugnissen.

Accordingly the invention proposes a method to manufacture a coated metal sheet, such a coated metal sheet, a hot dip galvanizing device and its combination with a cold rolling mill in accordance with one or more of the appended claims.

In a first aspect of the invention the method of manufacturing a coated metal sheet wherein the upper horizontal plane tangent to the surface of the stabilization roll is located at a predefined depth level (Depth) below the surface level of the liquid bath, has the feature that a distance (D) of a closest gas knife to the passing metal sheet is determined, said distance (D) being measured as the length of a shortest possible virtual straight line between the gas knife and the metal sheet, and a height (H) of a lowest gas knife above the liquid bath of the metal coating is determined and that Depth, D and H are selected at values so as to satisfy a formula X <= (Wsa - 0.1395) / 0.0016, wherein X = D^*ln(H^*Depth), wherein Wsa is selected at a value representing a targeted maximum waviness,

In this specification <= symbolizes“less than or equal”.

In applying the above formula, Wsa is selected at a value representing a targeted maximum waviness, and values for distance D, height H and Depth are calculated.

The method of the invention can suitably be executed by providing that D is 9 mm or less, preferably 8 mm or less, preferably 7 mm or less.

Alternatively the method of the invention can be executed by providing that H is 550 mm or less, preferably 400 mm or less, more preferably 200 mm or less.

Favourable results can be achieved by providing that Depth is 150 mm or less, preferably 140 mm or less, more preferably 130 mm or less, most preferably 120 mm or less.

In a further aspect of the invention wherein working rolls of a cold rolling mill have a predefined roughness Ra, it is found beneficial that Depth, D and H are selected at values so as to satisfy X<= (Wsa - b) / a, wherein a and b are calculated as follows:

a = -0.00044 ^* Ra ^* Ra + 0.00297 ^* Ra - 0.00067, and

b = 0.03764^* Ra ^* Ra - 0.23352 ^* Ra + 0.23885.

Ra is determined in accordance with ISO 4287, using a cut-off of 2.5 mm.

More preferred is that Ra is 4.5 pm or less, 1.5 pm or less, preferably 0.6 pm or less.

According to the invention a coated metal sheet can effectively be provided with a waviness Wsa of 0.41 pm or less, preferably 0.35 pm or less, more preferably 0.31 pm or less, more preferably 0.26 pm or less, most preferably 0.23 pm or less. A suitable minimum value for the targeted maximum waviness Wsa is 0.18 pm.

The invention is also embodied in a hot dip galvanizing device to provide a metal coating on a moving metal sheet, comprising a liquid bath of metal coating to be provided on the metal sheet, and at least one stabilization roll guiding the moving metal sheet through the bath, the upper horizontal plane tangent to the surface of which stabilization roll is located at a predefined depth level (Depth) below the surface level of the liquid bath, and at least one gas knife provided above the liquid bath, said gas knife having an outlet to project wiping gas on the metal coating provided on the metal sheet that in use passes along the gas knife, having a distance (D) of the a closest gas knife to the passing metal sheet, said distance (D) being measured as the length of a shortest possible virtual straight line between the gas knife and the metal sheet, and a height (H) of a lowest gas knife above the liquid bath of the metal coating, characterized in that Depth, D and H are selected so as to satisfy a formula X <= (Wsa - 0.1395) / 0.0016, wherein X = D^*ln(H^*Depth), wherein Wsa is representing a targeted maximum waviness.

In one preferred embodiment of the hot dip galvanizing device D is 9 mm or less, preferably 8 mm or less, more preferably 7 mm or less.

In another preferred embodiment of the hot dip galvanizing device H is 550 mm or less, preferably 400 mm or less, more preferably 200 mm or less.

Preferably Depth is 150 mm or less, preferably 140 mm or less, more preferably 130 mm or less, most preferably 120 mm or less.

The invention is further embodied in a combination of a hot dip galvanizing device according to any one of claims 8 - 1 1 , with working rolls of a cold rolling mill have a predefined roughness Ra, characterized in that Depth, D and/or H are calculated in dependence of the roughness Ra of the working rolls of the cold rolling mill in relation to a targeted maximum waviness Wsa of the coated metal sheet according to a formula: X<= (Wsa - b) / a, wherein a and b are calculated as follows:

a = -0.00044 ^* Ra ^* Ra + 0.00297 ^* Ra - 0.00067, and

b = 0.03764^* Ra ^* Ra - 0.23352 ^* Ra + 0.23885.

The objects of the invention can be further promoted when Ra is 4.5 pm or less, 1.5 pm or less, preferably 0.6 pm or less.

The invention will hereinafter be further elucidated with reference to the drawing of an exemplary embodiment of an apparatus according to the invention that is not limiting as to the appended claims.

In the drawing:

-figure 1 schematically shows a hot dip galvanizing device.

Whenever in the figures the same reference numerals are applied, these numerals refer to the same parts.

A typical flow of manufacturing steps that leads to a coated metal sheet according to the invention, is as follows: A metal slab is cast, and subsequently hot rolled in a hot strip mill to provide a metal strip, that is processed in a pickling line, cold rolled in a cold rolling mill, annealed in a continuous annealing line, and provided with a metal coating in a hot dip galvanizing line, temper rolled in a temper mill, shipped to customers, press formed and painted. Some of these operations can be dispensed with, while it is also possible that some other operations are added to this sequence of events. The skilled person further knows that many operations precede the casting step.

Relevant to the invention is particularly what occurs in the hot dip galvanizing line 6, although of course the surface quality of the steel that arrives at the cold rolling mill also plays a decisive role in the resulting waviness of the final product. It is therefore expressly pointed out that albeit that the disclosure of the instant invention concentrates on the process of hot dip galvanizing, the other processing steps are not without importance and should be maintained at their normal high quality standard. A particular desirable relation between the hot dip galvanizing operation and a prior processing step will accordingly be discussed hereinafter.

Turning now to figure 1 it shows a hot dip galvanizing device 1 1 to provide a metal coating on one surface 12 or both surfaces 12, 13 of a moving metal sheet 14, comprising a tank 15 that holds a liquid bath of the metal coating 16 that is to be provided on the moving metal sheet 14.

Figure 1 shows the application of a stabilization roll 17 and a sink roll 21 to guide the moving metal sheet 14 through the bath, wherein the stabilization roll 17 is provided at a predefined depth (Depth) below a surface level 18 of the liquid bath. This Depth is defined as the distance between the surface level 18 of the liquid bath and an upper edge of the stabilization roll 17. It is remarked that the application of plural stabilization rolls is also possible, wherein then the Depth-parameter relates to the uppermost stabilization roll. Above the liquid bath at least one gas knife 19 is provided, which has an outlet 20 to project -in known way- wiping gas on the metal coating provided on the surface or surfaces 12, 13 of the metal sheet 15 that passes along the gas knife 19. Figure 1 shows both the height H of the gas knife or knives 19 above the liquid bath with reference to its surface level 18, and the distance D of the shown two air knives 19 with reference to the metal sheet 14.

According to the invention the distance D of the at least one gas knife 19 with reference to the passing metal sheet 14 and the height H of the at least one gas knife 19 above the liquid bath of the metal coating 16 are selected at values so as to satisfy a formula X <= (Wsa - 0.1395) / 0.0016, wherein X = D^*ln(H^*Depth) and wherein Wsa is selected at a value representing a targeted maximum waviness, and wherein Depth stands for the depth of the at least one stabilization roll 17 below the surface level 18 of the liquid bath.

Table 1 shows the influence of the height H of the gas knife 19 above the liquid bath, and the influence of the distance D from sheet 14 to knife 19 in relation to the waviness Wsa of the coated metal sheet 14.

Table 1

Table 2 shows the influence of the height H of the gas knife 19 above the liquid bath and the Depth of the at least one stabilizing roll 17 below the surface level 18 of the liquid bath. Table 2

It follows from table 1 and table 2 that preferably the distance D of the at least one gas knife 19 to the passing metal sheet 14 is equal or less than 9 mm, more preferably equal or less than 8 mm, even more preferable equal or less than 7 mm, and the height H of the at least one gas knife above the liquid bath of the metal coating is then selected at a value so as to satisfy the formula X <= (Wsa - 0.1395) / 0.0016, wherein X = D^*ln(H^*Depth).

Alternatively it follows from table 1 and table 2 that the height H of the at least one gas knife 19 above the liquid bath of the metal coating 16 is preferably equal or less than 550 mm, preferably equal or less than 400 mm, more preferably equal or less than 200 mm, and the distance D of the at least one gas knife 19 to the passing metal sheet 14 is selected at a value so as to satisfy the formula X <= (Wsa - 0.1395) / 0.0016, wherein X = D^*ln(H^*Depth).

Table 3 shows the influence of the roughness Ra of the last working rolls in the cold rolling mill in relation to X and their impact on the waviness of the product.

Table 3

According to the results of Tables 2 and 3 stabilization roll 17 is preferably provided at a depth D below surface level 18 of the liquid bath at a value of equal or less than 150 mm, preferably at a value equal or less than 140 mm, more preferably at a value equal or less than 130 mm, most preferably at a value equal or less than 120 mm.

Table 3 shows a calculation of the parameters to arrive at a target Wsa and it also shows the measured waviness as Realised Wsa. X is determined with the formula X<= (Wsa - b) / a, wherein a and b are calculated as follows:

a = -0.00044 ^* Ra ^* Ra + 0.00297 ^* Ra - 0.00067, and

b = 0.03764^* Ra ^* Ra - 0.23352 ^* Ra + 0.23885,

wherein X = D^*ln(H^*Depth), and Ra stands for the roughness of the working rolls in the last stand of the cold rolling mill. From the data found in experimenting with the invention it could be derived that the stabilization roll 17 is preferably provided at a depth D below surface level 18 of the liquid bath of the metal coating 16 in dependence of the roughness Ra of the final working rolls of the cold rolling mill in order to achieve a maximum waviness Wsa of the coated metal sheet. Further preferred values of the roughness Ra are equal or less than 4.5 pm, equal or less than 1.5 pm, and more preferably 0.6 pm or less.

The method of coating a metal sheet according to the invention results in a coated metal sheet with a waviness value Wsa equal or less than 0.41 pm; preferably equal or less than 0.35 pm; more preferably equal or less than 0.31 pm; more preferably equal or less than 0.26 pm; most preferably equal or less than 0.23 pm.

Although the invention has been discussed in the foregoing with reference to exemplary embodiments of the method and devices of the invention, the invention is not restricted to these particular embodiments which can be varied in many ways without departing from the invention. The discussed exemplary embodiments shall therefore not be used to construe the appended claims strictly in accordance therewith. On the contrary, the embodiments are merely intended to explain the wording of the appended claims without intent to limit the claims to these exemplary embodiments. The scope of protection of the invention shall therefore be construed in accordance with the appended claims only, wherein a possible ambiguity in the wording of the claims shall be resolved using these exemplary embodiments.

Claims

1. Method of providing a coating on a metal sheet, wherein a cold rolled metal sheet is subjected to a hot dip galvanizing operation to provide a metal coating on the metal sheet, which hot dip galvanizing operation comprises guiding the metal sheet through a liquid bath of the metal coating with at least one stabilization roll, the upper horizontal plane tangent to the surface of which is located at a predefined depth level (Depth) below the surface level of the liquid bath, and wiping the metal coating that is provided on the metal sheet with at least one gas knife having an outlet to project wiping gas on the metal coating on the metal sheet that passes along the gas knife, characterized in that a distance (D) of a closest gas knife to the passing metal sheet is determined, said distance (D) being measured as the length of a shortest possible virtual straight line between the gas knife and the metal sheet, and a height (H) of a lowest gas knife above the liquid bath of the metal coating is determined and in that Depth, D and H are selected at values so as to satisfy a formula X <= (Wsa - 0.1395) / 0.0016, wherein X = D^*ln(H^*Depth), wherein Wsa is selected at a value representing a targeted maximum waviness.

2. Method according to claim 1 , characterized by providing that D is 9 mm or less, preferably 8 mm or less, preferably 7 mm or less.

3. Method according to claim 1 or claim 2, characterized by providing that H is 550 mm or less, preferably 400 mm or less, more preferably 200 mm or less.

4. Method according to any one of claims 1 - 3, characterized by providing that Depth is 150 mm or less, preferably 140 mm or less, more preferably 130 mm or less, most preferably 120 mm or less.

5. Method according to any one of claims 1 - 4, wherein working rolls of a cold rolling mill have a predefined roughness Ra, characterized in that Depth, D and H are selected at values so as to satisfy X<= (Wsa - b) / a, wherein a and b are calculated as follows:

a = -0.00044 ^* Ra ^* Ra + 0.00297 ^* Ra - 0.00067, and

b = 0.03764^* Ra ^* Ra - 0.23352 ^* Ra + 0.23885.

6. Method according to claim 5, characterized by providing that Ra is 4.5 pm or less, 1.5 pm or less, preferably 0.6 pm or less.

7. Coated metal sheet manufactured in accordance with the method of any one of the previous claims 1 - 6, with a waviness value Wsa of 0.41 pm or less, preferably 0.35 pm or less, more preferably 0.31 pm or less, more preferably 0.26 pm or less, most preferably

0.23 pm or less.

8. Hot dip galvanizing device to provide a metal coating on a moving metal sheet, comprising a liquid bath of metal coating to be provided on the metal sheet, and at least one stabilization roll guiding the moving metal sheet through the bath, the upper horizontal plane tangent to the surface of which stabilization roll is located at a predefined depth level (Depth) below the surface level of the liquid bath, and at least one gas knife provided above the liquid bath, said gas knife having an outlet to project wiping gas on the metal coating provided on the metal sheet that in use passes along the gas knife, having a distance (D) of the a closest gas knife to the passing metal sheet, said distance (D) being measured as the length of a shortest possible virtual straight line between the gas knife and the metal sheet, and a height (H) of a lowest gas knife above the liquid bath of the metal coating, characterized in that Depth, D and H are selected so as to satisfy a formula X <= (Wsa - 0.1395) / 0.0016, wherein X = D^*ln(H^*Depth), wherein Wsa is representing a targeted maximum waviness.

9. Hot dip galvanizing device according to claim 8, characterized in that D is 9 mm or less, preferably 8 mm or less, more preferably 7 mm or less.

10. Hot dip galvanizing device according to claim 8 or 9, characterized in that H is 550 mm or less, preferably 400 mm or less, more preferably 200 mm or less.

1 1. Hot dip galvanizing device according to any one of claims 8 - 10, characterized in that Depth is 150 mm or less, preferably 140 mm or less, more preferably 130 mm or less, most preferably 120 mm or less.

12. Combination of a hot dip galvanizing device according to any one of claims 8 - 1 1 , with working rolls of a cold rolling mill have a predefined roughness Ra, characterized in that Depth, D and/or H are calculated in dependence of the roughness Ra of the working rolls of the cold rolling mill in relation to a targeted maximum waviness Wsa of the coated metal sheet according to a formula X<= (Wsa - b) / a, wherein a and b are calculated as follows:

a = -0.00044 ^* Ra ^* Ra + 0.00297 ^* Ra - 0.00067, and

b = 0.03764^* Ra ^* Ra - 0.23352 ^* Ra + 0.23885.

13. Combination of a hot dip galvanizing device with working rolls of a cold rolling mill according to claim 12, characterized in that Ra is 4.5 pm or less, 1.5 pm or less, preferably 0.6 pm or less.