WO2020027702A3 - Apparatus and method for plasma-chemical hydrocracking, and plant with such apparatus - Google Patents

Apparatus and method for plasma-chemical hydrocracking, and plant with such apparatus Download PDF

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Publication number
WO2020027702A3
WO2020027702A3 PCT/RU2019/050121 RU2019050121W WO2020027702A3 WO 2020027702 A3 WO2020027702 A3 WO 2020027702A3 RU 2019050121 W RU2019050121 W RU 2019050121W WO 2020027702 A3 WO2020027702 A3 WO 2020027702A3
Authority
WO
WIPO (PCT)
Prior art keywords
reactor
hydrogen
containing medium
hydrocarbons
plasma
Prior art date
Application number
PCT/RU2019/050121
Other languages
French (fr)
Other versions
WO2020027702A2 (en
Inventor
Alexey Vladimirovich TVERSKOY
Vladimir Semenovich TVERSKOY
Original Assignee
Plazarium
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Plazarium filed Critical Plazarium
Publication of WO2020027702A2 publication Critical patent/WO2020027702A2/en
Publication of WO2020027702A3 publication Critical patent/WO2020027702A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G15/00—Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs
    • C10G15/12—Cracking of hydrocarbon oils by electric means, electromagnetic or mechanical vibrations, by particle radiation or with gases superheated in electric arcs with gases superheated in an electric arc, e.g. plasma
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/22—Non-catalytic cracking in the presence of hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0869—Feeding or evacuating the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0871—Heating or cooling of the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0875—Gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0877—Liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0881—Two or more materials
    • B01J2219/0884—Gas-liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0894—Processes carried out in the presence of a plasma
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0894—Processes carried out in the presence of a plasma
    • B01J2219/0898—Hot plasma

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electromagnetism (AREA)
  • Plasma & Fusion (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

The present invention relates to an apparatus for plasma-chemical hydrocracking, comprising a reactor, a plasmatron, a tubular element, and means for feeding liquid hydrocarbons and a hydrogen-containing medium and means for discharging non-reacted liquid hydrocarbons and produced gaseous hydrocarbons. The tubular element surrounds plasma flow inside the reactor and has an outer circumferential wall, an inner circumferential wall and a gap formed between the two circumferential walls and connected to a hydrogen-containing medium inlet. The inner circumferential wall has through channels for passage of the hydrogen-containing medium from the gap to the plasma flow and thereby defines a mixing zone in the reactor for mixing the plasma flow with the hydrogen-containing medium; the mixing zone together with a partition provided in the reactor and forming a surface for spreading liquid hydrocarbons at least partially define a reaction zone inside the reactor, having a constriction of a gas-dynamic nozzle type. The invention also relates to a method and a plant using the apparatus. Technical result includes enhancing the intensity of vaporization of hydrocarbons during plasma-chemical hydrocracking and increasing the speed of mixing the components of vaporous hydrocarbons and the hydrogen-containing medium with significant acceleration of the rate of chemical reactions between these components.
PCT/RU2019/050121 2018-07-31 2019-07-26 Apparatus and method for plasma-chemical hydrocracking, and plant with such apparatus WO2020027702A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2018128013 2018-07-31
RU2018128013A RU2671822C1 (en) 2018-07-31 2018-07-31 Device and method for plasma-chemical hydrocracking and installation equipped therewith

Publications (2)

Publication Number Publication Date
WO2020027702A2 WO2020027702A2 (en) 2020-02-06
WO2020027702A3 true WO2020027702A3 (en) 2020-03-12

Family

ID=64103482

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2019/050121 WO2020027702A2 (en) 2018-07-31 2019-07-26 Apparatus and method for plasma-chemical hydrocracking, and plant with such apparatus

Country Status (2)

Country Link
RU (1) RU2671822C1 (en)
WO (1) WO2020027702A2 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006099070A1 (en) * 2005-03-10 2006-09-21 Arvin Technologies, Inc. Electrode assembly of a plasma fuel reformer
CN101550056A (en) * 2009-05-08 2009-10-07 清华大学 A thermal plasma coal cracking - gasification coupling process and reaction unit
US20150044106A1 (en) * 2011-12-01 2015-02-12 National Institute Of Clean-And-Low-Carbon Energy Multi-stage plasma reactor system with hollow cathodes for cracking carbonaceous material
US20160017247A1 (en) * 2014-07-15 2016-01-21 Magnegas Corporation Gas Production from an Oil Feedstock

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2724806A1 (en) * 1994-09-16 1996-03-22 Pompes Maupu Entreprise Novel method for the non-catalytic vapour cracking of hydrocarbon(s) and halogen-organic cpds.
RU2319730C1 (en) * 2006-11-09 2008-03-20 Евгений Ефимович Беличенко Methods of hydrocracking of the heavy hydrocarbon fractions and the device for its implementation
RU2411286C1 (en) * 2009-10-02 2011-02-10 Евгений Ефимович Беличенко Installation for plasma-chemical hydro-cracking of hydrocarbon fractions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006099070A1 (en) * 2005-03-10 2006-09-21 Arvin Technologies, Inc. Electrode assembly of a plasma fuel reformer
CN101550056A (en) * 2009-05-08 2009-10-07 清华大学 A thermal plasma coal cracking - gasification coupling process and reaction unit
US20150044106A1 (en) * 2011-12-01 2015-02-12 National Institute Of Clean-And-Low-Carbon Energy Multi-stage plasma reactor system with hollow cathodes for cracking carbonaceous material
US20160017247A1 (en) * 2014-07-15 2016-01-21 Magnegas Corporation Gas Production from an Oil Feedstock

Also Published As

Publication number Publication date
RU2671822C1 (en) 2018-11-07
WO2020027702A2 (en) 2020-02-06

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