WO2020010690A1 - 一种含有环吡氟草酮的三元除草组合物及其应用 - Google Patents

一种含有环吡氟草酮的三元除草组合物及其应用 Download PDF

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WO2020010690A1
WO2020010690A1 PCT/CN2018/105271 CN2018105271W WO2020010690A1 WO 2020010690 A1 WO2020010690 A1 WO 2020010690A1 CN 2018105271 W CN2018105271 W CN 2018105271W WO 2020010690 A1 WO2020010690 A1 WO 2020010690A1
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Prior art keywords
ciclopiromone
ciclopirox
stellate
bovine
polyoxyethylene ether
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PCT/CN2018/105271
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English (en)
French (fr)
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金涛
彭学岗
赵德
张景远
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青岛清原化合物有限公司
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Publication of WO2020010690A1 publication Critical patent/WO2020010690A1/zh

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18Nitro compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/661,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/681,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/7071,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof

Definitions

  • the invention belongs to the field of pesticides, and particularly relates to a ternary herbicidal composition containing ciclopirox and its application.
  • Chemical weed control is the most economical and effective method for controlling weeds in farmland.
  • long-term continuous high-dose use of a single variety or single action chemical herbicide can easily cause problems such as resistance and evolution of weeds.
  • Reasonable compounding or mixing of herbicide compounds has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of weed resistance and resistance, and is one of the most effective methods to solve the above problems. Therefore, there is an urgent need to develop a variety of herbicidal compositions with high safety, broad herbicidal spectrum, which can produce synergistic effects and solve the problem of resistant weeds.
  • the present invention provides a ternary herbicidal composition containing ciclopirox and its application.
  • the composition can effectively prevent weeds in cattle fields such as cattle stellariae, cockroaches, wheat maidens, pig crickets, mother-in-law, amaranth and other weeds in crop fields. And address the characteristics of resistant weeds.
  • a ternary herbicidal composition comprising a herbicidally effective amount of active ingredient A, active ingredient B and active ingredient C, wherein,
  • the active ingredient A is ciclopirox (CAS: 1855929-45-1);
  • the active ingredients B and C are respectively selected from any one of the following types of compounds and another compound different from them:
  • PPO inhibitor oxadiazon (CAS: 19666-30-9);
  • PS class II inhibitors Prometryn (CAS: 7287-19-6), terbutin (CAS: 886-50-0), oxadiazon (CAS: 21087-64-9), oxadiazon (CAS) : 129909-90-6), green wheat (CAS: 15545-48-9), isoprolong (CAS: 34123-59-6), pyracote (CAS: 55512-33-9);
  • ALS inhibitor thifensulfuron (CAS: 79277-27-3);
  • Inhibitors of microtubule assembly Flulorene (CAS: 1582-09-8), Zhongdingling (CAS: 33629-47-9), pendimethalin (CAS: 40487-42-1);
  • PDS inhibitors furazone (CAS: 96525-23-4), flufenamid (CAS: 83164-33-4), flufenamid (CAS: 137641-05-5);
  • Lipid synthesis (non-acetyl-Coenzyme A carboxylase) inhibitors benzalacetam (CAS: 52888-80-9), wild wheat (CAS: 2303-17-5);
  • VLCFA-type inhibitors acetochlor (CAS: 34256-82-1), butachlor (CAS: 23184-66-9), propachlor (CAS: 51218-49-6), metolachlor ( CAS: 51218-45-2), mesometamine (CAS: 87392-12-9 (S-body), CAS: 178961-20-1 (R-body)), fluoxadi (CAS: 142459-58-3), sulfamethoxazole (CAS: 447399-55-5);
  • the weight ratio of A, B, and C is 1 to 200: 1 to 1000: 1 to 1000 and 1 to 150: 5 to 800: 5 to 800; preferably 3 to 100: 10 to 500: 10 to 500 and 5 to 80 : 20 to 300: 20 to 300; more preferably 8 to 60: 50 to 200: 50 to 200 and 10 to 50: 60 to 100: 60 to 100.
  • the mass percentage of A, B, and C in the herbicidal composition is 1-95% of the total, preferably 10-80%.
  • the herbicidal composition further includes a conventional auxiliary agent, and the conventional auxiliary agent includes a carrier and a surfactant.
  • carrier herein means an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carrier is generally inert and must be agriculturally acceptable, especially by the treated plant.
  • the carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, etc .; or liquid, such as water, alcohols, ketones, petroleum fractions, aromatic or wax hydrocarbons, chlorine Hydrocarbon replacement, liquefied gas, etc.
  • the surfactant may include an emulsifier, a dispersant, or a wetting agent, and it may be ionic or non-ionic.
  • examples which may be mentioned are salts of polyacrylic acid, ligninsulfonates, phenolsulfonic or naphthalenesulfonic acids, ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols (particularly Is an alkylphenol or an arylphenol) polymer, a sulfosuccinate, a taurine derivative (especially an taurine alkyl ester), and a phosphate of an alcohol or a polyhydroxyethylated phenol, Alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates, and sulfated cetyl-, hepta- and stearyl alcohol
  • composition may also contain various other components such as protective colloids, adhesives, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
  • the ternary composition of the present invention can be mixed with the following active substances, for example, "World Encyclopedia of New Pesticide Technology", China Agricultural Science and Technology Press, 2010.9 and the known substances in the literature cited here.
  • the herbicide active substances mentioned below (note: the name of the compound, or the common name according to the International Organization for Standardization (ISO), or the chemical name, with a code when appropriate): acetochlor, butachlor, Alachlor, Promethachlor, Metolachlor, Prometachlor, Promechlor, Toxachlor, Chlortochlor, Naproxyl, R-Lonaphal , Fenoxadi, fenoxyfen, fenflufen, chlorfenapyr, flubutyramide, bromobutyramide, methacetamide, high-efficiency methacetamide, ethoxylate Acetochlor, fluoxadi, methachlor, prazachlor, clomazone, high-performance dic
  • the herbicidal composition further includes at least one safener selected from:
  • Dichlorophenylpyrazoline-3-carboxylic acid (S1) compounds and preferred compounds are, for example, 1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl Ethyl-2-pyrazoline-3-carboxylic acid ethyl ester (S1-1, mefenpyr-diethyl, PM, pages 594-595), and described in, for example, WO91 / 07874 and PM (page 594-595).
  • Dichlorophenylpyrazolecarboxylic acid derivatives are, for example, 1- (2,4-dichlorophenyl) -5-methylpyrazole-3-carboxylic acid ethyl ester (S1-2), 1- (2,4-dichlorophenyl) -5-isopropylpyrazole-3-carboxylic acid ethyl ester (S1-3), 1- (2,4-dichlorophenyl) -5- (1 1,1-dimethyl-ethyl) pyrazole-3-carboxylic acid ethyl ester (S1-4), 1- (2,4-dichlorophenyl) -5-phenylpyrazole-3-carboxylic acid ethyl Esters (S1-5), and related compounds described in EP-A-333131 and EP-A-269806.
  • Triazolecarboxylic acid (S1) compounds and preferred compounds are, for example, fenchlorazole, that is, 1- (2,4-dichlorophenyl) -5-trichloromethyl- (1H) -1 , 2,4-triazole-3-carboxylic acid ethyl ester (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
  • 5-benzyl- or 5-phenyl-2-isooxazoline-3-carboxylic acids or 5,5-diphenyl-2-isooxazoline-3-carboxylic acids preferably
  • the compound is, for example, 5- (2,4-dichlorobenzyl) -2-isoxazoline-3-carboxylic acid ethyl ester (S1-7) or 5-phenyl-2-isooxazoline-3-carboxylic acid Ethyl Ester (S1-8) and related compounds described in WO91 / 08202, or 5,5-diphenyl-2-isooxazoline- described in patent application (WO-A-95 / 07897) Ethyl 3-carboxylate (S1-9, isoxadifen-ethyl) or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid n-propyl ester (S1-10) Or 5- (4-fluorophenyl) -5-phenyl
  • S2 8-quinolinoxyacetic acid (S2) compounds, preferably 1-methylhex-1-yl (5-chloro-8-quinolinoxy) acetate (S2-1, cloquintocet- mexyl), such as PM (p.195-196), (1,3-dimethylbut-1-yl) (5-chloro-8-quinolinyloxy) acetate (S2-2), 4- Allyloxybutyl (5-chloro-8-quinolinoxy) acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy (Yl) acetate (S2-4), (5-chloro-8-quinolinoxy) ethyl acetate (S2-5), (5-chloro-8-quinolinoxy) methyl acetate (S2- 6), (5-chloro-8-quinolinoxy) allyl acetate (S2-7), 2- (2-propyleneiminooxy) -1-ethyl (5-chloro-8
  • 5-chloro-8-quinolinyloxy) malonic acid compounds and preferred compounds are, for example, (5-chloro-8-quinolinyloxy) malonic acid diethyl ester, (5-chloro-8 -Quinolinoxy) diallyl malonate, (5-chloro-8-quinolinoxy) -methyl malonate and related compounds described in EP-A-0582198.
  • active compounds of phenoxyacetic acid, phenoxypropionic acid or aromatic carboxylic acids such as 2,4-dichlorophenoxyacetic acid (and esters) (2,4-D), 4-chloro-2- Methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and esters) (dicamba) .
  • Corn seed dressings are called safeners to prevent damage from thiourethane herbicides
  • the safener is preferably dibenzoxazolic acid (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), pyrazolidin (CAS: 135590-91-9), and detoxification quinone (CAS : 99607-70-2), gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8), metcamifen (CAS: 129531-12-0).
  • composition of the invention can be diluted or used directly by the user before use.
  • Its formulation can be prepared by ordinary processing methods, that is, after mixing the active substance with a liquid solvent or a solid carrier, and then adding one or more of a surfactant such as a dispersant, a stabilizer, a wetting agent, a binder, an antifoaming agent, etc. Species.
  • the specific preparation of the herbicidal composition is a dispersible oil suspension, an aqueous suspension, a suspoemulsion, a wettable powder, an emulsifiable concentrate, a water-dispersible granule (dry suspension), an aqueous emulsion, and a microemulsion.
  • compositions of the present invention can be mixed with solid and liquid additives conventionally used in prior art formulations.
  • the invention also provides an application of the ternary herbicidal composition for controlling harmful weeds in crops; and a method for controlling unwanted plant growth, which comprises applying the ternary herbicidal composition to plants , Plant parts, plant seeds or areas where plants grow, preferably for selective control of harmful plants in crops.
  • composition of the present invention can be applied to the leaves of the plant to be treated by spraying, that is, to the weeds, especially to the surface of weeds that are harmful to crop growth or are easily affected by the weeds.
  • composition of the present invention is environment-friendly and easily degrades in the environment, and is suitable for various crop fields.
  • the herbicidal composition of the present invention has low cost and convenient use, and its promotion and application has huge economic and social benefits.
  • Ciclopiromone + pendimethalin + flufenamid 1.5 + 15 + 0.75) dispersible oil suspension
  • the above-mentioned water suspending agent processing equipment mixing kettle, colloid mill, sand mill, shearing machine, etc.
  • the above-mentioned water suspending agent processing process Put all the materials into the mixing tank, stir and mix the colloid mill, then enter the sand mill three-stage sand mill, and finally cut it uniformly in the shearing machine. After passing the test, transfer to the storage Can filling.
  • dispersible oil suspending agent processing equipment mixing kettle, colloid mill, sand mill, shearing machine, etc.
  • the above-mentioned dispersible oil suspending agent processing process Put all the materials into the mixing tank, stir and mix through the colloid mill, then enter the sand mill three-stage sand mill, and finally cut evenly in the shearing machine. After passing the test, transfer Fill to tank.
  • the above suspension emulsion processing equipment mixing kettle, colloid mill, sand mill, shearing machine, shearing kettle.
  • the above suspension emulsion processing process Put some materials into the mixing tank, stir and mix and then pass the colloid mill, and then enter the three-stage sand mill of the sand mill. After passing the test, enter the shear kettle for backup, and use it as the water phase material. The drug and solvent are put into the mixing kettle, stirred to dissolve until completely transparent, and then an emulsifier is added, and the oil phase is evenly stirred. Then, the shearing machine is turned on, and the oil phase is slowly drawn into the shearing kettle under the shearing state. After all the materials are drawn in, continue to cut for 1 hour. After passing the test, transfer to the storage tank for filling.
  • the aforementioned water-dispersed granule processing equipment jet mill, coulter mixer, basket granulator, drying box, sieving machine, etc.
  • the above-mentioned water-dispersed granule processing process the above materials are mixed uniformly and pulverized by air flow, water is added into the kneaded granulation, then dried, and finally sieved to obtain a finished product.
  • the above wettable powder processing equipment mechanical pulverizer, jet pulverizer.
  • the above wettable powder processing process the original medicine, auxiliary agent, white carbon black, kaolin, etc. are put into a mechanical pulverizer, and then passed through an air jet pulverizer, and the sample is tested and passed for use.
  • the cattle weeds were collected from Xinghua, Jiangsu.
  • the above weeds were cultivated in a pot method. They were placed in an enamel pan with a 180 ⁇ 140mm plastic nutrition bowl, and the surface soil (4/5 places) was collected from the farmland and air-dried. The initial humidity of the soil is controlled at 20%. Weed seeds with full and uniform grains are selected, soaked in warm water at 25 ° C for 6 hours, and germinated in a 28 ° C biochemical incubator (dark). The soil surface is then covered with 0.5-1cm of soil according to the seed particle size.
  • 3WP-2000 walking spray tower Nanjing Agricultural Machinery Research Institute, Ministry of Agriculture. GA10 type one ten thousandth electronic balance (Germany); ZDR2000 intelligent data recorder (Hangzhou Zeda Instrument Co., Ltd.); SPX intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory).
  • the required active ingredient, ciclopirox, is produced by the company, and the others are purchased by the reagent company.
  • the original drugs use acetone as the solvent, diluted with 0.1% emulsifier T-80 aqueous solution, and are now diluted.
  • the characteristics of the agent and its virulence should be measured, and the main purpose of the formula should also be considered. Based on the preliminary test in this study, the single and mixed dosages of the active ingredients are shown in the table. Water containing no drugs, containing the same solvents and emulsifiers was used as a blank control.
  • Each treatment was repeated 4 times, each treatment was 3 pots, and 20 weed seeds were sown in each pot, for a total of 60 plants per treatment.
  • the trial shared the drug once. When the weeds are in the 1-leaf stage and thinning, keep 15 weeds in each pot and 45 plants in each treatment, and then continue to grow until the 2 to 3 leaf stage is sprayed with uniform stems and leaves.
  • the cultivated test material was evenly placed on a platform with an area of 0.5 m 2 , and sprayed with the stems and leaves of a 3WP-2000 walking spray tower, and the spray amount was calculated as 30 kg / ha.
  • Spray pressure is 0.3MPa. After spraying all the chemicals, close the gas valve. After 30 seconds, open the spray tower door and remove the nutrition bowl. Then open the air valve, spray 50ml of clean water, and clean the spray pipe.
  • Absolute number survey method was used to cut the whole seedlings of surviving weeds along the soil surface with a blade, and the fresh weeds were weighed with an analytical balance. For dead weeds, the fresh weight is zero.
  • the Colby method was used to evaluate the combined effect of any two and three on weeds.
  • E (%) (fresh weed weight in the treatment area / fresh weed weight in the control area) ⁇ 100
  • X represents the weed survival rate of A when the amount is P
  • Y is the weed survival rate of B when the amount is Q
  • E0 is the theoretical weed survival rate of A + B when the amount is (P + Q)
  • E represents Actual weed survival rate for each treatment.
  • E0 (%) X ⁇ Y ⁇ Z ⁇ ... ⁇ N / 100 (n-1) (mixed with ternary and above)
  • X, Y, Z, and N respectively represent the actual survival rates of n single agents, and n is the number of compound herbicide varieties.
  • E0-E> 10% it means synergistic effect; when E0-E ⁇ -10%, it means antagonistic effect; when E0-E is between ⁇ 10%, it means additive effect.
  • Table 1 A is ciclopirox, B is oxadiazon, C is prochloraz, and the test material is boll stellate
  • Table 2 A is ciclopirox, B is oxadiazon, C is terbutin, and the material is bovine stellate
  • Table 3 A is cycloflufenone, B is oxadiazon, C is oxadiazon, and the test material is bovine stellate
  • Table 4 A is ciclopirox, B is oxadiazon, C is flubendione, and the test material is bovine stellate
  • Table 5 A is ciclopirox, B is oxadiazon, C is green malon, and the test material is bovine stellate
  • Table 6 A is ciclopirox, B is oxadiazon, C is isoprolong, and the test material is bovine stellate
  • Table 7 A is ciclopirox, B is oxadiazon, C is pyridate, and the test material is bovine stellate
  • Table 8 A is ciclopirox, B is oxadiazon, C is thifensulfuron, and the material is bovine stellate
  • Table 9 A is ciclopirox, B is oxadiazon, C is flulorin, and the material is bovine stellate
  • Table 10 A is ciclopirox, B is oxadiazon, C is bupropion, and the material is bovine stellate
  • A is cimifloxazone
  • B is clomazone
  • C is pendimethalin
  • the material is bovine stellate
  • Table 12 A is ciclopirox, B is oxadiazon, C is furazone, and the test material is bovine stellate
  • Table 13 A is cycloflufenone, B is oxadiazon, C is flufenamid, and the material is bovine stellate
  • Table 14 A is ciclopirox, B is oxadiazon, C is fluoxamid, and the test material is bovine stellate
  • Table 15 A is ciclopirox, B is oxadiazon, C is benpropran, and the test material is boll stellate
  • Table 16 A is ciclopirox, B is oxadiazon, C is wild wheat, and the test material is bovine stellate
  • Table 17 A is ciclopirox, B is oxadiazon, C is acetochlor, and the material is bovine stellate
  • Table 18 A is ciclopirox, B is oxadiazon, C is butachlor, and the material is bovine stellate
  • Table 19 A is ciclopirox, B is oxadiazon, C is propachlor, and the material is bovine stellate
  • Table 20 A is cimifloxazone, B is clomazone, C is mesotrichlor, and the material is bovine stellate
  • Table 21 A is ciclopirox, B is clomazone, C is mesotrichlor, and the test material is bovine stellate
  • Table 22 A is ciclopirox, B is oxadiazon, C is fluoxamid, and the material is bovine stellate
  • Table 23 A is ciclopirox, B is oxadiazon, C is sulfamethoxazole, and the test material is bovine stellate
  • Table 24 A is cimiflufenone, B is profenuron, C is thifensulfuron, and the material is bovine stellate
  • Table 25 A is ciclopirox, B is profenazine, C is fluroxyline, and the test material is bovine stellate
  • Table 26 A is ciclopirox, B is profenazine, C is bupropion, and the test material is bovine stellate
  • A is cimifloxazone
  • B is profenazine
  • C is pendimethalin
  • the material is bovine stellate
  • Table 28 A is ciclopirox, B is profenacet, C is furazone, and the test material is bovine stellate
  • Table 29 A is ciclopirox, B is profenacet, C is flufenamid, and the test material is bovine stellate
  • Table 30 A is ciclopirox, B is profenazine, C is flufenamid, and the material is boll stellaria
  • A is ciclopirox
  • B is profencol
  • C is benzbutazone
  • the test material is bovine stellate
  • Table 32 A is ciclopirox, B is profenazine, C is wild wheat, and the test material is cattle stellate
  • Table 33 A is ciclopirox, B is profenazine, C is acetochlor, and the test material is bovine stellate
  • Table 34 A is ciclopirox, B is profencol, C is butachlor, and the material is bovine stellate
  • Table 35 A is ciclopirox, B is profenacet, C is prochlorfen, and the test material is bovine stellate
  • Table 36 A is ciclopirox, B is profenazine, C is mesotrichlor, and the material is bovine stellate
  • Table 37 A is ciclopirox, B is profencol, C is mesotrichlor, and the test material is boll stellaria
  • Table 38 A is ciclopirox, B is profenacet, C is fluoxamid, and the test material is boll stellaria
  • A is cimifloxazone
  • B is profenazine
  • C is sulfamethoxazole
  • the material is bovine stellate
  • A is cimifloxazone
  • B is terbutin
  • C is thifensulfuron
  • the material is bovine stellate
  • A is cimifloxazone
  • B is terbutin
  • C is fluroxyline
  • the material is bovine stellate
  • Table 42 A is cimifloxazone, B is terbutin, C is bupropion, and the material is bovine stellate
  • Table 43 A is cimifloxazone, B is terbutin, C is pendimethalin, and the sample is bovine stellate
  • A is cimifloxazone
  • B is terbutin
  • C is furazone
  • the material is bovine stellate
  • Table 45 A is ciclopirox, B is terbutin, C is flufenamid, and the material is bovine stellate
  • A is ciclopirox
  • B is terbutin
  • C is flufenamid
  • the test material is bovine stellate
  • A is ciclopirox
  • B is terbutin
  • C is benzbutazone
  • the material is bovine stellate
  • Table 48 A is cimifloxazone, B is terbutin, C is wild wheat, and the test material is bovine stellate
  • A is cimifloxazone
  • B is terbutin
  • C is acetochlor
  • the material is bovine stellate
  • Table 50 A is ciclopirox, B is terbutin, C is butachlor, and the material is bovine stellate
  • Table 51 A is ciclopirox, B is terbutin, C is propachlor, and the test material is bovine stellate
  • A is cimifloxazone
  • B is terbutin
  • C is metolachlor
  • the material is bovine stellate
  • A is cimifloxazone
  • B is terbutin
  • C is mesotrichlor
  • the test material is bovine stellate
  • Table 54 A is ciclopirox, B is terbutin, C is fluoxamid, and the material is bovine stellate
  • A is cimifloxazone
  • B is terbutin
  • C is sulfamethoxazole
  • the material is bovine stellate
  • Table 56 A is ciclopirox, B is oxafluzone, C is thifensulfuron, and the material is bovine stellate
  • A is ciclopirox
  • B is oxafluzone
  • C is fluroxyline
  • the test material is bovine stellate
  • Table 58 A is ciclopirox, B is azoxystrozone, C is bupropion, and the test material is bovine stellate
  • Table 59 A is ciclopirox, B is oxafluzone, C is pendimethalin, and the sample is bovine stellate
  • Table 60 A is ciclopirox, B is oxafluzone, C is furazone, and the test material is bovine stellate
  • A is ciclopirox
  • B is oxaflutoid
  • C is flufenamid
  • the material is bovine stellate
  • Table 62 A is ciclopirox, B is oxaflutoid, C is flufenamid, and the test material is bovine stellate
  • A is ciclopirox
  • B is azoxystroben
  • C is benpropazone
  • the test material is bovine stellate
  • Table 64 A is ciclopirox, B is azoxystrozone, C is wild wheat, and the test material is bovine stellate
  • Table 65 A is ciclopirox, B is oxaflutoid, C is acetochlor, and the test material is bovine stellate
  • Table 66 A is ciclopirox, B is oxaflutoid, C is butachlor, and the test material is bovine stellate
  • A is ciclopirox
  • B is azoxystroben
  • C is prochlorfen
  • the test material is bovine stellate
  • A is ciclopirox
  • B is azoxystrozone
  • C is mesotrichlor
  • the test material is bovine stellate
  • A is cimifloxazone
  • B is azoxystrozone
  • C is mesotrichlor
  • the test material is bovine stellate
  • Table 70 A is ciclopirox, B is azoxystroben, C is fluoxamid, and the test material is bovine stellate
  • A is cimifloxazone
  • B is azoxystrozone
  • C is sulfamethoxazole
  • the test material is bovine stellate
  • Table 72 A is ciclopirox, B is flufenazone, C is thifensulfuron, and the material is bovine stellate
  • A is ciclopirox
  • B is flumecarbazone
  • C is fluroxaline
  • the test material is bovine stellate
  • Table 74 A is ciclopirox, B is flumezone, C is bupropion, and the test material is bovine stellate
  • Table 75 A is ciclopirox, B is flumeprin, C is pendimethalin, and the material is bovine stellate
  • Table 76 A is ciclopirox, B is flufenazone, C is furazone, and the material is bovine stellate
  • Table 77 A is ciclopirox, B is flumecarbazone, C is flufenamid, and the test material is bovine stellate
  • Table 78 A is ciclopirox, B is flumetox, C is flufenamid, and the test material is boll stellate
  • Table 79 A is ciclopirox, B is flubendicarb, C is acetam, and the test material is boll stellate
  • Table 80 A is ciclopirox, B is flubendicarb, C is wild wheat, and the test material is boll stellaria
  • Table 81 A is ciclopirox, B is flubendicarb, C is acetochlor, and the test material is bovine stellate
  • Table 82 A is ciclopirox, B is flupronil, C is butachlor, and the test material is bovine stellate
  • A is cimiflufenone
  • B is flubendicarb
  • C is propachlor
  • the test material is bovine stellate
  • Table 84 A is cimiflufenone, B is flubendicarb, C is metolachlor, and the material is bovine stellate
  • Table 85 A is ciclopirox, B is flumezone, C is mesotrichlor, and the material is bovine stellate
  • Table 86 A is ciclopirox, B is flumecarbazone, C is fluoxamid, and the test material is bovine stellate
  • A is cimiflubenone
  • B is flumeprin
  • C is sulfamethoxazole
  • the material is bovine stellate
  • Table 88 A is cimifloxazone, B is green melon, C is thifensulfuron, and the material is bovine stellate
  • A is cimifloxazone
  • B is green malon
  • C is flulorin
  • the test material is bovine stellate
  • Table 90 A is ciclopirox, B is green melon, C is bupropion, and the material is bovine stellate
  • Table 91 A is cimifloxazone, B is green malon, C is pendimethalin, and the material is bovine stellate
  • Table 92 A is ciclopirox, B is green melon, C is furazone, and the material is bovine stellate
  • A is ciclopirox
  • B is green melon
  • C is flufenamid
  • the test material is bovine stellate
  • Table 94 A is ciclopirox, B is green melon, C is flufenamid, and the material is bovine stellate
  • A is ciclopirox
  • B is chlormetron
  • C is benzbutazone
  • the test material is bovine stellate
  • Table 96 A is ciclopirox, B is green wheat, C is wild wheat, and the test material is bovine stellate
  • Table 97 A is ciclopirox, B is green melon, C is acetochlor, and the material is bovine stellate
  • Table 98 A is ciclopirox, B is green wheat, C is butachlor, and the material is bovine stellate
  • A is ciclopirox
  • B is green melon
  • C is prochlorfen
  • the test material is bovine stellate
  • Table 100 A is cimifloxazone, B is green wheat, C is metolachlor, and the test material is bovine stellate
  • A is cimifloxazone
  • B is green melon
  • C is mesotrichlor
  • the test material is bovine stellate
  • Table 102 A is ciclopirox, B is green melon, C is fluoxamid, and the test material is bovine stellate
  • Table 103 A is cimifloxazone, B is green melon, C is sulfamethoxazole, and the material is bovine stellate
  • Table 104 A is cimifloxazone, B is isoprolong, C is thifensulfuron, and the material is bovine stellate
  • Table 105 A is ciclopirox, B is isoprolong, C is flulorin, and the material is bovine stellate
  • Table 106 A is ciclopirox, B is isoprolong, C is bupropion, and the material is bovine stellate
  • A is cimifloxazone
  • B is isoprolong
  • C is pendimethalin
  • the material is bovine stellate
  • Table 108 A is ciclopirox, B is isoprolong, C is furazone, and the material is bovine stellate
  • Table 109 A is ciclopirox, B is isoprolong, C is flufenamid, and the test material is bovine stellate
  • Table 110 A is ciclopirox, B is isoprolong, C is flufenamid, and the test material is bovine stellate
  • Table 111 A is ciclopirox, B is isoprolong, C is benzbutazone, and the test material is cattle stellate
  • Table 112 A is cimifloxazone, B is isoprolong, C is wild wheat, and the test material is bovine stellate
  • A is cimifloxazone
  • B is isoprolong
  • C is acetochlor
  • the test material is bovine stellate
  • Table 114 A is cimifloxazone, B is isoproturon, C is butachlor, and the test material is bovine stellate
  • A is cimifloxazone
  • B is isoproturon
  • C is prochlorfen
  • the test material is bovine stellate
  • Table 116 A is cimifloxazone, B is isoproturon, C is metolachlor, and the test material is bovine stellate
  • A is cimifloxazone
  • B is isoproturon
  • C is mesotrichlor
  • the test material is bovine stellate
  • Table 118 A is ciclopirox, B is isoprolong, C is fluoxamid, and the sample is bovine stellate
  • A is cimifloxazone
  • B is isoprolong
  • C is sulfamethoxazole
  • the test material is bovine stellate
  • Table 120 A is ciclopirox, B is pyridate, C is thifensulfuron, and the material is bovine stellate
  • Table 121 A is ciclopirox, B is pyridate, C is flulorin, and the material is cattle stellate
  • Table 122 A is ciclopirox, B is pyridate, C is bupropion, and the test material is bovine stellate
  • Table 123 A is ciclopirox, B is pyridate, C is pendimethalin, and the material is bovine stellate
  • Table 124 A is ciclopirox, B is pyridate, C is furazone, and the material is bovine stellate
  • A is cicoflavone
  • B is pyridapate
  • C is flufenamid
  • the test material is bovine stellate
  • A is ciclopirox
  • B is pyridoxet
  • C is flufenamid
  • the test material is bovine stellate
  • A is ciclopirox
  • B is pyridate
  • C is benzbutazone
  • the test material is bovine stellate
  • Table 128 A is ciclopirox, B is pyridate, C is wild wheat, and the test material is cattle stellate
  • Table 129 A is ciclopirox, B is pyridate, C is acetochlor, and the material is bovine stellate
  • Table 130 A is ciclopirox, B is pyridate, C is butachlor, and the test material is bovine stellate
  • A is cimiflufenone
  • B is pyridapram
  • C is prochlorfen
  • the test material is bovine stellate
  • Table 132 A is ciclopirox, B is pyridate, C is metolachlor, and the material is bovine stellate
  • A is ciclopirox
  • B is pyridate
  • C is mesotrichlor
  • the test material is bovine stellate
  • A is ciclopirox
  • B is pyridapate
  • C is fluoxamid
  • the test material is bovine stellate
  • Table 135 A is cimifloxazone, B is pyridapram, C is sulfafenap, and the test material is bovine stellate
  • Table 136 A is cimifloxazone, B is thifensulfuron, C is flulorin, and the material is bovine stellate
  • A is cimifloxazone
  • B is thifensulfuron
  • C is bupropion
  • the material is bovine stellate
  • Table 138 A is cimifloxazone, B is thifensulfuron, C is pendimethalin, and the material is bovine stellate
  • A is cimifloxazone
  • B is thifensulfuron
  • C is furazone
  • the material is bovine stellate
  • Table 140 A is ciclopirofen, B is thifensulfuron, C is flufenamid, and the material is bovine stellate
  • Table 141 A is ciclopirox, B is thifensulfuron, C is flufenamid, and the test material is bovine stellate
  • Table 142 A is cimiflufenone, B is thifensulfuron, C is benzbutazone, and the material is bovine stellate
  • A is cimifloxazone
  • B is thifensulfuron
  • C is wild wheat
  • the test material is bovine stellate
  • A is cimifloxazone
  • B is thifensulfuron
  • C is acetochlor
  • the material is bovine stellate
  • Table 145 A is cimiflufenone, B is thifensulfuron, C is butachlor, and the material is bovine stellate
  • Table 146 A is cimifloxazone, B is thifensulfuron, C is propachlor, and the material is bovine stellate
  • A is cimiflufenone
  • B is thifensulfuron
  • C is mesotrichlor
  • the material is bovine stellate
  • Table 148 A is cimifloxazone, B is thifensulfuron, C is mesotrichlor, and the test material is bovine stellate
  • Table 149 A is cimiflubenone, B is thifensulfuron, C is fluoxacil, and the material is bovine stellate
  • Table 150 A is cimifloxazone, B is thifensulfuron-methyl, C is sulfamethoxazole, and the material is bovine stellate
  • Table 151 A is ciclopirox, B is fluroxyline, C is furazone, and the material is bovine stellate
  • Table 152 A is ciclopirox, B is fluroxaline, C is flufenamid, and the test material is bovine stellate
  • A is ciclopirox
  • B is fluroxyline
  • C is flufenamid
  • the test material is bovine stellate
  • Table 154 A is ciclopirox, B is fluroxyline, C is benzpropan, and the test material is bovine stellate
  • Table 155 A is ciclopirox, B is fluroxaline, C is wild wheat, and the test material is bovine stellate
  • Table 156 A is ciclopirox, B is flulorin, C is acetochlor, and the test material is bovine stellate
  • Table 157 A is ciclopirox, B is fluroxaline, C is butachlor, and the test material is bovine stellate
  • Table 158 A is ciclopirox, B is fluroxyline, C is propachlor, and the material is bovine stellate
  • A is cimifloxazone
  • B is fluroxaline
  • C is mesotrichlor
  • the test material is bovine stellate
  • Table 160 A is ciclopirox, B is fluroxaline, C is mesotrichlor, and the test material is bovine stellate
  • A is ciclopirox
  • B is fluroxyline
  • C is fluoxamid
  • the test material is bovine stellate
  • A is cimifloxazone
  • B is fluroxaline
  • C is sulfamethoxazole
  • the material is bovine stellate
  • Table 163 A is ciclopirox, B is sec-butalin, C is furazone, and the material is bovine stellate
  • Table 164 A is cicoflavone, B is secbutazone, C is flufenamid, and the test material is bovine stellate
  • A is cicoflavone
  • B is sec-butalin
  • C is flufenamid
  • the test material is bovine stellate
  • Table 166 A is ciclopirofen, B is bupropion, C is benzbutazone, and the material is bovine stellate
  • Table 167 A is ciclopirox, B is bupropion, C is wild wheat, and the test material is bovine stellate
  • Table 168 A is ciclopirox, B is secbutazone, C is acetochlor, and the material is bovine stellate
  • A is ciclopirox
  • B is secbutazone
  • C is butachlor
  • the material is bovine stellate
  • Table 170 A is ciclopirox, B is secbutazone, C is propachlor, and the material is bovine stellate
  • A is cimifloxazone
  • B is sec-butalin
  • C is metolachlor
  • the material is bovine stellate
  • A is cimifloxazone
  • B is secbutazone
  • C is mesometamine
  • the test material is bovine stellate
  • A is ciclopirox
  • B is secbutazone
  • C is fluoxamid
  • the test material is bovine stellate
  • A is cimifloxazone
  • B is sec-butalin
  • C is sulfamethoxazole
  • the material is bovine stellate
  • Table 175 A is ciclopirox, B is pendimethalin, C is furazone, and the material is bovine stellate
  • Table 176 A is ciclopirox, B is pendimethalin, C is flufenamid, and the test material is bovine stellate
  • Table 177 A is ciclopirox, B is pendimethalin, C is flufenamid, and the material is bovine stellate
  • Table 178 A is cimifloxazone, B is pendimethalin, C is benpropazone, and the material is bovine stellate
  • Table 179 A is cimifloxazone, B is pendimethalin, C is wild wheat, and the test material is cattle stellate
  • Table 180 A is ciclopirox, B is pendimethalin, C is acetochlor, and the material is bovine stellate
  • Table 181 A is ciclopirox, B is pendimethalin, C is butachlor, and the material is bovine stellate
  • A is cimifloxazone
  • B is pendimethalin
  • C is pretilachlor
  • the test material is bovine stellate
  • A is cimifloxazone
  • B is pendimethalin
  • C is metolachlor
  • the material is bovine stellate
  • A is cimifloxazone
  • B is pendimethalin
  • C is mesotrichlor
  • the material is bovine stellate
  • A is cimifloxazone
  • B is pendimethalin
  • C is fluoxamid
  • the material is bovine stellate
  • A is cimifloxazone
  • B is pendimethalin
  • C is sulfamethoxazole
  • the test material is bovine stellate
  • Table 187 A is ciclopirox, B is furazone, C is benpropazone, and the material is bovine stellate
  • Table 188 A is ciclopirox, B is furazone, C is bivalve, and the material is bovine stellate
  • A is ciclopirox
  • B is furazone
  • C is acetochlor
  • the material is bovine stellate
  • Table 190 A is ciclopirox, B is furazone, C is butachlor, and the test material is bovine stellate
  • A is ciclopirox
  • B is furazone
  • C is propachlor
  • the material is bovine stellate
  • Table 192 A is ciclopirox, B is furazone, C is mesotrichlor, and the material is bovine stellate
  • A is ciclopirox
  • B is furazone
  • C is mesotrichlor
  • the material is bovine stellate
  • A is ciclopirox
  • B is furacid
  • C is fluoxamid
  • the test material is bovine stellate
  • A is cimifloxazone
  • B is furazone
  • C is sulfamethoxazole
  • the material is bovine stellate
  • Table 196 A is ciclopirofen, B is flufenamid, C is fenfluracetam, and the material is bovine stellate
  • A is cycloflufenone
  • B is flufenamid
  • C is bivalve
  • the material is bovine stellate
  • A is ciclopirofen
  • B is flufenamid
  • C is acetochlor
  • the test material is bovine stellate
  • A is ciclopirofen
  • B is flufenamid
  • C is butachlor
  • the test material is bovine stellate
  • Table 200 A is ciclopirofen, B is flufenamid, C is prochlorfen, and the test material is bovine stellate
  • Table 201 A is ciclopirofen, B is flufenamid, C is metolachlor, and the test material is bovine stellate
  • Table 202 A is ciclopirofen, B is flufenamid, C is mesotrichlor, and the test material is bovine stellate
  • A is cimiflufenone
  • B is flufenamid
  • C is fluoxamid
  • the test material is bovine stellate
  • A is cimiflufenone
  • B is flufenamid
  • C is sulfamethoxazole
  • the test material is bovine stellate
  • Table 205 A is ciclopirox, B is flufenamid, C is fenfluramine, and the test material is bovine stellate
  • Table 206 A is cycloflufenone, B is flufenamid, C is wild wheat, and the test material is boll stellaria
  • A is cycloflufenone
  • B is flufenamid
  • C is acetochlor
  • the test material is bovine stellate
  • Table 208 A is ciclopirox, B is flufenamid, C is butachlor, and the test material is bovine stellate
  • A is ciclopirox
  • B is flufenamid
  • C is propachlor
  • the test material is bovine stellate
  • A is cycloflufenone
  • B is flufenamid
  • C is mesotrichlor
  • the test material is bovine stellate
  • A is cycloflufenone
  • B is flufenamid
  • C is mesotrichlor
  • the test material is boll stellate
  • Table 212 A is ciclopirox, B is flufenamid, C is fluoxamid, and the test material is bovine stellate
  • A is cimiflufenone
  • B is flufenamid
  • C is sulfamethoxazole
  • the test material is bovine stellate
  • A is ciclopirox
  • B is benzbutazone
  • C is acetochlor
  • the material is bovine stellate
  • A is ciclopirox
  • B is benzbutazone
  • C is butachlor
  • the material is bovine
  • Table 216 A is cimiflufenone, B is benpropazone, C is pretilachlor, and the material is bovine stellate
  • A is ciclopirox
  • B is benzbutazone
  • C is metolachlor
  • the material is bovine stellate

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  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

一种含有环吡氟草酮的三元除草组合物及其应用。所述三元除草组合物包括除草有效量的活性成分A、活性成分B和活性成分C,其中,活性成分A为环吡氟草酮;活性成分B和C分别选自以下类型中的任一种化合物和与其不同类型的另一种化合物:PPO类抑制剂、PSⅡ类抑制剂、ALS类抑制剂、微管组装抑制剂、PDS类抑制剂、脂类合成(非乙酰辅酶A羧化酶)抑制剂、VLCFA类抑制剂。该组合物能有效防除作物田中的牛繁缕、繁缕、蚤缀、苘麻、鸭舌草、碎米荠、荠菜、播娘蒿等杂草。

Description

一种含有环吡氟草酮的三元除草组合物及其应用 技术领域
本发明属于农药领域,具体涉及一种含有环吡氟草酮的三元除草组合物及其应用。
背景技术
化学除草是农田杂草防除中最为经济、有效的手段,但长期连续高剂量地使用单一品种或单一作用方式的化学除草剂,容易造成杂草耐药和抗性演化等问题。
除草剂化合物的合理复配或混配具有扩大杂草谱、提高防除效果、延缓杂草耐药性和抗药性的发生与发展等优点,是解决上述问题的最为有效的方法之一。因此生产上亟需开发安全性高、杀草谱广、能够产生增效作用并解决抗性杂草问题的除草组合物品种。
发明内容
为解决现有技术中存在的上述问题,本发明提供一种含有环吡氟草酮的三元除草组合物及其应用。该组合物能有效防除作物田中的牛繁缕、大穂看麦娘、猪殃殃、婆婆纳、荠菜等杂草问题,具有扩大杀草谱、减少施用量、对作物安全、能够产生增效作用并解决抗性杂草等特点。
一种三元除草组合物,包括除草有效量的活性成分A、活性成分B和活性成分C,其中,
活性成分A为环吡氟草酮(CAS:1855929-45-1);
活性成分B和C分别选自以下类型中的任一种化合物和与其不同类型的另一种化合物:
PPO类抑制剂:噁草酮(CAS:19666-30-9);
PSⅡ类抑制剂:扑草净(CAS:7287-19-6)、特丁净(CAS:886-50-0)、嗪草酮(CAS:21087-64-9)、氨唑草酮(CAS:129909-90-6)、绿麦隆(CAS:15545-48-9)、异丙隆(CAS:34123-59-6)、哒草特(CAS:55512-33-9);
ALS类抑制剂:噻吩磺隆(CAS:79277-27-3);
微管组装抑制剂:氟乐灵(CAS:1582-09-8)、仲丁灵(CAS:33629-47-9)、二甲戊灵(CAS:40487-42-1);
PDS类抑制剂:呋草酮(CAS:96525-23-4)、吡氟酰草胺(CAS:83164-33-4)、氟吡酰草胺(CAS:137641-05-5);
脂类合成(非乙酰辅酶A羧化酶)抑制剂:苄草丹(CAS:52888-80-9)、野麦畏(CAS:2303-17-5);
VLCFA类抑制剂:乙草胺(CAS:34256-82-1)、丁草胺(CAS:23184-66-9)、丙草胺(CAS:51218-49-6)、异丙甲草胺(CAS:51218-45-2)、精异丙甲草胺(CAS:87392-12-9 (S-体)、CAS:178961-20-1(R-体))、氟噻草胺(CAS:142459-58-3)、砜吡草唑(CAS:447399-55-5);
A、B和C的重量比为1~200:1~1000:1~1000和1~150:5~800:5~800;优选为3~100:10~500:10~500和5~80:20~300:20~300;更优选为8~60:50~200:50~200和10~50:60~100:60~100。
所述除草组合物中A、B和C的质量百分含量占总量的1-95%,优选10-80%。
所述除草组合物中还包含常规助剂,所述常规助剂包括载体、表面活性剂。
本文中的术语“载体”表示一种有机或无机、天然或合成的物质。它们有助于活性成分的施用,该载体一般是惰性的且必须是农业上可接受的,特别是被处理的植物所接受。载体可以是固体的,如陶土、天然或合成的硅酸盐、二氧化硅、树脂、蜡、固体肥料等;或者液体的,如水、醇类、酮类、石油馏分、芳烃或蜡烃、氯代烃、液化气等。
表面活性剂可包括乳化剂、分散剂或润湿剂,它可以是离子型或非离子型的。可提及的实例是聚丙烯酸的盐、木质素磺酸盐、苯酚磺酸或萘磺酸的盐、环氧乙烷与脂肪族醇或与脂族酸或与脂肪族胺与取代苯酚(特别是烷基苯酚或芳基苯酚)的聚合物、磺基琥珀酸盐、牛磺酸衍生物(特别是牛磺酸烷脂)及醇的磷酸酯或多羟乙基化的苯酚的磷酸酯、烷基磺酸盐、烷基芳基磺酸盐、烷基硫酸盐、月桂基醚硫酸盐、脂肪醇硫酸盐,以及硫酸化十六-、十七-和十八烷醇以及硫酸化脂肪醇乙二醇醚,此外还有萘或萘磺酸与苯酚和甲醛的缩合物、聚氧乙烯辛基苯基醚、乙氧基化异辛基酚、辛基酚或壬基酚、烷基苯基聚乙二醇醚、三丁基苯基聚乙二醇醚、三硬脂基苯基聚乙二醇醚、烷基芳基聚醚醇、醇和脂肪醇/氧化乙烯缩合物、乙氧基化蓖麻油、聚氧乙烯烷基醚、乙氧基化聚氧丙烯、月桂醇聚乙二醇醚缩醛、山梨醇酯、木素亚硫酸盐废液,以及蛋白质、变性蛋白、多糖(例如甲基纤维素)、疏水改性淀粉、聚乙烯醇、聚羧酸盐、聚烷氧基化物、聚乙烯胺、聚乙烯吡咯烷酮及其共聚物。至少需要一种表面活性剂存在,以有利于活性成分在水中的分散并有利于使它们能正确地施用于植物。
上述组合物也可含有各种其他的组分,如保护胶体、粘合剂、增稠剂、触变剂、渗透剂、稳定剂、螯合剂、染料、着色剂和聚合物。
另外,本发明的三元组合物可以与以下活性物质混合,例如《世界农药新品种技术大全》,中国农业科学技术出版社,2010.9和这里引用的文献中的已知物质。例如以下提到的除草剂活性物质,(备注:化合物的名称,或者为根据国际标准化组织(ISO)的普通名称,或者为化学名称,适当的时候有代号):乙草胺、丁草胺、甲草胺、异丙草胺、异丙甲草胺、精异丙甲草胺、丙草胺、毒草胺、克草胺、萘丙酰草胺、R-左旋萘丙酰草胺、敌稗、苯噻酰草胺、双苯酰草胺、吡氟酰草胺、杀草胺、氟丁酰草胺、溴丁酰草胺、二甲噻草胺、高效二甲噻草胺、乙氧苯草胺、氟噻草胺、甲氧噻草胺、吡草胺、异恶草胺、高效麦草伏甲酯、高效麦草 伏丙酯、二丙烯草胺、烯草胺、丁酰草胺、环丙草胺、氟磺酰草胺、庚酰草胺、异丁草胺、丙炔草胺、特丁草胺、二甲苯草胺、二甲草胺、落草胺、三甲环草胺、氯甲酰草胺、炔苯酰草胺、戊酰苯草胺、卡草胺、新燕灵、三环赛草胺、丁烯草胺、牧草胺、苄草胺、醌萍胺、苯氟磺胺、萘丙胺、乙酰甲草胺、萘草胺、噻草胺、吡氰草胺、苯草多克死、草克乐、氯酞亚胺、丁脒胺、氟吡草胺、莠去津、西玛津、扑草净、氰草净、西草净、莠灭净、扑灭津、异丙净、氟草净、特丁净、特丁津、三嗪氟草胺、环丙津、甘扑津、草达津、扑灭通、西玛通、叠氮净、敌草净、异戊乙净、环丙青津、灭莠津、另丁津、仲丁通、特丁通、甲氧丙净、氰草净、抑草津、可乐津、莠去通、灭草通、甘草津、三聚氰酸、Indaziflam、绿磺隆、甲磺隆、苄嘧磺隆、氯嘧黄隆、苯磺隆、噻磺隆、吡嘧黄隆、甲基二磺隆、甲基碘磺隆钠盐、甲酰氨基嘧磺隆、醚磺隆、醚苯磺隆、甲嘧磺隆、烟嘧磺隆、胺苯磺隆、酰嘧磺隆、乙氧嘧磺隆、环丙嘧磺隆、砜嘧磺隆、四唑嘧磺隆、啶嘧黄隆、单嘧磺隆、单嘧磺酯、氟唑磺隆、氟啶嘧磺隆、氟吡嘧磺隆、环氧嘧磺隆、唑吡嘧磺隆、氟嘧磺隆、丙苯磺隆、三氟丙磺隆、磺酰磺隆、三氟啶磺隆、氟胺磺隆、三氟甲磺隆、甲磺隆钠盐、氟吡磺隆、甲硫嘧磺隆、嘧苯胺磺隆、Propyrisulfuron(丙嗪嘧磺隆)、嗪吡嘧磺隆、三氟羧草醚、氟磺胺草醚、乳氟禾草灵、乙羧氟草醚、乙氧氟草醚、草枯醚、苯草醚、氯氟草醚乙酯、甲羧除草醚、三氟甲草醚、甲氧除草醚、三氟硝草醚、氟化除草醚、氟呋草醚、除草醚、甲草醚、二甲草醚、氟酯肟草醚、氟草醚酯、Halosafen、绿麦隆、异丙隆、利谷隆、敌草隆、莎扑隆、氟草隆、苯噻隆、甲基苯噻隆、苄草隆、磺噻隆、异恶隆、特丁噻草隆、炔草隆、氯溴隆、甲基杀草隆、酰草隆、甲氧杀草隆、溴谷隆、甲氧隆、绿谷隆、灭草隆、环草隆、非草隆、氟硫隆、草不隆、枯草隆、草完隆、异草完隆、环莠隆、噻氟隆、丁噻隆、枯莠隆、对氟隆、甲胺噻唑隆、隆草特、三甲异脲、恶唑隆、Monisouron、Anisuron、Methiuron、Chloreturon、四氟隆、甜菜宁、甜菜宁-乙酯、甜菜安、磺草灵、特草灵、燕麦灵、苯胺灵、氯苯胺灵、二氯苄草酯、灭草灵、氯炔灵、Carboxazole、Chlorprocarb、Fenasulam、BCPC、CPPC、Carbasulam、丁草特、禾草丹、灭草猛、禾草特、野麦畏、哌草丹、禾草畏、稗草丹、环草敌、燕麦敌、菌达灭、乙硫草特、坪草丹、克草猛、苄草丹、仲草丹、硫烯草丹、草灭散、Isopolinate、Methiobencarb、2,4-D异辛酯丁酯、2甲4氯钠、2,4-D异辛酯异辛酯、2甲4氯异辛酯、2,4-D异辛酯钠盐、2,4-D异辛酯二甲胺盐、2甲4氯乙硫酯、2甲4氯、2,4-D异辛酯丙酸、高2,4-D异辛酯丙酸盐、2,4-D异辛酯丁酸、2甲4氯丙酸、2甲4氯丙酸盐、2甲4氯丁酸、2,4,5-涕、2,4,5-涕丙酸、2,4,5-涕丁酸、2甲4氯胺盐、麦草畏、抑草蓬、伐草克、赛松、三氯苯酸、氨二氯苯酸、甲氧三氯苯酸、禾草灵、吡氟禾草灵、精吡氟禾草灵、氟吡甲禾灵、高效吡氟氯禾灵、喹禾灵、精喹禾灵、恶唑禾草灵、精恶唑禾草灵、喔草酯、氰氟草酯、恶唑酰草胺、炔草酯、噻 唑禾草灵、炔禾灵、羟戊禾灵、三氟禾草肟、异恶草醚、百草枯、敌草快、安磺灵、乙丁烯氟灵、异丙乐灵、甲磺乐灵、环丙氟灵、氨基丙氟灵、乙丁氟灵、氯乙氟灵、氨基乙氟灵、地乐灵、氯乙地乐灵、Methalpropalin、丙硝酚、草甘膦、莎稗膦、草铵膦、甲基胺草磷、草硫膦、哌草膦、双丙氨膦、地散磷、抑草磷、蔓草磷、伐垅磷、双甲胺草磷、草特磷、咪唑烟酸、咪唑乙烟酸、咪唑喹啉酸、甲氧咪草烟、甲氧咪草烟铵盐、甲咪唑烟酸、咪草酯、氯氟吡氧乙酸、氯氟吡氧乙酸异辛酯、二氯吡啶酸、氨氯吡啶酸、三氯吡氧乙酸、氟硫草定、卤草定、三氯吡啶酚、噻草啶、氟啶草酮、氯氨吡啶酸、氟吡草腙、三氯吡氧乙酸丁氧基乙酯、Cliodinate、稀禾啶、烯草酮、噻草酮、禾草灭、环苯草酮、丁苯草酮、肟草酮、吡喃草酮、Buthidazole、嗪草酮、环嗪酮、苯嗪草酮、乙嗪草酮、Ametridione、Amibuzin、溴苯腈、辛酰溴苯腈、辛酰碘苯腈、碘苯腈、敌草腈、二苯乙腈、双唑草腈、羟敌草腈、Iodobonil、唑嘧磺草胺、双氟磺草胺、五氟磺草胺、磺草唑胺、氯酯磺草胺、双氯磺草胺、啶磺草胺、氟草黄、双草醚、嘧啶肟草醚、环酯草醚、嘧草醚、嘧硫草醚、双环磺草酮、硝磺草酮、磺草酮、Tembotrione、Tefuryltrione、Bicyclopyrone、Ketodpiradox、异恶唑草酮、异恶氯草酮、Fenoxasulfone、Methiozolin、异丙吡草酯、吡草醚、吡唑特、野燕枯、苄草唑、吡草酮、吡氯草胺、Pyrasulfotole、苯唑草酮、Pyroxasulfone、唑草胺、氟胺草唑、杀草强、氨唑草酮、唑啶草酮、氟唑草酮、甲磺草胺、Bencarbazone、双苯嘧草酮、氟丙嘧草酯、除草定、异草定、环草啶、特草定、Flupropacil、吲哚酮草酯、氟烯草酸、丙炔氟草胺、炔草胺、酞苄醚、Flumezin、五氯酚(钠)、地乐酚、特乐酚、特乐酯、戊硝酚、二硝酚、氯硝酚、地乐施、地乐特、丙炔恶草酮、恶草酮、环戊恶草酮、氟唑草胺、嗪草酸甲酯、四唑酰草胺、氟哒嗪草酯、杀草敏、溴莠敏、二甲达草伏、哒草醚、草哒酮、草哒松、哒草伏、Pyridafol、二氯喹啉酸、氯甲喹啉酸、苯达松、哒草特、恶嗪草酮、草除灵、异恶草酮、环庚草醚、异丙酯草醚、丙酯草醚、茚草酮、氯酸钠、茅草枯、三氯醋酸、一氯醋酸、六氯丙酮、四氟丙酸、牧草快、溴酚肟、***磺、灭杀唑、呋草酮、呋草磺、乙呋草磺、嘧草胺、氯酞酸、氟咯草酮、稗草稀、丙烯醛、苯草灭、灭草环、燕麦酯、噻二唑草胺、棉胺宁、羟草酮、甲氧苯酮、苯嘧磺草胺、氯酰草膦、三氯丙酸、Alorac、Diethamquat、Etnipromid、Iprymidam、Ipfencarbazone、Thiencarbazone-methyl、Pyrimisulfan、Chlorflurazole、Tripropindan、Sulglycapin、甲硫磺乐灵、Cambendichlor、环丙嘧啶酸、硫氰苯胺、解草酮、解草啶、解草安、解草唑、解草喹、解草腈、解草烷、解草胺腈、解草烯、吡唑解草酯、呋喃解草唑、肟草安、双苯噁唑酸、二氯丙烯胺、氟氯吡啶酯、DOW氯氟吡啶酯、UBH-509、D489,LS 82-556、KPP-300、NC-324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、KIH-6127和KIH-2023。
所述除草组合物进一步包括至少一种安全剂,其选自:
a)二氯苯基吡唑啉-3-羧酸(S1)类化合物,优选的化合物为例如1-(2,4-二氯苯基)-5-(乙氧基羰基)-5-甲基-2-吡唑啉-3-羧酸乙酯(S1-1,吡唑解草酯(mefenpyr-diethyl),PM,第594-595页),以及记载于例如WO91/07874和PM(第594-595页)中的相关化合物。
b)二氯苯基吡唑羧酸衍生物,优选的化合物为例如1-(2,4-二氯苯基)-5-甲基吡唑-3-羧酸乙酯(S1-2)、1-(2,4-二氯苯基)-5-异丙基吡唑-3-羧酸乙酯(S1-3)、1-(2,4-二氯苯基)-5-(1,1-二甲基-乙基)吡唑-3-羧酸乙酯(S1-4)、1-(2,4-二氯苯基)-5-苯基吡唑-3-羧酸乙酯(S1-5),以及记载于EP-A-333131和EP-A-269806中的相关化合物。
c)***羧酸(S1)类化合物,优选的化合物为例如解草唑(fenchlorazole),即1-(2,4-二氯苯基)-5-三氯甲基-(1H)-1,2,4-***-3-羧酸乙酯(S1-6)及相关化合物(参见EP-A-174562和EP-A-346620)。
d)5-苄基-或5-苯基-2-异噁唑啉-3-羧酸类或5,5-二苯基-2-异噁唑啉-3-羧酸类化合物,优选的化合物为例如5-(2,4-二氯苄基)-2-异噁唑啉-3-羧酸乙酯(S1-7)或5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-8)及记载于WO91/08202中的相关化合物,或记载于专利申请(WO-A-95/07897)中的5,5-二苯基-2-异噁唑啉-3-羧酸乙酯(S1-9,双苯噁唑酸(isoxadifen-ethyl))或5,5-二苯基-2-异噁唑啉-3-羧酸正丙酯(S1-10)或5-(4-氟苯基)-5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-11)。
e)8-喹啉氧基乙酸(S2)类化合物,优选1-甲基己-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-1,解毒喹(cloquintocet-mexyl),如PM(第195-196页),(1,3-二甲基丁-1-基)(5-氯-8-喹啉氧基)乙酸酯(S2-2),4-烯丙基氧基丁基(5-氯-8-喹啉氧基)乙酸酯(S2-3),1-烯丙基氧基丙-2-基(5-氯-8-喹啉氧基)乙酸酯(S2-4),(5-氯-8-喹啉氧基)乙酸乙酯(S2-5),(5-氯-8-喹啉氧基)乙酸甲酯(S2-6),(5-氯-8-喹啉氧基)乙酸烯丙酯(S2-7),2-(2-亚丙基亚氨基氧基)-1-乙基(5-氯-8-喹啉氧基)乙酸酯(S2-8),2-氧代丙-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-9),以及记载于EP-A-86750、EP-A-94349和EP-A-191736或EP-A-0492366中的相关化合物。
f)(5-氯-8-喹啉氧基)丙二酸类化合物,优选的化合物为例如(5-氯-8-喹啉氧基)丙二酸二乙酯、(5-氯-8-喹啉氧基)丙二酸二烯丙酯、(5-氯-8-喹啉氧基)-丙二酸甲基乙酯和记载于EP-A-0582198中的相关化合物。
g)苯氧基乙酸、苯氧基丙酸或芳族羧酸类活性化合物,例如2,4-二氯苯氧基乙酸(和酯)(2,4-D)、4-氯-2-甲基苯氧基丙酸酯(2-甲-4-氯丙酸(mecoprop))、MCPA或3,6-二氯-2-甲氧基苯甲酸(和酯)(麦草畏(dicamba))。
h)嘧啶类活性化合物,例如“解草啶(fenclorim)”(PM,第386-387页)(=4,6-二氯-2-苯基嘧啶),
i)二氯乙酰胺类活性化合物,其常用作苗前安全剂(作用于土壤的安全剂),例如“二氯丙烯胺(dichloromid)”(PM,第270-271页)(=N,N-二烯丙基-2,2-二氯乙酰胺),“AR-29148”(=3-二氯乙酰基-2,2,5-三甲基-1,3-噁唑烷酮,购自Stauffer),“解草嗪(benoxacor)”(PM,第74-75页)(=4-二氯乙酰基-3,4-二氢-3-甲基-2H-1,4-苯并噁嗪),“APPG-1292”(=N-烯丙基-N[(1,3-二氧戊环-2-基)-甲基]二氯乙酰胺,购自PPG Industries),“ADK-24”(=N-烯丙基-N-[(烯丙基氨基羰基)-甲基]-二氯乙酰胺,购自Sagro-Chem),“AAD-67”或“AMON4660”(=3-二氯乙酰基-1-氧杂-3-氮杂-螺[4,5]癸烷,购自Nitrokemia或Monsanto),“diclonon”或“ABAS145138”或“ALAB145138”(=(=3-二氯乙酰基-2,5,5-三甲基-1,3-二氮杂双环[4.3.0]壬烷,购自BASF),和“furilazol”或“AMON13900”(参见PM,482-483)(=(RS)-3-二氯乙酰基-5-(2-呋喃基)-2,2-二甲基噁唑烷酮),
j)二氯丙酮衍生物类活性化合物,例如,“AMG191”(CAS登记号96420-72-3)(=2-二氯甲基-2-甲基-1,3-二氧戊环,购自Nitrokemia),
k)氧基亚氨基化合物类活性化合物,其被称为拌种材料,例如,“解草腈(oxabetrinil)”(PM,第689页)(=(Z)-1,3-二氧戊环-2-基甲氧基亚氨基(苯基)乙腈),其在拌种中称为安全剂,以防止异丙甲草胺(metolachlor)的损害,“氟草肟(fluxofenim)”(PM,第467-468页)(=1-(4-氯苯基)-2,2,2-三氟-1-乙酮O-(1,3-二氧戊环-2-基甲基)-肟,其在拌种中称为安全剂,以防止异丙甲草胺(metolachlor)的损害,和“解草胺腈(cyometrinil)”或“A-CGA-43089”(PM,第983页)(=(Z)-氰基甲氧基亚氨基(苯基)乙腈),其在拌种中称为安全剂,以防止异丙甲草胺(metolachlor)的损害,
l)噻唑羧酸酯类活性化合物,其被称为拌种材料,例如“解草安(flurazol)”(PM,第450-451页)(=2-氯-4-三氟甲基-1,3-噻唑-5-羧酸苄酯),其在拌种中被称为安全剂,以防止甲草胺(alachlor)和异丙甲草胺的损害,
m)萘二羧酸衍生物类活性化合物,其被称为拌种剂,例如“萘二甲酸酐”(PM,第1009-1010页)(=1,8-萘二甲酸酐),其在玉米拌种中称为安全剂,以防止硫代氨基甲酸酯除草剂的损害,
n)色满乙酸(chromaneaceticacid)衍生物类活性化合物,例如,“ACL304415”(CAS登记号31541-57-8)(=2-84-羧基色满-4-基)乙酸,购自AmericanCyanamid),
o)除了对有害植物具有除草作用外还对作物植物具有安全剂作用的活性化合物,例如,“哌草丹(dimepiperate)”或“AMY-93”(PM,第302-303页)(=S-1-甲基-1-苯基乙基哌啶-1-硫代羧酸酯),“杀草隆(daimuron)”或“ASK23”(PM,第247页)(=1-(1-甲基-1-苯基乙基)-3-对甲苯基脲),“苄草隆(cumyluron)”=“AJC-940”(=3-(2-氯苯基甲基)-1-(1-甲基-1-苯基-乙基)脲,参见JP-A-60087254),“苯甲酮(methoxyphenon)”或“ANK049”(=3,3'-二甲基-4-甲氧基-二苯甲酮), “CSB”(=1-溴-4-(氯甲基磺酰基)苯)(CAS登记号54091-06-4,购自Kumiai)。
所述安全剂优选双苯噁唑酸(CAS:163520-33-0)、cyprosulfamide(CAS:221667-31-8)、吡唑解草酯(CAS:135590-91-9)、解毒喹(CAS:99607-70-2)、赤霉酸(CAS:7-06-5)、furilazole(CAS:121776-33-8)、metcamifen(CAS:129531-12-0)中的一种或多种。
本发明的组合物可以由使用者在使用前经稀释或直接使用。其配制可由通常的加工方法制备,即将活性物质与液体溶剂或固体载体混合后,再加入表面活性剂如分散剂、稳定剂、湿润剂、粘合剂、消泡剂等中的一种或几种。
所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂(干悬浮剂)、水乳剂、微乳剂。
简而言之,本发明的组合物可以和现有技术的配方中常规使用的固体和液体添加剂混合。
本发明还提供一种所述三元除草组合物在防治作物中有害杂草上的应用;以及提供一种防治不想要的植物生长的方法,其包括将所述三元除草组合物施用于植物、植物部位、植物种子或植物生长的区域,优选用于选择性防治作物中的有害植物。
另外,本发明的组合物可通过喷雾的方法被施用于待处理植物叶片上,即施用于杂草,特别是对作物生长有害的杂草侵扰或易侵扰影响的表面上。
当施用本发明的除草组合物时,获得了预料不到的增效效果,并且除草活性比使用单个除草剂的活性预期总和,以及单个或其中任两个除草剂组合的活性更为显著。增效效果表现为施用量减少、更宽的杂草控制谱、除草作用更快、更持久,这些特性是杂草控制实践过程中所需要的。就所描述的特性来说,这些新组合物明显地优越于现有的除草剂,达到减量使用,对环境更友好。
本发明的三元增效除草组合物还具有下述优点:
(1)本发明的组合物为环境友好型,在环境中均易于降解,适用于多种作物田。
(2)本发明的除草组合物成本低、使用方便,其推广应用有巨大的经济效益和社会效益。
具体实施方式
下列实施例并非限制本发明,而只是用来说明本发明是如何实现的。对于某些杂草,这些实施例显示出特别显著的有效性。举例如下:
A)实施例
1、环吡氟草酮+噁草酮+扑草净(6+10+20)水悬浮剂
6%环吡氟草酮+10%噁草酮+20%扑草净+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12%黄原胶+1.2%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
2、环吡氟草酮+噁草酮+特丁净(6+10+50)可湿性粉剂
6%环吡氟草酮+10%噁草酮+50%特丁净+8%萘磺酸盐分散剂+3%十二烷基硫酸钠+5%沉淀法白炭黑+高岭土补足
3、环吡氟草酮+噁草酮+嗪草酮(6+10+6)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+6%嗪草酮+5%十二烷基苯磺酸钙+4%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1%有机膨润土+1%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
4、环吡氟草酮+噁草酮+氨唑草酮(6+10+12)水悬浮剂
6%环吡氟草酮+10%噁草酮+12%氨唑草酮+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14%黄原胶+1.3%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
5、环吡氟草酮+噁草酮+绿麦隆(6+10+50)水分散粒剂
6%环吡氟草酮+10%噁草酮+50%绿麦隆+10%萘磺酸盐分散剂+2%聚羧酸盐分散剂+4%十二烷基硫酸钠+5%沉淀法白炭黑+1%聚乙烯醇+高岭土补足
6、环吡氟草酮+噁草酮+异丙隆(6+10+50)水分散粒剂
6%环吡氟草酮+10%噁草酮+50%异丙隆+10%萘磺酸盐分散剂+2%聚羧酸盐分散剂+4%十二烷基硫酸钠+5%沉淀法白炭黑+1%聚乙烯醇+高岭土补足
7、环吡氟草酮+噁草酮+哒草特(3+5+25)悬乳剂
3%环吡氟草酮+5%噁草酮+25%哒草特+10%100#溶剂油+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+4%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.11%黄原胶+1.2%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
8、环吡氟草酮+噁草酮+噻吩磺隆(6+10+1)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+1%噻吩磺隆+5%十二烷基苯磺酸钙+6%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.6%有机膨润土+1.5%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
9、环吡氟草酮+噁草酮+氟乐灵(6+10+15)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+15%氟乐灵+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.6%有机膨润土+1.5%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
10、环吡氟草酮+噁草酮+仲丁灵(6+10+20)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+20%仲丁灵+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.6%有机膨润土+1.5%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
11、环吡氟草酮+噁草酮+二甲戊灵(3+5+25)可分散油悬浮剂
3%环吡氟草酮+5%噁草酮+25%二甲戊灵+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.5%有机膨润土+2.5%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
12、环吡氟草酮+噁草酮+呋草酮(6+10+8)水悬浮剂
6%环吡氟草酮+10%噁草酮+8%呋草酮+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
13、环吡氟草酮+噁草酮+吡氟酰草胺(6+10+8)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+8%吡氟酰草胺+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+1.0%气相法白炭黑+8%100#溶剂油+油酸甲酯补足
14、环吡氟草酮+噁草酮+氟吡酰草胺(6+10+3)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+3%氟吡酰草胺+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+1.5%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
15、环吡氟草酮+噁草酮+苄草丹(3+5+40)悬乳剂
3%环吡氟草酮+5%噁草酮+40%苄草丹+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.1%黄原胶+1.0%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
16、环吡氟草酮+噁草酮+野麦畏(3+5+40)悬乳剂
3%环吡氟草酮+5%噁草酮+40%野麦畏+8%100#溶剂油+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.1%黄原胶+1.0%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
17、环吡氟草酮+噁草酮+乙草胺(6+10+18)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+18%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.6%有机膨润土+1.5%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
18、环吡氟草酮+噁草酮+丁草胺(6+10+50)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+50%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+5%100#溶剂油+油酸甲酯补足
19、环吡氟草酮+噁草酮+丙草胺(6+10+30)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+30%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.5%有机膨润土+1.5%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
20、环吡氟草酮+噁草酮+异丙甲草胺(6+10+40)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+40%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.5%有机膨润土+1.5%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
21、环吡氟草酮+噁草酮+精异丙甲草胺(6+10+30)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+30%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.5%有机膨润土+1.5%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
22、环吡氟草酮+噁草酮+氟噻草胺(6+10+12)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+12%氟噻草胺+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
23、环吡氟草酮+噁草酮+砜吡草唑(6+10+6)可分散油悬浮剂
6%环吡氟草酮+10%噁草酮+6%砜吡草唑+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.5%有机膨润土+1.5%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
24、环吡氟草酮+扑草净+噻吩磺隆(6+20+1)可分散油悬浮剂
6%环吡氟草酮+20%扑草净+1%噻吩磺隆+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+8%100#溶剂油+油酸甲酯补足
25、环吡氟草酮+扑草净+氟乐灵(6+20+15)可分散油悬浮剂
6%环吡氟草酮+20%扑草净+15%氟乐灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+1.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
26、环吡氟草酮+扑草净+仲丁灵(6+20+20)可分散油悬浮剂
6%环吡氟草酮+20%扑草净+20%仲丁灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+1.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
27、环吡氟草酮+扑草净+二甲戊灵(2+6.6+20)可分散油悬浮剂
2%环吡氟草酮+6.6%扑草净+20%二甲戊灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+1.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
28、环吡氟草酮+扑草净+呋草酮(6+20+8)水悬浮剂
6%环吡氟草酮+20%扑草净+8%呋草酮+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
29、环吡氟草酮+扑草净+吡氟酰草胺(6+20+8)水悬浮剂
6%环吡氟草酮+20%扑草净+8%吡氟酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
30、环吡氟草酮+扑草净+氟吡酰草胺(6+20+3)水悬浮剂
6%环吡氟草酮+20%扑草净+3%氟吡酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
31、环吡氟草酮+扑草净+苄草丹(3+10+40)悬乳剂
3%环吡氟草酮+10%扑草净+40%苄草丹+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.1%黄原胶+1.0%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
32、环吡氟草酮+扑草净+野麦畏(3+10+40)悬乳剂
3%环吡氟草酮+10%扑草净+40%野麦畏+8%100#溶剂油+3%苯乙基苯酚聚氧乙烯醚磷酸酯三 乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.1%黄原胶+1.0%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
33、环吡氟草酮+扑草净+乙草胺(6+20+18)可分散油悬浮剂
6%环吡氟草酮+20%扑草净+18%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.6%有机膨润土+1.5%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
34、环吡氟草酮+扑草净+丁草胺(3+10+25)可分散油悬浮剂
3%环吡氟草酮+10%扑草净+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.8%有机膨润土+1.5%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
35、环吡氟草酮+扑草净+丙草胺(6+20+30)可分散油悬浮剂
6%环吡氟草酮+20%扑草净+30%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+5%100#溶剂油+油酸甲酯补足
36、环吡氟草酮+扑草净+异丙甲草胺(6+20+40)可分散油悬浮剂
6%环吡氟草酮+20%扑草净+40%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+5%100#溶剂油+油酸甲酯补足
37、环吡氟草酮+扑草净+精异丙甲草胺(6+20+30)可分散油悬浮剂
6%环吡氟草酮+20%扑草净+30%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+5%100#溶剂油+油酸甲酯补足
38、环吡氟草酮+扑草净+氟噻草胺(6+20+12)水悬浮剂
6%环吡氟草酮+20%扑草净+12%氟噻草胺+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
39、环吡氟草酮+扑草净+砜吡草唑(6+20+6)可分散油悬浮剂
6%环吡氟草酮+20%扑草净+6%砜吡草唑+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
40、环吡氟草酮+特丁净+噻吩磺隆(3+25+0.5)可分散油悬浮剂
3%环吡氟草酮+25%特丁净+0.5%噻吩磺隆+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.0%有机膨润土+8%100#溶剂油+油酸甲酯补足
41、环吡氟草酮+特丁净+氟乐灵(3+25+7.5)可分散油悬浮剂
3%环吡氟草酮+25%特丁净+7.5%氟乐灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.0%有机膨润土+15%100#溶剂油+油酸甲酯补足
42、环吡氟草酮+特丁净+仲丁灵(3+25+10)可分散油悬浮剂
3%环吡氟草酮+25%特丁净+10%仲丁灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖 麻油氧乙烯醚+1.0%有机膨润土+15%100#溶剂油+油酸甲酯补足
43、环吡氟草酮+特丁净+二甲戊灵(2+16.6+20)可分散油悬浮剂
2%环吡氟草酮+16.6%特丁净+20%二甲戊灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.8%有机膨润土+1.5%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
44、环吡氟草酮+特丁净+呋草酮(3+25+4)水悬浮剂
3%环吡氟草酮+25%特丁净+4%呋草酮+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
45、环吡氟草酮+特丁净+吡氟酰草胺(3+25+4)水悬浮剂
3%环吡氟草酮+25%特丁净+4%吡氟酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
46、环吡氟草酮+特丁净+氟吡酰草胺(3+25+1.5)水悬浮剂
3%环吡氟草酮+25%特丁净+1.5%氟吡酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
47、环吡氟草酮+特丁净+苄草丹(1.5+12.5+20)悬乳剂
1.5%环吡氟草酮+12.5%特丁净+20%苄草丹+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.16%黄原胶+1.5%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
48、环吡氟草酮+特丁净+野麦畏(1.5+12.5+20)悬乳剂
1.5%环吡氟草酮+12.5%特丁净+20%野麦畏+8%100#溶剂油+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.16%黄原胶+1.5%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
49、环吡氟草酮+特丁净+乙草胺(3+25+9)可分散油悬浮剂
3%环吡氟草酮+25%特丁净+9%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
50、环吡氟草酮+特丁净+丁草胺(3+25+25)可分散油悬浮剂
3%环吡氟草酮+25%特丁净+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
51、环吡氟草酮+特丁净+丙草胺(3+25+15)可分散油悬浮剂
3%环吡氟草酮+25%特丁净+15%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
52、环吡氟草酮+特丁净+异丙甲草胺(3+25+20)可分散油悬浮剂
3%环吡氟草酮+25%特丁净+20%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
53、环吡氟草酮+特丁净+精异丙甲草胺(3+25+15)可分散油悬浮剂
3%环吡氟草酮+25%特丁净+15%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
54、环吡氟草酮+特丁净+氟噻草胺(3+25+6)水悬浮剂
3%环吡氟草酮+25%特丁净+6%氟噻草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
55、环吡氟草酮+特丁净+砜吡草唑(3+25+3)水悬浮剂
3%环吡氟草酮+25%特丁净+3%砜吡草唑+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
56、环吡氟草酮+嗪草酮+噻吩磺隆(6+6+1)可分散油悬浮剂
6%环吡氟草酮+6%嗪草酮+1%噻吩磺隆+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.2%有机膨润土+2.0%气相法白炭黑+8%100#溶剂油+油酸甲酯补足
57、环吡氟草酮+嗪草酮+氟乐灵(6+6+15)可分散油悬浮剂
6%环吡氟草酮+6%嗪草酮+15%氟乐灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.2%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
58、环吡氟草酮+嗪草酮+仲丁灵(6+6+20)可分散油悬浮剂
6%环吡氟草酮+6%嗪草酮+20%仲丁灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.2%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
59、环吡氟草酮+嗪草酮+二甲戊灵(2+2+20)可分散油悬浮剂
2%环吡氟草酮+2%嗪草酮+20%二甲戊灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.5%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
60、环吡氟草酮+嗪草酮+呋草酮(6+6+8)水悬浮剂
6%环吡氟草酮+6%嗪草酮+8%呋草酮+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.2%黄原胶+1.5%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
61、环吡氟草酮+嗪草酮+吡氟酰草胺(6+6+8)水悬浮剂
6%环吡氟草酮+6%嗪草酮+8%吡氟酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.18%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
62、环吡氟草酮+嗪草酮+氟吡酰草胺(6+6+3)水悬浮剂
6%环吡氟草酮+6%嗪草酮+3%氟吡酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三 乙醇胺盐+0.2%黄原胶+1.8%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
63、环吡氟草酮+嗪草酮+苄草丹(3+3+40)悬乳剂
3%环吡氟草酮+3%嗪草酮+40%苄草丹+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.12%黄原胶+1.2%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
64、环吡氟草酮+嗪草酮+野麦畏(3+3+40)悬乳剂
3%环吡氟草酮+3%嗪草酮+40%野麦畏+8%100#溶剂油+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.12%黄原胶+1.2%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
65、环吡氟草酮+嗪草酮+乙草胺(6+6+18)可分散油悬浮剂
6%环吡氟草酮+6%嗪草酮+18%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.2%有机膨润土+2.0%气相法白炭黑+油酸甲酯补足
66、环吡氟草酮+嗪草酮+丁草胺(3+3+25)可分散油悬浮剂
3%环吡氟草酮+3%嗪草酮+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+油酸甲酯补足
67、环吡氟草酮+嗪草酮+丙草胺(6+6+30)可分散油悬浮剂
6%环吡氟草酮+6%嗪草酮+30%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+油酸甲酯补足
68、环吡氟草酮+嗪草酮+异丙甲草胺(6+6+40)可分散油悬浮剂
6%环吡氟草酮+6%嗪草酮+40%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
69、环吡氟草酮+嗪草酮+精异丙甲草胺(6+6+30)可分散油悬浮剂
6%环吡氟草酮+6%嗪草酮+30%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
70、环吡氟草酮+嗪草酮+氟噻草胺(6+6+12)水悬浮剂
6%环吡氟草酮+6%嗪草酮+12%氟噻草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
71、环吡氟草酮+嗪草酮+砜吡草唑(6+6+6)水悬浮剂
6%环吡氟草酮+6%嗪草酮+6%砜吡草唑+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.18%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
72、环吡氟草酮+氨唑草酮+噻吩磺隆(6+6+1)可分散油悬浮剂
6%环吡氟草酮+6%氨唑草酮+1%噻吩磺隆+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5% 蓖麻油氧乙烯醚+2.2%有机膨润土+2.0%气相法白炭黑+8%100#溶剂油+油酸甲酯补足
73、环吡氟草酮+氨唑草酮+氟乐灵(6+12+15)可分散油悬浮剂
6%环吡氟草酮+12%氨唑草酮+15%氟乐灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.8%有机膨润土+2.01.5%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
74、环吡氟草酮+氨唑草酮+仲丁灵(6+12+20)可分散油悬浮剂
6%环吡氟草酮+12%氨唑草酮+20%仲丁灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.6%有机膨润土+1.5%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
75、环吡氟草酮+氨唑草酮+二甲戊灵(2+4+20)可分散油悬浮剂
2%环吡氟草酮+4%氨唑草酮+20%二甲戊灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.5%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
76、环吡氟草酮+氨唑草酮+呋草酮(6+12+8)水悬浮剂
6%环吡氟草酮+12%氨唑草酮+8%呋草酮+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15%黄原胶+1.5%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
77、环吡氟草酮+氨唑草酮+吡氟酰草胺(6+12+8)水悬浮剂
6%环吡氟草酮+12%氨唑草酮+8%吡氟酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
78、环吡氟草酮+氨唑草酮+氟吡酰草胺(6+12+3)水悬浮剂
6%环吡氟草酮+12%氨唑草酮+3%氟吡酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.8%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
79、环吡氟草酮+氨唑草酮+苄草丹(3+6+40)悬乳剂
3%环吡氟草酮+6%氨唑草酮+40%苄草丹+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.12%黄原胶+1.0%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
80、环吡氟草酮+氨唑草酮+野麦畏(3+6+40)悬乳剂
3%环吡氟草酮+6%氨唑草酮+40%野麦畏+8%100#溶剂油+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.12%黄原胶+1.0%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
81、环吡氟草酮+氨唑草酮+乙草胺(6+12+18)可分散油悬浮剂
6%环吡氟草酮+12%氨唑草酮+18%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.8%有机膨润土+1.8%气相法白炭黑+油酸甲酯补足
82、环吡氟草酮+氨唑草酮+丁草胺(3+6+25)可分散油悬浮剂
3%环吡氟草酮+6%氨唑草酮+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+油酸甲酯补足
83、环吡氟草酮+氨唑草酮+丙草胺(6+12+30)可分散油悬浮剂
6%环吡氟草酮+12%氨唑草酮+30%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+油酸甲酯补足
84、环吡氟草酮+氨唑草酮+异丙甲草胺(6+12+40)可分散油悬浮剂
6%环吡氟草酮+12%氨唑草酮+40%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
85、环吡氟草酮+氨唑草酮+精异丙甲草胺(6+12+30)可分散油悬浮剂
6%环吡氟草酮+12%氨唑草酮+30%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
86、环吡氟草酮+氨唑草酮+氟噻草胺(6+12+12)水悬浮剂
6%环吡氟草酮+12%氨唑草酮+12%氟噻草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
87、环吡氟草酮+氨唑草酮+砜吡草唑(6+12+6)水悬浮剂
6%环吡氟草酮+12%氨唑草酮+6%砜吡草唑+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.18%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
88、环吡氟草酮+绿麦隆+噻吩磺隆(3+25+0.5)可分散油悬浮剂
3%环吡氟草酮+25%绿麦隆+0.5%噻吩磺隆+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+8%100#溶剂油+油酸甲酯补足
89、环吡氟草酮+绿麦隆+氟乐灵(3+25+7.5)可分散油悬浮剂
3%环吡氟草酮+25%绿麦隆+7.5%氟乐灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+15%100#溶剂油+油酸甲酯补足
90、环吡氟草酮+绿麦隆+仲丁灵(3+25+10)可分散油悬浮剂
3%环吡氟草酮+25%绿麦隆+10%仲丁灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+15%100#溶剂油+油酸甲酯补足
91、环吡氟草酮+绿麦隆+二甲戊灵(2+16.6+20)可分散油悬浮剂
2%环吡氟草酮+16.6%绿麦隆+20%二甲戊灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.8%有机膨润土+1.5%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
92、环吡氟草酮+绿麦隆+呋草酮(3+25+4)水悬浮剂
3%环吡氟草酮+25%绿麦隆+4%呋草酮+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙 醇胺盐+0.14%黄原胶+1.5%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
93、环吡氟草酮+绿麦隆+吡氟酰草胺(3+25+4)水悬浮剂
3%环吡氟草酮+25%绿麦隆+4%吡氟酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
94、环吡氟草酮+绿麦隆+氟吡酰草胺(3+25+1.5)水悬浮剂
3%环吡氟草酮+25%绿麦隆+1.5%氟吡酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.8%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
95、环吡氟草酮+绿麦隆+苄草丹(2.4+20+32)悬乳剂
2.4%环吡氟草酮+20%绿麦隆+32%苄草丹+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.1%黄原胶+1.0%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
96、环吡氟草酮+绿麦隆+野麦畏(2.4+20+32)悬乳剂
2.4%环吡氟草酮+20%绿麦隆+32%野麦畏+8%100#溶剂油+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.12%黄原胶+1.0%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
97、环吡氟草酮+绿麦隆+乙草胺(3+25+9)可分散油悬浮剂
3%环吡氟草酮+25%绿麦隆+9%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+油酸甲酯补足
98、环吡氟草酮+绿麦隆+丁草胺(3+25+25)可分散油悬浮剂
3%环吡氟草酮+25%绿麦隆+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.5%有机膨润土+油酸甲酯补足
99、环吡氟草酮+绿麦隆+丙草胺(3+25+15)可分散油悬浮剂
3%环吡氟草酮+25%绿麦隆+15%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+油酸甲酯补足
100、环吡氟草酮+绿麦隆+异丙甲草胺(3+25+20)可分散油悬浮剂
3%环吡氟草酮+25%绿麦隆+20%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+5%100#溶剂油+油酸甲酯补足
101、环吡氟草酮+绿麦隆+精异丙甲草胺(3+25+15)可分散油悬浮剂
3%环吡氟草酮+25%绿麦隆+15%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+5%100#溶剂油+油酸甲酯补足
102、环吡氟草酮+绿麦隆+氟噻草胺(3+25+6)水悬浮剂
3%环吡氟草酮+25%绿麦隆+6%氟噻草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
103、环吡氟草酮+绿麦隆+砜吡草唑(3+25+3)水悬浮剂
3%环吡氟草酮+25%绿麦隆+3%砜吡草唑+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.18%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
104、环吡氟草酮+异丙隆+噻吩磺隆(3+25+0.5)可分散油悬浮剂
3%环吡氟草酮+25%异丙隆+0.5%噻吩磺隆+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+8%100#溶剂油+油酸甲酯补足
105、环吡氟草酮+异丙隆+氟乐灵(3+25+7.5)可分散油悬浮剂
3%环吡氟草酮+25%异丙隆+7.5%氟乐灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+15%100#溶剂油+油酸甲酯补足
106、环吡氟草酮+异丙隆+仲丁灵(3+25+10)可分散油悬浮剂
3%环吡氟草酮+25%异丙隆+10%仲丁灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+15%100#溶剂油+油酸甲酯补足
107、环吡氟草酮+异丙隆+二甲戊灵(2+16.6+20)可分散油悬浮剂
2%环吡氟草酮+16.6%异丙隆+20%二甲戊灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.8%有机膨润土+1.5%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
108、环吡氟草酮+异丙隆+呋草酮(3+25+4)水悬浮剂
3%环吡氟草酮+25%异丙隆+4%呋草酮+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14%黄原胶+1.5%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
109、环吡氟草酮+异丙隆+吡氟酰草胺(3+25+4)水悬浮剂
3%环吡氟草酮+25%异丙隆+4%吡氟酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
110、环吡氟草酮+异丙隆+氟吡酰草胺(3+25+1.5)水悬浮剂
3%环吡氟草酮+25%异丙隆+1.5%氟吡酰草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16%黄原胶+1.8%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
111、环吡氟草酮+异丙隆+苄草丹(2.4+20+32)悬乳剂
2.4%环吡氟草酮+20%异丙隆+32%苄草丹+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.1%黄原胶+1.0%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
112、环吡氟草酮+异丙隆+野麦畏(2.4+20+32)悬乳剂
2.4%环吡氟草酮+20%异丙隆+32%野麦畏+8%100#溶剂油+3%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+3%蓖麻油聚氧乙烯醚+2%丁醇嵌段聚醚+0.12%黄原胶+1.0%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
113、环吡氟草酮+异丙隆+乙草胺(3+25+9)可分散油悬浮剂
3%环吡氟草酮+25%异丙隆+9%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+油酸甲酯补足
114、环吡氟草酮+异丙隆+丁草胺(3+25+25)可分散油悬浮剂
3%环吡氟草酮+25%异丙隆+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.5%有机膨润土+油酸甲酯补足
115、环吡氟草酮+异丙隆+丙草胺(3+25+15)可分散油悬浮剂
3%环吡氟草酮+25%异丙隆+15%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+油酸甲酯补足
116、环吡氟草酮+异丙隆+异丙甲草胺(3+25+20)可分散油悬浮剂
3%环吡氟草酮+25%异丙隆+20%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+5%100#溶剂油+油酸甲酯补足
117、环吡氟草酮+异丙隆+精异丙甲草胺(3+25+15)可分散油悬浮剂
3%环吡氟草酮+25%异丙隆+15%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+0.6%有机膨润土+5%100#溶剂油+油酸甲酯补足
118、环吡氟草酮+异丙隆+氟噻草胺(3+25+6)水悬浮剂
3%环吡氟草酮+25%异丙隆+6%氟噻草胺+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
119、环吡氟草酮+异丙隆+砜吡草唑(3+25+3)水悬浮剂
3%环吡氟草酮+25%异丙隆+3%砜吡草唑+5%聚羧酸盐+2%苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.18%黄原胶+1.6%硅酸镁铝+0.1%消泡剂+3%乙二醇+水
120、环吡氟草酮+哒草特+噻吩磺隆(3+25+0.5)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+0.5%噻吩磺隆+5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.2%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
121、环吡氟草酮+哒草特+氟乐灵(3+25+7.5)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+7.5%氟乐灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.2%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
122、环吡氟草酮+哒草特+仲丁灵(3+25+10)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+10%仲丁灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.2%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
123、环吡氟草酮+哒草特+二甲戊灵(2+16.6+20)可分散油悬浮剂
2%环吡氟草酮+16.6%哒草特+20%二甲戊灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+25%100#溶剂油+油酸甲酯补足
124、环吡氟草酮+哒草特+呋草酮(3+25+4)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+4%呋草酮+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
125、环吡氟草酮+哒草特+吡氟酰草胺(3+25+4)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+4%吡氟酰草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
126、环吡氟草酮+哒草特+氟吡酰草胺(3+25+1.5)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+1.5%氟吡酰草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
127、环吡氟草酮+哒草特+苄草丹(1.8+15+24)可分散油悬浮剂
1.8%环吡氟草酮+15%哒草特+24%苄草丹+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
128、环吡氟草酮+哒草特+野麦畏(1.5+12.5+20)可分散油悬浮剂
1.5%环吡氟草酮+12.5%哒草特+20%野麦畏+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
129、环吡氟草酮+哒草特+乙草胺(3+25+9)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+9%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
130、环吡氟草酮+哒草特+丁草胺(3+25+25)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
131、环吡氟草酮+哒草特+丙草胺(3+25+15)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+15%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
132、环吡氟草酮+哒草特+异丙甲草胺(3+25+20)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+20%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚 +5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
133、环吡氟草酮+哒草特+精异丙甲草胺(3+25+15)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+15%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
134、环吡氟草酮+哒草特+氟噻草胺(3+25+6)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+6%氟噻草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
135、环吡氟草酮+哒草特+砜吡草唑(3+25+3)可分散油悬浮剂
3%环吡氟草酮+25%哒草特+3%砜吡草唑+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
136、环吡氟草酮+噻吩磺隆+氟乐灵(6+1+15)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+15%氟乐灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
137、环吡氟草酮+噻吩磺隆+仲丁灵(6+1+20)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+20%仲丁灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
138、环吡氟草酮+噻吩磺隆+二甲戊灵(2+0.33+20)可分散油悬浮剂
2%环吡氟草酮+0.33%噻吩磺隆+20%二甲戊灵+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+25%100#溶剂油+油酸甲酯补足
139、环吡氟草酮+噻吩磺隆+呋草酮(6+1+8)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+8%呋草酮+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.8%有机膨润土+1.8%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
140、环吡氟草酮+噻吩磺隆+吡氟酰草胺(6+1+8)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+8%吡氟酰草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.8%有机膨润土+1.8%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
141、环吡氟草酮+噻吩磺隆+氟吡酰草胺(6+1+3)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+3%氟吡酰草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
142、环吡氟草酮+噻吩磺隆+苄草丹(3+0.5+40)可分散油悬浮剂
3%环吡氟草酮+0.5%噻吩磺隆+40%苄草丹+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+油酸甲酯补足
143、环吡氟草酮+噻吩磺隆+野麦畏(2.4+0.4+32)可分散油悬浮剂
2.4%环吡氟草酮+0.4%噻吩磺隆+32%野麦畏+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+油酸甲酯补足
144、环吡氟草酮+噻吩磺隆+乙草胺(6+1+18)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+18%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+油酸甲酯补足
145、环吡氟草酮+噻吩磺隆+丁草胺(3+0.5+25)可分散油悬浮剂
3%环吡氟草酮+0.5%噻吩磺隆+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
146、环吡氟草酮+噻吩磺隆+丙草胺(6+1+30)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+30%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
147、环吡氟草酮+噻吩磺隆+异丙甲草胺(6+1+40)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+40%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+油酸甲酯补足
148、环吡氟草酮+噻吩磺隆+精异丙甲草胺(6+1+30)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+30%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
149、环吡氟草酮+噻吩磺隆+氟噻草胺(6+1+12)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+12%氟噻草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+1.5%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
150、环吡氟草酮+噻吩磺隆+砜吡草唑(6+1+6)可分散油悬浮剂
6%环吡氟草酮+1%噻吩磺隆+6%砜吡草唑+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
151、环吡氟草酮+氟乐灵+呋草酮(6+15+8)可分散油悬浮剂
6%环吡氟草酮+15%氟乐灵+8%呋草酮+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
152、环吡氟草酮+氟乐灵+吡氟酰草胺(6+15+8)可分散油悬浮剂
6%环吡氟草酮+15%氟乐灵+8%吡氟酰草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
153、环吡氟草酮+氟乐灵+氟吡酰草胺(6+15+3)可分散油悬浮剂
6%环吡氟草酮+15%氟乐灵+3%氟吡酰草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
154、环吡氟草酮+氟乐灵+苄草丹(3+7.5+40)可分散油悬浮剂
3%环吡氟草酮+7.5%氟乐灵+40%苄草丹+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+5%100#溶剂油+油酸甲酯补足
155、环吡氟草酮+氟乐灵+野麦畏(2.4+6+32)可分散油悬浮剂
2.4%环吡氟草酮+6%氟乐灵+32%野麦畏+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+15%100#溶剂油+油酸甲酯补足
156、环吡氟草酮+氟乐灵+乙草胺(6+15+18)可分散油悬浮剂
6%环吡氟草酮+15%氟乐灵+18%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+15%100#溶剂油+油酸甲酯补足
157、环吡氟草酮+氟乐灵+丁草胺(3+7.5+25)可分散油悬浮剂
3%环吡氟草酮+7.5%氟乐灵+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
158、环吡氟草酮+氟乐灵+丙草胺(6+15+30)可分散油悬浮剂
6%环吡氟草酮+15%氟乐灵+30%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
159、环吡氟草酮+氟乐灵+异丙甲草胺(3+7.5+20)可分散油悬浮剂
3%环吡氟草酮+7.5%氟乐灵+20%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+7.5%100#溶剂油+油酸甲酯补足
160、环吡氟草酮+氟乐灵+精异丙甲草胺(6+15+30)可分散油悬浮剂
6%环吡氟草酮+15%氟乐灵+30%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
161、环吡氟草酮+氟乐灵+氟噻草胺(6+15+12)可分散油悬浮剂
6%环吡氟草酮+15%氟乐灵+12%氟噻草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+1.5%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
162、环吡氟草酮+氟乐灵+砜吡草唑(6+15+6)可分散油悬浮剂
6%环吡氟草酮+15%氟乐灵+6%砜吡草唑+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
163、环吡氟草酮+仲丁灵+呋草酮(6+20+8)可分散油悬浮剂
6%环吡氟草酮+20%仲丁灵+8%呋草酮+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖 麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
164、环吡氟草酮+仲丁灵+吡氟酰草胺(6+20+8)可分散油悬浮剂
6%环吡氟草酮+20%仲丁灵+8%吡氟酰草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
165、环吡氟草酮+仲丁灵+氟吡酰草胺(6+20+3)可分散油悬浮剂
6%环吡氟草酮+20%仲丁灵+3%氟吡酰草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
166、环吡氟草酮+仲丁灵+苄草丹(3+10+40)可分散油悬浮剂
3%环吡氟草酮+10%仲丁灵+40%苄草丹+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+10%100#溶剂油+油酸甲酯补足
167、环吡氟草酮+仲丁灵+野麦畏(2.4+8+32)可分散油悬浮剂
2.4%环吡氟草酮+8%仲丁灵+32%野麦畏+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+15%100#溶剂油+油酸甲酯补足
168、环吡氟草酮+仲丁灵+乙草胺(6+20+18)可分散油悬浮剂
6%环吡氟草酮+20%仲丁灵+18%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+20%100#溶剂油+油酸甲酯补足
169、环吡氟草酮+仲丁灵+丁草胺(3+10+25)可分散油悬浮剂
3%环吡氟草酮+10%仲丁灵+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
170、环吡氟草酮+仲丁灵+丙草胺(6+20+30)可分散油悬浮剂
6%环吡氟草酮+20%仲丁灵+30%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
171、环吡氟草酮+仲丁灵+异丙甲草胺(3+10+20)可分散油悬浮剂
3%环吡氟草酮+10%仲丁灵+20%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+7.5%100#溶剂油+油酸甲酯补足
172、环吡氟草酮+仲丁灵+精异丙甲草胺(6+20+30)可分散油悬浮剂
6%环吡氟草酮+20%仲丁灵+30%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
173、环吡氟草酮+仲丁灵+氟噻草胺(6+20+12)可分散油悬浮剂
6%环吡氟草酮+20%仲丁灵+12%氟噻草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+1.5%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
174、环吡氟草酮+仲丁灵+砜吡草唑(6+20+6)可分散油悬浮剂
6%环吡氟草酮+20%仲丁灵+6%砜吡草唑+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
175、环吡氟草酮+二甲戊灵+呋草酮(1.5+15+2)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+2%呋草酮+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.5%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
176、环吡氟草酮+二甲戊灵+吡氟酰草胺(1.5+15+2)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+2%吡氟酰草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.5%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
177、环吡氟草酮+二甲戊灵+氟吡酰草胺(1.5+15+0.75)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+0.75%氟吡酰草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.5%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
178、环吡氟草酮+二甲戊灵+苄草丹(1.5+15+20)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+20%苄草丹+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
179、环吡氟草酮+二甲戊灵+野麦畏(1.5+15+20)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+20%野麦畏+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
180、环吡氟草酮+二甲戊灵+乙草胺(1.5+15+4.5)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+4.5%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
181、环吡氟草酮+二甲戊灵+丁草胺(1.5+15+12.5)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+12.5%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
182、环吡氟草酮+二甲戊灵+丙草胺(1.5+15+7.5)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+7.5%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
183、环吡氟草酮+二甲戊灵+异丙甲草胺(1.5+15+10)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+10%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补 足
184、环吡氟草酮+二甲戊灵+精异丙甲草胺(1.5+15+7.5)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+7.5%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+15%100#溶剂油+油酸甲酯补足
185、环吡氟草酮+二甲戊灵+氟噻草胺(1.5+15+3)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+3%氟噻草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+1.5%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
186、环吡氟草酮+二甲戊灵+砜吡草唑(1.5+15+1.5)可分散油悬浮剂
1.5%环吡氟草酮+15%二甲戊灵+1.5%砜吡草唑+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+20%100#溶剂油+油酸甲酯补足
187、环吡氟草酮+呋草酮+苄草丹(3+4+40)可分散油悬浮剂
3%环吡氟草酮+4%呋草酮+40%苄草丹+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
188、环吡氟草酮+呋草酮+野麦畏(3+4+40)可分散油悬浮剂
3%环吡氟草酮+4%呋草酮+40%野麦畏+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
189、环吡氟草酮+呋草酮+乙草胺(6+8+18)可分散油悬浮剂
6%环吡氟草酮+8%呋草酮+18%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
190、环吡氟草酮+呋草酮+丁草胺(3+4+25)可分散油悬浮剂
3%环吡氟草酮+4%呋草酮+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
191、环吡氟草酮+呋草酮+丙草胺(6+8+30)可分散油悬浮剂
6%环吡氟草酮+8%呋草酮+30%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
192、环吡氟草酮+呋草酮+异丙甲草胺(6+8+40)可分散油悬浮剂
6%环吡氟草酮+8%呋草酮+40%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
193、环吡氟草酮+呋草酮+精异丙甲草胺(6+8+30)可分散油悬浮剂
6%环吡氟草酮+8%呋草酮+30%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚 +5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
194、环吡氟草酮+呋草酮+氟噻草胺(6+8+12)可分散油悬浮剂
6%环吡氟草酮+8%呋草酮+12%氟噻草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+1.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
195、环吡氟草酮+呋草酮+砜吡草唑(6+8+6)可分散油悬浮剂
6%环吡氟草酮+8%呋草酮+6%砜吡草唑+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.4%有机膨润土+1.2%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
196、环吡氟草酮+吡氟酰草胺+苄草丹(3+4+40)可分散油悬浮剂
3%环吡氟草酮+4%吡氟酰草胺+40%苄草丹+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
197、环吡氟草酮+吡氟酰草胺+野麦畏(3+4+40)可分散油悬浮剂
3%环吡氟草酮+4%吡氟酰草胺+40%野麦畏+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
198、环吡氟草酮+吡氟酰草胺+乙草胺(6+8+18)可分散油悬浮剂
6%环吡氟草酮+8%吡氟酰草胺+18%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
199、环吡氟草酮+吡氟酰草胺+丁草胺(3+4+25)可分散油悬浮剂
3%环吡氟草酮+4%吡氟酰草胺+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
200、环吡氟草酮+吡氟酰草胺+丙草胺(6+8+30)可分散油悬浮剂
6%环吡氟草酮+8%吡氟酰草胺+30%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
201、环吡氟草酮+吡氟酰草胺+异丙甲草胺(6+8+40)可分散油悬浮剂
6%环吡氟草酮+8%吡氟酰草胺+40%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
202、环吡氟草酮+吡氟酰草胺+精异丙甲草胺(6+8+30)可分散油悬浮剂
6%环吡氟草酮+8%吡氟酰草胺+30%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
203、环吡氟草酮+吡氟酰草胺+氟噻草胺(6+8+12)可分散油悬浮剂
6%环吡氟草酮+8%吡氟酰草胺+12%氟噻草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+1.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
204、环吡氟草酮+吡氟酰草胺+砜吡草唑(6+8+6)可分散油悬浮剂
6%环吡氟草酮+8%吡氟酰草胺+6%砜吡草唑+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.4%有机膨润土+1.2%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
205、环吡氟草酮+氟吡酰草胺+苄草丹(3+1.5+40)可分散油悬浮剂
3%环吡氟草酮+1.5%氟吡酰草胺+40%苄草丹+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
206、环吡氟草酮+氟吡酰草胺+野麦畏(3+1.5+40)可分散油悬浮剂
3%环吡氟草酮+1.5%氟吡酰草胺+40%野麦畏+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+10%100#溶剂油+油酸甲酯补足
207、环吡氟草酮+氟吡酰草胺+乙草胺(6+3+18)可分散油悬浮剂
6%环吡氟草酮+3%氟吡酰草胺+18%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
208、环吡氟草酮+氟吡酰草胺+丁草胺(3+1.5+25)可分散油悬浮剂
3%环吡氟草酮+1.5%氟吡酰草胺+25%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
209、环吡氟草酮+氟吡酰草胺+丙草胺(6+3+30)可分散油悬浮剂
6%环吡氟草酮+3%氟吡酰草胺+30%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
210、环吡氟草酮+氟吡酰草胺+异丙甲草胺(6+3+40)可分散油悬浮剂
6%环吡氟草酮+3%氟吡酰草胺+40%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
211、环吡氟草酮+氟吡酰草胺+精异丙甲草胺(6+3+30)可分散油悬浮剂
6%环吡氟草酮+3%氟吡酰草胺+30%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
212、环吡氟草酮+氟吡酰草胺+氟噻草胺(6+3+12)可分散油悬浮剂
6%环吡氟草酮+3%氟吡酰草胺+12%氟噻草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+1.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
213、环吡氟草酮+氟吡酰草胺+砜吡草唑(6+3+6)可分散油悬浮剂
6%环吡氟草酮+3%氟吡酰草胺+6%砜吡草唑+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.4%有机膨润土+1.2%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
214、环吡氟草酮+苄草丹+乙草胺(3+40+9)可分散油悬浮剂
3%环吡氟草酮+40%苄草丹+9%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+油酸甲酯补足
215、环吡氟草酮+苄草丹+丁草胺(1.5+20+12.5)可分散油悬浮剂
1.5%环吡氟草酮+20%苄草丹+12.5%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
216、环吡氟草酮+苄草丹+丙草胺(3+40+15)可分散油悬浮剂
3%环吡氟草酮+40%苄草丹+15%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+油酸甲酯补足
217、环吡氟草酮+苄草丹+异丙甲草胺(1.5+20+10)可分散油悬浮剂
1.5%环吡氟草酮+20%苄草丹+10%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
218、环吡氟草酮+苄草丹+精异丙甲草胺(3+40+15)可分散油悬浮剂
3%环吡氟草酮+40%苄草丹+15%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+油酸甲酯补足
219、环吡氟草酮+苄草丹+氟噻草胺(3+40+6)可分散油悬浮剂
3%环吡氟草酮+40%苄草丹+6%氟噻草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+1.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
220、环吡氟草酮+苄草丹+砜吡草唑(3+40+3)可分散油悬浮剂
3%环吡氟草酮+40%苄草丹+3%砜吡草唑+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.4%有机膨润土+1.2%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
221、环吡氟草酮+野麦畏+乙草胺(3+40+9)可分散油悬浮剂
3%环吡氟草酮+40%野麦畏+9%乙草胺+6%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
222、环吡氟草酮+野麦畏+丁草胺(1.5+20+12.5)可分散油悬浮剂
1.5%环吡氟草酮+20%野麦畏+12.5%丁草胺+8%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
223、环吡氟草酮+野麦畏+丙草胺(3+40+15)可分散油悬浮剂
3%环吡氟草酮+40%野麦畏+15%丙草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
224、环吡氟草酮+野麦畏+异丙甲草胺(1.5+20+10)可分散油悬浮剂
1.5%环吡氟草酮+20%野麦畏+10%异丙甲草胺+6.5%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
225、环吡氟草酮+野麦畏+精异丙甲草胺(3+40+15)可分散油悬浮剂
3%环吡氟草酮+40%野麦畏+15%精异丙甲草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+2.0%有机膨润土+2.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
226、环吡氟草酮+野麦畏+氟噻草胺(3+40+6)可分散油悬浮剂
3%环吡氟草酮+40%野麦畏+6%氟噻草胺+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.2%有机膨润土+1.0%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
227、环吡氟草酮+野麦畏+砜吡草唑(3+40+3)可分散油悬浮剂
3%环吡氟草酮+40%野麦畏+3%砜吡草唑+7%十二烷基苯磺酸钙+5%脂肪醇聚氧乙烯醚+5%蓖麻油氧乙烯醚+1.4%有机膨润土+1.2%气相法白炭黑+5%100#溶剂油+油酸甲酯补足
上述水悬浮剂加工设备:混料釜、胶体磨、砂磨机、剪切机等。
上述水悬浮剂加工过程:将所有物料投入混料釜中,搅拌混合后过胶体磨,之后进入砂磨机三级砂磨,最后在剪切机中剪切均匀,化验合格后,转移至储罐灌装。
上述可分散油悬浮剂加工设备:混料釜、胶体磨、砂磨机、剪切机等。
上述可分散油悬浮剂加工过程:将所有物料投入混料釜中,搅拌混合后过胶体磨,之后进入砂磨机三级砂磨,最后在剪切机中剪切均匀,化验合格后,转移至储罐灌装。
上述悬乳剂加工设备:混料釜、胶体磨、砂磨机、剪切机,剪切釜。
上述悬乳剂加工过程:将部分物料投入混料釜中,搅拌混合后过胶体磨,之后进入砂磨机三级砂磨,合格后打入剪切釜备用,为水相物料;之后将剩余原药和溶剂投入混料釜中,搅拌溶解至完全透明,之后加入乳化剂,搅拌均匀为油相,之后开启剪切机,在剪切状态下,将油相缓缓抽入剪切釜内,全部物料抽入后,继续剪切1个小时,化验合格后,转移至储罐灌装。
上述水分散粒剂加工设备:气流粉碎机,犁刀式混合机,篮式造粒机,干燥箱,筛分机等。
上述水分散粒剂加工过程:将上述物料混合均匀过气流粉碎,加水入捏合造粒,之后干燥,最后筛分得到成品。
上述可湿性粉剂加工设备:机械粉碎机,气流粉碎机。
上述可湿性粉剂加工过程:将原药、助剂、白炭黑、高岭土等投入机械粉碎机中,之后过气流粉碎机,取样化验合格后备用。
B)药效试验(苗后茎叶喷雾处理)
1)试验条件
1.1)、供试靶标
牛繁缕采自江苏兴化,上述杂草采用盆栽法培养,用180×140mm塑料营养钵,摆放于搪瓷盘中,内装从农田采回经风干过筛的表层土壤(4/5处),土壤湿度初期均控制在20%,挑选籽粒饱满均一的杂草种子,用25℃温水浸泡6小时,在28℃生化培养箱(黑暗)中催芽,将刚刚露白的杂草种子均匀摆放在土壤表面,根据种子粒径大小然后覆土0.5-1cm。
1.2)、培养条件
在可控日光温室内进行,温度20~30℃,自然光照,相对湿度57%~72%。土壤类型为壤土,有机质含量为1.63%,pH=7.1,碱解氮84.3mg/kg,速效磷38.5mg/kg,速效钾82.1mg/kg。
1.3)、仪器设备
3WP-2000型行走式喷雾塔,农业部南京农业机械研究所。GA10型万分之一电子天平(德国);ZDR2000智能数据记录仪(杭州泽大仪器有限公司);SPX型智能生化培养箱(宁波江南仪器厂)。
2)试验设计
2.1)、试剂
所需活性成分环吡氟草酮为本公司生产,其他由试剂公司购买。原药均采用丙酮作溶剂,用含量0.1%乳化剂T-80水溶液稀释,现用现稀释。
2.2)、试验处理
2.2.1)、剂量设置
在确定活性成分配比或含量时,应从药剂的作用特点及其毒力等衡量,还要考虑该配方的主要使用目的。本研究在前期预试的基础上,设活性成分单用及混合用量分别见表格。以不含药剂、含相同溶剂及乳化剂的水作为空白对照。
2.2.2)、试验重复
每处理重复4次,每次每处理3盆,每盆播种杂草种子20粒,每处理共60株。
2.3)、处理方式
2.3.1)、处理时间和次数
试验共用药1次。待杂草1叶期,间苗,保持每盆内杂草15株,每处理保留45株,然后继续培养至2~3叶期均匀茎叶喷雾处理。
2.3.2)、使用器械和用药方法
将培养好的试材均匀摆放在面积0.5m 2的平台上,用3WP-2000型行走式喷雾塔茎叶喷雾,喷液量按30公斤/公顷计。喷雾压力0.3MPa。待全部药液喷完后,关闭气阀,30秒后,打开喷雾塔门,取出营养钵。然后打开气阀,喷清水50ml,清洗喷液管。
3)试验方法
采用盆栽法。杂草培养见1.1,参照《农药室内生物测定试验准则除草剂》进行。用药方法见2.3.2,采用茎叶处理法。处理后移入温室常规培养,试验期间始终保持1-2cm水层。
4)数据调查与统计分析
4.1)、调查方法
采用绝对数调查法,用刀片沿土壤表面切断存活杂草整株幼苗,用分析天平称量杂草鲜重。对于已经死亡的杂草,按鲜重为零计。
4.2)、调查时间和次数
处理后15天调查,共调查1次。
4.3)、数据统计分析
用Colby法检验,评价任意两者及三者混用对杂草的联合作用类型。
15d时剪取各处理地上绿色组织,采用电子天平称重,计算实际存活率:E(%)=(处理区杂草鲜重/对照区杂草鲜重)×100
理论杂草存活率计算公式为:E0(%)=X×Y/100(二元混用)
式中X代表用量为P时A的杂草存活率,Y代表用量为Q时B的杂草存活率,E0代表用量为(P+Q)时A+B的理论杂草存活率,E代表各处理的实际杂草存活率。
E0(%)=X×Y×Z×…×N/100(n-1)(三元及以上混用)
式中X、Y、Z、N分别代表n种单剂的实际存活率,n为复配除草剂品种数量。
当E0-E>10%时,说明产生增效作用;当E0-E<-10%时,说明产生拮抗作用;当E0-E介于±10%时,说明产生相加作用。
统计结果见下表1-227:
表1 A为环吡氟草酮,B为噁草酮,C为扑草净,试材为牛繁缕
Figure PCTCN2018105271-appb-000001
Figure PCTCN2018105271-appb-000002
表2 A为环吡氟草酮,B为噁草酮,C为特丁净,试材为牛繁缕
Figure PCTCN2018105271-appb-000003
表3 A为环吡氟草酮,B为噁草酮,C为嗪草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000004
表4 A为环吡氟草酮,B为噁草酮,C为氨唑草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000005
表5 A为环吡氟草酮,B为噁草酮,C为绿麦隆,试材为牛繁缕
Figure PCTCN2018105271-appb-000006
表6 A为环吡氟草酮,B为噁草酮,C为异丙隆,试材为牛繁缕
Figure PCTCN2018105271-appb-000007
Figure PCTCN2018105271-appb-000008
表7 A为环吡氟草酮,B为噁草酮,C为哒草特,试材为牛繁缕
Figure PCTCN2018105271-appb-000009
表8 A为环吡氟草酮,B为噁草酮,C为噻吩磺隆,试材为牛繁缕
Figure PCTCN2018105271-appb-000010
表9 A为环吡氟草酮,B为噁草酮,C为氟乐灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000011
表10 A为环吡氟草酮,B为噁草酮,C为仲丁灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000012
Figure PCTCN2018105271-appb-000013
表11 A为环吡氟草酮,B为噁草酮,C为二甲戊灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000014
表12 A为环吡氟草酮,B为噁草酮,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000015
表13 A为环吡氟草酮,B为噁草酮,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000016
表14 A为环吡氟草酮,B为噁草酮,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000017
Figure PCTCN2018105271-appb-000018
表15 A为环吡氟草酮,B为噁草酮,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000019
表16 A为环吡氟草酮,B为噁草酮,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000020
表17 A为环吡氟草酮,B为噁草酮,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000021
表18 A为环吡氟草酮,B为噁草酮,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000022
表19 A为环吡氟草酮,B为噁草酮,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000023
Figure PCTCN2018105271-appb-000024
表20 A为环吡氟草酮,B为噁草酮,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000025
表21 A为环吡氟草酮,B为噁草酮,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000026
表22 A为环吡氟草酮,B为噁草酮,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000027
表23 A为环吡氟草酮,B为噁草酮,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000028
Figure PCTCN2018105271-appb-000029
表24 A为环吡氟草酮,B为扑草净,C为噻吩磺隆,试材为牛繁缕
Figure PCTCN2018105271-appb-000030
表25 A为环吡氟草酮,B为扑草净,C为氟乐灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000031
表26 A为环吡氟草酮,B为扑草净,C为仲丁灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000032
表27 A为环吡氟草酮,B为扑草净,C为二甲戊灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000033
表28 A为环吡氟草酮,B为扑草净,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000034
表29 A为环吡氟草酮,B为扑草净,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000035
表30 A为环吡氟草酮,B为扑草净,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000036
表31 A为环吡氟草酮,B为扑草净,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000037
表32 A为环吡氟草酮,B为扑草净,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000038
Figure PCTCN2018105271-appb-000039
表33 A为环吡氟草酮,B为扑草净,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000040
表34 A为环吡氟草酮,B为扑草净,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000041
表35 A为环吡氟草酮,B为扑草净,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000042
表36 A为环吡氟草酮,B为扑草净,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000043
Figure PCTCN2018105271-appb-000044
表37 A为环吡氟草酮,B为扑草净,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000045
表38 A为环吡氟草酮,B为扑草净,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000046
表39 A为环吡氟草酮,B为扑草净,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000047
表40 A为环吡氟草酮,B为特丁净,C为噻吩磺隆,试材为牛繁缕
Figure PCTCN2018105271-appb-000048
表41 A为环吡氟草酮,B为特丁净,C为氟乐灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000049
表42 A为环吡氟草酮,B为特丁净,C为仲丁灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000050
表43 A为环吡氟草酮,B为特丁净,C为二甲戊灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000051
表44 A为环吡氟草酮,B为特丁净,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000052
表45 A为环吡氟草酮,B为特丁净,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000053
Figure PCTCN2018105271-appb-000054
表46 A为环吡氟草酮,B为特丁净,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000055
表47 A为环吡氟草酮,B为特丁净,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000056
表48 A为环吡氟草酮,B为特丁净,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000057
表49 A为环吡氟草酮,B为特丁净,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000058
Figure PCTCN2018105271-appb-000059
表50 A为环吡氟草酮,B为特丁净,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000060
表51 A为环吡氟草酮,B为特丁净,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000061
表52 A为环吡氟草酮,B为特丁净,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000062
表53 A为环吡氟草酮,B为特丁净,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000063
表54 A为环吡氟草酮,B为特丁净,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000064
Figure PCTCN2018105271-appb-000065
表55 A为环吡氟草酮,B为特丁净,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000066
表56 A为环吡氟草酮,B为嗪草酮,C为噻吩磺隆,试材为牛繁缕
Figure PCTCN2018105271-appb-000067
表57 A为环吡氟草酮,B为嗪草酮,C为氟乐灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000068
表58 A为环吡氟草酮,B为嗪草酮,C为仲丁灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000069
Figure PCTCN2018105271-appb-000070
表59 A为环吡氟草酮,B为嗪草酮,C为二甲戊灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000071
表60 A为环吡氟草酮,B为嗪草酮,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000072
表61 A为环吡氟草酮,B为嗪草酮,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000073
表62 A为环吡氟草酮,B为嗪草酮,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000074
表63 A为环吡氟草酮,B为嗪草酮,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000075
表64 A为环吡氟草酮,B为嗪草酮,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000076
表65 A为环吡氟草酮,B为嗪草酮,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000077
表66 A为环吡氟草酮,B为嗪草酮,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000078
表67 A为环吡氟草酮,B为嗪草酮,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000079
Figure PCTCN2018105271-appb-000080
表68 A为环吡氟草酮,B为嗪草酮,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000081
表69 A为环吡氟草酮,B为嗪草酮,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000082
表70 A为环吡氟草酮,B为嗪草酮,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000083
表71 A为环吡氟草酮,B为嗪草酮,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000084
Figure PCTCN2018105271-appb-000085
表72 A为环吡氟草酮,B为氨唑草酮,C为噻吩磺隆,试材为牛繁缕
Figure PCTCN2018105271-appb-000086
表73 A为环吡氟草酮,B为氨唑草酮,C为氟乐灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000087
表74 A为环吡氟草酮,B为氨唑草酮,C为仲丁灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000088
表75 A为环吡氟草酮,B为氨唑草酮,C为二甲戊灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000089
表76 A为环吡氟草酮,B为氨唑草酮,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000090
Figure PCTCN2018105271-appb-000091
表77 A为环吡氟草酮,B为氨唑草酮,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000092
表78 A为环吡氟草酮,B为氨唑草酮,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000093
表79 A为环吡氟草酮,B为氨唑草酮,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000094
表80 A为环吡氟草酮,B为氨唑草酮,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000095
Figure PCTCN2018105271-appb-000096
表81 A为环吡氟草酮,B为氨唑草酮,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000097
表82 A为环吡氟草酮,B为氨唑草酮,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000098
表83 A为环吡氟草酮,B为氨唑草酮,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000099
表84 A为环吡氟草酮,B为氨唑草酮,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000100
表85 A为环吡氟草酮,B为氨唑草酮,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000101
表86 A为环吡氟草酮,B为氨唑草酮,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000102
表87 A为环吡氟草酮,B为氨唑草酮,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000103
表88 A为环吡氟草酮,B为绿麦隆,C为噻吩磺隆,试材为牛繁缕
Figure PCTCN2018105271-appb-000104
表89 A为环吡氟草酮,B为绿麦隆,C为氟乐灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000105
Figure PCTCN2018105271-appb-000106
表90 A为环吡氟草酮,B为绿麦隆,C为仲丁灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000107
表91 A为环吡氟草酮,B为绿麦隆,C为二甲戊灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000108
表92 A为环吡氟草酮,B为绿麦隆,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000109
表93 A为环吡氟草酮,B为绿麦隆,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000110
Figure PCTCN2018105271-appb-000111
表94 A为环吡氟草酮,B为绿麦隆,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000112
表95 A为环吡氟草酮,B为绿麦隆,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000113
表96 A为环吡氟草酮,B为绿麦隆,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000114
表97 A为环吡氟草酮,B为绿麦隆,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000115
表98 A为环吡氟草酮,B为绿麦隆,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000116
Figure PCTCN2018105271-appb-000117
表99 A为环吡氟草酮,B为绿麦隆,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000118
表100 A为环吡氟草酮,B为绿麦隆,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000119
表101 A为环吡氟草酮,B为绿麦隆,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000120
表102 A为环吡氟草酮,B为绿麦隆,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000121
Figure PCTCN2018105271-appb-000122
表103 A为环吡氟草酮,B为绿麦隆,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000123
表104 A为环吡氟草酮,B为异丙隆,C为噻吩磺隆,试材为牛繁缕
Figure PCTCN2018105271-appb-000124
表105 A为环吡氟草酮,B为异丙隆,C为氟乐灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000125
表106 A为环吡氟草酮,B为异丙隆,C为仲丁灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000126
表107 A为环吡氟草酮,B为异丙隆,C为二甲戊灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000127
表108 A为环吡氟草酮,B为异丙隆,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000128
表109 A为环吡氟草酮,B为异丙隆,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000129
表110 A为环吡氟草酮,B为异丙隆,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000130
表111 A为环吡氟草酮,B为异丙隆,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000131
Figure PCTCN2018105271-appb-000132
表112 A为环吡氟草酮,B为异丙隆,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000133
表113 A为环吡氟草酮,B为异丙隆,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000134
表114 A为环吡氟草酮,B为异丙隆,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000135
表115 A为环吡氟草酮,B为异丙隆,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000136
Figure PCTCN2018105271-appb-000137
表116 A为环吡氟草酮,B为异丙隆,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000138
表117 A为环吡氟草酮,B为异丙隆,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000139
表118 A为环吡氟草酮,B为异丙隆,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000140
表119 A为环吡氟草酮,B为异丙隆,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000141
表120 A为环吡氟草酮,B为哒草特,C为噻吩磺隆,试材为牛繁缕
Figure PCTCN2018105271-appb-000142
Figure PCTCN2018105271-appb-000143
表121 A为环吡氟草酮,B为哒草特,C为氟乐灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000144
表122 A为环吡氟草酮,B为哒草特,C为仲丁灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000145
表123 A为环吡氟草酮,B为哒草特,C为二甲戊灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000146
表124 A为环吡氟草酮,B为哒草特,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000147
Figure PCTCN2018105271-appb-000148
表125 A为环吡氟草酮,B为哒草特,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000149
表126 A为环吡氟草酮,B为哒草特,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000150
表127 A为环吡氟草酮,B为哒草特,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000151
表128 A为环吡氟草酮,B为哒草特,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000152
表129 A为环吡氟草酮,B为哒草特,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000153
表130 A为环吡氟草酮,B为哒草特,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000154
表131 A为环吡氟草酮,B为哒草特,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000155
表132 A为环吡氟草酮,B为哒草特,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000156
表133 A为环吡氟草酮,B为哒草特,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000157
Figure PCTCN2018105271-appb-000158
表134 A为环吡氟草酮,B为哒草特,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000159
表135 A为环吡氟草酮,B为哒草特,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000160
表136 A为环吡氟草酮,B为噻吩磺隆,C为氟乐灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000161
表137 A为环吡氟草酮,B为噻吩磺隆,C为仲丁灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000162
Figure PCTCN2018105271-appb-000163
表138 A为环吡氟草酮,B为噻吩磺隆,C为二甲戊灵,试材为牛繁缕
Figure PCTCN2018105271-appb-000164
表139 A为环吡氟草酮,B为噻吩磺隆,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000165
表140 A为环吡氟草酮,B为噻吩磺隆,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000166
表141 A为环吡氟草酮,B为噻吩磺隆,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000167
表142 A为环吡氟草酮,B为噻吩磺隆,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000168
Figure PCTCN2018105271-appb-000169
表143 A为环吡氟草酮,B为噻吩磺隆,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000170
表144 A为环吡氟草酮,B为噻吩磺隆,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000171
表145 A为环吡氟草酮,B为噻吩磺隆,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000172
表146 A为环吡氟草酮,B为噻吩磺隆,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000173
Figure PCTCN2018105271-appb-000174
表147 A为环吡氟草酮,B为噻吩磺隆,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000175
表148 A为环吡氟草酮,B为噻吩磺隆,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000176
表149 A为环吡氟草酮,B为噻吩磺隆,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000177
表150 A为环吡氟草酮,B为噻吩磺隆,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000178
表151 A为环吡氟草酮,B为氟乐灵,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000179
表152 A为环吡氟草酮,B为氟乐灵,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000180
表153 A为环吡氟草酮,B为氟乐灵,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000181
表154 A为环吡氟草酮,B为氟乐灵,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000182
表155 A为环吡氟草酮,B为氟乐灵,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000183
Figure PCTCN2018105271-appb-000184
表156 A为环吡氟草酮,B为氟乐灵,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000185
表157 A为环吡氟草酮,B为氟乐灵,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000186
表158 A为环吡氟草酮,B为氟乐灵,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000187
表159 A为环吡氟草酮,B为氟乐灵,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000188
Figure PCTCN2018105271-appb-000189
表160 A为环吡氟草酮,B为氟乐灵,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000190
表161 A为环吡氟草酮,B为氟乐灵,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000191
表162 A为环吡氟草酮,B为氟乐灵,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000192
表163 A为环吡氟草酮,B为仲丁灵,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000193
表164 A为环吡氟草酮,B为仲丁灵,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000194
表165 A为环吡氟草酮,B为仲丁灵,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000195
表166 A为环吡氟草酮,B为仲丁灵,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000196
表167 A为环吡氟草酮,B为仲丁灵,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000197
表168 A为环吡氟草酮,B为仲丁灵,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000198
Figure PCTCN2018105271-appb-000199
表169 A为环吡氟草酮,B为仲丁灵,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000200
表170 A为环吡氟草酮,B为仲丁灵,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000201
表171 A为环吡氟草酮,B为仲丁灵,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000202
表172 A为环吡氟草酮,B为仲丁灵,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000203
Figure PCTCN2018105271-appb-000204
表173 A为环吡氟草酮,B为仲丁灵,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000205
表174 A为环吡氟草酮,B为仲丁灵,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000206
表175 A为环吡氟草酮,B为二甲戊灵,C为呋草酮,试材为牛繁缕
Figure PCTCN2018105271-appb-000207
表176 A为环吡氟草酮,B为二甲戊灵,C为吡氟酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000208
表177 A为环吡氟草酮,B为二甲戊灵,C为氟吡酰草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000209
Figure PCTCN2018105271-appb-000210
表178 A为环吡氟草酮,B为二甲戊灵,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000211
表179 A为环吡氟草酮,B为二甲戊灵,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000212
表180 A为环吡氟草酮,B为二甲戊灵,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000213
表181 A为环吡氟草酮,B为二甲戊灵,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000214
Figure PCTCN2018105271-appb-000215
表182 A为环吡氟草酮,B为二甲戊灵,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000216
表183 A为环吡氟草酮,B为二甲戊灵,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000217
表184 A为环吡氟草酮,B为二甲戊灵,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000218
表185 A为环吡氟草酮,B为二甲戊灵,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000219
表186 A为环吡氟草酮,B为二甲戊灵,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000220
表187 A为环吡氟草酮,B为呋草酮,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000221
表188 A为环吡氟草酮,B为呋草酮,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000222
表189 A为环吡氟草酮,B为呋草酮,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000223
表190 A为环吡氟草酮,B为呋草酮,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000224
Figure PCTCN2018105271-appb-000225
表191 A为环吡氟草酮,B为呋草酮,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000226
表192 A为环吡氟草酮,B为呋草酮,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000227
表193 A为环吡氟草酮,B为呋草酮,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000228
表194 A为环吡氟草酮,B为呋草酮,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000229
Figure PCTCN2018105271-appb-000230
表195 A为环吡氟草酮,B为呋草酮,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000231
表196 A为环吡氟草酮,B为吡氟酰草胺,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000232
表197 A为环吡氟草酮,B为吡氟酰草胺,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000233
表198 A为环吡氟草酮,B为吡氟酰草胺,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000234
表199 A为环吡氟草酮,B为吡氟酰草胺,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000235
Figure PCTCN2018105271-appb-000236
表200 A为环吡氟草酮,B为吡氟酰草胺,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000237
表201 A为环吡氟草酮,B为吡氟酰草胺,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000238
表202 A为环吡氟草酮,B为吡氟酰草胺,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000239
表203 A为环吡氟草酮,B为吡氟酰草胺,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000240
Figure PCTCN2018105271-appb-000241
表204 A为环吡氟草酮,B为吡氟酰草胺,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000242
表205 A为环吡氟草酮,B为氟吡酰草胺,C为苄草丹,试材为牛繁缕
Figure PCTCN2018105271-appb-000243
表206 A为环吡氟草酮,B为氟吡酰草胺,C为野麦畏,试材为牛繁缕
Figure PCTCN2018105271-appb-000244
表207 A为环吡氟草酮,B为氟吡酰草胺,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000245
表208 A为环吡氟草酮,B为氟吡酰草胺,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000246
表209 A为环吡氟草酮,B为氟吡酰草胺,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000247
表210 A为环吡氟草酮,B为氟吡酰草胺,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000248
表211 A为环吡氟草酮,B为氟吡酰草胺,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000249
表212 A为环吡氟草酮,B为氟吡酰草胺,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000250
Figure PCTCN2018105271-appb-000251
表213 A为环吡氟草酮,B为氟吡酰草胺,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000252
表214 A为环吡氟草酮,B为苄草丹,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000253
表215 A为环吡氟草酮,B为苄草丹,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000254
表216 A为环吡氟草酮,B为苄草丹,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000255
Figure PCTCN2018105271-appb-000256
表217 A为环吡氟草酮,B为苄草丹,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000257
表218 A为环吡氟草酮,B为苄草丹,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000258
表219 A为环吡氟草酮,B为苄草丹,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000259
表220 A为环吡氟草酮,B为苄草丹,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000260
表221 A为环吡氟草酮,B为野麦畏,C为乙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000261
Figure PCTCN2018105271-appb-000262
表222 A为环吡氟草酮,B为野麦畏,C为丁草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000263
223 A为环吡氟草酮,B为野麦畏,C为丙草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000264
表224 A为环吡氟草酮,B为野麦畏,C为异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000265
表225 A为环吡氟草酮,B为野麦畏,C为精异丙甲草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000266
Figure PCTCN2018105271-appb-000267
表226 A为环吡氟草酮,B为野麦畏,C为氟噻草胺,试材为牛繁缕
Figure PCTCN2018105271-appb-000268
表227 A为环吡氟草酮,B为野麦畏,C为砜吡草唑,试材为牛繁缕
Figure PCTCN2018105271-appb-000269
注:E(A):在给定剂量下,组分A处理的实测鲜重存活率
E(B):在给定剂量下,组分B处理的实测鲜重存活率
E(C):在给定剂量下,组分C处理的实测鲜重存活率
E(A+B):在给定剂量下,组分A和组分B二元混用的实测鲜重存活率
E(A+C):在给定剂量下,组分A和组分C二元混用的实测鲜重存活率
E(B+C):在给定剂量下,组分B和组分C二元混用的实测鲜重存活率
E(A+B+C):在给定剂量下,组分A、B、C三元混用的实测鲜重存活率
E 0(A+B+C):在给定剂量下,组分A、B、C三元混用的理论鲜重存活率
E 0((A+B)+C):在给定剂量下,组分A、B作为一个整体与组分C二元混用的理论鲜重存活率
E 0((A+C)+B):在给定剂量下,组分A、C作为一个整体与组分B二元混用的理论鲜重存活率
E 0(A+(B+C)):在给定剂量下,组分B、C作为一个整体与组分A二元混用的理论鲜重存活率C)大田示范
利用实施例1-227制得的除草剂组合物防除大田杂草试验。
2017年在河南驻马店4个试验点进行试验。田间发生的杂草主要有:大穗看麦娘、荠菜、牛繁缕、猪殃殃、婆婆纳等。
试验方法:杂草1叶期,手动喷雾器,兑水量30公斤/667m 2,采用茎叶喷雾均匀喷雾,具体试验药剂及剂量详见表228,小区面积50平方米,每处理重复4次。施药后45天调查防除效果见表228。
Figure PCTCN2018105271-appb-000270
表228 大田示范效果情况
实施例 剂型 用量(g a.i./ha) 鲜重防效(%)
实施例1 SC 540 95.6
实施例2 WP 990 94.5
实施例3 OD 330 97.4
实施例4 SC 420 98.5
实施例5 WDG 990 95.1
实施例6 WDG 990 99.5
实施例7 SE 990 99.4
实施例8 OD 255 97.5
实施例9 OD 465 99.8
实施例10 OD 540 93.1
实施例11 OD 990 97.9
实施例12 SC 360 98.5
实施例13 OD 360 94.4
实施例14 OD 285 99.8
实施例15 SE 1440 93.4
实施例16 SE 1440 94.4
实施例17 OD 510 96.1
实施例18 OD 990 94.7
实施例19 OD 690 95.6
实施例20 OD 840 94.6
实施例21 OD 690 95.3
实施例22 OD 420 94.7
实施例23 OD 330 95.6
实施例24 OD 405 93.2
实施例25 OD 615 91.6
实施例26 OD 690 93.2
实施例27 OD 1287 94.7
实施例28 SC 510 94.9
实施例29 SC 510 91.6
实施例30 SC 435 93.8
实施例31 SE 1590 99.4
实施例32 SE 1590 96.3
实施例33 OD 660 98.4
实施例34 OD 1140 98.9
实施例35 OD 840 95.7
实施例36 OD 990 98.7
实施例37 OD 840 98.0
实施例38 SC 570 98.1
实施例39 OD 480 99.4
实施例40 OD 855 94.5
实施例41 OD 1065 95.8
实施例42 OD 1140 97.6
实施例43 OD 1737 97.9
实施例44 SC 960 90.5
实施例45 SC 960 93.2
实施例46 SC 885 90.5
实施例47 SE 2040 96.3
实施例48 SE 2040 94.6
实施例49 OD 1110 95.0
实施例50 OD 1590 93.6
实施例51 OD 1290 99.3
实施例52 OD 1440 99.3
实施例53 OD 1290 98.4
实施例54 SC 1020 96.4
实施例55 SC 930 93.7
实施例56 OD 195 95.9
实施例57 OD 405 93.9
实施例58 OD 480 93.0
实施例59 OD 1080 97.6
实施例60 SC 300 96.9
实施例61 SC 300 96.5
实施例62 SC 225 94.5
实施例63 SE 1380 94.7
实施例64 SE 1380 96.2
实施例65 OD 450 96.4
实施例66 OD 930 96.1
实施例67 OD 630 97.3
实施例68 OD 780 99.1
实施例69 OD 630 94.8
实施例70 SC 360 92.0
实施例71 SC 270 94.8
实施例72 OD 195 94.8
实施例73 OD 495 93.0
实施例74 OD 570 97.9
实施例75 OD 1170 94.3
实施例76 SC 390 93.9
实施例77 SC 390 92.9
实施例78 SC 315 95.8
实施例79 SE 1470 94.8
实施例80 SE 1470 92.7
实施例81 OD 540 93.5
实施例82 OD 1020 94.9
实施例83 OD 720 96.1
实施例84 OD 870 93.4
实施例85 OD 720 95.4
实施例86 SC 450 93.1
实施例87 SC 360 97.7
实施例88 OD 855 98.1
实施例89 OD 1065 96.3
实施例90 OD 1140 97.6
实施例91 OD 1737 98.3
实施例92 SC 960 98.5
实施例93 SC 960 98.3
实施例94 SC 885 97.5
实施例95 SE 2040 97.7
实施例96 SE 2040 96.8
实施例97 OD 1110 94.8
实施例98 OD 1590 99.2
实施例99 OD 1290 95.2
实施例100 OD 1440 92.7
实施例101 OD 1290 95.0
实施例102 SC 1020 99.1
实施例103 SC 930 96.7
实施例104 OD 855 92.3
实施例105 OD 1065 94.3
实施例106 OD 1140 95.5
实施例107 OD 1737 94.4
实施例108 SC 960 97.3
实施例109 SC 960 96.9
实施例110 SC 885 96.1
实施例111 SE 2040 96.8
实施例112 SE 5100 95.0
实施例113 OD 1110 97.6
实施例114 OD 1590 98.0
实施例115 OD 1290 97.6
实施例116 OD 1440 96.1
实施例117 OD 1290 94.9
实施例118 SC 1020 94.0
实施例119 SC 930 93.2
实施例120 OD 855 95.4
实施例121 OD 1065 98.6
实施例122 OD 1140 93.5
实施例123 OD 1737 93.9
实施例124 OD 960 92.8
实施例125 OD 960 98.2
实施例126 OD 885 95.8
实施例127 OD 2040 96.9
实施例128 OD 2040 98.9
实施例129 OD 1110 94.5
实施例130 OD 1590 96.4
实施例131 OD 1290 97.4
实施例132 OD 1440 97.2
实施例133 OD 1290 96.4
实施例134 OD 1020 96.4
实施例135 OD 930 95.5
实施例136 OD 330 93.5
实施例137 OD 405 99.1
实施例138 OD 1004.85 96.1
实施例139 OD 225 95.2
实施例140 OD 225 93.2
实施例141 OD 150 98.8
实施例142 OD 1305 97.8
实施例143 OD 1305 99.2
实施例144 OD 375 94.1
实施例145 OD 855 98.3
实施例146 OD 555 98.8
实施例147 OD 705 96.8
实施例148 OD 555 95.6
实施例149 OD 285 97.8
实施例150 OD 195 96.9
实施例151 OD 435 95.1
实施例152 OD 435 96.4
实施例153 OD 360 98.4
实施例154 OD 1515 96.3
实施例155 OD 1515 94.4
实施例156 OD 585 98.5
实施例157 OD 915 98.2
实施例158 OD 765 98.7
实施例159 OD 915 95.4
实施例160 OD 765 96.9
实施例161 OD 495 96.7
实施例162 OD 405 95.3
实施例163 OD 510 95.8
实施例164 OD 510 98.5
实施例165 OD 435 95.5
实施例166 OD 1590 94.8
实施例167 OD 1590 94.9
实施例168 OD 660 98.6
实施例169 OD 1140 96.9
实施例170 OD 840 97.1
实施例171 OD 990 96.9
实施例172 OD 840 96.1
实施例173 OD 570 96.7
实施例174 OD 480 96.6
实施例175 OD 1110 94.7
实施例176 OD 1110 98.8
实施例177 OD 1035 98.5
实施例178 OD 2190 99.0
实施例179 OD 2190 95.7
实施例180 OD 1260 97.2
实施例181 OD 1740 97.0
实施例182 OD 1440 95.6
实施例183 OD 1590 96.1
实施例184 OD 1440 98.8
实施例185 OD 1170 95.8
实施例186 OD 1080 95.1
实施例187 OD 1410 95.2
实施例188 OD 1410 98.9
实施例189 OD 480 97.2
实施例190 OD 960 97.4
实施例191 OD 660 96.7
实施例192 OD 810 94.3
实施例193 OD 660 97.7
实施例194 OD 390 95.8
实施例195 OD 300 94.1
实施例196 OD 1410 92.0
实施例197 OD 1410 99.1
实施例198 OD 480 97.4
实施例199 OD 960 99.7
实施例200 OD 660 92.8
实施例201 OD 810 99.7
实施例202 OD 660 93.9
实施例203 OD 390 98.6
实施例204 OD 300 95.4
实施例205 OD 1335 97.1
实施例206 OD 1335 98.7
实施例207 OD 405 95.4
实施例208 OD 885 97.9
实施例209 OD 585 98.2
实施例210 OD 735 97.9
实施例211 OD 585 96.6
实施例212 OD 315 91.7
实施例213 OD 225 93.4
实施例214 OD 1560 98.3
实施例215 OD 2040 97.7
实施例216 OD 1740 95.8
实施例217 OD 1890 98.1
实施例218 OD 1740 99.6
实施例219 OD 1470 96.2
实施例220 OD 1380 96.8
实施例221 OD 1560 98.3
实施例222 OD 2040 98.1
实施例223 OD 1740 96.7
实施例224 OD 1890 97.2
实施例225 OD 1740 94.0
实施例226 OD 1470 96.9
实施例227 OD 1380 96.2
6%环吡氟草酮OD   90 22.5
25%噁草酮EC   150 21.5
50%扑草净WP   300 28.8
50%特丁净SC   750 17.5
70%嗪草酮WP   90 21.7
70%氨唑草酮WDG   180 22.4
50%绿麦隆WP   750 29.3
50%异丙隆SC   750 23.7
40%哒草特SC   750 20.0
10%噻吩磺隆WP   15 19.9
480克/升氟乐灵EC   225 22.4
48%仲丁灵EC   300 28.7
330克/升二甲戊灵EC   900 21.9
40%呋草酮SC   120 28.4
50%吡氟酰草胺WP   120 20.4
10%氟吡酰草胺SC   45 22.5
800克/升苄草丹EC   1200 20.8
500克/升野麦畏SC   1200 28.9
50%乙草胺乳油   270 22.7
50%丁草胺乳油   750 21.6
50%丙草胺乳油   450 29.9
960克/升异丙甲草胺乳油   600 22.3
960克/升精异丙甲草胺乳油   450 22.0
20%氟噻草胺SC   180 27.5
850克/升砜吡草唑WG   90 14.5
经过大量试验和探索,本发明意外地发现,所述组合物用于防除看麦娘、日本看麦娘、大穗看麦娘、多花黑麦草、菵草、硬草、早熟禾、棒头草、蜡烛草、牛繁缕、繁缕、蚤缀、苘麻、鸭舌草、碎米荠、荠菜、播娘蒿、猪殃殃、婆婆纳等杂草,具有令人惊讶的、意想不到的增效作用,并且除草活性比使用单个除草剂的活性预期总和,以及单个或其中任两个除草剂组合的活性更为显著,这种增效作用在低剂量下表现更为显著,可降低用药量,降低对环境的污染,且合理复配降低了农用成本,对ALS抑制剂、PPO抑制剂、激素类除草剂抗性杂草高效,具有很好的应用前景。同时经过测试在小麦田、玉米田、水稻田、花生、甘蔗、高粱、谷子、马铃薯、油菜、大豆、棉花、蔬菜、早熟禾、高羊茅、结缕草等草坪和作物显示良好的选择性和优异的增效作用,可以开发成广泛市场价值的除草剂混剂。

Claims (10)

  1. 一种含有环吡氟草酮的三元除草组合物,其特征在于,包括除草有效量的活性成分A、活性成分B和活性成分C,其中,
    活性成分A为环吡氟草酮;
    活性成分B和C分别选自以下类型中的任一种化合物和与其不同类型的另一种化合物:
    PPO类抑制剂:噁草酮;
    PSⅡ类抑制剂:扑草净、特丁净、嗪草酮、氨唑草酮、绿麦隆、异丙隆、哒草特;
    ALS类抑制剂:噻吩磺隆;
    微管组装抑制剂:氟乐灵、仲丁灵、二甲戊灵;
    PDS类抑制剂:呋草酮、吡氟酰草胺、氟吡酰草胺;
    脂类合成(非乙酰辅酶A羧化酶)抑制剂:苄草丹、野麦畏;
    VLCFA类抑制剂:乙草胺、丁草胺、丙草胺、异丙甲草胺、精异丙甲草胺、氟噻草胺、砜吡草唑。
  2. 根据权利要求1所述的三元除草组合物,其特征在于,A、B和C的重量比为1~200:1~1000:1~1000和1~150:5~800:5~800;优选为3~100:10~500:10~500和5~80:20~300:20~300;更优选为8~60:50~200:50~200和10~50:60~100:60~100。
  3. 根据权利要求1或2所述的三元除草组合物,其特征在于,所述除草组合物中A、B和C的质量百分含量占总量的1-95%,优选10-80%。
  4. 根据权利要求1至3任意一项所述的三元除草组合物,其特征在于,所述除草组合物中还包括常规助剂。
  5. 根据权利要求4所述的三元除草组合物,其特征在于,所述常规助剂包括载体、表面活性剂。
  6. 根据权利要求1至5任意一项所述的三元除草组合物,其特征在于,所述除草组合物进一步包括至少一种安全剂。
  7. 根据权利要求1至6任意一项所述的三元除草组合物,其特征在于,所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂、水乳剂或微乳剂。
  8. 如权利要求1至7任意一项所述三元除草组合物在防治作物中有害杂草上的应用。
  9. 一种防治不想要的植物生长的方法,其包括将权利要求1至7任意一项所述三元除草组合物施用于植物、植物部位、植物种子或植物生长的区域。
  10. 根据权利要求9所述的方法,其特征在于,用于选择性防治作物中的有害植物。
PCT/CN2018/105271 2018-07-09 2018-09-12 一种含有环吡氟草酮的三元除草组合物及其应用 WO2020010690A1 (zh)

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CN109418274B (zh) * 2018-06-01 2022-12-06 青岛清原化合物有限公司 一种三元除草组合物及其应用
CN111362913B (zh) * 2018-12-25 2021-03-12 青岛清原化合物有限公司 一种无定形态环吡氟草酮三乙醇胺盐及其制备方法和用途
CN111362914B (zh) * 2018-12-25 2021-03-12 青岛清原化合物有限公司 环吡氟草酮三乙醇胺盐b晶型及其制备方法和用途
CN110463716B (zh) * 2019-07-04 2020-07-21 福建凯立生物制品有限公司 一种中生菌素可湿性粉剂及其制备方法
CN111264537A (zh) * 2020-04-13 2020-06-12 辽宁海佳农化有限公司 一种含特丁净的除草组合物
CN111567523A (zh) * 2020-06-22 2020-08-25 安徽喜田生物科技有限公司 一种包含氟乐灵和丙草胺的除草组合物
CN112790192A (zh) * 2021-02-03 2021-05-14 安徽润农腾辉生物科技有限公司 一种包含氟吡酰草胺的三元除草组合物

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