WO2019227250A1 - 一种液体口罩贴及防霾抗菌口罩 - Google Patents

一种液体口罩贴及防霾抗菌口罩 Download PDF

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Publication number
WO2019227250A1
WO2019227250A1 PCT/CN2018/000227 CN2018000227W WO2019227250A1 WO 2019227250 A1 WO2019227250 A1 WO 2019227250A1 CN 2018000227 W CN2018000227 W CN 2018000227W WO 2019227250 A1 WO2019227250 A1 WO 2019227250A1
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Prior art keywords
weight
parts
mask
liquid
liquid mask
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PCT/CN2018/000227
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English (en)
French (fr)
Inventor
刘雅璇
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Liu Yaxuan
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Publication of WO2019227250A1 publication Critical patent/WO2019227250A1/zh

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Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A41D13/05—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
    • A41D13/11—Protective face masks, e.g. for surgical use, or for use in foul atmospheres
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
    • C09D105/02—Dextran; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Definitions

  • the invention belongs to the technical field of preventive medical auxiliary consumables, and particularly relates to a liquid mask sticker, and further discloses a preparation method thereof, and a haze-proof and antibacterial mask containing the liquid mask sticker.
  • Volatile organic compounds generally refer to organic compounds that are easy to evaporate or volatilize under specific environmental conditions. VOCs easily generate PM2.5 and ozone, which causes photochemical smog and aggravates haze, which seriously pollutes the environment and affects human health.
  • Acid gas refers to a gas that can react with alkali to form a salt.
  • the acid gases in the polluted air include carbon dioxide, chlorine, hydrogen sulfide, nitrogen dioxide, hydrogen chloride, sulfur dioxide, and the like.
  • acid gases are the culprits of the greenhouse effect and acid rain.
  • polluting gases such as smoking and kitchen oil fume pose a greater threat to health.
  • Air droplets, droplets, and dust in the air are important transmission routes of respiratory infections.
  • respiratory diseases transmitted through the air such as influenza, measles, chicken pox, rubella, epidemic encephalomyelitis, and atypical pneumonia. Therefore, the prevention of infectious diseases of the respiratory tract is mainly to cut off its transmission route, change the quality of the air and the environment, and control or kill the bacteria, viruses and pathogenic microorganisms in the air.
  • masks In order to prevent fine particles, harmful gases, bacteria and viruses from invading the human body, masks have become an indispensable product in people's lives.
  • the main material currently used for masks is traditional non-woven fabrics.
  • the diameter of this material is about ten microns. Even tens of microns, the larger pore size can only filter larger particles, and it has a poor interception effect on fine particles, harmful gases, and bacterial viruses, which cannot meet people's needs.
  • anti-particulate matter and bacteriostatic masks are mainly implemented by adding a filter core layer and / or a bacteriostatic layer in the inner layer of the mask.
  • the filter core layer mostly contains adsorbents such as activated carbon for adsorbing polluted particles.
  • the bacteriostatic layer is mostly prepared by impregnating a bacteriostatic solution.
  • the functional mask can effectively remove a variety of polluting particles and has a certain antibacterial and antiviral effect.
  • the filter element is disposed on the inner layer of the mask.
  • the mask sticker is developed on the basis of the existing functional masks.
  • the application principle is to place the filter layer and / or the bacteriostatic layer that was originally placed on the inner layer of the mask on the outside of the mask.
  • the mask can be repeatedly used repeatedly by replacing the corresponding filter element layer and / or the bacteriostatic layer, which effectively reduces the consumption cost.
  • most of the existing mask stickers are sewn or pasted on the outside of the mask, and there are defects of complicated sewing operations or inadequate adhesion, which limits the convenience and effectiveness of the use of the mask stickers.
  • the technical problem to be solved by the present invention is to provide a liquid mask sticker to solve the problems of poor convenience and effectiveness of the mask sticker in the prior art;
  • the second technical problem to be solved by the present invention is to provide a haze-proof antibacterial mask including the liquid mask sticker.
  • the preparation materials of the liquid mask sticker include: 20-30 parts by weight of konjac glucomannan, 5-10 parts by weight of sugar palm powder, and sodium alginate 5-10 parts by weight, 3-8 parts by weight of bacterial cellulose, 30-50 parts by weight of ethanol, 5-12 parts by weight of propolis, 1-3 parts by weight of laurazone, 1-5 parts by weight of glycerol, ethyl acetate 3-8 parts by weight of ester, 2-6 parts by weight of cyclodextrin, 5-10 parts by weight of functional particles, 5-10 parts by weight of traditional Chinese medicine bacteriostatic agent, 80-120 parts by weight of purified water.
  • the raw materials for preparing the liquid mask include 25 parts by weight of konjac glucomannan, 8 parts by weight of sugar palm powder, 8 parts by weight of sodium alginate, 5 parts by weight of bacterial cellulose, 40 parts by weight of ethanol, and propolis 9 Part by weight, 2 parts by weight of laurazolone, 3 parts by weight of glycerol, 5 parts by weight of ethyl acetate, 4 parts by weight of cyclodextrin, 8 parts by weight of functional particles, 8 parts by weight of Chinese medicine bacteriostatic agent, and purified water 100 Parts by weight.
  • the functional particles include at least one of nano activated carbon, bentonite, nano silica, and nano titanium dioxide.
  • the traditional Chinese medicine bacteriostatic agent includes at least one of Yinchen, Sophora flavescens, Zhimu, and Daqingye.
  • the invention also discloses a method for preparing the liquid mask patch, which comprises the following steps:
  • step (3) adding the premix obtained in step (1) to the film-forming liquid, and stirring thoroughly to obtain a mixed glue solution;
  • step (4) Add the selected functional particles and the traditional Chinese medicine concentrated solution obtained in step (4) to the mixed glue solution while stirring, and stir well to obtain.
  • the amount of water added is 2-3 times the total amount of the Chinese medicine bacteriostatic agent.
  • the method for preparing the liquid mask patch further includes the step of making the obtained liquid mask patch into a spray according to a conventional technique.
  • the invention also discloses a method for using the liquid mask sticker, comprising the steps of coating or spraying the liquid mask sticker on the outer surface of a conventional mask for curing and forming a film.
  • the invention also discloses a haze-proof antibacterial mask, which comprises a mask body and a mask sticker adhered to the outer side of the body of the mask, and the mask sticker is formed by curing the liquid mask sticker into a film.
  • the invention also discloses a method for preparing the anti-haze antibacterial mask, which comprises the steps of applying or spraying the liquid mask on the outside surface of the body of the mask, and curing and forming a film.
  • the liquid mask sticker of the present invention uses konjac glucomannan, sugar palm powder, sodium alginate, bacterial cellulose, ethanol, propolis, laurazolone, glycerol, ethyl acetate, and cyclodextrin as raw materials. And add functional particles with adsorption and / or photocatalytic decomposition, and traditional Chinese medicine ingredients with antibacterial and / or antiviral effects of traditional Chinese medicine, so that the liquid mask sticker can be quickly cured to form a film on the outer surface of existing conventional masks To form an effective filtering barrier against pollutant particles and / or bacteria and viruses, which can effectively prevent the inhalation of pollutants such as haze particles and effectively prevent the spread of bacteria and viruses.
  • the liquid mask sticker of the present invention has a short curing film-forming time, and has good adhesion and breathability after curing, and high daily comfort.
  • the liquid mask sticker of the present invention has a wide range of raw materials and manufacturing costs. Lower.
  • the liquid mask sticker of the present invention When used, it only needs to be directly coated or sprayed on the outer side of a conventional mask to be cured, and then torn off directly after use. Since the mask sticker filters pollutant particles in the air, the daily use of The mask is free from pollution and can be reused, which effectively reduces the use cost and has better economic benefits.
  • the raw materials used in the following examples of the present invention are all known raw materials in the prior art, and either commercially available products or extraction methods known in the prior art may be used.
  • the bacterial cellulose may be purchased commercially.
  • the product can also be obtained by fermentation and secretion of model strains in accordance with known methods in the prior art; for example, the konjac glucomannan can be purchased from a commercial product, or it can be extracted by itself according to the methods described in the prior art.
  • the raw materials for the preparation of the liquid mask in this embodiment include: 20 kg of konjac glucomannan, 10 kg of sugar palm powder, 5 kg of sodium alginate, 8 kg of bacterial cellulose, 30 kg of ethanol, 12 kg of propolis, 1 kg of laurazone, and glycerol 5kg, ethyl acetate 3kg, cyclodextrin 6kg, functional particles 5kg, traditional Chinese medicine bacteriostatic agent 10kg, purified water 80kg.
  • the functional particles are nano-silica and nano-titanium dioxide particles with a mass ratio of 1: 1.
  • the traditional Chinese medicine bacteriostatic agent includes Yinchen and Daqingye in a mass ratio of 1: 1.
  • step (3) adding the premix obtained in step (1) to the film-forming liquid, and stirring thoroughly at normal temperature to obtain a mixed glue solution;
  • step (4) Add the selected functional particles and the traditional Chinese medicine concentrated solution obtained in step (4) to the mixed glue solution while stirring, and stir well to obtain.
  • the liquid mask sticker described in this embodiment can be filled into a gel dosage form. When in use, it can be directly coated on the outer side of an existing mask and cured at room temperature for 1-2 minutes to form a film. Or it can be filled into a spray device. When in use, spray directly on the outer side of the existing mask, and solidify at room temperature for 2-3 minutes to form a film. The mask is simply torn off after use.
  • the raw materials for the preparation of the liquid mask in this embodiment include: 30 kg of konjac glucomannan, 5 kg of sugar palm powder, 10 kg of sodium alginate, 3 kg of bacterial cellulose, 50 kg of ethanol, 5 kg of propolis, 3 kg of laurinone, and glycerol 1 kg, ethyl acetate 8 kg, cyclodextrin 2 kg, functional particles 10 kg, traditional Chinese medicine bacteriostatic agent 5 kg, purified water 120 kg.
  • the functional particles are nano-active carbon.
  • the traditional Chinese medicine bacteriostatic agent includes Yinchen, Sophora flavescens and Daqingye with a mass ratio of 1: 1.
  • the preparation method of the liquid mask sticker in this embodiment is the same as that in Embodiment 1.
  • the method for using the liquid mask sticker in this embodiment is the same as that in the first embodiment.
  • the raw materials for the preparation of the liquid mask in this embodiment include: 25 kg of konjac glucomannan, 8 kg of sugar palm powder, 8 kg of sodium alginate, 5 kg of bacterial cellulose, 40 kg of ethanol, 9 kg of propolis, 2 kg of laurazolone, and glycerol. 3kg, ethyl acetate 5kg, cyclodextrin 4kg, functional particles 8kg, Chinese medicine bacteriostatic agent 8kg, purified water 100kg.
  • the functional particles include nano-active carbon, nano-silica, and nano-titanium dioxide in a mass ratio of 2: 1: 1.
  • the traditional Chinese medicine bacteriostatic agent includes Yinchen, Sophora flavescens, Zhimu and Daqingye in a mass ratio of 1: 1: 1: 1.
  • the preparation method of the liquid mask sticker in this embodiment is the same as that in Embodiment 1.
  • the method for using the liquid mask sticker in this embodiment is the same as that in the first embodiment.
  • the raw materials for the preparation of the liquid mask in this embodiment include: 22 kg of konjac glucomannan, 9 kg of sugar palm powder, 6 kg of sodium alginate, 6 kg of bacterial cellulose, 35 kg of ethanol, 10 kg of propolis, 1.5 kg of laurinone 4 kg of alcohol, 4 kg of ethyl acetate, 5 kg of cyclodextrin, 6 kg of functional particles, 9 kg of Chinese medicine bacteriostatic agent, and 90 kg of purified water.
  • the functional particles include nano activated carbon, nano silica and nano titanium dioxide in a mass ratio of 1: 1.
  • the traditional Chinese medicine bacteriostatic agent comprises Sophora flavescens, Zhimu and Daqingye in a mass ratio of 1: 1.
  • the preparation method of the liquid mask sticker in this embodiment is the same as that in Example 1, and the liquid mask sticker is made into a spray type according to conventional methods and processes in the prior art.
  • the liquid mask is applied, it is directly sprayed on the outer surface of the existing mask, and can be formed into a film by curing at room temperature for 2-3 minutes. The mask is simply torn off after use.
  • the raw materials for the preparation of the liquid mask in this embodiment include: 28 kg of konjac glucomannan, 7 kg of sugar palm powder, 9 kg of sodium alginate, 4 kg of bacterial cellulose, 45 kg of ethanol, 7 kg of propolis, 2.5 kg of laurazide, and III. 2 kg of alcohol, 6 kg of ethyl acetate, 3 kg of cyclodextrin, 9 kg of functional particles, 6 kg of traditional Chinese medicine bacteriostatic agent, and 110 kg of purified water.
  • the functional particles include nano activated carbon, nano silica and nano titanium dioxide in a mass ratio of 1: 1.
  • the traditional Chinese medicine bacteriostatic agent includes Yinchen, Sophora flavescens, Zhimu and Daqingye in a mass ratio of 1: 1: 1: 1.
  • the preparation method of the liquid mask sticker in this embodiment is the same as that in Example 1, and the liquid mask sticker is made into a spray type according to conventional methods and processes in the prior art.
  • the liquid mask is applied, it is directly sprayed on the outer surface of the existing mask, and can be formed into a film by curing at room temperature for 2-3 minutes. The mask is simply torn off after use.
  • the liquid mask paste prepared in the above Example 3 was applied to the outer surface of commercially available masks made of different materials, and the coating thickness was controlled to be about 5 mm.
  • the curing film formation time of the liquid mask paste was observed at ordinary room temperature, and Observe the adhesiveness and breathability of the mask after sticking the mask for daily wearing for 12 hours. The test results are recorded in Table 1 below.
  • the liquid mask sticker of the present invention has a short curing time and good film forming performance, and has good air permeability during use, and because the mask sticker film is bonded to the outer side of the mask, It does not come into direct contact with the mouth of the human body, and has better safety.
  • the liquid mask prepared in Example 3 was applied on a sterile watch glass, and the thickness of the application was controlled to be about 5 mm.
  • Example 3 The liquid mask prepared in Example 3 was applied to the outer surface of a commercially available cotton mask, and the thickness of the coating was controlled to be about 5 mm. The film was cured for 1-2 minutes. A cotton mask without applying the liquid mask is used as a comparative example.
  • Test equipment portable American TSI8530 dust meter Dust PM2.5 direct tester, test at 25 °C.
  • test environment PM2.5 test value ⁇ g / m 3 PM2.5 removal rate% Indoor air 35.2 Zh Indoor air / Example 3 mask 1.5 95.7 Indoor air / cotton masks 19.5 44.6
  • liquid mask sticker of the present invention has a better effect of filtering particulate matter, and can effectively inhale haze particles.
  • the liquid mask used in the present invention is tested for degradability after being removed.
  • the experimental results show that the liquid mask described in the present invention has good degradability after use and has an environmentally friendly advantage.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Textile Engineering (AREA)
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Abstract

属于预防医学辅助耗材技术领域，具体涉及一种液体口罩贴，及其制备方法，以及含有液体口罩贴的防霾抗菌口罩。液体口罩贴，以魔芋葡甘聚糖、桄榔粉、海藻酸钠、细菌纤维素、乙醇、蜂胶、月桂氮卓酮、丙三醇、乙酸乙酯、环糊精为制备原料，并添加具有吸附和/或光触媒分解作用的功能性粒子，以及具有中药抑菌和/或抗病毒作用的中药成分，使得液体口罩贴可在现有常规口罩的外侧表面快速固化成膜，形成对污染物颗粒和/或细菌、病毒的有效滤过屏障，能够有效防止雾霾颗粒等污染物的吸入，并能有效防止细菌及病毒的飞沫传播。

Description

一种液体口罩贴及防霾抗菌口罩 技术领域
本发明属于预防医学辅助耗材技术领域，具体涉及一种液体口罩贴，并进一步公开其制备方法，以及含有该液体口罩贴的防霾抗菌口罩。
背景技术
随着我国经济持续高速发展，城市化和工业化进程日益加快，工业生产、日常发电、汽车尾气排放等过程向空气中排放了大量残留物使空气中的颗粒物浓度大大增加，特别是PM10(空气中直径小于10um的极细颗粒物)和PM2.5(空气中直径小于2.5um的极细颗粒物)，它们对空气质量和能见度等都产生了重要的影响。目前，影响我国城市空气质量的主要污染物是大气中漂浮的PM2.5颗粒，严重威胁着人们的健康。除此之外，空气中还漂浮着大量的致病细菌、病毒及多种有害气体等，都严重威胁着人类的健康。
挥发性有机物(VOCs)，通常是指特定环境条件下容易蒸发或挥发的有机化合物，VOCs容易生成PM2.5和臭氧，导致光化学烟雾并加重灰霾，严重污染环境和影响人类健康。酸性气体，指能与碱作用生成盐的气体，污染空气中的酸性气体有二氧化碳、氯气、硫化氢、二氧化氮、氯化氢、二氧化硫等。酸性气体作为造成环境污染和导致生态破坏的主要气体是温室效应和酸雨泛滥的元凶。此外，如吸烟，厨房油烟等污染性气体也对健康构成较大的威胁。
再者，空气中漂浮的细菌、病毒等微生物也是呼吸道感染的重要来源，空气及空气中的飞沫、飞沫粒及尘埃是呼吸道感染的重要传播途径。经空气中传播的呼吸道疾病很多，如流行性感冒、麻疹、水痘、风疹、流行性 脑脊髓膜炎、非典型肺炎等。因此，预防呼吸道传染病主要是切断它的传播途径，改变空气及环境质量，控制或杀灭空气中的细菌、病毒及致病微生物。
研究表明，污染气体会对经呼吸***(肺部)、皮肤表皮、呼吸道***、神经***、免疫能力、肝脏、内分泌***等产生毒害作用，使人出现易疲劳、紧张等不良反应，并且降低工作、严重影响学习效率。长期处于空气质量较差的环境，不仅会引起呼吸功能下降、呼吸道症状加重，还会导致慢性支气管炎、支气管哮喘、肺气肿等疾病，严重的还会导致肺癌、鼻咽癌患病率的增加
为了防止细颗粒物、有害气体、细菌及病毒对人体的侵害，口罩成了人们生活中的必备品，目前的口罩主要应用的材料为传统的非织造布，这种材料的直径约十几微米甚至几十微米，孔径较大只能过滤较大的颗粒，对细颗粒物、有害气体、细菌病毒的拦截效果较差，无法满足人们的需求。
随着空气污染物的日益严重，各种专业的防雾霾、抑菌的功能性口罩应运而生。现有技术中防颗粒物及抑菌口罩主要是通过在口罩内层中增设过滤芯层和/或抑菌层实现的，所述过滤芯层多含有活性炭等吸附物用于吸附污染颗粒物之用，所述抑菌层多通过浸渍抑菌液的形式制得。上述功能性口罩能够有效去除多种污染颗粒物并具有一定的抑菌抑病毒作用。但是，诸如此类的功能性口罩中滤芯设置于口罩内层，一方面有吸附颗粒泄露导致误吸入的问题，另一方面也存在着不易清洗及解吸附困难的缺陷。另有一些功能性口罩是采用具有抑菌性能的材料编织制得，虽然解决了抑菌等问题，但依然存在多次清洗后抑菌及污染物吸附能力下降的问题。因此，现有技术中几乎所有的功能性口罩都无法实现长期使用的问题，即便是价格高昂的功能性口罩，使用次数也是有限制的，造成了较大的资源浪费，也给消费者造成较大的经济负担。
口罩贴是在现有功能性口罩基础上发展而来，其应用原理即是将原本置于口罩内层的滤芯层和/或抑菌层设置于口罩的外侧，在起到防雾霾及抑 菌效果的同时，可以通过更换相应的滤芯层和/或抑菌层实现口罩的多次反复使用，有效降低了消费成本。但是，现有口罩贴多是通过缝制或是黏贴于口罩的外侧，存在着缝制操作复杂或者黏贴不紧密的缺陷，限制了口罩贴使用的便捷性和有效性。
发明内容
为此，本发明所要解决的技术问题在于提供一种液体口罩贴，以解决现有技术中口罩贴的便捷性和有效性较差的问题；
本发明所要解决的第二个技术问题在于提供一种包含所述液体口罩贴的防霾抗菌口罩。
为解决上述技术问题，本发明所述的一种液体口罩贴，所述液体口罩贴的制备原料包括：魔芋葡甘聚糖20-30重量份、桄榔粉5-10重量份、海藻酸钠5-10重量份、细菌纤维素3-8重量份、乙醇30-50重量份、蜂胶5-12重量份、月桂氮卓酮1-3重量份、丙三醇1-5重量份、乙酸乙酯3-8重量份、环糊精2-6重量份、功能性粒子5-10重量份、中药抑菌剂5-10重量份、纯化水80-120重量份。
优选的，所述液体口罩贴的制备原料包括：魔芋葡甘聚糖25重量份、桄榔粉8重量份、海藻酸钠8重量份、细菌纤维素5重量份、乙醇40重量份、蜂胶9重量份、月桂氮卓酮2重量份、丙三醇3重量份、乙酸乙酯5重量份、环糊精4重量份、功能性粒子8重量份、中药抑菌剂8重量份、纯化水100重量份。
所述功能性粒子包括纳米活性碳、膨润土、纳米二氧化硅、纳米二氧化钛中的至少一种。
所述中药抑菌剂包括茵陈、苦参、知母、大青叶中的至少一种。
本发明还公开了一种制备所述液体口罩贴的方法，包括如下步骤：
(1)取选定量的乙醇、蜂胶、月桂氮卓酮、丙三醇、乙酸乙酯和环糊 精进行混匀，得到预混料；
(2)取选定量的所述纯化水加热，保温后降温至40-50℃，随后向处理后的所述纯化水中加入选定量的所述魔芋葡甘聚糖、桄榔粉、海藻酸钠和细菌纤维素，充分搅拌至分散均匀，得到成膜液；
(3)将步骤(1)中制得的所述预混料加入至所述成膜液中，充分搅拌得到混合胶液；
(4)取选定量的所述中药抑菌剂混合，并加水进行煎煮，收集煎煮液浓缩得到中药浓缩液；
(5)将选定的所述功能性粒子与步骤(4)中得到的中药浓缩液边搅拌边加入所述混合胶液中，充分搅拌均匀，即得。
所述步骤(4)中，所述水的加入量为所述中药抑菌剂总量的2-3倍量。
所述的制备所述液体口罩贴的方法，还包括将所得液体口罩贴按照常规技术制成喷雾剂的步骤。
本发明还公开了所述的液体口罩贴的使用方法，包括将所述液体口罩贴经涂布或喷涂于常规口罩外侧面进行固化成膜的步骤。
本发明还公开了一种防霾抗菌口罩，包括口罩本体及黏贴于所述口罩本体外侧面的口罩贴，所述口罩贴由所述的液体口罩贴经固化成膜形成。
本发明还公开了一种制备所述防霾抗菌口罩的方法，包括将所述液体口罩贴经涂布或喷涂于所述口罩本体外侧面，并进行固化成膜的步骤。
本发明所述液体口罩贴，以魔芋葡甘聚糖、桄榔粉、海藻酸钠、细菌纤维素、乙醇、蜂胶、月桂氮卓酮、丙三醇、乙酸乙酯、环糊精为制备原料，并添加具有吸附和/或光触媒分解作用的功能性粒子，以及具有中药抑菌和/或抗病毒作用的中药成分，使得所述液体口罩贴可在现有常规口罩的外侧表面快速固化成膜，形成对污染物颗粒和/或细菌、病毒的有效滤过屏障，能够有效防止雾霾颗粒等污染物的吸入，并能有效防止细菌及病毒的飞沫传播。同时，本发明所述液体口罩贴的固化成膜时间较短，且固化后 粘结性及透气性较好，日常使用舒适度较高；本发明所述液体口罩贴的原料来源广泛，制造成本较低。
本发明所述液体口罩贴使用时只需直接涂布或喷涂于常规口罩的外侧面固化，并在使用后直接撕掉即可，由于口罩贴过滤了空气中的污染物颗粒，使得日常使用的口罩免受污染，可以重复使用，有效降低了使用成本，具有较好的经济效益。
具体实施方式
本发明下述实施例中所选用原料均为现有技术中的已知原料，采用市售产品或采用现有技术中已知的提取方法均可以，如所述细菌纤维素既可以购买市售产品也可按照现有技术已知方法以模式菌株经发酵分泌并提取获得；又如所述魔芋葡甘聚糖既可以购买市售产品，也可以按照现有技术记载的方法自行提取。
实施例1
本实施例所述液体口罩贴的制备原料包括：魔芋葡甘聚糖20kg、桄榔粉10kg、海藻酸钠5kg、细菌纤维素8kg、乙醇30kg、蜂胶12kg、月桂氮卓酮1kg、丙三醇5kg、乙酸乙酯3kg、环糊精6kg、功能性粒子5kg、中药抑菌剂10kg、纯化水80kg。
所述功能性粒子为质量比1∶1的纳米二氧化硅和纳米二氧化钛粒子。
所述中药抑菌剂包括质量比为1∶1的茵陈和大青叶。
本实施例所述液体口罩贴的制备方法，包括如下步骤：
(1)取选定量的乙醇、蜂胶、月桂氮卓酮、丙三醇、乙酸乙酯和环糊精进行混匀，得到预混料；
(2)取选定量的所述纯化水加热至80-90℃，保温2-3h后降温至40-50℃，随后向处理后的所述纯化水中加入选定量的所述魔芋葡甘聚糖、桄榔粉、海藻酸钠和细菌纤维素，充分搅拌至分散均匀，得到成膜液；
(3)将步骤(1)中制得的所述预混料加入至所述成膜液中，常温下充分搅拌得到混合胶液；
(4)取选定量的所述中药抑菌剂粉碎并混合，并加入占所述中药总量2-3重量倍量的水进行煎煮1-2次，收集煎煮液浓缩至原煎煮液体积的1/10，得到中药浓缩液；
(5)将选定的所述功能性粒子与步骤(4)中得到的中药浓缩液边搅拌边加入所述混合胶液中，充分搅拌均匀，即得。
本实施例所述液体口罩贴可以灌装成凝胶剂型，在使用时，直接涂布于现有口罩的外侧面，常温下固化1-2min即可成膜；或者灌装至喷雾装置中，在使用时，直接喷涂于现有口罩的外侧面，常温下固化2-3min即可成膜。所述口罩贴在使用后只需直接撕掉即可。
实施例2
本实施例所述液体口罩贴的制备原料包括：魔芋葡甘聚糖30kg，桄榔粉5kg、海藻酸钠10kg、细菌纤维素3kg、乙醇50kg、蜂胶5kg、月桂氮卓酮3kg、丙三醇1kg、乙酸乙酯8kg、环糊精2kg、功能性粒子10kg、中药抑菌剂5kg、纯化水120kg。
所述功能性粒子为纳米活性碳。
所述中药抑菌剂包括质量比为1∶1∶1的茵陈、苦参和大青叶。
本实施例所述液体口罩贴的制备方法同实施例1。
本实施例所述液体口罩贴的使用方法同实施例1。
实施例3
本实施例所述液体口罩贴的制备原料包括：魔芋葡甘聚糖25kg、桄榔粉8kg、海藻酸钠8kg、细菌纤维素5kg、乙醇40kg、蜂胶9kg、月桂氮卓酮2kg、丙三醇3kg、乙酸乙酯5kg、环糊精4kg、功能性粒子8kg、中药抑菌剂8kg、纯化水100kg。
所述功能性粒子包括质量比2∶1∶1的纳米活性碳、纳米二氧化硅和纳米二氧化钛。
所述中药抑菌剂包括质量比为1∶1∶1∶1的茵陈、苦参、知母和大青叶。
本实施例所述液体口罩贴的制备方法同实施例1。
本实施例所述液体口罩贴的使用方法同实施例1。
实施例4
本实施例所述液体口罩贴的制备原料包括：魔芋葡甘聚糖22kg、桄榔粉9kg、海藻酸钠6kg、细菌纤维素6kg、乙醇35kg、蜂胶10kg、月桂氮卓酮1.5kg、丙三醇4kg、乙酸乙酯4kg、环糊精5kg、功能性粒子6kg、中药抑菌剂9kg、纯化水90kg。
所述功能性粒子包括质量比1∶1∶1的纳米活性碳、纳米二氧化硅和纳米二氧化钛。
所述中药抑菌剂包括质量比为1∶1∶1的苦参、知母和大青叶。
本实施例所述液体口罩贴的制备方法同实施例1，并将所述液体口罩贴按照现有技术常规手段和工艺制成喷雾剂型。所述液体口罩贴在使用时，直接喷涂于现有口罩的外侧面，常温下固化2-3min即可成膜。所述口罩贴在使用后只需直接撕掉即可。
实施例5
本实施例所述液体口罩贴的制备原料包括：魔芋葡甘聚糖28kg、桄榔粉7kg、海藻酸钠9kg、细菌纤维素4kg、乙醇45kg、蜂胶7kg、月桂氮卓酮2.5kg、丙三醇2kg、乙酸乙酯6kg、环糊精3kg、功能性粒子9kg、中药抑菌剂6kg、纯化水110kg。
所述功能性粒子包括质量比1∶1∶1的纳米活性碳、纳米二氧化硅和纳米二氧化钛。
所述中药抑菌剂包括质量比为1∶1∶1∶1的茵陈、苦参、知母和大青叶。
本实施例所述液体口罩贴的制备方法同实施例1，并将所述液体口罩贴按照现有技术常规手段和工艺制成喷雾剂型。所述液体口罩贴在使用时，直接喷涂于现有口罩的外侧面，常温下固化2-3min即可成膜。所述口罩贴在使用后只需直接撕掉即可。
实验例
1、透气性及成模性
以上述实施例3中制得的液体口罩贴涂布于不同材质的市售口罩的外侧面，控制涂布厚度约为5mm，于日常室温下观察所述液体口罩贴的固化成膜时间，并观察黏贴有所述口罩贴后的口罩进行日常佩戴12h的粘结性及透气性，测试结果记录于下表1。
表1口罩贴的透气性及成膜性结果
材质 固化时间 粘结性 透气性
无纺布口罩 1-2min 无开裂 良好
棉布口罩 1-2min 无开裂 良好
海绵口罩 1-2min 无开裂 良好
从上表结果可见，本发明所述液体口罩贴固化时间较短且成膜性能较好，而且使用时透气性较好，并且由于所述口罩贴成膜粘结于所述口罩的外侧面，不与人体口部直接接触，安全性较好。
2、抑菌性
以上述实施例3中制得的液体口罩贴涂布于无菌的表面皿上，控制涂布厚度约为5mm。将培养好的大肠杆菌液(菌数约为10 6个/ml)滴到所述液体口罩贴形成的膜上10mm直径的圆形中，然后放入37℃恒温培养箱内培养。分别在经过1、2、3、4、5、6h后在显微镜下观测滴液圆(R＝5mm) 中的菌落，菌落的数量变化表示防菌、抑菌性，每个试样做三份平行样取平均值。
实验结果表面，随着时间变化菌落数明显减少，说明本发明所述液体口罩贴具有较好的抑菌性能。
3、防雾霾测试
以上述实施例3中制得的液体口罩贴涂布于市售棉布口罩的外侧面，控制涂布厚度约为5mm，固化1-2min成膜。并以未涂布所述液体口罩贴的棉布口罩作为对比例。
测试仪器：便携式美国TSI8530粉尘仪Dust pm2.5直测仪，于25℃下进行测试。
国际卫生组织(WHO)认为空气中pm2.5在10μg/m 3以下是允许的，测试结果见表2。
表2防雾霾测试结果
测试环境 PM2.5测试值μg/m 3 PM2.5去除率％
室内空气 35.2  
室内空气/实施例3口罩 1.5 95.7
室内空气/棉布口罩 19.5 44.6
从上表结果可见，本发明所述液体口罩贴具有较好的过滤颗粒物的效果，能有效方式雾霾颗粒吸入。
4、生物降解性
将本发明中使用过的液体口罩贴取下后进行降解性测试，实验结果表面，本发明所述液体口罩贴在使用后的可降解性较好，具有环境友好型优势。
显然，上述实施例仅仅是为清楚地说明所作的举例，而并非对实施方式的限定。对于所属领域的普通技术人员来说，在上述说明的基础上还可 以做出其它不同形式的变化或变动。这里无需也无法对所有的实施方式予以穷举。而由此所引伸出的显而易见的变化或变动仍处于本发明创造的保护范围之中。

Claims (10)

  1. 一种液体口罩贴，其特征在于，所述液体口罩贴的制备原料包括：魔芋葡甘聚糖20-30重量份、桄榔粉5-10重量份、海藻酸钠5-10重量份、细菌纤维素3-8重量份、乙醇30-50重量份、蜂胶5-12重量份、月桂氮卓酮1-3重量份、丙三醇1-5重量份、乙酸乙酯3-8重量份、环糊精2-6重量份、功能性粒子5-10重量份、中药抑菌剂5-10重量份、纯化水80-120重量份。
  2. 根据权利要求1所述的液体口罩贴，其特征在于，所述液体口罩贴的制备原料包括：魔芋葡甘聚糖25重量份、桄榔粉8重量份、海藻酸钠8重量份、细菌纤维素5重量份、乙醇40重量份、蜂胶9重量份、月桂氮卓酮2重量份、丙三醇3重量份、乙酸乙酯5重量份、环糊精4重量份、功能性粒子8重量份、中药抑菌剂8重量份、纯化水100重量份。
  3. 根据权利要求1或2所述的液体口罩贴，其特征在于，所述功能性粒子包括纳米活性碳、膨润土、纳米二氧化硅、纳米二氧化钛中的至少一种。
  4. 根据权利要求1-3任一项所述的液体口罩贴，其特征在于，所述中药抑菌剂包括茵陈、苦参、知母、大青叶中的至少一种。
  5. 一种制备权利要求1-4任一项所述液体口罩贴的方法，其特征在于，包括如下步骤：
    (1)取选定量的乙醇、蜂胶、月桂氮卓酮、丙三醇、乙酸乙酯和环糊精进行混匀，得到预混料；
    (2)取选定量的所述纯化水加热，保温后降温至40-50℃，随后向处理后的所述纯化水中加入选定量的所述魔芋葡甘聚糖、桄榔粉、海藻酸钠和细菌纤维素，充分搅拌至分散均匀，得到成膜液；
    (3)将步骤(1)中制得的所述预混料加入至所述成膜液中，充分搅拌得到混合胶液；
    (4)取选定量的所述中药抑菌剂混合，并加水进行煎煮，收集煎煮液浓缩得到中药浓缩液；
    (5)将选定的所述功能性粒子与步骤(4)中得到的中药浓缩液边搅拌边加入所述混合胶液中，充分搅拌均匀，即得。
  6. 根据权利要求5所述的制备所述液体口罩贴的方法，其特征在于，所述步骤(4)中，所述水的加入量为所述中药抑菌剂总量的2-3倍量。
  7. 根据权利要求5或6所述的制备所述液体口罩贴的方法，其特征在于，还包括将所得液体口罩贴按照常规技术制成喷雾剂的步骤。
  8. 权利要求1-4任一项所述的液体口罩贴的使用方法，其特征在于，包括将所述液体口罩贴经涂布或喷涂于常规口罩外侧面进行固化成膜的步骤。
  9. 一种防霾抗菌口罩，其特征在于，包括口罩本体及黏贴于所述口罩本体外侧面的口罩贴，所述口罩贴由权利要求1-4任一项所述的液体口罩贴经固化成膜形成。
  10. 一种制备权利要求9所述防霾抗菌口罩的方法，其特征在于，包括将所述液体口罩贴经涂布或喷涂于所述口罩本体外侧面，并进行固化成膜的步骤。
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