WO2019126956A1 - 一种装饰涂料及其喷涂方法 - Google Patents

一种装饰涂料及其喷涂方法 Download PDF

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WO2019126956A1
WO2019126956A1 PCT/CN2017/118347 CN2017118347W WO2019126956A1 WO 2019126956 A1 WO2019126956 A1 WO 2019126956A1 CN 2017118347 W CN2017118347 W CN 2017118347W WO 2019126956 A1 WO2019126956 A1 WO 2019126956A1
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parts
water
decorative
propylene glycol
thickener
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PCT/CN2017/118347
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French (fr)
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姚锋平
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姚锋平
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Priority to PCT/CN2017/118347 priority Critical patent/WO2019126956A1/zh
Publication of WO2019126956A1 publication Critical patent/WO2019126956A1/zh
Priority to PH12020551086A priority patent/PH12020551086A1/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers

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  • the invention relates to the field of construction, home improvement, kitchen appliance, furniture, automobile, and various industrial product processing, and particularly relates to a decorative coating and a spraying method thereof.
  • Decorative panels especially metal decorative panels, have both unique gloss and strength, as well as strong corrosion resistance. Therefore, since the advent of the decorative panels in the 1970s, they have been widely used in the fields of building materials, chemicals, automobiles, electronics, and arts and crafts.
  • the metal decorative board In order to color the metal decorative board, especially the use of traditional paint, it requires a certain pretreatment, including the following steps: degreasing, chemical cleaning, whitewashing, water washing, air drying and baking, among which, the whitening process is mostly adopted.
  • the layer is destroyed and the corrosion resistance is lowered, and it is easy to leave marks on the surface of the substrate by hand touch.
  • Cida patent CN104742435A discloses a "slip-resistant acid-proof and anti-corrosion stainless steel plate", which comprises a stainless steel plate body.
  • the stainless steel plate body is provided with a plurality of mutually staggered anti-slip stripes.
  • the upper surface of the stainless steel plate body has a pickling layer, and the pickling layer is outside. It is coated with a fluorocarbon paint anti-corrosion layer, the surface of the anti-corrosion layer is coated with a PVC (polyvinyl chloride) protective film, and the lower surface of the stainless steel plate body is provided with a polishing layer.
  • the stainless steel plate has good acid and corrosion resistance and anti-slip effect, and the inner surface of the stainless steel pipe is polished, which is better for industrial buildings.
  • this stainless steel plate is only silver-white, and the color is relatively simple. It can not meet the pursuit of diversified colors pursued by modern people, reducing the overall quality and modernity, and the damage to the environment is more serious.
  • the technical problem to be solved by the invention is that the existing decorative panels, especially the metal decorative panels, are not easy to be colored, and the color is relatively simple, which cannot meet the pursuit of diversified colors pursued by modern people, and reduces the overall quality and modernity, and The damage to the environment is more serious.
  • the technical solution adopted by the present invention provides a decorative coating comprising the following raw materials by weight: 11 to 21 parts of water, 60 to 70 parts of acrylic resin, and defoaming agent 1 ⁇ 2 parts, 1 to 2 parts of thickener, 3 to 4 parts of glycerin, 1 to 5 parts of color paste, and 1 to 2 parts of amine water.
  • the method further comprises: 3 to 5 parts of dipropylene glycol methyl ether and 0.05 to 0.2 parts of dimethylethanolamine.
  • the invention also discloses a spraying method for a decorative coating, which adopts the above-mentioned decorative coating, uniformly sprays the surface of the decorative board, and is placed in an oven or a drying tunnel for baking, and finally heat preservation.
  • the spraying time is 5 minutes
  • the baking temperature is 150 to 200 ° C
  • the curing is performed at room temperature for 60 minutes.
  • the spraying time is 5 minutes
  • the baking temperature is 50 to 60 ° C
  • the curing is performed at room temperature for 120 minutes.
  • the invention Compared with the traditional paint, the invention has the advantages of oil resistance, water resistance, salt spray resistance, acid resistance, alkali resistance, impact resistance, friction resistance and fire resistance while improving the wear resistance and acid and alkali resistance of the decorative board. And so on, can meet the pursuit of modern people's diversified colors, improve the overall quality and modernity of home improvement, kitchen appliances, furniture, automobiles, industrial products, and reduce the damage to the environment, more environmentally friendly.
  • the invention provides a decorative coating comprising the following raw materials by weight: 11-21 parts of water, 60-70 parts of acrylic resin, 1-2 parts of antifoaming agent, 1-2 parts of thickener, glycerin 3 to 4 parts, 1 to 5 parts of color paste, and 1 to 2 parts of amine water.
  • the decorative coating further comprises the following parts by weight of raw materials: 1 to 2 parts of ethylene glycol butyl ether, propylene glycol or propylene glycol diethyl ether or a mixture of two to 2 parts, and ethanolamine 0.05 to 0.2 parts.
  • the above metal products are steel, stainless steel, copper, aluminum alloy, zinc alloy and the like.
  • the decorative coating further comprises the following raw materials by weight: 3 to 5 parts of dipropylene glycol methyl ether and 0.05 to 0.2 parts of dimethylethanolamine.
  • the decorative paint comprises the following parts by weight:
  • the decorative paint comprises the following parts by weight:
  • the decorative paint comprises the following parts by weight:
  • the decorative paint comprises the following parts by weight:
  • the decorative coating includes the following parts by weight:
  • the decorative coating includes the following parts by weight:
  • the decorative coating includes the following parts by weight:
  • the decorative coating includes the following parts by weight:
  • the first embodiment and the fifth embodiment are preferred embodiments, and the comparison of the components is balanced, and the ratio can be adjusted as needed.
  • the invention also provides a spraying method for a decorative paint, which adopts the above decorative paint to uniformly spray the surface of the decorative plate of steel, stainless steel, copper, aluminum alloy, zinc alloy, wood, plastic, etc., and is placed in an explosion-proof oven. Or bake the oven for baking, and finally keep warm.
  • the spraying time is 5 minutes
  • the baking temperature is 150-200 ° C
  • the curing is performed at room temperature for 60 minutes.
  • the baking temperature of steel, stainless steel, and copper is 200 ° C
  • the baking temperature of the aluminum alloy is 150-160 ° C
  • the baking temperature of the zinc alloy is 150-160 ° C.
  • the spraying time is 5 minutes
  • the baking temperature is 50 to 60 ° C
  • the curing is performed at room temperature for 120 minutes.
  • the invention improves the wear resistance and acid and alkali resistance of the decorative board, and makes the decorative board have the characteristics of oil resistance, water resistance, salt spray resistance, acid resistance, alkali resistance, impact resistance, friction resistance and fire prevention, and can meet the diversity of modern people.
  • the pursuit of color improve the overall quality and modernity of home improvement, kitchen appliances, furniture, automobiles, industrial products, and reduce the damage to the environment, more environmentally friendly.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

一种装饰涂料及其喷涂方法，其中，所述装饰涂料包括以下重量份数的原料：水11～21份，丙烯酸树脂60-70份，消泡剂1～2份，增稠剂1～2份，甘油3～4份，色浆1～5份，胺水1～2份，丙二醇2-3份，丙二醇***2-3份，乙二醇丁醚1-2份。与较传统的油漆相比，在提高装饰板的耐磨、耐酸碱性能的同时，使装饰板具有耐油、耐水、耐盐雾、耐酸、耐碱、耐冲击、耐摩擦以及防火等特点，能够满足现代人的多元化颜色的追求，提高了家装，厨电，家具，汽车，各工业产品的整体品质跟现代感，而且减轻了对环境的破坏，更加环保。

Description

一种装饰涂料及其喷涂方法 技术领域
本发明涉及建筑，家装，厨电，家具，汽车，各工业产品加工领域，具体涉及一种装饰涂料及其喷涂方法。
背景技术
装饰板尤其是金属装饰板，既具备特有的光泽和强度，又具有很强的耐腐蚀性能。因此，装饰板从20世纪70年代问世以来，在建材、化工、汽车、电子工业以及工艺美术等领域得到了广泛的应用。
目前为了给金属装饰板上色，尤其是使用传统油漆上色，需要经过一定的预处理，包括以下步骤：脱脂、化学清洗、洗白、水洗、风干以及烘烤，其中，洗白工艺多采用高浓度(约40％-60％)硝酸，危险系数较高，对人体和环境危害大，且洗白后的基材多为灰白色并常伴有消光不良；在洗白后常常会因其钝化层被破坏而耐蚀性下降，且用手触摸很容易在基材的表面留下痕迹。
中国发明专利CN104742435A公开了一种“防滑耐酸防腐蚀不锈钢板”，包括不锈钢板本体，不锈钢板本体上设置有复数个相互交错的防滑条纹，不锈钢板本体上表面具有酸洗层，酸洗层外涂覆有氟碳漆防腐层，防腐层表面包覆有PVC(聚氯乙烯)保护膜，不锈钢板本体下表面设置有抛光层。该不锈钢板能够起到良好的耐酸防腐蚀以及防滑效果，并且对不锈钢管内表面进行抛光处理，用于工业建筑时效果更好。但这种不锈钢板只有银白色，颜色比较单一，不能够满足现代人追求的多元化颜色的追求，降低了整体品质跟现代感，而且，对环境的破坏比较严重。
发明内容
本发明所要解决的技术问题是现有的装饰板尤其是金属装饰板不易上色，颜色比较单一，不能够满足现代人追求的多元化颜色的追求，降低了整体品质跟现代感的，而且对环境的破坏比较严重的问题，。
为了解决上述技术问题，本发明所采用的技术方案是提供了一种装饰涂料，所述装饰涂料包括以下重量份数的原料：水11～21份，丙烯酸树脂60～70份，消泡剂1～2份，增稠剂1～2份，甘油3～4份，色浆1～5份，胺水1～2份。
在上述方案中，还包括：乙二醇丁醚1～2份，丙二醇或丙二醇***或两者的混合物2～3份，乙醇胺0.05～0.2份。
在上述方案中，还包括：二丙二醇甲醚3～5份，二甲基乙醇胺0.05～0.2份。
在上述方案中，水11份，丙烯酸树脂70份，乙二醇丁醚2份，丙二醇或丙二醇***或两者的混合物2.9份，乙醇胺0.1份，消泡剂2份，增稠剂2份，甘油3份，色浆5份，胺水2份。
在上述方案中，水21份，丙烯酸树脂60份，乙二醇丁醚1.98份，丙二醇或丙二醇***或两者的混合物3份，乙醇胺0.18份，消泡剂1份，增稠剂1.98份，甘油3.9份，色浆4.98份，胺水1.98份。
在上述方案中，水18份，丙烯酸树脂67.17份，乙二醇丁醚1份，丙二醇或丙二醇***或两者的混合物2.98份，乙醇胺0.05份，消泡剂1.9份，增稠剂1.9份，甘油4份，色浆1份，胺水2份。
在上述方案中，水16份，丙烯酸树脂68.4份，乙二醇丁醚1.8份，丙二醇或丙二醇***或两者的混合物2份，乙醇胺0.2份，消泡剂1.8份，增稠剂1份，甘油3.8份，色浆4份，胺水1份。
在上述方案中，水11份，丙烯酸树脂70份，二丙二醇甲醚3.9份，二甲基乙醇胺0.1份，消泡剂2份，增稠剂2份，甘油4份，色浆5份， 胺水2份。
在上述方案中，水21份，丙烯酸树脂60份，二丙二醇甲醚5份，二甲基乙醇胺0.2份，消泡剂1.8份，增稠剂1.3份，甘油3.9份，色浆4.9份，胺水1.9份。
在上述方案中，水18.05份，丙烯酸树脂68份，二丙二醇甲醚3份，二甲基乙醇胺0.05份，消泡剂1份，增稠剂1.9份，甘油3份，色浆4份，胺水1份。
在上述方案中，水19份，丙烯酸树脂67份，二丙二醇甲醚4.8份，二甲基乙醇胺0.16份，消泡剂1.8份，增稠剂1份，甘油3.34份，色浆1份，胺水1.9份。
本发明还公开了一种装饰涂料的喷涂方法，采用上述的装饰涂料，对对装饰板表面进行均匀的喷涂处理，并放置在烤箱或烘道进行烘烤，最后进行保温。
在上述方案中，当所述装饰板为金属制品时，喷涂时间为5分钟，烘烤温度为150～200℃，常温固化60分钟。
在上述方案中，当所述装饰板为包括木料或者塑料在内的材料时，喷涂时间为5分钟，烘烤温度为50～60℃，常温固化120分钟。
本发明，与较传统的油漆相比，在提高装饰板的耐磨、耐酸碱性能的同时，使装饰板具有耐油、耐水、耐盐雾、耐酸、耐碱、耐冲击、耐摩擦以及防火等特点，能够满足现代人的多元化颜色的追求，提高了家装，厨电，家具，汽车，各工业产品的整体品质跟现代感，而且减轻了对环境的破坏，更加环保。
具体实施方式
下面结合具体实施例对本发明予以详细说明。
本发明提供的一种装饰涂料，该装饰涂料包括以下重量份数的原料： 水11～21份，丙烯酸树脂60～70份，消泡剂1～2份，增稠剂1～2份，甘油3～4份，色浆1～5份，胺水1～2份。
当装饰板为金属制品时，该装饰涂料还包括以下重量份数的原料：乙二醇丁醚1～2份，丙二醇或丙二醇***或两者的混合物2～3份，乙醇胺0.05～0.2份。上述金属制品为钢铁，不锈钢，铜，铝合金，锌合金等制品。
当装饰板为包括木料或者塑料在内的材料时，该装饰涂料还包括以下重量份数的原料：二丙二醇甲醚3～5份，二甲基乙醇胺0.05～0.2份。
具体实施例：
实施例一
当装饰板为金属制品时，该装饰涂料包括以下重量份数的原料：
水11份，丙烯酸树脂70份，乙二醇丁醚2份，丙二醇或丙二醇***或两者的混合物2.9份，乙醇胺0.1份，消泡剂2份，增稠剂2份，甘油3份，色浆5份，胺水2份。
实施例二
当装饰板为金属制品时，该装饰涂料包括以下重量份数的原料：
水21份，丙烯酸树脂60份，乙二醇丁醚1.98份，丙二醇或丙二醇***或两者的混合物3份，乙醇胺0.18份，消泡剂1份，增稠剂1.98份，甘油3.9份，色浆4.98份，胺水1.98份。
实施例三
当装饰板为金属制品时，该装饰涂料包括以下重量份数的原料：
水18份，丙烯酸树脂67.17份，乙二醇丁醚1份，丙二醇或丙二醇***或两者的混合物2.98份，乙醇胺0.05份，消泡剂1.9份，增稠剂1.9份，甘油4份，色浆1份，胺水2份。
实施例四
当装饰板为金属制品时，该装饰涂料包括以下重量份数的原料：
水16份，丙烯酸树脂68.4份，乙二醇丁醚1.8份，丙二醇或丙二醇 ***或两者的混合物2份，乙醇胺0.2份，消泡剂1.8份，增稠剂1份，甘油3.8份，色浆4份，胺水1份。
实施例五
当装饰板为包括木料或者塑料在内的材料时，该装饰涂料包括以下重量份数的原料：
水11份，丙烯酸树脂70份，二丙二醇甲醚3.9份，二甲基乙醇胺0.1份，消泡剂2份，增稠剂2份，甘油4份，色浆5份，胺水2份。
实施例六
当装饰板为包括木料或者塑料在内的材料时，该装饰涂料包括以下重量份数的原料：
水21份，丙烯酸树脂60份，二丙二醇甲醚5份，二甲基乙醇胺0.2份，消泡剂1.8份，增稠剂1.3份，甘油3.9份，色浆4.9份，胺水1.9份。
实施例七
当装饰板为包括木料或者塑料在内的材料时，该装饰涂料包括以下重量份数的原料：
水18.05份，丙烯酸树脂68份，二丙二醇甲醚3份，二甲基乙醇胺0.05份，消泡剂1份，增稠剂1.9份，甘油3份，色浆4份，胺水1份。
实施例八
当装饰板为包括木料或者塑料在内的材料时，该装饰涂料包括以下重量份数的原料：
水19份，丙烯酸树脂67份，二丙二醇甲醚4.8份，二甲基乙醇胺0.16份，消泡剂1.8份，增稠剂1份，甘油3.34份，色浆1份，胺水1.9份。
其中实施例一和实施例五为较为理想的最佳实施例，各组分的配比较为均衡，也可根据需要对比例进行调整。
本发明还提供了一种装饰涂料的喷涂方法，采用上述的装饰涂料，对 钢铁，不锈钢，铜，铝合金，锌合金，木料，塑料等装饰板表面进行均匀的喷涂处理，并放置在防爆烤箱或烘道进行烘烤，最后进行保温。
当装饰板为钢铁，不锈钢，铜，铝合金，锌合金等金属制品时，喷涂时间为5分钟，烘烤温度为150～200℃，常温固化60分钟。具体的，钢铁、不锈钢和铜的烘烤温度为200℃，铝合金的烘烤温度为150-160℃，锌合金的烘烤温度为150-160℃。
当所述装饰板为包括木料或者塑料在内的材料时，喷涂时间为5分钟，烘烤温度为50～60℃，常温固化120分钟。本发明，与较传统的装饰涂料相比，在对装饰板进行喷涂处理时，不同材质的装饰板采用不同组分的装饰涂料，而且不同材质的装饰板的喷涂时间和固化温度也不相同，本发明在提高装饰板的耐磨、耐酸碱性能的同时，使装饰板具有耐油、耐水、耐盐雾、耐酸、耐碱、耐冲击、耐摩擦以及防火等特点，能够满足现代人的多元化颜色的追求，提高家装，厨电，家具，汽车，各工业产品的整体品质跟现代感，而且减轻了对环境的破坏，更加环保。
本发明不局限于上述最佳实施方式，任何人应该得知在本发明的启示下作出的结构变化，凡是与本发明具有相同或相近的技术方案，均落入本发明的保护范围之内。

Claims (14)

  1. 一种装饰涂料，其特征在于，所述装饰涂料包括以下重量份数的原料：水11～21份，丙烯酸树脂60～70份，消泡剂1～2份，增稠剂1～2份，甘油3～4份，色浆1～5份，胺水1～2份。
  2. 如权利要求1所述的装饰涂料，其特征在于，还包括：乙二醇丁醚1～2份，丙二醇或丙二醇***或两者的混合物2～3份，乙醇胺0.05～0.2份。
  3. 如权利要求1所述的装饰涂料，其特征在于，还包括：二丙二醇甲醚3～5份，二甲基乙醇胺0.05～0.2份。
  4. 如权利要求2所述的装饰涂料，其特征在于，水11份，丙烯酸树脂70份，乙二醇丁醚2份，丙二醇或丙二醇***或两者的混合物2.9份，乙醇胺0.1份，消泡剂2份，增稠剂2份，甘油3份，色浆5份，胺水2份。
  5. 如权利要求2所述的装饰涂料，其特征在于，水21份，丙烯酸树脂60份，乙二醇丁醚1.98份，丙二醇或丙二醇***或两者的混合物3份，乙醇胺0.18份，消泡剂1份，增稠剂1.98份，甘油3.9份，色浆4.98份，胺水1.98份。
  6. 如权利要求2所述的装饰涂料，其特征在于，水18份，丙烯酸树脂67.17份，乙二醇丁醚1份，丙二醇或丙二醇***或两者的混合物2.98份，乙醇胺0.05份，消泡剂1.9份，增稠剂1.9份，甘油4份，色浆1份，胺水2份。
  7. 如权利要求2所述的装饰涂料，其特征在于，水16份，丙烯酸树脂68.4份，乙二醇丁醚1.8份，丙二醇或丙二醇***或两者的混合物2份，乙醇胺0.2份，消泡剂1.8份，增稠剂1份，甘油3.8份，色浆4份，胺水1份。
  8. 如权利要求3所述的装饰涂料，其特征在于，水11份，丙烯酸树 脂70份，二丙二醇甲醚3.9份，二甲基乙醇胺0.1份，消泡剂2份，增稠剂2份，甘油4份，色浆5份，胺水2份。
  9. 如权利要求3所述的装饰涂料，其特征在于，水21份，丙烯酸树脂60份，二丙二醇甲醚5份，二甲基乙醇胺0.2份，消泡剂1.8份，增稠剂1.3份，甘油3.9份，色浆4.9份，胺水1.9份。
  10. 如权利要求3所述的装饰涂料，其特征在于，水18.05份，丙烯酸树脂68份，二丙二醇甲醚3份，二甲基乙醇胺0.05份，消泡剂1份，增稠剂1.9份，甘油3份，色浆4份，胺水1份。
  11. 如权利要求3所述的装饰涂料，其特征在于，水19份，丙烯酸树脂67份，二丙二醇甲醚4.8份，二甲基乙醇胺0.16份，消泡剂1.8份，增稠剂1份，甘油3.34份，色浆1份，胺水1.9份。
  12. 一种装饰涂料的喷涂方法，其特征在于，采用如权利要求1～11任一项所述的装饰涂料，对装饰板表面进行均匀的喷涂处理，并放置在烤箱或烘道进行烘烤，最后进行保温。
  13. 如权利要求12所述的装饰涂料的喷涂方法，其特征在于，当所述装饰板为金属制品时，喷涂时间为5分钟，烘烤温度为150～200℃，常温固化60分钟。
  14. 如权利要求12所述的装饰涂料的喷涂方法，其特征在于，当所述装饰板为包括木料或者塑料在内的材料时，喷涂时间为5分钟，烘烤温度为50～60℃，常温固化120分钟。
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