WO2019112720A1 - Alkylphenol detergents - Google Patents

Abstract

The disclosed technology relates to hydrocarbyl- (e.g. alkyl-) phenol detergents and their salts, where the hydrocarbyl group includes moieties equivalent to 5 to 10 carbon branched polyene compounds. Such compounds and their salts are useful as lubricant additives.

Description

TITLE

Alkylphenol Detergents

BACKGROUND OF THE INVENTION

[0001] The disclosed technology relates to hydrocarbyl- (e.g. alkyl-) phenol detergents and their salts having oligomers of branched olefins, including branched polyenes, such as terpenes. Such compounds and their salts are useful as lubricant additives.

[0002] Phenol-based detergents are known. Among these are phenates based on phenolic monomers, linked with sulfur bridges or alkylene bridges such as meth ylene linkages derived from formaldehyde. The phenolic monomers themselves are typically substituted with an aliphatic hydrocarbyl group to provide a measure of oil solubility. The hydrocarbyl groups may be alkyl groups, and, historically, do- decylphenol (or propylene tetramer-substituted phenol) has been widely used. An early reference to basic sulfurized polyvalent metal phenates is U.S. Patent 2,680,96, Walker et ak, June 1, 1954; see also U.S. Patent 3,372, 1 16, Meinhardt, March 6, 1968.

[0003] Recently, however, certain alkylphenols and products prepared from them have come under increased scrutiny due to their association as potential endo crine disruptive materials. In particular, alkylphenol detergents which are based on phenols alkylated with oligomers of propylene, specifically propylene tetramer (or tetrapropenyl), may contain residual alkyl phenol species. There is interest, therefore, in developing alkyl-substituted phenol detergents, for uses in lubricants, fuels, and as industrial additives, which contain a reduced or eliminated amount of dodecylphe- nol component and other substituted phenols having propylene oligomer substituents of 10 to 15 carbon atoms. Nevertheless, it is desirable that the products should have similar oil-solubility parameters as phenates prepared from Cl 0-15 propylene oligo mers.

[0004] There have been several efforts to prepare phenate detergents that do not contain C_n alkyl phenols derived from oligomers of propylene. U.S. Patent 7,435,709, Stonebraker et ak, October 14, 2008, discloses a linear alkylphenol de rived detergent substantially free of endocrine disruptive chemicals. It comprises a salt of a reaction product of (1) an olefin having at least 10 carbon atoms, where greater than 90 mole % of the olefin is a linear C20-C30 n-alpha olefin, and wherein less than 10 mole % of the olefin is a linear olefin of less than 20 carbon atoms, and less than 5 mole %of the olefin a branched chain olefin of 18 carbons or less, and (2) a hydroxyaromatic compound

[0005] U.S. Application 2011/0190185, Sinquin et al, August 4, 201 1, dis closes an overbased salt of an oligomerized alkylhydroxyaromatic compound. The alkyl group is derived form an olefin mixture comprising propylene oligomers having an initial boiling point of at least about 195 °C and a final boiling point of greater than 325 °C. The propylene oligomers may contain a distribution of carbon atoms that comprise at least about 50 weight percent of C 14 to C20 carbon atoms.

[0006] U.S. Application 201 1/0124539, Sinquin et al, May 26, 2011, dis closes an overbased, sulfurized salt of an alkylated hydroxyaromatic compound. The alkyl substituent is a residue of at least one isomerized a-olefm having from 15 to about 99 wt. % branching. The hydroxyaromatic compound may be phenol, cresols, xylenols, or mixtures thereof.

[0007] U.S. Application 2011/01 18160, Campbell et al., May 19, 2011, dis- closes an alkylated hydroxyaromatic compound substantially free of endocrine dis ruptive chemicals. An alkylated hydroxyaromatic compound is prepared by reacting a hydroxyaromatic compound with at least one branched olefmic propylene oligomer having from about 20 to about 80 carbon atoms. Suitable hydroxyaromatic com pounds include phenol, catechol, resorcinol, hydroquinone, pyrogallol, cresol, and the like.

[0008] U.S. Application 2010/0029529, Campbell et al., February 4, 2010, discloses an overbased salt of an oligomerized alkylhydroxyaromatic compound. The alkyl group is derived from an olefin mixture comprising propylene oligomers having an initial boing point of at least about 195 °C and a final boiling point of no more than about 325 °C. Suitable hydroxyaromatic compounds include phenol, catechol, resorcinol, hydroquinone, pyrogallol, cresol, and the like.

[0009] U.S. Application 2008/0269351, Campbell et al., October 30, 2008, discloses an alkylated hydroxyaromatic compound substantially free of endocrine disruptive chemicals, prepared by reacting a hydroxyaromatic compound with a branched olefmic oligomer having from about 20 to about 80 carbon atoms.

[0010] U.S. Application 2017/0211008, Walker et al., July 27, 2017, discloses metal salts and overbased metal salts of an oligomerized alkylphenol compound. The alkyl group is derived from oligomers of an olefin compound containing 3 to 8 carbon atoms, and wherein the polyolefin-derived alkyl group comprises at least 30 mol per cent of an olefin with 4 or more carbon atoms, especially n-butene.

[0011] WO/PCT application 2013/059173, Cook et al., discloses discloses an overbased salt of an oligomerized alkylhydroxyaromatic compound. The alkyl group is a combination of very short hydrocarbyl group (i.e. 1 to 8 carbon atoms) and a long hydrocarbyl group (at least about 25 carbon atoms). Suitable compounds incude those made from a mixture of para-cresol and polyisobutylene-substituted phenol.

[0012] Other general technology includes that of U.S. Patent 6,310,009, Car- rick et al., October 30, 2001 , which discloses salts of the general structure

where R¹ may be an alkyl group of 1 to 60 carbon atoms, e.g., 9 to 18 carbon atoms. It is understood that R¹ will normally comprise a mixture of various chain lengths, so that the foregoing numbers will normally represent an average number of carbon at oms in the Rl groups (number average).

SUMMARY OF THE INVENTION

[0013] The disclosed technology, may solve at least one problem of providing a phenolic material with appropriate oil solubility, providing anti-wear performance, frictional performance, providing oxidation performance, viscosity performance, and detergency (characteristic of moderate chain length alkyl groups). In one embodi- ment the disclosed technology may also solve the problem of containing C12 alkyl phenol moieties i.e., the disclosed technology may be free from or substantially free from C12 alkyl phenol moieties typically formed from oligomerisation or polymeri sation of propylene.

[0014] One aspect of the disclosed technology relates to an alkylphenol deter gent composition comprising at least one phenol moiety having a hydrocarbyl group attached thereto. The hydrocarbyl group can include at least one oligomer having monomers equivalent, in some embodiments, to 5 to 10 carbon atom branched olefins, and in some embodiments, more particularly to 5 to 10 carbon atom branched poly enes. In embodiments, the monomers making up the oligomers can be equivalent to isoprene. The oligomer itself can be equivalent to a terpene, and more particularly can be equivalent to any of (2E, 5E,7E,l0E)-3, 6,10-trimethyldodeca-2, 5,7,10-tet- raene; (3E,7E,l0E)-2,7, l0-trimethyldodeca-l,3,7,l0-tetraene; (E)-2,9-dimethyl-5- (prop-l-ene-2-yl)deca-l,3,8-triene; (3E,6E, l0E)-2,6, l0-trimethyldodeca-l,3,6, l0- tetraene; (E)-7, 11 -dimethyl-3 -methylenedodeca- 1,6, 10-triene; (6E, 10E)-7, 11, 15 -tri- methyl-3 -methylenehexadeca- 1,6, 10, 14-tetraene; (3E,6E, 10E)-3,7, 1 l,l 5-tetra- methylhexadeca- 1,3,6,10, 1 -pentaene; (6E, 10E, 14E)-7, 11 , 14-trimethyl-3 -methylene hexadeca- 1,6, 10, 14-tetraene; (3E,9E, 13E)-2, 10, 13 -trimethyl-6-(prop- 1 -en-2-yl)pen- tadeca- 1,3,9, 13 -tetraene .

[0015] The oligomer can also be equivalent to a hydrogenated (partial or com plete) form of a terpene, such as, for example, any of 3,7,1 l-trimethyldodec-l-ene; 2,6, l0-trimethyldodec-2-ene; (E)-3,7, l l-trimethyldodec-2-ene; 2,6-dimethyl- 10- methylenedodecane; (E)-2,6,l0-trimethyldodec-6-ene; (E)-3,7,l l-trimethyldodec-3- ene; (E)-2,6, l0-trimethyldodec-5-ene; 3,7, 1 l-trimethyldodeca-l, lO-diene

[0016] In embodiments, the hydrocarbyl unit of the alkylphenol detergent can contain from 15 to 60 carbon atoms.

[0017] The alkylphenol detergent can include alkylphenol moiety equivalent to any of 4-(3,7, l l-trimethyldodecan-2-yl)phenol; 4-(2,6,l0-trimethyldodecan-2- yl)phenol; 4-(3,7, l l-trimethyldodec-l0-en-2-yl)phenol; 4-(2,6,l0-trimethyldodec- 1 l-en-2-yl)phenol.

[0018] The alkylphenol detergent can be a sulfur-bridged phenate detergent, a sulfur-free alkylene-bridged phenate detergent, a salicylate detergent, or mixtures thereof. The alkylphenol detergent can include one or more alkali metals, one or more alkaline earth metals, or mixtures thereof. The alkylphenol detergent compo sition can be overbased, and in embodiments, have a metal ratio of at least 1.5, at least 5, or at least 7.

[0019] In an embodiment, the alklylphenol detergent can be an overbased sul fur-coupled phenate detergent with a metal ratio of at least 1.5.

[0020] In an embodiment, the alkylphenol detergent composition can be a sul fur-bridged phenate represented by the structure

wherein each R is an aliphatic hydrocarbyl group equivalent to an oligomer of iso- prene, higher branched olefins, or mixtures thereof, that contains 15 to 60 carbon atoms; each y can be 1 to 4; and n = 0 to 8, or 1 to 6, or 1 to 4, or 2 to 4.

[0021] In an embodiment, the alkylphenol detergent can be a neutral or over based salt of alkylsalicylic acid.

[0022] In an embodiment, the alkylphenol detergent can be an alkylsalicylate represented by the structure

where R is an aliphatic hydrocarbyl group equivalent to an oligomer of isoprene, higher branched olefins, or mixtures thereof, and wherein the hydrocarbyl group con tains 15 to 60 carbon atoms. [0023] Another aspect of the technology relates to a lubricating composition having (a) an oil of lubricating viscosity and (b) the alkylphenol detergent composi- tion as described herein. In embodiments, lubricating composition can be substan tially free to free of an alkylphenol-containing detergent wherein the alkylphenol is derived from oligomers of propene. The lubricating composition can also include other additives, such as, for example, other detergents besides the instant alkylphenol detergent, zinc dialkyldithiophosphate, dispersants, antiwear agents, extreme pres- sure agents, corrosion inhibitors, etc.

[0024] A further aspect of the technology relates to methods of lubricating a mechanical device, for example, by supplying to the device the lubricating composi- tion described herein containing the alkylphenol detergent. The mechanical device can be, for example, an internal combustion engine, an automotive driveline device, such as a transmission or an axle, or an off-highway vehicle. The technology could also be employed in industrial applications, such as industrial hydraulics.

DETAILED DESCRIPTION OF THE INVENTION

[0025] Various preferred features and embodiments will be described below by way of non-limiting illustration.

[0026] The disclosed technology includes an alkylphenol detergent composi tion (or just alkylphenol for short), a lubricating composition containing the alkylphe- nol, a method for lubricating a mechanical device with a lubricating composition containing the alkylphenol, and a use of the alkylphenol, all of which will be more particularly described herein.

[0027] One aspect of the disclosed technology is an alkylphenol detergent composition. The alkylphenol detergent will include at least one phenol moiety with at least one hydrocarbyl group attached thereto. Those of ordinary skill in the art can observe a chemical composition and readily imagine the moieties to which the com position may be derived from. As used herein, reference to the phenol moiety means that moiety of the alkylphenol detergent composition one of ordinary skill in the art could imagine would be derived from a phenol, i.e., of Formula I. Formula I

[0028] The alkylphenol will also include a hydrocarbyl group. As used herein, the term "hydrocarbyl group" is used in its ordinary sense, which is well-known to those skilled in the art. Specifically, it refers to a group having a carbon atom directly attached to the remainder of the molecule and having predominantly hydrocarbon char acter. Examples of hydrocarbyl groups include, for example: hydrocarbon substituents, including aliphatic, alicyclic, and aromatic substituents; substituted hydrocarbon sub- stituents, that is, substituents containing non-hydrocarbon groups which, in the context of this invention, do not alter the predominantly hydrocarbon nature of the substituent; and hetero substituents, that is, substituents which similarly have a predominantly hy drocarbon character but contain other than carbon in a ring or chain.

[0029] While the hydrocarbyl group can include elements of non-hydrocarbyl character (i.e., nitrogen, halogens, etc.), in many embodiments the hydrocarbyl group can be of substantially, or even completely, hydrocarbon character. In some embodi ments, the hydrocarbyl group can be of substantially or completely aliphatic character.

[0030] The hydrocarbyl group can comprise, consist essentially of, or consist of at least one oligomer, and the at least one oligomer itself can comprise, consist essentially of, or consist of monomers equivalent to 5 to 10 carbon atom branched olefins. By employing the terminology“equivalent to,” it is recognized that the ref erenced compound, in this case the monomers of the oligomer, are slightly altered in their final state from their original state; for example, an oligomerized monomer ver sus the lone monomer. In other words, the hydrocarbyl group, when looked at in discreet units, contains identifiable oligomer units, and the identifiable oligomer units can be further broken down into identifiable alkyl units that, as a monomer would be considered a 5 to 10 carbon atom branched olefin. [0031] A branched olefin, as used herein, refers to an alkyl chain having at least one double bond and at least one tertiary carbon atom. Without limiting the branched olefin, examples of such branched olefins can be represented by the follow- ing example branched olefin formulas.

where Ra, Rb, and Rc can be H or a lower Ci to C₅ alkyl group; n and m can be, independently, integers of 0 to 6, with the proviso that n+m is from 1 to 6; and the olefin has from 5 to 10 carbon atoms. An oligomer of such a branched olefin could be, for example, oligomers of the following formula.

where Ra, Rb, Rc, m and n are as above, and y is an integer of 2 to 18, or 2 to 15, or 2 to 12.

[0032] The branched olefin can also be polyenes. That is, the hydrocarbyl group can comprise, consist essentially of, or consist of at least one oligomer, and the at least one oligomer itself can comprise, consist essentially of, or consist of mon omers equivalent to 5 to 10 carbon atom branched polyene compounds. As used herein a polyene is a poly-unsaturated alkylene compound having at least 2 double bonds (also known as a diene), and in some cases 3, 4, or 5 double bonds.

[0033] Branched polyene compounds can be described as alkyl chains having at least two double bonds in the chain, and at least one tertiary carbon atom. Although the polyene compound may include more than 2 double bonds, an example branched polyene compound may be a branched conjugated diene represented by the following formula,

where Ri, R₂, R₃, and R₄ are independently H, or lower Ci to C5 alkyl groups; with the proviso that at least one of Ri, R₂, R₃, and R₄ is an alkyl group and that taken together the conjugated diene has a total of from 5 to 10 carbon atoms.

[0034] The at least one oligomer in the hydrocarbyl group can be oligomerized from 5 to 10 carbon atom branched olefin/polyenes, or the oligomer may be prepared in some other manner. For example, the oligomer may be formed by 1, 2-monomer addition or 1, 4-monomer addition. In one embodiment, oligomers of 5 to 10 carbon atom branched polyenes may formed by 1, 4-addition of the monomers, followed by partial hydrogenation of the resulting material to form a mono-olefmic alkylating agent, which could then react with phenol to form the oligomeric alkyl phenol. The hydrocarbyl group may also be derived from an alkylating agent containing a het eroatom, such as phytol or farnesol, which may be prepared from reacting monomers of a mono or polyene containing a heteroatom. For instance, Tetrahedron Vol 43. No. 19. pp. 4481 to 4486, 1987 describes the synthesis of phytol from two C10 units derived from geraniol. In another example, the oligomer may also be produced via biological activity, such as through the fermentation of a cell culture system that is capable of producing the desired branched olefin/polyene or a composition having the appearance of an oli- gomer containing monomers equivalent to 5 to 10 carbon atom branched olefin/pol- yene compounds. For instance, WO 201 1/160081 provides a biological pathway for the production of isoprene, and the use of the so-produced isoprene to produce oli- gomers (also called terpenes, i.e., having a formula of (0₅I¾)_h, where n is 2, 3, 4, 5 or higher). The hydrocarbyl group may also be derived from an alkylating agent produced from a biological pathway, including, for instance, a biological pathway for the production of natural phytol from the crude extraction of silkworm excre ment, Morns alba leaf, bamboo leaf, pine needle and Ginkgo bi!oba leaf, for exam ple as taught in CN 102807471 A Dec 05, 2012. Other biological pathways are known to produce the oligomers (e.g., terpenes) themselves.

[0035] An oligomer containing monomers equivalent to 5 to 10 carbon atom branched olefins could be, for example, oligomers of the following formula

where Rl, R2, R3, and R4 and y are the same as defined above.

[0036] The branched polyene compound containing 5 to 10 carbon atoms may include isoprene monomers of Formula IV.

In addition to isoprene, suitable branched olefins 2-methyl- 1 -butene, 3 -methyl -1 -bu tene, 4-methyl- l-pentene, 2 -methyl- l-pentene, 3 -methyl- l-pentene, 2-methyl- 1 -hex ene, 3 -methyl- 1 -hexene, 5-methyl-l-hexene, 4-methyl- 1 -hexene, 2-methyl- l-hep- tene, 2.3-dimethyl-l, 3-butadiene, 2,4-dimethyl-l,3-pentadiene, 3 -methyl -1,3 -penta- diene, and mixtures thereof.

[0037] In an embodiment, the oligomer contains units equivalent to isoprene.

An isoprene oligomer containing 15 to 60 carbon atoms would contain 3 to 12 iso prene monomer units. An isoprene polymer or oligomer containing 15 to 30 carbon atoms would contain 3 or 6 isoprene monomer units.

[0038] In an embodiment, the oligomer can be a trimer of isoprene, which can be envisioned in the following forms

[0039] Tetramers of isoprene may also be employed in the oligomer, and can be envisioned in the following forms

(6^, 1 q£) -7,11,15 -trimethy 1-3 -methy lenehexadeca- 1,6,10,14 -tetraene

(6^, 10-E, 14^)-7, 11 , 14-trimethyl-3-methylenehexadeca-l,6, 10, 14-tetraene

p-E ^E iT_j-l O^-tiimethyl-O-iprop-l-en-l-y^pentadeca-l^^lS-tetraene

[0040] In one embodiment, the hydrocarbyl group of the alkylphenol detergent can comprise, consist essentially of, or consist of oligomer compounds comprising, consisting essentially of, or consisting of at least 50 mol% monomers equivalent to isoprene, at least 75 mol% monomers equivalent to isoprene, or at least 90 mol% monomers equivalent to isoprene. In one embodiment, the hydrocarbyl group in the alkylphenol detergent consists of oligomers of isoprene.

[0041] In some embodiments, the oligomer can be hydrogenated forms, either partial or complete, of what the oligomer of the alkylene units would otherwise ap- pear as. Hydrogenation may be performed, for example, by any hydrogenating agent known to a skilled artisan. For example, a saturated oligomer of polyene compounds can be prepared by hydrogenating at least a portion of the double bonds in the oligo- mer in the presence of a hydrogenation reagent, such as hydrogen in the presence of a catalyst, or by treatment with hydrazine in the presence of a catalyst.

[0042] In some embodiments, at least a portion of the C=C bonds of the oli- gomer is reduced to the corresponding C— C bonds by hydrogenation. In some em bodiments, all of the C=C bonds of the oligomer are reduced to the corresponding C- C bonds by hydrogenation. In an embodiment, the oligomer can include a hydrogen ated form of oligomer in the form of any of the following structures:

[0043] Whether prepared from the oligomerization of discreet units or other- wise, one of ordinary skill in the art will recognize the presence of the oligomers and monomers therein equivalent to 5 to 10 carbon atom branched polyenes within the hydrocarbyl group. [0044] The hydrocarbyl group can contain from 10 to 200 carbon atoms, or in some examples 12 to 100 carbon atoms, or even 15 to 80 carbon atoms. In some em bodiments, the hydrocarbyl group can have 15 to 60 carbon atoms, or in some cases 15 to 30 or 45 carbon atoms, or 20 to 30 carbon atoms.

[0045] The alkylphenol detergent, including the phenol moiety and the hydro- carbyl group, may include the structure represented by the following formula.

where R represents the hydrocarbyl group described above. For example, the al- kylphenol can include the structure shown in the following formulas.

[0046] In certain embodiments, the alkylphenol-containing detergent may be a sulfur-bridged phenate detergent, a sulfur-free alkylene-bridged phenate detergent, or mixtures thereof. Detergents of this type are ionic (usually metal) salts of bridged phenolic compounds. The bridged phenolic compound material may be represented by the structure:

or isomers thereof, wherein each R represents the hydrocarbyl group described above having substantially or completely aliphatic character and 15 to 60, or in some cases 15 to 30 carbon atoms; aliphatic hydrocarbyl groups containing 30 to 200 or 35 to 80 carbon atoms; methyl groups; and mixtures thereof, each y can be 1 to 4.

[0047] The average number of carbon atoms in all the R groups, combined, may be 15 to 100 (or 20 to 50, or 24 to 36 or 14 to 20 or 18 to 36). Where the bridging group may be listed as "X", each X may independently a carbon-containing bridge, or an alkylene group, or a methylene group, or a bridge of 1 or more sulfur atoms represented by S_y, where y may be 1 to 4, especially 1 or 2. In these structures, n may, in certain embodiments, be 0 to 8, or 1 to 6, or 1 to 4, or 2 to 4. That is, the bridged material may, in these embodiments, contain 2 to 10 bridged phenolic groups, or 3 to 7, or 3 to 5, or 4 such groups. Since n may be zero, it may be evident that throughout this specification, the expression "oligomeric" may be interpreted to in- elude dimeric species. Accordingly, sometimes the expression "dimeric or oligo- meric" may be used to express this concept, which may include, as above, as an ex- ample, 0 to 8 interior units bracketed by [ ]_n or 2 to 10 units overall.

[0048] In one embodiment, the sulfur-bridged alkylphenol-containing deter gent may be an oligomer of p-(isoprene)phenol. A sulfur-bridged oligomer of ol- igo(isoprene)phenol may be represented by the structure

where n = 0 to 4, and m = 1 to 4 and each y can be 1 to 4.

[0049] In certain embodiments, the alkylene-bridged phenate detergent may be a saligenin detergent. A saligenin detergent contains a bridged-alkyl phenol com- pound that may be an alkylene coupled alkylphenol represented by the structure

where each R represents the hydrocarbyl group described above having 15 to 60, or in some cases 15 to 30 carbon atoms; aliphatic hydrocarbyl groups containing 30 to 200 or 35 to 80 carbon atoms; methyl groups; and mixtures thereof; where the each bridging group (X) may be independently a carbon-containing bridge, or a hydro- carbylether linkage (such as -CH2-O-CH2-), or an alkylene group, or a methylene group; each Y may be independently -CHO or -CH2OH; wherein the -CHO groups comprise at least about 10 mole percent of the X and Y groups; and n may be an integer from 1 to 10.

[0050] In certain embodiments, the alkylene-bridged phenate detergent may be a salixarate detergent. A salixarate detergent contains a bridged-alkyl phenol com pound that may be an alkylene coupled alkylphenol that may be further bridged or coupled to salicylic acid. The bridged phenol of a salixarate may be represented by the structure (V)

where R represents the hydrocarbyl group described above having substantially or completely aliphatic character and 15 to 60, or in some cases 15 to 30 carbon atoms; aliphatic hydrocarbyl groups containing 30 to 200 or 35 to 80 carbon atoms; methyl groups; and mixtures thereof; where the each bridging group (X) may be inde- pendently a carbon-containing bridge, or an alkylene group, or a methylene group; and n may be an integer from 1 to 10.

[0051] The bridged alkylphenol detergents may be neutral or overbased or su- perbased. Such overbased detergents are generally single phase, homogeneous New- tonian systems characterized by a metal and/or ammonium content in excess of that which would be present for neutralization according to the stoichiometry of the metal or ammonium and the particular acidic organic compound reacted with the metal or ammonium compound. The overbased materials are typically prepared by reacting an acidic material (typically an inorganic acid or lower carboxylic acid such as carbon dioxide) with a mixture of bridged alkylphenol compounds (referred to as a sub- strate), a stoichiometric excess of a metal base, typically in a reaction medium of an one inert, organic solvent (e.g., mineral oil, naphtha, toluene, xylene) for the acidic organic substrate. Typically also a small amount of promoter such as a phenol or alcohol is present, and in some cases a small amount of water. The acidic organic substrate will normally have a sufficient number of carbon atoms to provide a degree of solubility in oil.

[0052] In certain embodiments, the overbased bridged-phenol detergent may be a metal-containing detergent, an amine or ammonium containing detergent, or mixtures thereof. In one embodiment, the overbased metal-containing detergent may be zinc, sodium, calcium or magnesium salts of a phenate, sulfur containing phenate, salixarate or saligenin. In one embodiment, the overbased detergent comprises a salt of an alkylamine or quaternary ammonium compound. Overbased salixarates, phen- ates and saligenins typically have a total base number (TBN) (by ASTM D3896) of 120 to 600 mg KOH/g.

[0053] In certain embodiments, the alkylphenol detergent composition may be an alkylsalicylate or salicylate detergent. A salicylate detergent may be a neutral or overbased metal salt of alkylsalicylic acid. Alkylsalicylic acid may be represented by the formula (VI)

where R represents the hydrocarbyl group described above having substantially or completely aliphatic character and 15 to 60, or in some cases 15 to 30 carbon atoms; aliphatic hydrocarbyl groups containing 30 to 200 or 35 to 80 carbon atoms; methyl groups; and mixtures thereof.

[0054] The alkyl sal icy late may be a neutral or nearly neutral salt of alkylsali- cylic acid; by nearly neutral, it is meant that there is an excess of base of no more than 15 mol percent, i.e. if the salt is metal-containing, the metal ratio is 1.15 or less. In one embodiment, the neutral salt of the alkylsalicylic acid may be an amine or ammonium salt, a metal salt, or mixtures thereof.

[0055] Amines suitable for use in the preparation of the neutral amine salted alkyl sal icy late are not overly limited and may include any alkyl amine, di- or tri-alkyl amine, though generally are fatty acid amines derived from fatty carboxylic acids. The alkyl group present in the amine may contain from 10 to 30 carbon atoms, or from 12 to 18 carbon atoms, and may be linear or branched. In some embodiments, the alkyl group may be linear and unsaturated. Typical amines include 2-ethylexhyl- amine, pentadecylamine, octadecylamine, cetylamine, oleylamine, decylamine, do- decylamine, dimethyldodecylamine, tridecylamine, heptadecylamine, octadecyla- mine, stearylamine, and any combination thereof. In some embodiments, the fatty acid derived amine salt of an alkylsalicylic acid may be a salt of oleylamine. In certain embodiments, the amine may be a gamma-aminoester compound; aminoesters of this type may be derived from Michael addition of a primary amine to an alkyl diester of itaconic acid represented by the formula

where Rio and Rn are hydrocarbyl groups containing 2 to 30 carbon atoms, and R12 is a hydrocarbyl group containing 4 to 50 carbon atoms. In some embodiments, R12 of the aminoester compound is an alkyl group that has at least one hydrocarbyl group substituted at the 1-, or 2-position of the alkyl group. In one embodiment, the ami noester is dibutyl 2-(((2-ethylhexyl)-amino)methyl)succinate.

[0056] In certain embodiments, the neutral salt of the alkylsalicylic acid may be a quaternary ammonium salt, also referred to as a quaternary nitrogen compound. Quaternary nitrogen compounds are characterized in that the nitrogen atom is four- coordinate; this results in a cationic species that is not protic, i.e. an acidic proton is not released under basic conditions. Quaternary nitrogen compounds may be charac terized as falling into two large groups, four coordinate tetrahydrocarbyl ammonium compounds, for example tetrabutylammonium, and three coordinate aromatic com pounds, for example N-hydrocarbylpyridinium.

[0057] The alkylphenol-containing detergents, be they phenates, saligenins, salixrates, or salicylates, may be metal-containing detergents. Metal-containing de tergents may be neutral, or very nearly neutral, or overbased. An overbased detergent contains a stoichiometric excess of a metal base for the acidic organic substrate. This is also referred to as metal ratio. The term "metal ratio" is the ratio of the total equiv- alents of the metal to the equivalents of the acidic organic compound. A neutral metal salt has a metal ratio of one. A salt having 4.5 times as much metal as present in a normal salt will have metal excess of 3.5 equivalents, or a ratio of 4.5. The term “metal ratio is also explained in standard textbook entitled“Chemistry and Technol ogy of Lubricants”, Third Edition, Edited by R. M. Mortier and S. T. Orszulik, Cop- yright 2010, page 219, sub-heading 7.25.

[0058] In one embodiment the overbased metal -containing alkylphenol deter gent may be calcium or magnesium overbased detergent. In one embodiment, the overbased detergent may comprise a calcium alkylphenol detergent with a metal ratio of at least 1.5, at least 3, at least 5, or at least 7. In certain embodiments, the overbased calcium alkylphenol detergent may have a metal ratio of 1.5 to 25, 2.5 to 20 or 5 to 16.

[0059] Alternatively, the alkylphenol detergent may be described as having

TBN. Overbased phenates and salicylates typically have a total base number of 120 to 600 mg KOH/g, or 150 to 550 mg KOH/g, or 180 to 350 mg KOH/g. The amount of the alkylphenol-containing detergent present in a lubricant composition may be defined as the amount necessary to deliver an amount, or range of amounts, of TBN to the lubricant composition. In certain embodiments, the alkylphenol-containing de- tergent may be present in a lubricant composition in amount to deliver 0.5 to 10 TBN to the composition, or 1 to 7 TBN, or 1.5 to 5 TBN to the composition.

[0060] Overbased detergents may also be defined as the ratio of the neutral detergent salt, also referred to as detergent soap, and the detergent ash. The overbased detergent may have a weight ratio of ash to soap of 3 : 1 to 1 :8, or 1.5: 1 to 1 to 4.1, or 1.3 : 1 to 1 :3.4.

[0061] The product of the disclosed technology may beneficially be used as an additive in a lubricant. The amount of the alkylphenol detergent in a lubricant may be 0.1 to 8 percent by weight, on an oil-free basis, but including the calcium carbonate and other salts present in an overbased composition. When present as an overbased detergent, the amount may typically be in the range of 0.1 to 25 weight percent, or 0.2 to 28, or 0.3 to 20, or 0.5 to 15 percent. The higher amounts are typical of marine diesel cylinder lubricants, e.g., 1 or 3 or 5 percent up to 25, 20, or 15 percent. Amounts used in gasoline or heavy-duty diesel engines (not marine) will typically be in lower ranges, such as 0.1 to 10 percent or 0.5 to 5 or 1 to 3 percent by weight. When used as a substantially neutral or non-overbased salt, its amount may typically be correspond- ingly less for each of the engine types, e.g., 0.1 to 10 percent or 0.2 to 8 or 0.3 to 6 percent.

[0062] In certain embodiments, the amount of the alkylphenol detergent in a lubricant may be measured as the amount of alkylphenol-containing soap that is pro- vided to the lubricant composition, irrespective of any overbasing. In one embodi- ment, the lubricant composition may contain 0.05 weight percent to 1.5 weight per cent alkylphenol-containing soap, or 0.1 weight percent to 0.9 weight percent al- kylphenol-containing soap. In one embodiment, the alkylphenol-containing soap pro- vides 20 percent by weight to 100 percent by weight of the total detergent soap in the lubricating composition. In one embodiment the alkylphenol-containing soap pro- vides 30 percent by weight to 80 percent by weight of the total detergent soap, or 40 percent by weight to 75 percent by weight of the total detergent soap of the lubricat- ing composition.

[0063] A lubricant composition may contain alkylphenol-containing deter gents different from that of the disclosed technology. In one embodiment, the lubri cant composition of the disclosed technology comprises the alkylphenol detergent of the disclosed technology in an amount 0.1 to 25 weight percent, or 0.2 to 23, or 0.3 to 20, or 0.5 to 15 weight percent, and is free of or substantially free of an alkylphenol- containing detergent derived from alkylphenol which is derived from oligomers of pro pylene, especially tetrapropenyl.“Substantially free of’ in this case means no more than 0.01 weight percent or an amount considered to arise through contamination or other unintentional means. In some embodiments, the lubricant composition can in clude the alkylphenol detergent at from about 0.01 to about 2 wt%, or from about 0.1 to about 1.75 wt%, or about 0.2 to about 1.5 wt% of the lubricating composition.

Oil of Lubricating Viscosity

[0064] Another aspect of the technology is a lubricant containing the alkylphe nol detergent composition. The lubricating composition includes an oil of lubricating viscosity. Such oils include natural and synthetic oils, oil derived from hydrocrack ing, hydrogenation, and hydrofinishing, unrefined, refined, re-refined oils or mix tures thereof. A more detailed description of unrefined, refined and re-refined oils is provided in International Publication W02008/147704, paragraphs [0054] to [0056] (a similar disclosure is provided in US Patent Application 2010/197536, see [0072] to [0073]). A more detailed description of natural and synthetic lubricating oils is described in paragraphs [0058] to [0059] respectively of W02008/147704 (a similar disclosure is provided in US Patent Application 2010/197536, see [0075] to [0076]). Synthetic oils may also be produced by Fischer-Tropsch reactions and typically may be hydroisomerized Fischer-Tropsch hydrocarbons or waxes. In one embodiment oils may be prepared by a Fischer-Tropsch gas-to-liquid synthetic procedure as well as other gas-to-liquid oils.

[0065] Oils of lubricating viscosity may also be defined as specified in the

American Petroleum Institute (API) Base Oil Interchangeability Guidelines (2011). The five base oil groups are as follows: Group I (sulfur content >0.03 wt %, and/or <90 wt % saturates, viscosity index 80 to less than 120); Group II (sulfur content <0.03 wt %, and >90 wt % saturates, viscosity index 80 to less than 120); Group III (sulfur content <0.03 wt %, and >90 wt % saturates, viscosity index >120); Group IV (all polyalphaolefms (PAOs)); and Group V (all others not included in Groups I, II, III, or IV). The oil of lubricating viscosity may also be a Group 11+ base oil, which is an unofficial API category that refers to a Group II base oil having a viscosity index greater than or equal to 110 and less than 120, as described in SAE publication“Design Practice: Passenger Car Automatic Transmissions,” fourth Edition, AE-29, 2012, page 12-9, as well as in US 8,216,448, column 1 line 57. The oil of lubricating viscosity may also be a Group III+ base oil, which, again, is an unofficial API category that refers to a Group III base oil having a viscosity index of greater than 130, for example 130 to 133 or even greater than 135, such as 135-145. Gas to liquid (“GTL”) oils are sometimes considered Group III+ base oils.

[0066] The oil of lubricating viscosity may be an API Group IV oil, or mixtures thereof, i.e., a polyalphaolefm. The polyalphaolefm may be prepared by metallocene catalyzed processes or from a non-metallocene process. The oil of lubricating viscosity may also comprise an API Group I, Group II, Group III, Group IV, Group V oil or mixtures thereof. Often the oil of lubricating viscosity is an API Group I, Group II, Group 11+ , Group III, Group IV oil or mixtures thereof. Alternatively the oil of lubri cating viscosity is often an API Group II, Group II+, Group III or Group IV oil or mixtures thereof. Alternatively the oil of lubricating viscosity is often an API Group II, Group 11+ , Group III oil or mixtures thereof.

[0067] The oil of lubricating viscosity, or base oil, will overall have a kinematic viscosity at 100 °C of 2 to 10 cSt or, in some embodiments 2.25 to 9 or 2.5 to 6 or 7 or 8 cSt, as measured by ASTM D445. Kinematic viscosities for the base oil at 100 °C of from about 3.5 to 6 or from 6 to 8 cSt are also suitable. [0068] The amount of the oil of lubricating viscosity present is typically the balance remaining after subtracting from 100 wt % the sum of the amount of the per formance additives in the composition. Illustrative amounts may include 50 to 99 per cent by weight, or 60 to 98, or 70 to 95, or 80 to 94, or 85 to 93 percent.

[0069] The lubricating composition may be in the form of a concentrate and/or a fully formulated lubricant. If the lubricating composition of the invention is in the form of a concentrate (which may be combined with additional oil to form, in whole or in part, a finished lubricant), the ratio of the of components of the invention to the oil of lubricating viscosity and/or to diluent oil include the ranges of 1 :99 to 99: 1 by weight, or 80:20 to 10:90 by weight.

[0070] A lubricating composition may be prepared by adding the product of the process described herein to an oil of lubricating viscosity, optionally in the pres ence of other performance additives (as described herein below).

[0071] The other performance additives can include at least one of metal de activators, viscosity modifiers (other than the soot dispersing additive of the present invention), detergents, friction modifiers, antiwear agents, corrosion inhibitors, dis persants (other than those of the present invention), extreme pressure agents, antiox idants, foam inhibitors, demulsifiers, pour point depressants, seal swelling agents and mixtures thereof. Typically, fully-formulated lubricating oil will contain one or more of these performance additives.

[0072] In one embodiment the invention provides a lubricating composition further comprising an overbased metal-containing detergent in addition to the al- kylphenol-containing detergent of the present invention. The metal of the metal-con taining detergent may be zinc, sodium, calcium, barium, or magnesium. Typically the metal of the metal-containing detergent may be sodium, calcium, or magnesium.

[0073] The overbased metal-containing detergent may be chosen from sul fonates, non-sulfur containing phenates, sulfur containing phenates, salixarates, sa licylates, and mixtures thereof, or borated equivalents thereof. The overbased deter gent may be borated with a borating agent such as boric acid.

[0074] The overbased metal-containing detergent may also include“hybrid” detergents formed with mixed surfactant systems including phenate and/or sulfonate components, e.g. phenate/salicylates, sulfonate/phenates, sulfonate/salicylates, sul- fonates/phenates/salicylates, as described; for example, in US Patents 6,429,178; 6,429, 179; 6,153,565; and 6,281,179. Where, for example, a “hybrid” sul- fonate/phenate detergent is employed, the“hybrid” detergent would be considered equivalent to amounts of distinct phenate and sulfonate detergents introducing like amounts of phenate and sulfonate soaps, respectively.

[0075] Typically, an overbased metal-containing detergent may be a zinc, so- dium, calcium or magnesium salt of a sulfonate, a phenate, sulfur containing phenate, salixarate or salicylate. Overbased sulfonates, salixarates, phenates and salicylates typically have a total base number of 120 to 700 TBN.

[0076] Typically, the overbased metal-containing detergent may be a calcium or magnesium overbased detergent.

[0077] In another embodiment the lubricating composition further comprises a calcium sulfonate overbased detergent having a TBN of 120 to 700. The overbased sulfonate detergent may have a metal ratio of 12 to less than 20, or 12 to 18, or 20 to 30, or 22 to 25.

[0078] Overbased sulfonates typically have a total base number of 120 to 700, or 250 to 600, or 300 to 500 (on an oil free basis). Overbased detergents are known in the art. In one embodiment the sulfonate detergent may be a predominantly linear alkylbenzene sulfonate detergent having a metal ratio of at least 8 as is described in paragraphs [0026] to [0037] of US Patent Application 2005065045 (and granted as US 7,407,919). Linear alkyl benzenes may have the benzene ring attached anywhere on the linear chain, usually at the 2, 3, or 4 position, or mixtures thereof. The pre- dominantly linear alkylbenzene sulfonate detergent may be particularly useful for assisting in improving fuel economy. In one embodiment the sulfonate detergent may be a metal salt of one or more oil-soluble alkyl toluene sulfonate compounds as dis closed in paragraphs [0046] to [0053] of US Patent Application 2008/0119378.

[0079] In one embodiment the lubricating composition further comprises

0.01 wt % to 2 wt %, or 0.1 to 1 wt % of a detergent different from the alkylphenol detergent of the disclosed technology, wherein the further detergent is chosen from sulfonates, non-sulfur containing phenates, sulfur containing phenates, sulfonates, salixarates, salicylates, and mixtures thereof, or borated equivalents thereof. [0080] In one embodiment the lubricating composition further comprises a

“hybrid”detergent formed with mixed surfactant systems including phenate and/or sulfonate components, e.g. phenate/salicylates, sulfonate/phenates, sulfonate/salicy- lates, or sulfonates/phenates/salicylates.

[0081] The lubricating composition in a further embodiment comprises an an tioxidant, wherein the antioxidant comprises a phenolic or an aminic antioxidant or mixtures thereof. The antioxidants include diarylamines, alkylated diarylamines, hin dered phenols, or mixtures thereof. When present the antioxidant is present at 0.1 wt % to 3 wt %, or 0.5 wt % to 2.75 wt %, or 1 wt % to 2.5 wt % of the lubricating composition.

[0082] The diarylamine or alkylated diarylamine may be a phenyl-a-naphthyl- amine (PANA), an alkylated diphenylamine, or an alkylated phenylnapthylamine, or mixtures thereof. The alkylated diphenylamine may include di-nonylated diphenyla mine, nonyl diphenylamine, octyl diphenylamine, di-octylated diphenylamine, di-decylated diphenylamine, decyl diphenylamine and mixtures thereof. In one em bodiment the diphenylamine may include nonyl diphenylamine, dinonyl diphenyla mine, octyl diphenylamine, dioctyl diphenylamine, or mixtures thereof. In another embodiment the alkylated diphenylamine may include nonyl diphenylamine, or di nonyl diphenylamine. The alkylated diarylamine may include octyl, di-octyl, nonyl, di-nonyl, decyl or di-decyl phenylnapthylamines.

[0083] The hindered phenol antioxidant often contains a secondary butyl and/or a tertiary butyl group as a sterically hindering group. The phenol group may be further substituted with a hydrocarbyl group (typically linear or branched alkyl) and/or a bridging group linking to a second aromatic group. Examples of suitable hindered phenol antioxidants include 2,6-di-tert-butylphenol, 4-methyl-2,6-di-tert- butylphenol, 4-ethyl-2,6-di-tert-butylphenol, 4-propyl-2,6-di-tert-butyl^_,phenol or 4-butyl-2,6-di-tert-butylphenol, or 4-dodecyl-2,6-di-tert-butyl^_,phenol. In one em bodiment the hindered phenol antioxidant may be an ester and may include, e.g., Irganox™ L-135 from Ciba. A more detailed description of suitable ester-containing hindered phenol antioxidant chemistry is found in US Patent 6,559, 105.

[0084] The lubricating composition may in a further embodiment include a dispersant, or mixtures thereof. The dispersant may be a succinimide dispersant, a Mannich dispersant, a succinamide dispersant, a polyolefin succinic acid ester, am ide, or ester-amide, or mixtures thereof. In one embodiment the dispersant may be present as a single dispersant. In one embodiment the dispersant may be present as a mixture of two or three different dispersants, wherein at least one may be a succin- imide dispersant.

[0085] The succinimide dispersant may be derived from an aliphatic polyam ine, or mixtures thereof. The aliphatic polyamine may be aliphatic polyamine such as an ethylenepolyamine, a propylenepolyamine, a butylenepolyamine, or mixtures thereof. In one embodiment the aliphatic polyamine may be ethylenepolyamine. In one embodiment the aliphatic polyamine may be chosen from ethyl enedi amine, di ethyl enetri amine, triethylenetetramine, tetra-'ethylene-'pentamine, pentaethylene- hexamine, polyamine still bottoms, and mixtures thereof.

[0086] In one embodiment the dispersant may be a polyolefin succinic acid ester, amide, or ester-amide. For instance, a polyolefin succinic acid ester may be a polyisobutylene succinic acid ester of pentaerythritol, or mixtures thereof. A poly olefin succinic acid ester-amide may be a polyisobutylene succinic acid reacted with an alcohol (such as pentaerythritol) and a polyamine as described above.

[0087] The dispersant may be an N-substituted long chain alkenyl succin imide. An example of an N substituted long chain alkenyl succinimide is polyisobu tylene succinimide. Typically the polyisobutylene from which polyisobutylene suc cinic anhydride is derived has a number average molecular weight of 350 to 5000, or 550 to 3000 or 750 to 2500. Succinimide dispersants and their preparation are dis closed, for instance in US Patents 3,172,892, 3,219,666, 3,316, 177, 3,340,281,

3 351,552, 3,381,022, 3,433,744, 3,444, 170, 3,467,668, 3,501,405, 3,542,680

3,576,743, 3,632,51 1, 4,234,435, Re 26,433, and 6,165,235, 7,238,650 and EP Patent Application 0 355 895 A.

[0088] The dispersants may also be post-treated by conventional methods by a reaction with any of a variety of agents. Among these are boron compounds (such as boric acid), urea, thiourea, dimercaptothiadiazoles, carbon disulfide, aldehydes, ketones, carboxylic acids such as terephthalic acid, hydrocarbon-substituted succinic anhydrides, maleic anhydride, nitriles, epoxides, and phosphorus compounds. In one embodiment the post-treated dispersant is borated. In one embodiment the post- treated dispersant is reacted with dimercaptothiadiazoles. In one embodiment the post-treated dispersant is reacted with phosphoric or phosphorous acid. In one em bodiment the post-treated dispersant is reacted with terephthalic acid and boric acid (as described in US Patent Application US2009/0054278.

[0089] When present, the dispersant may be present at 0.01 wt % to 20 wt %, or 0.1 wt % to 15 wt %, or 0.1 wt % to 10 wt %, or 1 wt % to 6 wt %, or 1 to 3 wt % of the lubricating composition.

[0090] The succinimide dispersant may comprise a polyisobutylene succin- imide, wherein the polyisobutylene from which polyisobutylene succinimide is de- rived has a number average molecular weight of 350 to 5000, or 750 to 2500.

[0091] In one embodiment the friction modifier may be chosen from long chain fatty acid derivatives of amines, long chain fatty esters, or derivatives of long chain fatty epoxides; fatty imidazolines; amine salts of alkylphosphoric acids; fatty alkyl tartrates; fatty alkyl tartrimides; fatty alkyl tartramides; fatty glycolates; and fatty glycolamides. The friction modifier may be present at 0 wt % to 6 wt %, or 0.01 wt % to 4 wt %, or 0.05 wt % to 2 wt %, or 0.1 wt % to 2 wt % of the lubricating composition.

[0092] As used herein the term“fatty alkyl” or“fatty” in relation to friction modifiers means a carbon chain having 10 to 22 carbon atoms, typically a straight carbon chain.

[0093] Examples of suitable friction modifiers include long chain fatty acid derivatives of amines, fatty esters, or fatty epoxides; fatty imidazolines such as con densation products of carboxylic acids and polyalkylene-polyamines; amine salts of alkylphosphoric acids; fatty alkyl tartrates; fatty alkyl tartrimides; fatty alkyl tar tramides; fatty phosphonates; fatty phosphites; borated phospholipids, borated fatty epoxides; glycerol esters; borated glycerol esters; fatty amines; alkoxylated fatty amines; borated alkoxylated fatty amines; hydroxyl and polyhydroxy fatty amines including tertiary hydroxy fatty amines; hydroxy alkyl amides; metal salts of fatty acids; metal salts of alkyl salicylates; fatty oxazolines; fatty ethoxylated alcohols; condensation products of carboxylic acids and polyalkylene polyamines; or reaction products from fatty carboxylic acids with guanidine, aminoguanidine, urea, or thiou rea and salts thereof. [0094] Friction modifiers may also encompass materials such as sulfurised fatty compounds and olefins, molybdenum dialkyldithiophosphates, molybdenum di- thiocarbamates, sunflower oil or soybean oil monoester of a polyol and an aliphatic carboxylic acid.

[0095] In another embodiment the friction modifier may be a long chain fatty acid ester. In another embodiment the long chain fatty acid ester may be a mono-ester and in another embodiment the long chain fatty acid ester may be a triglyceride.

[0096] The lubricating composition optionally further includes at least one an tiwear agent. Examples of suitable antiwear agents include titanium compounds, tar trates, tartrimides, oil soluble amine salts of phosphorus compounds, sulfurized ole fins, metal dihydrocarbyldithiophosphates (such as zinc dialkyldithiophosphates), phosphites (such as dibutyl phosphite), phosphonates, thiocarbamate-containing compounds, such as thiocarbamate esters, thiocarbamate amides, thiocarbamic ethers, alkylene-coupled thiocarbamates, and bis(S-alkyldithiocarbamyl) disulfides.

[0097] The antiwear agent may in one embodiment include a tartrate, or tar- trimide as disclosed in International Publication W02006/044411 or Canadian Patent CA 1183125. The tartrate or tartrimide may contain alkyl-ester groups, where the sum of carbon atoms on the alkyl groups is at least 8. The antiwear agent may in one embodiment include a citrate as is disclosed in US Patent Application 2005/0198894.

[0098] Another class of additives includes oil-soluble titanium compounds as disclosed in US 7,727,943 and US2006/0014651. The oil-soluble titanium com pounds may function as antiwear agents, friction modifiers, antioxidants, deposit con trol additives, or more than one of these functions. In one embodiment the oil soluble titanium compound is a titanium (IV) alkoxide. The titanium alkoxide is formed from a monohydric alcohol, a polyol or mixtures thereof. The monohydric alkoxides may have 2 to 16, or 3 to 10 carbon atoms. In one embodiment, the titanium alkoxide is titanium (IV) isopropoxide. In one embodiment, the titanium alkoxide is tita nium (IV) 2 ethylhexoxide. In one embodiment, the titanium compound comprises the alkoxide of a vicinal 1 ,2-diol or polyol. In one embodiment, the l,2-vicinal diol comprises a fatty acid mono-ester of glycerol, often the fatty acid is oleic acid. [0099] In one embodiment, the oil soluble titanium compound is a titanium carboxylate. In a further embodiment the titanium (IV) carboxylate is titanium ne- odecanoate.

[0100] The lubricating composition may in one embodiment further include a phosphorus-containing antiwear agent. Typically the phosphorus-containing anti wear agent may be a zinc dialkyldithiophosphate, phosphite, phosphate, phosphonate, and ammonium phosphate salts, or mixtures thereof. Zinc dialkyldithiophosphates are known in the art. The antiwear agent may be present at 0 wt % to 3 wt %, or 0.1 wt % to 1.5 wt %, or 0.5 wt % to 0.9 wt % of the lubricating composition. In some embodiments, the antiwear agent may be present in an amount sufficient to provide from 0 to 0.12 wt% phosphorus to the lubricating composition, or from 0.01 to 0.08 wt%, or 0.03 to 0.08 wt%, or even 0.025 to 0.06 wt% phosphorus.

[0101] Extreme Pressure (EP) agents that are soluble in the oil include sulfur- and chlorosulfur-containing EP agents, dimercaptothiadiazole or CS2 derivatives of dispersants (typically succinimide dispersants), derivative of chlorinated hydrocar bon EP agents and phosphorus EP agents. Examples of such EP agents include chlo rinated wax; sulfurized olefins (such as sulfurized isobutylene), a hydrocarbyl-sub- stituted 2,5-dimercapto-l,3,4-thiadiazole, or oligomers thereof, organic sulfides and polysulfides such as dibenzyldisulfide, bis-(chlorobenzyl) disulfide, dibutyl tetrasul- fide, sulfurized methyl ester of oleic acid, sulfurized alkylphenol, sulfurized dipen- tene, sulfurized terpene, and sulfurized Diels-Alder adducts; phosphosulfurized hy drocarbons such as the reaction product of phosphorus sulfide with turpentine or me thyl oleate; phosphorus esters such as the dihydrocarbon and trihydrocarbon phos phites, e.g., dibutyl phosphite, diheptyl phosphite, dicyclohexyl phosphite, pen- tylphenyl phosphite; dipentylphenyl phosphite, tridecyl phosphite, distearyl phos phite and polypropylene substituted phenol phosphite; metal thiocarbamates such as zinc dioctyldithiocarbamate and barium heptylphenol diacid; amine salts of alkyl and dialkylphosphoric acids or derivatives including, for example, the amine salt of a reaction product of a dialkyldithiophosphoric acid with propylene oxide and subse quently followed by a further reaction with P2O5 ; and mixtures thereof (as described in US 3,197,405). [0102] Foam inhibitors that may be useful in the lubricant compositions of the disclosed technology include polysiloxanes, copolymers of ethyl acrylate and 2-ethylhexylacrylate and optionally vinyl acetate; demulsifiers including fluorinated polysiloxanes, trialkyl phosphates, polyethylene glycols, polyethylene oxides, poly- propylene oxides and (ethylene oxide-propylene oxide) polymers.

[0103] Other viscosity modifiers may include a block copolymer comprising

(i) a vinyl aromatic monomer block and (ii) a conjugated diene olefin monomer block (such as a hydrogenated styrene-butadiene copolymer or a hydrogenated styrene-iso- prene copolymer), a polymethacrylate, or mixtures thereof.

[0104] Pour point depressants that may be useful in the lubricant compositions of the disclosed technology include polyalphaolefms, esters of maleic anhydride-sty- rene copolymers, poly(meth)acrylates, polyacrylates or polyacrylamides.

[0105] Demulsifiers include trialkyl phosphates, and various polymers and co- polymers of ethylene glycol, ethylene oxide, propylene oxide, or mixtures thereof.

[0106] Metal deactivators include derivatives of benzotri azoles (typically tol- yltriazole), 1,2, 4-triazoles, benzimidazoles, 2-alkyl dithiobenzimidazoles or 2-alkyl - dithiobenzothiazoles. The metal deactivators may also be described as corrosion in hibitors.

[0107] Seal swell agents include sulfolene derivatives Exxon Necton-37™ (FN 1380) and Exxon Mineral Seal Oil™ (FN 3200).

[0108] In an embodiment, the lubricating composition can be employed to lu bricate a mechanical device. The mechanical device can be associated with an auto motive vehicle. For example, the mechanical device may be a driveline device.

[0109] Driveline devices include automatic transmissions, manual transmis- sion, dual clutch transmissions, or an axle or differential. A driveline device lubricating composition in different embodiments may have a composition as disclosed in the follow ing table:

Footnote:

The viscosity modifier in the table above may also be considered as an alternative to an oil of lubricating viscosity.

Column A may be representative of an automotive or axle gear lubricant.

Column B may be representative of an automatic transmission lubricant.

Column C may be representative of an off-highway lubricant.

Column D may be representative of a manual transmission lubricant. [0110] The mechanical device can be an internal combustion engine, such as, for example, a spark ignited internal combustion engine or a compression ignition internal combustion engine. An engine lubricant composition in different embodi- ments may have a composition as disclosed in the following table:

[0111] The mechanical device may also be in a hydraulic system. A hydraulic lubricant may also comprise a formulation defined in the following table:

[0112] The disclosed technology further provides a method of lubricating a circulating oil system.

[0113] The disclosed technology further provides a method of lubricating a turbine system.

[0114] The alkylphenol can be employed to lubricate any of the foregoing me- chanical devices by supplying to the mechanical device the aforementioned lubricat- ing compositions.

[0115] The amount of each chemical component described is presented exclu- sive of any solvent or diluent oil, which may be customarily present in the commercial material, that is, on an active chemical basis, unless otherwise indicated. However, unless otherwise indicated, each chemical or composition referred to herein should be interpreted as being a commercial grade material which may contain the isomers, by- products, derivatives, and other such materials which are normally understood to be present in the commercial grade.

[0116] It is known that some of the materials described above may interact in the final formulation, so that the components of the final formulation may be different from those that are initially added. For instance, metal ions (of, e.g., a detergent) can migrate to other acidic or anionic sites of other molecules. The products formed thereby, including the products formed upon employing the composition of the present invention in its intended use, may not be susceptible of easy description. Nevertheless, all such modifications and reaction products are included within the scope of the pre- sent invention; the present invention encompasses the composition prepared by admix ing the components described above.

[0117] As used herein, the term "about" means that a value of a given quantity is within ±20% of the stated value. In other embodiments, the value is within ±15% of the stated value. In other embodiments, the value is within ±10% of the stated value. In other embodiments, the value is within ±5% of the stated value. In other embodiments, the value is within ±2.5% of the stated value. In other embodiments, the value is within ±1% of the stated value. [0118] Additionally, as used herein, the term "substantially" means that a value of a given quantity is within ±10% of the stated value. In other embodiments, the value is within ±5% of the stated value. In other embodiments, the value is within ±2.5% of the stated value. In other embodiments, the value is within ±1% of the stated value.

[0119] Each of the documents referred to above is incorporated herein by ref- erence, including any prior applications, whether or not specifically listed above, from which priority is claimed. The mention of any document is not an admission that such document qualifies as prior art or constitutes the general knowledge of the skilled per son in any jurisdiction. Except in the Examples, or where otherwise explicitly indi- cated, all numerical quantities in this description specifying amounts of materials, re- action conditions, molecular weights, number of carbon atoms, and the like, are to be understood as modified by the word "about." It is to be understood that the upper and lower amount, range, and ratio limits set forth herein may be independently combined. Similarly, the ranges and amounts for each element of the invention can be used to- gether with ranges or amounts for any of the other elements.

[0120] As used herein, the transitional term“comprising,” which is synony mous with“including,”“containing,” or“characterized by,” is inclusive or open- ended and does not exclude additional, un-recited elements or method steps. How ever, in each recitation of“comprising” herein, it is intended that the term also encom pass, as alternative embodiments, the phrases“consisting essentially of’ and“consist ing of,” where“consisting of’ excludes any element or step not specified and“con sisting essentially of’ permits the inclusion of additional un-recited elements or steps that do not materially affect the essential or basic and novel characteristics of the com position or method under consideration.

[0121] While certain representative embodiments and details have been shown for the purpose of illustrating the subject invention, it will be apparent to those skilled in this art that various changes and modifications can be made therein without de parting from the scope of the subject invention. In this regard, the scope of the in vention is to be limited only by the following claims.

Claims

What is claimed is:

1. An alkylphenol detergent composition comprising at least one phenol moiety having a hydrocarbyl group attached thereto, the hydrocarbyl group compris- ing at least one oligomer comprising monomers equivalent to 5 to 10 carbon atom branched olefins.

2. The alkylphenol detergent composition of claim 1, where the monomers are equivalent to 5 to 10 carbon atom branched polyenes.

3. The alkylphenol detergent composition of claim 2, where the monomers are equivalent to isoprene.

4. The alkylphenol detergent composition of any previous claim, where the oli gomer is a terpene.

5. The alkylphenol detergent composition of any previous claim, where the oli gomer is equivalent to at least one of formula

6. The detergent composition of any previous claim, wherein the oligomer is equivalent to a partially or completely hydrogenated form of a terpene.

7. The detergent composition of claim 5, wherein the oligomer is equivalent to any of formula:

8. The detergent composition of any previous claim, where the hydrocarbyl unit comprises 15 to 60 carbon atoms.

9. The detergent composition of any previous claim, where the detergent com prises an alkylphenol moiety of any of formula:

10. The detergent composition of any previous claim, wherein the detergent is a sulfur-bridged phenate detergent, a sulfur-free alkylene-bridged phenate de tergent, a salicylate detergent, or mixtures thereof.

11. The detergent composition of any previous claim, where the detergent com prises one or more alkali metals, one or more alkaline earth metals, or mixtures thereof.

12. The detergent composition of any previous claim, where the detergent is over based.

13. The detergent composition of claim 12, where the overbased detergent has a metal ratio of at least 1.5, at least 5, or at least 7.

14. The detergent composition of any previous claim, wherein the detergent is an overbased sulfur-coupled phenate detergent with a metal ratio of at least 1.5.

15. The detergent composition of any previous claim, wherein the composition is a sulfur-bridged phenate represented by the structure

wherein each R is an aliphatic hydrocarbyl group equivalent to an oligomer of isoprene, higher branched olefins, or mixtures thereof, that contains 15 to 60 carbon atoms: and n = 0 to 8, or 1 to 6, or 1 to 4, or 2 to 4.

16. The detergent composition of any previous claim, wherein the detergent is a neutral or overbased salt of alkylsalicylic acid.

17. The detergent composition of any previous claim, wherein the composition is an alkylsalicylate represented by the structure

where R is an aliphatic hydrocarbyl group equivalent to an oligomer of iso prene, higher branched olefins, or mixtures thereof, and wherein the hydro carbyl group contains 15 to 60 carbon atoms

18. A lubricating composition comprising (a) an oil of lubricating viscosity and (b) the alkylphenol detergent composition of any previous claim.

19. The lubricating composition of claim 18, wherein the alkylphenol detergent is present from about 0.01 to about 2 wt%, or from about 0.1 to about 1.75 wt%, or about 0.2 to about 1.5 wt% of the lubricating composition.

20. The lubricating composition of claim 18 or 19, wherein the composition is substantially free of an alkylphenol-containing detergent wherein the al- kylphenol is derived from oligomers of propene.

21. The lubricating composition of any of claims 18 to 20, further comprising a zinc dialkyldithiophosphate.

22. The lubricating composition of any of claims 18 to 21, further comprising a dispersant.

23. The lubricating composition of claim 22, wherein the dispersant is a polyiso- butylene succinimide dispersant.

24. The lubricating composition of any of claims 22 to 23, wherein the dispersant is present at 0.1 to 5 wt %, or 0.3 to 4 wt %, or 0.5 to 3 wt %, or 1 to 2.5 or 3 wt %, or 1.5 to 4 wt %, or 1.5 to 3 wt %, or even 0.1 to 3 wt %, or 0.1 to 2.5 wt %, or 0.2 to 2 wt %.

25. The lubricating composition of any of claims 18 to 24, further comprising a phosphorus-containing antiwear agent chosen from (i) a non-ionic phosphorus compound, which may be a hydrocarbyl phosphite; or (ii) an amine salt of a phosphorus compound.

26. The lubricating composition of any of claims 18 to 25, further comprising a thiadi azole.

27. The lubricating composition of claim 26, wherein the thiadiazole is present at 0.1 to 0.5 wt %,or 0.2 to 0.4 wt %, or 0.25 to 0.35 wt %., or even from 0.05 to 1 wt %, or 0.07 to 0.7 wt %, or 0.1 to 0.3 wt %, or 0.15 to 0.25 wt %.

28. A method of lubricating a mechanical device comprising supplying to the de- vice the lubricating composition of any of claims 18 to 27.

29. The method of claim 28, wherein the mechanical device is an internal com bustion engine.

30. The method of claim 29, wherein the internal combustion engine is a heavy duty diesel compression ignited internal combustion engine or a spark assisted compression ignited internal combustion engine.

31. The method of claim 28, wherein the mechanical device is an automatic trans- mission.

32. The method of claim 28, wherein the mechanical device is a manual transmis- sion.

33. The method of claim 28, wherein the mechanical device is an automotive axle.

34. The method of claim 28, wherein the mechanical device is an off-highway vehicle.