WO2019100956A1 - Device for brine evaporation and extraction by solar energy - Google Patents

Device for brine evaporation and extraction by solar energy Download PDF

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Publication number
WO2019100956A1
WO2019100956A1 PCT/CN2018/114987 CN2018114987W WO2019100956A1 WO 2019100956 A1 WO2019100956 A1 WO 2019100956A1 CN 2018114987 W CN2018114987 W CN 2018114987W WO 2019100956 A1 WO2019100956 A1 WO 2019100956A1
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brine
solar
evaporation
pool
extraction device
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PCT/CN2018/114987
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French (fr)
Chinese (zh)
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雷政军
吴浩
高超
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西安威西特消防科技有限责任公司
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Publication of WO2019100956A1 publication Critical patent/WO2019100956A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/30Accessories for evaporators ; Constructional details thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D9/00Crystallisation
    • B01D9/02Crystallisation from solutions

Definitions

  • the utility model relates to the technical field of comprehensive utilization of brine, and more particularly to a device for extracting minerals in brine water by using solar energy.
  • the salt lake brine contains abundant mineral resources such as magnesium, lithium, calcium and potassium. China's salt lake resources are mainly distributed in Qinghai, Cambodia, Xinjiang and other provinces. However, because the salt lakes in these provinces are often sparsely populated, infrastructure is not perfect, and energy supply is insufficient, it has brought serious constraints to the development and utilization of these resources.
  • the devices for extracting minerals in brine mainly include evaporation crystallization method, precipitation method, salting out method, carbonization method, flotation method, extraction method, ion exchange adsorption method, calcination method, membrane separation method and the like.
  • the existing production process uses natural beach drying and evaporation crystallization, but the sun exposure time of Rizhao Beach often reaches 3 to 6 months, which severely limits the improvement of production efficiency.
  • the industrial evaporative crystallization method is not suitable for direct application in the salt lake area due to its huge energy consumption, and the promotion of brine extraction and comprehensive utilization technology is also limited. Therefore, it is particularly important to seek a simple, efficient and energy-saving extraction technology.
  • the utility model provides a device for extracting halogen by using solar energy, which is economical, efficient, energy-saving and environmentally friendly, and is suitable for large-scale promotion of the salt lake area.
  • a solar energy evaporation and halogen extraction device comprises a solar collector, a brine feed unit, a brine pool and a crystal slurry outlet, wherein the solar collector has a brine inlet at one end and a brine outlet at the other end;
  • the brine outlet of the solar collector is connected to the brine feed unit disposed above the brine pool through a pipeline; the brine heated by the solar collector is evaporated and crystallized in the brine pool, and is returned to the solar collector through the pipeline.
  • the loop is completed.
  • a feed valve is disposed between the solar collector and the brine feed unit, and a brine storage tank is further disposed at a rear end of the brine pool, and a rear end of the brine storage tank is provided with a tank ball valve and a reflux pump.
  • the brine feed unit above the brine pool comprises a plurality of uniform shower head sets and a spray circulation line, the free end of the spray circulation line is open and disposed in the brine pool, and the other end is sprayed through the spray cycle.
  • the pump is connected to the shower head set.
  • An air duct is formed on the outer side of the brine pool, and the two long sides and the top of the air duct are closed, and the two wide sides are provided with openings; and one of the open ends is provided with a fan.
  • the fan is driven by an external pneumatic impeller through a speed reduction mechanism.
  • the air duct is a solar greenhouse structure, and the upper part of the structure is a transparent glass or plastic ceiling, which can absorb the heat of the sunlight and increase the temperature around the brine pool.
  • the solar collector is an all-glass vacuum tube solar collector, comprising a vertically disposed intermediate header and a glass vacuum tube group arranged in parallel on both sides of the collector tube, the open end and the current collection of the glass vacuum tube The tubes are connected.
  • the closed end of the glass vacuum tube is slightly higher than the open end thereof to facilitate circulation of the heat carrier.
  • the feed valve is provided with a temperature sensor for monitoring the temperature of the feed brine and controlling the opening of the valve in real time; a temperature and concentration sensor is arranged at the exit of the crystal slurry in the brine pool, and the brine is evaporated to the desired concentration in the brine pool. At the time, the valve controlling the outlet of the crystal slurry is opened to discharge the crystal slurry.
  • the utility model combines the actual conditions of the salt lake area, utilizes the characteristics of the local light intensity, and adopts a device that replaces the traditional hot steam by using a solar collector, directly heating the brine, evaporating and crystallizing the brine, and extracting the desired minerals.
  • High thermal efficiency, effective energy conservation, and reduced infrastructure requirements are suitable for large-scale promotion in the salt lake area.
  • the fan group at one end of the air duct and the spray system above the brine pool are used to further reduce the evaporation effect by increasing the evaporation surface area and increasing the air flow rate to reduce the air humidity in the evaporation area; meanwhile, the sprayed water
  • the curtain can flush out the surface salt layer deposited on the surface of the brine pool due to evaporation and accelerate evaporation.
  • the utility model can increase the air flow rate by setting the greenhouse type air duct, and can also directly add the air in the greenhouse by using the solar radiation, and combine the fan to reduce the regional air humidity and enhance the evaporation effect.
  • the utility model adopts a specially designed horizontal-row glass vacuum tube solar collector to effectively solve the problem of heat carrier circulation.
  • Figure 1 is a schematic view of the structure of the embodiment of the present invention
  • a solar energy evaporation and halogen extraction device comprises a solar collector 1, a brine feed unit 2, a brine pool 3, and a crystal slurry outlet 4, wherein the solar collector 1 is provided with a brine inlet at one end and the other end is provided. There is a brine outlet; the brine outlet of the solar collector 1 is connected to the brine feed unit 2 disposed above the brine pool 3 through a pipeline; the brine heated by the solar collector is evaporated and crystallized in the brine pool 3, And the circulation is completed by returning the pipeline to the solar collector 1.
  • a feed valve 6 is disposed between the solar collector 1 and the brine feed unit 2, and a brine storage tank 5 is further disposed at a rear end of the brine pool 3. The rear end of the brine storage tank 5 is provided with a storage tank Ball valve 7 and return pump 8.
  • the brine feed unit 2 above the brine pool comprises a plurality of uniform showerhead sets 201 and a spray circulation line 202.
  • the free end 204 of the spray circulation line 202 is disposed in the brine pool and passes through the other end.
  • the spray circulation pump 203 is connected to the shower head group 201.
  • An air duct 12 is formed on the outer side of the brine pool 3.
  • the two long sides and the top of the air duct are closed, and the two wide sides are provided with openings; and one of the open ends is provided with a fan 9.
  • the fan 9 is driven by the external pneumatic impeller 11 through the speed reduction mechanism 10.
  • the air duct 12 is a solar greenhouse structure, and the upper part of the structure is a transparent glass or plastic ceiling, which can absorb the heat of the sunlight to increase the temperature of the air around the brine pool and promote evaporation.
  • the solar collector 1 is an all-glass vacuum tube solar collector, comprising a vertically disposed intermediate header and a glass vacuum tube group arranged in parallel on both sides of the collector tube, the open end and the set of the glass vacuum tube The flow tubes are connected.
  • the closed end of the glass vacuum tube is slightly higher than the open end thereof, so that the heat carrier in the glass vacuum tube is completely drained.
  • the feed valve 6 is provided with a temperature sensor for monitoring the temperature of the feed brine and controlling the opening of the valve in real time; the temperature and concentration sensor is arranged at the outlet 4 of the brine in the brine pool 3, when the brine in the brine pool is evaporated to At the desired concentration, the valve that controls the exit of the slurry opens and discharges the slurry.
  • the working process of the device of the utility model is:
  • the solar collector is used to heat the brine.
  • the feed valve is opened, the hot brine is injected through the brine feed unit, the hot brine is evaporated in the brine, and the cooled brine is circulated through the circulation line.
  • the solar collector is heated again.
  • the fan group at one end of the air duct and the spray system above the brine pool can further enhance the evaporation effect by increasing the evaporation surface area and increasing the air flow rate to reduce the air humidity in the evaporation area; meanwhile, the water curtain can be sprayed out.
  • the surface of the brine pool is washed away by evaporation and crystallized to accelerate evaporation.
  • the crystal slurry outlet valve is opened, and the mineral crystal slurry is discharged from the crystal slurry outlet, and the desired mineral is obtained through subsequent processing.
  • the apparatus of the present invention and the industrial vapor source evaporation crystallization apparatus can reach a high level in terms of extraction efficiency, extraction purity and treatment cycle, but the utility model directly utilizes solar energy and wind energy, and is energy-saving and environmentally friendly. , low dependence on infrastructure.
  • the natural beach sun method directly uses solar energy, it has a large area and is easy to accept the influence of external environment changes.
  • the treatment cycle and extraction efficiency are far lower than the utility model.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

A device for brine evaporation and extraction by solar energy, comprising a solar thermal collector (1), a brine feeding unit (2), a brine pond (3), a magma outlet (4); one end of the solar thermal collector (1) is provided with a brine inlet, and the other end thereof is provided with a brine outlet; the brine outlet of the solar thermal collector (1) is connected, through a pipeline, to the brine feeding unit (2) arranged above the brine pond (3). Brine heated by the solar thermal collector (1) is evaporated and crystallized in the brine pond (3), and returns, through the pipeline, to the solar thermal collector (1) to complete the circulation.

Description

一种太阳能蒸发提卤设备Solar energy evaporation and halogen extraction device 技术领域Technical field
本实用新型涉及卤水综合利用技术领域,更具体地说是一种利用太阳能提取卤水中矿物质的装置。The utility model relates to the technical field of comprehensive utilization of brine, and more particularly to a device for extracting minerals in brine water by using solar energy.
背景技术Background technique
盐湖卤水中蕴含着丰富的镁、锂、钙、钾等矿物资源。我国盐湖资源主要分布在青海、西藏、新疆等省份,但由于这些省的盐湖地区往往人口稀少,基础设施尚不完善,能源供应不充足,因此给开发利用这些资源带来了严重的制约。目前卤水中提取矿物质的装置主要有蒸发结晶法、沉淀法、盐析法、碳化法、浮选法、萃取法、离子交换吸附法、煅烧法、膜分离法等多种装置。现有的生产工艺,为了节约能源、降低对基础设施的要求,多采用自然滩晒、蒸发结晶等装置,但由于日照滩晒耗时往往达到3~6个月,严重限制了生产效率的提升,而工业用蒸发结晶法由于能耗巨大,也不适于在盐湖区直接应用,卤水提取及综合利用技术的推广也因此受到了限制。因此寻求一种简单、高效并且节能环保的提取技术,显得尤为重要。The salt lake brine contains abundant mineral resources such as magnesium, lithium, calcium and potassium. China's salt lake resources are mainly distributed in Qinghai, Tibet, Xinjiang and other provinces. However, because the salt lakes in these provinces are often sparsely populated, infrastructure is not perfect, and energy supply is insufficient, it has brought serious constraints to the development and utilization of these resources. At present, the devices for extracting minerals in brine mainly include evaporation crystallization method, precipitation method, salting out method, carbonization method, flotation method, extraction method, ion exchange adsorption method, calcination method, membrane separation method and the like. In order to save energy and reduce the requirements for infrastructure, the existing production process uses natural beach drying and evaporation crystallization, but the sun exposure time of Rizhao Beach often reaches 3 to 6 months, which severely limits the improvement of production efficiency. However, the industrial evaporative crystallization method is not suitable for direct application in the salt lake area due to its huge energy consumption, and the promotion of brine extraction and comprehensive utilization technology is also limited. Therefore, it is particularly important to seek a simple, efficient and energy-saving extraction technology.
实用新型内容Utility model content
针对现有技术的缺陷,特别是我国盐湖资源分布地的特点,本实用新型提供了一种利用太阳能蒸发提卤的设备,经济高效并且节能环保,适于盐湖区规模化推广。In view of the defects of the prior art, especially the characteristics of the distribution of salt lake resources in China, the utility model provides a device for extracting halogen by using solar energy, which is economical, efficient, energy-saving and environmentally friendly, and is suitable for large-scale promotion of the salt lake area.
本实用新型采用的技术方案是:The technical solution adopted by the utility model is:
一种太阳能蒸发提卤设备,包括太阳能集热器、卤水进料单元、卤水池、晶浆出口,其特征在于:所述太阳能集热器一端设有卤水进口,另一端设有卤水出口;所述太阳能集热器的卤水出口通过管路与设置于卤水池上方的卤水进料单元连接;经太阳能集热器加热的卤水,在卤水池中的蒸发结晶,并通过管路回流至太阳能集热器完成循环。A solar energy evaporation and halogen extraction device comprises a solar collector, a brine feed unit, a brine pool and a crystal slurry outlet, wherein the solar collector has a brine inlet at one end and a brine outlet at the other end; The brine outlet of the solar collector is connected to the brine feed unit disposed above the brine pool through a pipeline; the brine heated by the solar collector is evaporated and crystallized in the brine pool, and is returned to the solar collector through the pipeline. The loop is completed.
所述太阳能集热器和卤水进料单元之间设有进料阀,所述卤水池后端还设有卤水储罐,所述卤水储罐的后端设有储罐球阀和回流泵。A feed valve is disposed between the solar collector and the brine feed unit, and a brine storage tank is further disposed at a rear end of the brine pool, and a rear end of the brine storage tank is provided with a tank ball valve and a reflux pump.
所述卤水池上方的卤水进料单元包括均布的多个喷淋头组和喷淋循环管路,所述喷淋循环管路的自由端开口并设置于卤水池内,另一端通过喷淋循环泵与喷淋头组相连。The brine feed unit above the brine pool comprises a plurality of uniform shower head sets and a spray circulation line, the free end of the spray circulation line is open and disposed in the brine pool, and the other end is sprayed through the spray cycle. The pump is connected to the shower head set.
所述卤水池外侧建有风道,所述风道的两长边及顶部封闭,两宽边处设开口;所述其中一开口端处设有风扇。An air duct is formed on the outer side of the brine pool, and the two long sides and the top of the air duct are closed, and the two wide sides are provided with openings; and one of the open ends is provided with a fan.
所述风扇由外部风动叶轮通过减速机构进行传动。The fan is driven by an external pneumatic impeller through a speed reduction mechanism.
所述风道为太阳能温室结构,其结构上部为透明玻璃或塑料顶棚,可吸收阳光热量提高卤水池周围温度。The air duct is a solar greenhouse structure, and the upper part of the structure is a transparent glass or plastic ceiling, which can absorb the heat of the sunlight and increase the temperature around the brine pool.
所述的太阳能集热器为全玻璃真空管式太阳能集热器,包括垂直设置的中间集流管和位于集流管两侧平行排布的玻璃真空管组,所述玻璃真空管的开口端与集流管相连通。The solar collector is an all-glass vacuum tube solar collector, comprising a vertically disposed intermediate header and a glass vacuum tube group arranged in parallel on both sides of the collector tube, the open end and the current collection of the glass vacuum tube The tubes are connected.
所述玻璃真空管的封闭端略高于其开口端,方便热载体循环。The closed end of the glass vacuum tube is slightly higher than the open end thereof to facilitate circulation of the heat carrier.
所述进料阀处设有温度传感器,可监控进料卤水温度,并实时控制阀门开启;所述卤水池中晶浆出口处设有温度和浓度传感器,当卤水池 中卤水蒸发至所需浓度时,控制晶浆出口的阀门开启,排出晶浆。The feed valve is provided with a temperature sensor for monitoring the temperature of the feed brine and controlling the opening of the valve in real time; a temperature and concentration sensor is arranged at the exit of the crystal slurry in the brine pool, and the brine is evaporated to the desired concentration in the brine pool. At the time, the valve controlling the outlet of the crystal slurry is opened to discharge the crystal slurry.
相对于现有技术,本实用新型的优势在于:Compared with the prior art, the advantages of the utility model are:
1)本实用新型结合盐湖地区实际情况,利用当地光照强的特点,因地制宜,提出利用太阳能集热器代替传统热蒸汽的装置,直接加热卤水,对卤水进行蒸发结晶处理,提取所需矿物质,热效率高,有效节约能源、降低对基础设施的要求,适于盐湖地区大面积推广。1) The utility model combines the actual conditions of the salt lake area, utilizes the characteristics of the local light intensity, and adopts a device that replaces the traditional hot steam by using a solar collector, directly heating the brine, evaporating and crystallizing the brine, and extracting the desired minerals. High thermal efficiency, effective energy conservation, and reduced infrastructure requirements are suitable for large-scale promotion in the salt lake area.
2)蒸发过程中结合风道一端的风扇组和卤水池上方的喷淋***,通过增大蒸发表面积和增强空气流速降低蒸发区域空气湿度的方法,进一步加强蒸发效果;同时,喷淋出的水帘可冲散卤水池表面由于蒸发结晶析出的表面盐层,加速蒸发。2) In the evaporation process, the fan group at one end of the air duct and the spray system above the brine pool are used to further reduce the evaporation effect by increasing the evaporation surface area and increasing the air flow rate to reduce the air humidity in the evaporation area; meanwhile, the sprayed water The curtain can flush out the surface salt layer deposited on the surface of the brine pool due to evaporation and accelerate evaporation.
3)本实用新型通过设置温室式结构风道,增强空气流速的同时也可利用太阳辐射直接加温室内空气,结合风扇降低区域空气湿度,加强蒸发效果。3) The utility model can increase the air flow rate by setting the greenhouse type air duct, and can also directly add the air in the greenhouse by using the solar radiation, and combine the fan to reduce the regional air humidity and enhance the evaporation effect.
4)本实用新型采用特殊设计的横排式玻璃真空管太阳能集热器,有效解决了热载体循环问题。4) The utility model adopts a specially designed horizontal-row glass vacuum tube solar collector to effectively solve the problem of heat carrier circulation.
附图说明DRAWINGS
图1为本实用新型实施例的结构示意图Figure 1 is a schematic view of the structure of the embodiment of the present invention
具体实施方式Detailed ways
以下是本实用新型内容的具体实施例,用于阐述本申请文件中所要解决技术问题的技术方案,有助于本领域技术人员理解本实用新型内容,但本实用新型技术方案的实现并不限于这些实施例。The following is a specific embodiment of the content of the present invention, which is used to explain the technical solution to solve the technical problem in the present application, and helps the person skilled in the art to understand the content of the present invention, but the implementation of the technical solution of the present invention is not limited to These embodiments.
一种太阳能蒸发提卤设备,包括太阳能集热器1、卤水进料单元2、 卤水池3、晶浆出口4,其特征在于:所述太阳能集热器1一端设有卤水进口,另一端设有卤水出口;所述太阳能集热器1的卤水出口通过管路与设置于卤水池3上方的卤水进料单元2连接;经太阳能集热器加热的卤水,在卤水池3中的蒸发结晶,并通过管路回流至太阳能集热器1完成循环。所述太阳能集热器1和卤水进料单元2之间设有进料阀6,所述卤水池3后端还设有卤水储罐5,所述卤水储罐5的后端设有储罐球阀7和回流泵8。A solar energy evaporation and halogen extraction device comprises a solar collector 1, a brine feed unit 2, a brine pool 3, and a crystal slurry outlet 4, wherein the solar collector 1 is provided with a brine inlet at one end and the other end is provided. There is a brine outlet; the brine outlet of the solar collector 1 is connected to the brine feed unit 2 disposed above the brine pool 3 through a pipeline; the brine heated by the solar collector is evaporated and crystallized in the brine pool 3, And the circulation is completed by returning the pipeline to the solar collector 1. A feed valve 6 is disposed between the solar collector 1 and the brine feed unit 2, and a brine storage tank 5 is further disposed at a rear end of the brine pool 3. The rear end of the brine storage tank 5 is provided with a storage tank Ball valve 7 and return pump 8.
所述卤水池上方的卤水进料单元2包括均布的多个喷淋头组201和喷淋循环管路202,所述喷淋循环管路202的自由端204设置于卤水池内,另一端通过喷淋循环泵203与喷淋头组201相连。The brine feed unit 2 above the brine pool comprises a plurality of uniform showerhead sets 201 and a spray circulation line 202. The free end 204 of the spray circulation line 202 is disposed in the brine pool and passes through the other end. The spray circulation pump 203 is connected to the shower head group 201.
所述卤水池3外侧建有风道12,所述风道的两长边及顶部封闭,两宽边处设开口;所述其中一开口端处设有风扇9。所述风扇9由外部风动叶轮11通过减速机构10进行传动。所述风道12为太阳能温室结构,其结构上部为透明玻璃或塑料顶棚,可吸收阳光热量提高卤水池周围空气温度,促进蒸发。An air duct 12 is formed on the outer side of the brine pool 3. The two long sides and the top of the air duct are closed, and the two wide sides are provided with openings; and one of the open ends is provided with a fan 9. The fan 9 is driven by the external pneumatic impeller 11 through the speed reduction mechanism 10. The air duct 12 is a solar greenhouse structure, and the upper part of the structure is a transparent glass or plastic ceiling, which can absorb the heat of the sunlight to increase the temperature of the air around the brine pool and promote evaporation.
所述的太阳能集热器1为全玻璃真空管式太阳能集热器,包括垂直设置的中间集流管和位于集流管两侧平行排布的玻璃真空管组,所述玻璃真空管的开口端与集流管相连通。所述玻璃真空管的封闭端略高于其开口端,便于玻璃真空管内热载体完全排净。The solar collector 1 is an all-glass vacuum tube solar collector, comprising a vertically disposed intermediate header and a glass vacuum tube group arranged in parallel on both sides of the collector tube, the open end and the set of the glass vacuum tube The flow tubes are connected. The closed end of the glass vacuum tube is slightly higher than the open end thereof, so that the heat carrier in the glass vacuum tube is completely drained.
所述进料阀6处设有温度传感器,可监控进料卤水温度,并实时控制阀门开启;所述卤水池3中晶浆出口4处设有温度和浓度传感器,当卤水池中卤水蒸发至所需浓度时,控制晶浆出口的阀门开启,排出晶浆。The feed valve 6 is provided with a temperature sensor for monitoring the temperature of the feed brine and controlling the opening of the valve in real time; the temperature and concentration sensor is arranged at the outlet 4 of the brine in the brine pool 3, when the brine in the brine pool is evaporated to At the desired concentration, the valve that controls the exit of the slurry opens and discharges the slurry.
本实用新型装置的工作流程为:The working process of the device of the utility model is:
利用太阳能集热器加热卤水,当卤水加热到指定温度时,打开进料阀,通过卤水进料单元注入热卤水,热卤水在卤水池中进行水分蒸发,冷却后的卤水经循环管路循环至太阳能集热器再次加热。蒸发过程中结合风道一端的风扇组和卤水池上方的喷淋***,通过增大蒸发表面积和增强空气流速降低蒸发区域空气湿度的方法,进一步加强蒸发效果;同时,喷淋出的水帘可冲散卤水池表面由于蒸发结晶析出的表面盐层,加速蒸发。当卤水池中浓度达到要求时,开启晶浆出口阀门,所述矿物质晶浆从晶浆出口排出,经后续工艺处理得到所需矿物质。The solar collector is used to heat the brine. When the brine is heated to the specified temperature, the feed valve is opened, the hot brine is injected through the brine feed unit, the hot brine is evaporated in the brine, and the cooled brine is circulated through the circulation line. The solar collector is heated again. During the evaporation process, the fan group at one end of the air duct and the spray system above the brine pool can further enhance the evaporation effect by increasing the evaporation surface area and increasing the air flow rate to reduce the air humidity in the evaporation area; meanwhile, the water curtain can be sprayed out. The surface of the brine pool is washed away by evaporation and crystallized to accelerate evaporation. When the concentration in the brine pool reaches the requirement, the crystal slurry outlet valve is opened, and the mineral crystal slurry is discharged from the crystal slurry outlet, and the desired mineral is obtained through subsequent processing.
本实用新型装置与现有技术对比The device of the utility model is compared with the prior art
Figure PCTCN2018114987-appb-000001
Figure PCTCN2018114987-appb-000001
从表中可以看出,从提取效率、提取纯度和处理周期看,本实用新型装置与工业上蒸汽源蒸发结晶装置均能达到较高水平,但本实用新型装置直接利用太阳能和风能,节能环保,对基础设施依赖度小。自然滩 晒法虽然直接利用太阳能,但占地面积巨大,易收外部环境变化影响,处理周期及提取效率均远低于本实用新型。It can be seen from the table that the apparatus of the present invention and the industrial vapor source evaporation crystallization apparatus can reach a high level in terms of extraction efficiency, extraction purity and treatment cycle, but the utility model directly utilizes solar energy and wind energy, and is energy-saving and environmentally friendly. , low dependence on infrastructure. Although the natural beach sun method directly uses solar energy, it has a large area and is easy to accept the influence of external environment changes. The treatment cycle and extraction efficiency are far lower than the utility model.
上述实施例仅仅是对本实用新型优选方案的说明,并不限制本实用新型。只要在本实用新型的实质精神范围内对上述实施例的变化、变型都应落入本申请的权利要求书请求保护的范围内。The above embodiments are merely illustrative of the preferred embodiments of the present invention and are not intended to limit the present invention. Variations and modifications of the above-described embodiments are intended to fall within the scope of the claims as claimed in the appended claims.

Claims (9)

  1. 一种太阳能蒸发提卤设备,包括太阳能集热器(1)、卤水进料单元(2)、卤水池(3)、晶浆出口(4),其特征在于:所述太阳能集热器(1)一端设有卤水进口,另一端设有卤水出口;所述太阳能集热器(1)的卤水出口通过管路与设置于卤水池(3)上方的卤水进料单元(2)连接;经太阳能集热器加热的卤水,在卤水池(3)中的蒸发结晶,并通过管路回流至太阳能集热器(1)完成循环。A solar energy evaporation and halogen extraction device comprises a solar collector (1), a brine feed unit (2), a brine pool (3), and a crystal slurry outlet (4), characterized in that: the solar collector (1) a brine inlet at one end and a brine outlet at the other end; the brine outlet of the solar collector (1) is connected to a brine feed unit (2) disposed above the brine pool (3) via a pipeline; The brine heated by the collector is evaporated and crystallized in the brine pool (3), and is returned to the solar collector (1) through the pipeline to complete the cycle.
  2. 根据权利要求1所述的太阳能蒸发提卤设备,其特征在于:所述太阳能集热器(1)和卤水进料单元(2)之间设有进料阀(6),所述卤水池(3)后端还设有卤水储罐(5),所述卤水储罐(5)的后端设有储罐球阀(7)和回流泵(8)。The solar evaporation halogen extraction device according to claim 1, characterized in that: between the solar collector (1) and the brine feed unit (2), a feed valve (6) is provided, the brine pool ( 3) The rear end is further provided with a brine storage tank (5), and a rear end of the brine storage tank (5) is provided with a tank ball valve (7) and a return pump (8).
  3. 根据权利要求1所述的太阳能蒸发提卤设备,其特征在于:所述卤水池上方的卤水进料单元(2)包括均布的多个喷淋头组(201)和喷淋循环管路(202),所述喷淋循环管路(202)的自由端(204)设置于卤水池内,另一端通过喷淋循环泵(203)与喷淋头组(201)相连。The solar evaporation halogen extraction device according to claim 1, characterized in that the brine feed unit (2) above the brine pool comprises a plurality of uniform showerhead sets (201) and a spray circulation line ( 202), the free end (204) of the spray circulation line (202) is disposed in the brine pool, and the other end is connected to the shower head set (201) through a spray circulation pump (203).
  4. 根据权利要求1所述的太阳能蒸发提卤设备,其特征在于:所述卤水池(3)外侧建有风道(12),所述风道的两长边及顶部封闭,两宽边处设开口;所述其中一开口端处设有风扇(9)。The solar energy evaporation and halogen extraction device according to claim 1, characterized in that: the outer side of the brine pool (3) is provided with a duct (12), the two long sides and the top of the air duct are closed, and the two wide sides are arranged An opening; a fan (9) is disposed at one of the open ends.
  5. 根据权利要求4所述的太阳能蒸发提卤设备,其特征在于:所述风扇(9)由外部风动叶轮(11)通过减速机构(10)传动。The solar evaporation evacuation device according to claim 4, characterized in that the fan (9) is driven by an external pneumatic impeller (11) through a reduction mechanism (10).
  6. 根据权利要求4所述的太阳能蒸发提卤设备,其特征在于:所述风道(12)为太阳能温室结构,其结构上部为透明玻璃或塑料顶棚,可吸收阳光热量提高卤水池周围温度。The solar energy evaporation and halogen extraction device according to claim 4, wherein the air passage (12) is a solar greenhouse structure, and the upper part of the structure is a transparent glass or plastic ceiling, which can absorb sunlight heat and increase the temperature around the brine pool.
  7. 根据权利要求1所述的太阳能蒸发提卤设备,其特征在于:所述的太阳能集热器(1)为全玻璃真空管式太阳能集热器,包括垂直设置的中间集流管和位于集流管两侧平行排布的玻璃真空管组,所述玻璃真空管的开口端与集流管相连通。The solar evaporation halogen extraction device according to claim 1, wherein the solar collector (1) is an all-glass vacuum tube solar collector, comprising a vertically disposed intermediate header and a collector. A glass vacuum tube set arranged in parallel on both sides, the open end of the glass vacuum tube being in communication with the header.
  8. 根据权利要求7所述的太阳能蒸发提卤设备,其特征在于:所述玻璃真空管的封闭端略高于其开口端。The solar evaporation halogen extraction apparatus according to claim 7, wherein the closed end of the glass vacuum tube is slightly higher than the open end thereof.
  9. 根据权利要求1所述的太阳能蒸发提卤设备,其特征在于:所述进料阀(6)处设有温度传感器,所述卤水池(3)中晶浆出口处设有温度和浓度传感器。The solar evaporation and halogen extraction device according to claim 1, characterized in that: the feed valve (6) is provided with a temperature sensor, and a temperature and concentration sensor is arranged at the outlet of the crystal slurry in the brine pool (3).
PCT/CN2018/114987 2017-11-22 2018-11-12 Device for brine evaporation and extraction by solar energy WO2019100956A1 (en)

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CN207680079U (en) * 2017-11-22 2018-08-03 西安威西特消防科技有限责任公司 A kind of evaporation of solar energy puies forward halogen equipment
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