WO2019037746A1 - 发泡织物结构及其制造方法 - Google Patents

发泡织物结构及其制造方法 Download PDF

Info

Publication number
WO2019037746A1
WO2019037746A1 PCT/CN2018/101834 CN2018101834W WO2019037746A1 WO 2019037746 A1 WO2019037746 A1 WO 2019037746A1 CN 2018101834 W CN2018101834 W CN 2018101834W WO 2019037746 A1 WO2019037746 A1 WO 2019037746A1
Authority
WO
WIPO (PCT)
Prior art keywords
thermoplastic polyester
polyester elastomer
foamed
fabric structure
yarns
Prior art date
Application number
PCT/CN2018/101834
Other languages
English (en)
French (fr)
Inventor
陆一平
Original Assignee
清远广硕技研服务有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 清远广硕技研服务有限公司 filed Critical 清远广硕技研服务有限公司
Priority to EP18848512.2A priority Critical patent/EP3674460A1/en
Priority to US16/640,384 priority patent/US20200362483A1/en
Publication of WO2019037746A1 publication Critical patent/WO2019037746A1/zh

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
    • D01D5/247—Discontinuous hollow structure or microporous structure
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D02G3/045—Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04C—BRAIDING OR MANUFACTURE OF LACE, INCLUDING BOBBIN-NET OR CARBONISED LACE; BRAIDING MACHINES; BRAID; LACE
    • D04C1/00—Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof
    • D04C1/02—Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof made from particular materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0004—Use of compounding ingredients, the chemical constitution of which is unknown, broadly defined, or irrelevant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/08—Addition of substances to the spinning solution or to the melt for forming hollow filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • D01F6/86—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from polyetheresters
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/32—Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/56—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/06—Flexible foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • D01F6/84—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyesters
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/04—Heat-responsive characteristics
    • D10B2401/041—Heat-responsive characteristics thermoplastic; thermosetting
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/06—Load-responsive characteristics
    • D10B2401/061—Load-responsive characteristics elastic
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/08—Physical properties foamed

Definitions

  • the present invention relates to a foamed fabric structure and a method of making a foamed fabric structure.
  • the sole of the footwear In order to make the user feel comfortable and reduce the burden, the sole of the footwear often uses a resilient material/structure. Further, in addition to having excellent elasticity to absorb vibration during walking and providing double-foot cushioning for comfort, the elastic structure for manufacturing a footwear sole preferably has a lighter weight to reduce the burden on the user. .
  • One of the common practices is to place the foamed material on the bottom layer in a simple tiling manner.
  • this approach there are other ways to further increase the flexibility.
  • the main object of the present invention is to provide a foamed fabric structure which has better elasticity.
  • Another object of the present invention is to provide a method for producing a foamed fabric structure which can produce a foamed fabric structure having better elasticity.
  • the expanded fabric structure of the present invention comprises a plurality of thermoplastic polyester elastomer yarns woven with each other, wherein the plurality of thermoplastic polyester elastomer yarns are already foamed.
  • the plurality of thermoplastic polyester elastomer yarns are in contact with each other at the weaving intersection and are squeezed to sink inward.
  • thermoplastic polyester elastomer yarn is squeezed inward by the first yarn.
  • the foamed fabric structure comprises a plurality of mixed yarns woven with each other, wherein the mixed yarn is formed by mixing and twisting the first yarn with the thermoplastic polyester elastomer yarn, wherein The thermoplastic polyester elastomer yarn in the plurality of mixed yarns is foamed.
  • the expanded fabric structure comprises a plurality of thermoplastic polyester elastomer yarns interwoven with each other and a plurality of first yarns, wherein the plurality of thermoplastic polyester elastomer yarns are foamed.
  • the foamed fabric structure manufacturing method of the present invention comprises: Step 1010: providing a thermoplastic polyester elastomer; Step 1020: mixing a foaming agent into the thermoplastic polyester elastomer to form a thermoplastic polyester elastomer mixture; Step 1030: Thermoplastic polyester Elastomeric mixture is drawn to obtain a thermoplastic polyester elastomer blend yarn; Step 1040: Woven using a plurality of thermoplastic polyester elastomer blend yarns to obtain a thermoplastic polyester elastomer fabric; Step 1050: Thermoplastic polyester elastomer fabric Foaming to obtain a foamed fabric structure.
  • the foamed fabric structure manufacturing method comprises: step 1010: providing a thermoplastic polyester elastomer; and step 1020: mixing a foaming agent into the thermoplastic polyester elastomer to form a thermoplastic polyester elastomer mixture; 1030: The thermoplastic polyester elastomer mixture is drawn to obtain a thermoplastic polyester elastomer mixture yarn; Step 1041: the thermoplastic polyester elastomer mixture yarn is spun and kneaded with the first yarn to obtain a mixed yarn; Step 1042: Weaving using a plurality of mixed yarns to obtain a thermoplastic polyester elastomer fabric; Step 1050: foaming the thermoplastic polyester elastomer fabric to obtain a foamed fabric structure.
  • the foamed fabric structure manufacturing method comprises: step 1010: providing a thermoplastic polyester elastomer; and step 1020: mixing a foaming agent into the thermoplastic polyester elastomer to form a thermoplastic polyester elastomer mixture; 1030: drawing a thermoplastic polyester elastomer mixture to obtain a thermoplastic polyester elastomer mixture yarn; step 1043: providing a first yarn; and step 1044: using a plurality of thermoplastic polyester elastomer mixture yarns and a plurality of first yarns
  • the wire is woven to obtain a thermoplastic polyester elastomer fabric; step 1050: the thermoplastic polyester elastomer fabric is foamed to obtain a foamed fabric structure.
  • step 1020 comprises: step 1021: heating the thermoplastic polyester elastomer to form a molten state; and step 1022: mixing the blowing agent into the molten thermoplastic polyester elastomer.
  • the blowing agent used in step 1020 is a chemical blowing agent; and step 1050 comprises heating the thermoplastic polyester elastomer fabric to foam it to obtain a foamed fabric structure.
  • the method before step 1050, further comprises: step 1049: placing the thermoplastic polyester elastomer fabric into the mold, wherein the mold has a cavity; and step 1050 comprises foaming the thermoplastic polyester elastomer fabric to obtain A foamed fabric structure that is complementary to the shape of the cavity.
  • the foamed fabric structure of the present invention has a preferred elasticity, and the foamed fabric structure manufacturing method can be used to manufacture the above-described foamed fabric structure, which provides a solution to the problems described in the prior art.
  • FIG. 1A is a top plan view showing an embodiment of a foamed fabric structure of the present invention.
  • FIG. 1B is a top plan view showing a foamed fabric structure of the present invention in a foamed embodiment
  • FIG. 2A is a top plan view showing different embodiments of the foamed fabric structure of the present invention.
  • 2B is a schematic view showing an embodiment of a mixed yarn in the present invention.
  • FIG. 3 is a top plan view showing another embodiment of the foamed fabric structure of the present invention.
  • FIG. 4A is a schematic flow chart of an embodiment of a method for manufacturing a foamed fabric structure according to the present invention.
  • 4B to 6 are schematic flow charts showing different embodiments of a method for manufacturing a foamed fabric structure according to the present invention.
  • thermoplastic polyester elastomer yarn 100 thermoplastic polyester elastomer yarn
  • the fabric structure of the present invention is used as a sole for footwear, particularly a midsole, based on its elasticity and light weight.
  • the foamed fabric structure of the present invention can be used for other purposes, such as a cushion for a backpack, a hard hat inner casing or a brace.
  • the foamed fabric structure 810 of the present invention comprises a plurality of thermoplastic polyester elastomer (TPEE) yarns 100 interwoven with each other, wherein the plurality of thermoplastic polyester elastomer yarns 100 It has been foamed.
  • TPEE thermoplastic polyester elastomer
  • a plurality of thermoplastic polyester elastomer yarns 100 can be woven using a weave such as woven and knitted.
  • FIG. 1B a plurality of thermoplastic polyester elastomer mixture yarns 101 mixed with a foaming agent but not yet foamed are previously woven into a woven structure 801, and then foamed by heating or the like.
  • Foamed fabric structure 810 as shown in 1A.
  • the foamed fabric structure is woven from the foamed thermoplastic polyester elastomer yarn, it has good elasticity.
  • the voids between the yarns in the foamed fabric structure also provide additional cushioning space, further enhancing the overall elasticity of the foamed fabric structure.
  • the foamed thermoplastic polyester elastomer yarn has elasticity and can be squeezed inward by an external force, a plurality of thermoplastic polyester elastomer yarns can also contact and be pressed at the weaving intersection. Caught inward.
  • the expanded fabric structure is not limited to being woven solely from thermoplastic polyester elastomer yarns, and may be woven with other yarns depending on the manufacturing or use requirements.
  • the foamed fabric structure 820 includes a plurality of hybrid yarns 200 that are woven together.
  • the mixed yarn 200 is formed by mixing and kneading the first yarn 300 with the thermoplastic polyester elastomer yarn 100, wherein the thermoplastic polyester elastomer in the plurality of mixed yarns 200 is formed. Yarn 100 is already foamed.
  • the expanded fabric structure 830 comprises a plurality of thermoplastic polyester elastomer yarns 100 woven together and a plurality of first yarns 300, wherein the plurality of thermoplastic polyester elastomer yarns 100 are Foaming.
  • the thermoplastic polyester elastomer yarn is pressed by the first yarn to be caught inward.
  • the foamed fabric structure manufacturing method of the present invention comprises, for example, the following steps.
  • thermoplastic polyester elastomer a thermoplastic polyester elastomer (TPEE) is provided.
  • TPEE thermoplastic polyester elastomer
  • a particulate thermoplastic polyester elastomer or a molten thermoplastic polyester elastomer can be provided.
  • step 1020 a blowing agent is blended into the thermoplastic polyester elastomer to form a thermoplastic polyester elastomer mixture.
  • step 1020 includes: step 1021, heating the thermoplastic polyester elastomer to form a molten state; and step 1022, mixing the blowing agent into the molten thermoplastic polyester elastomer.
  • thermoplastic polyester elastomer mixture is drawn to obtain a thermoplastic polyester elastomer blend yarn.
  • the thermoplastic polyester elastomer mixture yarn can be operated on various knitting equipments, including circular machines, flat knitting machines, woven fabrics, etc., and is suitable for wire diameter standards of various equipment knitting conditions.
  • thermoplastic polyester elastomer blend yarns are woven to obtain a thermoplastic polyester elastomer fabric. More specifically, weaving is performed using a plurality of thermoplastic polyester elastomer blend yarns to obtain a fabric structure 801 as shown in FIG. 1B.
  • the thermoplastic polyester elastomeric fabric is foamed to obtain a foamed fabric structure. More specifically, the fabric structure 801 as shown in FIG. 1B is foamed to obtain a foamed fabric structure 810 as shown in FIG. 1A.
  • the yarn having the thermoplastic polyester elastomer is first woven and then foamed, so that it has better weaving workability.
  • the foamed thermoplastic polyester elastomer has a relatively large diameter and a low density and is less convenient for weaving, the foamed fabric structure of the present invention is manufactured by first weaving and then foaming. The way to improve the operability of the process.
  • the blowing agent used in the foregoing step 1020 is a chemical blowing agent.
  • step 1050 includes heating the thermoplastic polyester elastomer fabric to foam it to obtain a foamed fabric structure.
  • the method further includes: step 1049: placing the thermoplastic polyester elastomer fabric into the mold, wherein the mold has a cavity; and step 1050 comprises foaming the thermoplastic polyester elastomer fabric to obtain a shape complementary to the cavity shape. Foamed fabric structure. More specifically, since the thermoplastic polyester elastomer has thermoplasticity so that the thermoplastic polyester elastomer fabric also has thermoplasticity, the thermoplastic polyester elastomer fabric can be molded into a mold while being heated and foamed in a mold. The cavity shape complements the foamed fabric structure.
  • the foamed fabric structure manufacturing method of the present invention comprises, for example, the following steps.
  • thermoplastic polyester elastomer is provided.
  • step 1020 a blowing agent is blended into the thermoplastic polyester elastomer to form a thermoplastic polyester elastomer mixture.
  • thermoplastic polyester elastomer mixture is drawn to obtain a thermoplastic polyester elastomer blend yarn.
  • step 1041 the thermoplastic polyester elastomer mixture yarn is spun and kneaded with the first yarn to obtain a mixed yarn.
  • step 1042 a plurality of mixed yarns are used for weaving to obtain a thermoplastic polyester elastomer fabric.
  • thermoplastic polyester elastomeric fabric is foamed to obtain a foamed fabric structure. More specifically, the thermoplastic polyester elastomeric fabric is foamed to obtain a foamed fabric structure 820 as shown in Figure 2A.
  • the foamed fabric structure manufacturing method of the present invention comprises, for example, the following steps.
  • thermoplastic polyester elastomer is provided.
  • step 1020 a blowing agent is blended into the thermoplastic polyester elastomer to form a thermoplastic polyester elastomer mixture.
  • thermoplastic polyester elastomer mixture is drawn to obtain a thermoplastic polyester elastomer blend yarn.
  • step 1043 a first yarn is provided.
  • thermoplastic polyester elastomer blend yarns and a plurality of first yarns are woven to obtain a thermoplastic polyester elastomer fabric.
  • thermoplastic polyester elastomeric fabric is foamed to obtain a foamed fabric structure. More specifically, the thermoplastic polyester elastomer fabric is foamed to obtain a foamed fabric structure 830 as shown in FIG.
  • the foamed fabric structure of the present invention has a preferred elasticity, and the foamed fabric structure manufacturing method can be used to manufacture the above-described foamed fabric structure, which provides a solution to the problems described in the prior art.
  • the foamed fabric structure of the present invention has a preferred elasticity, and the foamed fabric structure manufacturing method can be used to manufacture the above-described foamed fabric structure.
  • the fabric structure of the present invention is used as a sole for footwear, especially a midsole, based on its elasticity and light weight.
  • the foamed fabric structure of the present invention can also be used for other purposes, such as a cushion for a backpack, a hard hat inner casing or a brace.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Woven Fabrics (AREA)

Abstract

公开了一种发泡织物结构及其制造方法。该发泡织物结构包含相互编织的多条热塑性聚酯弹性体纱线（100），其中多条热塑性聚酯弹性体纱线（100）为已发泡。该发泡织物结构制造方法包含下列步骤：提供热塑性聚酯弹性体；将发泡剂混入热塑性聚酯弹性体以形成热塑性聚酯弹性体混合物；对热塑性聚酯弹性体混合物抽纱以获得热塑性聚酯弹性体混合物纱线；使用多条热塑性聚酯弹性体混合物纱线进行编织以获得热塑性聚酯弹性体织物；以及将热塑性聚酯弹性体织物发泡以获得发泡织物结构。

Description

发泡织物结构及其制造方法 技术领域
本发明是有关于一种发泡织物结构以及一种发泡织物结构制造方法。
背景技术
为了让使用者感到舒适并减轻其负担，鞋类的鞋底经常使用具有弹性的材料/结构。进一步而言，用于制造鞋类鞋底的弹性结构除了具有优良的弹性以吸收行走时的震动、提供双脚缓冲以提升舒适度外，较佳亦应具有较轻的重量以减轻使用者的负担。
常见的作法之一是将发泡材料以单纯平铺覆盖方式设置于底层上。然而，除了此方式外，仍有其他方式可进一步增加弹性。
发明的公开
本发明的主要目的在于提供一种发泡织物结构，具有较佳的弹性。
本发明的另一目的在于提供一种发泡织物结构制造方法，可制造具有较佳的弹性的发泡织物结构。
本发明的发泡织物结构包含相互编织的多条热塑性聚酯弹性体纱线，其中多条热塑性聚酯弹性体纱线为已发泡。
在本发明的一实施例中，多条热塑性聚酯弹性体纱线于编织交会处相互接触并挤压而向内陷入。
在本发明的一实施例中，热塑性聚酯弹性体纱线被第一纱线挤压而向内陷入。
在本发明的一实施例中，发泡织物结构包含相互编织的多条混合纱线，其中混合纱线由第一纱线与热塑性聚酯弹性体纱线混合纺制与捻合而成，其中多条混合纱线中的热塑性聚酯弹性体纱线为已发泡。
在本发明的一实施例中，发泡织物结构包含相互编织的多条热塑性聚酯 弹性体纱线以及多条第一纱线，其中多条热塑性聚酯弹性体纱线为已发泡。
本发明的发泡织物结构制造方法包含：步骤1010：提供热塑性聚酯弹性体；步骤1020：将发泡剂混入热塑性聚酯弹性体以形成热塑性聚酯弹性体混合物；步骤1030：对热塑性聚酯弹性体混合物抽纱以获得热塑性聚酯弹性体混合物纱线；步骤1040：使用多条热塑性聚酯弹性体混合物纱线进行编织以获得热塑性聚酯弹性体织物；步骤1050：将热塑性聚酯弹性体织物发泡以获得发泡织物结构。
在本发明的一实施例中，发泡织物结构制造方法包含：步骤1010：提供热塑性聚酯弹性体；步骤1020：将发泡剂混入热塑性聚酯弹性体以形成热塑性聚酯弹性体混合物；步骤1030：对热塑性聚酯弹性体混合物抽纱以获得热塑性聚酯弹性体混合物纱线；步骤1041：将热塑性聚酯弹性体混合物纱线与第一纱线混合纺制与捻合以获得混合纱线；步骤1042：使用多条混合纱线进行编织以获得热塑性聚酯弹性体织物；步骤1050：将热塑性聚酯弹性体织物发泡以获得发泡织物结构。
在本发明的一实施例中，发泡织物结构制造方法包含：步骤1010：提供热塑性聚酯弹性体；步骤1020：将发泡剂混入热塑性聚酯弹性体以形成热塑性聚酯弹性体混合物；步骤1030：对热塑性聚酯弹性体混合物抽纱以获得热塑性聚酯弹性体混合物纱线；步骤1043：提供第一纱线；步骤1044：使用多条热塑性聚酯弹性体混合物纱线以及多条第一纱线进行编织以获得热塑性聚酯弹性体织物；步骤1050：将热塑性聚酯弹性体织物发泡以获得发泡织物结构。在本发明的一实施例中，步骤1020包含：步骤1021：将热塑性聚酯弹性体加热形成熔融状态；步骤1022：将发泡剂混入熔融状态的热塑性聚酯弹性体。
在本发明的一实施例中，步骤1020使用的发泡剂为化学发泡剂；步骤1050包含对热塑性聚酯弹性体织物加热以使其发泡而获得发泡织物结构。
在本发明的一实施例中，步骤1050之前还包括：步骤1049：将热塑性聚酯弹性体织物放入模具中，其中模具具有型腔；步骤1050包含将热塑性 聚酯弹性体织物发泡以获得与型腔形状互补的发泡织物结构。
基于上述，本发明的发泡织物结构具有较佳的弹性，发泡织物结构制造方法可用于制造上述发泡织物结构，对现有技术中所述的问题给出了解决方案。
附图的简要说明
图1A为本发明的发泡织物结构的实施例俯视示意图；
图1B为本发明的发泡织物结构在发泡的实施例俯视示意图；
图2A为本发明发泡织物结构的不同实施例俯视示意图；
图2B为本发明中混合纱线的实施例示意图；
图3为本发明发泡织物结构的另一实施例俯视示意图；
图4A为本发明发泡织物结构制造方法的实施例流程示意图；
图4B到6为本发明发泡织物结构制造方法的不同实施例流程示意图。
主要元件符号说明：
100 热塑性聚酯弹性体纱线
101 热塑性聚酯弹性体混合物纱线
200 混合纱线
300 第一纱线
801 织物结构
810 发泡织物结构
820 发泡织物结构
830 发泡织物结构
1010 步骤
1020 步骤
1021 步骤
1022 步骤
1030 步骤
1040 步骤
1041 步骤
1042 步骤
1043 步骤
1044 步骤
1049 步骤
1050 步骤
实现本发明的最佳方式
以较佳实施例而言，基于具有弹性及较轻的重量，本发明的织物结构是作为鞋类的鞋底、尤其是中底(midsole)使用。然而在不同实施例中，本发明的发泡织物结构可作为其他用途，例如作为背包的缓冲垫、安全帽内壳或护具等。
如图1A所示的实施例，本发明的发泡织物结构810包含相互编织的多条热塑性聚酯弹性体(thermoplastic polyester elastomer，TPEE)纱线100，其中多条热塑性聚酯弹性体纱线100为已发泡。其中，多条热塑性聚酯弹性体纱线100可使用例如梭织与针织等织法编织。进一步而言，如图1B所示，混有发泡剂但尚未发泡的多条热塑性聚酯弹性体混合物纱线101是在先编织成织物结构801，而后利用加热等方式发泡形成如图1A所示的发泡织物结构810。
由于发泡织物结构是由已发泡的热塑性聚酯弹性体纱线编织而成，故其具有良好的弹性。此外，除了已发泡的热塑性聚酯弹性体纱线本身具有弹性外，发泡织物结构中纱线间的空隙也提供额外的缓冲空间，进一步提升了发泡织物结构整体的弹性。另一方面，因为已发泡的热塑性聚酯弹性体纱线具有弹性可受外力挤压而向内陷入，所以多条热塑性聚酯弹性体纱线还可于编织交会处相互接触并挤压而向内陷入。
在不同实施例中，发泡织物结构不限于纯粹由热塑性聚酯弹性体纱线编 织而成，可视制造或使用需求与其他纱线混合编织。举例而言，如图2A所示的实施例，发泡织物结构820包含相互编织的多条混合纱线200。其中，如图2B所示，混合纱线200由第一纱线300与热塑性聚酯弹性体纱线100混合纺制与捻合而成，其中多条混合纱线200中的热塑性聚酯弹性体纱线100为已发泡。如图3所示的实施例，发泡织物结构830包含相互编织的多条热塑性聚酯弹性体纱线100以及多条第一纱线300，其中多条热塑性聚酯弹性体纱线100为已发泡。另一方面，在图2A至图3所示的实施例中，热塑性聚酯弹性体纱线被第一纱线挤压而向内陷入。
如图4A所示的实施例流程图，本发明的发泡织物结构制造方法包含例如以下步骤。
步骤1010，提供热塑性聚酯弹性体(thermoplastic polyester elastomer，TPEE)。其中，可提供颗粒状的热塑性聚酯弹性体或熔融状的热塑性聚酯弹性体。
步骤1020，将发泡剂混入热塑性聚酯弹性体以形成热塑性聚酯弹性体混合物。以较佳实施例而言，步骤1020包含：步骤1021，将热塑性聚酯弹性体加热形成熔融状态；以及步骤1022，将发泡剂混入熔融状态的热塑性聚酯弹性体。
步骤1030，对热塑性聚酯弹性体混合物抽纱以获得热塑性聚酯弹性体混合物纱线。其中，热塑性聚酯弹性体混合物纱线可操作于各种编织设备，包含圆机、横机、梭织等，且适合各种设备编织条件的线径标准。
步骤1040，使用多条热塑性聚酯弹性体混合物纱线进行编织以获得热塑性聚酯弹性体织物。更具体而言，是使用多条热塑性聚酯弹性体混合物纱线进行编织以获得如图1B所示的织物结构801。
步骤1050，将热塑性聚酯弹性体织物发泡以获得发泡织物结构。更具体而言，是将如图1B所示的织物结构801发泡，以获得如图1A所示的发泡织物结构810。
综上所述，在本发明的发泡织物结构制造方法中，是先将具有热塑性聚 酯弹性体的纱线编织，然后再进行发泡，因此具有较佳的编织操作性。以不同角度观之，因为已发泡的具有热塑性聚酯弹性体的纱线线径较粗且密度较低，较不便于编织，所以本发明的发泡织物结构制造方法采用先编织再发泡的方式，由以提升工艺的可操作性。
如图4B所示，在较佳实施例中，前述步骤1020使用的发泡剂为化学发泡剂。与此对应的，步骤1050包含对热塑性聚酯弹性体织物加热以使其发泡而获得发泡织物结构。
另一方面，步骤1050之前还包括：步骤1049：将热塑性聚酯弹性体织物放入模具中，其中模具具有型腔；步骤1050包含将热塑性聚酯弹性体织物发泡以获得与型腔形状互补的发泡织物结构。更具体而言，因为热塑性聚酯弹性体具有热塑性，从而使热塑性聚酯弹性体织物亦具有热塑性，所以将热塑性聚酯弹性体织物放在模具中加热发泡的同时可以将其塑形成与模具的型腔形状互补的发泡织物结构。
如图5所示的本发明的另一实施例流程图，本发明的发泡织物结构制造方法包含例如以下步骤。
步骤1010，提供热塑性聚酯弹性体。
步骤1020，将发泡剂混入热塑性聚酯弹性体以形成热塑性聚酯弹性体混合物。
步骤1030，对热塑性聚酯弹性体混合物抽纱以获得热塑性聚酯弹性体混合物纱线。
步骤1041，将热塑性聚酯弹性体混合物纱线与第一纱线混合纺制与捻合以获得混合纱线。
步骤1042，使用多条混合纱线进行编织以获得热塑性聚酯弹性体织物。
步骤1050，将热塑性聚酯弹性体织物发泡以获得发泡织物结构。更具体而言，是将热塑性聚酯弹性体织物发泡以获得如图2A所示的发泡织物结构820。
如图6所示的本发明的另一实施例流程图，本发明的发泡织物结构制造 方法包含例如以下步骤。
步骤1010，提供热塑性聚酯弹性体。
步骤1020，将发泡剂混入热塑性聚酯弹性体以形成热塑性聚酯弹性体混合物。
步骤1030，对热塑性聚酯弹性体混合物抽纱以获得热塑性聚酯弹性体混合物纱线。
步骤1043，提供第一纱线。
步骤1044，使用多条热塑性聚酯弹性体混合物纱线以及多条第一纱线进行编织以获得热塑性聚酯弹性体织物。
步骤1050，将热塑性聚酯弹性体织物发泡以获得发泡织物结构。更具体而言，是将热塑性聚酯弹性体织物发泡以获得如图3所示的发泡织物结构830。
基于上述，本发明的发泡织物结构具有较佳的弹性，发泡织物结构制造方法可用于制造上述发泡织物结构，对现有技术中所述的问题给出了解决方案。
虽然前述的描述及附图已公开本发明的较佳实施例，必须了解到各种增添、许多修改和取代可能使用于本发明较佳实施例，而不会脱离如所附权利要求所界定的本发明原理的精神及范围。熟悉本发明所属技术领域的技术人员将可体会，本发明可使用于许多形式、结构、布置、比例、材料、元件和组件的修改。因此，本文于此所公开的实施例应被视为用以说明本发明，而非用以限制本发明。本发明的范围应由后附权利要求所界定，并涵盖其合法均等物，并不限于先前的描述。
工业应用性
本发明的发泡织物结构具有较佳的弹性，发泡织物结构制造方法可用于制造上述发泡织物结构。基于具有弹性及较轻的重量，本发明的织物结构是作为鞋类的鞋底、尤其是中底(midsole)使用。然而在实际应用中，本发明 的发泡织物结构还可作为其他用途，例如作为背包的缓冲垫、安全帽内壳或护具等。

Claims (11)

  1. 一种发泡织物结构，其特征在于，包含相互编织的多条热塑性聚酯弹性体纱线，其中所述多条热塑性聚酯弹性体纱线为已发泡。
  2. 如权利要求1所述的发泡织物结构，其特征在于，该多条热塑性聚酯弹性体纱线于编织交会处相互接触并挤压而向内陷入。
  3. 一种发泡织物结构，其特征在于，包含相互编织的多条混合纱线，其中所述混合纱线由一第一纱线与一热塑性聚酯弹性体纱线混合纺制与捻合而成，其中所述多条混合纱线中的热塑性聚酯弹性体纱线为已发泡。
  4. 一种发泡织物结构，其特征在于，包含相互编织的多条热塑性聚酯弹性体纱线以及多条第一纱线，其中所述多条热塑性聚酯弹性体纱线为已发泡。
  5. 如权利要求3或4所述的发泡织物结构，其特征在于，该热塑性聚酯弹性体纱线被该第一纱线挤压而向内陷入。
  6. 一种发泡织物结构制造方法，其特征在于，包含：
    步骤1010：提供一热塑性聚酯弹性体；
    步骤1020：将一发泡剂混入该热塑性聚酯弹性体以形成一热塑性聚酯弹性体混合物；
    步骤1030：对该热塑性聚酯弹性体混合物抽纱以获得一热塑性聚酯弹性体混合物纱线；
    步骤1040：使用多条该热塑性聚酯弹性体混合物纱线进行编织以获得一热塑性聚酯弹性体织物；
    步骤1050：将该热塑性聚酯弹性体织物发泡以获得该发泡织物结构。
  7. 一种发泡织物结构制造方法，其特征在于，包含：
    步骤1010：提供一热塑性聚酯弹性体；
    步骤1020：将一发泡剂混入该热塑性聚酯弹性体以形成一热塑性聚酯弹性体混合物；
    步骤1030：对该热塑性聚酯弹性体混合物抽纱以获得一热塑性聚酯弹 性体混合物纱线；
    步骤1041：将该热塑性聚酯弹性体混合物纱线与一第一纱线混合纺制与捻合以获得一混合纱线；
    步骤1042：使用多条该混合纱线进行编织以获得一热塑性聚酯弹性体织物；
    步骤1050：将该热塑性聚酯弹性体织物发泡以获得该发泡织物结构。
  8. 一种发泡织物结构制造方法，其特征在于，包含：
    步骤1010：提供一热塑性聚酯弹性体；
    步骤1020：将一发泡剂混入该热塑性聚酯弹性体以形成一热塑性聚酯弹性体混合物；
    步骤1030：对该热塑性聚酯弹性体混合物抽纱以获得一热塑性聚酯弹性体混合物纱线；
    步骤1043：提供一第一纱线；
    步骤1044：使用多条该热塑性聚酯弹性体混合物纱线以及多条该第一纱线进行编织以获得一热塑性聚酯弹性体织物；
    步骤1050：将该热塑性聚酯弹性体织物发泡以获得该发泡织物结构。
  9. 如权利要求6到8任一项所述的织物结构制造方法，其特征在于，该步骤1020包含：
    步骤1021：将该热塑性聚酯弹性体加热形成熔融状态；
    步骤1022：将该发泡剂混入熔融状态的该热塑性聚酯弹性体。
  10. 如权利要求6到8任一项所述的织物结构制造方法，其特征在于，
    该步骤1020使用的该发泡剂为化学发泡剂；
    该步骤1050包含对该热塑性聚酯弹性体织物加热以使其发泡而获得该发泡织物结构。
  11. 如权利要求6到8任一项所述的织物结构制造方法，其特征在于，
    在该步骤1050之前还包括：
    步骤1049：将该热塑性聚酯弹性体织物放入一模具中，其中该模具具 有一形腔；
    该步骤1050包含将该热塑性聚酯弹性体织物发泡以获得与该形腔形状互补的该发泡织物结构。
PCT/CN2018/101834 2017-08-24 2018-08-23 发泡织物结构及其制造方法 WO2019037746A1 (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP18848512.2A EP3674460A1 (en) 2017-08-24 2018-08-23 Foamed fabric structure and manufacturing method therefor
US16/640,384 US20200362483A1 (en) 2017-08-24 2018-08-23 Foamed fabric structure and manufacturing method thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710733670.8 2017-08-24
CN201710733670.8A CN109423769A (zh) 2017-08-24 2017-08-24 发泡织物结构及其制造方法

Publications (1)

Publication Number Publication Date
WO2019037746A1 true WO2019037746A1 (zh) 2019-02-28

Family

ID=65438418

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2018/101834 WO2019037746A1 (zh) 2017-08-24 2018-08-23 发泡织物结构及其制造方法

Country Status (5)

Country Link
US (1) US20200362483A1 (zh)
EP (1) EP3674460A1 (zh)
CN (1) CN109423769A (zh)
TW (1) TW201912398A (zh)
WO (1) WO2019037746A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021195498A1 (en) * 2020-03-27 2021-09-30 Zephyros, Inc. Foamable continuous filaments

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111038042A (zh) * 2019-12-31 2020-04-21 浙江华江科技股份有限公司 一种超轻高强高吸音纤维增强热塑性发泡复合板材及其制备方法
CN111560677B (zh) * 2020-05-11 2022-05-24 江苏华信亚麻纺织有限公司 一种内置空隙式亚麻包覆xla纤维的包芯纱的制备方法
CN111560689B (zh) * 2020-05-11 2021-11-05 江苏华信亚麻纺织有限公司 一种高弹性亚麻包覆xla纤维的丝光弹力面料及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3507741A (en) * 1966-04-26 1970-04-21 Du Pont Composite filament with elastomeric core and closed-cell foam sheath
WO2007103247A1 (en) * 2006-03-03 2007-09-13 Milliken & Company Needled three layered composite
CN102505347A (zh) * 2011-10-28 2012-06-20 中原工学院 应用超临界流体熔喷纺丝制备微孔纤维非织造布的方法
CN102850570A (zh) * 2012-09-24 2013-01-02 吴江市信许塑料鞋用配套有限公司 一种减震发泡鞋底材料的制备方法
CN104995351A (zh) * 2012-12-13 2015-10-21 十凯特荷兰有限公司 阻尼层以及制造方法
CN105350339A (zh) * 2014-08-22 2016-02-24 三芳化学工业股份有限公司 复合长纤维纺织品及用其制得的环保复合长纤维人工皮革

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB977513A (en) * 1961-06-29 1964-12-09 British Ropes Ltd Improvements in or relating to woven material
GB1229672A (zh) * 1968-02-26 1971-04-28
US3694873A (en) * 1970-04-02 1972-10-03 Richard P Crowley Method of preparing a tufted rug with cellular fibers
US20160309839A1 (en) * 2015-04-24 2016-10-27 Ji Sang Jang Shoe midsole coated with adhesive fabric
JP2017086295A (ja) * 2015-11-06 2017-05-25 株式会社イノアックコーポレーション 靴底用部材
TWI614111B (zh) * 2015-12-16 2018-02-11 寶成工業股份有限公司 熱可塑高分子之發泡鞋底及熱可塑高分子之發泡鞋底的製作方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3507741A (en) * 1966-04-26 1970-04-21 Du Pont Composite filament with elastomeric core and closed-cell foam sheath
WO2007103247A1 (en) * 2006-03-03 2007-09-13 Milliken & Company Needled three layered composite
CN102505347A (zh) * 2011-10-28 2012-06-20 中原工学院 应用超临界流体熔喷纺丝制备微孔纤维非织造布的方法
CN102850570A (zh) * 2012-09-24 2013-01-02 吴江市信许塑料鞋用配套有限公司 一种减震发泡鞋底材料的制备方法
CN104995351A (zh) * 2012-12-13 2015-10-21 十凯特荷兰有限公司 阻尼层以及制造方法
CN105350339A (zh) * 2014-08-22 2016-02-24 三芳化学工业股份有限公司 复合长纤维纺织品及用其制得的环保复合长纤维人工皮革

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021195498A1 (en) * 2020-03-27 2021-09-30 Zephyros, Inc. Foamable continuous filaments

Also Published As

Publication number Publication date
US20200362483A1 (en) 2020-11-19
EP3674460A1 (en) 2020-07-01
TW201912398A (zh) 2019-04-01
CN109423769A (zh) 2019-03-05

Similar Documents

Publication Publication Date Title
WO2019037746A1 (zh) 发泡织物结构及其制造方法
CN104995351B (zh) 阻尼层及其制造方法和使用方法以及一种纺织物
EP2487284A1 (en) Knitted glove
CN103504886A (zh) 可水洗长丝被
CN107920908A (zh) 热可塑性石膏
JP6654385B2 (ja) 可撓性加飾積層体、及び可撓性加飾積層体の製造方法
JP2012132123A (ja) 立体形状布帛
CN104762720A (zh) 一种复合面料
JP2000096322A (ja) 背抜き手袋およびその製造方法
JP3235865U (ja) コーヒー炭を含有する冷感生地および同生地にて構成された衣類
CN209284394U (zh) 供一织物结构使用的位置定义层以及织物结构
TWI649203B (zh) Fabric structure, laminated fabric structure, and fabric fabric manufacturing method
EP1553861A9 (en) New structure for a ventilated mattress
CN205674602U (zh) 一种牛津布
KR20150143238A (ko) 촉감과 흡습성을 향상시킨 기능성 원단 및 그 제조방법
WO2015180273A1 (zh) 一种羊毛毡玩偶及其制作方法
CN108618260A (zh) 鞋垫组成物、鞋垫结构及其制造方法
CN207416171U (zh) 一种散热型汽车座椅面料
CN212889262U (zh) 一种麻棉混纺牛仔面料
KR20180087828A (ko) 직물구조, 두께 증가된 직물구조 및 직물구조의 제조방법
CN207898290U (zh) 一种沙发经编面料
US1177408A (en) Garment-pad.
JP3117128U (ja) 前身中央生地シームレスブリーフ
KR200341981Y1 (ko) 전기매트
CN207608691U (zh) 椅座用人造皮革结构

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18848512

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2018848512

Country of ref document: EP

Effective date: 20200324