WO2019016757A1 - Appareils et procédés associés à la séparation de produits à base de cire à partir de produits - Google Patents
Appareils et procédés associés à la séparation de produits à base de cire à partir de produits Download PDFInfo
- Publication number
- WO2019016757A1 WO2019016757A1 PCT/IB2018/055390 IB2018055390W WO2019016757A1 WO 2019016757 A1 WO2019016757 A1 WO 2019016757A1 IB 2018055390 W IB2018055390 W IB 2018055390W WO 2019016757 A1 WO2019016757 A1 WO 2019016757A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- product
- condenser
- gas stream
- wax
- product gas
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1022—Fischer-Tropsch products
Definitions
- an apparatus comprising: a) an isothermal or adiabatic fixed bed reactor; b) a first condenser; and c) a second condenser, wherein the first condenser and the second condenser are in parallel fluid communication with the isothermal or adiabatic fixed bed reactor via a first connector.
- Both the wax product and the hydrocarbon product are in gas form in the first product gas.
- the wax product has a lower boiling point than the hydrocarbon product.
- the first condenser and the second condenser lower the temperature of the first product gas such that the temperature is below the boiling point of the wax product but above the boiling point of the hydrocarbon products.
- the wax product liquefies or solidifies in the condenser while the hydrocarbon product remains in gas form, thereby separating the wax product from the hydrocarbon product in the first product gas stream.
- the hydrocarbon product remains in gas form and exits the condenser, such as the first condenser or second condenser, for further processing.
- the temperature of the first product gas stream from about 230 °C to about 250 °C.
- the condenser such as the first condenser or second condenser, lowers the temperature of the first product gas stream such that the temperature is from about 160 °C to about 190 °C.
- the valve in the second line is closed and the valve in the first line is reopened to redirect the flow of the first product gas stream from the second condenser to the first condenser. This is done after a portion of the wax product in the first condenser that was first collected has been removed to allow more wax product to be collected in the first condenser.
- the wax product in the second condenser can be removed while the first condenser again is used to continue the process of separating the first wax product from the hydrocarbon product in the first product gas stream.
- the use of the first condenser and the second condenser can be alternated in this way such that the apparatus can be used in operation continuously.
- the isothermal or adiabatic fixed bed reactor, first condenser, and second condenser is configured to support a Fischer-Tropsch system on an industrial scale.
- Aspect 6 The method of any one of aspects 1-5, wherein the first product gas stream before lowering the temperature in step e) has a temperature of from about 230 °C to about 250 °C.
- Aspect 8 The method of any one of aspects 1-7, wherein the method is continuous.
- Aspect 9 The method of any one of aspects 1-8, wherein the second product gas stream comprises at least 95 wt % of the hydrocarbon product.
- Aspect 16 The method of any one of aspects 1-15, wherein the method is performed using an apparatus comprising: a) an isothermal or adiabatic fixed bed reactor; b) a first condenser; and c) a second condenser, wherein the first condenser and the second condenser are in parallel fluid communication with the isothermal or adiabatic fixed bed reactor via a first connector.
- Aspect 18 The apparatus of aspect 17, wherein the first connector comprises a first line that is in fluid communication with the first condenser, and wherein the first line comprises a valve that configured to regulate the flow of a first product gas stream comprising a wax product and a hydrocarbon product from the isothermal or adiabatic fixed bed reactor to the first condenser.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
L'invention concerne un appareil qui comprend a) un réacteur à lit fixe isotherme ou adiabatique ; b) un premier condenseur ; et c) un deuxième condenseur, le premier condenseur et le deuxième condenseur étant en communication fluidique en parallèle avec le réacteur à lit fixe isotherme ou adiabatique par l'intermédiaire d'un premier raccord.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201762535503P | 2017-07-21 | 2017-07-21 | |
US62/535,503 | 2017-07-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2019016757A1 true WO2019016757A1 (fr) | 2019-01-24 |
Family
ID=63209637
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2018/055390 WO2019016757A1 (fr) | 2017-07-21 | 2018-07-19 | Appareils et procédés associés à la séparation de produits à base de cire à partir de produits |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2019016757A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020234772A1 (fr) * | 2019-05-20 | 2020-11-26 | Sabic Global Technologies B.V. | Procédé en ligne pour le traitement d'un flux de méthanol brut contenant une cire |
CN114531875A (zh) * | 2019-05-20 | 2022-05-24 | 沙特基础工业全球技术公司 | 处理含蜡粗甲醇流的在线方法 |
WO2023175293A1 (fr) | 2022-03-15 | 2023-09-21 | Johnson Matthey Davy Technologies Limited | Appareil et procédé de séparation gaz-liquide d'un flux de sortie de réacteur fischer-tropsch |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020010221A1 (en) * | 1999-05-19 | 2002-01-24 | Olga Ionkina | Fischer-tropsch processes and catalysts with promoters |
US20020045671A1 (en) * | 1998-05-22 | 2002-04-18 | Wenchun Chao | Fischer-Tropsch processes and catalysts with promoters |
US20030018088A1 (en) * | 2001-02-28 | 2003-01-23 | Conoco Inc. | Fischer-tropsch process using sponge cobalt catalyst |
-
2018
- 2018-07-19 WO PCT/IB2018/055390 patent/WO2019016757A1/fr active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020045671A1 (en) * | 1998-05-22 | 2002-04-18 | Wenchun Chao | Fischer-Tropsch processes and catalysts with promoters |
US20020010221A1 (en) * | 1999-05-19 | 2002-01-24 | Olga Ionkina | Fischer-tropsch processes and catalysts with promoters |
US20030018088A1 (en) * | 2001-02-28 | 2003-01-23 | Conoco Inc. | Fischer-tropsch process using sponge cobalt catalyst |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020234772A1 (fr) * | 2019-05-20 | 2020-11-26 | Sabic Global Technologies B.V. | Procédé en ligne pour le traitement d'un flux de méthanol brut contenant une cire |
CN114531875A (zh) * | 2019-05-20 | 2022-05-24 | 沙特基础工业全球技术公司 | 处理含蜡粗甲醇流的在线方法 |
US11753359B2 (en) | 2019-05-20 | 2023-09-12 | Sabic Global Technologies B.V. | Online method for processing wax-containing crude methanol stream |
CN114531875B (zh) * | 2019-05-20 | 2024-03-26 | 沙特基础工业全球技术公司 | 处理含蜡粗甲醇流的在线方法 |
WO2023175293A1 (fr) | 2022-03-15 | 2023-09-21 | Johnson Matthey Davy Technologies Limited | Appareil et procédé de séparation gaz-liquide d'un flux de sortie de réacteur fischer-tropsch |
GB2617450A (en) * | 2022-03-15 | 2023-10-11 | Johnson Matthey Davy Technologies Ltd | Apparatus and methods for gas-liquid separation |
GB2617450B (en) * | 2022-03-15 | 2024-05-08 | Johnson Matthey Davy Technologies Ltd | Apparatus and methods for gas-liquid separation |
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