WO2018205496A1 - 一种不易褪色的染料配方 - Google Patents
一种不易褪色的染料配方 Download PDFInfo
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- WO2018205496A1 WO2018205496A1 PCT/CN2017/105338 CN2017105338W WO2018205496A1 WO 2018205496 A1 WO2018205496 A1 WO 2018205496A1 CN 2017105338 W CN2017105338 W CN 2017105338W WO 2018205496 A1 WO2018205496 A1 WO 2018205496A1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
- D06P1/5228—Polyalkenyl alcohols, e.g. PVA
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/627—Sulfates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/647—Nitrogen-containing carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
- D06P1/67366—Phosphates or polyphosphates
Definitions
- the invention relates to the field of home textile printing and dyeing technology, in particular to a dye formulation which is not easy to fade.
- Textile dyes are dyes used in textile dyeing and are often classified into natural dyes and synthetic dyes.
- the existing textile dyes are usually prepared by artificial proportioning according to different needs, and the existing dye-dyed fabrics have poor colorability and insufficient color fastness, and fade and fade after repeated cleaning. The phenomenon.
- the dye formulation consisting of parts by weight of natural plant dye 20-40 parts; 2-5 parts of fatty alcohol sodium sulfate; 5-10 parts of polyvinyl alcohol; sodium propionate 3-6 parts; methyl acrylate 5-8 parts; acrylic resin 1-3 parts; glacial acetic acid 3-6 parts; fluorescer 2-5 parts; inorganic antibacterial agent 5-10 parts; anionic antistatic agent 0.5-2 parts Deionized water 50-70 parts.
- the natural plant dye is one of valerian, comfrey, sorghum, indigo, and scutellaria.
- the fluorescent agent is one of a fluorescent agent BC, a fluorescent agent EBF, a fluorescent agent R, a fluorescent agent AD, and a fluorescent agent ER.
- the inorganic antibacterial agent is one of zinc oxide, copper oxide, ammonium dihydrogen phosphate, and lithium carbonate.
- the anionic antistatic agent is an alkali metal salt of an alkylsulfonic acid, a phosphoric acid or a dithiocarbamic acid.
- the dye formulation consists of parts by weight of the following components: natural vegetable dye 30 parts; fatty alcohol sodium sulfate 3 parts; polyvinyl alcohol 7 parts; sodium propionate 4 parts; methyl acrylate 6 parts; 2 parts of resin; 4 parts of glacial acetic acid; 3 parts of fluorescent agent; 6 parts of inorganic antibacterial agent; 1 part of anionic antistatic agent; 60 parts of deionized water.
- the dye formulation of the present invention contains a fluorescent agent, so that the cloth emits fluorescence in a dark environment, and the visual effect is good.
- the anionic antistatic agent is added to the dye formulation of the invention, thereby rapidly conducting static electricity, and the antistatic property of the dye of the invention can be improved, so that the printed fabric can quickly conduct static electricity and has excellent antistatic property.
- the inorganic antibacterial agent is added to the dye formulation of the invention to prevent the growth and reproduction of bacteria, and effectively improve the antibacterial property of the printed fabric.
- a dye formulation that is not easily faded consisting of parts by weight of natural plant dye 20 parts; 2 parts of fatty alcohol sodium sulfate; 5 parts of polyvinyl alcohol; 3 parts of sodium propionate; 1 part; acrylic resin 1 part; glacial acetic acid 3 parts; 2 parts of fluorescent agent; 5 parts of inorganic antibacterial agent; 0.5 part of anionic antistatic agent; 50 parts of deionized water.
- the natural plant dye is valerian.
- the fluorescent agent is a fluorescent agent BC.
- the inorganic antibacterial agent is zinc oxide.
- the anionic antistatic agent is an alkali metal salt of an alkylsulfonic acid.
- a dye formulation which is not easily faded, and the dye formulation is composed of parts by weight of natural plant dye 30 parts; 3 parts of fatty alcohol sodium sulfate; 7 parts of polyvinyl alcohol; 4 parts of sodium propionate; 6 parts of ester; 2 parts of acrylic resin; 4 parts of glacial acetic acid; 3 parts of fluorescent agent; 6 parts of inorganic antibacterial agent; 1 part of anionic antistatic agent; 60 parts of deionized water.
- the natural vegetable dye is comfrey.
- the fluorescent agent is a fluorescent agent EBF.
- the inorganic antibacterial agent is copper oxide.
- the anionic antistatic agent is an alkali metal salt of phosphoric acid.
- a non-fading dye formulation consisting of parts by weight of natural plant dyes 35 parts; 4 parts of fatty alcohol sodium sulfate; 8 parts of polyvinyl alcohol; 5 parts of sodium propionate; 2 parts; 2 parts of acrylic resin; 5 parts of glacial acetic acid; 4 parts of fluorescent agent; 8 parts of inorganic antibacterial agent; 1.5 parts of anionic antistatic agent; 65 parts of deionized water.
- the natural vegetable dye is Susie.
- the fluorescent agent is a fluorescent agent R.
- the inorganic antibacterial agent is ammonium dihydrogen phosphate.
- the anionic antistatic agent is an alkali metal salt of a dithiocarbamic acid.
- a dye formulation that is not easily faded consisting of parts by weight of natural plant dye 20 parts; 2 parts of fatty alcohol sodium sulfate; 5 parts of polyvinyl alcohol; 3 parts of sodium propionate; 1 part; acrylic resin 1 part; glacial acetic acid 3 parts; 2 parts of fluorescent agent; 5 parts of inorganic antibacterial agent; 0.5 part of anionic antistatic agent; 50 parts of deionized water.
- the natural plant dye is indigo.
- the fluorescent agent is a fluorescent agent AD.
- the inorganic antibacterial agent is lithium carbonate.
- the anionic antistatic agent is an alkali metal salt of a dithiocarbamic acid.
- a dye formulation which is not easily faded, and the dye formulation is composed of parts by weight of natural plant dye 30 parts; 3 parts of fatty alcohol sodium sulfate; 7 parts of polyvinyl alcohol; 4 parts of sodium propionate; 6 parts of ester; 2 parts of acrylic resin; 4 parts of glacial acetic acid; 3 parts of fluorescent agent; 6 parts of inorganic antibacterial agent; 1 part of anionic antistatic agent; 60 parts of deionized water.
- the natural plant dye is scutellaria.
- the fluorescent agent is a fluorescent agent ER.
- the inorganic antibacterial agent is zinc oxide.
- the anionic antistatic agent is an alkali metal salt of phosphoric acid.
- the pigments of the respective formulations of Examples 1-5 make the fabric dyed by the dye less fading, so that the fabric dyed with the dye formulation has excellent coloring property and color fastness.
- the dye formulation contains a fluorescent agent that causes the fabric to fluoresce in a dark environment with good visual effects.
- An anionic antistatic agent is added to the dye formulation, thereby rapidly conducting static electricity, and the antistatic property of the dye of the present invention can be improved, thereby enabling the printed fabric to rapidly conduct static electricity and having excellent antistatic properties.
- An inorganic antibacterial agent is added to the dye formulation to prevent the growth and reproduction of bacteria, and effectively improve the antibacterial properties of the printed fabric.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Coloring (AREA)
Abstract
一种不易褪色的染料配方,由以下重量份的组分组成:天然植物染料20-40份;脂肪醇硫酸钠2-5份;聚乙烯醇5-10份;丙酸钠3-6份;丙烯酸甲酯5-8份;丙烯酸树脂1-3份;冰醋酸3-6份;荧光剂2-5份;无机抗菌剂5-10份;阴离子抗静电剂0.5-2份;去离子水50-70份。该染料配方中添加有丙烯酸树脂,使得经该染料染整的布料不易褪色,且染料配方中含有荧光剂,使得布料在黑暗环境下发出荧光,视觉效果好。
Description
本发明涉及家纺印染技术领域,特别是涉及一种不易褪色的染料配方。
纺织染料是用于纺织品染色的一种染剂,常分为天然染料和合成染料。现有的纺织染料通常是根据不同需求通过人工配比的方式配制而成,且现有的染料染整的布料的着色性差,且色牢度不够,且经过多次清洗后会出现褪色、掉色的现象。
发明内容
本发明的目的在于避免现有技术中的不足之处而提供一种不易褪色的染料配方。
本发明的目的通过以下技术方案实现:
提供一种不易褪色的染料配方,所述染料配方由以下组分的重量份组成:天然植物染料20-40份;脂肪醇硫酸钠2-5份;聚乙烯醇5-10份;丙酸钠3-6份;丙烯酸甲酯5-8份;丙烯酸树脂1-3份;冰醋酸3-6份;荧光剂2-5份;无机抗菌剂5-10份;阴离子抗静电剂0.5-2份;去离子水50-70份。
作为优选,所述的天然植物染料为茜草、紫草、苏枋、靛蓝、黄栀子中的一种。
作为优选,所述的荧光剂为荧光剂BC、荧光剂EBF、荧光剂R、荧光剂AD、荧光剂ER中的一种。
作为优选,所述的无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵、碳酸锂中的一种。
作为优选,所述的阴离子抗静电剂为烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐。
作为优选,所述所述染料配方由以下组分的重量份组成:天然植物染料30份;脂肪醇硫酸钠3份;聚乙烯醇7份;丙酸钠4份;丙烯酸甲酯6份;丙烯酸树脂2份;冰醋酸4份;荧光剂3份;无机抗菌剂6份;阴离子抗静电剂1份;去离子水60份。
本发明的有益效果:
1)本发明的染料配方中添加有丙烯酸树脂,使得经该染料染整的布料不易褪色,使得利用该染料配方印染的布料具有优异的着色性和色牢度。
2)本发明的染料配方中含有荧光剂,使得布料在黑暗环境下发出荧光,视觉效果好。
3)本发明的染料配方中添加阴离子抗静电剂,进而可以快速传导静电,可以提高本发明的染料的抗静电性能,进而使得印染后的布料可以快速传导静电,而具有优异的抗静电性能。
4)本发明的染料配方中添加无机抗菌剂,防止细菌的滋生与繁殖,有效提高印染布料的抗菌性能。
以下结合实施例对本发明作进一步详细描述。
实施例1:
一种不易褪色的染料配方,所述染料配方由以下组分的重量份组成:天然植物染料20份;脂肪醇硫酸钠2份;聚乙烯醇5份;丙酸钠3份;丙烯酸甲酯5份;丙烯酸树脂1份;冰醋酸3份;荧光剂2份;无机抗菌剂5份;阴离子抗静电剂0.5份;去离子水50份。其中,所述的天然植物染料为茜草。所述的荧光剂为荧光剂BC。所述的无机抗菌剂为氧化锌。所述的阴离子抗静电剂为烷基磺酸的碱金属盐。
实施例2:
一种不易褪色的染料配方,所述所述染料配方由以下组分的重量份组成:天然植物染料30份;脂肪醇硫酸钠3份;聚乙烯醇7份;丙酸钠4份;丙烯酸甲酯6份;丙烯酸树脂2份;冰醋酸4份;荧光剂3份;无机抗菌剂6份;阴离子抗静电剂1份;去离子水60份。所述的天然植物染料为紫草。所述的荧光剂为荧光剂EBF。所述的无机抗菌剂为氧化铜。所述的阴离子抗静电剂为磷酸的碱金属盐。
实施例3:
一种不易褪色的染料配方,所述染料配方由以下组分的重量份组成:天然植物染料35份;脂肪醇硫酸钠4份;聚乙烯醇8份;丙酸钠5份;丙烯酸甲酯7份;丙烯酸树脂2份;冰醋酸5份;荧光剂4份;无机抗菌剂8份;阴离子抗静电剂1.5份;去离子水65份。所述的天然植物染料为苏枋。所述的荧光剂为荧光剂R。所述的无机抗菌剂为磷酸二氢铵。所述的阴离子抗静电剂为二硫代氨基甲酸的碱金属盐。
实施例4:
一种不易褪色的染料配方,所述染料配方由以下组分的重量份组成:天然植物染料20份;脂肪醇硫酸钠2份;聚乙烯醇5份;丙酸钠3份;丙烯酸甲酯5份;丙烯酸树脂1份;冰醋酸3份;荧光剂2份;无机抗菌剂5份;阴离子抗静电剂0.5份;去离子水50份。其中,所述的天然植物染料为靛蓝。所述的荧光剂为荧光剂AD。所述的无机抗菌剂为碳酸锂。所述
的阴离子抗静电剂为二硫代氨基甲酸的碱金属盐。
实施例5:
一种不易褪色的染料配方,所述所述染料配方由以下组分的重量份组成:天然植物染料30份;脂肪醇硫酸钠3份;聚乙烯醇7份;丙酸钠4份;丙烯酸甲酯6份;丙烯酸树脂2份;冰醋酸4份;荧光剂3份;无机抗菌剂6份;阴离子抗静电剂1份;去离子水60份。所述的天然植物染料为黄栀子。所述的荧光剂为荧光剂ER。所述的无机抗菌剂为氧化锌。所述的阴离子抗静电剂为磷酸的碱金属盐。
实施例1-5各配方的颜料,通过各自组分的配合作用,使得经该染料染整的布料不易褪色,使得利用该染料配方印染的布料具有优异的着色性和色牢度。染料配方中含有荧光剂,使得布料在黑暗环境下发出荧光,视觉效果好。染料配方中添加阴离子抗静电剂,进而可以快速传导静电,可以提高本发明的染料的抗静电性能,进而使得印染后的布料可以快速传导静电,而具有优异的抗静电性能。染料配方中添加无机抗菌剂,防止细菌的滋生与繁殖,有效提高印染布料的抗菌性能。
最后应当说明的是,以上实施例仅用于说明本发明的技术方案而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和范围。。
Claims (6)
- 一种不易褪色的染料配方,其特征在于,所述染料配方由以下组分的重量份组成:天然植物染料20-40份;脂肪醇硫酸钠2-5份;聚乙烯醇5-10份;丙酸钠3-6份;丙烯酸甲酯5-8份;丙烯酸树脂1-3份;冰醋酸3-6份;荧光剂2-5份;无机抗菌剂5-10份;阴离子抗静电剂0.5-2份;去离子水50-70份。
- 根据权利要求1所述的染料配方,其特征在于,所述的天然植物染料为茜草、紫草、苏枋、靛蓝、黄栀子中的一种。
- 根据权利要求1所述的染料配方,其特征在于,所述的荧光剂为荧光剂BC、荧光剂EBF、荧光剂R、荧光剂AD、荧光剂ER中的一种。
- 根据权利要求1所述的染料配方,其特征在于,所述的无机抗菌剂为氧化锌、氧化铜、磷酸二氢铵、碳酸锂中的一种。
- 根据权利要求1所述的染料配方,其特征在于,所述的阴离子抗静电剂为烷基磺酸、磷酸或二硫代氨基甲酸的碱金属盐。
- 根据权利要求1所述的染料配方,其特征在于,所述所述染料配方由以下组分的重量份组成:天然植物染料30份;脂肪醇硫酸钠3份;聚乙烯醇7份;丙酸钠4份;丙烯酸甲酯6份;丙烯酸树脂2份;冰醋酸4份;荧光剂3份;无机抗菌剂6份;阴离子抗静电剂1份;去离子水60份。
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