WO2018196363A1 - 甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的流化床装置及方法 - Google Patents
甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的流化床装置及方法 Download PDFInfo
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Definitions
- the present invention relates to a device for producing low-carbon olefins produced by co-p-xylene (PX) and a production method thereof, and is particularly suitable for fluidization of co-production of low-carbon olefins by alkylation of methanol and/or dimethyl ether with benzene to para-xylene.
- Bed device and production method belong to the field of chemistry and chemical industry.
- Paraxylene is one of the basic organic raw materials in the petrochemical industry. It has a wide range of applications in chemical fiber, synthetic resins, pesticides, pharmaceuticals, and polymer materials.
- p-xylene production mainly uses toluene, C 9 aromatic hydrocarbons and mixed xylene as raw materials, and is obtained by disproportionation, isomerization, adsorption separation or cryogenic separation. Since the p-xylene content in the product is controlled by thermodynamics, p-xylene only accounts for ⁇ 24% of the C 8 mixed aromatics, and the material circulation processing amount is large during the process, and the equipment is large and the operation cost is high.
- Low-carbon olefins namely ethylene, propylene and butene
- Ethylene and propylene are mainly produced from naphtha, depending on the petroleum route.
- the non-oil route to produce ethylene and propylene has received more and more attention, especially the methanol conversion to low-carbon olefin (MTO) process route, which is to achieve oil substitution strategy, reduce and alleviate China's demand for oil and dependence. An important way.
- MTO low-carbon olefin
- the alkylation of benzyl alcohol to the preparation of p-xylene and the alkylation of benzyl alcohol to toluene and xylene are both new ways to increase the production of aromatics.
- the selective alkylation of benzyl alcohol can produce highly selective para-xylene products, but the toluene required for the process is also an intermediate raw material for the production of para-xylene by the aromatics unit, which is in short supply in the market.
- benzene is a by-product of the aromatics unit, it is estimated that an annual output of 800,000 tons of PX aromatics unit can produce about 300,000 tons of benzene. Therefore, the alkylation of benzene with methanol to produce toluene and xylene will increase the production of aromatics. An effective way.
- a conventional toluene alkylation process involves mixing methanol and/or dimethyl ether with benzene upstream of the reactor and then feeding the mixture together into the reactor.
- the reactor type consists of a fixed bed and a fluidized bed.
- the phased injection of reactants has been employed in various fixed bed and fluidized bed processes.
- Methanol is the raw material for the alkylation of benzene and / or methyl methoxide and / or dimethyl ether with benzene, and is also the raw material for MTO reaction, but the MTO reaction rate is much higher than benzene and / or methyl methoxide and / or dimethyl ether and benzene The rate of alkylation reaction.
- the reaction rate is much higher than the alkylation reaction of methanol and/or dimethyl ether with benzene.
- Another important feature is that after the catalyst is carbonized, the methanol conversion rate decreases and the selectivity of the low carbon olefin increases. Therefore, controlling the carbonation of the catalyst is an effective way to improve the selectivity of low-carbon olefins in the MTO reaction.
- the technical field needs to coordinate and optimize the competition between the alkylation reaction and the MTO reaction from the two aspects of catalyst design and reactor design, so as to synergistically improve the conversion of benzene and the yield of p-xylene. And low carbon olefin yield.
- a turbulent fluidized bed reactor for co-production of a low carbon olefin with methanol and/or dimethyl ether and benzene para-xylene
- the turbulent fluidized bed reactor Or improve the competition between MTO reaction and alkylation reaction in the process of co-production of low-carbon olefin by methanol and/or dimethyl ether and benzene to produce p-xylene, and realize the synergistic effect of MTO reaction and alkylation reaction through control Mass transfer and reaction, coordination, optimization of competition between alkylation reaction and MTO reaction, synergistic effect, increase benzene conversion, p-xylene yield and low carbon olefin selectivity.
- the low amount is also not conducive to the alkylation of methanol and / or dimethyl ether with benzene. Therefore, optimizing the concentration of methanol and benzene and/or toluene in the reaction zone is an effective way to increase the conversion of benzene and/or toluene and the yield of p-xylene.
- a turbulent fluidized bed reactor for co-producing low carbon olefins with methanol and/or dimethyl ether and benzene para-xylene, comprising a first reactor feed distributor and a plurality of second reactor feed distributors, The first reactor feed distributor and the plurality of second reactor feed distributors are arranged in sequence along the gas flow direction in the reaction zone of the turbulent fluidized bed reactor.
- the second reactor feed distributor is from 2 to 10.
- the turbulent fluidized bed reactor comprises a first reactor gas-solids separator and a second reactor gas-solids separator, the first reactor gas-solids separator being placed in a dilute phase zone or a reactor shell Outside the body, the second reactor gas-solids separator is placed in a dilute phase zone or outside the reactor housing;
- the first reactor gas-solids separator is provided with a regenerated catalyst inlet, the catalyst outlet of the first reactor gas-solid separator is placed at the bottom of the reaction zone, and the gas outlet of the first reactor gas-solid separator is placed In the dilute phase zone;
- An inlet of the second reactor gas-solids separator is placed in the dilute phase zone, a catalyst outlet of the second reactor gas-solids separator is placed in the reaction zone, and the second reactor gas-solid separator a gas outlet connected to the gas outlet of the product of the turbulent fluidized bed reactor;
- the reaction zone is located in a lower portion of the turbulent fluidized bed reactor, the dilute phase zone being located in an upper portion of the turbulent fluidized bed reactor.
- the first reactor gas-solid separator and the second reactor gas-solid separator are cyclones.
- the turbulent fluidized bed reactor comprises a reactor heat takeer placed inside or outside the turbulent fluidized bed reactor housing.
- the reactor heat extractor is disposed between the plurality of reactor feed distributors.
- the turbulent fluidized bed reactor comprises a reactor stripper that passes through the reactor housing from the outside to the inside at the bottom of the turbulent fluidized bed reactor and is open to turbulence
- the bottom of the reactor stripper is provided with a reactor stripping gas inlet and a catalyst outlet to be produced.
- the turbulent fluidized bed reactor comprises a perforated plate located between a first reactor feed distributor and at least one second reactor feed distributor, the perforated plate opening The rate is ⁇ 50%.
- the turbulent fluidized bed reactor comprises a multiwell plate located in a first reactor feed distributor and a second reactor feed distributor closest to the first reactor feed distributor
- the open porosity of the porous plate is between 5% and 50%.
- the reactor stripper is passed from the outside to the inside of the reactor housing at the bottom of the turbulent fluidized bed reactor and is open to the reaction zone of the turbulent fluidized bed reactor, the reactor being stripped Reactor stripping at the bottom of the reactor a gas inlet and a catalyst outlet to be produced;
- the turbulent fluidized bed reactor comprises a multiwell plate positioned between a first reactor feed distributor and at least one second reactor feed distributor, the perforated plate having an open porosity of ⁇ 50 %;
- the reactor stripper has a level of opening in the interior of the reactor housing that is higher than the first reactor feed distributor and higher than the perforated plate.
- the lower olefin includes at least one of ethylene, propylene, and butene.
- the methanol in the feed may be replaced in whole or in part by dimethyl ether. If the feed contains dimethyl ether, the dimethyl ether may be converted into methanol having the same number of carbon atoms in the calculation.
- methanol and/or dimethyl ether means including three cases: only methanol; or only dimethyl ether; or both methanol and dimethyl ether.
- methanol and / or dimethyl ether and benzene includes three cases: benzene and methanol; or benzene and dimethyl ether; or the present with methanol and dimethyl ether.
- the methanol in the present application may be replaced by all or part of dimethyl ether, and the amount of methanol may be calculated by converting dimethyl ether into methanol having the same number of carbon atoms.
- an apparatus for co-producing a lower olefin of methanol and/or dimethyl ether with benzene para-xylene solving or improving methanol and/or dimethyl ether
- the competition between MTO reaction and alkylation reaction in the production of p-xylene to produce low-carbon olefins, the synergistic effect of MTO reaction and alkylation reaction, coordination and optimization of alkylation by controlling mass transfer and reaction The competition between the reaction and the MTO reaction synergizes to increase benzene conversion, p-xylene yield and low olefin selectivity.
- the apparatus comprises at least one of the turbulent fluidized bed reactors of any of the above and a fluidized bed regenerator for regenerating the catalyst.
- the fluidized bed regenerator is a turbulent fluidized bed regenerator comprising a regenerator housing, a regenerator gas solids separator, a regenerator heat extractor, and a regenerator stripper
- the lower part of the fluidized bed regenerator is the regeneration zone
- the upper part of the fluidized bed regenerator is the regenerator dilute phase zone
- the regenerator feed distributor is placed at the bottom of the regeneration zone
- the regenerator heat extractor is placed in the regeneration zone for regeneration.
- the gas-solid separator is placed outside the dilute phase zone or the regenerator housing;
- the inlet of the regenerator gas-solids separator is placed in a regenerator dilute phase zone, the catalyst outlet of the regenerator gas-solids separator is placed in a regeneration zone, and the regenerator stripper is open at the bottom of the regenerator housing.
- the fluidized bed regenerator comprises a regenerator housing, a regenerator feed distributor, a regenerator gas-solid separator, a regenerator heat extractor, a flue gas outlet, and a regenerator stripper;
- the lower part of the fluidized bed regenerator is a regeneration zone, and the upper part of the fluidized bed regenerator is a dilute phase zone;
- the regenerator feed distributor is placed at the bottom of the regeneration zone, the regenerator heat extractor is placed in the regeneration zone, and the regenerator gas-solids separator is placed outside the dilute phase zone or the regenerator housing, and the inlet of the regenerator gas-solids separator is placed In the dilute phase region, the catalyst outlet of the regenerator gas-solid separator is placed in the regeneration zone, the gas outlet of the regenerator gas-solid separator is connected to the flue gas outlet, and the regenerator stripper is open at the bottom of the regenerator housing;
- the outlet of the catalyst to be produced in the reactor stripper is connected to the inlet of the inclined tube to be produced, and the slip tube to be produced is provided with a slide valve to be produced, and the outlet of the inclined tube is connected to the inlet of the riser tube to be raised.
- the bottom of the tube is provided with a rising gas inlet, and the outlet of the rising riser is connected to the dilute phase region of the fluidized bed regenerator;
- the bottom of the regenerator stripper is provided with a regenerator stripping gas inlet, the bottom of the regenerator stripper is connected to the inlet of the regenerative inclined tube, and the regenerative inclined tube is provided with a regenerative sliding valve, and the outlet of the regenerative inclined tube is connected to
- the inlet of the regeneration riser is provided with a regeneration lift gas inlet at the bottom of the regeneration riser, and the outlet of the regeneration riser is connected to the regeneration catalyst inlet of the first reactor gas-solid separator, the first reactor gas-solid separator is placed The dilute phase zone of the fluidized bed reactor or the exterior of the reactor housing.
- a process for the co-production of a lower olefin with methanol and/or dimethyl ether and benzene para-xylene which method solves or improves methanol and/or dimethyl ether
- the competition between the reaction and the MTO reaction synergizes to increase benzene conversion, p-xylene yield and low olefin selectivity.
- the method for co-producing a lower olefin with methanol and/or dimethyl ether and benzene para-xylene employs at least one of the turbulent fluidized bed reactors according to any one of the above.
- the feedstock A containing methanol and/or dimethyl ether and benzene is fed from the first reactor feed distributor to the reaction zone of the turbulent fluidized bed reactor to feed the feedstock containing methanol and/or dimethyl ether.
- B is fed to the reaction zone of the turbulent fluidized bed reactor by a plurality of second reactor feed distributors, respectively, in contact with the catalyst to form stream C and the spent catalyst comprising para-xylene and low-carbon olefin products.
- the stream C is separated to obtain para-xylene, low-carbon olefins, C 5+ chain hydrocarbons, aromatic hydrocarbon by-products, and unconverted methanol, dimethyl ether and benzene;
- the unconverted methanol and dimethyl ether are fed to the reaction zone of the turbulent fluidized bed reactor by a plurality of second reactor feed distributors, and the aromatics by-product and unconverted benzene are distributed by the first reactor feed.
- the reaction zone fed to the turbulent fluidized bed reactor is contacted with a catalyst.
- the spent catalyst is regenerated by a fluidized bed regenerator and then enters the bottom of the reaction zone in the turbulent fluidized bed reactor.
- the method comprises the following steps:
- Stream A containing methanol and/or dimethyl ether and benzene is fed into the reaction zone of the turbulent fluidized bed reactor from the first reactor feed distributor below the turbulent fluidized bed reactor to contact the catalyst ;
- the methanol-containing stream B is fed from 2 to 10 second reactor feed distributors to the reaction zone of the turbulent fluidized bed reactor to contact the catalyst to form a product containing para-xylene and low-carbon olefins.
- Stream C and a catalyst to be produced; the 2 to 10 second reactor feed distributors are arranged in sequence above the first reactor feed distributor;
- step C (3) separating step C from stream (c) to obtain unconverted methanol and dimethyl ether stream C-1, unconverted benzene and aromatics by-product stream C-2; and stream C-1 from 2 to 10, respectively
- the second reactor feed distributor is fed to the reaction zone of the turbulent fluidized bed reactor to contact the catalyst;
- the stream C-2 is fed from the first reactor feed distributor to the reaction zone of the turbulent fluidized bed reactor Contact with the catalyst;
- the aromatic by-product comprises toluene, o-xylene, m-xylene, ethylbenzene and C 9+ arene;
- the first reactor feed distributor is fed to the mixture of the turbulent fluidized bed reactor, the ratio of the molecular moles of aromatic hydrocarbons to the carbon moles of methanol and/or dimethyl ether being greater than 0.5.
- the first reactor feed distributor is fed to the mixture of the turbulent fluidized bed reactor, the ratio of the molecular moles of the aromatic hydrocarbon to the carbon moles of methanol and/or dimethyl ether being from 0.5 to 5.
- the number of moles of molecules refers to the number of moles of molecules in the substance
- the number of moles of carbon refers to the number of moles of carbon atoms in the substance.
- the molar ratio of all oxygenates entering from the plurality of second reactor feed distributors to methanol in the mixture entering the turbulent fluidized bed reactor from the first reactor feed distributor is greater than one.
- the molar ratio of all oxygenates entering from the plurality of second reactor feed distributors to methanol entering from the first reactor feed distributor is from 1 to 20.
- the catalyst to be produced passes through the reactor stripper, the inclined tube to be produced, the standby slide valve and the standby riser into the dilute phase region of the fluidized bed regenerator;
- the regeneration medium is passed into the regeneration zone of the fluidized bed regenerator, and the charcoal reacts with the catalyst to be generated to generate flue gas containing CO and CO 2 and a regenerated catalyst, and the flue gas is discharged after being removed by the regenerator gas-solid separator;
- the regenerated catalyst enters the inlet of the first reactor gas-solid separator through the regenerator stripper, the regeneration inclined pipe, the regeneration slide valve and the regeneration riser. After the gas-solid separation, the regenerated catalyst enters the reaction zone of the turbulent fluidized bed reactor. bottom;
- the reactor stripping gas enters the reactor stripper from the reactor stripping gas inlet and is in countercurrent contact with the catalyst to be produced, and then enters the turbulent fluidized bed reactor; the rising gas to be produced enters the waiting riser from the inlet of the rising gas to be produced Passing in contact with the catalyst to be produced, and then entering the dilute phase region of the fluidized bed regenerator;
- the regenerator stripping gas enters the regenerator stripper and the regenerated catalyst in countercurrent contact with the regenerator stripping gas inlet, and then enters the fluidized bed regenerator; the regenerative lifting gas enters the regenerative riser and the regenerated catalyst in downstream flow from the regenerative lift gas inlet And then entering the inlet of the first reactor gas-solids separator, the first reactor gas-solids separator being placed in the dilute phase zone of the fluidized bed reactor or outside the reactor housing.
- the regenerated catalyst has a carbon content of ⁇ 0.5 wt%.
- the regeneration medium is at least one of air, oxygen-depleted air or water vapor;
- the reactor stripping gas, the regenerator stripping gas, the spent lift gas, and the regeneration lift gas are water vapor and/or nitrogen.
- the reaction conditions of the reaction zone of the turbulent fluidized bed reactor are: an apparent linear velocity of gas of 0.1 m/s to 2.0 m/s, a reaction temperature of 350 ° C to 600 ° C, and a reaction pressure of 0.1 Mpa to 1.0. MPa, bed density is from 200 kg/m 3 to 1200 kg/m 3 .
- the reaction condition of the fluidized bed regenerator regeneration zone is: an apparent apparent linear velocity of gas of 0.1 m/s to 2 m/s, a regeneration temperature of 500 ° C to 750 ° C, and a regeneration pressure of 0.1 Mpa to 1.0 MPa, and a bed.
- the layer density is from 200 kg/m 3 to 1200 kg/m 3 .
- the catalyst in the turbulent fluidized bed reactor, has a lower dense phase region and an upper rare phase region in a fluidized state.
- the dense phase zone is the reaction zone of the turbulent fluidized bed reactor.
- the present application provides a turbulent fluidized bed reactor for co-production of low carbon olefins with methanol and/or dimethyl ether and benzene to produce para-xylene, the turbulent fluidized bed reactor comprising: a reactor housing 2. n reactor feed distributors (3-1 to 3-n), reactor gas-solid separator 4, reactor gas-solid separator 5, reactor heat extractor (6), product gas outlet 7 and Reactor stripper 8, wherein the lower part of the turbulent fluidized bed reactor 1 is a reaction zone, the upper part of the turbulent fluidized bed reactor 1 is a dilute phase zone, and n reactor feed distributors (3-1 ⁇ ) 3-n) placed in the reaction zone from bottom to top, the reactor heat extractor (6) is placed outside the reaction zone or reactor housing 2, and the reactor gas-solids separator 4 and the reactor gas-solid separator 5 are placed Outside the dilute phase zone or reactor housing 2, the reactor gas-solids separator 4 is provided with a regenerated catalyst inlet, and the catalyst outlet of the reactor gas-solids separator 4 is placed at
- the n reactor feed distributors (3-1 to 3-n) of the turbulent fluidized bed reactor 1 are placed in the reaction zone from bottom to top, 3 ⁇ n ⁇ 11, said n The total number of distributors fed to the reactor.
- the level of the opening of the reactor stripper 8 inside the reactor housing 2 is higher than the first reactor feed distributor to avoid direct entry of fresh catalyst into the reactor stripper.
- the reactor gas-solids separator 4 and the reactor gas-solids separator 5 are cyclones.
- the present application further provides an apparatus for co-production of a lower olefin with methanol and/or dimethyl ether and benzene to produce para-xylene, the apparatus comprising the above-described turbulent fluidized bed reactor 1 and a catalyst for regenerating the catalyst Fluidized bed regenerator 14.
- the fluidized bed regenerator 14 is a turbulent fluidized bed regenerator.
- the fluidized bed regenerator 14 includes a regenerator housing 15, a regenerator feed distributor 16, a regenerator gas solids separator 17, a regenerator heat extractor 18, a flue gas outlet 19, and a regenerator.
- the stripper 20 wherein the lower portion of the fluidized bed regenerator 14 is a regeneration zone, the upper portion of the fluidized bed regenerator 14 is a dilute phase zone, and the regenerator feed distributor 16 is placed at the bottom of the regeneration zone, the regenerator heats up 18 is placed in the regeneration zone, the regenerator gas-solids separator 17 is placed outside the dilute phase zone or the regenerator housing 15, the inlet of the regenerator gas-solids separator 17 is placed in the dilute phase zone, and the catalyst of the regenerator gas-solids separator 17 The outlet is placed in the regeneration zone, the gas outlet of the regenerator gas-solid separator 17 is connected to the flue gas outlet 19, and the inlet of the regenerator stripper 20 is connected to the bottom of the regenerator housing 15;
- the catalyst outlet of the reactor stripper 8 is connected to the inlet of the inclined tube 10, and the inlet inclined tube 10 is provided with a slide valve 11 to be produced, and the outlet of the inclined tube 10 is connected to the inlet of the riser tube 12 to be produced.
- the bottom of the standby riser 12 is provided with a riser gas inlet 13 to be connected, the outlet of the riser riser 12 is connected to the dilute phase zone of the fluidized bed regenerator 14; and the bottom of the regenerator stripper 20 is provided with a regenerator vapor
- the gas extraction inlet 21, the bottom of the regenerator stripper 20 is connected to the inlet of the regeneration inclined tube 22, and the regeneration inclined tube 22 is provided with a regeneration spool 23, and the outlet of the regeneration inclined tube 22 is connected to the inlet of the regeneration riser 24 to be regenerated.
- the bottom of the riser 24 is provided with a regeneration lift gas inlet 25, and the outlet of the regeneration riser 24 is connected to the inlet of the reactor gas-solid separator 4.
- the present application provides a co-production of low carbon for methanol and/or dimethyl ether and benzene to produce para-xylene.
- a method of olefins comprising:
- the stream containing para-xylene and low-carbon olefin products flowing out of the turbulent fluidized bed reactor 1 is sent to a product separation system, and separated to obtain para-xylene, ethylene, propylene, butene, C 5+ chain hydrocarbons, and aromatic hydrocarbons.
- Products and unconverted methanol, dimethyl ether and benzene, aromatic by-products including toluene, o-xylene, m-xylene, ethylbenzene and C 9+ aromatics, unconverted methanol and dimethyl ether from the reactor feed distributor 3-2 to 3-n are fed to the reaction zone of the turbulent fluidized bed reactor 1, and aromatics by-products and unconverted benzene are fed from the reactor feed distributor 3-1 to the turbulent fluidized bed reactor 1 a reaction zone, in contact with a catalyst, converted to a product;
- the catalyst to be produced is regenerated by the fluidized bed regenerator 14, and the regenerated catalyst is separated into the bottom of the reaction zone in the turbulent fluidized bed reactor 1 after gas-solid separation of the reactor gas-solids separator 4.
- the process described herein is carried out using the apparatus described above for the co-production of lower olefins of methanol and/or dimethyl ether with benzene to produce para-xylene.
- the catalyst to be produced passes through the reactor stripper 8, the inclined tube 10, the slide valve 11 to be produced, and the riser tube 12 to enter the dilute phase region of the fluidized bed regenerator 14;
- the regeneration medium passes from the regenerator feed distributor 16 to the regeneration zone of the fluidized bed regenerator 14 and reacts with the catalyst to be activated to generate flue gas containing CO, CO 2 and regenerated catalyst, and the flue gas passes through the regenerator gas.
- the solid separator 17 is discharged after dust removal;
- the regenerated catalyst enters the inlet of the reactor gas-solid separator 4 through the regenerator stripper 20, the regeneration inclined tube 22, the regeneration slide valve 23 and the regeneration riser 24, and after the gas-solid separation, the regenerated catalyst enters the turbulent fluidized bed reactor 1 The bottom of the middle reaction zone;
- the reactor stripping gas enters the reactor stripper 8 from the reactor stripping gas inlet 9 and is in countercurrent contact with the catalyst to be produced, and then enters the turbulent fluidized bed reactor 1; the rising gas to be produced enters the rising gas inlet 13
- the standby riser 12 and the catalyst to be produced are in downstream contact, and then enter the dilute phase region of the fluidized bed regenerator 14;
- regenerator stripping gas is fed from the regenerator stripping gas inlet 21 into the regenerator stripper 20 in countercurrent contact with the regenerated catalyst, and then into the fluidized bed regenerator 14; the regenerating propellant gas is passed from the regenerating ascending gas inlet 25 into the regeneration riser 24 and The regenerated catalyst is contacted in a downstream flow and then enters the inlet of the reactor gas-solids separator 4.
- the mass ratio of the aromatic hydrocarbon to the methanol is greater than 0.5, further preferably greater than 1.
- the oxygenates introduced by the reactor feed distributors 3-2 to 3-n and The reactor feed distributor 3-1 enters a mass ratio of methanol of greater than 1, more preferably greater than 5.
- the catalyst comprises a HZSM-5 molecular sieve having both the function of alkylation of methanol and/or dimethyl ether with benzene, methanol to alkene and methanol aromatization.
- the catalyst comprises a HZSM-11 molecular sieve having both the function of alkylation of methanol and/or dimethyl ether with benzene, methanol to alkene and methanol aromatization.
- the regenerated catalyst has a carbon content of ⁇ 0.5 wt.%, and more preferably, the regenerated catalyst has a carbon content of ⁇ 0.1 wt.%.
- the reaction conditions of the reaction zone of the turbulent fluidized bed reactor are: an apparent linear velocity of gas of 0.1 m/s to 2.0 m/s, a reaction temperature of 350 to 600 ° C, and a reaction pressure of 0.1 Mpa to 1.0 MPa, and the bed density is 200 kg/m 3 to 1200 kg/m 3 .
- the reaction conditions of the fluidized bed regenerator regeneration zone are: the apparent apparent linear velocity of the gas is 0.1 m/s to 2 m/s, the regeneration temperature is 500 ° C to 750 ° C, and the regeneration pressure is 0.1 Mpa. 1.0 MPa, the bed density is 200 kg/m 3 to 1200 kg/m 3 .
- the regeneration medium is any one or a mixture of any one of air, oxygen-depleted air or water vapor; the reactor stripping gas, the regenerator stripping gas, and the rising gas to be produced.
- the regeneration lift gas is water vapor or nitrogen.
- the method for co-producing low-carbon olefins for methanol and/or dimethyl ether and benzene to produce para-xylene as described in the present application the conversion of benzene is higher than 40%, the conversion of methanol is higher than 70%, and the selectivity of para-xylene Above 90%, the yield per unit of para-xylene based on aromatics is higher than 32%, and the selectivity of low-carbon olefins (ethylene + propylene + butene) in chain hydrocarbons is more than 70%, and good technical results are obtained.
- the main feature of the turbulent fluidized bed reactor in the present application is that the aromatic hydrocarbon feedstock is introduced from the lowermost reactor feed distributor, and the oxygenates are separately introduced by the n reactor feed distributors, and the highly active regenerated catalyst is directly Enter the bottom of the reaction zone.
- the aromatic feedstock comprises fresh benzene, unconverted benzene, and aromatic by-products, the oxygenate comprising fresh methanol, unconverted methanol, and dimethyl ether.
- the catalyst activity is high, which is favorable for the alkylation reaction of benzene and the isomerization reaction of aromatic hydrocarbon by-products, methyl transfer reaction, etc.;
- the method of multi-stage feeding of oxygenates Only a small portion of the oxygenate is fed from the bottom of the reactor, and the bottom zone contains The low concentration of oxygen compounds and the high concentration of aromatic hydrocarbons weaken the adsorption competitive advantage of oxygen-containing compounds with fast diffusion rate in the pores of molecular sieves to the aromatic hydrocarbons with slow diffusion rate, and ensure that most of the aromatic hydrocarbons are adsorbed in the catalyst in the bottom region;
- Most of the oxygenates are fed from the middle and upper parts, and the oxygenate conversion reaction mainly occurs in the upper middle part of the reaction zone, which avoids the high activity of the regenerated catalyst in the bottom region to rapidly reduce the activity due to carbon formation during the MTO reaction;
- the higher carbon content of the catalyst in the upper middle region of the reaction zone is beneficial to improve the
- the distribution is relatively uniform, and a sufficient alkylation reactant is provided. After the aromatic hydrocarbon adsorbed in the catalyst is contacted with the alkylation reactant, the alkylation reaction rapidly occurs to increase the conversion of benzene and the yield of p-xylene.
- the turbulent fluidized bed reactor in the present application can coordinate and optimize the competition between methanol and/or dimethyl ether and benzene alkylation reaction and MTO reaction, so as to synergistically and increase benzene conversion rate. , p-xylene yield and low carbon olefin yield.
- the present invention coordinates and optimizes the competition between the alkylation reaction and the MTO reaction by controlling the concentration of methanol and/or dimethyl ether relative to benzene to increase the yield of p-xylene and Low-carbon olefin selectivity to ensure that neither the MTO reaction rapidly consumes most of the methanol and/or dimethyl ether to inhibit the alkylation reaction, nor does it occur due to the high levels of methanol and/or dimethyl ether.
- MTO reaction occurs in a large amount, and the amount of benzene adsorbed in the catalyst per unit time is low, which is disadvantageous for the alkylation reaction.
- the fluidized bed reactor and apparatus provided by the present application in a common feed system with a large difference in raw material reaction rates, distributes feeds in different regions through different raw material streams, thereby realizing mass transfer control, thereby coordinating and optimizing
- the cofeed system increases the reaction yield.
- FIG. 1 is a schematic diagram of an apparatus for co-production of low carbon olefins from methanol and/or dimethyl ether with benzene to produce p-xylene according to one embodiment of the present application.
- FIG. 1 a schematic diagram of a device for co-production of a low-carbon olefin with methanol and/or dimethyl ether and benzene to produce para-xylene is shown in FIG. 1 , and the device comprises: a turbulent fluidized bed reactor 1 , which comprises a reactor housing 2, n reactor feed distributors 3-1 to 3-n (the distributor between 3-1 and 3-n in Fig.
- a reactor takes 3-i as an example), a reactor a gas-solid separator 4, a reactor gas-solid separator 5, a reactor heat extractor 6, a product gas outlet 7, a reactor stripper 8, and a perforated plate 26, wherein the lower portion of the turbulent fluidized bed reactor 1 is a reaction
- the upper part of the turbulent fluidized bed reactor 1 is a dilute phase zone, and the n reactor feed distributors 3-1 to 3-n are arranged in the reaction zone from bottom to top, 2 ⁇ n ⁇ 11, perforated plate 26
- the reactor heat extractor 6 is placed outside the reaction zone or reactor housing 2, the reactor gas-solid separator 4 and the reaction
- the gas-solid separator 5 is placed outside the dilute phase zone or the reactor casing 2
- the inlet of the reactor gas-solids separator 4 is connected to the regeneration riser 24, and the catalyst outlet of the reactor gas-solid separator 4 is placed in the reaction zone.
- the gas outlet of the reactor gas-solid separator 4 is placed in a dilute phase zone, the inlet of the reactor gas-solids separator 5 is placed in a dilute phase zone, and the catalyst outlet of the reactor gas-solids separator 5 is placed in the reaction zone, the reactor
- the gas outlet of the gas-solid separator 5 is connected to the product gas outlet 7, and the inlet of the reactor stripper 8 is in the reaction zone of the turbulent fluidized bed reactor 1, the level of which is higher than the first reactor feed distributor And higher than the perforated plate 26.
- the apparatus comprises: a fluidized bed regenerator 14 comprising a regenerator housing 15, a regenerator feed distributor 16, a regenerator gas-solid separator 17, a regenerator heat extractor 18, and a flue gas.
- the regenerator heat extractor 18 is placed in the regeneration zone, the regenerator gas-solid separator 17 is placed outside the dilute phase zone or the regenerator housing 15, and the inlet of the regenerator gas-solids separator 17 is placed in the dilute phase zone, and the regenerator gas is solidified.
- the catalyst outlet of the separator 17 is placed in the regeneration zone, and the gas outlet of the regenerator gas-solid separator 17 is connected to the smoke.
- the gas outlet 19, the inlet of the regenerator stripper 20, is connected to the bottom of the regenerator housing 15.
- the bottom of the reactor stripper 8 is provided with a reactor stripping gas inlet 9, and the bottom of the reactor stripper 8 is connected to the inlet of the inclined tube 10 to be produced.
- the slide valve 11 is connected to the inlet of the riser pipe 12, and the bottom of the riser pipe 12 is provided with a lift gas inlet 13 to be produced.
- the outlet of the riser pipe 12 is connected to the fluidized bed regeneration. a thin phase region of the device 14;
- the bottom of the regenerator stripper 20 is provided with a regenerator stripping gas inlet 21, and the bottom of the regenerator stripper 20 is connected to the inlet of the regenerative inclined tube 22, and the regenerative inclined tube 22 is provided with regenerative sliding
- the valve 23 the outlet of the regeneration ramp 22 is connected to the inlet of the regeneration riser 24, the bottom of the regeneration riser 24 is provided with a regeneration lift gas inlet 25, and the outlet of the regeneration riser 24 is connected to the inlet of the reactor gas-solid separator 4.
- the fluidized bed regenerator 14 may be a turbulent fluidized bed regenerator; the reactor gas-solids separator 4, the reactor gas-solid separator 5, and the regenerator gas-solid separator 17 may be It is a cyclone separator.
- the method for co-producing low-carbon olefins for methanol and/or dimethyl ether and benzene to produce para-xylene includes:
- the methanol is fed from the reactor feed distributors 3-2 to 3-n in the turbulent fluidized bed reactor 1 to the reaction zone of the turbulent fluidized bed reactor 1, and is contacted with the catalyst to form p-xylene and a stream of low olefin products and a carbon-containing catalyst;
- the regenerated catalyst passes through the regenerator stripper 20, the regeneration inclined tube 22, the regeneration slide valve 23 and the regeneration riser 24 to enter the inlet of the reactor gas-solid separator 4, and after the gas-solid separation, the regenerated catalyst enters the turbulent fluidized bed reaction.
- the device 1 The bottom of the reaction zone;
- the reactor stripping gas is fed from the reactor stripping gas inlet 9 into the reactor stripper 8 in countercurrent contact with the catalyst to be produced, and then enters the turbulent fluidized bed reactor 1; the rising gas is raised by the rising gas inlet 13 entering the standby riser 12 and the catalyst to be produced in downstream contact, and then entering the dilute phase region of the fluidized bed regenerator 14;
- regenerator stripping gas is fed from the regenerator stripping gas inlet 21 into the regenerator stripper 20 in countercurrent contact with the regenerated catalyst and then into the fluidized bed regenerator 14; the regenerative ascending gas is passed from the regenerating ascending gas inlet 25 to the regenerative riser 24 is in downstream contact with the regenerated catalyst and then enters the inlet of the reactor gas-solids separator 4.
- the apparatus shown in Fig. 1 is employed, but the reactor fluid-bed reactor 1 does not include the reactor gas-solid separator 4 and the perforated plate 26, and the regeneration riser 24 is directly connected to the dilute phase of the turbulent fluidized bed reactor 1. Area.
- the turbulent fluidized bed reactor 1 contains one reactor feed distributor 3-1.
- the reaction conditions of the reaction zone of the fluidized bed reactor 1 are: the apparent linear velocity of the gas is about 1.0 m/s, the reaction temperature is about 500 ° C, the reaction pressure is about 0.15 MPa, and the bed density is about 350 kg/m 3 .
- the reaction conditions of the regeneration zone of the fluidized bed regenerator 14 are: the apparent apparent linear velocity of the gas is about 1.0 m/s, the regeneration temperature is about 650 ° C, the regeneration pressure is about 0.15 MPa, and the bed density is about 350 kg/m 3 .
- the catalyst contains HZSM-5 molecular sieve, and the regenerated catalyst has a carbon content of about 0.1 wt.%.
- the regeneration medium is air; the reactor stripping gas, the regenerator stripping gas, the waiting lift gas and the regeneration lift gas are water vapor.
- the molar ratio of aromatic hydrocarbon to methanol was 0.5.
- the experimental results are: benzene conversion rate of 20%, methanol conversion rate of 99%, para-xylene selectivity of 98%, aromatics-based para-xylene mass per pass yield of 15%, low-carbon olefins (ethylene + propylene + butyl)
- the selectivity of the alkene in the chain hydrocarbon is 66%.
- the turbulent fluidized bed reactor 1 contains three reactor feed distributors 3-1 to 3-3, The opening ratio of the perforated plate 26 was 10%, and the reactor gas-solid separator 4 was placed inside the reactor case 2.
- the reaction conditions of the reaction zone of the fluidized bed reactor 1 are: the apparent linear velocity of the gas is about 1.0 m/s, the reaction temperature is about 500 ° C, the reaction pressure is about 0.15 MPa, and the bed density is about 350 kg/m 3 .
- the reaction conditions of the regeneration zone of the fluidized bed regenerator 14 are: the apparent apparent linear velocity of the gas is about 1.0 m/s, the regeneration temperature is about 650 ° C, the regeneration pressure is about 0.15 MPa, and the bed density is about 350 kg/m 3 .
- the catalyst contains HZSM-5 molecular sieve, and the regenerated catalyst has a carbon content of about 0.1 wt.%.
- the regeneration medium is air; the reactor stripping gas, the regenerator stripping gas, the waiting lift gas and the regeneration lift gas are water vapor.
- the mass ratio of aromatic hydrocarbon to methanol was 2 by the reactor inlet distributor 3-1 at the bottom of the fluidized bed reactor.
- the molar ratio of the oxygenate entering from the reactor feed distributors 3-2 to 3-3 to the methanol entering from the reactor feed distributor 3-1 was three.
- the experimental results are: benzene conversion rate of 41%, methanol conversion rate of 97%, para-xylene selectivity of 98%, aromatics-based para-xylene mass per pass yield of 32%, low-carbon olefins (ethylene + propylene + butyl The selectivity of the alkene in the chain hydrocarbon is 75%.
- the regenerated catalyst enters the bottom of the turbulent fluidized bed reactor, while the regenerated catalyst of Example 1 enters the dilute phase zone of the turbulent fluidized bed reactor;
- Example 3 contained a porous plate, and Example 1 contained no porous plate.
- Example 2 Comparing the present example with Example 1, it is known that the catalyst is first exposed to a high concentration of aromatic hydrocarbon raw material, which greatly improves the conversion of benzene, the yield of p-xylene and the selectivity of lower olefins.
- the turbulent fluidized bed reactor 1 contains six reactor feed distributors 3-1 to 3-6, the open cell ratio of the perforated plate is 5%, and the reactor gas-solid separator 4 Placed inside the reactor housing 2.
- the reaction conditions of the reaction zone of the fluidized bed reactor 1 are: the apparent linear velocity of the gas is about 0.8 m/s, the reaction temperature is about 560 ° C, the reaction pressure is about 0.6 MPa, and the bed density is about 460 kg/m 3 .
- the reaction conditions of the regeneration zone of the fluidized bed regenerator 14 are: the apparent apparent linear velocity of the gas is about 1.7 m/s, the regeneration temperature is about 600 ° C, the regeneration pressure is about 0.6 MPa, and the bed density is about 220 kg/m 3 .
- the catalyst contains HZSM-11 molecular sieve, and the regenerated catalyst has a carbon content of about 0.15 wt.%.
- the regeneration medium is air; the reactor stripping gas, the regenerator stripping gas, the waiting lift gas and the regeneration lift gas are water vapor.
- the mass ratio of aromatic hydrocarbon to methanol was 4 by the reactor inlet distributor 3-1 at the bottom of the fluidized bed reactor.
- the molar ratio of the oxygenate entering from the reactor feed distributors 3-2 to 3-6 to the methanol entering from the reactor feed distributor 3-1 was 20.
- the experimental results are: benzene conversion rate of 45%, methanol conversion rate of 73%, para-xylene selectivity of 94%, aromatics-based para-xylene mass per pass yield of 42%, low-carbon olefins (ethylene + propylene + butyl)
- the selectivity of the alkene in the chain hydrocarbon is 73%.
- the turbulent fluidized bed reactor 1 contains four reactor feed distributors 3-1 to 3-4, without the perforated plate 26, and the reactor gas-solid separator 4 is placed in the reactor.
- the reaction conditions of the reaction zone of the fluidized bed reactor 1 are: the apparent linear velocity of the gas is about 1.5 m/s, the reaction temperature is about 440 ° C, the reaction pressure is about 0.2 MPa, and the bed density is about 280 kg/m 3 .
- the reaction conditions of the regeneration zone of the fluidized bed regenerator 14 are: the apparent apparent linear velocity of the gas is about 1.2 m/s, the regeneration temperature is about 700 ° C, the regeneration pressure is about 0.2 MPa, and the bed density is about 330 kg/m 3 .
- the catalyst contains HZSM-5 molecular sieve, and the regenerated catalyst has a carbon content of about 0.15 wt.%.
- the regeneration medium is water vapor; the reactor stripping gas, the regenerator stripping gas, the waiting lift gas, and the regeneration lift gas are nitrogen.
- the mass ratio of aromatic hydrocarbon to methanol was 3 by the reactor feed distributor 3-1 entering the lowermost portion of the fluidized bed reactor.
- the molar ratio of the oxygenate entering from the reactor feed distributors 3-1 to 3-4 to the methanol entering from the reactor feed distributor 3-1 was 10.
- the experimental results are: benzene conversion rate of 42%, methanol conversion rate of 86%, para-xylene selectivity of 91%, aromatics-based para-xylene mass per pass yield of 38%, low-carbon olefins (ethylene + propylene + butyl)
- the selectivity of the alkene in the chain hydrocarbon is 71%.
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Claims (26)
- 一种用于甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的湍动流化床反应器,其特征在于,所述湍动流化床反应器包含第一反应器进料分布器和多个第二反应器进料分布器,所述第一反应器进料分布器和多个第二反应器进料分布器沿所述湍动流化床反应器中气体流向依次布置。
- 根据权利要求1所述的湍动流化床反应器,其特征在于,所述第二反应器进料分布器为2至10个。
- 根据权利要求1所述的湍动流化床反应器,其特征在于,所述湍动流化床反应器包括第一反应器气固分离器和第二反应器气固分离器,所述第一反应器气固分离器置于稀相区或反应器壳体外部,所述第二反应器气固分离器置于稀相区或反应器壳体外部;所述第一反应器气固分离器设有再生催化剂入口,所述第一反应器气固分离器的催化剂出口置于反应区的底部,所述第一反应器气固分离器的气体出口置于稀相区;所述第二反应器气固分离器的入口置于所述稀相区,所述第二反应器气固分离器的催化剂出口置于所述反应区,所述第二反应器气固分离器的气体出口连接于湍动流化床反应器产品气出口;所述反应区位于所述湍动流化床反应器的下部,所述稀相区位于所述湍动流化床反应器的上部。
- 根据权利要求3所述的湍动流化床反应器,其特征在于,所述第一反应器气固分离器和第二反应器气固分离器是旋风分离器。
- 根据权利要求1所述的湍动流化床反应器,其特征在于,所述湍动流化床反应器包括反应器取热器,反应器取热器置于所述湍动流化床反应器壳体内部或外部。
- 根据权利要求5所述的湍动流化床反应器,其特征在于,所述反应器取热器设置于所述多个反应器进料分布器之间。
- 根据权利要求1所述的湍动流化床反应器,其特征在于,所述湍动流化床反应器包括反应器汽提器,所述反应器汽提器在湍动流化床反应器的底部由外向内穿过反 应器壳体并且开口于湍动流化床反应器的反应区内,所述反应器汽提器的底部设有反应器汽提气入口和待生催化剂出口。
- 根据权利要求1所述的湍动流化床反应器,其特征在于,所述湍动流化床反应器包含多孔板,所述多孔板位于第一反应器进料分布器和至少一个第二反应器进料分布器之间,所述多孔板的开孔率≤50%。
- 根据权利要求8所述的湍动流化床反应器,其特征在于,所述湍动流化床反应器包含多孔板,所述多孔板位于第一反应器进料分布器和与第一反应器进料分布器最近的一个第二反应器进料分布器之间,所述多孔板的开孔率为5%~50%。
- 根据权利要求1所述的湍动流化床反应器,其特征在于,所述反应器汽提器在湍动流化床反应器的底部由外向内穿过反应器壳体并且开口于湍动流化床反应器的反应区内,所述反应器汽提器的底部设有反应器汽提气入口和待生催化剂出口;所述湍动流化床反应器包含多孔板,所述多孔板位于第一反应器进料分布器和至少一个第二反应器进料分布器之间,所述多孔板的开孔率≤50%;所述反应器汽提器在反应器壳体内部的开口的水平高度高于第一反应器进料分布器且高于所述多孔板。
- 一种用于甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的装置,其特征在于,所述装置包含权利要求1至10任一项所述的湍动流化床反应器中的至少一种和用于再生催化剂的流化床再生器。
- 根据权利要求11所述的装置,其特征在于,所述流化床再生器是湍动流化床再生器,所述流化床再生器包含再生器壳体、再生器气固分离器、再生器取热器和再生器汽提器;流化床再生器的下部是再生区,流化床再生器的上部是再生器稀相区,再生器进料分布器置于再生区的底部,再生器取热器置于再生区,再生器气固分离器置于稀相区或再生器壳体外部;所述再生器气固分离器的入口置于再生器稀相区,所述再生器气固分离器的催化剂出口置于再生区,再生器汽提器开口于再生器壳体的底部。
- 根据权利要求11所述的装置,其特征在于,所述流化床再生器包含再生器壳体、再生器进料分布器、再生器气固分离器、再生器取热器、烟气出口和再生器汽提 器;所述流化床再生器的下部是再生区,流化床再生器的上部是稀相区;再生器进料分布器置于再生区的底部,再生器取热器置于再生区,再生器气固分离器置于稀相区或再生器壳体外部,再生器气固分离器的入口置于稀相区,再生器气固分离器的催化剂出口置于再生区,再生器气固分离器的气体出口连接于烟气出口,再生器汽提器开口于再生器壳体的底部;所述反应器汽提器的待生催化剂出口连接于待生斜管的入口,待生斜管中设有待生滑阀,待生斜管的出口连接于待生提升管的入口,待生提升管的底部设有待生提升气入口,待生提升管的出口连接于流化床再生器的稀相区;所述再生器汽提器的底部设有再生器汽提气入口,再生器汽提器的底部连接于再生斜管的入口,再生斜管中设有再生滑阀,再生斜管的出口连接于再生提升管的入口,再生提升管的底部设有再生提升气入口,再生提升管的出口连接于第一反应器气固分离器的再生催化剂入口,所述第一反应器气固分离器置于流化床反应器的稀相区或反应器壳体外部。
- 一种甲醇和/或二甲醚与苯制对二甲苯联产低碳烯烃的方法,其特征在于,采用权利要求1至10任一项所述湍动流化床反应器中的至少一种。
- 根据权利要求14所述的方法,其特征在于,将含有甲醇和/或二甲醚与苯的原料A由第一反应器进料分布器送入湍动流化床反应器的反应区,将含有甲醇和/或二甲醚的原料B分别由多个第二反应器进料分布器送入湍动流化床反应器的反应区与催化剂接触,生成含有对二甲苯和低碳烯烃产品的物流C和待生催化剂。
- 根据权利要求15所述的方法,其特征在于,将所述物流C分离获得对二甲苯、低碳烯烃、C5+链烃、芳烃副产物以及未转化的甲醇、二甲醚和苯;其中,未转化的甲醇和二甲醚由多个第二反应器进料分布器送入湍动流化床反应器的反应区,芳烃副产物和未转化的苯由第一反应器进料分布器送入湍动流化床反应器的反应区与催化剂接触。
- 根据权利要求15所述的方法,其特征在于,所述待生催化剂经流化床再生器再生后,进入湍动流化床反应器中反应区的底部。
- 根据权利要求15所述的方法,其特征在于,所述方法包括如下步骤:(1)将含有甲醇和/或二甲醚与苯的物流A由湍动流化床反应器下方的第一反应器进料分布器送入湍动流化床反应器的反应区与催化剂接触;(2)将含有甲醇和/或二甲醚的物流B分别由2至10个第二反应器进料分布器送入湍动流化床反应器的反应区与催化剂接触,生成含有对二甲苯和低碳烯烃产品的物流C和待生催化剂;所述2至10个第二反应器进料分布器依次布置在第一反应器进料分布器的上方;(3)将步骤(2)得到物流C分离得到未转化的甲醇和二甲醚物流C-1,未转化的苯和芳烃副产物物流C-2;将物流C-1分别由2至10个第二反应器进料分布器送入湍动流化床反应器的反应区与催化剂接触;将物流C-2由第一反应器进料分布器送入湍动流化床反应器的反应区与催化剂接触;所述芳烃副产物包含甲苯、邻二甲苯、间二甲苯、乙苯和C9+芳烃;(4)将步骤(2)得到待生催化剂经流化床再生器再生,再生催化剂经第一反应器气固分离器,气固分离后,进入湍动流化床反应器中反应区的底部。
- 根据权利要求15或18所述的方法,其特征在于,由第一反应器进料分布器送入湍动流化床反应器的混合物中,芳烃的分子摩尔数与甲醇和/或二甲醚的碳摩尔数之比大于0.5。
- 根据权利要求15或18所述的方法,其特征在于,由多个第二反应器进料分布器进入湍动流化床反应器的混合物中的全部含氧化合物和由第一反应器进料分布器进入的甲醇的摩尔比大于1。
- 根据权利要求18所述的方法,其特征在于,催化剂再生采用权利要求11所述的装置中的至少一种。
- 根据权利要求18所述的方法,其特征在于,待生催化剂经过反应器汽提器、待生斜管、待生滑阀和待生提升管进入流化床再生器的稀相区;再生介质通入流化床再生器的再生区,和待生催化剂发生烧炭反应,生成含有CO、CO2的烟气和再生催化剂,烟气经过再生器气固分离器除尘后排放;再生催化剂经过再生器汽提器、再生斜管、再生滑阀和再生提升管进入第一反应器气固分离器入口,气固分离后,再生催化剂进入湍动流化床反应器中反应区的底部;反应器汽提气由反应器汽提气入口进入反应器汽提器和待生催化剂逆流接触,然后进入湍动流化床反应器;待生提升气由待生提升气入口进入待生提升管和待生催化 剂顺流接触,然后进入流化床再生器的稀相区;再生器汽提气由再生器汽提气入口进入再生器汽提器和再生催化剂逆流接触,然后进入流化床再生器;再生提升气由再生提升气入口进入再生提升管和再生催化剂顺流接触,然后进入第一反应器气固分离器的入口,所述第一反应器气固分离器置于流化床反应器的稀相区或反应器壳体外部。
- 根据权利要求22所述的方法,其特征在于,所述再生催化剂碳含量≤0.5wt%。
- 根据权利要求22所述的方法,其特征在于,所述再生介质为空气、贫氧空气或水蒸气中的至少一种;和/或,所述反应器汽提气、再生器汽提气、待生提升气和再生提升气为水蒸气和/或氮气。
- 根据权利要求22所述的方法,其特征在于,所述湍动流化床反应器反应区反应条件为:气体表观线速度为0.1m/s~2.0m/s,反应温度为350℃~600℃,反应压力为0.1Mpa~1.0MPa,床层密度为200kg/m3~1200kg/m3。
- 根据权利要求22所述的方法,其特征在于,所述流化床再生器再生区反应条件为:气体表观线速度为0.1m/s~2.0m/s,再生温度为500℃~750℃,再生压力为0.1Mpa~1.0MPa,床层密度为200kg/m3~1200kg/m3。
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US11161085B2 (en) | 2021-11-02 |
EP3616782A1 (en) | 2020-03-04 |
JP6848088B2 (ja) | 2021-03-24 |
RU2743135C9 (ru) | 2021-08-12 |
KR20190140468A (ko) | 2019-12-19 |
CN108786671B (zh) | 2021-04-23 |
KR102309236B1 (ko) | 2021-10-06 |
CN108786671A (zh) | 2018-11-13 |
JP2020517596A (ja) | 2020-06-18 |
EP3616782A4 (en) | 2020-05-13 |
US20210121842A1 (en) | 2021-04-29 |
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