WO2018132247A3 - Bridged bis(indenyl) transitional metal complexes, production, and use thereof - Google Patents

Bridged bis(indenyl) transitional metal complexes, production, and use thereof Download PDF

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Publication number
WO2018132247A3
WO2018132247A3 PCT/US2017/068158 US2017068158W WO2018132247A3 WO 2018132247 A3 WO2018132247 A3 WO 2018132247A3 US 2017068158 W US2017068158 W US 2017068158W WO 2018132247 A3 WO2018132247 A3 WO 2018132247A3
Authority
WO
WIPO (PCT)
Prior art keywords
indenyl
production
metal complexes
catalysts
transitional metal
Prior art date
Application number
PCT/US2017/068158
Other languages
French (fr)
Other versions
WO2018132247A2 (en
Inventor
Jian Yang
Xiongdong Lian
Original Assignee
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.
Priority to EP17891908.0A priority Critical patent/EP3568418A4/en
Publication of WO2018132247A2 publication Critical patent/WO2018132247A2/en
Publication of WO2018132247A3 publication Critical patent/WO2018132247A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The present disclosure relates to bridged metallocene catalysts that include at least one indenyl ligand substituted at the 2-position with a C3-C10 branched alkyl, such as isopropyl. Catalyst systems including the catalysts, polymerization processes using the catalysts, and polymers made using the catalysts are also described.
PCT/US2017/068158 2017-01-13 2017-12-22 Bridged bis(indenyl) transitional metal complexes, production, and use thereof WO2018132247A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP17891908.0A EP3568418A4 (en) 2017-01-13 2017-12-22 Bridged bis(indenyl) transitional metal complexes, production, and use thereof

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201762446007P 2017-01-13 2017-01-13
US62/446,007 2017-01-13
EP17162056 2017-03-21
EP17162056.0 2017-03-21

Publications (2)

Publication Number Publication Date
WO2018132247A2 WO2018132247A2 (en) 2018-07-19
WO2018132247A3 true WO2018132247A3 (en) 2018-08-30

Family

ID=58412886

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2017/068158 WO2018132247A2 (en) 2017-01-13 2017-12-22 Bridged bis(indenyl) transitional metal complexes, production, and use thereof

Country Status (1)

Country Link
WO (1) WO2018132247A2 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003002583A2 (en) * 2001-06-29 2003-01-09 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US20100113717A1 (en) * 2004-12-16 2010-05-06 Voskoboynikov Alexander Z Process For Producing Substituted Metallocene Compounds For Olefin Polymerization
WO2014070655A1 (en) * 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems and methods of preparation thereof
WO2015009471A1 (en) * 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
WO2016196331A1 (en) * 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003002583A2 (en) * 2001-06-29 2003-01-09 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US20100113717A1 (en) * 2004-12-16 2010-05-06 Voskoboynikov Alexander Z Process For Producing Substituted Metallocene Compounds For Olefin Polymerization
WO2014070655A1 (en) * 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems and methods of preparation thereof
WO2015009471A1 (en) * 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
WO2016196331A1 (en) * 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization

Also Published As

Publication number Publication date
WO2018132247A2 (en) 2018-07-19

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