WO2018109002A1 - Combinaisons de composés actifs - Google Patents
Combinaisons de composés actifs Download PDFInfo
- Publication number
- WO2018109002A1 WO2018109002A1 PCT/EP2017/082607 EP2017082607W WO2018109002A1 WO 2018109002 A1 WO2018109002 A1 WO 2018109002A1 EP 2017082607 W EP2017082607 W EP 2017082607W WO 2018109002 A1 WO2018109002 A1 WO 2018109002A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- methyl
- difluoromethyl
- pyrazole
- carboxamide
- fluoro
- Prior art date
Links
- 0 C*c1c(*)c(*)c(*)c(Oc(cc2*)c(*C)cc2N)c1 Chemical compound C*c1c(*)c(*)c(*)c(Oc(cc2*)c(*C)cc2N)c1 0.000 description 9
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/52—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
Definitions
- WO2003/093224 discloses the use of arylamidine derivatives as fungicides.
- WO2007/031508 and WO2007/093227 disclose the use of arylamidine derivatives as fungicides and insecticides.
- the active compound combinations according to the invention have further surprising properties which, in a wider sense, may also be called synergistic, such as, for example: broadening of the activity spectrum to other insects, nematodes and/or phytopathogens, for example to resistant strains of plant diseases; lower application rates of the active compounds; sufficient control of pests with the aid of the active compound combinations according to the invention even at application rates where the individual compounds show no or virtually no activity; advantageous behaviour during formulation or during use, for example during grinding, sieving, emulsifying, dissolving or dispensing; improved storage stability and light stability; advantageous residue formation; improved toxicological or ecotoxicological behaviour; improved properties of the plant so called plant physiology effects, for example better growth, increased harvest yields, a better developed root system, a larger leaf area, greener leaves, stronger shoots, less seed required, lower phytotoxicity, mobilization of the defence system of the plant, good compatibil
- the present invention provides an active compound combination comprising: (A) at least one compound of the formula (I)
- R 1 is selected from the group consisting of ethyl and isopropyl
- R 3 is selected from the group consisting of methyl, halogen and halomethyl
- the compounds of formula (I) can exist in one or more optical or chiral isomer forms depending on the number of asymmetric centres in the compound.
- the invention thus relates equally to combinations comprising any of the optical isomers and their racemic or scalemic mixtures (the term “scalemic” denotes a mixture of enantiomers in different proportions) and mixtures of all the possible stereoisomers, in all proportions.
- the diastereoisomers and/or the optical isomers can be separated according to the methods which are known per se by the man ordinary skilled in the art.
- the compounds of the formula (I) carry amidine groups which induce basic properties. Thus, these compounds can be reacted with acids to give salts.
- inorganic acids are hydrohalic acids, such as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide, sulfuric acid, phosphoric acid and nitric acid, and acidic salts, such as NaHS0 4 and KHS0 4 .
- tertiary amines such as, for example, trimethylamine, triethylamine, tributylamine, N,N- dimethylaniline, ⁇ , ⁇ -dimethylbenzylamine, pyridine, N-methylpiperidine, N-methylpyrolidone, N,N- dimethylaminopyridine, diazabicyclooctane (DABCO), diazabicyclononene (DBN) and diazabicycloundecene (DBU).
- DABCO diazabicyclooctane
- DBN diazabicyclononene
- DBU diazabicycloundecene
- Step (c) In a further alternative embodiment according to the invention, aniline derivatives of the formula (VII) are reacted with phenol derivatives of the formula (II) or the phenoxides formed therefrom in accordance with the reaction scheme above to give aminophenyl ethers of the formula (VIII).
- aminophenols of the formula (XII) are reacted with phenyl derivatives of the formula (IV) in accordance with the reaction scheme above to give aminophenyl ethers of the formula (VIII).
- the reaction conditions the solvents, the catalysts, the substitution patterns of the aminophenyl ether (VIII) and the suitable leaving groups, reference may be made to steps (a) and (c).
- compositions according to the invention comprise (B) at least one further active compound selected from:
- Preferred combinations are selected from the group (GO) consisting of the following active compound combinations:
- Also preferred combinations are selected from the group (G9) consisting of the following active compound combinations: (1-9) + (1.001), (1-9) + (1.002), (1-9) + (1.003), (1-9) + (1.004), (1-9) + (1.005), (1-9) + (1.006), (1-9) +
- Most preferred combinations are selected from the group (G4-2) consisting of the following active compound combinations: (1-4) + (1.002), (1-4) + (1.005), (1-4) + (1.006), (1-4) + (1.018), (1-4) + (1.020), (1-4) + (1.021), (1-4) + (1.081), (1-4) + (2.001), (1-4) + (2.002), (1-4) + (2.005), (1-4) + (2.007), (1-4) + (2.019), (1-4) + (2.027), (1-4) + (2.030), (1-4) + (2.057), (1-4) + (3.016), (1-4) + (3.020), (1-4) + (3.025), (1-4) + (3.026), (1-4) + (3.030), (1-4) + (5.004), (1-4) + (5.013), (1-4) + (5.018), (1-4) + (15.047).
- an "effective but non-phytotoxic amount” means an amount of the inventive composition which is sufficient to control the fungal disease of the plant in a satisfactory manner or to eradicate the fungal disease completely, and which, at the same time, does not cause any significant symptoms of phytotoxicity.
- this application rate may vary within a relatively wide range. It depends on several factors, for example on the fungus to be controlled, the plant, the climatic conditions and the ingredients of the inventive compositions.
- a carrier is a solid or liquid, natural or synthetic, organic or inorganic substance that is generally inert.
- the carrier generally improves the application of the compounds, for instance, to plants, plants parts or seeds.
- suitable solid carriers include, but are not limited to, ammonium salts, natural rock flours, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite and diatomaceous earth, and synthetic rock flours, such as finely divided silica, alumina and silicates.
- composition of the invention may be in any customary form, such as solutions (e.g aqueous solutions), emulsions, wettable powders, water- and oil-based suspensions, powders, dusts, pastes, soluble powders, soluble granules, granules for broadcasting, suspoemulsion concentrates, natural or synthetic products impregnated with the active compound combinations, fertilizers and also microencapsulations in polymeric substances.
- solutions e.g aqueous solutions
- emulsions e.g. aqueous solutions
- emulsions e.g. aqueous solutions
- emulsions e.g. aqueous solutions
- emulsions e.g. aqueous solutions
- emulsions e.g. aqueous solutions
- emulsions e.g. aqueous solutions
- wettable powders e.g., water- and oil-based suspensions
- powders e.
- Control or controlling as used herein encompasses curative and protective treatment of unwanted microorganisms.
- Unwanted microorganisms may be pathogenic bacteria or pathogenic fungi, more specifically phytopathogenic bacteria or phytopathogenic fungi.
- these phytopathogenic microorganims are the causal agents of a broad spectrum of plants diseases.
- the active compound combination according to the invention and the composition of the invention can be used as fungicides.
- they can be useful in crop protection, for example for the control of unwanted fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.
- Effective and non-phytotoxic amount means an amount that is sufficient to control or destroy the fungi present or liable to appear on the cropland and that does not entail any appreciable symptom of phytotoxicity for said crops. Such an amount can vary within a wide range depending on the fungus to be controlled, the type of crop, the climatic conditions and the respective active compound combination or composition of the invention used. This amount can be determined by systematic field trials that are within the capabilities of a person skilled in the art. Plants and plant parts
- GMO Genetically modified plants
- GMO Genetically modified plants
- heterologous gene essentially means a gene which is provided or assembled outside the plant and when introduced in the nuclear, chloroplastic or mitochondrial genome. This gene gives the transformed plant new or improved agronomic or other properties by expressing a protein or polypeptide of interest or by downregulating or silencing other gene(s) which are present in the plant (using for example, antisense technology, cosuppression technology, RNA interference - RNAi - technology or microRNA - miRNA - technology).
- a heterologous gene that is located in the genome is also called a transgene.
- a transgene that is defined by its particular location in the plant genome is called a transformation or transgenic event.
- Rubiaceae sp. for example coffee
- Theaceae sp. Sterculiceae sp.
- Rutaceae sp. for example lemons, oranges and grapefruit
- Solanaceae sp. for example tomatoes
- Liliaceae sp. for example lettuce
- Umbelliferae sp. for example lettuce
- Alliaceae sp. for example leek, onion
- peas for example peas
- major crop plants such as Gramineae sp. (for example maize, turf, cereals such as wheat, rye, rice, barley, oats, millet and triticale), Asteraceae sp. (for example sunflower), Brassicaceae sp. (for example white cabbage, red cabbage, broccoli, cauliflower, Brussels sprouts, pak choi, kohlrabi, radishes, and oilseed rape, mustard, horseradish and cress), Fabacae sp. (for example bean, peanuts), Papilionaceae sp. (for example soya bean), Solanaceae sp. (for example potatoes), Chenopodiaceae sp. (for example sugar beet, fodder beet, swiss chard, beetroot); useful plants and ornamental plants for gardens and wooded areas; and genetically modified varieties of each of these plants
- Gramineae sp.
- Increased plant vigor comprising plant health / plant quality and seed vigor, reduced stand failure, improved appearance, increased recovery after periods of stress, improved pigmentation (e.g. chlorophyll content, stay-green effects, etc.) and improved photosynthetic efficiency.
- the invention further comprises a method for treating seed.
- the treatment of the seed of cereals (such as wheat, barley, rye, triticale and oats), maize and rice is of particular significance.
- the treatment of transgenic seed with the inventive active compound combinations or compositions is of particular significance.
- This relates to the seed of plants containing at least one heterologous gene which enables the expression of a polypeptide or protein having insecticidal properties.
- the heterologous gene in transgenic seed can originate, for example, from microorganisms of the species Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium.
- This heterologous gene preferably originates from Bacillus sp., in which case the gene product is effective against the European maize borer and/or the Western maize rootworm
- the heterologous gene more preferably originates from Bacillus thuringiensis .
- Useful wetting agents which may be present in the seed dressing formulations usable in accordance with the invention are all substances which promote wetting and which are conventionally used for the formulation of active agrochemical ingredients. Preference is given to using alkyl naphthalenesulphonates, such as diisopropyl or diisobutyl naphthalenesulphonates.
- the compounds A and B are advantageously present in a synergistically effective weight ratio of A:B in a range of 100:1 to 1 :100, preferably in a weight ratio of 50:1 to 1 :50, more preferably in a weight ratio of 20:1 to 1 :20, even more preferably in a weight ratio of 10: 1 to 1 : 10.
- a synergistic effect of e.g. fungicides is always present when the fungicidal activity of the active compound combinations exceeds the total of the activities of the active compounds when applied individually.
- the expected activity for a given combination of two active compounds can be calculated as follows:
- E represents the expected percentage of inhibition of the disease for the combination of two fungicides at defined doses (for example equal to x and y respectively)
- x is the percentage of inhibition observed for the disease by the compound (A) at a defined dose (equal to x)
- y is the percentage of inhibition observed for the disease by the compound (B) at a defined dose (equal to y).
- Y is the efficacy when active compound B is applied at an application rate of n ppm (or g/ha),
- the degree of efficacy, expressed in % is denoted. 0 % means an efficacy which corresponds to that of the control while an efficacy of 100 % means that no disease is observed.
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
L'invention concerne des combinaisons de composés actifs, en particulier dans une composition qui comprend (A) un ou plusieurs composés phénylamidine de formule (I) et un ou plusieurs composés fongicides (B). En outre, l'invention concerne un procédé de lutte contre les champignons phytopathogènes des plantes, l'utilisation d'une combinaison de composés actifs selon l'invention pour le traitement d'une ou de plusieurs graines, un procédé de protection d'une ou de plusieurs graines et de la graine traitée correspondante. (I)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16204164 | 2016-12-14 | ||
EP16204164.4 | 2016-12-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2018109002A1 true WO2018109002A1 (fr) | 2018-06-21 |
Family
ID=57570157
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2017/082607 WO2018109002A1 (fr) | 2016-12-14 | 2017-12-13 | Combinaisons de composés actifs |
Country Status (3)
Country | Link |
---|---|
AR (1) | AR110367A1 (fr) |
UY (1) | UY37521A (fr) |
WO (1) | WO2018109002A1 (fr) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3616515A1 (fr) * | 2018-08-31 | 2020-03-04 | Sumitomo Chemical Company, Limited | Composition et procédé de lutte contre les maladies des plantes |
EP3616517A1 (fr) * | 2018-08-31 | 2020-03-04 | Sumitomo Chemical Company, Limited | Composition et procédé de lutte contre les maladies des plantes |
EP3616516A1 (fr) * | 2018-08-31 | 2020-03-04 | Sumitomo Chemical Company, Limited | Composition de lutte de maladies végétales et procédé de lutte de maladies végétales |
WO2021069706A1 (fr) * | 2019-10-11 | 2021-04-15 | Bayer Aktiengesellschaft | Combinaisons de composés actifs |
WO2021069707A1 (fr) * | 2019-10-11 | 2021-04-15 | Bayer Aktiengesellschaft | Combinaisons de composés actifs |
WO2021069704A1 (fr) * | 2019-10-11 | 2021-04-15 | Bayer Aktiengesellschaft | Combinaisons de composés actifs |
WO2021069702A1 (fr) * | 2019-10-11 | 2021-04-15 | Bayer Aktiengesellschaft | Combinaisons de composés actifs |
WO2022238157A1 (fr) | 2021-05-11 | 2022-11-17 | Basf Se | Mélanges fongicides comprenant des 3-phényl-5-(trifluorométhyl)-1,2,4-oxadiazoles substitués |
US11634389B2 (en) | 2018-11-28 | 2023-04-25 | The Regents Of The University Of Michigan | Succinate dehydrogenase inhibitors and methods of making and using the same |
Citations (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4245432A (en) | 1979-07-25 | 1981-01-20 | Eastman Kodak Company | Seed coatings |
US4272417A (en) | 1979-05-22 | 1981-06-09 | Cargill, Incorporated | Stable protective seed coating |
US4808430A (en) | 1987-02-27 | 1989-02-28 | Yazaki Corporation | Method of applying gel coating to plant seeds |
WO1991007874A1 (fr) | 1989-11-30 | 1991-06-13 | Hoechst Aktiengesellschaft | Pyrazoline pour la protection de plantes cultivees contre les herbicides |
US5876739A (en) | 1996-06-13 | 1999-03-02 | Novartis Ag | Insecticidal seed coating |
WO2000046184A1 (fr) | 1999-02-06 | 2000-08-10 | Aventis Cropscience Gmbh | Derive n2-phenylamidine |
WO2002028186A2 (fr) | 2000-10-06 | 2002-04-11 | Monsanto Technology, Llc | Traitement de semences avec des melanges d'insecticides |
WO2002080675A1 (fr) | 2001-03-21 | 2002-10-17 | Monsanto Technology, Llc | Procede permettant de commander la liberation de principes actifs agricoles de semences traitees de plantes |
WO2003024219A1 (fr) | 2001-09-10 | 2003-03-27 | Bayer Cropscience S.A. | Melange fongicide contenant des derives d'arylamidine |
US20030176428A1 (en) | 1998-11-16 | 2003-09-18 | Schneidersmann Ferdinand Martin | Pesticidal composition for seed treatment |
WO2003093224A1 (fr) | 2002-05-03 | 2003-11-13 | E.I. Du Pont De Nemours And Company | Composes amidinylphenyle et utilisations de ceux-ci comme fongicides |
WO2004037239A1 (fr) | 2002-10-24 | 2004-05-06 | Bayer Cropscience S.A. | Medicaments antifongiques contenant des derives d'arylamidine |
WO2005089547A1 (fr) | 2004-03-05 | 2005-09-29 | Bayer Cropscience Sa | Composition fongicide comprenant un derive arylamidine et des composes fongicides connus |
WO2005094582A1 (fr) * | 2004-03-22 | 2005-10-13 | Basf Aktiengesellschaft | Melanges fongicides |
WO2005120234A2 (fr) | 2004-06-03 | 2005-12-22 | E.I. Dupont De Nemours And Company | Melanges fongicides de composes d'amidinylphenyle |
WO2007031508A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives pesticides phenyloxy substitues phenylamidine |
WO2007031512A2 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives de biphenylamidine pesticides |
WO2007031507A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Préparation fongicide comprenant un dérivé d'arylamidine et deux composés fongicides connus |
WO2007031524A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives de phenylamidine pesticides pyrimidinyloxy substitues |
WO2007031523A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives fongicides pyridinyloxy substitues phenylamidine |
WO2007031527A1 (fr) | 2005-09-13 | 2007-03-22 | Marc Deweerdt | Ensemble de profiles |
WO2007031526A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives de phenylamidine pesticides benzyloxy- et phenetyl-substitues |
WO2007031513A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives de phenylamidine pesticides thiazolyloxy substitues |
WO2007061966A2 (fr) | 2005-11-23 | 2007-05-31 | E. I. Du Pont De Nemours And Company | Composes amidinylphenyle et utilisation de ceux-ci en comme fongicides |
WO2007093227A1 (fr) | 2005-09-13 | 2007-08-23 | Bayer Cropscience Ag | Derives phenylamidine a substitution naphtyloxy a action pesticide |
WO2008101682A2 (fr) | 2007-02-22 | 2008-08-28 | Syngenta Participations Ag | Nouveaux microbiocides |
WO2008110313A1 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Phénoxyphénylamidines utilisées comme fongicides |
WO2008110314A1 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Fluoroalkylphénylamidines et leur utilisation comme fongicides |
WO2008110312A1 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Phénylamidines substituées et utilisation en tant que fongicides |
WO2008110281A2 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Phénoxyphénylamidines 3,4-disubstituées et leur utilisation comme fongicides |
WO2008110315A1 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Aktiengesellschaft | Phénoxyphénylamidines à substitution 4-cycloalkyle ou 4-aryle et leur utilisation en tant que fongicides |
WO2008110279A1 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Dihalogénophénoxyphénylamidines et leur utilisation comme fongicides |
WO2008110280A2 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Phénoxyphénylamidines 3-substituées et leur utilisation comme fongicides |
WO2008128639A1 (fr) | 2007-04-19 | 2008-10-30 | Bayer Cropscience Aktiengesellschaft | Thiadiazolyloxyphénylamidines et leur utilisation comme fongicides |
WO2009140624A2 (fr) | 2008-05-16 | 2009-11-19 | Takeda San Diego, Inc. | Activateurs de la glucokinase |
WO2009156074A2 (fr) | 2008-06-27 | 2009-12-30 | Bayer Cropscience Ag | Thiadiazolyloxyphénylamidines et leur utilisation comme fongicides |
WO2009156098A2 (fr) | 2008-06-27 | 2009-12-30 | Bayer Cropscience Ag | Thiadiazolyloxyphénylamidines et utilisation comme fongicides |
WO2010086118A1 (fr) | 2009-02-02 | 2010-08-05 | Bayer Cropscience Ag | Isothiazolyloxyphénylamidine et son utilisation comme fongicide |
US20110082036A1 (en) * | 2009-10-07 | 2011-04-07 | Philippe Desbordes | Active Compound Combinations Comprising Arylamidines and N-Cycloalkylamides |
WO2012025450A1 (fr) | 2010-08-23 | 2012-03-01 | Isagro Ricerca S.R.L. | Phénylamidines ayant une activité fongicide élevée et leur utilisation |
WO2012090969A1 (fr) | 2010-12-27 | 2012-07-05 | Sumitomo Chemical Company, Limited | Composés amidine et leur utilisation pour lutter contre des maladies de plantes |
WO2012146125A1 (fr) | 2011-04-26 | 2012-11-01 | Syngenta Participations Ag | Compositions fongicides |
WO2013136275A1 (fr) | 2012-03-15 | 2013-09-19 | Isagro S.P.A. | Compositions synergiques à activité fongicide et leur utilisation |
WO2014037314A2 (fr) | 2012-09-07 | 2014-03-13 | Bayer Cropscience Ag | Combinaisons de composés actifs |
WO2014157596A1 (fr) | 2013-03-25 | 2014-10-02 | 住友化学株式会社 | Composé d'amidine et utilisation de celui-ci |
WO2015121231A1 (fr) * | 2014-02-13 | 2015-08-20 | Bayer Cropscience Ag | Combinaisons de composés actifs comprenant des composés de phénylamidine et d'autres fongicides |
EP3011832A1 (fr) * | 2015-06-15 | 2016-04-27 | Bayer CropScience AG | Combinaison fongicide contenant du phenoxyphenylamidine et un l'autre fongicide |
-
2017
- 2017-12-13 WO PCT/EP2017/082607 patent/WO2018109002A1/fr active Application Filing
- 2017-12-14 AR ARP170103500A patent/AR110367A1/es unknown
- 2017-12-14 UY UY0001037521A patent/UY37521A/es unknown
Patent Citations (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4272417A (en) | 1979-05-22 | 1981-06-09 | Cargill, Incorporated | Stable protective seed coating |
US4245432A (en) | 1979-07-25 | 1981-01-20 | Eastman Kodak Company | Seed coatings |
US4808430A (en) | 1987-02-27 | 1989-02-28 | Yazaki Corporation | Method of applying gel coating to plant seeds |
WO1991007874A1 (fr) | 1989-11-30 | 1991-06-13 | Hoechst Aktiengesellschaft | Pyrazoline pour la protection de plantes cultivees contre les herbicides |
US5876739A (en) | 1996-06-13 | 1999-03-02 | Novartis Ag | Insecticidal seed coating |
US20030176428A1 (en) | 1998-11-16 | 2003-09-18 | Schneidersmann Ferdinand Martin | Pesticidal composition for seed treatment |
WO2000046184A1 (fr) | 1999-02-06 | 2000-08-10 | Aventis Cropscience Gmbh | Derive n2-phenylamidine |
WO2002028186A2 (fr) | 2000-10-06 | 2002-04-11 | Monsanto Technology, Llc | Traitement de semences avec des melanges d'insecticides |
WO2002080675A1 (fr) | 2001-03-21 | 2002-10-17 | Monsanto Technology, Llc | Procede permettant de commander la liberation de principes actifs agricoles de semences traitees de plantes |
WO2003024219A1 (fr) | 2001-09-10 | 2003-03-27 | Bayer Cropscience S.A. | Melange fongicide contenant des derives d'arylamidine |
WO2003093224A1 (fr) | 2002-05-03 | 2003-11-13 | E.I. Du Pont De Nemours And Company | Composes amidinylphenyle et utilisations de ceux-ci comme fongicides |
WO2004037239A1 (fr) | 2002-10-24 | 2004-05-06 | Bayer Cropscience S.A. | Medicaments antifongiques contenant des derives d'arylamidine |
WO2005089547A1 (fr) | 2004-03-05 | 2005-09-29 | Bayer Cropscience Sa | Composition fongicide comprenant un derive arylamidine et des composes fongicides connus |
WO2005094582A1 (fr) * | 2004-03-22 | 2005-10-13 | Basf Aktiengesellschaft | Melanges fongicides |
WO2005120234A2 (fr) | 2004-06-03 | 2005-12-22 | E.I. Dupont De Nemours And Company | Melanges fongicides de composes d'amidinylphenyle |
WO2007031513A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives de phenylamidine pesticides thiazolyloxy substitues |
WO2007031512A2 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives de biphenylamidine pesticides |
WO2007031507A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Préparation fongicide comprenant un dérivé d'arylamidine et deux composés fongicides connus |
WO2007031524A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives de phenylamidine pesticides pyrimidinyloxy substitues |
WO2007031523A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives fongicides pyridinyloxy substitues phenylamidine |
WO2007031527A1 (fr) | 2005-09-13 | 2007-03-22 | Marc Deweerdt | Ensemble de profiles |
WO2007031526A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives de phenylamidine pesticides benzyloxy- et phenetyl-substitues |
WO2007031508A1 (fr) | 2005-09-13 | 2007-03-22 | Bayer Cropscience Ag | Derives pesticides phenyloxy substitues phenylamidine |
WO2007093227A1 (fr) | 2005-09-13 | 2007-08-23 | Bayer Cropscience Ag | Derives phenylamidine a substitution naphtyloxy a action pesticide |
WO2007061966A2 (fr) | 2005-11-23 | 2007-05-31 | E. I. Du Pont De Nemours And Company | Composes amidinylphenyle et utilisation de ceux-ci en comme fongicides |
WO2008101682A2 (fr) | 2007-02-22 | 2008-08-28 | Syngenta Participations Ag | Nouveaux microbiocides |
WO2008110315A1 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Aktiengesellschaft | Phénoxyphénylamidines à substitution 4-cycloalkyle ou 4-aryle et leur utilisation en tant que fongicides |
WO2008110314A1 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Fluoroalkylphénylamidines et leur utilisation comme fongicides |
WO2008110312A1 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Phénylamidines substituées et utilisation en tant que fongicides |
WO2008110281A2 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Phénoxyphénylamidines 3,4-disubstituées et leur utilisation comme fongicides |
WO2008110313A1 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Phénoxyphénylamidines utilisées comme fongicides |
WO2008110279A1 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Dihalogénophénoxyphénylamidines et leur utilisation comme fongicides |
WO2008110280A2 (fr) | 2007-03-12 | 2008-09-18 | Bayer Cropscience Ag | Phénoxyphénylamidines 3-substituées et leur utilisation comme fongicides |
WO2008128639A1 (fr) | 2007-04-19 | 2008-10-30 | Bayer Cropscience Aktiengesellschaft | Thiadiazolyloxyphénylamidines et leur utilisation comme fongicides |
WO2009140624A2 (fr) | 2008-05-16 | 2009-11-19 | Takeda San Diego, Inc. | Activateurs de la glucokinase |
WO2009156074A2 (fr) | 2008-06-27 | 2009-12-30 | Bayer Cropscience Ag | Thiadiazolyloxyphénylamidines et leur utilisation comme fongicides |
WO2009156098A2 (fr) | 2008-06-27 | 2009-12-30 | Bayer Cropscience Ag | Thiadiazolyloxyphénylamidines et utilisation comme fongicides |
WO2010086118A1 (fr) | 2009-02-02 | 2010-08-05 | Bayer Cropscience Ag | Isothiazolyloxyphénylamidine et son utilisation comme fongicide |
US20110082036A1 (en) * | 2009-10-07 | 2011-04-07 | Philippe Desbordes | Active Compound Combinations Comprising Arylamidines and N-Cycloalkylamides |
WO2012025450A1 (fr) | 2010-08-23 | 2012-03-01 | Isagro Ricerca S.R.L. | Phénylamidines ayant une activité fongicide élevée et leur utilisation |
WO2012090969A1 (fr) | 2010-12-27 | 2012-07-05 | Sumitomo Chemical Company, Limited | Composés amidine et leur utilisation pour lutter contre des maladies de plantes |
WO2012146125A1 (fr) | 2011-04-26 | 2012-11-01 | Syngenta Participations Ag | Compositions fongicides |
WO2013136275A1 (fr) | 2012-03-15 | 2013-09-19 | Isagro S.P.A. | Compositions synergiques à activité fongicide et leur utilisation |
WO2014037314A2 (fr) | 2012-09-07 | 2014-03-13 | Bayer Cropscience Ag | Combinaisons de composés actifs |
WO2014157596A1 (fr) | 2013-03-25 | 2014-10-02 | 住友化学株式会社 | Composé d'amidine et utilisation de celui-ci |
WO2015121231A1 (fr) * | 2014-02-13 | 2015-08-20 | Bayer Cropscience Ag | Combinaisons de composés actifs comprenant des composés de phénylamidine et d'autres fongicides |
EP3011832A1 (fr) * | 2015-06-15 | 2016-04-27 | Bayer CropScience AG | Combinaison fongicide contenant du phenoxyphenylamidine et un l'autre fongicide |
Non-Patent Citations (3)
Title |
---|
"Isoboles, a graphic representation of synergism in pesticides", NETH. J. PLANT PATH., vol. 70, 1964, pages 73 - 80 |
R. WEGLER: "Chemie der Pflanzenschutz- und Schadlingsbekampfungsmittel'' [Chemistry of the Crop Protection Compositions and Pesticides", vol. 2, 1970, SPRINGER VERLAG, pages: 401 - 412 |
SCHLEMMER, HANS-PETER ET A: "Citation of NMR Peaklist Data within Patent Applications", RESEARCH DISCLOSURE, vol. 564, no. 025, April 2011 (2011-04-01) |
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EP3616516A1 (fr) * | 2018-08-31 | 2020-03-04 | Sumitomo Chemical Company, Limited | Composition de lutte de maladies végétales et procédé de lutte de maladies végétales |
US11634389B2 (en) | 2018-11-28 | 2023-04-25 | The Regents Of The University Of Michigan | Succinate dehydrogenase inhibitors and methods of making and using the same |
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