WO2018073910A1 - Cosmetic and cosmetic spraying device - Google Patents

Cosmetic and cosmetic spraying device Download PDF

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Publication number
WO2018073910A1
WO2018073910A1 PCT/JP2016/080936 JP2016080936W WO2018073910A1 WO 2018073910 A1 WO2018073910 A1 WO 2018073910A1 JP 2016080936 W JP2016080936 W JP 2016080936W WO 2018073910 A1 WO2018073910 A1 WO 2018073910A1
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Prior art keywords
cosmetic
hydrogen
container
oxide
mass
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PCT/JP2016/080936
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French (fr)
Japanese (ja)
Inventor
あい子 阿部
山田　晃久
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株式会社プライマリーステップ
株式会社ミヤコケミカル
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Priority to PCT/JP2016/080936 priority Critical patent/WO2018073910A1/en
Publication of WO2018073910A1 publication Critical patent/WO2018073910A1/en

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods

Definitions

  • the present invention relates to a cosmetic used by generating hydrogen and a cosmetic spraying device for effectively using the cosmetic.
  • reducing water containing reducing components such as hydrogen in water is used for beauty and the like.
  • Patent Document 1 an apparatus for producing hydrogen water configured to dissolve hydrogen generated by electrolyzing water in the water
  • Patent Document 4 an apparatus for producing hydrogen water configured to dissolve hydrogen generated by electrolyzing water in the water
  • Such hydrogen water is used by drinking or spraying it on the face, hair, body, etc. in the form of a mist.
  • water is used, but water in which ascorbic acid is dissolved has also been used (Patent Document 3).
  • the conventional manufacturing apparatus since the conventional manufacturing apparatus is configured to use hydrogen water obtained by electrolysis of water, it basically uses water and is referred to as a dedicated cosmetic. There was nothing. In other words, water can be obtained simply by electrolysis, so that hydrogen water consisting of reducing components can be obtained easily and at a low cost. Therefore, every time it is used, the water remaining in the device is discarded and new water is used when it is used again. It can be used by being put in, but when it comes to cosmetics, the cost increases if the remaining cosmetics are discarded every time it undergoes electrolysis. However, if the used cosmetic is left in the apparatus and electrolysis is performed every time it is used, the cosmetic may be deteriorated and deteriorated, and in some cases, bad odor may be generated or discolored. Will result.
  • the present invention has been made in view of such circumstances, and a cosmetic that does not deteriorate even if electrolyzed every time it is used and does not cause discoloration or foul odor, and to effectively use this cosmetic. It is an object to provide a cosmetic spraying device.
  • a cosmetic according to the present invention for solving the above problems is a cosmetic applied to the skin together with hydrogen generated by electrolysis of a cosmetic in a container and applied to the cosmetic.
  • a cosmetic applied to the skin together with hydrogen generated by electrolysis of a cosmetic in a container and applied to the cosmetic Is a mixture containing 5 to 90% by mass of a liquid obtained by steam distillation of a plant.
  • the plants are rose, jasmine, daidai, chamomile, and ylang ylang flowers and their buds, sage, eucalyptus, tea tree and salvia leaves, citrus mandarin, daidai, orange, lemon, lime, and bergamot.
  • the cosmetic may further contain 0.01 to 30 ppm of metal oxide.
  • the metal oxide may be one or more selected from titanium oxide, zinc oxide, iron oxide, barium sulfate, silver oxide, aluminum oxide, and calcium oxide.
  • the above cosmetic may further contain 0.001 to 20% by mass of one or more selected from ascorbic acid, ascorbate, and ascorbic acid derivatives.
  • the cosmetic may further contain 0.0001 to 10% by mass of one or more amino acids.
  • a cosmetic spraying device for solving the above-mentioned problems is a device for filling and spraying the cosmetic according to any one of claims 1 to 6, wherein the device is provided on a power supply unit.
  • the cosmetic according to any one of claims 1 to 6 is provided in the container main body, and the cosmetic in the container main body is electrolyzed at the bottom of the container main body by power supply from a power supply unit.
  • An electrode plate for generating hydrogen is provided, and the container body is provided with a spray pump capable of spraying cosmetics in the container body by pressing, and the suction provided in the container body from the spray pump
  • the nozzle is provided at a position where hydrogen that is generated by the electrode plate and floats inside the container body passes, so that cosmetics containing hydrogen after hydrogen generation can be sprayed.
  • the cosmetic in the container is electrolyzed to generate hydrogen, and with the generated hydrogen, the cosmetic can be repeatedly applied to the skin, It is possible to prevent the cosmetic material from being deteriorated and causing discoloration and odor.
  • FIG. 1 It is the schematic of the whole structure of the cosmetics spraying apparatus which concerns on this invention. It is a longitudinal cross-sectional view of the cosmetic spraying apparatus shown in FIG. It is a disassembled perspective view of the electrode plate part in the cosmetic spraying apparatus which concerns on this invention.
  • FIG. 1 and 2 show an outline of the overall configuration of a cosmetic spraying apparatus 1 for spraying a cosmetic 10 according to the present invention
  • FIG. 3 is an exploded perspective view of a portion of an electrode plate 21 in the cosmetic spraying apparatus 1. Show.
  • the cosmetic spraying device 1 is configured to be able to fill the cosmetic 10 and spray the cosmetic 10, and the cosmetic spraying device 1 is a container provided on the power supply unit 2.
  • a cosmetic 10 is provided in the main body 3 and is configured to generate hydrogen by electrolysis from an electrode plate 21 provided at the bottom of the container main body 3.
  • the cosmetic 10 will be described.
  • the cosmetic is blended with a liquid obtained by steam distillation of the plant so that it does not deteriorate even when hydrogen is repeatedly generated by the cosmetic spraying device 1.
  • the plants include roses, jasmine, daidai, chamomile, and ylang ylang flowers and their buds, sage, eucalyptus, tea tree, and salvia leaves, mandarin orange, daidai, orange, lemon, lime, and bergamot peels, sandals
  • One or more selected from wood, pine, cypress, and cinnamon bark, lavender, lemongrass, basil, rosemary, and whole mint can be used.
  • it can be used without particular limitation as long as it is various plants used as raw materials such as skin lotions and perfumes.
  • various kinds of plants such as flowers, trees, grasses, roots and fruits can be used for this plant.
  • a distillate of an aqueous component obtained by steam distillation is used for this plant.
  • the amount of the distillate obtained by this steam distillation is 5 to 90% by mass of the entire cosmetic.
  • the amount of the distillate used is less than 5% by mass of the entire cosmetic, a sufficient effect cannot be obtained, and the odor of the distillate is weak, so that the base odor of other active ingredients is worrisome. A feeling cannot be obtained.
  • the amount of the distillate used exceeds 90% by mass of the entire cosmetic, the effect is saturated and wasted, and the scent of the distillate itself is so strong that some users feel uncomfortable. End up.
  • Specific examples of the distillate include centifolia rose flower water (INCI name: RosaICentifolia Flower Water, CAS No.
  • lavender flower water obtained by steam distillation of lavender flowers ( INCI name: Lavandula Angustifolia (Lavender) Flower Water, CAS No. 90063-37-9), Sage leaf water obtained by steam distillation of Salvia leaves (INCI name: Salvia Officinalis (Sage) Leaf Water, CAS No.84082-79) -1), chamomile water obtained by steam distillation of chamomile flowers (INCI name: ChamillaomRecutita (Matricaria) Flower Water, CAS No.84082-60-0).
  • the cosmetic 10 containing the distilled liquid may generate hydrogen by electrolysis each time the cosmetic 10 is used, and the cosmetic 10 may be used even if it is repeatedly used part of the cosmetic 10. It can be used to the end without deteriorating and causing discoloration or odor.
  • the cosmetic 10 may contain a metal oxide in addition to the above-described distillate.
  • a metal oxide one or more selected from titanium oxide, zinc oxide, iron oxide, barium sulfate, silver oxide, aluminum oxide, and calcium oxide can be used. In addition, it can be used without particular limitation as long as it has an antiseptic action and does not adversely affect the human body.
  • the amount of the metal oxide used is 0.01 ppm to 30 ppm of the entire cosmetic 10. When the amount of the metal oxide used is less than 0.01 ppm, a sufficient effect cannot be obtained. When the amount exceeds 30 ppm, the effect is saturated and the metal oxide is precipitated and wasted.
  • the cosmetic 10 may contain one or more selected from among ascorbic acid, ascorbate, and ascorbic acid derivatives.
  • ascorbic acid Ascorbate, and ascorbic acid derivatives.
  • the amount of these acids used is 0.001 to 20% by mass of the total amount of the cosmetic 10. When the amount is less than 0.001% by mass, a sufficient effect cannot be obtained. When the amount exceeds 20% by mass, the effect is saturated and is wasted.
  • this cosmetic 10 contains 0.0001 to 10% by mass of one or more amino acids based on the total cosmetic for the purpose of increasing the amount of hydrogen generated in the same manner as the acid described above. Also good.
  • the type of amino acid is not particularly limited, and various amino acids can be used alone or in combination of two or more. In particular, components necessary for the recovery and synthesis of skin and hair, and amino acids serving as precursors thereof are effective because the cosmetic effect is enhanced.
  • the cosmetic spraying device 1 is provided with the cosmetic 10 in the container main body 3 provided on the power supply unit 2, and is electrolyzed from the electrode plate 21 provided at the bottom of the container main body 3. To generate hydrogen.
  • the power supply unit 2 is configured to constitute a lower half portion of the cosmetic spraying device 1, and a battery 20 is provided therein.
  • the power supply unit 2 is energized from the battery 20 by pressing a switch 22 at the bottom for a predetermined time, for example, 10 to 30 seconds, and energizes the electrode plate 21 exposed at the bottom in the container body 3.
  • the energized battery 20 is configured to be replaced with various dry batteries including a button battery when the battery 20 is exhausted, or configured to be rechargeable when the battery 20 is exhausted with a built-in battery. It may be a thing.
  • the container body 3 is configured on the power supply unit 2 and has a capacity space in which the cosmetic 10 can be filled.
  • the electrode plate 21 of the power supply unit 2 described above is provided at the bottom of the container body 3. As shown in FIG. 3, the electrode plate 21 forms a plurality of slit-shaped gaps in the disc so that the electrode plate 21 is in sufficient contact with the cosmetic 10 and allows the generated hydrogen to pass upward.
  • the cathode 21a and the anode 21b configured as described above are provided, and a separator 21c is provided between the cathode 21a and the anode 21b.
  • the cathode 21a is fixed by an adapter 21d on the separator 21c and provided in a space on the container body 3 side, and the anode 21b is provided in a space formed by the separator 21c and the anode space forming spacer 21e below the separator 21c. It is done.
  • the electrode plate 21 When the electrode plate 21 is energized from the power supply unit 2, hydrogen is generated at the cathode 21a, and the cosmetic 10 containing a large amount of reducing components is generated. In addition, oxygen is generated at the anode 21b and the oxidized cosmetic 10 is generated.
  • the cosmetic 10 containing a large amount of hydrogen and reducing components by energization. Will be actively generated.
  • a screw portion 31 is provided on the upper portion of the container body 3, and a manual acupressure spray pump 32 adapted to be screwed into and removed from the screw portion 31 can be provided.
  • the nozzle portion 32a extending into the container body 3 has a portion serving as a suction port for the cosmetic 10 at the tip thereof directly above the cathode 21a where hydrogen is generated (for example, 2 mm). It is provided so as to be spaced apart.
  • the cosmetic 10 containing a large amount of hydrogen and reducing components generated at the cathode 21a is sprayed after being sucked from the nozzle portion 32a by the pumping action of the spray pump 32, and applied to a desired part of the human body.
  • the cosmetic 10 containing a large amount of hydrogen and reducing components applied in this way has a cosmetic effect enhanced by the cosmetic components of the distillate obtained by steam-distilling plants in addition to hydrogen and reducing components. Become. In particular, hydrogen and reducing components are generated each time they are used, so that they can be used in a high concentration state. In addition to the cosmetic effect, the cosmetic component is also effective because it does not cause discoloration or malodor due to deterioration even when hydrogen is generated each time the cosmetic liquid is used.
  • the container body 3 is housed in the cover case 11 so as to be integrated with the power supply unit 2 so that the pressing portion 32b of the spray pump 32 is exposed.
  • the pressing portion 32 b is provided with a lid 12 that is integrated with the cover case 11.
  • the cosmetic spraying apparatus 1 configured in this way is configured to generate hydrogen by pressing the switch 22 every time it is used, so that the power supply unit 2 breaks down or the battery 20 runs out to generate hydrogen. If this does not occur, sufficient effects cannot be achieved. Therefore, the container main body 3 is formed transparent so that the generation state of hydrogen can be confirmed, and the internal hydrogen is introduced from the window portion 11a of the cover case 11 that integrally covers the power supply unit 2 and the container main body 3.
  • the degree of occurrence can be visually recognized by the amount of foam. However, it is not limited to what was comprised so that it might be visually recognized from such a window part 11a, but it is comprised so that the electric power feeding unit 2 and the container main body 3 may be integrated, and the whole part of the container main body 3 is transparent. You may be comprised so that it can visually recognize.
  • Example 1-Example 22 Cosmetics having respective compositions shown in Table 1 were prepared.
  • centifolia rose flower water (INCI name: Rosa Centifolia Flower Water, CAS No. 84604-12-6) was used.
  • the color tone was evaluated by 26 panelists in a four-step evaluation of “0” without change, “1” slightly colored, “2” light brown, and “3” changed to brown, and the average value was taken. A value less than “1” was considered acceptable.
  • Odors were evaluated by 26 panelists based on a four-step evaluation: “0”, no odor change, “1” with slightly different odors, “2” with slightly odors, and “3” with odors. I took the value. A value less than “1” was considered acceptable.
  • the amount of hydrogen generated is “0” where almost no hydrogen bubbles are observed, “1” where hydrogen bubbles are generated, “2” where many hydrogen bubbles are generated, and very many hydrogen bubbles are generated. Twenty-six panelists were evaluated in four stages of “3”, and the average value was taken. “1” or higher was accepted. The results are shown in Table 2.
  • centifolia rose flower water is 95 mass%, silver oxide 0.00001 mass%, sodium ascorbate 0.1 mass%, alanine 0.0001 mass%, remainder
  • it was difficult to use as a cosmetic because the odor of the liquid obtained by steam distillation of rose flowers was too strong.
  • centifolia rose flower water used was 2% by mass, 0.00001% by mass of silver oxide, 0.1% by mass of sodium ascorbate, 0.0001% by mass of alanine, and the balance being water,
  • the fragrance of the rose derived from the centifolia rose flower water was weak, and the base odor of other components other than the odor of the rose was not obtained, and the satisfaction as a cosmetic was not obtained.
  • Example 1-22 the centifolia rose flower water (INCI name: RosaRCentifolia Flower Water, CAS No. 84604-12-6) used as a liquid obtained by steam distillation of rose flowers was used as a lavender.
  • a similar experiment was carried out by changing to lavender flower water (INCI name: Lavandula Angustifolia (Lavender) Flower Water, CAS No. 90063-37-9), which is a liquid obtained by steam distillation of flowers.
  • Successful results were obtained for all of the following items: color tone, odor, and amount of hydrogen generated.
  • centifolia rose flower water (INCI name: Rosa : Centifolia Flower Water, CAS No. 84604-12-) used as a liquid obtained by steam distillation of rose flowers. 6) was changed to sage water (INCI name: Salvia Officinalis (Sage) Leaf Water, CAS No.84082-79-1), which is a liquid obtained by steam distillation of sage leaves, and the same experiment was conducted. However, the passing results were obtained in all items of color tone, odor, and hydrogen generation amount after hydrogen generation.

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Abstract

Provided is a cosmetic that does not deteriorate, thereby leading to discoloration or malodors, even if electrolyzed during each use, and a cosmetic spraying device for effective use of said cosmetic. A cosmetic inside a container is electrolyzed, this cosmetic is applied to the skin together with hydrogen generated by the electrolysis, and the cosmetic contains 5 to 90 mass% of a liquid obtained by steam distilling a plant. The plant is at least one plant selected from rose, jasmine, bitter orange, chamomile, and ylang-ylang flowers or buds thereof; sage, eucalyptus, tea tree, and salvia leaves; satsuma orange, bitter orange, orange, lemon, lime, and bergamot peel; sandalwood, pine, cypress, and cinnamon bark; and entire plants of lavender, lemon grass, basil, rosemary, and mint.

Description

化粧料および化粧料噴霧装置Cosmetics and cosmetic spraying equipment
　本発明は、水素を発生させて使用する化粧料と、この化粧料を有効に使用するための化粧料噴霧装置とに関するものである。 The present invention relates to a cosmetic used by generating hydrogen and a cosmetic spraying device for effectively using the cosmetic.
　一般に、水素などの還元成分を水に含有させた還元水を、美容等に利用することが行われている。 Generally, reducing water containing reducing components such as hydrogen in water is used for beauty and the like.
　従来より、このような還元水を製造するための装置としては、水を電気分解することによって生じる水素を、当該水中に溶存させるように構成された水素水の製造装置が知られている（例えば、特許文献１ないし特許文献４参照）。このような水素水は、飲用したり、ミスト状にして顔、髪、身体などに噴霧することによって使用される。基本的には、水を使用するようになされているが、アスコルビン酸が溶解された水を使用することも行われていた（特許文献３）。 Conventionally, as an apparatus for producing such reduced water, there is known an apparatus for producing hydrogen water configured to dissolve hydrogen generated by electrolyzing water in the water (for example, Patent Document 1 to Patent Document 4). Such hydrogen water is used by drinking or spraying it on the face, hair, body, etc. in the form of a mist. Basically, water is used, but water in which ascorbic acid is dissolved has also been used (Patent Document 3).
特開２０１４－２２６５７５号公報JP 2014-226575 A 特開２０１２－２１７８６８号公報JP 2012-217868 A 特開２０１０－８２２１２号公報JP 2010-82212 A 特開２０１０－５６０６号公報JP 2010-5606 A
　上記したように、従来の製造装置は、水の電気分解によって得られる水素水を使用するように構成されているため、基本的には水を利用するものであって、それ専用の化粧料というものが無かった。すなわち、水は、電気分解するだけで、簡単に還元成分からなる水素水が得られ、しかも安価なため、使用する毎に装置に残った水を捨てて、再度使用する際に新たな水を入れて使用することができるが、化粧料となると、電気分解する毎に残った化粧料を捨ててしまうとなるとコストが嵩むこととなる。しかし、装置内に使用後の化粧料を残しておき、使用する毎に電気分解を行うとなると、化粧料が変質して劣化し、場合によっては悪臭が発生したり、変色したりするといった不都合を生じることとなる。 As described above, since the conventional manufacturing apparatus is configured to use hydrogen water obtained by electrolysis of water, it basically uses water and is referred to as a dedicated cosmetic. There was nothing. In other words, water can be obtained simply by electrolysis, so that hydrogen water consisting of reducing components can be obtained easily and at a low cost. Therefore, every time it is used, the water remaining in the device is discarded and new water is used when it is used again. It can be used by being put in, but when it comes to cosmetics, the cost increases if the remaining cosmetics are discarded every time it undergoes electrolysis. However, if the used cosmetic is left in the apparatus and electrolysis is performed every time it is used, the cosmetic may be deteriorated and deteriorated, and in some cases, bad odor may be generated or discolored. Will result.
　本発明は、係る実情に鑑みてなされたものであって、使用する毎に電気分解しても劣化して変色や悪臭が発生することの無い化粧料と、この化粧料を有効に使用するための化粧料噴霧装置とを提供することを目的としている。 The present invention has been made in view of such circumstances, and a cosmetic that does not deteriorate even if electrolyzed every time it is used and does not cause discoloration or foul odor, and to effectively use this cosmetic. It is an object to provide a cosmetic spraying device.
　上記課題を解決するための本発明に係る化粧料は、容器中の化粧料を電気分解し、この電気分解によって発生させた水素とともに、皮膚に塗布される化粧料であって、当該化粧料には、植物を水蒸気蒸留して得られた液が５～９０質量％配合されているものである。 A cosmetic according to the present invention for solving the above problems is a cosmetic applied to the skin together with hydrogen generated by electrolysis of a cosmetic in a container and applied to the cosmetic. Is a mixture containing 5 to 90% by mass of a liquid obtained by steam distillation of a plant.
　上記化粧料において、植物は、バラ、ジャスミン、ダイダイ、カモミール、およびイランイランの花およびその蕾、セージ、ユーカリ、ティートリーおよびサルビアの葉、温州ミカン、ダイダイ、オレンジ、レモン、ライム、およびベルガモットの果皮、サンダルウッド、マツ、ヒノキ、およびシナモンの樹皮、ラベンダー、レモングラス、バジル、ローズマリー、およびミントの全草、の中から選択される１種または２種以上であってもよい。 In the above cosmetics, the plants are rose, jasmine, daidai, chamomile, and ylang ylang flowers and their buds, sage, eucalyptus, tea tree and salvia leaves, citrus mandarin, daidai, orange, lemon, lime, and bergamot. One or more selected from among, bark of sandalwood, pine, cypress, and cinnamon, lavender, lemongrass, basil, rosemary, and whole mint.
　上記化粧料には、さらに、金属酸化物が０．０１ｐｐｍ～３０ｐｐｍ配合されているものであってもよい。 The cosmetic may further contain 0.01 to 30 ppm of metal oxide.
　上記金属酸化物は、酸化チタン、酸化亜鉛、酸化鉄、硫酸バリウム、酸化銀、酸化アルミニウム、酸化カルシウムから選択される１種または２種以上であってもよい。 The metal oxide may be one or more selected from titanium oxide, zinc oxide, iron oxide, barium sulfate, silver oxide, aluminum oxide, and calcium oxide.
　上記化粧料には、さらに、アスコルビン酸、アスコルビン酸塩、アスコルビン酸誘導体の中から選択される１種または２種以上が、０．００１～２０質量％配合されているものであってもよい。 The above cosmetic may further contain 0.001 to 20% by mass of one or more selected from ascorbic acid, ascorbate, and ascorbic acid derivatives.
　上記化粧料には、さらに、１種または２種以上のアミノ酸が、０．０００１～１０質量％配合されているものであってもよい。 The cosmetic may further contain 0.0001 to 10% by mass of one or more amino acids.
　上記課題を解決するための本発明の化粧料噴霧装置は、請求項１ないし６の何れか一に記載の化粧料を充填し、噴霧する装置であって、前記装置は、給電ユニット上に設けられた容器本体内に、請求項１ないし６の何れか一に記載の化粧料が設けられ、前記容器本体の底部に、給電ユニットからの給電によって、容器本体内の化粧料を電気分解して水素を発生させるための電極板が設けられ、容器本体には、押圧することによって当該容器本体内の化粧料を噴霧可能なスプレーポンプが設けられ、当該スプレーポンプから容器本体内に設けられた吸入ノズルは、電極板で発生して容器本体内を浮上する水素が通過する位置に設けられ、水素発生後の水素を含んだ化粧料を噴霧できるようになされたものである。 A cosmetic spraying device according to the present invention for solving the above-mentioned problems is a device for filling and spraying the cosmetic according to any one of claims 1 to 6, wherein the device is provided on a power supply unit. The cosmetic according to any one of claims 1 to 6 is provided in the container main body, and the cosmetic in the container main body is electrolyzed at the bottom of the container main body by power supply from a power supply unit. An electrode plate for generating hydrogen is provided, and the container body is provided with a spray pump capable of spraying cosmetics in the container body by pressing, and the suction provided in the container body from the spray pump The nozzle is provided at a position where hydrogen that is generated by the electrode plate and floats inside the container body passes, so that cosmetics containing hydrogen after hydrogen generation can be sprayed.
　本発明によると、化粧料を使用する毎に、容器内の化粧料を電気分解して水素を発生させ、この発生させた水素とともに、当該化粧料を皮膚に塗布することを繰り返し行っても、化粧料が劣化して変色や悪臭を発生することを防止できる。 According to the present invention, every time the cosmetic is used, the cosmetic in the container is electrolyzed to generate hydrogen, and with the generated hydrogen, the cosmetic can be repeatedly applied to the skin, It is possible to prevent the cosmetic material from being deteriorated and causing discoloration and odor.
本発明に係る化粧料噴霧装置の全体構成の概略図である。It is the schematic of the whole structure of the cosmetics spraying apparatus which concerns on this invention. 図１に示す化粧料噴霧装置の縦断面図である。It is a longitudinal cross-sectional view of the cosmetic spraying apparatus shown in FIG. 本発明に係る化粧料噴霧装置における電極板部分の分解斜視図である。It is a disassembled perspective view of the electrode plate part in the cosmetic spraying apparatus which concerns on this invention.
　以下、本発明の実施の形態について図面を参照して説明する。 Hereinafter, embodiments of the present invention will be described with reference to the drawings.
　図１および図２は本発明に係る化粧料１０を噴霧するための化粧料噴霧装置１の全体構成の概略を示し、図３は同化粧料噴霧装置１における電極板２１部分の分解斜視図を示している。 1 and 2 show an outline of the overall configuration of a cosmetic spraying apparatus 1 for spraying a cosmetic 10 according to the present invention, and FIG. 3 is an exploded perspective view of a portion of an electrode plate 21 in the cosmetic spraying apparatus 1. Show.
　この化粧料噴霧装置１は、化粧料１０を充填して当該化粧料１０を噴霧することができるように構成されており、前記化粧料噴霧装置１は、給電ユニット２の上に設けられた容器本体３内に、化粧料１０が設けられ、容器本体３の底部に設けられた電極板２１から、電気分解による水素を発生するように構成されている。 The cosmetic spraying device 1 is configured to be able to fill the cosmetic 10 and spray the cosmetic 10, and the cosmetic spraying device 1 is a container provided on the power supply unit 2. A cosmetic 10 is provided in the main body 3 and is configured to generate hydrogen by electrolysis from an electrode plate 21 provided at the bottom of the container main body 3.
　まず、化粧料１０について説明する。
　化粧料は、化粧料噴霧装置１によって水素を反復して発生させても劣化しないように、植物を水蒸気蒸留して得られた液が配合されている。 First, the cosmetic 10 will be described.
The cosmetic is blended with a liquid obtained by steam distillation of the plant so that it does not deteriorate even when hydrogen is repeatedly generated by the cosmetic spraying device 1.
　上記植物としては、バラ、ジャスミン、ダイダイ、カモミール、およびイランイランの花およびその蕾、セージ、ユーカリ、ティートリー、およびサルビアの葉、温州ミカン、ダイダイ、オレンジ、レモン、ライム、およびベルガモットの果皮、サンダルウッド、マツ、ヒノキ、およびシナモンの樹皮、ラベンダー、レモングラス、バジル、ローズマリー、およびミントの全草、の中から選択される１種または２種以上のものを使用することができる。また、それ以外にも、化粧水や香水などの原料として使用されている各種植物であれば、特に限定されることなく使用することができる。この植物は、上記したように、花、木、草、根、果実などの各種のものを使用することができる。また、この植物は、水蒸気蒸留によって得られた水性成分の蒸留液が使用される。この水蒸気蒸留によって得られた蒸留液の使用量としては、化粧料全体の５～９０質量％とされる。この蒸留液の使用量が化粧料全体の５質量％未満の場合は、十分な効果が得られず、かつ、蒸留液の香りが弱いので他の有効成分のベース臭が気になって心地よい使用感が得られなくなる。また、この蒸留液の使用量が化粧料全体の９０質量％を超えると、効果が飽和して無駄になってしまうとともに、蒸留液自体の香りが強すぎて使用者によっては不快感を感じてしまう。この蒸留液の具体的なものとしては、例えば、センチフォリアバラ花水（ＩＮＣＩ名：Rosa Centifolia Flower Water、ＣＡＳNo.84604-12-6）、ラベンダーの花を水蒸気蒸留して得られるラベンダー花水（ＩＮＣＩ名：Lavandula Angustifolia (Lavender) Flower Water、ＣＡＳNo.90063-37-9）、サルビアの葉を水蒸気蒸留して得られるセージ葉水（ＩＮＣＩ名：Salvia Officinalis (Sage) Leaf Water、ＣＡＳNo.84082-79-1）、カモミールの花を水蒸気蒸留して得られるカミツレ水（ＩＮＣＩ名：Chamomilla Recutita (Matricaria) Flower Water、ＣＡＳNo.84082-60-0）などが挙げられる。 The plants include roses, jasmine, daidai, chamomile, and ylang ylang flowers and their buds, sage, eucalyptus, tea tree, and salvia leaves, mandarin orange, daidai, orange, lemon, lime, and bergamot peels, sandals One or more selected from wood, pine, cypress, and cinnamon bark, lavender, lemongrass, basil, rosemary, and whole mint can be used. In addition, it can be used without particular limitation as long as it is various plants used as raw materials such as skin lotions and perfumes. As described above, various kinds of plants such as flowers, trees, grasses, roots and fruits can be used for this plant. In addition, a distillate of an aqueous component obtained by steam distillation is used for this plant. The amount of the distillate obtained by this steam distillation is 5 to 90% by mass of the entire cosmetic. When the amount of the distillate used is less than 5% by mass of the entire cosmetic, a sufficient effect cannot be obtained, and the odor of the distillate is weak, so that the base odor of other active ingredients is worrisome. A feeling cannot be obtained. In addition, when the amount of the distillate used exceeds 90% by mass of the entire cosmetic, the effect is saturated and wasted, and the scent of the distillate itself is so strong that some users feel uncomfortable. End up. Specific examples of the distillate include centifolia rose flower water (INCI name: RosaＩCentifolia Flower Water, CAS No. 84604-12-6), lavender flower water obtained by steam distillation of lavender flowers ( INCI name: Lavandula Angustifolia (Lavender) Flower Water, CAS No. 90063-37-9), Sage leaf water obtained by steam distillation of Salvia leaves (INCI name: Salvia Officinalis (Sage) Leaf Water, CAS No.84082-79) -1), chamomile water obtained by steam distillation of chamomile flowers (INCI name: ChamillaomRecutita (Matricaria) Flower Water, CAS No.84082-60-0).
　この蒸留液を入れた化粧料１０は、当該化粧料１０を使用する毎に、電気分解による水素を発生させて、当該化粧料１０の一部を使用することを繰り返しても、化粧料１０が劣化して変色や悪臭を発生することが無く、最後まで使用することができる。 The cosmetic 10 containing the distilled liquid may generate hydrogen by electrolysis each time the cosmetic 10 is used, and the cosmetic 10 may be used even if it is repeatedly used part of the cosmetic 10. It can be used to the end without deteriorating and causing discoloration or odor.
　なお、この化粧料１０には、上記した蒸留液以外に、金属酸化物が配合されていてもよい。この金属酸化物としては、酸化チタン、酸化亜鉛、酸化鉄、硫酸バリウム、酸化銀、酸化アルミニウム、酸化カルシウムから選択される１種または２種以上を使用することができる。また、それ以外にも、防腐作用を持ち、かつ、人体に悪影響を与えないものであれば、特に限定されることなく使用することができる。この金属酸化物の使用量としては、化粧料１０の全体の０．０１ｐｐｍ～３０ｐｐｍとされる。この金属酸化物の使用量が０．０１ｐｐｍ未満の場合は、十分な効果が得られず、３０ｐｐｍを超えると、効果が飽和するとともに、当該金属酸化物が沈殿して無駄になってしまう。 The cosmetic 10 may contain a metal oxide in addition to the above-described distillate. As the metal oxide, one or more selected from titanium oxide, zinc oxide, iron oxide, barium sulfate, silver oxide, aluminum oxide, and calcium oxide can be used. In addition, it can be used without particular limitation as long as it has an antiseptic action and does not adversely affect the human body. The amount of the metal oxide used is 0.01 ppm to 30 ppm of the entire cosmetic 10. When the amount of the metal oxide used is less than 0.01 ppm, a sufficient effect cannot be obtained. When the amount exceeds 30 ppm, the effect is saturated and the metal oxide is precipitated and wasted.
　また、この化粧料１０には、アスコルビン酸、アスコルビン酸塩、アスコルビン酸誘導体の中から選択される１種または２種以上が配合されていてもよい。これらの酸を使用することで、化粧料１０を電気分解して水素を発生させる際、水素の発生量を増やすことができるとともに、肌の美容成分として効果的となる。これらの酸の使用量としては、化粧料１０の全体の０．００１～２０質量％とされる。０．００１質量％未満の場合は、十分な効果が得られず、２０質量％を超えると、効果が飽和して無駄になってしまう。 In addition, the cosmetic 10 may contain one or more selected from among ascorbic acid, ascorbate, and ascorbic acid derivatives. By using these acids, when the cosmetic 10 is electrolyzed to generate hydrogen, the amount of hydrogen generated can be increased, and it is effective as a skin beauty component. The amount of these acids used is 0.001 to 20% by mass of the total amount of the cosmetic 10. When the amount is less than 0.001% by mass, a sufficient effect cannot be obtained. When the amount exceeds 20% by mass, the effect is saturated and is wasted.
　また、この化粧料１０には、上記した酸同様に水素の発生量を増やすことを目的として、１種または２種以上のアミノ酸が、化粧料全体の０．０００１～１０質量％配合されていてもよい。このアミノ酸の種類としては、特に限定されることなく、各種のアミノ酸を１種または２種以上組み合わせて使用することができる。特に、皮膚や髪の回復や合成に必要な成分、その前駆体となるアミノ酸は、美容効果が増進することとなり有効である。 Further, this cosmetic 10 contains 0.0001 to 10% by mass of one or more amino acids based on the total cosmetic for the purpose of increasing the amount of hydrogen generated in the same manner as the acid described above. Also good. The type of amino acid is not particularly limited, and various amino acids can be used alone or in combination of two or more. In particular, components necessary for the recovery and synthesis of skin and hair, and amino acids serving as precursors thereof are effective because the cosmetic effect is enhanced.
　このようにして構成される化粧料１０は、上記した原料の他に、必要に応じて着色料、香料、保存料、その他、一般的に化粧料１０に添加される原料を添加することができる。ただし、それらの原料は、電気分解による水素の発生を阻害するものであってはならない。 In the cosmetic 10 thus configured, in addition to the above-described raw materials, coloring materials, fragrances, preservatives, and other raw materials that are generally added to the cosmetics 10 can be added as necessary. . However, these raw materials should not inhibit the generation of hydrogen by electrolysis.
　次に、この化粧料１０を噴霧するための化粧料噴霧装置１の構成について説明する。 Next, the configuration of the cosmetic spraying device 1 for spraying the cosmetic 10 will be described.
　化粧料噴霧装置１は、上記したように、給電ユニット２の上に設けられた容器本体３内に、化粧料１０が設けられ、容器本体３の底部に設けられた電極板２１から、電気分解による水素を発生するように構成されている。 As described above, the cosmetic spraying device 1 is provided with the cosmetic 10 in the container main body 3 provided on the power supply unit 2, and is electrolyzed from the electrode plate 21 provided at the bottom of the container main body 3. To generate hydrogen.
　給電ユニット２は、化粧料噴霧装置１の下半分の部分を構成するようになされており、内部にバッテリー２０が設けられている。この給電ユニット２は、底部にあるスイッチ２２を押すことで、所定時間、例えば１０～３０秒間に渡ってバッテリー２０からの通電が行われ、容器本体３内の底部に露出した電極板２１に通電可能となされている。この通電を行うバッテリー２０としては、ボタン電池を含む各種乾電池でバッテリー２０が切れた場合に交換するように構成されたものや、内蔵電池でバッテリー２０が切れた場合に充電できるように構成されたものであってもよい。 The power supply unit 2 is configured to constitute a lower half portion of the cosmetic spraying device 1, and a battery 20 is provided therein. The power supply unit 2 is energized from the battery 20 by pressing a switch 22 at the bottom for a predetermined time, for example, 10 to 30 seconds, and energizes the electrode plate 21 exposed at the bottom in the container body 3. Made possible. The energized battery 20 is configured to be replaced with various dry batteries including a button battery when the battery 20 is exhausted, or configured to be rechargeable when the battery 20 is exhausted with a built-in battery. It may be a thing.
　容器本体３は、上記給電ユニット２の上に構成され、その内部に化粧料１０を充填することができる容量の空間が形成されている。この容器本体３の底部には、上記した給電ユニット２の電極板２１が設けられている。この電極板２１は、図３に示すように、化粧料１０と十分に接触し、かつ、発生した水素を上方に通過させることができるように、円板に複数のスリット状の空隙を形成して構成された陰極２１ａと陽極２１ｂとを備えており、これら陰極２１ａと陽極２１ｂとの間にはセパレータ２１ｃが設けられている。陰極２１ａは、セパレータ２１ｃ上のアダプター２１ｄによって固定され、容器本体３側の空間に設けられ、陽極２１ｂはセパレータ２１ｃ下の、当該セパレータ２１ｃと陽極空間形成用スペーサ２１ｅとによって形成される空間に設けられる。この電極板２１に給電ユニット２からの通電が行われると、陰極２１ａでは水素が発生するとともに、還元成分を多く含んだ化粧料１０が生成される。また、陽極２１ｂでは酸素が発生するとともに、酸化された化粧料１０が生成される。しかし、セパレータ２１ｃより下の陽極２１ｂに与えられた空間は小さく、ほとんどの空間を占める容器本体３内の空間は陰極２１ａと接しているため、通電によって水素および還元成分を多く含んだ化粧料１０の生成が積極的に行われることとなる。 The container body 3 is configured on the power supply unit 2 and has a capacity space in which the cosmetic 10 can be filled. The electrode plate 21 of the power supply unit 2 described above is provided at the bottom of the container body 3. As shown in FIG. 3, the electrode plate 21 forms a plurality of slit-shaped gaps in the disc so that the electrode plate 21 is in sufficient contact with the cosmetic 10 and allows the generated hydrogen to pass upward. The cathode 21a and the anode 21b configured as described above are provided, and a separator 21c is provided between the cathode 21a and the anode 21b. The cathode 21a is fixed by an adapter 21d on the separator 21c and provided in a space on the container body 3 side, and the anode 21b is provided in a space formed by the separator 21c and the anode space forming spacer 21e below the separator 21c. It is done. When the electrode plate 21 is energized from the power supply unit 2, hydrogen is generated at the cathode 21a, and the cosmetic 10 containing a large amount of reducing components is generated. In addition, oxygen is generated at the anode 21b and the oxidized cosmetic 10 is generated. However, since the space given to the anode 21b below the separator 21c is small and the space in the container body 3 occupying most of the space is in contact with the cathode 21a, the cosmetic 10 containing a large amount of hydrogen and reducing components by energization. Will be actively generated.
　また、この容器本体３の上部には螺子部３１が設けられ、螺子部３１に螺合して着脱することができるようになされた手動指圧式のスプレーポンプ３２を設けることができるようになされている。このスプレーポンプ３２における容器本体３内に伸びたノズル部３２ａは、その先端の化粧料１０の吸込み口となる部分が、上記した水素が発生する陰極２１ａの直上に、所定の間隔（例えば、２ｍｍ程度）を空けて位置するように設けられている。これにより、陰極２１ａで発生した水素および還元成分を多く含んだ化粧料１０は、ノズル部３２ａからスプレーポンプ３２によるポンピング作用によって吸い込まれた後に噴霧されることとなり、人体の所望の部位に塗布して馴染ませることが可能となる。このようにして塗布される水素および還元成分を多く含んだ化粧料１０は、水素と還元成分に加え、植物を水蒸気蒸留して得られた蒸留液の美容成分によって美容効果が増進されることとなる。特に、水素と還元成分は、使用する毎に発生させるので高濃度な状態で使用できる。また、美容成分も、美容効果以外に、当該美容液を使用する毎に水素を発生させても劣化による変色や悪臭の発生を生じないので、効果的である。 Further, a screw portion 31 is provided on the upper portion of the container body 3, and a manual acupressure spray pump 32 adapted to be screwed into and removed from the screw portion 31 can be provided. Yes. In the spray pump 32, the nozzle portion 32a extending into the container body 3 has a portion serving as a suction port for the cosmetic 10 at the tip thereof directly above the cathode 21a where hydrogen is generated (for example, 2 mm). It is provided so as to be spaced apart. As a result, the cosmetic 10 containing a large amount of hydrogen and reducing components generated at the cathode 21a is sprayed after being sucked from the nozzle portion 32a by the pumping action of the spray pump 32, and applied to a desired part of the human body. It becomes possible to get used to it. The cosmetic 10 containing a large amount of hydrogen and reducing components applied in this way has a cosmetic effect enhanced by the cosmetic components of the distillate obtained by steam-distilling plants in addition to hydrogen and reducing components. Become. In particular, hydrogen and reducing components are generated each time they are used, so that they can be used in a high concentration state. In addition to the cosmetic effect, the cosmetic component is also effective because it does not cause discoloration or malodor due to deterioration even when hydrogen is generated each time the cosmetic liquid is used.
　さらに、容器本体３は、給電ユニット２と一体化するようにカバーケース１１に収納されてスプレーポンプ３２の押圧部分３２ｂが露出するようになされている。この押圧部分３２ｂには、カバーケース１１と一体化する蓋体１２が設けられる。 Furthermore, the container body 3 is housed in the cover case 11 so as to be integrated with the power supply unit 2 so that the pressing portion 32b of the spray pump 32 is exposed. The pressing portion 32 b is provided with a lid 12 that is integrated with the cover case 11.
　なお、このようにして構成される化粧料噴霧装置１は、使用する毎にスイッチ２２を押して水素を発生させるように構成されているため、給電ユニット２が故障したり、バッテリー２０が切れて水素が発生しなくなると、十分な効果を発揮できなくなってしまう。したがって、水素の発生状態が確認できるように、容器本体３は、透明に形成されており、給電ユニット２と容器本体３とを一体化して被覆するカバーケース１１の窓部１１ａから、内部の水素の発生具合を泡の量によって視認できるようになされている。ただし、このような窓部１１ａから視認するように構成されたものに限定されるものではなく、給電ユニット２と容器本体３とが一体化するように構成され、容器本体３の部分全体が透明で視認できるように構成されていてもよい。 Note that the cosmetic spraying apparatus 1 configured in this way is configured to generate hydrogen by pressing the switch 22 every time it is used, so that the power supply unit 2 breaks down or the battery 20 runs out to generate hydrogen. If this does not occur, sufficient effects cannot be achieved. Therefore, the container main body 3 is formed transparent so that the generation state of hydrogen can be confirmed, and the internal hydrogen is introduced from the window portion 11a of the cover case 11 that integrally covers the power supply unit 2 and the container main body 3. The degree of occurrence can be visually recognized by the amount of foam. However, it is not limited to what was comprised so that it might be visually recognized from such a window part 11a, but it is comprised so that the electric power feeding unit 2 and the container main body 3 may be integrated, and the whole part of the container main body 3 is transparent. You may be comprised so that it can visually recognize.
　次に、本発明に係る化粧料による実施例について説明する。 Next, examples of cosmetics according to the present invention will be described.
実施例１－実施例２２
　表１に示す各組成の化粧料を調製した。なお、バラの花を水蒸気蒸留して得られた液としては、センチフォリアバラ花水（ＩＮＣＩ名：Rosa Centifolia Flower Water、ＣＡＳNo.84604-12-6）を使用した。 Example 1-Example 22
Cosmetics having respective compositions shown in Table 1 were prepared. In addition, as a liquid obtained by steam-distilling rose flowers, centifolia rose flower water (INCI name: Rosa Centifolia Flower Water, CAS No. 84604-12-6) was used.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
　得られた化粧料５０ｇを、図１に示す構成の化粧料噴霧装置１に入れ、スイッチ２２を入れて連続的に水素を発生させた。化粧料の容量５０ｇに対し、化粧料噴霧装置１の１プッシュで出る化粧料の量が約０．１４ｇなので、通常使用量は１～１０プッシュであるが、最小の１プッシュ毎に１０秒の通電を行ったと仮定すると、５０ｇの化粧料が使用される間に、約６０分（５０ｇ÷０．１４ｇ×１０秒＝３５７１秒≒６０分）の通電が行われることとなる。そこで、６０分の３倍の約１８０分間にわたり、連続的に水素を発生させる過酷試験を行って、水素発生後の色調、臭気、水素の発生量を評価した。 1) 50 g of the obtained cosmetic material was placed in the cosmetic spray device 1 having the configuration shown in FIG. 1, and the switch 22 was turned on to continuously generate hydrogen. Since the amount of cosmetics produced by one push of the cosmetic spraying device 1 is about 0.14 g for a cosmetic amount of 50 g, the normal usage is 1 to 10 pushes, but 10 seconds for every minimum push. Assuming that energization is performed, energization is performed for about 60 minutes (50 g ÷ 0.14 g × 10 seconds = 3571 seconds≈60 minutes) while 50 g of cosmetic is used. Therefore, a severe test for continuously generating hydrogen was performed for about 180 minutes, which is three times 60 minutes, and the color tone, odor, and hydrogen generation amount after hydrogen generation were evaluated.
　色調は、変化なし「０」、少し着色「１」、淡い茶色「２」、褐色に変化「３」の４段階評価で２６名のパネラーに評価をしてもらい、その平均値を取った。「１」未満を合格とした。 The color tone was evaluated by 26 panelists in a four-step evaluation of “0” without change, “1” slightly colored, “2” light brown, and “3” changed to brown, and the average value was taken. A value less than “1” was considered acceptable.
　臭気は、臭気変化なし「０」、少し臭気が異なる「１」、やや悪臭がする「２」、悪臭がする「３」の４段階評価で２６名のパネラーに評価をしてもらい、その平均値をとった。「１」未満を合格とした。 Odors were evaluated by 26 panelists based on a four-step evaluation: “0”, no odor change, “1” with slightly different odors, “2” with slightly odors, and “3” with odors. I took the value. A value less than “1” was considered acceptable.
　水素発生量は、水素の泡がほとんど認められない「０」、水素の泡が出ている「１」、水素の泡が多く出ている「２」、水素の泡が非常に多く出ている「３」の４段階で２６名のパネラーに評価してもらい、その平均値を取った。「１」以上を合格とした。
　結果を表２に示す。 The amount of hydrogen generated is “0” where almost no hydrogen bubbles are observed, “1” where hydrogen bubbles are generated, “2” where many hydrogen bubbles are generated, and very many hydrogen bubbles are generated. Twenty-six panelists were evaluated in four stages of “3”, and the average value was taken. “1” or higher was accepted.
The results are shown in Table 2.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
　表２の結果から、本発明に係る化粧料は、水素の発生によって劣化して変色や悪臭が発生するといったことを防止できるので、水素や有効成分の含まれた化粧料を使用者が快適に使用できることとなる。 From the results of Table 2, since the cosmetic according to the present invention can be prevented from being deteriorated due to the generation of hydrogen and causing discoloration and malodor, the user can comfortably use the cosmetic containing hydrogen and active ingredients. It can be used.
　なお、上記各実施例と比較するために、センチフォリアバラ花水の使用量を９５質量％、酸化銀０．００００１質量％、アスコルビン酸ナトリウム０．１質量％、アラニン０．０００１質量％、残部を水としたものを用意したが、バラの花を水蒸気蒸留して得られた液の臭気が強すぎて化粧料としての使用が困難であった。また、センチフォリアバラ花水の使用量を２質量％、酸化銀０．００００１質量％、アスコルビン酸ナトリウム０．１質量％、アラニン０．０００１質量％、残部を水としたものを用意したが、センチフォリアバラ花水由来のバラの香りが弱く、当該バラの臭気以外に他の成分のベース臭がして化粧料として満足感が得られるものではなかった。 In addition, in order to compare with each said Example, the usage-amount of centifolia rose flower water is 95 mass%, silver oxide 0.00001 mass%, sodium ascorbate 0.1 mass%, alanine 0.0001 mass%, remainder However, it was difficult to use as a cosmetic because the odor of the liquid obtained by steam distillation of rose flowers was too strong. In addition, the amount of centifolia rose flower water used was 2% by mass, 0.00001% by mass of silver oxide, 0.1% by mass of sodium ascorbate, 0.0001% by mass of alanine, and the balance being water, The fragrance of the rose derived from the centifolia rose flower water was weak, and the base odor of other components other than the odor of the rose was not obtained, and the satisfaction as a cosmetic was not obtained.
　上記実施例１－２２において、バラの花を水蒸気蒸留して得られた液として使用しているセンチフォリアバラ花水（ＩＮＣＩ名：Rosa Centifolia Flower Water、ＣＡＳNo.84604-12-6）を、ラベンダーの花を水蒸気蒸留して得られた液であるラベンダー花水（ＩＮＣＩ名：Lavandula Angustifolia (Lavender) Flower Water、ＣＡＳNo.90063-37-9）に変更して同様の実験を行ったが、水素発生後の色調、臭気、水素の発生量の全ての項目で合格の成績が得られた。 In Example 1-22, the centifolia rose flower water (INCI name: RosaRCentifolia Flower Water, CAS No. 84604-12-6) used as a liquid obtained by steam distillation of rose flowers was used as a lavender. A similar experiment was carried out by changing to lavender flower water (INCI name: Lavandula Angustifolia (Lavender) Flower Water, CAS No. 90063-37-9), which is a liquid obtained by steam distillation of flowers. Successful results were obtained for all of the following items: color tone, odor, and amount of hydrogen generated.
　また、同様に、上記実施例１－２２において、バラの花を水蒸気蒸留して得られた液として使用しているセンチフォリアバラ花水（ＩＮＣＩ名：Rosa Centifolia Flower Water、ＣＡＳNo.84604-12-6）を、セージの葉を水蒸気蒸留して得られた液であるセージ水（ＩＮＣＩ名：Salvia Officinalis (Sage) Leaf Water、ＣＡＳNo.84082-79-1）に変更して同様の実験を行ったが、水素発生後の色調、臭気、水素の発生量の全ての項目で合格の成績が得られた。 Similarly, in Example 1-22, centifolia rose flower water (INCI name: Rosa ： Centifolia Flower Water, CAS No. 84604-12-) used as a liquid obtained by steam distillation of rose flowers. 6) was changed to sage water (INCI name: Salvia Officinalis (Sage) Leaf Water, CAS No.84082-79-1), which is a liquid obtained by steam distillation of sage leaves, and the same experiment was conducted. However, the passing results were obtained in all items of color tone, odor, and hydrogen generation amount after hydrogen generation.
　なお、本発明は、その精神または主要な特徴から逸脱することなく、他のいろいろな形で実施することができる。そのため、上述の実施例はあらゆる点で単なる例示に過ぎず、限定的に解釈してはならない。本発明の範囲は特許請求の範囲によって示すものであって、明細書本文には、なんら拘束されない。さらに、特許請求の範囲に属する変形や変更は、全て本発明の範囲内のものである。 Note that the present invention can be implemented in various other forms without departing from the spirit or main features thereof. For this reason, the above-described embodiments are merely examples in all respects and should not be interpreted in a limited manner. The scope of the present invention is indicated by the claims, and is not restricted by the text of the specification. Furthermore, all modifications and changes belonging to the scope of the claims are within the scope of the present invention.
１　化粧料噴霧装置
１０　化粧料
２　給電ユニット
２１　電極板
３　容器本体
３２　スプレーポンプ
３２ａ　ノズル部（吸入ノズル）
  DESCRIPTION OF SYMBOLS 1 Cosmetic spraying apparatus 10 Cosmetics 2 Electric power feeding unit 21 Electrode plate 3 Container main body 32 Spray pump 32a Nozzle part (suction nozzle)

Claims (7)

  1. 　容器中の化粧料を電気分解し、この電気分解によって発生させた水素とともに、皮膚に塗布される化粧料であって、
    　当該化粧料には、植物を水蒸気蒸留して得られた液が５～９０質量％配合されていることを特徴とする化粧料。     A cosmetic applied to the skin by electrolyzing the cosmetic in the container and hydrogen generated by the electrolysis,
    A cosmetic comprising 5 to 90% by mass of a liquid obtained by steam distillation of a plant.
  2. 　植物は、バラ、ジャスミン、ダイダイ、カモミール、およびイランイランの花およびその蕾、セージ、ユーカリ、ティートリー、およびサルビアの葉、温州ミカン、ダイダイ、オレンジ、レモン、ライム、およびベルガモットの果皮、サンダルウッド、マツ、ヒノキ、およびシナモンの樹皮、ラベンダー、レモングラス、バジル、ローズマリー、およびミントの全草、の中から選択される１種または２種以上である請求項１に記載の化粧料。 Plants include roses, jasmine, daidai, chamomile, and ylang ylang flowers and their buds, sage, eucalyptus, tea tree, and salvia leaves, mandarin orange, daidai, orange, lemon, lime, and bergamot peel, sandalwood, The cosmetic according to claim 1, wherein the cosmetic is one or more selected from pine, cypress, and cinnamon bark, lavender, lemongrass, basil, rosemary, and whole mint.
  3. 　化粧料には、さらに、金属酸化物が０．０１ｐｐｍ～３０ｐｐｍ配合されている請求項１または２に記載の化粧料。 The cosmetic according to claim 1, wherein the cosmetic further contains 0.01 ppm to 30 ppm of a metal oxide.
  4. 　金属酸化物は、酸化チタン、酸化亜鉛、酸化鉄、硫酸バリウム、酸化銀、酸化アルミニウム、酸化カルシウムから選択される１種または２種以上である請求項３に記載の化粧料。 The cosmetic according to claim 3, wherein the metal oxide is one or more selected from titanium oxide, zinc oxide, iron oxide, barium sulfate, silver oxide, aluminum oxide, and calcium oxide.
  5. 　化粧料には、さらに、アスコルビン酸、アスコルビン酸塩、アスコルビン酸誘導体の中から選択される１種または２種以上が、０．００１～２０質量％配合されている請求項１ないし４の何れか一に記載の化粧料。 5. The cosmetic according to claim 1, further comprising 0.001 to 20% by mass of one or more selected from ascorbic acid, ascorbate, and ascorbic acid derivatives. Cosmetics according to 1.
  6. 　化粧料には、さらに、１種または２種以上のアミノ酸が、０．０００１～１０質量％配合されている請求項１ないし５の何れか一に記載の化粧料。 The cosmetic according to any one of claims 1 to 5, wherein the cosmetic further contains 0.0001 to 10% by mass of one or more amino acids.
  7. 　請求項１ないし６の何れか一に記載の化粧料を充填し、噴霧する装置であって、
    　前記装置は、給電ユニット上に設けられた容器本体内に、請求項１ないし６の何れか一に記載の化粧料が設けられ、前記容器本体の底部に、給電ユニットからの給電によって、容器本体内の化粧料を電気分解して水素を発生させるための電極板が設けられ、容器本体には、押圧することによって当該容器本体内の化粧料を噴霧可能なスプレーポンプが設けられ、当該スプレーポンプから容器本体内に設けられた吸入ノズルは、電極板で発生して容器本体内を浮上する水素が通過する位置に設けられ、水素発生後の水素を含んだ化粧料を噴霧できるようになされたことを特徴とする化粧料噴霧装置。
          A device for filling and spraying the cosmetic according to any one of claims 1 to 6,
    In the apparatus, the cosmetic according to any one of claims 1 to 6 is provided in a container main body provided on the power supply unit, and the container main body is supplied with power from the power supply unit at the bottom of the container main body. An electrode plate for electrolyzing the cosmetics in the container to generate hydrogen is provided, and the container body is provided with a spray pump capable of spraying the cosmetics in the container body by pressing, the spray pump The suction nozzle provided in the container body is provided at a position where the hydrogen generated in the electrode plate and floating in the container body passes, so that cosmetics containing hydrogen after hydrogen generation can be sprayed. Cosmetic spraying device characterized by that.
PCT/JP2016/080936 2016-10-19 2016-10-19 Cosmetic and cosmetic spraying device WO2018073910A1 (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004107304A (en) * 2002-09-20 2004-04-08 Nara Camicee Japan:Kk Method for conditioning skin or hair, and cosmetic material
JP2005281177A (en) * 2004-03-29 2005-10-13 Kaname Nakanishi Cosmetic gel and dentifrice
JP2007007591A (en) * 2005-07-01 2007-01-18 Mikuni Corp Electrolylic water and its production method
JP2008114138A (en) * 2006-11-02 2008-05-22 Arika Co Ltd Functional water
JP2008127583A (en) * 2006-11-16 2008-06-05 Permelec Electrode Ltd Membrane-electrode assembly, electrolytic unit using the same, electrolytic water jetting device and sterilization method
JP2013017667A (en) * 2011-07-12 2013-01-31 Ya Man Ltd Mist generator
JP2015086220A (en) * 2013-09-26 2015-05-07 文士 張 Hydrogen-containing aerosol, and storage method of hydrogen-containing aerosol
JP2016069323A (en) * 2014-09-30 2016-05-09 株式会社レドックス Liquid composition for skin care or hair care

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004107304A (en) * 2002-09-20 2004-04-08 Nara Camicee Japan:Kk Method for conditioning skin or hair, and cosmetic material
JP2005281177A (en) * 2004-03-29 2005-10-13 Kaname Nakanishi Cosmetic gel and dentifrice
JP2007007591A (en) * 2005-07-01 2007-01-18 Mikuni Corp Electrolylic water and its production method
JP2008114138A (en) * 2006-11-02 2008-05-22 Arika Co Ltd Functional water
JP2008127583A (en) * 2006-11-16 2008-06-05 Permelec Electrode Ltd Membrane-electrode assembly, electrolytic unit using the same, electrolytic water jetting device and sterilization method
JP2013017667A (en) * 2011-07-12 2013-01-31 Ya Man Ltd Mist generator
JP2015086220A (en) * 2013-09-26 2015-05-07 文士 張 Hydrogen-containing aerosol, and storage method of hydrogen-containing aerosol
JP2016069323A (en) * 2014-09-30 2016-05-09 株式会社レドックス Liquid composition for skin care or hair care

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