WO2018005287A1

WO2018005287A1 - Adhesive article and method of making the same

Info

Publication number: WO2018005287A1
Application number: PCT/US2017/039040
Authority: WO
Inventors: Maria A. Appeaning; Marie A. Boulos; David J. Kinning; Georgiy Teverovskiy; Michael L. Steiner; Sai VANG
Original assignee: 3M Innovative Properties Company
Priority date: 2016-06-29
Filing date: 2017-06-23
Publication date: 2018-01-04

Abstract

A method of making an adhesive article comprises three steps. First, a backing is provided having first and second opposed major surfaces with respective first and second, silicone release layers disposed thereon. The second silicone release layer comprises an at least partially crosslinked silicone and from 5 to 20 percent by weight of inert flowable silicone. The inert flowable silicone has a number average molecular weight between 1000 grams/mole and 100,000 grams/mole. Second, an adhesive layer is disposed onto the first silicone release layer. Third, at least the adhesive layer is exposed to E-beam radiation within a process chamber thereby providing a crosslinked adhesive layer. The process chamber contains oxygen. The second silicone release layer is exposed to the oxygen during crosslinking of the adhesive layer.

Description

ADHESIVE ARTICLE AND METHOD OF MAKING THE SAME

TECHNICAL FIELD

The present disclosure broadly relates to adhesive articles and methods of making them.

BACKGROUND

Adhesive tape comes in many varieties; for example, single-sided or double-sided tape, typically wound into a roll. Double-sided adhesive tape (also termed "adhesive transfer tapes") has adhesive properties on both sides, generally covered by a liner to protect the adhesive, which is removed prior to when the adhesive layer is bonded to a substrate. In some embodiments, a double-sided release liner is used, wherein a first release layer is coated on a first major surface of a backing, and a second release layer is coated on a second major surface of the backing opposite the first major surface. Typically, the first and second release layers are designed to have different release properties to facilitate dispensing the tape in roll form. For example, the first release layer may bind somewhat more tightly to the adhesive layer than the second release layer in order to achieve a clean unwind of the roll.

Methods of producing double-sided adhesive tape can be relatively simple, and one method of production and the resulting structure is as follows. A layer of an adhesive composition is readied and extruded, or otherwise coated by some acceptable method, onto the first release layer of the release liner. For high performance adhesive tapes, the adhesive composition is often then crosslinked (e.g., chemically, by visible or ultraviolet light, or by electron beam radiation). Next, the double-sided release liner and adhesive construction is wound into a roll such that the adhesive layer is sandwiched between the first and second release layers.

Production of double-sided adhesive tape by this method is desirable, but significant problems are encountered when electron beam ("E-Beam") radiation is used to crosslink the adhesive polymer. E-Beam radiation is advantageous as a method of crosslinking because it is effective to crosslink adhesive polymers that have high amounts of pigments or fillers, and/or adhesive films of greater thicknesses. In tape constructions with a single double-sided liner, it is typically necessary to perform the electron beam (E-Beam) exposure step with a major surface of the silicone release layer exposed (the exposed surface) to the ambient environment of the E-Beam processing chamber. If the exposed surface of the silicone release layer is exposed to E-Beam radiation ("E-Beam treated") before winding into a roll, the release properties of the silicone release layer as adhered to the adhesive layer itself are typically altered in a deleterious fashion. Moreover, in this configuration the adhesive bond between the adhesive layer and the release layer onto which it is subsequently wound tends to increase over time, leading to unpredictable product performance. This can create an undesirable situation in the final product wherein the adhesion of the adhesive layer to both release layers is comparable, resulting in what is known as "liner confusion". In some cases, the release liner cannot even be removed. This is known as "liner blocking". Even when the adhesive material is E-Beam treated directly (i.e., not through a release liner), the side of the silicone release layer opposite the adhesive material will typically be affected if the radiation penetrates through the liner.

One solution to this problem has been to manufacture the double-sided adhesive tape on a temporary liner, crosslink the adhesive with E-Beam radiation, and then replace the temporary release liner with another release liner before it is packaged into the final product. However, this solution is unacceptable because it adds to the complexity of the process, increases waste of the process, and adds the additional cost of another liner. Therefore, there is a need for a release liner that can be E-Beam treated while still maintaining essentially the same pre-E-Beam treated release characteristics so that it need not be replaced before the consumer can utilize the final product. SUMMARY

Without wishing to be bound by theory, Applicants believe that the detrimental effect of E-beam exposure on the open side of the adhesive layer (discussed above) and exposed silicone release layer leads to formation of various chemical species (e.g., peroxide groups and/or peroxy radicals) that chemically transform the adhesive and release material surfaces as well as their interface over time, thereby contributing to the problems enumerated above.

Advantageously, the present disclosure describes methods of overcoming the

aforementioned problems, without the need for a costly temporary release liner.

Accordingly, in one aspect the present disclosure provides a method of making an adhesive article, the method comprising:

providing a backing having first and second opposed major surfaces, wherein a first silicone release layer is disposed on the first major surface, wherein a second silicone release layer is disposed on the second major surface, wherein the second silicone release layer comprises an at least partially crosslinked silicone and from 5 to 20 percent by weight of inert flowable silicone, based on the total weight of the first silicone release layer, and wherein the inert flowable silicone has a number average molecular weight between 1000 grams/mole and 100,000 grams/mole; disposing an adhesive layer onto the first silicone release layer; and

exposing at least the adhesive layer to electron beam radiation within a process chamber thereby providing a crosslinked adhesive layer, wherein the process chamber contains oxygen, wherein the second silicone release layer is exposed to the oxygen during crosslinking of the adhesive layer. In another aspect, the present disclosure provides an adhesive article prepare according to the method of the present disclosure.

As used herein:

The chemical group "Me" refers to methyl.

The term "siliconized release liner" refers to a backing (e.g., a tape or sheet) having silicone release layers on opposed major surfaces thereof.

Features and advantages of the present disclosure will be further understood upon consideration of the detailed description as well as the appended claims.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic representation of a vertical cross-section of an exemplary double- sided adhesive tape according to the present disclosure.

FIG. 2 is a schematic representation of an exemplary method of winding up double-sided adhesive tape in to a roll.

FIG. 3 is a schematic representation of an exemplary process for making a double-sided adhesive tape according to the present disclosure.

Repeated use of reference characters in the specification and drawings is intended to represent the same or analogous features or elements of the disclosure. It should be understood that numerous other modifications and embodiments can be devised by those skilled in the art, which fall within the scope and spirit of the principles of the disclosure. The figures may not be drawn to scale.

DETAILED DESCRIPTION

FIG. 1 depicts a vertical cross-section of one configuration of a double-sided adhesive tape 10 after its production and before it has been packaged. The double-sided adhesive tape 10 includes an adhesive layer 12. Polymers that can be used in the adhesive layer 12 are discussed more fully below. The adhesive layer 12 is generally formed in a sheet and has a first surface 1 1 and a second surface 13. When the double-sided adhesive tape 10 is produced, the method of production leaves the first surface 1 1 of the adhesive layer 12 uncovered.

The double-sided adhesive tape 10 also includes a siliconized release liner 20. The siliconized release liner 20 includes a backing 21. Suitable materials for the backing 21 are discussed more fully below. The backing 21 has a first surface 23 and a second surface 24. The siliconized release liner 20 includes a first silicone release layer 22 and a second silicone release layer 25. While FIG. 1 shows siliconized release liner 20 with first silicone release layer 22, backing 21 may have sufficient liner release such that first silicone release layer 22 is not necessary. If used, first silicone release layer 22 is applied to the first surface 23 of the backing 21. The second silicone release layer 25 is applied to the second surface 24 of the backing 21. The first silicone release layer 22 has a release side 27 next to the second surface 13 of the adhesive layer 12 and a backing side 28. The release side 27 of the first silicone release layer 22 also defines a first surface 23 of siliconized release liner 20. The second silicone release layer 25 has a backing side 29 and a non-backing side 30. The non-backing side 30 of the second silicone release layer 25 also defines a second surface 32 of siliconized release liner 20. The first and second silicone release layers 22 and 25 can be composed of the same or different material. Preferably, the first and second silicone release layers (22, 25) are composed of different materials.

FIG. 2 depicts one method of readying a double-sided adhesive tape 10 for packaging.

The double-sided adhesive tape 10 is wound around itself into a roll to form a packageable article 50. In use, double-sided adhesive tape is unwound, optionally cut, and applied to a surface with the exposed side of the adhesive layer 12 (the first side 1 1 discussed above) and the backing 21 is then removed. Optionally, the second side 13 of the adhesive layer 12 is applied to a second surface after the backing 21 is removed. This method of forming a packageable article 50 results in portions of the double-sided adhesive tape 10 interacting with other portions of the double-sided adhesive tape 10. Once the double-sided adhesive tape 10 begins to be wound on itself, the first surface 1 1 of the adhesive layer 12 comes into contact with the non-backing side 30 of the second silicone release layer 25 (also referred to as the second surface 32 of siliconized release liner 20).

The contact of the non-backing side 30 of the second silicone release layer 25 and the first surface 1 1 of the adhesive layer 12 becomes important when the packageable article 50 is unrolled to use the double-sided adhesive tape 10. It is desirable that the adhesive layer 12 and the siliconized release liner 20 maintain contact through the second surface 13 instead of the first surface 1 1 of the adhesive layer 12. Therefore, the siliconized release liner 20 should release preferentially from the first surface 1 1 before it releases from the second surface 13 of the adhesive layer 12. Thus the siliconized release liner 20 should have a liner release from the first surface 1 1 of the adhesive layer 12 that is sufficiently different from the liner release from the second surface 13 of the adhesive layer 12. The second surface 32 of siliconized release liner 20 and adhesive layer 12 are configured so that this differential effect is developed. Preferably, the ratio of release forces from the first release layer and the second release layer is at least 2: 1, more preferably at least 3: 1.

FIG. 3 schematically depicts one method of producing double-sided adhesive tape 10 and forming it into a packageable article 50. The adhesive layer 12 is dispensed from a dispenser 101 onto a siliconized release liner 20. Next the siliconized release liner 20 and the adhesive layer 12 are laminated together between a pair of nip rollers 102 to form the double-sided adhesive tape 10. Then, the double-sided adhesive tape 10 is exposed to radiation from a radiation source 103 through the siliconized release liner 20 to cause crosslinking of the adhesive layer 12. The radiation source 103 is preferably an E-Beam source. The double-sided adhesive tape 10 is then formed into a packageable article 50 by winding upon itself to form a roll.

The siliconized release liner has a backing with first and second opposed major surfaces

(23, 24). First and second silicone release layers (22, 25) are disposed on the respective surfaces of the backing 21.

Suitable materials for the backing 21 include, for example, polymeric films, such as polyester films (e.g., polyethylene terephthalate films (PET)), polyethylene naphthalate (PEN), and polyolefin films (e.g., polyethylene films, polypropylene films, biaxially-oriented polypropylene films (BOPP films)), metallized film, sealed paper (e.g., polyethylene -coated paper, metallized paper, and clay-coated paper), and paper. Usually the backing or substrate is primed in order to increase the anchorage of the silicone coating. Typical priming methods include corona or flame treatment, or coating of a primer onto the substrate. An example of a primer coating for anchorage of silicone to PET film is disclosed in U.S. Pat. No. 5,077,353 (Culbertson et al). In addition, the backing or substrate may contain an anti-static coating in order to prevent electrostatic charging, thereby helping to keep the laminates free of debris. Examples of anti-static coatings include, but are not limited to, vanadium oxide, as described in U.S. Pat. No. 5,637,368 (Cadalbert et al.). Preferably, the release liner, and hence the backing is optically clear.

The first silicone release layer 22 on the first surface 23 of the backing 21 can include conventional silicone release materials, including those that are known in the art such as, e.g., chemistries using the following curing mechanisms: condensation cure (e.g., hydrolytic or hydrosilation-based), addition cure, free-radical cure, cationic cure, and triggered condensation cure. See also U.S. Pat. Nos. 4,504,645 (Melancon), 4,600,484 (Drahnak), and 7,279,210 (Hulteen et al.), PCT Publication No. WO 98/40439 (Liu et al.) and Handbook of Pressure Sensitive

Adhesive Technology, 3rd ed. , Chapters 23 and 24, Van Nostrand Reinhold Co., Inc. (1989) for further examples.

The second silicone release layer 25 on the second surface 24 of the backing 21 can also include conventional silicone release materials. Preferably, the second silicone release layer materials comprise tightly crosslinked siloxane networks with minimal polar or reactive functionalities, especially free-radical reactive functionalities. It is known that chemical bond cleavage will occur from excited states in an irradiated polymer when a polymer is exposed to E- Beam radiation, which leads to free radical formation. The free radicals formed have a short life and will either recombine with other free-radicals to lose their reactivity, react with a polymer, or react with other functional groups to create free radicals having a longer life. The relatively long- lived free radicals can further react with molecular oxygen, for example, and give a relatively stable peroxide compound when the irradiated material is exposed to an oxygen containing environment (i.e., radiation-oxidation).

Thus formed peroxides have a relatively longer life, so that they may be able to migrate to the adhesive-release interface to further react (or interact) with the adhesive. This causes higher liner release values (meaning that a relatively undesirable high unwind force is required) or liner blocking. To minimize liner blocking and make the second silicone release layer 25 function in the desired way, the silicone release layer material should contain minimal free-radical-reactive functionalities, such as the acrylate, methacrylate, vinyl, and silicon hydride functionalities.

The present inventors have found, unexpectedly, that a release liner coated with a silicone release composition containing certain inert silicone fluids or gums, provides acceptable release after exposing the release layer to electron beam radiation.

Silicone or polydimethylsiloxane is the most important and widely used release material. To reduce or avoid silicone transfer to the adhesive layer the silicone release layer is generally crosslinked. Crosslinking can be either physical crosslinking or chemical crosslinking. Chemical crosslinking is also referred to as "curing" in this patent application.

Among the silicone cure chemistries, free-radical cure, addition cure, and condensation cure all may give crosslinked networks.

Crosslinked silicones are typically derived from at least one corresponding reactive silicone precursor that includes two or more reactive groups. The reactive groups preferably include epoxy, acrylate, silane, silanol, or ethylenically-unsaturated (e.g., vinyl or hexenyl) groups. Silicone precursors that include two or more epoxy or acrylate groups will typically

homopolymerize without the need for a separate crosslinker. The silicone precursors that include two or more, silanol, or ethylenically-unsaturated groups use a separate crosslinker, such as a hydride-functional silicone crosslinker. Alternatively, a silanol, alkoxysilane, or acyloxysilane- functional silicone precursor can be reacted with an alkoxy-functional crosslinker, as described in U.S. Pat. No. 6,204,350 (Liu et al.).

In some embodiments, the number average molecular weight between functional groups of the silicone base precursor is less than about 500000 g/mol, preferably less than about 20000 or less. In some embodiments, the number average molecular weight between functional groups is at least about 500 g/mol, and often at least about 2,000 g/mol.

Suitable epoxy-functional silicone precursors are described, for example, in U.S. Pat. Nos. 4,279,717 (Eckberg et al.) and 5,332,797 (Kessel et al.). Examples of epoxy-functional silicone precursors include, for example, those available as SILFORCE UV 9400, SILFORCE UV 9315, SILFORCE UV 9430, SILFORCE UV 9600, all available from Momentive, Columbus, Ohio, and as SILCOLEASE UV200 series from Bluestar Silicones, East Brunswick, New Jersey.

Suitable aery late -functional silicone precursors are described, for example, in U.S. Pat. No. 4,348,454 (Eckberg). Examples of acrylate -functional silicone precursors include, for example, those available as SILCOLEASE UV100 Series, from Bluestar Silicones, and those available as TEGO RC 902, TEGO RC 922, and TEGO RC 71 1, from Evonik Industries, Parsippany, New Jersey.

Suitable silanol-functional silicone polymers are well known and are available from a variety of sources including, e.g., those available as DMS-S 12 and DMS-S21 from Gelest, Inc., Morrisville, Pennsylvania.

Suitable ethylenically-unsaturated functional silicone precursors include

polydimethylsiloxanes with pendant and/or terminal vinyl groups, as well as

polydimethylsiloxanes with pendant and/or terminal hexenyl groups. Suitable hexenyl functional silicones are described, for example, in U.S. Pat. No. 4,609,574 (Keryk et al). An example of a hexenyl-functional silicone includes, for example, one available as SYL-OFF 7677, available from Dow Corning, Midland, Michigan. Suitable vinyl-functional silicones are described, for example, in U.S. Pat. Nos. 3,814,731 (Nitzsche et al.) and 4, 162,356 (Grenoble), and are available from a wide variety of sources. Examples of vinyl-terminated polydimethylsiloxane include those available as DMS-V21 (molecular weight=6000) and DMS-V25 (molecular weight=17,200), from Gelest Inc. Suitable vinyl-functional silicone polymers are also available as SYL-OFF from Dow Corning. An exemplary material containing end-blocked and pendant vinyl-functional silicone polymers is SYL-OFF 7680-020 polymer from Dow Corning.

Suitable hydride-functional silicone crosslinkers are described, for example, in U.S. Pat. Nos. 3,814,731 (Nitzsche et al.) and 4, 162,356 (Grenoble). Suitable crosslinkers are well known, and one of ordinary skill in the art would be readily able to select an appropriate crosslinker, including identifying appropriate functional groups on such crosslinkers, for use with a wide variety of silicone-based polymers. For example, hydride-functional crosslinkers are available as SYL-OFF from Dow Corning, including those available as SYL-OFF 7048 and SYL-OFF 7678. Other exemplary hydride -functional crosslinkers include those available as SS4300C and SL4320, available from Momentive Performance Materials, Albany, New York.

The hydride equivalent weight of a hydride -functional silicone crosslinker is typically at least about 60 grams per equivalent (g/eq), and typically no greater than about 150 g/eq.

In embodiments including a silanol-functional silicone precursor and a hydride functional crosslinker, the equivalent ratio of hydride groups to silanol groups is preferably at least about 1.0 (1 : 1) and often no more than about 25.0 (25 : 1). In embodiments including an ethylenically-unsaturated functional silicone precursor and a hydride functional crosslinker, the equivalent ratio of hydride groups to ethylenically-unsaturated groups is preferably at least about 1.0 (1 : 1), and more preferably at least about 1.1. Often, the equivalent ratio is no more than about 2.0 (2: 1) and more often no more than about 1.5.

Suitable alkoxy-functional crosslinkers, and conditions of crosslinking, including relative amounts of crosslinker, are described in U.S. Pat. No. 6,204,350 (Liu et al.).

The crosslinked (e.g., cured) silicone described herein may be derived from one or more reactive silicone precursors crosslinked using a catalyst. Examples of suitable catalysts are described, for example, in U.S. Pat. No. 5,520,978 (Boardman et al.). Preferably, the catalyst is a platinum or rhodium catalyst for vinyl- and hexenyl -functional silicones. Preferably, the catalyst is a tin catalyst for silanol functional silicones. Examples of commercially available platinum catalysts include, but are not limited to, those available under the trade designation SIP6831.2 (a platinum -divinyltetramethyldisiloxane catalyst complex in xylene; 2.1-2.4 weight percent platinum concentration), available from Gelest Inc. The amount of Pt is typically about 60 to about 150 parts per million (ppm) by weight.

Other components used in making silicone release layers include, for example, inhibitors such as, e.g., a diallyl maleate inhibitor available as SL 6040-D 1 01P, from Momentive, MQ resins such as that available as SYL-OFF 7210 RELEASE MODIFIER from Dow Corning, and anchorage additives such as that available as SYL-OFF 297 available from Dow Corning.

According to the present disclosure, improved release stability for siliconized release liners that are exposed to E-Beam radiation in the presence of oxygen is achieved by including inert flowable silicone having a number average molecular weight between 1000 grams/mole and 100,000 grams/mole.

As used herein, the term "inert flowable silicone" refers to flowable polydimethylsiloxane oils, fluids, and gums described by the formula:

wherein n is at least 6. Flow may be induced by moderate applied pressure and/or heat, if not otherwise fluid at ambient temperature (e.g., 21-23 °C). Inert flowable silicone oils, fluids, and gums are widely available from commercial sources and/or can be made according to known methods. Exemplary vendors include Alfa Aesar, Ward Hill, Massachusetts; Gelest Inc., Morrisville, Pennsylvania; Dow Corning, Midland, Michigan; and Aldrich Chemical Co., Milwaukee, Wisconsin.

In some embodiments, the inert flowable silicone has a number average molecular weight (M_n) of at least 250 grams per mole (g/mol), at least 500 g/mol, at least 2000 g/mol, at least 5000 g/mol, at least 10000 g/mol, at least 15000 g/mol, at least 20000 g/mol, or even at least 25000 g/mol up to and including 30000 g/mol, up to and including 35000 g/mol, up to and including 40000 g/mol, up to and including 45000 g/mol, or even up to and including 50,000 g/mol, in any combination of the lower and upper number average molecular weights given above. In these embodiments, low release values (corresponding to lower adhesion to the adhesive) are typically achieved after aging, but very low release values may be obtained at shorter times. However, lower cost is an advantage.

The inert flowable silicone is preferably included (e.g., blended) in the second silicone release layer before curing the layer. Being inert, it does not participate in curing or crosslinking reactions. Alternatively, the second silicone release layer may be swelled with the inert flowable silicone and optionally solvent. From 5 to 20 percent by weight, inclusive, of the inert flowable silicone may be included in the silicone release layer, based on the total weight of the silicone release layer. In some preferred embodiments, the inert flowable silicone is included in the silicone release layer in an amount for from 5 to 15 percent by weight, more preferably 5 to 10 percent by weight, inclusive, based on the total weight of the silicone release layer.

Preferably, the adhesive layer retains at least 80 percent of its adhesion to any adherend relative to its adhesiveness prior to being brought into contact with the liner.

Any suitable methods can be used to coat the silicone release layers on the backing.

2

Typical silicone release layer weights are greater than 0.2 g/m and more typically are from 0.7 g/m 2 to 2.5 g/m 2. Liner release values observed with siliconized release liners that have been E- Beam treated vary both with coating weight and the specific backing utilized.

Additives such as for example, fillers, antioxidants, viscosity modifiers, pigments, release modifiers can be added to both the first and second silicone release layers (22 and 25) to the extent that they do not substantially and deleteriously alter the desired properties of the final product.

Once silicone release layer formulations are chosen, the components are mixed and delivered to a coater. Useful coating methods include, for example, bar coating; roll coating (e.g., gravure coating, offset gravure coating (also called 3 -roll coating), and 5 -roll coating); spray coating; curtain coating; and brush coating.

The silicone release layer formulations are coated directly onto the backing, either from 100% solids or from a solution. Useful backings include, but are not limited to, polyester (e.g., PET), polyolefin (e.g., polyethylene, polypropylene, biaxially oriented polypropylene (BOPP)), polycoated paper, metallized paper, clay sealed paper, and metallized films. The surfaces of the backing may be further treated to enhance silicone release layer anchorage to the backing chemically or physically, for example, with a primer, corona treatment, or flame treatment.

After each curable silicone release layer formulation is coated onto the backing, the coated curable silicone release layer formulation is cured, for example, by ultraviolet (UV) or thermal radiation, depending on the requirements of the system. Examples of useful UV lights include high intensity UV lights, such as H-type lamps (commercially available from Fusion UV Curing Systems, Rockville, Maryland) and medium pressure mercury lamps. When solvent-based formulations are used as silicone release layers, treatment in a thermal oven also may be needed before UV curing to remove solvents.

This general procedure works for both the first silicone release layer 21 and second silicone release layer 25. Generally, the first silicone release layer 21 is coated before the second silicone release layer 25. Alternatively, both of the first and second silicone release layers 21, 25 may be coated and cured at the same time.

A variety of different polymer resins, as well as blends thereof, are suitable for forming the adhesive layer 12. The particular resin is selected based upon the desired properties of the final article. An example of a class of polymer resins useful in the adhesive layer 12 can be found in U.S. Pat. No. 6, 103, 152 (Gehlsen et al). It may be desirable to blend two or more acrylate polymers having different chemical compositions. A wide range of physical properties can be obtained by manipulation of the type and concentration of the blend components.

One class of polymers useful for the adhesive layer 12 includes acrylate and methacrylate polymers and copolymers. Such polymers are formed, for example, by polymerizing one or more monomeric acrylic or methacrylic esters of non-tertiary alkyl alcohols, with the alkyl groups having from 1 to 20 carbon atoms (e.g., from 3 to 18 carbon atoms). Suitable acrylate monomers include, for example, methyl acrylate, ethyl acrylate, n-butyl acrylate, lauryl acrylate, 2-ethylhexyl acrylate, cyclohexyl acrylate, iso-octyl acrylate, octadecyl acrylate, nonyl acrylate, decyl acrylate, and dodecyl acrylate. The corresponding methacrylates are useful as well. Also useful are aromatic acrylates and methacrylates (e.g., benzyl acrylate and benzyl methacrylate).

Optionally, one or more monoethylenically-unsaturated co-monomers may be polymerized with the acrylate or methacrylate monomers. The particular type and amount of co-monomer is selected based upon the desired properties of the polymer. One group of useful co-monomers includes those having a homopolymer glass transition temperature greater than the glass transition temperature of the (meth)acrylate (i.e., acrylate or methacrylate) homopolymer. Examples of suitable co-monomers falling within this group include: acrylic acid; acrylamides; methacrylamides; substituted acrylamides (such as N,N-dimethylacrylamide); itaconic acid; methacrylic acid; acrylonitrile; methacrylonitrile; vinyl acetate; N-vinylpyrrolidone; isobornyl acrylate; cyanoethyl acrylate; N-vinylcaprolactam; maleic anhydride; hydroxyalkyl

(meth)acrylates; N,N-dimethylaminoethyl (meth)acrylate; N,N-diethylacrylamide; beta- carboxyethyl acrylate; vinyl esters of neodecanoic, neononanoic, neopentanoic, 2-ethylhexanoic, or propionic acids; vinylidene chloride; styrene; vinyltoluene, and alkyl vinyl ethers.

A second group of monoethylenically -unsaturated co-monomers that may be polymerized with the acrylate or methacrylate monomers includes those having a homopolymer glass transition temperature (Tg) less than the glass transition temperature of the acrylate homopolymer.

Examples of suitable co-monomers falling within this class include ethyloxyethoxyethyl acrylate (Tg = -71 degrees Celsius (°C)) and a methoxypolyethylene glycol 400 acrylate (Tg = -65 °C; available from Shin Nakamura Chemical Co., Ltd. under the designation "NK Ester AM-90G").

A second class of polymers useful in the adhesive layer 12 includes: semicrystalline polymer resins, such as polyolefins and polyolefin copolymers (e.g., polymer resins based upon monomers having between 2 and 8 carbon atoms, such as low-density polyethylene, high-density polyethylene, polypropylene, and ethylene -propylene copolymers); polyesters and co-polyesters; polyamides and co-polyamides; fluorinated homopolymers and copolymers; polyalkylene oxides (e.g., polyethylene oxide and polypropylene oxide); polyvinyl alcohol; ionomers (e.g., ethylene- methacrylic acid copolymers neutralized with a base); and cellulose acetate. Other examples of polymers in this class include amorphous polymers such as polyacrylonitrile polyvinyl chloride, thermoplastic polyurethanes, aromatic epoxies, polycarbonates, amorphous polyesters, amorphous polyamides, ABS block copolymers, polyphenylene oxide alloys, ionomers (e.g., ethylene- methacrylic acid copolymers neutralized with salt), fluorinated elastomers, and polydimethyl siloxane.

A third class of polymers useful in the adhesive layer 12 includes elastomers containing ultraviolet radiation-activatable groups. Examples include polybutadiene, polyisoprene, polychloroprene, random and block copolymers of styrene and dienes (e.g., SBR), and ethylene- propylene -diene monomer rubber. This class of polymer is typically combined with tackifying resins.

A fourth class of polymers useful in the adhesive layer 12 includes pressure-sensitive and hot melt applied adhesives prepared from non-photopolymerizable monomers. Such polymers can be adhesive polymers (i.e., polymers that are inherently adhesive), or polymers that are not inherently adhesive but are capable of forming adhesive compositions when compounded with components such as plasticizers, or tackifiers. Specific examples include poly-alpha-olefins (e.g., polyoctene, polyhexene, and atactic polypropylene), block copolymer-based adhesives, natural and synthetic rubbers, silicone adhesives, ethylene-vinyl acetate, and epoxy -containing structural adhesive blends (e.g., epoxy-acrylate and epoxy-polyester blends).

The adhesive layer 12 may also optionally have other components in it. Normal additives such as, for example, fillers, antioxidants, viscosity modifiers, pigments, tackifying resins, fibers, and the like can also be added to the adhesive layer 12, to the extent that they do not alter the desired properties of the final product.

A preferred optional additive is a pigment, or a light blocking fillers. Any compound generally used as a pigment can be utilized, as long as the desired properties of the final product are not altered thereby. Exemplary pigments include carbon black and titanium dioxide. The amount of pigment also depends on the desired use of the product. Generally, the concentration of pigment is greater than 0.10% by weight. Preferably, the concentration of pigment is greater than 0.15% by weight, and more preferably greater than 0.18% by weight to give the adhesive layer 12 an opaque color.

The thickness of the adhesive layer 12 varies depending on the use of the product. In the case of certain foam adhesive products, preferably the thickness of adhesive layer 12 is greater than 250 microns. More preferably, the thickness is greater than 500 microns. In the case of a single layer of non-foamed transfer adhesive, the adhesive layer preferably has a thickness of 2 to 5 mils (51 to 127 microns), although other thicknesses may also be used.

The adhesive layer 12 utilized in the invention is at least partially crosslinked by electron beam ("E-beam") radiation, although additional crosslinking means (e.g., chemical, heat, gamma radiation, and/or ultraviolet and/or visible radiation) may also be used. The adhesive layer 12 is crosslinked to impart more desirable characteristics (e.g., increased strength) to the double-sided adhesive tape 10. One method of crosslinking is using electron-beam radiation. E-Beam radiation is advantageous because it can crosslink polymers that other methods cannot, such as highly pigmented adhesives, adhesives with fillers, and relatively thick layers of adhesives.

E-Beam radiation causes crosslinking of the adhesive layer by initiating a free-radical chain reaction. Ionizing particulate radiation from the E-Beam is absorbed directly in the polymer and generates free radicals that initiate the crosslinking process. Generally, electron energies of at least about 100 kiloelectron volts (keV) are necessary to break chemical bonds and ionize, or excite, components of the polymer system. The scattered electrons that are produced lead to a large population of free radicals dispersed throughout the adhesive. These free radicals initiate crosslinking reactions (e.g., free-radical polymerization, radical-radical coupling), which results in a three-dimensionally crosslinked polymer.

An E-Beam processing unit supplies the radiation for this process. Generally, a processing unit includes a power supply and an E-Beam acceleration tube. The power supply increases and rectifies the current, and the accelerator generates and focuses the E-Beam and controls the scanning. The E-Beam may be produced, for example, by energizing a tungsten filament with high voltage. This causes electrons to be produced at high rates. These electrons are then concentrated to form a high energy beam and are accelerated to full velocity inside the electron gun. Electromagnets on the sides of the accelerator tube allow deflection, or scanning, of the beam.

Scanning widths and depths typically vary from about 61-183 centimeters (cm) to about 10-15 cm, respectively. The scanner opening is covered with a thin metal foil, usually titanium, which allows passage of electrons, but maintains a high vacuum in the processing chamber.

Characteristic power, current, and dose rates of accelerators are about 200-500 keV, about 25-200 milliamps (mA), and about 1-10 megarads (Mrads), respectively. To minimize peroxide formation, the process chamber should be kept at as low an oxygen content as is practical, for example, by nitrogen purging, although this is not a requirement.

After e-beam treatment the resultant double-sided adhesive tape can be wound into a roll, e.g., as shown in FIG. 3. Further converting steps such as, for example, slitting and/or packaging may also be carried out at this point.

SELECT EMBODIMENTS OF THE PRESENT DISCLOSURE

In a first embodiment, the present disclosure provides a method of making an adhesive article, the method comprising:

exposing at least the adhesive layer to electron beam radiation within a process chamber thereby providing a crosslinked adhesive layer, wherein the process chamber contains oxygen, wherein the second silicone release layer is exposed to the oxygen during crosslinking of the adhesive layer.

In a second embodiment, the present disclosure provides a method according to the first embodiment, wherein the inert flowable silicone has a number average molecular weight between 1000 grams/mole and 20,000 grams/mole. In a third embodiment, the present disclosure provides a method according to the first embodiment, wherein the inert flowable silicone has a number average molecular weight of less than or equal to 50000 grams/mole.

In a fourth embodiment, the present disclosure provides a method according to any one of the first to third embodiments, wherein the electron beam radiation is directed from opposing directions at both the adhesive layer and the second silicone release layer, respectively.

In a fifth embodiment, the present disclosure provides a method according to any one of the first to fourth embodiments, further comprising winding the crosslinked adhesive layer onto the second silicone release layer.

In a sixth embodiment, the present disclosure provides a method according to any one of the first to fifth embodiments, wherein the second silicone release layer comprises an addition cured silicone.

In a seventh embodiment, the present disclosure provides a method according to any one of the first to sixth embodiments, wherein the second silicone release layer comprises from 5 to 10 percent by weight of the inert flowable silicone.

In an eighth embodiment, the present disclosure provides an adhesive article prepared according to a method of any one of the first to seventh embodiments.

Objects and advantages of this disclosure are further illustrated by the following non- limiting examples, but the particular materials and amounts thereof recited in these examples, as well as other conditions and details, should not be construed to unduly limit this disclosure.

EXAMPLES

Unless otherwise noted, all parts, percentages, ratios, etc. in the Examples and the rest of the specification are by weight. Unless otherwise indicated, materials used in the examples available from commercial suppliers (e.g., Aldrich Chemical Co., Milwaukee, Wisconsin) and/or can be made by known methods.

TABLE OF MATERIALS USED IN THE EXAMPLES

Silicone Additive 1 A trimethylsiloxy terminated polydimethylsiloxane, having a viscosity of 10 centiStokes and a molecular weight of 1250 grams/mole, available under the product code DMS-T1 1 from Gelest, Morrisville, PA.

Silicone Additive 2 A trimethylsiloxy terminated polydimethylsiloxane, having a viscosity of 20 centiStokes and a molecular weight of 2000 grams/mole, available under the product code DMS-T12 from Gelest, Morrisville, PA.

Silicone Additive 3 A trimethylsiloxy terminated polydimethylsiloxane, having a viscosity of 50 centiStokes and a molecular weight of 3780 grams/mole, available under the product code DMS-T15 from Gelest, Morrisville, PA.

Silicone Additive 4 A trimethylsiloxy terminated polydimethylsiloxane, having a viscosity of 200 centiStokes and a molecular weight of 9430 grams/mole, available under the product code DMS-T22 from Gelest, Morrisville, PA.

Silicone Additive 5 A trimethylsiloxy terminated polydimethylsiloxane, having a viscosity of 350 centiStokes and a molecular weight of 13,650 grams/mole, available under the product code DMS-T23 from Gelest, Morrisville, PA.

Silicone Additive 6 A trimethylsiloxy terminated polydimethylsiloxane, having a viscosity of 60,000 centiStokes and a molecular weight of 1 16,000 grams/mole, available under the product code DMS-T46 from Gelest, Morrisville, PA.

HFSX A liquid, hydride functional polysiloxane crosslinker component, 100% solids and having a viscosity at 25 °C of 30 centiStokes, available under the trade designation SYL-OFF 7678 CROSSLINKER from Dow Corning Corporation, Midland, MI.

IOA Isooctyl acrylate

AA Acrylic acid

FORAL 85 A tackifier resin, the glycerol ester of highly hydrogenated refined wood rosin having a softening point of 80 to 86 °C and an acid number of between 3 and 10 milligrams KOH / gram resin, available under the trade designation FORAL

85 from Pinova Incorporated, Brunswick, GA.

Primed Polyester Film A polyester film having a thickness of 51 micrometers

(0.002 inches) and being primed on one side, available under the trade designation HOSTAPHAN 3 SAB from

Mitsubishi Polyester Film Incorporated, Greer, SC.

TEST METHODS

COATING WEIGHT DETERMINATION

The coating weight of silicone release coatings was determined using a Lab X 3000 XRF Spectrometer (Oxford Instruments, Elk Grove Village, Illinois) to measure the silicone coat weight compared to polydimethylsiloxane (PDMS) coated polyester film standards of known coat weights. Results are reported in grams per square meter (gsm).

EXTENT OF CURE BY EXTRACTION METHOD

The weight percent (%) extractable silicone in the release coating, which can be taken as an indicator of the extent of cure, was determined by calculating the % change in the silicone release coating weight before and after extraction with methyl isobutyl ketone (MIBK) for five minutes. The silicone release coating weights were determined by X-Ray fluorescence spectrometry as described above. The % extractable silicone was calculated as follows:

[(a-b)/a]* 100 = % extractables

where a = initial coating before extraction with MIBK; and b = final coating after extraction with MIBK.

RELEASE FORCE OF ADHESIVE TEST TAPE FROM RELEASE LINER

The release force between the release liner and the Adhesive Test Tape of a laminate construction was measured using a 180-degree peel geometry according to the manufacturer's instructions as follows. An IMASS SP 2100 peel force tester (IMASS, Incorporated, Accord, Massachusetts) equipped with a 5.0-pound (2.27-kilogram () load cell was employed using the following parameters: a 1 inch (2.54 centimeters) wide test specimen, a peel rate of 90 inches/minute (229 centimeters/minute), a two second delay before data acquisition, and a five second averaging time. The average of two test specimens was reported in grams/inches. Testing was done according to the following conditions.

A) Seven days at 22 °C (72 °F) and 50% Relative Humidity B) Seven days at 50 °C, followed by an equilibration at 22 °C (72 °F) and 50% Relative Humidity for a minimum of 24 hours before testing.

PEEL ADHESION STRENGTH OF ADHESIVE TEST TAPE

The peel adhesion strength of the Adhesive Test Tape from a glass panel was measured at 72 °F (22 °C) and 50% Relative Humidity, and was designated as Peel Adhesion Strength 1. In addition, a second sample of the Adhesive Test Tape was first laminated to the release liner such that it contacted the release coating layer and exposed to various conditions as noted in the Release Force of Adhesive Test Tape from Release Liner test method, then evaluated for release force. Upon removal of the Adhesive Test Tape from the release liner the Tape was evaluated for its Peel Adhesion Strength as before, with this result being designated as Peel Adhesion Strength 2.

Testing was done immediately after removal of the Adhesive Test Tape from the release liner (within one minute) and applying the test tape to a clean glass plate using a 5 lb (2.3 kg) roller. An IMASS SP 2100 Slip/Peel Tester (IMASS, Incorporated, Accord, Massachusetts) equipped with a 10 pound (4.54 kg) load cell was employed using the following parameters: one inch (2.54 cm) wide test specimen, peel rate of 90 inches/minute (229 cm/min), two second delay before data acquisition, 180 peel geometry, and a ten second averaging time. The average of two test specimens was reported in grams/inches (g/cm).

ADHESIVE TEST TAPE PREPARATION

The following components were mixed together: 95 parts IOA and 5 parts AA. A plastic pouch (ethylene -vinyl acetate copolymer) was filled with this mixture, sealed shut, and the filled pouch was exposed to a UV-A irradiation using a blacklight to completely polymerize the adhesive. The pouch and contents were then fed into a counter-rotating 34 millimeter twin-screw extruder (Leistritz, Somerset, New Jersey) at 149 °C (300 °F). About 33 parts of FORAL 85 per hundred parts adhesive pouch were also added to the extruder. The resulting composition was hot melt coated onto the silicone treated surface of an olefin liner, exposed to electron beam (E-beam) irradiation (9 MegaRads dosage at a voltage of 210 kiloelectron volts) to crosslink the adhesive, then covered with a second, treated olefin liner. The glass transition temperature (Tg) of the resulting adhesive was 19 °C. Later, the resulting article was used to transfer laminate the adhesive layer to Primed Polyester Film on its primed surface to provide a single coated Adhesive Test Tape without any protective cover film. EXAMPLES 1-3

The following were added to ajar and mixed to give a homogeneous solution: 39 grams VTSP, 0.99 grams of HFSX at a hydride: vinyl ratio of 1.2: 1, 113 grams of Heptane, 28 grams of Methyl Ethyl Ketone and either 2 grams (5 weight percent) or 4 grams (10 weight percent) or 8 grams (20 weight percent) of SAl . The solutions were coated at 22 weight percent solids onto the primed side of Primed Polyester Film using a #8 Meyer Rod. The silicone coating was then cured in an oven at 120 °C for 2 minutes. Coating weights of approximately 2.0 grams/square meter were obtained. The coated, cured release liners thus obtained were stored for one week at 22 °C (72 °F) and 50% relative humidity) before exposure to electron beam (E-beam) irradiation.

Next, the coated, cured release liners were exposed to E-beam radiation on the side having the release coating composition which contained Silicone Additive 1 (SAl). An

ELECTROCURTAIN CB-300 e-beam unit (Energy Sciences Incorporated, Wilmington,

Massachusetts) was employed, the accelerating voltage was 210 kiloelectron volts, and a dose of 9 megaRads was provided. The oxygen concentration in the nitrogen-inerted E-beam chamber was maintained between 8-15 ppm oxygen as measured by an Alpha Omega Series 3000 Trace Oxygen Analyzer (Alpha Omega Instruments Corporation, Lincoln, Rhode Island). The E-beam treated release liner was then immediately (within 30 seconds) laminated to the Adhesive Test Tape by hand using a rubber roller to ensure intimate contact. In this way, the adhesive of the Adhesive Test Tape was in direct contact with the cured, E-beam treated release coating of the release liner. The resulting laminate construction was then evaluated for release force, as well as the peel adhesion strength of the Adhesive Test Tape both before lamination, and after lamination to the release liner followed by conditioning, as described in the test methods above.

EXAMPLES 4-6

Examples 1-3 were repeated with the following modification. Silicone Additive 2

(SA2) was used in place of Silicone Additive 1.

EXAMPLES 7-9

Examples 1-3 were repeated with the following modification. Silicone Additive 3 (SA3) was used in place of Silicone Additive 1.

EXAMPLES 10-12

Examples 1-3 were repeated with the following modification. Silicone Additive 4 (SA4) was used in place of Silicone Additive 1. EXAMPLES 13-15

Examples 1-3 were repeated with the following modification. Silicone Additive 5 (SA5) was used in place of Silicone Additive 1.

COMPARATIVE EXAMPLE A

Example 1 was repeated with the following modification. Silicone Additive 1 was not used.

COMPARATIVE EXAMPLES B 1-B3

Examples 1-3 were repeated with the following modification. Silicone Additive 6 (SA6) was used in place of Silicone Additive 1.

Examples 1-15, Comparative Example A, and Comparative Examples B1-B3 were tested according to the RELEASE FORCE OF ADHESIVE TEST TAPE FROM

RELEASE LINER and PEEL ADHESION STRENGTH OF ADHESIVE TEST TAPE procedures. Results are reported in Table 1, below. Peel Adhesion Strength 1 of the test tape from glass was 2852 grams/inch (1123 g/cm).

TABLE 1

All cited references, patents, and patent applications in the above application for letters patent are herein incorporated by reference in their entirety in a consistent manner. In the event of inconsistencies or contradictions between portions of the incorporated references and this application, the information in the preceding description shall control. The preceding description, given in order to enable one of ordinary skill in the art to practice the claimed disclosure, is not to be construed as limiting the scope of the disclosure, which is defined by the claims and all equivalents thereto.

Claims

What is claimed is:

I , A method of making an adhesive article, the method comprising:

providing a becking having first and second opposed major surface;, wherein a first silicone release layer is disposed on the first major surface, wherein a second silicone release layer is disposed on the second major surfaee, wherein the second silicone release layer comprises an at least partially crosslinked silicone and from 5 to 20 percent by weight of inert flowable silicone, based on the total weight of the first silicone release layer, and wherein the inert flowable silicone has a number average molecular weight between 1000 grams/mole and 100,000 grams/mole;

disposing an adhesive layer onto the first silicone release layer; and

exposing at least the adhesive layer to electron beam radiation within a process chamber thereby providing a crosslinked adhesive layer, wherein the process chamber contains oxygen, wherein the second silicone release layer is exposed to the oxygen during crosslinklng of the adhesive layer.

2, The method of claim 1, wherein the inert flowable silicone has a number average molecular weight between 1000 grams/mole and 20,000 grams/mole.

3. The method of claim 1, wherein the electron beam radiation Is directed from opposing directions at both the adhesive layer and the second silicone release layer, respectively,

4. The method of claim 1, further comprising winding the crosslinked adhesive layer onto the second silicone release layer.

5. The method of claim 1, wherein the second silicone release layer comprises an addition cured silicone.

6. The method of claim 1, wherein the second silicone release layer comprises from 5 to 20 percent by weight of the inert flowable silicone,

7. An adhesive article mude according to the method of claim 1.