WO2017059674A1 - Energy-saving environmentally-friendly electric radiator - Google Patents

Energy-saving environmentally-friendly electric radiator Download PDF

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Publication number
WO2017059674A1
WO2017059674A1 PCT/CN2016/081627 CN2016081627W WO2017059674A1 WO 2017059674 A1 WO2017059674 A1 WO 2017059674A1 CN 2016081627 W CN2016081627 W CN 2016081627W WO 2017059674 A1 WO2017059674 A1 WO 2017059674A1
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metal
composite component
heat
reactor
energy
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PCT/CN2016/081627
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French (fr)
Chinese (zh)
Inventor
陈有孝
黄友权
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兴盛达元（天津）科技股份有限公司
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Publication of WO2017059674A1 publication Critical patent/WO2017059674A1/en

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D13/00—Electric heating systems
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Definitions

  • the invention belongs to the technical field of building heating, and particularly relates to an energy-saving and environmental protection electric radiator.
  • the energy consumption of buildings accounts for 50% of the world's total energy consumption.
  • the energy consumption for heating buildings accounts for 60% of the building's energy consumption, and the building heating consumes 30% of the world's total energy consumption.
  • reducing the energy consumption of building heating is of paramount importance.
  • Heating of buildings, developed countries generally use electricity and natural gas.
  • burning natural gas heating also produces a large amount of carbon emissions, and the pollution to the environment is very serious.
  • Coal-fired heating is commonly used in developing countries. The pollution caused by coal-fired heating is even more serious.
  • small boiler heating produces a large amount of carbides, nitrogen oxides, sulfides, cinders and soot that are very polluting to the environment.
  • Electric heating is a clean heating method.
  • the input power per square meter is 100W ⁇ 120W. It is expensive to use and unacceptable to developing countries.
  • the object of the present invention is to solve the problem that the electric power consumption of the existing electric heating equipment is too large, and to provide an energy-saving and environmental protection electric radiator.
  • the energy-saving and environmentally-friendly electric radiator proposed by the invention has an input power of 15 to 25 W per square meter in a standard building of a country and a country of the same dimension, and is 75 to 85% more energy efficient than an ordinary electric heater.
  • the energy-saving and environmental protection electric radiator comprises a heat dissipating body, an electric heating tube in the heat dissipating body and a heat generating substance, and the composition and the weight percentage of the heat generating substance are: 42 to 85% of the composite component A, 6 to 25%.
  • the preparation method of the heat generating substance is as follows:
  • the reaction kettle Lower mouth product The composite component A is prepared; the activation of the composite component A: the reactor is purified by an air purifier, and the carbon dioxide, carbon monoxide and the like in the air in the reactor are removed; 100 kg of the composite component A is injected into a high temperature and high pressure of 25000 L.
  • the reactor was heated to 460 ° C, an oxygen molecular sieve was installed on the reactor, and the reactor was evacuated to 500 Pa through an oxygen molecular sieve.
  • the rare earth metal was sawn into chips, 100Kg of metal ruthenium and 140Kg of naphthalene were placed in a dry, argon-substituted reactor, and evacuated to 500 Pa for 40 minutes to remove the adsorbed air from the surface of the naphthalene and anthracene.
  • the other volatiles were added with 2000 mol of THF (tetrahydrofuran) under argon atmosphere, and stirred for 50 hours with 50 mol of TiCl 4 , and then the black solution was taken out, placed under a argon atmosphere, and placed in a vacuum vessel, and the entire system was continuously evacuated.
  • the most THF solvent is removed, heated to 220 ° C, and the super-active metal ruthenium powder remaining in the reactor is taken out and stored in kerosene.
  • the super-active metal strontium is added according to the ratio. powder;
  • the PTFE powder was injected into a 100-cubic-meter high-temperature vacuum coating machine, heated to 1520 ° C, PTFE gasification, 100 g of argon gas was introduced into the vacuum coating machine per 500 g of PTFE powder, and reacted for 40 minutes to adjust the temperature of the vacuum coating machine.
  • PTFE is solidified at room temperature;
  • PTFE emulsion is prepared by emulsification of conventional PTFE;
  • the activated composite component A, the superactive metal ruthenium powder, the metal sodium, the PTFE emulsion prepared by the first to the third steps, and the diethylaluminum dichloride and the 1200 mesh molybdenum disulfide are mixed according to the ratio, and then placed.
  • the mixture was heated to 200 ° C in a vacuum high-speed mixer, evacuated to 500 Pa, stirred for 10 hours, and thoroughly mixed to obtain the above-mentioned heat generating substance.
  • the heat dissipating body is formed by welding a set of aluminum alloy fins with two upper and lower header tubes.
  • a ⁇ 15-30 mm hole is pressed into the middle of the aluminum alloy fins.
  • the two ends of the copper pipe or steel pipe are respectively inserted into the upper and lower header pipes and kept in communication. Both ends of the upper header pipe are welded and sealed by copper plate or steel plate; one end of the lower header pipe is welded with an injection pipe for injecting a heat generating substance, and the other end of the lower header pipe is internally fixed with an electric heating pipe.
  • the energy-saving and environmental protection electric radiator of the invention has an input power of 15 to 25 W per square meter in a standard building of a country and a country of the same dimension, and is 75 to 85% more energy-efficient than an ordinary electric heater.
  • the energy-saving and environmental protection electric radiator comprises a heat dissipating body, an electric heating tube in the heat dissipating body and a heat generating substance, and the composition and the weight percentage of the heat generating substance are: 42 to 85% of the composite component A, 6 to 25%.
  • the preparation method of the heat generating substance is as follows:
  • the reaction kettle The product of the lower mouth is taken out to form a composite component A; the activation of the composite component A: the reactor is purified by an air purifier, and carbon dioxide, carbon monoxide and the like in the air in the reaction vessel are removed; 100 kg of the composite component A is injected.
  • the reactor was heated to 460 ° C, an oxygen molecular sieve was installed on the reactor, and the reactor was evacuated to 500 Pa through an oxygen molecular sieve. After a constant temperature of 60 minutes, the reactor was injected into the kettle. 10Kg argon, the reactor is maintained at 500 ⁇ 1000 Pa, after 30 minutes, gradually reduce the reactor to room temperature, to obtain activated composite component A;
  • the rare earth metal was sawn into a crumb shape, and TiCl 4 was used as a catalyst.
  • 100 Kg of metal ruthenium and 140 Kg of naphthalene were placed in a dry, argon-substituted reaction vessel, and evacuated to 500 Pa for 40 minutes to remove naphthalene.
  • the adsorption air and other volatiles on the surface of the crucible were added with 2000 mol of THF (tetrahydrofuran) under argon atmosphere, and the reaction was stirred for 3 hours after 50 mol of TiCl 4 .
  • the black solution was taken out and placed under vacuum protection.
  • the PTFE powder was injected into a 100-cubic-meter high-temperature vacuum coating machine, heated to 1520 ° C, PTFE gasification, 100 g of argon gas was introduced into the vacuum coating machine per 500 g of PTFE powder, and reacted for 40 minutes to adjust the temperature of the vacuum coating machine.
  • PTFE is solidified at room temperature;
  • PTFE emulsion is prepared by emulsification of conventional PTFE;
  • the heat dissipating body of the invention is formed by welding a set of aluminum alloy fins with two upper and lower header tubes.
  • a press is used in the hole of the 15 ⁇ 30 mm in the middle of the aluminum alloy fins. Press into a ⁇ 15 ⁇ 30mm, A copper pipe or a steel pipe having a wall thickness of 1 to 2 mm. If a copper pipe is pressed in, the copper pipe is expanded by a water press to obtain good contact between the copper pipe and the aluminum alloy piece. If it is a steel pipe, the outer diameter of the steel pipe is required to be slightly larger than the size of the aluminum alloy hole to make it fit tightly and maintain good contact.
  • a set of holes is drilled on the upper and lower header pipes by the drill bit.
  • the diameter of the holes is the same as the diameter of the copper pipe or the steel pipe.
  • the copper pipe or the steel pipe is inserted into the hole of the upper and lower header pipes, and the copper pipe or the steel pipe is welded by the argon arc welding.
  • the copper pipe or the steel pipe is kept in communication with the upper and lower header pipes.
  • the two ends of the upper header tube are welded and sealed with a copper plate having a thickness of 2 to 3 mm and a diameter equal to that of the header tube.
  • One end of the lower header pipe is welded and sealed with a copper plate or steel plate having the same diameter as the header pipe, and the lower header pipe is welded and sealed at the center of the copper plate or steel plate.
  • a copper hole of 4 mm is welded to the center of the copper plate or steel plate.
  • the injection tube is used to inject a heat generating substance into the heat sink.
  • An electric heating tube is fixed inside the other end of the lower header tube, and the input power of the electric heating tube is 100-800W.
  • the heat sink is injected into the heat sink by a copper tube of 4 mm: 10.00 to 2000.00 g of the heat generating substance.
  • the 75 ⁇ 75 aluminum alloy profile is selected.
  • the inner diameter of the aluminum profile is mm20mm, the length is 1420mm, and the length is 1420mm.
  • a copper tube with a length of 1480mm, ⁇ 20mm and a wall thickness of 1.0mm is inserted by a press. The machine makes the copper tube and the aluminum profile closely match.
  • Two copper pipes of 35 mm in thickness, 1.5 mm in wall thickness and 500 mm in length were selected as the upper and lower header pipes; 6 holes of 20.2 mm were drilled with the drill bit on the pipe.
  • the two ends of one header tube are welded and sealed as a top header tube by a copper plate of 35 mm and a thickness of 2 mm. ⁇ 35mm, 2mm thick copper plate, a ⁇ 4.1mm hole is welded in the middle to weld a ⁇ 4mm copper tube with a thickness of 1mm, welded to one end of another ⁇ 35mm copper tube, and the other end is internally fixed with a 600W electric Heat the tube; inject 680 g of heat-generating material into the heat sink from the ⁇ 4 mm copper tube.
  • the composition and weight percentage of the heat-generating composition of the present embodiment are: 70% composite component A+2% metal lanthanum +15% metal sodium + 6% PTFE emulsion + 3% monochlorodiethylaluminum + 4% 1200 mesh Molybdenum disulfide.
  • the heat sink starts to work. After 15 minutes, the surface temperature of the aluminum alloy reaches 58-62 °C.
  • the heat sink has a heat dissipation of 1392W and a thermal efficiency of 232%.
  • the radiator is an energy-saving and environmentally-friendly electric radiator.
  • composition of the exothermic composition of this example is: 42% of composite component A + 25% of PTFE emulsion + 2% of metal strontium + 18% of metallic sodium + 5% of dichlorodiethylaluminum + 8% Molybdenum disulfide.
  • the preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
  • composition of the exothermic composition of this example is: 80% A + 5% PTFE emulsion + 1% metal ruthenium + 7% metal sodium + 3% monochlorodiethyl aluminum + 4% molybdenum disulfide .
  • the preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
  • composition of the exothermic composition of this example is: 60% A+18% PTFE emulsion + 1.5% metal lanthanum + 13.5% metal sodium + 3% monochlorodiethylaluminum + 4% molybdenum disulfide.
  • the preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
  • composition of the exothermic composition of this example is: 73% A+6% PTFE emulsion + 2% metal ruthenium + 11% sodium metal + 4% diethylaluminum dichloride + 4% molybdenum disulfide .
  • the preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
  • composition of the exothermic composition of this example is: 77% A+5% PTFE emulsion + 2% metal ruthenium + 9% metal sodium + 3% monochlorodiethylaluminum + 4% molybdenum disulfide .
  • the preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
  • composition of the exothermic composition of this example is: 53% A+20% PTFE emulsion + 2% metal ⁇ +15% metal sodium + 5% monochlorodiethylaluminum + 5% molybdenum disulfide .
  • the preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
  • composition of the exothermic composition of this example is: 63% A+15% PTFE emulsion + 1% metal ruthenium + 14% sodium metal + 3% monochlorodiethylaluminum + 4% molybdenum disulfide .
  • the preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
  • composition of the exothermic composition of this example is: 73% A+6% PTFE emulsion + 2% metal ruthenium + 12% metal sodium + 3% monochlorodiethylaluminum + 4% molybdenum disulfide .
  • the preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
  • composition of the exothermic composition of this example is: 72% A + 6% PTFE emulsion + 2% metal ruthenium + 12% sodium metal + 4% dichlorodiethylaluminum + 4% molybdenum disulfide .
  • the preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.

Abstract

An energy-saving environmentally-friendly electric radiator, comprising a heat dissipating body, and an electric heating pipe and a heat-emitting substance in the heat dissipating body. The composition and weight percentages of the heat-emitting substance are: 42-85% of a composite component A, 6-25% of a PTFE emulsion, 1-2% of cerium metal, 1-18% of sodium metal, 3-5% of diethylaluminium chloride, and 4-8% of 1200 mesh molybdenum disulfide, wherein the composition and weight percentages of the composite component A are: 7-12% of peracetic acid, 45-48% of allyl alcohol and 43-45% of ethyl acetate. The energy-saving environmentally-friendly electric radiator can achieve an electrothermal conversion efficiency of 232%, and can supply heat to buildings in high-latitude countries in winter.

Description

节能环保电散热器Energy saving and environmental protection electric radiator 技术领域Technical field
本发明属于建筑物供暖技术领域，特别涉及一种节能环保电散热器。The invention belongs to the technical field of building heating, and particularly relates to an energy-saving and environmental protection electric radiator.
背景技术Background technique
建筑物的能源消耗占到世界能源总消耗的50％。为建筑物供暖的能源消耗占到建筑物能源消耗的60％，建筑物供暖消耗占到世界总能源消耗的30％，为此，降低建筑物供暖的能源消耗有着极为重要的意义。建筑物供暖，世界发达国家一般采用电和天然气。然而，燃烧天然气供暖也会产生大量的碳排放，对环境的污染是很严重的。发展中国家普遍采用的是燃煤供暖。燃煤供暖的污染严重就更加严重了。尤其是小型锅炉供暖产生大量的碳化物、氮氧化物、硫化物、煤渣和烟尘对环境的污染相当严重。电采暖是清洁的供暖方式，由于目前电采暖设备的用电量太大，如意大利的迪伦、德国的西门子、美国的通用、日本的松下牌电采暖器供暖每平米输入功率要100W～120W，造成使用费用昂贵，对于发展中国家难以接受。The energy consumption of buildings accounts for 50% of the world's total energy consumption. The energy consumption for heating buildings accounts for 60% of the building's energy consumption, and the building heating consumes 30% of the world's total energy consumption. To this end, reducing the energy consumption of building heating is of paramount importance. Heating of buildings, developed countries generally use electricity and natural gas. However, burning natural gas heating also produces a large amount of carbon emissions, and the pollution to the environment is very serious. Coal-fired heating is commonly used in developing countries. The pollution caused by coal-fired heating is even more serious. In particular, small boiler heating produces a large amount of carbides, nitrogen oxides, sulfides, cinders and soot that are very polluting to the environment. Electric heating is a clean heating method. Because the current electricity consumption of electric heating equipment is too large, such as Dylan of Italy, Siemens of Germany, GM of the United States, and Matsushita Electric Heater of Japan, the input power per square meter is 100W~120W. It is expensive to use and unacceptable to developing countries.
发明内容Summary of the invention
本发明目的是解决现有电采暖设备用电量太大的问题，提供一种节能环保电散热器。本发明提出的节能环保电散热器在中国和相同维度的国家的标准建筑物供暖的输入功率为每平米15～25W，比普通的电采暖器节能75～85％。The object of the present invention is to solve the problem that the electric power consumption of the existing electric heating equipment is too large, and to provide an energy-saving and environmental protection electric radiator. The energy-saving and environmentally-friendly electric radiator proposed by the invention has an input power of 15 to 25 W per square meter in a standard building of a country and a country of the same dimension, and is 75 to 85% more energy efficient than an ordinary electric heater.
本发明提供的节能环保电散热器，包括散热体、散热体内的电加热管和发热物质，所述发热物质的组成及重量百分比为：42～85％的复合组分A，6～25％的PTFE乳液，1～2％的金属铈，1～18％的金属钠，3～5％的一氯二乙基铝和4～8％的1200目二硫化钼；其中复合组分A的组成及重量百分比为：7～12％的过氧乙酸，45～48％稀丙醇和43～45％的乙酸乙酯。The energy-saving and environmental protection electric radiator provided by the invention comprises a heat dissipating body, an electric heating tube in the heat dissipating body and a heat generating substance, and the composition and the weight percentage of the heat generating substance are: 42 to 85% of the composite component A, 6 to 25%. PTFE emulsion, 1-2% metal ruthenium, 1-18% metal sodium, 3 to 5% diethylaluminum dichloride and 4 to 8% 1200 mesh molybdenum disulfide; wherein the composition of composite component A and The weight percentages are: 7 to 12% peracetic acid, 45 to 48% dilute propanol and 43 to 45% ethyl acetate.
所述发热物质的制备方法如下：The preparation method of the heat generating substance is as follows:
第1、活化复合组分A的制备Preparation of the first and activated composite component A
将过氧乙酸、稀丙醇和乙酸乙酯三种物质按照所述比例加入真空反应釜中，调整反应釜内压力为10～30千帕，温度60～80度，反应时间40分钟，将反应釜下口的生成物取 出，制成复合组分A；复合组分A的活化：采用空气净化器将反应釜净化，除去反应釜内空气中的二氧化碳，一氧化碳等杂质；将100kg复合组分A注入一个25000L的高温高压真空反应釜中，给反应釜升温至460℃，在反应釜上安装一个氧分子筛，通过氧分子筛将反应釜抽真空至500帕，恒温60分钟后，向釜内注入2～10Kg氩气，使反应釜内保持在500～600帕，30分钟后，逐渐使反应釜降到室温，得到活化的复合组分A；Adding three substances of peracetic acid, dilute propanol and ethyl acetate to the vacuum reactor according to the above ratio, adjusting the pressure in the reactor to 10-30 kPa, the temperature of 60-80 degrees, and the reaction time of 40 minutes, the reaction kettle Lower mouth product The composite component A is prepared; the activation of the composite component A: the reactor is purified by an air purifier, and the carbon dioxide, carbon monoxide and the like in the air in the reactor are removed; 100 kg of the composite component A is injected into a high temperature and high pressure of 25000 L. In a vacuum reactor, the reactor was heated to 460 ° C, an oxygen molecular sieve was installed on the reactor, and the reactor was evacuated to 500 Pa through an oxygen molecular sieve. After a constant temperature of 60 minutes, 2 to 10 kg of argon gas was injected into the kettle to make argon gas into the kettle. The reactor is maintained at 500 to 600 Pa, after 30 minutes, the reactor is gradually lowered to room temperature to obtain an activated composite component A;
第2、超活性金属铈粉末的制备Preparation of the second and super active metal ruthenium powder
将稀土金属铈锯成屑状，将100Kg金属铈和140Kg萘放入已经干燥的，用氩气置换过的反应釜中，抽真空到500帕，40分钟，除去萘和铈表面的吸附空气和其它挥发物，在氩气保护下加入2000摩尔THF(四氢呋喃)，50摩尔TiCl4搅拌反应3小时后将黑色的溶液取出，在氩气保护下，放入真空容器，连续对整个体系抽真空，使绝大部分THF溶剂抽走，加热至220℃萘全面升华抽走，取出留在反应器中的超活性金属铈粉末，并放入煤油中保存，使用时按照所述比例加入超活性金属铈粉；The rare earth metal was sawn into chips, 100Kg of metal ruthenium and 140Kg of naphthalene were placed in a dry, argon-substituted reactor, and evacuated to 500 Pa for 40 minutes to remove the adsorbed air from the surface of the naphthalene and anthracene. The other volatiles were added with 2000 mol of THF (tetrahydrofuran) under argon atmosphere, and stirred for 50 hours with 50 mol of TiCl 4 , and then the black solution was taken out, placed under a argon atmosphere, and placed in a vacuum vessel, and the entire system was continuously evacuated. The most THF solvent is removed, heated to 220 ° C, and the super-active metal ruthenium powder remaining in the reactor is taken out and stored in kerosene. When used, the super-active metal strontium is added according to the ratio. powder;
第3、PTFE乳液的制备Third, the preparation of PTFE emulsion
将PTFE粉末注入100立方米的高温真空镀膜机中，加温至1520℃，PTFE气化，按照每500gPTFE粉末向真空镀膜机中通入100克氩气，反应40分钟，将真空镀膜机的温度降至室温，PTFE凝固；用常规PTFE的乳化法制成PTFE乳液；The PTFE powder was injected into a 100-cubic-meter high-temperature vacuum coating machine, heated to 1520 ° C, PTFE gasification, 100 g of argon gas was introduced into the vacuum coating machine per 500 g of PTFE powder, and reacted for 40 minutes to adjust the temperature of the vacuum coating machine. PTFE is solidified at room temperature; PTFE emulsion is prepared by emulsification of conventional PTFE;
第4、将第1至第3步制备的活化复合组分A、超活性金属铈粉末、金属钠、PTFE乳液，以及一氯二乙基铝和1200目二硫化钼按照所述比例混合后放入真空高速搅拌机中，升温到200℃，抽真空到500帕，搅拌10小时，使其充分混合后制得所述的发热物质。4. The activated composite component A, the superactive metal ruthenium powder, the metal sodium, the PTFE emulsion prepared by the first to the third steps, and the diethylaluminum dichloride and the 1200 mesh molybdenum disulfide are mixed according to the ratio, and then placed. The mixture was heated to 200 ° C in a vacuum high-speed mixer, evacuated to 500 Pa, stirred for 10 hours, and thoroughly mixed to obtain the above-mentioned heat generating substance.
所述散热体由一组铝合金散热片用上下两根联箱管焊接而成，为增加铝合金散热片的强度，在铝合金散热片中间的￠15～30mm的孔内压进一根￠15～30mm，壁厚为1～2mm的铜管或钢管，使铜管或钢管与铝合金散热片紧密配合，所述铜管或钢管的两端分别***上下两根联箱管内并保持联通，上联箱管的两端用铜板或钢板焊接密封；下联箱管的一端焊接一根用于注入发热物质的注入管，下联箱管的另一端内部固定一根电加热管。The heat dissipating body is formed by welding a set of aluminum alloy fins with two upper and lower header tubes. In order to increase the strength of the aluminum alloy fins, a ¢ 15-30 mm hole is pressed into the middle of the aluminum alloy fins. 15~30mm, copper pipe or steel pipe with a wall thickness of 1-2mm, so that the copper pipe or steel pipe is closely matched with the aluminum alloy fin. The two ends of the copper pipe or steel pipe are respectively inserted into the upper and lower header pipes and kept in communication. Both ends of the upper header pipe are welded and sealed by copper plate or steel plate; one end of the lower header pipe is welded with an injection pipe for injecting a heat generating substance, and the other end of the lower header pipe is internally fixed with an electric heating pipe.
本发明的优点和积极效果：Advantages and positive effects of the present invention:
本发明节能环保电散热器在中国和相同维度的国家的标准建筑物供暖的输入功率为每平米15～25W，比普通的电采暖器节能75～85％。The energy-saving and environmental protection electric radiator of the invention has an input power of 15 to 25 W per square meter in a standard building of a country and a country of the same dimension, and is 75 to 85% more energy-efficient than an ordinary electric heater.
具体实施方式detailed description
实施例1： Example 1:
本发明提供的节能环保电散热器，包括散热体、散热体内的电加热管和发热物质，所述发热物质的组成及重量百分比为：42～85％的复合组分A，6～25％的PTFE乳液，1～2％的金属铈，1～18％的金属钠，3～5％的一氯二乙基铝和4～8％的1200目二硫化钼；其中复合组分A的组成及重量百分比为：7～12％的过氧乙酸，45～48％稀丙醇和43～45％的乙酸乙酯。The energy-saving and environmental protection electric radiator provided by the invention comprises a heat dissipating body, an electric heating tube in the heat dissipating body and a heat generating substance, and the composition and the weight percentage of the heat generating substance are: 42 to 85% of the composite component A, 6 to 25%. PTFE emulsion, 1-2% metal ruthenium, 1-18% metal sodium, 3 to 5% diethylaluminum dichloride and 4 to 8% 1200 mesh molybdenum disulfide; wherein the composition of composite component A and The weight percentages are: 7 to 12% peracetic acid, 45 to 48% dilute propanol and 43 to 45% ethyl acetate.
所述发热物质的制备方法如下：The preparation method of the heat generating substance is as follows:
第1、活化复合组分A的制备Preparation of the first and activated composite component A
将过氧乙酸、稀丙醇和乙酸乙酯三种物质按照所述比例加入真空反应釜中，调整反应釜内压力为10～30千帕，温度60～80度，反应时间40分钟，将反应釜下口的生成物取出，制成复合组分A；复合组分A的活化：采用空气净化器将反应釜净化，除去反应釜内空气中的二氧化碳，一氧化碳等杂质；将100kg复合组分A注入一个25000L的高温高压真空反应釜中，给反应釜升温至460℃，在反应釜上安装一个氧分子筛，通过氧分子筛将反应釜抽真空至500帕，恒温60分钟后，向釜内注入2～10Kg氩气，使反应釜内保持在500～1000帕，30分钟后，逐渐使反应釜降到室温，得到活化的复合组分A；Adding three substances of peracetic acid, dilute propanol and ethyl acetate to the vacuum reactor according to the above ratio, adjusting the pressure in the reactor to 10-30 kPa, the temperature of 60-80 degrees, and the reaction time of 40 minutes, the reaction kettle The product of the lower mouth is taken out to form a composite component A; the activation of the composite component A: the reactor is purified by an air purifier, and carbon dioxide, carbon monoxide and the like in the air in the reaction vessel are removed; 100 kg of the composite component A is injected. In a 25000L high-temperature and high-pressure vacuum reactor, the reactor was heated to 460 ° C, an oxygen molecular sieve was installed on the reactor, and the reactor was evacuated to 500 Pa through an oxygen molecular sieve. After a constant temperature of 60 minutes, the reactor was injected into the kettle. 10Kg argon, the reactor is maintained at 500 ~ 1000 Pa, after 30 minutes, gradually reduce the reactor to room temperature, to obtain activated composite component A;
第2、超活性金属铈粉末的制备Preparation of the second and super active metal ruthenium powder
将稀土金属铈锯成屑状，用TiCl4，作为催化剂，将100Kg金属铈和140Kg萘放入已经干燥的，用氩气置换过的反应釜中，抽真空到500帕，40分钟，除去萘和铈表面的吸附空气和其它挥发物，在氩气保护下加入2000摩尔THF(四氢呋喃)，50摩尔TiCl4搅拌反应3小时后将黑色的溶液取出，在氩气保护下，放入抽真空容器，连续对整个体系抽真空，使绝大部分THF溶剂抽走，加热到220℃萘全面升华抽走，取出留在反应器中的超活性金属铈粉末，并放入煤油中保存，使用时按照所述比例加入超活性金属铈粉；The rare earth metal was sawn into a crumb shape, and TiCl 4 was used as a catalyst. 100 Kg of metal ruthenium and 140 Kg of naphthalene were placed in a dry, argon-substituted reaction vessel, and evacuated to 500 Pa for 40 minutes to remove naphthalene. The adsorption air and other volatiles on the surface of the crucible were added with 2000 mol of THF (tetrahydrofuran) under argon atmosphere, and the reaction was stirred for 3 hours after 50 mol of TiCl 4 . The black solution was taken out and placed under vacuum protection. Continuously pumping the whole system, so that most of the THF solvent is pumped away, heated to 220 ° C, and the super-active metal cerium powder remaining in the reactor is taken out and stored in kerosene. The ratio is added to the super active metal strontium powder;
第3、PTFE乳液的制备Third, the preparation of PTFE emulsion
将PTFE粉末注入100立方米的高温真空镀膜机中，加温至1520℃，PTFE气化，按照每500gPTFE粉末向真空镀膜机中通入100克氩气，反应40分钟，将真空镀膜机的温度降至室温，PTFE凝固；用常规PTFE的乳化法制成PTFE乳液；The PTFE powder was injected into a 100-cubic-meter high-temperature vacuum coating machine, heated to 1520 ° C, PTFE gasification, 100 g of argon gas was introduced into the vacuum coating machine per 500 g of PTFE powder, and reacted for 40 minutes to adjust the temperature of the vacuum coating machine. PTFE is solidified at room temperature; PTFE emulsion is prepared by emulsification of conventional PTFE;
第4、将第1至第3步制备的活化复合组分A、超活性金属铈粉末、PTFE乳液、金属钠，以及市售的一氯二乙基铝和1200目二硫化钼按照所述比例混合后放入真空高温高速搅拌机中，升温到200℃，抽真空到500帕，搅拌10小时，制得所述的发热物质。4. The activated composite component A, the superactive metal ruthenium powder, the PTFE emulsion, the metal sodium prepared in the first to third steps, and the commercially available diethylaluminum monochloride and 1200 mesh molybdenum disulfide according to the ratio. After mixing, the mixture was placed in a vacuum high-temperature high-speed mixer, heated to 200 ° C, evacuated to 500 Pa, and stirred for 10 hours to obtain the above-mentioned heat-generating substance.
本发明所述散热体由一组铝合金散热片用上下两根联箱管焊接而成，为增加铝合金散热片的强度，在铝合金散热片中间的￠15～30mm的孔内用压力机压进一根￠15～30mm， 壁厚为1～2mm的铜管或钢管，如果压进的是铜管，就用水压机使铜管膨胀，使铜管和铝合金片得到良好的接触。如果是钢管就用要求钢管外径略大于铝合金孔的尺寸，使之紧密配合并保持良好接触。在上下联箱管上用钻头打一组孔，孔的直径与铜管或钢管的直径相同，将铜管或钢管***上下联箱管的孔内，用氩弧焊将铜管或钢管焊接在上下联箱管上，使所述铜管或钢管与上下两根联箱管保持联通。用厚度2～3mm，直径与联箱管直径相同的铜板将上联箱管的两端焊接密封。下联箱管的一端用厚度2～3mm，与联箱管直径相同的的铜板或钢板将下联箱管焊接密封，铜板或钢板的中心处打一个￠4mm的孔，焊接一根￠4mm的铜管作为注入管，用于向散热体注入发热物质。在下联箱管的另一端内部固定一根电加热管，电加热管的输入功率100～800W。通过￠4mm的铜管向散热体注入：10.00～2000.00克发热物质。The heat dissipating body of the invention is formed by welding a set of aluminum alloy fins with two upper and lower header tubes. In order to increase the strength of the aluminum alloy fins, a press is used in the hole of the 15~30 mm in the middle of the aluminum alloy fins. Press into a ¢ 15 ~ 30mm, A copper pipe or a steel pipe having a wall thickness of 1 to 2 mm. If a copper pipe is pressed in, the copper pipe is expanded by a water press to obtain good contact between the copper pipe and the aluminum alloy piece. If it is a steel pipe, the outer diameter of the steel pipe is required to be slightly larger than the size of the aluminum alloy hole to make it fit tightly and maintain good contact. A set of holes is drilled on the upper and lower header pipes by the drill bit. The diameter of the holes is the same as the diameter of the copper pipe or the steel pipe. The copper pipe or the steel pipe is inserted into the hole of the upper and lower header pipes, and the copper pipe or the steel pipe is welded by the argon arc welding. On the upper and lower header pipes, the copper pipe or the steel pipe is kept in communication with the upper and lower header pipes. The two ends of the upper header tube are welded and sealed with a copper plate having a thickness of 2 to 3 mm and a diameter equal to that of the header tube. One end of the lower header pipe is welded and sealed with a copper plate or steel plate having the same diameter as the header pipe, and the lower header pipe is welded and sealed at the center of the copper plate or steel plate. A copper hole of 4 mm is welded to the center of the copper plate or steel plate. The injection tube is used to inject a heat generating substance into the heat sink. An electric heating tube is fixed inside the other end of the lower header tube, and the input power of the electric heating tube is 100-800W. The heat sink is injected into the heat sink by a copper tube of 4 mm: 10.00 to 2000.00 g of the heat generating substance.
本实施例选材及具体参数如下：The material selection and specific parameters of this embodiment are as follows:
选择75×75铝合金型材，铝型材的内孔径￠20mm，长度1420mm，6根；在铝型材的￠20mm孔内用压力机***长1480mm，￠20mm，壁厚1.0mm的铜管，用水涨机使铜管和铝型材紧密配合。The 75×75 aluminum alloy profile is selected. The inner diameter of the aluminum profile is mm20mm, the length is 1420mm, and the length is 1420mm. In the ¢20mm hole of the aluminum profile, a copper tube with a length of 1480mm, ¢20mm and a wall thickness of 1.0mm is inserted by a press. The machine makes the copper tube and the aluminum profile closely match.
选择两根￠35mm，壁厚1.5mm，长度500mm铜管作为上下联箱管；在该管上用钻头打6个￠20.2mm的孔。用￠35mm，厚2mm的铜板将一根联箱管的两端焊接密封作为上联箱管。￠35mm，厚2mm的铜板，中间打一个￠4.1mm的孔焊接一根￠4mm壁厚1mm的铜管，焊接在另一根￠35mm铜管的一端，另一端内部焊接固定一根600W的电加热管；从￠4mm铜管向散热体内注入680g发热物质。Two copper pipes of 35 mm in thickness, 1.5 mm in wall thickness and 500 mm in length were selected as the upper and lower header pipes; 6 holes of 20.2 mm were drilled with the drill bit on the pipe. The two ends of one header tube are welded and sealed as a top header tube by a copper plate of 35 mm and a thickness of 2 mm. ¢35mm, 2mm thick copper plate, a ¢4.1mm hole is welded in the middle to weld a ¢4mm copper tube with a thickness of 1mm, welded to one end of another ¢35mm copper tube, and the other end is internally fixed with a 600W electric Heat the tube; inject 680 g of heat-generating material into the heat sink from the ¢4 mm copper tube.
本实施例发热物质组合物的组成及重量百分比为：70％复合组分A+2％金属铈+15％的金属钠+6％PTFE乳液+3％一氯二乙基铝+4％1200目的二硫化钼。当投入220V交流电时，散热器开始工作，15分钟后铝合金表面温度达到58～62℃。散热器的散热量达到1392W，热效率达到232％。该散热器是节能环保型电散热器。The composition and weight percentage of the heat-generating composition of the present embodiment are: 70% composite component A+2% metal lanthanum +15% metal sodium + 6% PTFE emulsion + 3% monochlorodiethylaluminum + 4% 1200 mesh Molybdenum disulfide. When 220V AC is put into operation, the heat sink starts to work. After 15 minutes, the surface temperature of the aluminum alloy reaches 58-62 °C. The heat sink has a heat dissipation of 1392W and a thermal efficiency of 232%. The radiator is an energy-saving and environmentally-friendly electric radiator.
实施例2Example 2
本例发热物质组合物的组分为：42％的复合组分A+25％的PTFE乳液+2％的金属铈+18％的金属钠+5％的一氯二乙基铝+8％的二硫化钼。The composition of the exothermic composition of this example is: 42% of composite component A + 25% of PTFE emulsion + 2% of metal strontium + 18% of metallic sodium + 5% of dichlorodiethylaluminum + 8% Molybdenum disulfide.
所述发热物质的制备及散热器的加工方法同实施例1。The preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
实施例3 Example 3
本例发热物质组合物的组分为：80％的A+5％的PTFE乳液+1％的金属铈+7％的金属钠+3％的一氯二乙基铝+4％的二硫化钼。The composition of the exothermic composition of this example is: 80% A + 5% PTFE emulsion + 1% metal ruthenium + 7% metal sodium + 3% monochlorodiethyl aluminum + 4% molybdenum disulfide .
所述发热物质的制备及散热器的加工方法同实施例1。The preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
实施例4Example 4
本例发热物质组合物的组分为：60％的A+18％的PTFE乳液+1.5％的金属铈+13.5％金属钠+3％的一氯二乙基铝+4％的二硫化钼。The composition of the exothermic composition of this example is: 60% A+18% PTFE emulsion + 1.5% metal lanthanum + 13.5% metal sodium + 3% monochlorodiethylaluminum + 4% molybdenum disulfide.
所述发热物质的制备及散热器的加工方法同实施例1。The preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
实施例5、Example 5
本例发热物质组合物的组分为：73％的A+6％的PTFE乳液+2％的金属铈+11％的金属钠+4％的一氯二乙基铝+4％的二硫化钼。The composition of the exothermic composition of this example is: 73% A+6% PTFE emulsion + 2% metal ruthenium + 11% sodium metal + 4% diethylaluminum dichloride + 4% molybdenum disulfide .
所述发热物质的制备及散热器的加工方法同实施例1。The preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
实施例6、Example 6,
本例发热物质组合物的组分为：77％的A+5％的PTFE乳液+2％的金属铈+9％的金属钠+3％的一氯二乙基铝+4％的二硫化钼。The composition of the exothermic composition of this example is: 77% A+5% PTFE emulsion + 2% metal ruthenium + 9% metal sodium + 3% monochlorodiethylaluminum + 4% molybdenum disulfide .
所述发热物质的制备及散热器的加工方法同实施例1。The preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
实施例7、Example 7,
本例发热物质组合物的组分为：53％的A+20％的PTFE乳液+2％的金属铈+15％的金属钠+5％的一氯二乙基铝+5％的二硫化钼。The composition of the exothermic composition of this example is: 53% A+20% PTFE emulsion + 2% metal 铈+15% metal sodium + 5% monochlorodiethylaluminum + 5% molybdenum disulfide .
所述发热物质的制备及散热器的加工方法同实施例1。The preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
实施例8、Example 8,
本例发热物质组合物的组分为：63％的A+15％的PTFE乳液+1％的金属铈+14％的金属钠+3％的一氯二乙基铝+4％的二硫化钼。The composition of the exothermic composition of this example is: 63% A+15% PTFE emulsion + 1% metal ruthenium + 14% sodium metal + 3% monochlorodiethylaluminum + 4% molybdenum disulfide .
所述发热物质的制备及散热器的加工方法同实施例1。The preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
实施例9、 Example 9,
本例发热物质组合物的组分为：73％的A+6％的PTFE乳液+2％的金属铈+12％的金属钠+3％的一氯二乙基铝+4％的二硫化钼。The composition of the exothermic composition of this example is: 73% A+6% PTFE emulsion + 2% metal ruthenium + 12% metal sodium + 3% monochlorodiethylaluminum + 4% molybdenum disulfide .
所述发热物质的制备及散热器的加工方法同实施例1。The preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.
实施例10、Example 10
本例发热物质组合物的组分为：72％的A+6％的PTFE乳液+2％的金属铈+12％的金属钠+4％的一氯二乙基铝+4％的二硫化钼。The composition of the exothermic composition of this example is: 72% A + 6% PTFE emulsion + 2% metal ruthenium + 12% sodium metal + 4% dichlorodiethylaluminum + 4% molybdenum disulfide .
所述发热物质的制备及散热器的加工方法同实施例1。 The preparation of the heat generating substance and the processing method of the heat sink are the same as those in the first embodiment.

Claims (10)

  1. 一种节能环保电散热器，包括散热体、散热体内的电加热管和发热物质，其特征在于所述发热物质的组成及重量百分比为：42～85％的复合组分A，6～25％的PTFE乳液，1～2％的金属铈，1～18％的金属钠，3～5％的一氯二乙基铝和4～8％的1200目二硫化钼；其中复合组分A的组成及重量百分比为：7～12％的过氧乙酸，45～48％稀丙醇和43～45％的乙酸乙酯。The utility model relates to an energy-saving and environment-friendly electric radiator, which comprises a heat dissipating body, an electric heating tube in the heat dissipating body and a heat generating substance, wherein the composition and the weight percentage of the heat generating substance are: 42 to 85% of the composite component A, 6 to 25%. PTFE emulsion, 1-2% metal ruthenium, 1-18% metal sodium, 3 to 5% diethylaluminum dichloride and 4 to 8% 1200 mesh molybdenum disulfide; wherein the composition of composite component A And the weight percentage is: 7 to 12% peracetic acid, 45 to 48% of dilute propanol and 43 to 45% of ethyl acetate.
  2. 根据权利要求1所述的节能环保电散热器，其特征在于所述发热物质的制备方法如下：The energy-saving and environmentally-friendly electric radiator according to claim 1, wherein the method for preparing the heat-generating substance is as follows:
    第1、活化复合组分A的制备Preparation of the first and activated composite component A
    将过氧乙酸、稀丙醇和乙酸乙酯三种物质按照所述比例加入真空反应釜中，调整反应釜内压力为10～30千帕，温度60～80度，反应时间40分钟，将反应釜下口的生成物取出，制成复合组分A；复合组分A的活化：采用空气净化器将反应釜净化，除去反应釜内空气中的二氧化碳，一氧化碳等杂质；将100kg复合组分A注入一个25000L的高温高压真空反应釜中，给反应釜升温至460℃，在反应釜上安装一个氧分子筛，通过氧分子筛将反应釜抽真空至500帕，恒温60分钟后，向反应釜内注入2～10Kg氩气，使反应釜内保持在500～600帕，30分钟后，逐渐使反应釜降到室温，得到高活性的复合组分A；Adding three substances of peracetic acid, dilute propanol and ethyl acetate to the vacuum reactor according to the above ratio, adjusting the pressure in the reactor to 10-30 kPa, the temperature of 60-80 degrees, and the reaction time of 40 minutes, the reaction kettle The product of the lower mouth is taken out to form a composite component A; the activation of the composite component A: the reactor is purified by an air purifier, and carbon dioxide, carbon monoxide and the like in the air in the reaction vessel are removed; 100 kg of the composite component A is injected. In a 25000L high-temperature and high-pressure vacuum reactor, the reactor was heated to 460 ° C, an oxygen molecular sieve was installed on the reactor, and the reactor was evacuated to 500 Pa through an oxygen molecular sieve. After a constant temperature of 60 minutes, the reactor was injected into the reactor. ~ 10Kg argon, the reactor is maintained at 500 ~ 600 Pa, after 30 minutes, gradually reduce the reactor to room temperature, to obtain a highly active composite component A;
    第2、超活性金属铈粉末的制备Preparation of the second and super active metal ruthenium powder
    将稀土金属铈锯成屑状，将100Kg金属铈和140Kg萘放入已经干燥的，用氩气置换了的真空反应釜中，抽空到500帕，40分钟，除去萘和铈表面的吸附空气和其它挥发物，在氩气保护下加入2000摩尔THF(四氢呋喃)，50摩尔TiCl4，搅拌反应3小时后将黑色的溶液取出，在氩气保护下，放入抽真空容器，连续对整个体系抽真空，使绝大部分THF溶剂抽走，加热至220℃萘全面升华抽走，取出留在反应器中的超活性金属铈粉末，并放入煤油中保存，使用时按照所述比例加入超活性金属铈粉；The rare earth metal was sawn into chips, and 100 Kg of metal ruthenium and 140 Kg of naphthalene were placed in a vacuum reactor which had been dried and replaced with argon gas, evacuated to 500 Pa for 40 minutes, and the adsorbed air on the surface of the naphthalene and anthracene was removed. Other volatiles, under argon protection, add 2000 moles of THF (tetrahydrofuran), 50 moles of TiCl 4 , stir the reaction for 3 hours, then remove the black solution, put it in a vacuum container under argon protection, and continuously pump the whole system. Vacuum, so that most of the THF solvent is pumped away, heated to 220 ° C naphthalene full sublimation pumping away, take out the super active metal ruthenium powder remaining in the reactor, and put it in kerosene to store, use super-active according to the ratio Metal powder
    第3、PTFE乳液的制备Third, the preparation of PTFE emulsion
    将PTFE粉末注入100立方米的高温真空镀膜机中，加温至1520℃，PTFE气化，按照每500gPTFE粉末向真空镀膜机中通入100克氩气，反应40分钟，将真空镀膜机的温度降至室温，PTFE凝固；用常规PTFE的乳化法制成PTFE乳液；The PTFE powder was injected into a 100-cubic-meter high-temperature vacuum coating machine, heated to 1520 ° C, PTFE gasification, 100 g of argon gas was introduced into the vacuum coating machine per 500 g of PTFE powder, and reacted for 40 minutes to adjust the temperature of the vacuum coating machine. PTFE is solidified at room temperature; PTFE emulsion is prepared by emulsification of conventional PTFE;
    第4、将第1至第3步制备的活化复合组分A、超活性金属铈粉末、金属钠、PTFE乳液，以及一氯二乙基铝和1200目二硫化钼按照所述比例放入真空高温高速搅拌机中，升温到200℃，抽真空到500帕，搅拌10小时，使其充分混合后制得所述的发热物质。 4. The activated composite component A, the superactive metal ruthenium powder, the metal sodium, the PTFE emulsion prepared by the first to the third steps, and the diethylaluminum monochloride and the 1200 mesh molybdenum disulfide are placed in a vacuum according to the ratio. In a high-temperature high-speed mixer, the temperature was raised to 200 ° C, evacuated to 500 Pa, and stirred for 10 hours, and the mixture was thoroughly mixed to obtain the above-mentioned heat generating substance.
  3. 根据权利要求1所述的节能环保电散热器，其特征在于所述散热体由一组铝合金散热片用上下两根联箱管焊接而成，为增加铝合金散热片的强度，在铝合金散热片中间的￠15～30mm的孔内压进一根￠15～30mm，壁厚为1～2mm的铜管或钢管，使铜管或钢管与铝合金散热片紧密配合，所述铜管或钢管的两端分别***上下两根联箱管内并保持联通，上联箱管的两端用铜板或钢板焊接密封；下联箱管的一端焊接一根用于注入发热物质的注入管，下联箱管的另一端内部固定一根电加热管。The energy-saving and environmental protection electric radiator according to claim 1, wherein the heat dissipating body is formed by welding a set of aluminum alloy fins with two upper and lower header tubes, in order to increase the strength of the aluminum alloy fins, in the aluminum alloy. In the middle of the heat sink, a hole of 15 to 30 mm is pressed into a copper tube or a steel tube with a thickness of 1 to 2 mm, so that the copper tube or the steel tube is closely matched with the aluminum alloy heat sink. The two ends of the steel pipe are respectively inserted into the upper and lower header pipes and kept in communication. The two ends of the upper header pipe are welded and sealed by copper plates or steel plates; one end of the lower header pipe is welded with an injection pipe for injecting the heat generating material, and the lower header pipe is welded. The other end of the other end is fixed with an electric heating tube.
  4. 根据权利要求1至3任一项所述的节能环保电散热器，其特征在于所述发热物质的组成及重量百分比为：42％的复合组分A，25％的PTFE乳液，2％的金属铈，18％的金属钠，5％的一氯二乙基铝和8％的1200目二硫化钼。The energy-saving and environmentally-friendly electric radiator according to any one of claims 1 to 3, characterized in that the composition and weight percentage of the heat-generating substance are: 42% composite component A, 25% PTFE emulsion, 2% metal铈, 18% sodium metal, 5% diethylaluminum chloride and 8% 1200 mesh molybdenum disulfide.
  5. 根据权利要求1至3任一项所述的节能环保电散热器，其特征在于所述发热物质的组成及重量百分比为：80％的复合组分A，6％的PTFE乳液，1％的金属铈，6％的金属钠3％的一氯二乙基铝和4％的1200目二硫化钼。The energy-saving and environmentally-friendly electric radiator according to any one of claims 1 to 3, characterized in that the composition and weight percentage of the heat-generating substance are: 80% of composite component A, 6% of PTFE emulsion, and 1% of metal. Helium, 6% sodium metal 3% monochlorodiethylaluminum and 4% 1200 mesh molybdenum disulfide.
  6. 根据权利要求1至3任一项所述的节能环保电散热器，其特征在于所述发热物质的组成及重量百分比为：60％的复合组分A，18％的PTFE乳液，2％的金属铈，13％的金属钠3％的一氯二乙基铝和4％的1200目二硫化钼。The energy-saving and environmentally-friendly electric radiator according to any one of claims 1 to 3, characterized in that the composition and weight percentage of the heat-generating substance are: 60% of composite component A, 18% of PTFE emulsion, and 2% of metal. Helium, 13% sodium metal 3% monochlorodiethylaluminum and 4% 1200 mesh molybdenum disulfide.
  7. 根据权利要求1至3任一项所述的节能环保电散热器，其特征在于所述发热物质的组成及重量百分比为：70％的复合组分A，10％的PTFE乳液，1％的金属铈，9％的金属钠，5％的一氯二乙基铝和5％的1200目二硫化钼。The energy-saving and environmentally-friendly electric radiator according to any one of claims 1 to 3, characterized in that the composition and weight percentage of the heat-generating substance are: 70% of composite component A, 10% of PTFE emulsion, and 1% of metal. Helium, 9% sodium metal, 5% diethylaluminum chloride and 5% 1200 mesh molybdenum disulfide.
  8. 根据权利要求1至3任一项所述的节能环保电散热器，其特征在于所述发热物质的组成及重量百分比为：80％的复合组分A，6％的PTFE乳液，2％的金属铈，7％的金属钠，3％的一氯二乙基铝和2％的1200目二硫化钼。The energy-saving environmental protection electric radiator according to any one of claims 1 to 3, characterized in that the composition and weight percentage of the heat-generating substance are: 80% composite component A, 6% PTFE emulsion, 2% metal Helium, 7% sodium metal, 3% diethylaluminum chloride and 2% 1200 mesh molybdenum disulfide.
  9. 根据权利要求1至3任一项所述的节能环保电散热器，其特征在于所述发热物质的组成及重量百分比为：50％的复合组分A，20％的PTFE乳液，5％的金属铈，15％的金属钠，5％的一氯二乙基铝和5％的1200目二硫化钼。The energy-saving and environment-friendly electric radiator according to any one of claims 1 to 3, characterized in that the composition and weight percentage of the heat generating substance are: 50% of composite component A, 20% of PTFE emulsion, and 5% of metal.铈, 15% sodium metal, 5% diethylaluminum chloride and 5% 1200 mesh molybdenum disulfide.
  10. 根据权利要求1至3任一项所述的节能环保电散热器，其特征在于所述发热物质的组成及重量百分比为：65％的复合组分A，15％的PTFE乳液，2％的金属铈，10％的金属钠，3％的一氯二乙基铝和5％的1200目二硫化钼。 The energy-saving and environmentally-friendly electric radiator according to any one of claims 1 to 3, characterized in that the composition and weight percentage of the heat-generating substance are: 65% of composite component A, 15% of PTFE emulsion, and 2% of metal.铈, 10% sodium metal, 3% diethylaluminum chloride and 5% 1200 mesh molybdenum disulfide.
PCT/CN2016/081627 2015-10-08 2016-05-11 Energy-saving environmentally-friendly electric radiator WO2017059674A1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070276067A1 (en) * 2006-05-24 2007-11-29 Kim Balfour Poly(arylene ether) composition, method, and article
CN201103951Y (en) * 2007-08-19 2008-08-20 刘鉴梁 Heat storage type electric heater
CN104235931A (en) * 2013-06-13 2014-12-24 天津市天立成电子科技有限公司 Energy-saving environment-friendly heating device

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070276067A1 (en) * 2006-05-24 2007-11-29 Kim Balfour Poly(arylene ether) composition, method, and article
CN201103951Y (en) * 2007-08-19 2008-08-20 刘鉴梁 Heat storage type electric heater
CN104235931A (en) * 2013-06-13 2014-12-24 天津市天立成电子科技有限公司 Energy-saving environment-friendly heating device

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