WO2017047784A1 - 蓄電素子 - Google Patents
蓄電素子 Download PDFInfo
- Publication number
- WO2017047784A1 WO2017047784A1 PCT/JP2016/077538 JP2016077538W WO2017047784A1 WO 2017047784 A1 WO2017047784 A1 WO 2017047784A1 JP 2016077538 W JP2016077538 W JP 2016077538W WO 2017047784 A1 WO2017047784 A1 WO 2017047784A1
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- WO
- WIPO (PCT)
- Prior art keywords
- electrode body
- electrode
- spacer
- axis direction
- container
- Prior art date
Links
- 238000003860 storage Methods 0.000 title claims abstract description 57
- 125000006850 spacer group Chemical group 0.000 claims abstract description 132
- 238000004804 winding Methods 0.000 claims abstract description 41
- 230000005611 electricity Effects 0.000 claims description 18
- 238000005452 bending Methods 0.000 claims description 15
- 239000002390 adhesive tape Substances 0.000 description 19
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- 238000002347 injection Methods 0.000 description 14
- 239000007924 injection Substances 0.000 description 14
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- 239000010410 layer Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 239000008151 electrolyte solution Substances 0.000 description 8
- 238000004146 energy storage Methods 0.000 description 8
- 238000009434 installation Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000003466 welding Methods 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- 239000004734 Polyphenylene sulfide Substances 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 6
- 239000000470 constituent Substances 0.000 description 6
- 239000011810 insulating material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229920000069 polyphenylene sulfide Polymers 0.000 description 6
- -1 polypropylene Polymers 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- 229910000838 Al alloy Inorganic materials 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000003780 insertion Methods 0.000 description 5
- 230000037431 insertion Effects 0.000 description 5
- 238000010030 laminating Methods 0.000 description 5
- 239000007773 negative electrode material Substances 0.000 description 5
- 229920000515 polycarbonate Polymers 0.000 description 5
- 239000004417 polycarbonate Substances 0.000 description 5
- 239000007774 positive electrode material Substances 0.000 description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000011255 nonaqueous electrolyte Substances 0.000 description 4
- 238000010248 power generation Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910000881 Cu alloy Inorganic materials 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910000733 Li alloy Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000001989 lithium alloy Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 229910011157 LiMBO Inorganic materials 0.000 description 1
- 229910015118 LiMO Inorganic materials 0.000 description 1
- 229910013275 LiMPO Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910021469 graphitizable carbon Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- JWZCKIBZGMIRSW-UHFFFAOYSA-N lead lithium Chemical compound [Li].[Pb] JWZCKIBZGMIRSW-UHFFFAOYSA-N 0.000 description 1
- 235000013490 limbo Nutrition 0.000 description 1
- 229910021450 lithium metal oxide Inorganic materials 0.000 description 1
- UIDWHMKSOZZDAV-UHFFFAOYSA-N lithium tin Chemical compound [Li].[Sn] UIDWHMKSOZZDAV-UHFFFAOYSA-N 0.000 description 1
- 229910021437 lithium-transition metal oxide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910021470 non-graphitizable carbon Inorganic materials 0.000 description 1
- 229920000447 polyanionic polymer Polymers 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
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- 230000008961 swelling Effects 0.000 description 1
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Images
Classifications
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- H01M6/02—Details
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/74—Terminals, e.g. extensions of current collectors
- H01G11/76—Terminals, e.g. extensions of current collectors specially adapted for integration in multiple or stacked hybrid or EDL capacitors
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- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
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- H01G11/78—Cases; Housings; Encapsulations; Mountings
- H01G11/82—Fixing or assembling a capacitive element in a housing, e.g. mounting electrodes, current collectors or terminals in containers or encapsulations
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- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/103—Primary casings; Jackets or wrappings characterised by their shape or physical structure prismatic or rectangular
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- H01M50/50—Current conducting connections for cells or batteries
- H01M50/572—Means for preventing undesired use or discharge
- H01M50/584—Means for preventing undesired use or discharge for preventing incorrect connections inside or outside the batteries
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- H01M2220/00—Batteries for particular applications
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- H01M50/50—Current conducting connections for cells or batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to a power storage element.
- a power storage element a power storage element in which an electrode body is accommodated in a container via a spacer is known (see, for example, Patent Document 1).
- the conventional power storage element needs to be increased in size in order to increase the capacity.
- the actual state is that the electrode body cannot be enlarged by the thickness of the spacer.
- the present invention has been made in consideration of the above-described conventional problems, and an object of the present invention is to provide a storage element capable of increasing the capacity while suppressing an increase in size of the storage element.
- an energy storage device includes an electrode body in which an electrode is wound, a container that houses the electrode body, and a spacer that is interposed between the container and the electrode body.
- the spacer has an opening that exposes a part of the surface of the curved portion of the electrode body from one end to the other end of the electrode body in the winding axis direction of the electrode body.
- the capacity can be increased while suppressing an increase in the size of the power storage element.
- FIG. 1 is a perspective view showing an external appearance of a power storage device according to an embodiment.
- FIG. 2 is an exploded perspective view of the energy storage device according to the embodiment.
- FIG. 3 is an exploded perspective view of the lid plate structure according to the embodiment.
- FIG. 4 is a perspective view showing the configuration of the electrode body according to the embodiment.
- FIG. 5 is a cross-sectional view schematically showing an adhesive state of the adhesive tape to the main body portion of the electrode body according to the embodiment.
- FIG. 6 is a front view of the side spacer according to the embodiment as viewed from the inside.
- FIG. 7 is a cross-sectional view of the side spacer when cut along the XY plane passing through the line VII-VII in FIG. FIG.
- FIG. 8 is a top view of the side spacer according to the embodiment.
- FIG. 9 is a perspective view showing an assembled state of the side spacer and the electrode body according to the embodiment.
- FIG. 10 is a side view showing a positional relationship between the lid plate structure and the side spacer according to the embodiment after positioning.
- FIG. 11 is a schematic cross-sectional view showing the cover plate structure and the surrounding structure according to the embodiment.
- FIG. 12 is a perspective view showing a binding state of the binding sheet with respect to the electrode body according to the embodiment.
- FIG. 13 is a perspective view showing one step of the method for manufacturing the energy storage device according to the embodiment.
- FIG. 14 is a cross-sectional view showing a positional relationship among the side spacer, the electrode body, and the container according to the embodiment.
- FIG. 15 is a perspective view showing a state in which a modified example of the side spacer according to the embodiment is attached to the electrode body.
- FIG. 16 is a perspective view showing a state in which another modified example of the side spacer according to the embodiment is attached to the electrode body.
- FIG. 17 is a cross-sectional view showing the positional relationship between another modified example of the side spacer according to the embodiment and the container.
- an energy storage device includes an electrode body in which an electrode is wound, a container that houses the electrode body, and a spacer that is interposed between the container and the electrode body.
- the spacer has an opening that exposes a part of the surface of the curved portion of the electrode body from one end to the other end of the electrode body in the winding axis direction of the electrode body.
- the opening of the spacer exposes a part of the surface of the curved portion of the electrode body from one end to the other end in the winding axis direction of the electrode body.
- the body can be placed. Therefore, the installation space of the electrode body can be widened, and the external dimensions of the electrode body can be increased and the capacity can be increased without enlarging the entire power storage element.
- a part of the surface of the curved portion of the electrode body may be disposed in the opening.
- the installation space for the electrode body can be expanded into the opening. Therefore, the outer dimension of the electrode body can be further increased.
- a part of the surface of the electrode body and the outer surface of the spacer may be flush with each other.
- the entire opening can be used as an installation space for the electrode body. Therefore, the outer dimension of the electrode body can be further increased, and the capacity of the power storage element can be further increased.
- the electrode body may have an oval shape having two curved portions, and the spacer may be provided individually for the two curved portions.
- the spacer since the spacer is individually provided for each of the two curved portions of the ellipsoidal electrode body, the spacer can be formed with a simple configuration.
- the electrode body may be disposed at a position where one end portion in the winding axis direction of the electrode body faces the cover plate of the container.
- the electrode body is arranged so that one end portion in the winding axis direction of the electrode body faces the cover plate of the container, the capacity can be increased by using a so-called laterally wound electrode body. it can. Further, since the spacer is disposed between the container and the electrode body along the direction intersecting with the main surface of the lid plate, the spacer is used as a guide when the electrode body is accommodated in the container. The electrode body can be smoothly guided into the container.
- the container has a rectangular housing recess when viewed from the winding axis direction, and the spacer is disposed along a side surface that forms the short side of the housing recess. Also good.
- the spacer is disposed along the side surface forming the short side of the housing recess, the spacer is made smaller than when the spacer is disposed along the side surface forming the long side of the housing recess. be able to. Therefore, the installation space for the electrode body can be further secured, and the outer dimensions of the electrode body can be increased.
- a part of the surface of the bending portion may be a region including the apex portion of the bending portion.
- the apex portion of the bending portion is included in a part of the surface of the bending portion exposed by the opening, it is easy to arrange a part of the surface of the bending portion in the opening. Can do.
- FIG. 1 is a perspective view showing an appearance of a power storage device 10 according to the embodiment.
- FIG. 2 is an exploded perspective view of the energy storage device 10 according to the embodiment.
- FIG. 3 is an exploded perspective view of the cover plate structure 180 according to the embodiment.
- the positive electrode lead plate 145 and the negative electrode lead plate 155 bonded to the positive electrode current collector 140 and the negative electrode current collector 150 included in the lid plate structure 180 are illustrated by broken lines.
- the Z-axis direction is described as the vertical direction for convenience of explanation. However, in the actual usage, the Z-axis direction may not match the vertical direction.
- the electricity storage element 10 is a secondary battery that can charge electricity and discharge electricity.
- the electricity storage element 10 is a nonaqueous electrolyte secondary battery such as a lithium ion secondary battery.
- the power storage element 10 is applied to, for example, an electric vehicle (EV), a hybrid electric vehicle (HEV), a plug-in hybrid electric vehicle (PHEV), or the like.
- the electrical storage element 10 is not limited to a nonaqueous electrolyte secondary battery, A secondary battery other than a nonaqueous electrolyte secondary battery may be sufficient, and a capacitor may be sufficient as it.
- the power storage element 10 may be a primary battery.
- the electricity storage device 10 includes an electrode body 400 and a container 100 that houses the electrode body 400.
- a cover plate structure 180 configured by arranging various elements on the cover plate 110 of the container 100 is disposed above the electrode body 400.
- one end of the electrode body 400 faces the lid plate structure 180.
- the lid plate structure 180 includes a lid plate 110 of the container 100, a positive electrode terminal 200, a negative electrode terminal 300, upper insulating members 125 and 135, lower insulating members 120 and 130, a positive electrode current collector 140, and a negative electrode current collector 150.
- the positive electrode terminal 200 is electrically connected to the positive electrode of the electrode body 400 via the positive electrode current collector 140
- the negative electrode terminal 300 is electrically connected to the negative electrode of the electrode body 400 via the negative electrode current collector 150.
- Each of the conductive members electrically connected to the electrode body 400 such as the positive electrode terminal 200 is insulated from the container 100 by an insulating member such as the lower insulating member 120.
- Each of the upper insulating members 125 and 135 and the lower insulating members 120 and 130 is an insulating member at least partially disposed between the wall portion of the container 100 and the conductive member.
- each of the insulating members is arranged along the lid plate 110 that forms the upper wall portion among the six wall portions that form the container 100 having a substantially rectangular parallelepiped outer shape.
- the electricity storage device 10 includes an upper spacer 500 and a buffer sheet 600 disposed between the cover plate structure 180 and the electrode body 400 in addition to the above configuration.
- the upper spacer 500 is disposed between the electrode body 400 and the lid plate 110 and has a locking portion 510 that is locked to a part of the lid plate structure 180.
- the upper spacer 500 has a flat plate shape as a whole, and the two engaging portions 510 and the two insertion portions 520 into which the tab portions 410 and 420 are inserted (through the tab portions 410 and 420). And have.
- the insertion portion 520 is provided in a cutout shape in the upper spacer 500.
- the upper spacer 500 is made of an insulating material such as polycarbonate (PC), polypropylene (PP), polyethylene (PE), or polyphenylene sulfide resin (PPS).
- the upper spacer 500 is, for example, a member that directly or indirectly regulates the upward movement of the electrode body 400 (in the direction of the cover plate 110), or a short circuit between the cover plate structure 180 and the electrode body 400. It functions as a member to prevent.
- the upper spacer 500 includes two locking portions 510, and each of the two locking portions 510 is locked to the mounting portion 122 or 132 included in the lid plate structure 180.
- Buffer sheet 600 is formed of a highly flexible porous material such as foamed polyethylene and is a member that functions as a buffer material between electrode body 400 and upper spacer 500.
- a side spacer (spacer) 700 is disposed between the inner peripheral surface of the container 100.
- the side spacer 700 plays a role of regulating the position of the electrode body 400, for example. A specific configuration of the side spacer 700 will be described later.
- the electricity storage element 10 includes other elements such as a buffer sheet disposed between the electrode body 400 and the bottom 113 of the container 100 (main body 111). Also good.
- an electrolytic solution nonaqueous electrolyte
- the illustration of the electrolytic solution is omitted.
- the container 100 includes a main body 111 and a lid plate 110.
- the material of the main body 111 and the cover plate 110 is not particularly limited, but is preferably a weldable metal such as stainless steel, aluminum, or aluminum alloy.
- the main body 111 is a cylindrical body having a rectangular shape in a top view, and includes a receiving recess 112 having a rectangular shape in a top view and a bottom 113.
- An insulating sheet 350 that covers the electrode body 400 is provided inside the main body 111.
- the main body 111 is sealed by the electrode plate 400, the insulating sheet 350 and the like being accommodated in the accommodating recess 112, and then the lid plate 110 being welded.
- the lid plate 110 is a plate-like member that closes the opening of the housing recess 112. As shown in FIGS. 2 and 3, the cover plate 110 is formed with a gas discharge valve 170, a liquid injection port 117, through holes 110 a and 110 b, and two bulging portions 160.
- the gas discharge valve 170 has a role of releasing the gas inside the container 100 by being opened when the internal pressure of the container 100 increases.
- the liquid injection port 117 is a through hole for injecting an electrolytic solution at the time of manufacturing the electric storage element 10. Further, as shown in FIGS. 1 to 3, a liquid injection plug 118 is arranged on the lid plate 110 so as to close the liquid injection port 117. That is, at the time of manufacturing the electricity storage device 10, the electrolytic solution is injected into the container 100 from the liquid injection port 117, the liquid injection plug 118 is welded to the lid plate 110, and the liquid injection port 117 is closed. Housed inside.
- each of the two bulging portions 160 is provided on the lid plate 110 by forming a part of the lid plate 110 in a bulging shape.
- the upper insulating member 125 or 135 is provided. Used for positioning.
- a concave portion (not shown) that is a concave portion is formed on the back side (the side facing the electrode body 400) of the bulging portion 160, and the lower insulating member 120 or 130 is formed in a part of the concave portion.
- the engaging protrusion 120b or 130b is engaged. Thereby, the lower insulating member 120 or 130 is also positioned and fixed to the lid plate 110 in that state.
- the upper insulating member 125 is a member that electrically insulates the positive electrode terminal 200 and the cover plate 110 from each other.
- the lower insulating member 120 is a member that electrically insulates the positive electrode current collector 140 from the lid plate 110.
- the upper insulating member 135 is a member that electrically insulates the negative electrode terminal 300 from the lid plate 110.
- the lower insulating member 130 is a member that electrically insulates the negative electrode current collector 150 from the lid plate 110.
- the upper insulating members 125 and 135 may be called, for example, an upper gasket, and the lower insulating members 120 and 130 may be called, for example, a lower gasket. That is, in the present embodiment, the upper insulating members 125 and 135 and the lower insulating members 120 and 130 also have a function of sealing between the electrode terminal (200 or 300) and the container 100.
- the upper insulating members 125 and 135 and the lower insulating members 120 and 130 are formed of an insulating material such as PC, PP, PE, or PPS, for example, similarly to the upper spacer 500. Further, a through hole 126 that guides the electrolyte flowing from the liquid injection port 117 toward the electrode body 400 is provided in a portion of the lower insulating member 120 that is located immediately below the liquid injection port 117.
- the lower insulating members 120 and 130 are provided with engaging portions 121 and 131 that engage with the side spacer 700. Specifically, the engaging portions 121 and 131 protrude from the outer end portions of the lower insulating members 120 and 130.
- the positions of the lower insulating members 120 and 130 with respect to the side spacer 700 are determined.
- the position of the cover plate structure 180 with respect to the side spacer 700 is determined. The engagement state between the engagement portions 121 and 131 and the side spacer 700 will be described later.
- the positive electrode terminal 200 is an electrode terminal electrically connected to the positive electrode of the electrode body 400 through the positive electrode current collector 140.
- the negative electrode terminal 300 is an electrode terminal electrically connected to the negative electrode of the electrode body 400 via the negative electrode current collector 150. That is, the positive electrode terminal 200 and the negative electrode terminal 300 lead the electricity stored in the electrode body 400 to the external space of the power storage element 10, and in order to store the electricity in the electrode body 400, It is an electrode terminal made of metal for introducing.
- the positive electrode terminal 200 and the negative electrode terminal 300 are formed of aluminum or an aluminum alloy.
- the positive terminal 200 is provided with a fastening portion 210 that fastens the container 100 and the positive current collector 140.
- the negative electrode terminal 300 is provided with a fastening portion 310 that fastens the container 100 and the negative electrode current collector 150.
- the fastening portion 210 is a member (rivet) extending downward from the positive electrode terminal 200 and is inserted into the through hole 140a of the positive electrode current collector 140 and caulked. Specifically, the fastening portion 210 is inserted into the through hole 125 a of the upper insulating member 125, the through hole 110 a of the cover plate 110, the through hole 120 a of the lower insulating member 120, and the through hole 140 a of the positive electrode current collector 140. It is squeezed. Accordingly, the positive electrode terminal 200 and the positive electrode current collector 140 are electrically connected, and the positive electrode current collector 140 is fixed to the cover plate 110 together with the positive electrode terminal 200, the upper insulating member 125, and the lower insulating member 120.
- the fastening portion 310 is a member (rivet) extending downward from the negative electrode terminal 300 and is inserted into the through hole 150a of the negative electrode current collector 150 and caulked. Specifically, the fastening portion 310 is inserted into the through hole 135 a of the upper insulating member 135, the through hole 110 b of the lid plate 110, the through hole 130 a of the lower insulating member 130, and the through hole 150 a of the negative electrode current collector 150. It is squeezed. Thereby, the negative electrode terminal 300 and the negative electrode current collector 150 are electrically connected, and the negative electrode current collector 150 is fixed to the cover plate 110 together with the negative electrode terminal 300, the upper insulating member 135, and the lower insulating member 130.
- the fastening part 210 may be formed as an integral part of the positive electrode terminal 200, and the fastening part 210 manufactured as a separate part from the positive electrode terminal 200 is fixed to the positive electrode terminal 200 by a technique such as caulking or welding. It may be done. The same applies to the relationship between the fastening portion 310 and the negative electrode terminal 300.
- the positive electrode current collector 140 is a member that is disposed between the electrode body 400 and the container 100 and electrically connects the electrode body 400 and the positive electrode terminal 200.
- the positive electrode current collector 140 is made of aluminum or an aluminum alloy.
- the positive electrode current collector 140 is electrically connected to the tab portion 410 on the positive electrode side of the electrode body 400 via a positive electrode lead plate 145 as a lead plate.
- the positive electrode lead plate 145 is formed of aluminum or an aluminum alloy as with the positive electrode current collector 140.
- the negative electrode current collector 150 is a member that is disposed between the electrode body 400 and the container 100 and electrically connects the electrode body 400 and the negative electrode terminal 300.
- the negative electrode current collector 150 is made of copper or a copper alloy.
- the negative electrode current collector 150 is electrically connected to the tab portion 420 on the negative electrode side of the electrode body 400 via a negative electrode lead plate 155 as a lead plate.
- the negative electrode lead plate 155 is formed of copper or a copper alloy.
- FIG. 4 is a perspective view showing the configuration of the electrode assembly 400 according to the embodiment.
- FIG. 4 is a partially developed view of the wound state of the electrode body 400.
- the electrode body 400 is a power storage element (power generation element) that can store electricity.
- the electrode body 400 is formed by alternately stacking and winding positive electrodes 450 and negative electrodes 460 and separators 470a and 470b. That is, the electrode body 400 is formed by laminating the positive electrode 450, the separator 470a, the negative electrode 460, and the separator 470b in this order, and winding the cross section into an oval shape.
- the positive electrode 450 is an electrode plate in which a positive electrode active material layer is formed on the surface of a positive electrode base material layer that is a long strip-shaped metal foil made of aluminum or an aluminum alloy.
- a positive electrode active material used for a positive electrode active material layer if it is a positive electrode active material which can occlude / release lithium ion, a well-known material can be used suitably.
- a positive electrode active material a polyanion compound such as LiMPO 4 , LiMSiO 4 , LiMBO 3 (M is one or more transition metal elements selected from Fe, Ni, Mn, Co, etc.), lithium titanate, Spinel compounds such as lithium manganate, lithium transition metal oxides such as LiMO 2 (M is one or more transition metal elements selected from Fe, Ni, Mn, Co, etc.) and the like can be used.
- the negative electrode 460 is an electrode plate in which a negative electrode active material layer is formed on the surface of a negative electrode base material layer which is a long strip-shaped metal foil made of copper or a copper alloy.
- a negative electrode active material used for a negative electrode active material layer if it is a negative electrode active material which can occlude-release lithium ion, a well-known material can be used suitably.
- lithium metal lithium metal
- lithium alloy lithium metal-containing alloys such as lithium-aluminum, lithium-lead, lithium-tin, lithium-aluminum-tin, lithium-gallium, and wood alloy
- lithium Alloys that can be occluded / released
- carbon materials eg, graphite, non-graphitizable carbon, graphitizable carbon, low-temperature calcined carbon, amorphous carbon, etc.
- metal oxides lithium metal oxides (Li 4 Ti 5 O 12, etc.)
- polyphosphoric acid compounds e.g, lithium metal, lithium alloy (lithium metal-containing alloys such as lithium-aluminum, lithium-lead, lithium-tin, lithium-aluminum-tin, lithium-gallium, and wood alloy), and lithium Alloys that can be occluded / released
- carbon materials eg, graphite, non-graphitizable carbon, graphitizable carbon, low-temperature calcined carbon
- the separators 470a and 470b are microporous sheets made of resin.
- a well-known material can be used suitably as long as the performance of the electrical storage element 10 is not impaired.
- the positive electrode 450 has a plurality of protruding portions 411 protruding outward at one end in the winding axis direction.
- the negative electrode 460 includes a plurality of projecting portions 421 that project outward at one end in the winding axis direction.
- the plurality of protrusions 411 and the plurality of protrusions 421 are portions where the active material is not applied and the base material layer is exposed (active material uncoated portions).
- the winding axis is an imaginary axis that becomes a central axis when winding the positive electrode 450, the negative electrode 460, and the like.
- the winding axis is parallel to the Z-axis direction passing through the center of the electrode body 400. It is a straight line.
- the plurality of protrusions 411 and the plurality of protrusions 421 are arranged on the same end in the winding axis direction (the end on the plus side in the Z-axis direction in FIG. 4), and the positive electrode 450 and the negative electrode 460 are stacked.
- the electrode body 400 is laminated at a predetermined position. Specifically, the plurality of protrusions 411 are stacked at predetermined positions in the circumferential direction at one end in the winding axis direction by stacking the positive electrodes 450 by winding.
- the plurality of protrusions 421 are stacked at a predetermined position in the circumferential direction different from the position where the plurality of protrusions 411 are stacked at one end in the winding axis direction by stacking the negative electrode 460 by winding. Is done.
- the electrode body 400 is formed with a tab portion 410 formed by stacking a plurality of protrusions 411 and a tab portion 420 formed by stacking a plurality of protrusions 421.
- the tab portion 410 is gathered toward the center in the stacking direction, for example, and joined to the positive electrode lead plate 145 by, for example, ultrasonic welding.
- the tab portion 420 is gathered toward the center in the stacking direction, for example, and joined to the negative electrode lead plate 155 by, for example, ultrasonic welding.
- the positive electrode lead plate 145 bonded to the tab portion 410 is bonded to the positive electrode current collector 140, and the positive electrode lead plate 145 bonded to the tab portion 420 is bonded to the negative electrode current collector 150.
- the tab portions (410, 420) are portions for introducing and deriving electricity in the electrode body 400, and other names such as “lead (part)” and “current collector” may be attached. is there.
- the tab portion 410 is formed by laminating the protruding portion 411 that is the portion where the base material layer is exposed, the tab portion 410 does not contribute to power generation.
- the tab part 420 is formed by laminating the protruding part 421 that is the part where the base material layer is exposed, the tab part 420 does not contribute to power generation.
- the portions of the electrode body 400 that are different from the tab portions 410 and 420 are formed by laminating portions of the base material layer coated with the active material, and thus contribute to power generation.
- this part is referred to as a main body part 430. Both end portions in the X-axis direction of the main body 430 are curved portions 431 and 432 whose outer peripheral surfaces are curved.
- the electrode body 400 is formed in an oval shape having two curved portions 431 and 432.
- an adhesive tape 370 is attached to each of one end and the other end of the main body 430 in the winding axis direction (Z-axis direction) to prevent winding deviation (see FIG. 9). .
- FIG. 5 is a cross-sectional view schematically showing an adhesive state of the adhesive tape 370 to the main body 430 of the electrode body 400 according to the embodiment.
- FIG. 5 shows the state of one adhesive tape 370 affixed to the lower end of the main body 430 and the positive electrode 450, the negative electrode 460, and the separators 470a and 470b sandwiched between both ends of the adhesive tape 370.
- the positive electrode 450, the negative electrode 460, and the separators 470 a and 470 b do not correspond to the actual number of turns and are shown in a simplified manner.
- both end portions of the adhesive tape 370 are bonded to the outer peripheral surface of the main body 430 so that the protruding portions 470c and 470d of the separators 470a and 470b are brought to the center.
- the protruding portions 470c and 470d of the separators 470a and 470b block the end portion of the main body portion 430, and the main body portion 430 is suppressed while suppressing the winding displacement of the main body portion 430. Prevents foreign matter from getting inside.
- FIG. 6 is a front view of the side spacer 700 according to the embodiment as viewed from the inside.
- FIG. 7 is a cross-sectional view of the side spacer 700 when cut along the XY plane passing through the line VII-VII in FIG.
- FIG. 8 is a top view of the side spacer 700 according to the embodiment.
- the outer shape of the main body 430 of the electrode body 400 is indicated by a two-dot chain line.
- FIG. 8 shows a state in which the engaging portion 131 of the lower insulating member 130 is engaged with the side spacer 700. Since the positive electrode side has the same configuration, the description thereof is omitted here.
- the side spacer 700 is a long member extending in the winding axis direction (Z-axis direction) and has an insulating property such as PC, PP, PE, or PPS. It is made of material.
- the side spacer 700 has a base 710, a wall 720, and a bottom plate 730.
- the base 710 has a top plate 711 and a wall 712.
- the top plate 711 is formed in a substantially rectangular shape in a top view in which a part of the corner portion has an R shape.
- a wall portion 712 is formed on the top surface of the top plate 711.
- the wall portion 712 has a peripheral wall 713 and an inner wall 714.
- the peripheral wall 713 is open from a portion corresponding to one side of the top plate 711 and is erected from the top plate 711 along other sides of the top plate 711.
- the inner wall 714 is disposed inward of the peripheral wall 713 and is erected from three top plates 711 in parallel so as to extend inward continuously from the peripheral wall 713.
- the peripheral wall 713 and the inner wall 714 have the same end surface in the Z-axis direction.
- the inner wall 714a disposed at the center is formed longer in the X-axis direction than the other two inner walls 714b.
- the distal end portion of the central inner wall 714a is a positioning portion 715 with which the engaging portions 121 and 131 of the lower insulating members 120 and 130 are engaged.
- the wall body 720 extends in the Z-axis direction, a top plate 711 is connected to one end portion thereof, and a bottom plate 730 is connected to the other end portion thereof.
- An opening 740 that opens the wall 720 is formed at the center of the wall 720 in the Y-axis direction.
- the opening 740 is formed along the Z-axis direction so as to open from the top plate 711 to the bottom plate 730.
- the portions facing each other across the opening 740 are defined as a first wall body 720a and a second wall body 720b.
- the first wall body 720a and the second wall body 720b have a uniform shape from one end to the other end in the Z-axis direction.
- the cross-sectional shape of the 1st wall body 720a and the 2nd wall body 720b is a concave curved surface where the inner surface is smooth as a whole.
- the outer surfaces of the first wall body 720a and the second wall body 720b are smooth convex curved surfaces as a whole so as to correspond to the inner surface shape of the main body 111 of the container 100.
- the bottom plate 730 is formed in a substantially rectangular shape in top view with part of the corners having an R shape.
- a wall body 720 is connected to the upper surface of the bottom plate 730.
- FIG. 9 is a perspective view showing an assembled state of the side spacer 700 and the electrode body 400 according to the embodiment.
- the side spacer 700 is individually attached to the curved portions 431 and 432 of the electrode body 400. Specifically, the side spacer 700 is attached to the electrode body 400 so that the opening 740 accommodates the curved portions 431 and 432 from one end to the other end in the winding axis direction.
- the outer shape of the curved portion 432 is indicated by a two-dot chain line. Since the curved portions 431 and 432 have substantially the same outer shape, the positional relationship between the side spacer 700 and the curved portion 432 will be described as an example here, and the positional relationship between the side spacer 700 and the curved portion 431 will be described. Is omitted. As shown in FIG. 7, the side spacer 700 is attached to the electrode body 400 such that the outer surface of the wall body 720 is flush with a part of the surface of the curved portion 432. Here, a part of the surface of the bending portion 432 is a region including the apex portion of the bending portion 432.
- the curved portion 432 is accommodated in the opening 740 of the side spacer 700. Further, since the inner surface of the wall body 720 is a concave curved surface, the curved surface shape of the bending portion 432 is abutted against the surface of the bending portion 432 and the form is stabilized.
- the side spacer 700 is fixed to the main body 430 of the electrode body 400 by the adhesive tape 380. Specifically, the side spacer 700 is fixed to the main body 430 with an adhesive tape 380 at two positions spaced apart in the Z-axis direction.
- the side spacer 700 When the side spacer 700 is fixed to the main body 430 of the electrode body 400, as shown in FIG. 9, the side spacer 700 extends from one end of the main body 430 in the winding axis direction to the other end. . At this time, the bottom plate 730 of the side spacer 700 covers the other end of the main body 430. Further, the base portion 710 that is one end portion of the side spacer 700 is separated from the one end of the main body portion 430 by a predetermined gap S1 in the winding axis direction.
- connection state between each of the lower insulating members 120 and 130 and the side spacer 700 is the same. Therefore, in the following, the connection state between the lower insulating member 130 and the side spacer 700 will be described as an example, and description of the connection state between the lower insulating member 120 and the side spacer 700 will be omitted.
- the engaging portion 131 protrudes from an outer end portion of the lower insulating member 130. Ribs 133 extending over the entire length of the engaging portion 131 are provided on both sides of the engaging portion 131. The rib 133 increases the strength of the entire engaging portion 131. In addition, a notch 131 a that is recessed along the X-axis direction is provided at the center of the tip of the engaging portion 131. The notch 131 a engages with the positioning part 715 on the top plate 711 of the side spacer 700.
- the notch 131a penetrates in the Z-axis direction and is open on the positive side in the X-axis direction, so that it can be engaged with the positioning portion 715 from the Z-axis direction and the X-axis direction. Yes.
- the positioning portion 715 restricts movement in the direction intersecting the Z-axis direction, more specifically, movement in the Y-axis direction. That is, since the movement of the entire lower insulating member 130 in the Y-axis direction is restricted, the movement of the lid plate structure 180 having the lower insulating member 130 in the Y-axis direction is also restricted, and the position of the lid plate structure 180 Is decided.
- FIG. 10 is a side view showing a positional relationship between the lid plate structure 180 and the side spacer 700 according to the embodiment after positioning.
- the base portion 710 that is one end portion of the side spacer 700 is in contact with the lid plate 110 that is a part of the lid plate structure 180. Specifically, one end surface of the wall portion 712 of the base portion 710 is in contact with the lid plate 110. Even in this state, as described above, the base 710 is separated from the one end of the main body 430 of the electrode body 400 by a predetermined gap S1 in the winding axis direction (see FIG. 6). Thereby, even if the lid plate structure 180 is pressed from above, the force is suppressed from acting on one end of the main body 430.
- FIG. 11 is a schematic cross-sectional view showing the cover plate structure 180 and the surrounding structure according to the embodiment. Note that FIG. 11 shows a partial cross section of the electricity storage element 10 when cut along the YZ plane passing through the line XI-XI in FIG. 3, and a side spacer 700 on the X axis direction plus side (see FIG. 2). ) Is omitted. Further, the electrode body 400 is illustrated in a simplified manner.
- the tab portion 420 of the electrode body 400 and the negative electrode current collector 150 are electrically connected via a negative electrode lead plate 155 having a U-shaped cross section.
- a connection structure is produced, for example, by the following procedure.
- the end portion (first end portion) of the flat negative electrode lead plate 155 and the tab portion 420 of the electrode body 400 are joined by, for example, ultrasonic welding. Further, the end (second end) opposite to the first end of the negative electrode lead plate 155 is joined to the negative electrode current collector 150 incorporated in the lid plate structure 180 by, for example, laser welding. Thereafter, the negative electrode lead plate 155 is deformed into a U shape by being bent at a predetermined position between the first end and the second end. As a result, as shown in FIG. 11, a connection structure between the tab portion 420 of the electrode body 400 and the negative electrode current collector 150 is formed via the negative electrode lead plate 155 having a U-shaped cross section.
- the upper spacer 500 is disposed between the end of the main body 430 on the side where the tab 420 is provided and the cover plate 110. More specifically, the joint portion between the tab portion 420 and the negative electrode lead plate 155 and the main body portion 430 of the electrode body 400 are partitioned by the upper spacer 500. The tab part 420 is inserted into the insertion part 520 provided in the upper spacer 500 and arranged. Further, a buffer sheet 600 is sandwiched between the upper spacer 500 and the main body 430 of the electrode body 400.
- FIG. 11 the structure around the negative electrode lead plate 155 is shown and described, but the structure around the positive electrode lead plate 145 is the same. That is, the tab portion 410 of the electrode body 400 and the positive electrode current collector 140 are electrically connected via a positive electrode lead plate 145 (see, for example, FIG. 2) having a U-shaped cross section. Further, the joint portion between the tab portion 410 and the positive electrode lead plate 145 and the main body portion 430 of the electrode body 400 are partitioned by the upper spacer 500, and the tab portion 410 is inserted into the insertion portion 520 provided in the upper spacer 500. Inserted and placed.
- the electrode body 400 is connected to the positive electrode current collector 140 and the negative electrode current collector 150 via the positive electrode lead plate 145 and the negative electrode lead plate 155, so that the tab portions 410 and 420 of the electrode body 400 are provided.
- the width (length in the winding axis direction (Z-axis direction)) of the electrode plates of the positive electrode 450 and the negative electrode 460 necessary for manufacturing the electrode body 400 can be made relatively short. This is advantageous from the viewpoint of manufacturing efficiency of the electrode body 400, for example.
- the binding sheet 360 is arrange
- FIG. 12 is a perspective view showing a binding state of the binding sheet 360 with respect to the electrode body 400 according to the embodiment.
- a binding sheet 360 is wound around the main body 430 of the electrode body 400.
- the binding sheet 360 is a belt-like member that stabilizes the form of the main body portion 430 and is wound around the outer peripheral portion of the main body portion 430.
- One end of the binding sheet 360 is overlapped with the other end, and the ends of the binding sheet 360 are fixed with an adhesive tape 390.
- the ends of the binding sheet 360 may be fixed by an adhesive, heat welding, or the like.
- An annular binding member may be used.
- the binding sheet 360 is made of an insulating material having resistance to electrolyte. Specific examples of the insulating material include PC, PP, PE, and PPS. Note that the step of winding the binding sheet 360 around the main body 430 may be omitted when the form of the main body 430 is stable.
- the adhesive tapes 370, 380, and 390 are formed of an insulating material whose base material has resistance to electrolytic solution. Specific examples of the insulating material include PC, PP, PE, and PPS. Further, the adhesive layer provided on one surface of the base material of the adhesive tapes 370 and 380 is also formed of an adhesive having an electrolytic solution resistance and an insulating property.
- the tab portion 410 of the electrode body 400 is welded to the flat plate to be the positive electrode lead plate 145, and the tab portion 420 of the electrode body 400 is welded to the flat plate to be the negative electrode lead plate 155.
- a flat plate serving as the positive electrode lead plate 145 is welded to the positive electrode current collector 140 of the cover plate structure 180, and the negative electrode lead plate 155 is bonded to the negative electrode current collector 150.
- the positive electrode lead plate 145 and the negative electrode lead plate 155 are formed by bending the flat plate to be the positive electrode lead plate 145 and the flat plate to be the negative electrode lead plate 155, respectively.
- the side spacer 700 is attached to the main body 430 of the electrode body 400. Specifically, as shown in FIG. 7, the side spacers 700 are individually attached to the curved portions 431 and 432 of the main body portion 430. On the curved portion 431 side, the positioning portion 715 of the side spacer 700 is engaged with the engaging portion 121 of the lower insulating member 120 which is a part of the lid plate structure 180, and the position of both is determined. 700 is fixed to the main body 430 with an adhesive tape 380. On the other hand, the side spacer 700 is fixed to the main body 430 with the adhesive tape 380 in the same process on the curved portion 432 side. After the fixing, as shown in FIG. 10, the cover plate 110 that is a part of the cover plate structure 180 is in contact with the base 710 that is one end of the side spacer 700.
- the binding sheet 360 is wound around the main body 430 of the electrode body 400, and the ends of the binding sheet 360 are fixed with the adhesive tape 390.
- FIG. 13 is a perspective view showing one step of the method for manufacturing the electricity storage device 10 according to the embodiment.
- the electrode body 400 around which the binding sheet 360 is wound is accommodated in the main body 111 of the container 100 in that state.
- the base 710 of the side spacer 700 is in contact with the lid plate 110 of the lid plate structure 180, when the lid plate structure 180 is pushed, The electrode body 400 moves toward the inside of the main body 111 of the container 100. During movement, the side spacer 700 slides along the inner peripheral surface of the main body 111, so that the electrode body 400 is smoothly guided to the inside of the main body 111.
- FIG. 14 is a cross-sectional view showing a positional relationship among the side spacer 700, the electrode body 400, and the container 100 according to the embodiment.
- the outer shape of the curved portion 432 of the main body portion 430 of the electrode body 400 is indicated by a two-dot chain line.
- the side spacer 700 is disposed along the side surface forming the short side of the housing recess 112 when viewed from the winding axis direction.
- the inner surface of the housing recess 112 has an R shape at the corner. Since the outer surface of the wall body 720 of the side spacer 700 is a smooth convex curved surface so as to correspond to this R shape, the side spacer 700 is in close contact with the main body 111 and stably holds the electrode body 400. It will be.
- the curved portion 432 of the electrode body 400 is disposed in the opening 740 of the side spacer 700 so that a part of the surface of the curved portion 432 is flush with the outer surface of the wall body 720.
- the main body 430 of the electrode body 400 can be firmly accommodated in the main body 111 while using the side spacer 700.
- the electrode body 400 or the like is accommodated in the main body 111 of the container 100, one end of the main body portion 430 of the electrode body 400 faces the cover plate structure 180.
- the cover plate 110 is welded to the main body 111 to assemble the container 100.
- the storage element 10 is manufactured by welding the injection plug 118 to the lid plate 110 and closing the injection port 117.
- the opening 740 of the side spacer 700 extends from one end to the other end in the winding axis direction of the electrode body 400, and the surfaces of the curved portions 431 and 432 of the electrode body 400. Since a part of the electrode body 400 is exposed, the main body 430 of the electrode body 400 can be disposed in the opening 740. Therefore, the installation space of the electrode body 400 can be widened, and the external dimensions of the electrode body 400 can be increased and the capacity can be increased without enlarging the entire storage element 10.
- the entire opening 740 can be used as a space for installing the electrode body 400. Therefore, the capacity of the power storage element 10 can be further increased.
- the side spacer 700 is provided for each of the two curved portions 431 and 432 of the electrode body 400, the side spacer 700 can be formed with a simple configuration.
- the electrode body 400 is disposed so that one end portion in the winding axis direction of the electrode body 400 faces the cover plate 110, the capacity can be increased by using the so-called laterally wound electrode body 400.
- the side spacer 700 is disposed between the container 100 and the electrode body 400 along the direction intersecting the main surface of the lid plate 110, the electrode body 400 is accommodated in the container 100. At this time, the side spacer 700 can be used as a guide, and the electrode body 400 can be smoothly guided into the container 100.
- the side spacer 700 is disposed along the side surface forming the short side of the housing recess 112, the side spacer 700 can be compared with the case where the side spacer is disposed along the side surface forming the long side of the housing recess 112. Can be reduced. Therefore, the installation space of the electrode body 400 can be further secured, and the external dimensions of the electrode body 400 can be increased.
- the apex portions of the bending portions 431 and 432 are included in a part of the surfaces of the bending portions 431 and 432 exposed by the opening 740, a part of the surface of the bending portion is included in the opening 740. It can be easily arranged.
- the number of electrode bodies 400 included in the electricity storage element 10 is not limited to 1, and may be 2 or more.
- the storage element 10 includes a plurality of electrode bodies 400, the dead space in the corner portion of the container 100 can be reduced as compared with the case where a single electrode body 400 is accommodated in the container 100 having the same volume (volume). For this reason, it becomes possible to increase the ratio of the electrode body 400 to the volume of the container 100, and as a result, the capacity
- the positional relationship between the positive electrode side tab portion 410 and the negative electrode side tab portion 420 of the electrode body 400 is not particularly limited.
- the tab portion 410 and the tab portion 420 may be disposed on opposite sides in the winding axis direction.
- the positive-side tab portion and the negative-side tab portion may be provided so as to protrude in different directions.
- the side spacer 700 may have any shape as long as the curved portions 431 and 432 can be exposed from one end to the other end of the electrode body 400 in the winding axis direction.
- the side spacers 700 integrally provided on the curved portions 431 and 432 of the electrode body 400 are individually provided is illustrated.
- the side spacer may be divided.
- FIG. 15 is a perspective view showing a state in which a modified example of the side spacer according to the embodiment is attached to the electrode body 400.
- the side spacer 700A is obtained by dividing the side spacer 700 of the above-described embodiment at the approximate center in the Z-axis direction, and includes a first member 760 and a second member 770.
- the first member 760 has a base 710 and a wall body 721.
- the second member 770 includes a bottom plate 730 and a wall body 722.
- the wall body 721 of the first member 760 and the wall body 722 of the second member 770 are spaced apart from each other in the Z-axis direction.
- the slit between the first wall body 721a and the second wall body 721b in the wall body 721 and the slit between the first wall body 722a and the second wall body 722b in the wall body 722 form an opening 740a.
- the opening 740a Through the opening 740a, a part of the surface of the curved portions 431 and 432 is exposed from one end to the other end of the electrode body 400 in the winding axis direction.
- FIG. 16 is a perspective view showing a state in which another modified example of the side spacer according to the embodiment is attached to the electrode body 400.
- the side spacers 700B attached to the curved portions 431 and 432 are connected and integrated by a beam portion 780.
- a beam portion 780 extending in the X-axis direction is stretched over one end portion of the pair of side spacers 700B.
- the installation location of the beam portion 780 may be any location as long as the capacity of the electrode body 400 is not significantly reduced.
- the rigidity can be increased and the assembly can be easily performed.
- the outer surface of the wall body 720 of the side spacer 700 is a smooth convex curved surface
- the outer surface of the wall 720 may have any shape as long as it corresponds to the inner surface shape of the main body 111 of the container 100.
- FIG. 17 is a cross-sectional view showing the positional relationship between another modified example of the side spacer according to the embodiment and the container 100.
- the main body 111 c of the container 100 ⁇ / b> C has a shape in which the inner surface has corner portions that are substantially perpendicular.
- the outer surface of the wall body 720c of the side spacer 700C has a shape having substantially right-angled corners corresponding to the inner surface shape of the main body 111c. Also in this case, since the side spacer 700C is in close contact with the main body 111c, the electrode body 400 can be stably held.
- the case where the cover plate 110 abuts on the base 710 which is one end of the side spacer 700 has been described as an example.
- the object that contacts the base 710 may be a part other than the cover plate 110 as long as it is a part of the cover plate structure 180, and a member (for example, a member located inside the container 100 relative to the cover plate 110) Lower insulating members 120 and 130, positive electrode current collector 140, negative electrode current collector 150, etc.) may be used.
- the positioning portion 715 of the side spacer 700 is the tip portion of the inner wall 714a, and the engaging portion 131 of the lid plate structure 180 has the notch portion 131a that engages with the positioning portion 715.
- the positioning part 715 and the engaging part 131 may have any shape as long as they can be engaged and aligned.
- the positioning portion 715 may be a boss that protrudes along the Z-axis direction, and a hole in which the boss is inserted may be provided in the engaging portion 131. In this case, movement in the X-axis direction in addition to the Y-axis direction can be restricted.
- the case where a part of the surfaces of the curved portions 431 and 432 of the electrode body 400 and the outer surface of the side spacer 700 are flush with each other has been described as an example.
- a part of the surface of the curved portions 431 and 432 may be disposed at least in the opening 740. Even in this case, since the installation space of the electrode body 400 can be expanded to the inside of the opening 740, the outer dimensions of the electrode body 400 can be increased as compared with the case where the opening 740 is not provided.
- the power storage element 10 including the insulating sheet 350 and the binding sheet 360 has been described as an example, but the insulating sheet 350 and the binding sheet 360 are not essential.
- the present invention can be applied to power storage elements such as lithium ion secondary batteries.
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- Microelectronics & Electronic Packaging (AREA)
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- Connection Of Batteries Or Terminals (AREA)
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Abstract
Description
以上、本発明に係る蓄電素子について、実施の形態に基づいて説明した。しかしながら、本発明は、上記実施の形態に限定されるものではない。本発明の趣旨を逸脱しない限り、当業者が思いつく各種変形を上記実施の形態に施したものも、あるいは、上記説明された複数の構成要素を組み合わせて構築される形態も、本発明の範囲内に含まれる。
100,100C 容器
110 蓋板
110a 貫通孔
110b 貫通孔
111,111c 本体
112 収容凹部
113 底
117 注液口
118 注液栓
120,130 下部絶縁部材
120a,130a 貫通孔
120b,130b 係合突部
121,131 係合部
122,132 取付部
125,135 上部絶縁部材
125a,126,135a,140a,150a 貫通孔
131a 切欠き部
133 リブ
140 正極集電体
145 正極リード板
150 負極集電体
155 負極リード板
160 膨出部
170 ガス排出弁
180 蓋板構造体
200 正極端子
210,310 締結部
300 負極端子
350 絶縁シート
360 結束シート
370,380,390 接着テープ
400 電極体
410,420 タブ部
411,421 突出部
430 本体部
431,432 湾曲部
450 正極
460 負極
470a,470b セパレータ
470c,470d はみ出し部分
500 上部スペーサ
510 係止部
520 挿入部
600 緩衝シート
700,700A,700B,700C サイドスペーサ(スペーサ)
710 基部
711 天板
712 壁部
713 周壁
714,714a,714b 内壁
715 位置決め部
720,720c,721,722 壁体
720a,721a,722a 第1壁体
720b,721b,722b 第2壁体
730 底板
740,740a 開口部
760 第1部材
770 第2部材
780 梁部
Claims (7)
- 電極が巻回されてなる電極体と、
前記電極体を収容する容器と、
前記容器と前記電極体との間に介在するスペーサとを備え、
前記スペーサは、
前記電極体の巻回軸方向における前記電極体の一端部から他端部まで、前記電極体の湾曲部の表面の一部を露出する開口部を有する
蓄電素子。 - 前記電極体の湾曲部の前記表面の一部は、前記開口部内に配置されている
請求項1に記載の蓄電素子。 - 前記電極体の前記表面の一部と、前記スペーサの外表面とが面一となっている
請求項1または2に記載の蓄電素子。 - 前記電極体は、前記湾曲部を2つ有する長円状であり、
前記スペーサは、2つの前記湾曲部に対して個別に設けられている
請求項1~3のいずれか一項に記載の蓄電素子。 - 前記電極体は、当該電極体の前記巻回軸方向の一端部が、前記容器の蓋板に対向する位置に配置されている
請求項1~4のいずれか一項に記載の蓄電素子。 - 前記容器は、前記巻回軸方向から見て矩形状の収容凹部を有し、
前記スペーサは、前記収容凹部の短辺をなす側面に沿って配置されている
請求項1~5のいずれか一項に記載の蓄電素子。 - 前記湾曲部の表面の一部は、前記湾曲部の頂点部分を含む領域である
請求項1~6のいずれか一項に記載の蓄電素子。
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US15/760,940 US10833298B2 (en) | 2015-09-18 | 2016-09-16 | Energy storage device |
CN201680053319.8A CN108028343B (zh) | 2015-09-18 | 2016-09-16 | 蓄电元件 |
DE112016004250.7T DE112016004250T5 (de) | 2015-09-18 | 2016-09-16 | Energiespeichervorrichtung |
JP2017540021A JP6825567B2 (ja) | 2015-09-18 | 2016-09-16 | 蓄電素子 |
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US (1) | US10833298B2 (ja) |
JP (1) | JP6825567B2 (ja) |
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JPWO2018180749A1 (ja) * | 2017-03-27 | 2020-02-06 | 三洋電機株式会社 | 角形二次電池及びそれを用いた組電池 |
WO2020218213A1 (ja) * | 2019-04-25 | 2020-10-29 | 株式会社村田製作所 | 二次電池 |
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WO2020218217A1 (ja) * | 2019-04-25 | 2020-10-29 | 株式会社村田製作所 | 二次電池 |
CN209880668U (zh) * | 2019-07-25 | 2019-12-31 | 宁德时代新能源科技股份有限公司 | 顶盖组件及二次电池 |
CN211017216U (zh) * | 2019-12-26 | 2020-07-14 | 宁德时代新能源科技股份有限公司 | 盖板组件、电池单体、电池模块、电池组及装置 |
CN117480674A (zh) * | 2021-03-31 | 2024-01-30 | 艾诺维克斯公司 | 具有保护层的电池组合件及其制造方法 |
US11699830B2 (en) | 2021-06-15 | 2023-07-11 | Enovix Operations Inc. | Spacers for providing protection of electrochemical battery enclosures and systems and methods therefor |
WO2024016273A1 (zh) * | 2022-07-21 | 2024-01-25 | 宁德时代新能源科技股份有限公司 | 电池单体、电池及用电设备 |
CN115566375B (zh) * | 2022-11-11 | 2023-03-10 | 深圳海润新能源科技有限公司 | 储能设备以及用电设备 |
CN116799390B (zh) * | 2023-08-29 | 2023-12-26 | 深圳海辰储能控制技术有限公司 | 下塑胶、端盖组件、储能装置及储能*** |
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- 2016-09-16 WO PCT/JP2016/077538 patent/WO2017047784A1/ja active Application Filing
- 2016-09-16 DE DE112016004250.7T patent/DE112016004250T5/de active Pending
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CN108028343B (zh) | 2021-07-09 |
US20180261806A1 (en) | 2018-09-13 |
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JPWO2017047784A1 (ja) | 2018-08-09 |
CN108028343A (zh) | 2018-05-11 |
JP6825567B2 (ja) | 2021-02-03 |
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