WO2017044684A1 - Procédés de séparation d'ozone - Google Patents
Procédés de séparation d'ozone Download PDFInfo
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- WO2017044684A1 WO2017044684A1 PCT/US2016/050867 US2016050867W WO2017044684A1 WO 2017044684 A1 WO2017044684 A1 WO 2017044684A1 US 2016050867 W US2016050867 W US 2016050867W WO 2017044684 A1 WO2017044684 A1 WO 2017044684A1
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- WIPO (PCT)
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- adsorbent bed
- oxygen
- ozone
- adsorbent
- mixture
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/14—Ozone
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/104—Oxygen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40043—Purging
- B01D2259/4005—Nature of purge gas
- B01D2259/40056—Gases other than recycled product or process gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/404—Further details for adsorption processes and devices using four beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/406—Further details for adsorption processes and devices using more than four beds
- B01D2259/4065—Further details for adsorption processes and devices using more than four beds using eight beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/406—Further details for adsorption processes and devices using more than four beds
- B01D2259/4068—Further details for adsorption processes and devices using more than four beds using more than ten beds
Definitions
- Ozone is utilized in a number of industrial processes, including drinking water and waste water treatment and disinfection, pulp bleaching, ozonolysis reactions in fine chemical production, and flue-gas denitrification,
- Ozone is unstable decomposing to oxygen under ambient conditions and hence cannot be manufactured, transported and stored in the manner of typical chemicals of commerce. Instead, ozone must be produced at point-of-use at the time it is needed. Since ozone is a toxic material its generation only where and when it is required limits the possibility and potential impact of incidents.
- Ozone is typically generated from oxygen utilizing a corona discharge. If oxygen is used as the source of oxygen for a given ozone generator then ozone concentrations of 10 to 15% by weight (balance oxygen) can be prepared. If air is used as the source of oxygen then ozone concentrations of 1 .5 to 3% (balance air) can be prepared. For moderate to large ozone requirements, the overall capital plus operating costs are typically less when oxygen is used as the oxygen source.
- Ozone is therefore often utilized at 10 wt%, ozone with the balance being largely oxygen. It has long been recognized that the re-use of the oxygen from the ozone/oxygen mixture generated by oxygen-based ozone generators would substantially improve the economics for ozone generation. Many schemes have been proposed for the separation of ozone from the ozone/oxygen output stream from the ozone generator, thus allowing oxygen to be recycled back to the ozone generator. In most of these schemes the separated ozone is displaced into the final ozone-utilizing process by means of an inert gas stream. Balcar et al.
- US Pat No 4,786,489 targets reducing the costs for large scale ozone and teaches the use of a low temperature (-80 to -90°C) ozone/oxygen separation unit that is purged with an impure nitrogen carrier gas stream containing oxygen and/or air to give the ozone product.
- US Pat No 5,520,887 is targeted at reducing the costs of ozone generation for pulp bleaching and teaches the use of a PSA oxygen generator to provide an enriched oxygen feed to an ozone generator, an oxygen ozone PSA to adsorb ozone and at the same time recycle oxygen to the ozone generator.
- the nitrogen rich waste gas from the O2 PSA is used to purge adsorbed ozone from the ozone oxygen PSA to the ozone consuming process.
- US Pat No 6,030,598 describes the production of an ozone containing gas stream by subjecting oxygen to an electric discharge, adsorbing the ozone thus generated on to a solid adsorbent (such as zeolite) and recycling the oxygen containing stream leaving the adsorbent to the ozonising process.
- a solid adsorbent such as zeolite
- oxygen adsorbed on the adsorbent is desorbed by co-currently passing a purge gas over the adsorbent and the desorbed oxygen is also recycled to the ozonizer.
- Ozone is desorbed from the adsorbent by a counter- current flow of purge gas and used in the ozone demanding process.
- a 3-bed (or multiple thereof) process and cycle is described that allows ozone and recycled oxygen to be produced continuously, but still requires each bed to experience a non-productive hold step within a full cycle.
- US Pat No 6,197,091 describes the use of an ozone/oxygen membrane separation system in which ozone permeates through the membrane and is carried with a carrier gas, such as nitrogen, argon or CO2 into the ozone utilizing application, and at the same time the oxygen enriched stream is recycled to the ozone generator.
- a carrier gas such as nitrogen, argon or CO2
- US Pat No 6,916,359 describes a method of providing ozone at a pressure above atmospheric pressure that comprises an ozone generator and an oxygen ozone PSA system.
- the unadsorbed oxygen from the PSA is recycled back to the ozone generator and the ozone product is carried into the ozone application by means of an inert gas stream at a pressure such that no further compression is needed.
- the carrier gas can be nitrogen, but is preferentially compressed air used also to feed a PSA oxygen generator that can be used as the oxygen source.
- US Pat No 7,766,995 is targeted at reducing the cost of ozone utilized in the removal and capture of NOx from industrial flue-gas and other process streams. It teaches the use of an oxygen ozone separation means to allow recycle of oxygen back to the ozone generator and the use of clean dry air to carry the ozone into the industrial process. Optimum ozone production costs are achieved by recycling oxygen to the ozone generator, using the cheapest possible carrier gas to carry the ozone to the point of use, and reducing the power utilization in the ozone generator by operating the generator at lower ozone concentrations than normal (e.g., 6%).
- a method for the constant production of ozone and recovery of oxygen in a purge cycle adsorption process having four adsorbent beds comprising the steps: a) Feeding an oxygen and ozone gas mixture to a first adsorbent bed and a second adsorbent bed wherein the feeding of the oxygen and ozone gas mixture to the first adsorbent bed is stopping as the feeding to the second adsorbent bed is starting, and recovering oxygen from the first adsorbent bed and the second adsorbent bed and recycling the oxygen to a source of the oxygen and ozone gas mixture, wherein the first adsorbent bed and the second adsorbent bed were previously rinsed with oxygen before receiving the oxygen and ozone gas mixture; b) Feeding a second mixture of oxygen and ozone gas into a third adsorbent bed, wherein the second mixture of oxygen and ozone gas pushes nitrogen from the third adsorbent bed
- the oxygen and ozone gas mixture is first fed to the third adsorbent bed and the fourth adsorbent bed, and the second mixture of oxygen and ozone gas is fed to the first adsorbent bed and the second adsorbent bed.
- Step b) begins in the middle of step a).
- Step d) begins in the middle of step c).
- the second mixture of oxygen and ozone gas is fed to the third adsorbent bed and the fourth adsorbent bed.
- the method further comprises feeding a third mixture of oxygen and ozone gas to the first adsorbent bed and the second adsorbent bed.
- the oxygen and ozone gas mixture that is fed to the first adsorbent bed and the second adsorbent bed comprises about 1 to 30% by volume ozone.
- the oxygen and ozone gas mixture that is fed to the first adsorbent bed and the second adsorbent bed preferably comprises about 8 to 10% by volume ozone.
- the source of nitrogen can be clean dry air.
- the first adsorbent bed and the second adsorbent bed are successive beds of the four adsorbent beds.
- the ozone is adsorbed in the first adsorbent bed and the second adsorbent beds in step a).
- Buffer tanks are connected to a source selected from the group consisting of the recovered ozone, the recycled oxygen and both.
- the first adsorbent bed, the second adsorbent bed, the third adsorbent bed and the fourth adsorbent bed all contain an adsorbent material.
- the adsorbent material is selected from the group consisting of silica gel and high silica zeolites.
- the cycle is a concentration swing adsorption cycle.
- a method for the constant production of ozone and recovery of oxygen in a purge cycle adsorption process having four adsorbent beds comprising the steps: a) Feeding an oxygen and ozone gas mixture to a first adsorbent bed and a second adsorbent bed wherein the feeding of the oxygen and ozone gas mixture to the first adsorbent bed is stopping as the feeding to the second adsorbent bed is starting, and recovering oxygen from the first adsorbent bed and the second adsorbent bed and recycling the oxygen to a source of the oxygen and ozone gas mixture, wherein the first adsorbent bed and the second adsorbent bed were previously rinsed with oxygen before receiving the oxygen and ozone gas mixture; b) Feeding a second mixture of oxygen and ozone gas into a third adsorbent bed, wherein the second mixture of oxygen and ozone gas pushes nitrogen from the third adsorbent bed into the first
- the adsorbent, preferably silica gel bed design uses different particle sizes for the separation of ozone from the mixture of oxygen and ozone.
- high silica zeolites such as DAY, MFi or dealuminated mordentite may be employed in place of the silica gel.
- Venting of contaminants from the process will limit the build up of contaminants and harmful hydrocarbons that can cause damage to the ozone generator.
- the bed purge step allows reuse of a purge gas and preserves oxygen gas compared to other processes.
- the method utilizes four beds but eight and twelve bed cycles using similar steps can be employed as well.
- the regeneration of the adsorbent bed using purge gas at elevated temperature not greater than 100°C improves regeneration and can be used to deliver ozone in higher concentrations as well as potentially reduce the size of the adsorbent bed.
- the adsorption of the ozone and oxygen mixture can be at
- the feed to the ozone generator and/or the first adsorbent bed could be compressed to pressures up to 50 psig (3.44 bar) to increase the adsorption capacity of the adsorbent thereby reducing the size of the adsorbent beds.
- the purge gas could be dry air or other nitrogen-rich gas stream with a dew point of -80 °F or lower.
- the beds may be equipped with an internal source of heating or cooling to maximize the use of the adsorbent material.
- the feed to the adsorbent bed can be from the top of the bed and the purge can be performed from the bottom of the adsorbent bed.
- An external ozone buffer tank can be employed, in the line taking the ozone product to the customer process to reduce swings in ozone purity.
- the four bed method can be a continuous means to remove ozone from the ozone and oxygen gas mixture while minimizing the pressure or concentration swing impact in recycled oxygen gas and ozone product gas.
- Figure 1 is a schematic of the inventive four bed process to recover oxygen from an ozone and oxygen gas mixture.
- Figure 2 is a schematic of the cycle steps for the four bed oxygen recovery process.
- Figure 3 is a valve table illustrating the valve positions of Figure 1 in different cycle sequence steps.
- Figure 4 is a schematic illustrating step 1 for the bed D from Figure 1.
- Figure 5 is a schematic illustrating step 2 for the bed D from Figure 1.
- Figure 6 is a schematic illustrating step 3 for the bed D from Figure 1 .
- Figure 7 is a schematic illustrating step 4 for the bed D from Figure 1.
- Figure 8 is a schematic illustrating step 5 for the bed D from Figure 1 ⁇ DETAILED DESCRIPTION OF THE INVENTION
- the method of the present invention is an adsorption process for separating ozone from a mixture of oxygen and ozone in a process using four adsorption beds. It is envisioned that the process can be extended to include eight or twelve beds using similar sequence steps for the four bed as discussed below.
- the method of the present invention uses silica gel as the adsorbent material to adsorb ozone.
- This adsorbent material is designed to have low metal contamination to prevent dissociation of ozone molecules back to oxygen molecules.
- the adsorbent material is selected from the group consisting of silica gel and high silica zeolites, such as DAY, MFI or
- the beds as identified in Figure 1 as A, B, C and D have three layers of different sizes of silica gel.
- the first layer at the bottom of the bed contains larger particle sizes of 3 to 5 millimeter in size. This layer is designed in part to allow higher initial flow of gas into the process without danger of fluidization of the bed. This layer is between 5 to 15% of the total weight of silica gel adsorbent being used in the process.
- the second layer from the bottom or middle layer has a smaller particle size and thereby high adsorption capacity and faster diffusion kinetics to allow faster cycle steps.
- the smaller particle sizes are typically 0.5 to 1.5 millimeter. These particles will allow better gas distribution due to higher pressure drop.
- the top layer has a larger particle size. This layer will account for 5 to 15% of the total weight of adsorbent used in the process. The larger particle size allows lower susceptibility to fluidization of the top layer. These particles are typically 3 to 5 millimeters in size.
- the beds are designed to operate at about 0.5 to 2.5 pounds per square inch (psi) pressure drop during operation.
- Figure 1 is a 4-bed oxygen recovery schematic of the invention.
- Make up oxygen is supplied to the system through line 20 where it is mixed with recycled oxygen from the beds.
- the combined oxygen stream is fed through blower 9 to an ozone generator 7.
- the ozone generator will generate ozone at concentrations of 1 to 30%, pref. 5-15%, most pref. 8-10% by volume which is then fed through line 30 a manifold used to supply oxygen/ozone mixtures to the bottom of the adsorbent beds.
- Ozone is adsorbed within the selected adsorbent bed or beds.
- Line 40 collects the oxygen that passes un- adsorbed through the tops of the selected beds and recycles this stream back to the inlet to the blower 9 where it is mixed with make up oxygen.
- Line 50 supplies the external nitrogen rich purge gas to the tops of the beds that is used to desorb the ozone from said bed or beds.
- Line 60 collects the ozone product displaced from the bottom of the beds to the customer process.
- Manifold 70 allows oxygen rich gas to be passed from the top of a first bed to the top of a second bed, thus removing residual nitrogen from said second bed and optionally allowing any contaminants or excess inert gases to be vented externally through valve 6.
- X represents an adsorbent bed and this can be any of A, B, C or D as depicted in Figure 1. Likewise reference to a valve number preceded by X should be interpreted as being for that valve number for any of the beds A, B, C or D.
- Valves X4 connect the bottom of bed X to the oxygen/ozone manifold, Line 30, Valves X1 connect the top of Bed X to the recycle oxygen Line 40.
- Valves X3 connect the top of bed X to the external nitrogen rich purge gas stream line 40.
- Valves X5 connect the bottoms of the bed to Line 60 the ozone product line to the customer.
- Valves X2 connect the top of bed X to the manifold 70 that allows gas to be transferred between the tops of two of the beds and optionally vented externally via Valve 6.
- Figure 2 depicts the sequence of steps that are undergone in the four bed oxygen recovery process of this invention.
- step 1 of the process S1 the feed gas from the ozone generator enters the bed X through valve X-4.
- the ozone in the feed gas is selectively adsorbed on the adsorbent in bed X.
- the recovered oxygen passes through the bed X and through valve X-1 and is sent to the recycle circuit.
- the recovered oxygen is mixed with the makeup oxygen.
- the net oxygen is then compressed by a blower to overcome the pressure loss in the system and is sent to the ozone generator.
- step 2 (S2) of the cycle is initiated.
- a stream of initially nitrogen rich purge gas from another bed is fed from the top of bed X through valve X2.
- the purge gas comes from a bed which has just switched to oxygen/ozone feed gas and is under going step 4 (S4) and step 5 (S5) at that time.
- the purge gas causes the ozone adsorbed in the bed X to get desorbed and pass through valve X5 to give product ozone to the customer.
- an external purge gas stream is introduced into the process through valve X3 in step 3 (S3).
- This external purge gas can be either dry air or any other dry nitrogen rich gas with a dew point less than -80°F.
- the purge gas further desorbs ozone on the adsorbent bed X and passes through valve X5 as product in a manner similar as in S2.
- step 4 the feed gas from the ozone generator is reintroduced through valve X4.
- This commences step 4 (S4).
- the resulting unadsorbed gas at the top of the bed X initially has more nitrogen content from the purge step S3.
- This gas is utilized as a purge gas for another bed through valve X2. Also a portion of this gas is vented from the process through the vent valve to prevent the build up of unwanted contaminants like argon, hydrocarbons or water in the recycle oxygen gas.
- step 4 depends on the nature and amounts of impurities that can be tolerated in the feed to the ozone generator. Under some circumstances this step may be omitted or utilized only intermittently, e.g. once every x cycles. The duration of step 4 plus step 5, or step 5 alone if step 4 is omitted, depends on the level of nitrogen required in the feed to the ozone generator.
- FIG 3 is an overview of the adsorption process sequence steps S1 through S5 versus the status of the valves as being either "o" (open) or "c" (closed).
- the valves identified are those from Figure 1 (X-1 , X-2, X-3, X-4 and X- 5 where X can be one or more of A, B, C or D and valve 6).
- the sequence steps identified as S1 , S2, S3, S4 and S5 are those discussed above with reference to Figure 2.
- Step S4 and S5 When Bed B is in step S2 then Bed D undergoes Steps S4 and S5, and visa-versa.
- the internal purge step S2 vs S4/S5 for beds A and C occur in the middle of the oxygen recycle and ozone production steps S1/S3 for beds B and D, and visa-versa.
- the offset cycles of the subsets of beds, A / C and B / D ensure that, e.g.
- the last portion of bed A being on step S1 overlaps with the first portion of bed B being on step S1
- the last portion of bed B being on step S1 overlaps with the first portion of bed C being on step S1
- the last portion of bed C being on step S1 overlaps with the first portion of bed D being on step S1
- the last portion of bed D being on step 1 overlaps with the first portion of bed A being on step S1 , and so on, and likewise for step 3.
- the step time for step S1 is equal to the step time for step S3, and falls in the range 5 to 500 seconds pref. 30 to 250 seconds and most preferably 60 to 120 seconds.
- step time for step S2 equal to the sum of the step times of steps S4 and S5. and falls in the range 5 to 30% of the step time of step S1 , pref. 10 - 20% of S1.
- the 4 bed cycle of the current invention allows for the continuous production of recycle oxygen and of ozone in the external purge gas stream. Operation of the cycle in concentration swing mode, i.e. with the minimum of pressure or temperature swings between the adsorption and desorption steps, ensures that the pressures of the two product streams remain roughly constant. This mode of operation, together with the novel overlapping steps, allows the system to run without the need for large buffer tanks.
- Small buffer tanks may, however, be added to one or both of the recycle oxygen and ozone product lines, in order to meet stringent needs imposed by the ozone generator manufacturer or the ozone customer.
- the regeneration of the adsorbent bed using purge gas at elevated temperature not greater than 100°C improves regeneration and can be used to deliver ozone in higher concentrations as well as potentially reduce the size of the adsorbent bed.
- the adsorption of the ozone and oxygen mixture can be at temperatures down to 0°C thereby reducing the size of the adsorbent beds.
- the feed to the ozone generator could be compressed to pressures up to 50 psig (3.44 bar) to increase the adsorption capacity of the adsorbent thereby reducing the size of the adsorbent beds.
- Figures 4 through 8 are individual breakdowns of each step S1 through S5 described above in greater detail as exemplified for adsorbent bed D,
- adsorbent bed D is on the feed and recycle step.
- Makeup oxygen is fed through line 20 to blower 9 which will deliver pressurized oxygen through line 22 to ozone generator 7.
- the resulting mixture of ozone and oxygen is fed through line 24 and open valve D4 via line 30 to adsorbent bed D where ozone is adsorbed and the oxygen is fed through line 40 and open valve D1 back to line 20 to join with the makeup oxygen feed.
- adsorbent bed D is on bed purge step, S2.
- Line 70 delivers a purge gas which is removed from the top of bed B and is fed through open valve D2 into adsorbent bed D where it will sweep out part of the ozone adsorbed from S1.
- the ozone exits the adsorbent bed D through line 32 and open valve D5 to line 62 where it will be collected in Line 60 and delivered to the customer process.
- adsorbent bed D is on the third step S3 which is external purge step.
- An external purge gas which comprises air or another nitrogen rich gas is fed through line 50 and open valve D3 via line 52 into adsorbent bed D where it will sweep the adsorbed ozone out of the adsorbent and be fed through line 32 and open valve D5 to line 62 where the ozone can be collected in line 60 and delivered to the customer process.
- Figure 7 is the send purge and vent step S4 for adsorbent bed D.
- Makeup oxygen is fed through line 20 to blower 9 which will deliver pressurized oxygen through line 22 to ozone generator 7.
- the resulting mixture of ozone and oxygen is fed through line 24 and open valve D4 to adsorbent bed D via line 30.
- Oxygen will exit the adsorbent bed D through line 72 and open valve D2 after ozone is adsorbed from the mixture of oxygen and ozone.
- the oxygen will be fed through line 72 to line 70 where it will be directed to the top of another bed, B which is in step S2, where it will act to purge that bed as well as be fed through open valve 6 for venting to the atmosphere.
- the adsorbent bed D is on step 5 which is the send purge step S5.
- Makeup oxygen is fed through line 20 to blower 9 which will deliver pressurized oxygen through line 22 to ozone generator 7.
- the resulting mixture of ozone and oxygen is fed through line 24 and open valve D4 via line 30 to adsorbent bed D.
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- Separation Of Gases By Adsorption (AREA)
Abstract
L'invention concerne un procédé pour séparer l'ozone d'un mélange d'oxygène et d'ozone par acheminement du mélange vers au moins un lit adsorbant contenant un matériau adsorbant pour adsorber l'ozone. Le lit adsorbant peut être l'un des quatre lits adsorbants dans un cycle d'adsorption continue pour produire l'ozone recyclant l'oxygène non adsorbé conjointement avec l'oxygène d'appoint au niveau du générateur d'ozone, ou l'utiliser comme gaz de purge. Un gaz de purge externe est utilisé pour désorber l'ozone au niveau du processus client. Lorsque quatre lits sont présents, la plupart du temps, deux lits sont en mode d'adsorption tandis que les deux autres lits sont dans le mode de régénération/production.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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US201562216545P | 2015-09-10 | 2015-09-10 | |
US62/216,545 | 2015-09-10 | ||
US201615259775A | 2016-09-08 | 2016-09-08 | |
US15/259,775 | 2016-09-08 |
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WO2017044684A1 true WO2017044684A1 (fr) | 2017-03-16 |
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PCT/US2016/050867 WO2017044684A1 (fr) | 2015-09-10 | 2016-09-09 | Procédés de séparation d'ozone |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4786489A (en) * | 1985-04-16 | 1988-11-22 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Ozone-producing process |
US5507957A (en) * | 1992-03-31 | 1996-04-16 | Garrett; Michael E. | Treating materials with ozone |
US5520887A (en) * | 1993-11-22 | 1996-05-28 | Ishikawajima-Harima Heavy Industries Co., Ltd. | Apparatus for generating and condensing ozone |
US6916359B2 (en) * | 2002-04-25 | 2005-07-12 | The Boc Group, Inc. | Ozone production processes |
US20090293717A1 (en) * | 2008-06-02 | 2009-12-03 | Jun Izumi | Method and apparatus for producing and storing ozone using adsorbent |
-
2016
- 2016-09-09 WO PCT/US2016/050867 patent/WO2017044684A1/fr active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4786489A (en) * | 1985-04-16 | 1988-11-22 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Ozone-producing process |
US5507957A (en) * | 1992-03-31 | 1996-04-16 | Garrett; Michael E. | Treating materials with ozone |
US5520887A (en) * | 1993-11-22 | 1996-05-28 | Ishikawajima-Harima Heavy Industries Co., Ltd. | Apparatus for generating and condensing ozone |
US6916359B2 (en) * | 2002-04-25 | 2005-07-12 | The Boc Group, Inc. | Ozone production processes |
US20090293717A1 (en) * | 2008-06-02 | 2009-12-03 | Jun Izumi | Method and apparatus for producing and storing ozone using adsorbent |
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