WO2016186570A1 - A method of optimising energy usage - Google Patents

A method of optimising energy usage Download PDF

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Publication number
WO2016186570A1
WO2016186570A1 PCT/SG2015/000127 SG2015000127W WO2016186570A1 WO 2016186570 A1 WO2016186570 A1 WO 2016186570A1 SG 2015000127 W SG2015000127 W SG 2015000127W WO 2016186570 A1 WO2016186570 A1 WO 2016186570A1
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Prior art keywords
composition
coating
metal oxide
parts
weight
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PCT/SG2015/000127
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French (fr)
Inventor
Ah Eng Siaw
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Ah Eng Siaw
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Priority to PCT/SG2015/000127 priority Critical patent/WO2016186570A1/en
Priority to MYPI2017704380A priority patent/MY194904A/en
Publication of WO2016186570A1 publication Critical patent/WO2016186570A1/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals

Definitions

  • This invention relates to a method of optimising energy usage. More particularly, the present invention relates to a method of inducing electron vibration alignment in an electromechanical device to reduce energy loss as heat during flow of electricity.
  • Electricity has becoming an inescapable need for human and without electricity, human life would be in a chaos.
  • electricity can be costly as the existing methods of generating electricity or electrical energy are mainly dependent on non-renewable resources.
  • people are focusing on ways to minimise energy consumption or optimising energy usage, to reduce cost as well as to minimise negative impact to the environment as a result of extracting energy from the non-renewable resources.
  • Energy audit is done to identify possible reduction of energy input into a system without negatively affecting the performance or output.
  • Energy saving material such as a superconductor, which has a higher electrical conductivity and lower electrical resistance, is also developed as an alternative to the conventional conductive material. Despite some reduction in energy usage can be achieved, a substantial amount of energy loss as heat is unavoidable due to random and irregular electron spin.
  • Electricity involves the flow of electrons within a closed electric circuit. Typically, the flowing electrons move in a free and irregular manner rather being flow in a straight path therefore collision between atoms of the circuit occur. A substantial amount of energy is lost as heat due to the irregular movement of the electrons before reaching a load. The degree of energy loss is also dependent on the specification of a conductive wire used such as, material, diameter, length, resistivity, and temperature. In view of the above problems, there is a need to further optimise energy usage in which less energy is needed to drive an electric current as well as less energy is loss from irregular movement of electrons. Hence, it is desirable to develop a method of improving electrons flow or reducing irregular movement of electrons. This invention provides a solution to the problem.
  • One of the objects of the invention is to provide a method of optimising electrical energy consumption of an electromechanical device by coating a composition on a surface of the device.
  • Another object of the invention is to provide a use of a coating on a surface of an electromechanical device in which the coating can induce electron vibration alignment in the device thereby reducing energy loss or optimising energy consumption.
  • the embodiment of the present invention describes a method of reducing energy loss from an electromechanical device comprising the step of coating the surface of the device or a casing surrounding the device with a composition comprising a nano-sized particulate metal oxide; a binder; a liquid carrier; and a surface additive.
  • the electromechanical device is an electrical distribution board, a cable, an isolator, an inverter, a variable speed drive, or surface of a junction box.
  • the metal oxide is an oxide of platinium, titanium, silver, copper, tin, gold, or a mixture thereof;
  • the binder is a silane;
  • the surface additive is sulphuric acid, phosphoric acid, nitric acid, or hydrochloric acid;
  • the liquid carrier is a silicone oil, an alcohol, or a mixture thereof.
  • the silicone oil is hexamethyl disiloxane, octamethyl trisiloxane, decamethylcyclo pentasiloxane, polydimethyl siloxane or octamethylcyclo tetrasiloxane; and the alcohol is isopropanol, methanol, or ethanol.
  • the composition comprises 0.1 to 10 parts by weight of metal oxide, 0.1 to 30 parts by weight of binder, 75 to 94 parts by weight of liquid carrier, and 0.1 to 8 parts by weight of surface additive.
  • the thickness of the coating is at least 2 ⁇ .
  • This invention relates to a method of optimising energy usage. More particularly, the present invention relates to a method of inducing electron vibration alignment in an electromechanical device to reduce energy loss as heat during flow of electricity:
  • the invention discloses a method of reducing energy loss from an electromechanical device comprising the step of coating the surface of the device or a casing surrounding the device with a composition comprising a nano-sized particulate metal oxide; a binder; a liquid carrier; and a surface additive.
  • energy loss in an electromechanical device such as, but is not limiting to, electrical distribution board, cable, isolator, inverter, variable speed drive, or junction box is reduced by coating any surface of the device with the composition which comprises a nano-sized particulate metal oxide; a binder; a liquid carrier; and a surface additive.
  • the surface of the device may not be limited to any kind of material and, it can be made from glass, plastics material, metal, or rubber.
  • the coating has a thickness of at least 2 ⁇ so as to sufficiently provide an advantageous effect to the device which will be described later. However, it is not necessary to have a coating thickness of more than 5 ⁇ as additional thickness would have no or only minimal improvement in the advantageous effect.
  • the atoms of the coating hold sufficient energy which causes them to vibrate at a predetermined frequency similar to the natural frequency of the device for a period of time.
  • the atoms of the coating transferred the vibration energy to the atoms of the device, particularly the atoms of conductive wires, in all direction at a distance ranging from 300 mm to 600 mm. With that, the atoms of the device are induced to vibrate at a similar frequency. Particularly, the atoms of the device are vibrating at their natural frequency where resonance occurs. Electron vibration alignment on the affected area of the device occurs, in which randomly spinning electrons are forced to align and spinning uniformly.
  • the composition can be coated evenly on the surface of the electromechanical device by any coating method for example, but is not limiting to, hand spray. It shall be noted that the surface to be coated shall be clean and free from solid impurities to enhance binding of the composition to the surface. After coating the composition on the surface, the coating can be cured at room temperature.
  • the atoms of the composition shall hold the vibration energy for at least 1 month. Thereafter, recoating of the composition may be required.
  • the composition comprises particles of metal oxide, preferably in a scale of nano size. Smaller particle size is preferred as larger surface area is provided for capturing, holding, and releasing of the vibration energy.
  • the metal for the metal oxide can be selected from the group, but not limiting to, consisting of titanium, silver, copper, tin, or gold.
  • One skilled in the art shall not limit the metal oxide to one type of metal oxide; rather it can be a mixture of two or more types of metal oxide.
  • High electrical conductivity metal is preferred as it can hold higher charge and therefore, higher ability and capacity to hold vibration energy of which thereafter is transferred to the coated device.
  • the composition comprises 0.1 to 10 parts by weight of metal oxide. The amount of energy transferred to induce resonance may not be sufficient for less than 0.1 parts by weight of metal oxide. However, any amount more than 10 parts by weight of metal oxide would not provide any additional advantageous effect.
  • the particles of metal oxide are contained within a liquid carrier so that the prepared composition is readily to be applied and coated on a surface.
  • the liquid carrier also acts as a medium of transferring energy from an energy source to the metal oxide or from the metal oxide to the atoms of the device. Any kind of liquid carrier which does not react with the metal oxide can be used.
  • the liquid carrier is a silicone oil, an alcohol, or a mixture thereof.
  • the alcohol can be selected from isopropanol, methanol, or ethanol
  • the silicone oil can be selected from hexamethyl disiloxane, octamethyl trisiloxane, decamethylcyclo pentasiloxane, polydimethyl siloxane or octamethylcyclo tetrasiloxane.
  • the presence of silicone oil also provides the surface with a smooth appearance as well as anti-stick characteristics so that dust or other solid impurities will not adhere to the surface.
  • the composition comprises 75 to 94 parts by weight of liquid carrier.
  • a binder is needed to ensure the coating binds well to the surface to be coated.
  • the binder is a silane.
  • the silane is an alkyl silane.
  • the alkyl silane can be selected from methyl silane, dimethydiethoxysilane, tetraethoxysilane, linear dialkylsilane, fluorinated alkyl silane, or cyclic alkylsilane.
  • Any silane binder which can render the composition be cured at room temperature and reduced curing time can be used.
  • the composition comprises 0.1 to 30 parts by weight of binder.
  • surface additive is added to further enhance binding of the coating to the surface to be coated.
  • the surface additive is an acid to decrease the pH of the composition.
  • the acidic composition may slightly etch the surface and form bonds between the composition and the surface.
  • the amount of acid added shall not be high to the extent that the pH of the composition falls below 5 or become strongly acidic.
  • the composition has a pH ranging from 5 to 6 which effectively enhance binding of the coating without causing any corrosion to any part of the device.
  • the acid can be selected from sulphuric acid, phosphoric acid, nitric acid, or hydrochloric acid.
  • An alkaline composition is not preferred as it may render the coating to be easily detached from the surface due to .
  • the composition comprises 0.1 to 8 parts by weight of surface additive. More preferably, the composition comprises less than 2 parts by weight of surface additive.
  • the composition for the use in the method as described in any of the preceding description can be produced with the following method.
  • the metal oxide, binder, liquid carrier, and surface additive are homogeneously mixed one at a time.
  • the order of mixing is preferred to be binder, surface additive, liquid carrier, and metal oxide.
  • metal oxide shall not be added before silane in order to achieve a homogeneous mixture.
  • the composition is homogenised by an ultrasonic mixer operating at a frequency of 20 kHz to 60 kHz for at least 0.5 hour. However, it is not necessary to mix the composition for more than 2 hours to achieve a homogeneous mixture. Any other method of homogenising the mixture can be adopted.
  • nano particulates metal oxide can be further broken down into smaller size with a higher surface area to capture, hold, and release the vibration energy.
  • the mixture is subjected to bombardment with a vibration force at a frequency of 20 kHz to 1000 KHz for at least 12 hours to store energy within the nano-particles.
  • the vibration force can be provided in any form. However, it shall be noted that the vibration force shall not be induced by any kind of magnetic field in which the magnetic energy held within the atoms of the composition may cause impairment on the device.
  • the vibration force is provided by an ultrasonic means.
  • the homogenisation step and bombardment step can be in a single operation in which only ultrasonic treatment is utilised. After mixing the composition, the mixture is subjected to ultrasonic treatment where homogenisation and energy capturing occur simultaneously.
  • the ultrasonic frequency is preferably at 20 kHz to 1000 KHz and the treatment is preferably last for at least 12 hours, more preferably for at least 24 hours.
  • composition produced using single operation method is prone to have phase separation. Although phase separation may not affect the performance of the composition, the aesthetic view of the composition may not be welcome by the user.
  • the homogenisation step and bombardment step can be in two separate operations even only ultrasonic treatment is utilised.
  • the binder, surface additive, and liquid carrier are mixed and homogenise by ultrasonic mixer at a frequency of 20 kHz to 60 kHz for at least 0.5 hour, preferably not more than 2 hours.
  • metal oxide is added to the homogenised mixture.
  • the resultant mixture is subjected to ultrasonic treatment at a frequency of 20 kHz to 1000 kHz for at least 12 hours, more preferably for at least 24 hours.
  • Example 1 The composition as shown in Table 1 is mixed one by one. The mixture is subjected to ultrasonic treatment at a frequency of 50 kHz for 24 hours.
  • the composition is as shown in Table 2.
  • Methysilane, dimethyl diethoxysilane, sulphuric acid, and methanol are mixed one by one and homogenised in ultrasonic mixer at a frequency of 20 kHz for 1 hour. Copper oxide is added thereafter. The mixture is subjected to ultrasonic treatment at a frequency of 80 kHz for 24 hours.
  • composition as shown in Table 3 is mixed one by one.
  • the mixture is subjected to ultrasonic treatment at a frequency of 50 kHz for 24 hours.
  • Example 4 The composition is as shown in Table 2. Dimethyl diethoxysilane, tetraethoxysilane, sulphuric acid, ethanol, and dimethyl siloxane are mixed one by one and homogenised in ultrasonic mixer at a frequency of 30 kHz for 1 hour. Silver oxide and copper oxide are added thereafter. The mixture is subjected to ultrasonic treatment at a frequency of 80 kHz for 24 hours. Table 4
  • Example 3 The composition used in Example 3 is coated on clean surfaces of a cable. The effect of the cable with and without coating on the electricity usage of four electrical circuits is tested.
  • the first and second circuits use a 240 V, 50 Hz single-phase alternative current supply.
  • the voltage supplied to the circuit is maintained at 5 V for the first circuit whilst the electric current is maintained at 4.0 A for the second circuit.
  • Two 30 cm long cable, one with coating and another without coating, are connected in parallel for the first circuit and in series for the second circuit.
  • An ammeter and a voltmeter are connected to measure the electric current and voltage drop across the cables.
  • the third and fourth circuits use a 30 V direct current supply.
  • the electric current is maintained at 3.0 A for the fourth circuit.
  • two 30 cm long cable, one with coating and another without coating, are connected in parallel for the third circuit and in series for the fourth circuit.
  • An ammeter and a voltmeter are connected to measure the electric current and voltage drop across the cables.
  • the electric current and voltage across the cables in the third and fourth circuits over a period of time are as shown in Table 6 and Table 7 respectively.

Abstract

A method of reducing energy loss from an electromechanical device comprising the step of coating the surface of the device or a casing surrounding the device with a composition comprising a nano-sized particulate metal oxide; a binder; a liquid carrier; and a surface additive.

Description

A METHOD OF OPTIMISING ENERGY USAGE
FIELD OF INVENTION This invention relates to a method of optimising energy usage. More particularly, the present invention relates to a method of inducing electron vibration alignment in an electromechanical device to reduce energy loss as heat during flow of electricity.
BACKGROUND OF INVENTION
Electricity has becoming an inescapable need for human and without electricity, human life would be in a chaos. However, electricity can be costly as the existing methods of generating electricity or electrical energy are mainly dependent on non-renewable resources. Recently, people are focusing on ways to minimise energy consumption or optimising energy usage, to reduce cost as well as to minimise negative impact to the environment as a result of extracting energy from the non-renewable resources.
More research effort has been put into finding ways to reduce energy usage or to efficient use of energy. Energy audit is done to identify possible reduction of energy input into a system without negatively affecting the performance or output. Energy saving material such as a superconductor, which has a higher electrical conductivity and lower electrical resistance, is also developed as an alternative to the conventional conductive material. Despite some reduction in energy usage can be achieved, a substantial amount of energy loss as heat is unavoidable due to random and irregular electron spin.
Electricity involves the flow of electrons within a closed electric circuit. Typically, the flowing electrons move in a free and irregular manner rather being flow in a straight path therefore collision between atoms of the circuit occur. A substantial amount of energy is lost as heat due to the irregular movement of the electrons before reaching a load. The degree of energy loss is also dependent on the specification of a conductive wire used such as, material, diameter, length, resistivity, and temperature. In view of the above problems, there is a need to further optimise energy usage in which less energy is needed to drive an electric current as well as less energy is loss from irregular movement of electrons. Hence, it is desirable to develop a method of improving electrons flow or reducing irregular movement of electrons. This invention provides a solution to the problem.
SUMMARY OF INVENTION
One of the objects of the invention is to provide a method of optimising electrical energy consumption of an electromechanical device by coating a composition on a surface of the device.
Another object of the invention is to provide a use of a coating on a surface of an electromechanical device in which the coating can induce electron vibration alignment in the device thereby reducing energy loss or optimising energy consumption.
Still another object of the invention is to provide a composition for use in a coating on a surface of an electrochemical device in which the coating can induce electron vibration alignment therein. Yet another object of the invention is to reduce the cost of electricity by reducing energy usage of an electromechanical device.
At least one of the preceding aspects is met, in whole or in part, by the present invention, in which the embodiment of the present invention describes a method of reducing energy loss from an electromechanical device comprising the step of coating the surface of the device or a casing surrounding the device with a composition comprising a nano-sized particulate metal oxide; a binder; a liquid carrier; and a surface additive.
Preferably, the electromechanical device is an electrical distribution board, a cable, an isolator, an inverter, a variable speed drive, or surface of a junction box. In a preferred embodiment of the invention, the metal oxide is an oxide of platinium, titanium, silver, copper, tin, gold, or a mixture thereof; the binder is a silane; the surface additive is sulphuric acid, phosphoric acid, nitric acid, or hydrochloric acid; and the liquid carrier is a silicone oil, an alcohol, or a mixture thereof.
Preferably, the silicone oil is hexamethyl disiloxane, octamethyl trisiloxane, decamethylcyclo pentasiloxane, polydimethyl siloxane or octamethylcyclo tetrasiloxane; and the alcohol is isopropanol, methanol, or ethanol. Preferably, the composition comprises 0.1 to 10 parts by weight of metal oxide, 0.1 to 30 parts by weight of binder, 75 to 94 parts by weight of liquid carrier, and 0.1 to 8 parts by weight of surface additive.
Preferably, the thickness of the coating is at least 2μιη.
The preferred embodiment of the invention consists of novel features and a combination of parts hereinafter fully described and illustrated in the accompanying drawings and particularly pointed out in the appended claims; it being understood that various changes in the details may be effected by those skilled in the arts but without departing from the scope of the invention or sacrificing any of the advantages of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
This invention relates to a method of optimising energy usage. More particularly, the present invention relates to a method of inducing electron vibration alignment in an electromechanical device to reduce energy loss as heat during flow of electricity:
Hereinafter, the invention shall be described according to the preferred embodiments of the present invention and by referring to the accompanying description and drawings. However, it is to be understood that limiting the description to the preferred embodiments of the invention and to the drawings is merely to facilitate discussion of the present invention and it is envisioned that those skilled in the art may devise various modifications without departing from the scope of the appended claim.
The invention discloses a method of reducing energy loss from an electromechanical device comprising the step of coating the surface of the device or a casing surrounding the device with a composition comprising a nano-sized particulate metal oxide; a binder; a liquid carrier; and a surface additive.
In the preferred embodiment of the invention, energy loss in an electromechanical device such as, but is not limiting to, electrical distribution board, cable, isolator, inverter, variable speed drive, or junction box is reduced by coating any surface of the device with the composition which comprises a nano-sized particulate metal oxide; a binder; a liquid carrier; and a surface additive. The surface of the device may not be limited to any kind of material and, it can be made from glass, plastics material, metal, or rubber. Preferably, the coating has a thickness of at least 2μπι so as to sufficiently provide an advantageous effect to the device which will be described later. However, it is not necessary to have a coating thickness of more than 5μπι as additional thickness would have no or only minimal improvement in the advantageous effect.
The atoms of the coating hold sufficient energy which causes them to vibrate at a predetermined frequency similar to the natural frequency of the device for a period of time. When the surface of the device is coated, the atoms of the coating transferred the vibration energy to the atoms of the device, particularly the atoms of conductive wires, in all direction at a distance ranging from 300 mm to 600 mm. With that, the atoms of the device are induced to vibrate at a similar frequency. Particularly, the atoms of the device are vibrating at their natural frequency where resonance occurs. Electron vibration alignment on the affected area of the device occurs, in which randomly spinning electrons are forced to align and spinning uniformly. Collision between atoms of the affected area of the device is minimised therefore, minimal energy loss as heat due to friction between atoms. Electrical resistivity of the device is reduced as well. The composition can be coated evenly on the surface of the electromechanical device by any coating method for example, but is not limiting to, hand spray. It shall be noted that the surface to be coated shall be clean and free from solid impurities to enhance binding of the composition to the surface. After coating the composition on the surface, the coating can be cured at room temperature. Advantageously, the atoms of the composition shall hold the vibration energy for at least 1 month. Thereafter, recoating of the composition may be required.
According to the preferred embodiment of the invention, the composition comprises particles of metal oxide, preferably in a scale of nano size. Smaller particle size is preferred as larger surface area is provided for capturing, holding, and releasing of the vibration energy. The metal for the metal oxide can be selected from the group, but not limiting to, consisting of titanium, silver, copper, tin, or gold. One skilled in the art shall not limit the metal oxide to one type of metal oxide; rather it can be a mixture of two or more types of metal oxide. High electrical conductivity metal is preferred as it can hold higher charge and therefore, higher ability and capacity to hold vibration energy of which thereafter is transferred to the coated device. Preferably, the composition comprises 0.1 to 10 parts by weight of metal oxide. The amount of energy transferred to induce resonance may not be sufficient for less than 0.1 parts by weight of metal oxide. However, any amount more than 10 parts by weight of metal oxide would not provide any additional advantageous effect.
The particles of metal oxide are contained within a liquid carrier so that the prepared composition is readily to be applied and coated on a surface. The liquid carrier also acts as a medium of transferring energy from an energy source to the metal oxide or from the metal oxide to the atoms of the device. Any kind of liquid carrier which does not react with the metal oxide can be used. Preferably, the liquid carrier is a silicone oil, an alcohol, or a mixture thereof. More preferably, the alcohol can be selected from isopropanol, methanol, or ethanol, whilst the silicone oil can be selected from hexamethyl disiloxane, octamethyl trisiloxane, decamethylcyclo pentasiloxane, polydimethyl siloxane or octamethylcyclo tetrasiloxane. When a surface is coated with the composition, the presence of silicone oil also provides the surface with a smooth appearance as well as anti-stick characteristics so that dust or other solid impurities will not adhere to the surface. Preferably, the composition comprises 75 to 94 parts by weight of liquid carrier. As described by the preferred embodiment of the invention, a binder is needed to ensure the coating binds well to the surface to be coated. Preferably, the binder is a silane. More preferably, the silane is an alkyl silane. The alkyl silane can be selected from methyl silane, dimethydiethoxysilane, tetraethoxysilane, linear dialkylsilane, fluorinated alkyl silane, or cyclic alkylsilane. Any silane binder which can render the composition be cured at room temperature and reduced curing time can be used. Preferably, the composition comprises 0.1 to 30 parts by weight of binder.
In accordance to the preferred embodiment of the invention, surface additive is added to further enhance binding of the coating to the surface to be coated. Preferably, the surface additive is an acid to decrease the pH of the composition. When the composition is coated on the surface, the acidic composition may slightly etch the surface and form bonds between the composition and the surface. It shall be noted that the amount of acid added shall not be high to the extent that the pH of the composition falls below 5 or become strongly acidic. It is preferred that the composition has a pH ranging from 5 to 6 which effectively enhance binding of the coating without causing any corrosion to any part of the device. Preferably, the acid can be selected from sulphuric acid, phosphoric acid, nitric acid, or hydrochloric acid. An alkaline composition is not preferred as it may render the coating to be easily detached from the surface due to .
Preferably, the composition comprises 0.1 to 8 parts by weight of surface additive. More preferably, the composition comprises less than 2 parts by weight of surface additive.
The composition for the use in the method as described in any of the preceding description can be produced with the following method. The metal oxide, binder, liquid carrier, and surface additive are homogeneously mixed one at a time. The order of mixing is preferred to be binder, surface additive, liquid carrier, and metal oxide. It shall be noted that metal oxide shall not be added before silane in order to achieve a homogeneous mixture. More preferably, the composition is homogenised by an ultrasonic mixer operating at a frequency of 20 kHz to 60 kHz for at least 0.5 hour. However, it is not necessary to mix the composition for more than 2 hours to achieve a homogeneous mixture. Any other method of homogenising the mixture can be adopted. During the homogenisation, nano particulates metal oxide can be further broken down into smaller size with a higher surface area to capture, hold, and release the vibration energy. Subsequently, the mixture is subjected to bombardment with a vibration force at a frequency of 20 kHz to 1000 KHz for at least 12 hours to store energy within the nano-particles. The vibration force can be provided in any form. However, it shall be noted that the vibration force shall not be induced by any kind of magnetic field in which the magnetic energy held within the atoms of the composition may cause impairment on the device. Preferably, the vibration force is provided by an ultrasonic means. Sufficiently long period of bombardment time is required so as to allow atoms of the composition, particularly atoms of the metal oxide, to capture and hold the energy from the vibration force for a period of time. Atoms of the composition with the energy are excited to vibrate vigorously for a period of time at a frequency similar to the frequency of the vibration force.
The homogenisation step and bombardment step can be in a single operation in which only ultrasonic treatment is utilised. After mixing the composition, the mixture is subjected to ultrasonic treatment where homogenisation and energy capturing occur simultaneously. The ultrasonic frequency is preferably at 20 kHz to 1000 KHz and the treatment is preferably last for at least 12 hours, more preferably for at least 24 hours. However, composition produced using single operation method is prone to have phase separation. Although phase separation may not affect the performance of the composition, the aesthetic view of the composition may not be welcome by the user.
Alternatively, the homogenisation step and bombardment step can be in two separate operations even only ultrasonic treatment is utilised. The binder, surface additive, and liquid carrier are mixed and homogenise by ultrasonic mixer at a frequency of 20 kHz to 60 kHz for at least 0.5 hour, preferably not more than 2 hours. Subsequently, metal oxide is added to the homogenised mixture. The resultant mixture is subjected to ultrasonic treatment at a frequency of 20 kHz to 1000 kHz for at least 12 hours, more preferably for at least 24 hours.
Although the invention has been described and illustrated in detail, it is to be understood that the same is by the way of illustration and example, and is not to be taken by way of limitation. The spirit and scope of the present invention are to be limited only by the terms of the appended claims.
EXAMPLE
Example 1 The composition as shown in Table 1 is mixed one by one. The mixture is subjected to ultrasonic treatment at a frequency of 50 kHz for 24 hours.
Table 1
Figure imgf000010_0001
Example 2
The composition is as shown in Table 2. Methysilane, dimethyl diethoxysilane, sulphuric acid, and methanol are mixed one by one and homogenised in ultrasonic mixer at a frequency of 20 kHz for 1 hour. Copper oxide is added thereafter. The mixture is subjected to ultrasonic treatment at a frequency of 80 kHz for 24 hours.
Table 2
Material Amount (parts by weight)
Methylsilane 8
Dimethyl diethoxysilane 8
Sulphuric acid 1
Methanol 80.5
Copper oxide 2.5 Example 3
The composition as shown in Table 3 is mixed one by one. The mixture is subjected to ultrasonic treatment at a frequency of 50 kHz for 24 hours.
Table 3
Figure imgf000011_0001
Example 4 The composition is as shown in Table 2. Dimethyl diethoxysilane, tetraethoxysilane, sulphuric acid, ethanol, and dimethyl siloxane are mixed one by one and homogenised in ultrasonic mixer at a frequency of 30 kHz for 1 hour. Silver oxide and copper oxide are added thereafter. The mixture is subjected to ultrasonic treatment at a frequency of 80 kHz for 24 hours. Table 4
Material Amount (parts by weight)
Dimethyl diethoxysilane 7.5
Tetraethoxysilane 7.5
Sulphuric acid 0.5
Ethanol 75.5
Dimethyl siloxane 3
Silver oxide 3
Copper oxide 3 Example 5
The composition used in Example 3 is coated on clean surfaces of a cable. The effect of the cable with and without coating on the electricity usage of four electrical circuits is tested.
The first and second circuits use a 240 V, 50 Hz single-phase alternative current supply. The voltage supplied to the circuit is maintained at 5 V for the first circuit whilst the electric current is maintained at 4.0 A for the second circuit. Two 30 cm long cable, one with coating and another without coating, are connected in parallel for the first circuit and in series for the second circuit. An ammeter and a voltmeter are connected to measure the electric current and voltage drop across the cables.
The electric current and voltage across the cables in the first and second circuits over a period of time are as shown in Table 5.
Table 5
Figure imgf000012_0001
For the first circuit, a higher electric current is obtained at a constant voltage for the cable with the coating. For the second circuit, a lower voltage drop is obtained at a constant electric current for the cable with the coating. The effect shown in both circuits indicated that the electrical resistivity of the cable with coating is reduced.
The third and fourth circuits use a 30 V direct current supply. The electric current is maintained at 3.0 A for the fourth circuit. Likewise, two 30 cm long cable, one with coating and another without coating, are connected in parallel for the third circuit and in series for the fourth circuit. An ammeter and a voltmeter are connected to measure the electric current and voltage drop across the cables. The electric current and voltage across the cables in the third and fourth circuits over a period of time are as shown in Table 6 and Table 7 respectively.
Table 6
Figure imgf000013_0001
Figure imgf000013_0002
For the third circuit, a higher electric current is obtained at a constant voltage for the cable with the coating. For the fourth circuit, a lower voltage drop is obtained at a constant electric current for the cable with the coating. The effect shown in both circuits indicated that the electrical resistivity of the cable with coating is reduced.

Claims

1. A method of reducing energy loss from an electromechanical device comprising the step of coating the surface of the device or a casing surrounding the device with a composition comprising
a nano-sized particulate metal oxide;
a binder;
a liquid carrier; and
a surface additive.
2. A method according to claim 1, wherein the electromechanical device is an electrical distribution board, a cable, an isolator, an inverter, a variable speed drive, or surface of a junction box.
3. A method according to claim 1 or 2, wherein the metal oxide is an oxide of platinium, titanium, silver, copper, tin, gold, or a mixture thereof.
4. A method according to any of the preceding claims, wherein the binder is a silane.
5. A method according to any of the preceding claims, wherein the surface additive is sulphuric acid, phosphoric acid, nitric acid, or hydrochloric acid.
6. A method according to claim any of the preceding claims, wherein the liquid carrier is a silicone oil, an alcohol, or a mixture thereof.
7. A method according to claim 6, wherein the silicone oil is hexamethyldisiloxane, octamethyltrisiloxane, decamethylcyclopentasiloxane, polydimethylsiloxane or octamethylcyclotetrasi loxane.
8. A method according to claim 6 or 7 wherein the alcohol is isopropanol, methanol, or ethanol.
9. A method according to any of the preceding claims comprising 0.1 to 10 parts by weight of metal oxide, 0.1 to 30 parts by weight of binder, 75 to 94 parts by weight of liquid carrier, and 0.1 to 8 parts by weight of surface additive.
10. A method according to any of the preceding claims, wherein the thickness of the coating is at least 2μιη.
PCT/SG2015/000127 2015-05-19 2015-05-19 A method of optimising energy usage WO2016186570A1 (en)

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