WO2016171184A1 - ガスバリアフィルム、電子デバイス用部材、および電子デバイス - Google Patents
ガスバリアフィルム、電子デバイス用部材、および電子デバイス Download PDFInfo
- Publication number
- WO2016171184A1 WO2016171184A1 PCT/JP2016/062544 JP2016062544W WO2016171184A1 WO 2016171184 A1 WO2016171184 A1 WO 2016171184A1 JP 2016062544 W JP2016062544 W JP 2016062544W WO 2016171184 A1 WO2016171184 A1 WO 2016171184A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas barrier
- layer
- electronic device
- barrier film
- film
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/16—Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/048—Forming gas barrier coatings
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/48—Ion implantation
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2310/00—Treatment by energy or chemical effects
- B32B2310/08—Treatment by energy or chemical effects by wave energy or particle radiation
- B32B2310/0806—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation
- B32B2310/0831—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation using UV radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2310/00—Treatment by energy or chemical effects
- B32B2310/14—Corona, ionisation, electrical discharge, plasma treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/16—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
Definitions
- the present invention relates to a gas barrier film having a gas barrier layer that is excellent in gas barrier properties and generates a small amount of outgas, an electronic device member comprising the gas barrier film, and an electronic device including the electronic device member.
- a liquid crystal display and an electroluminescence (EL) display have a gas barrier on a transparent plastic film instead of a glass plate as a substrate having electrodes in order to realize a reduction in thickness, weight, and flexibility.
- a so-called gas barrier film in which layers are laminated is used.
- a method for forming a gas barrier layer a method of modifying a layer containing a polysilazane compound by implanting ions into the layer containing a polysilazane compound or exposing the surface of the layer to plasma is known. ing.
- Patent Document 1 describes a molded body having a layer in which ions are implanted into a layer containing a polysilazane compound. This document also describes that the layer into which ions are implanted can function as a gas barrier layer.
- a gas barrier film having excellent gas barrier properties can be obtained by modifying a layer containing a polysilazane compound formed on a substrate.
- the gas barrier film obtained by such a method sometimes generates a small amount of hydrogen gas or the like from the gas barrier layer when a small amount of water vapor enters the gas barrier layer.
- the generated gas may cause failure of the electronic device or appearance deterioration.
- the present invention has been made in view of the above circumstances, and has a gas barrier layer having a gas barrier layer that is excellent in gas barrier properties and generates a small amount of outgas, an electronic device member comprising the gas barrier film, and the electronic device It aims at providing an electronic device provided with a member.
- the present inventors have intensively studied a gas barrier film having a gas barrier layer formed by modifying a layer containing a polysilazane compound.
- a gas barrier layer formed by modifying a layer containing a polysilazane compound.
- the polysilazane compound in the obtained coating film is sufficiently brought into contact with moisture, and then the layer containing the polysilazane compound is modified.
- a gas barrier layer with a small amount of outgas generated can be formed even when a small amount of water vapor enters, and the present invention has been completed.
- gas barrier films (1) to (3), an electronic device member (4), and an electronic device (5) are provided.
- a gas barrier film having a base film and a gas barrier layer obtained by modifying a layer containing a polysilazane compound formed on the base film, and having a water vapor transmission rate of 0.100 g / ( m 2 ⁇ day), and in an argon gas atmosphere at 60 ° C. and 90% relative humidity, the amount of hydrogen gas released from the gas barrier layer is 5.5 ⁇ g or less per 1 cm 2 of the gas barrier film.
- gas barrier film according to (1) wherein the gas barrier layer is a layer modified by subjecting a layer containing a polysilazane compound to ion implantation treatment, plasma treatment, ultraviolet irradiation treatment, or heat treatment.
- An electronic device member comprising the gas barrier film according to any one of (1) to (3).
- An electronic device comprising the electronic device member according to (4).
- the gas barrier film which is excellent in gas barrier property and has the gas barrier layer with little generation amount of outgas
- the electronic device member which consists of this gas barrier film
- an electronic device provided with this electronic device member are provided. .
- the gas barrier film of the present invention is obtained by modifying a base film and a layer containing a polysilazane compound formed on the base film (hereinafter sometimes referred to as “polysilazane layer”).
- a gas barrier layer having a water vapor transmission rate of 0.100 g / (m 2 ⁇ day) or less and released from the gas barrier layer in an argon gas atmosphere at 60 ° C. and a relative humidity of 90%.
- the amount of hydrogen gas to be produced is 5.5 ⁇ g or less per 1 cm 2 of the gas barrier film.
- Base film which comprises the gas barrier film of this invention will not be restrict
- Resin components of the resin film include polyimide, polyamide, polyamideimide, polyphenylene ether, polyether ketone, polyether ether ketone, polyolefin, polyester, polycarbonate, polysulfone, polyethersulfone, polyphenylene sulfide, acrylic resin, cycloolefin Examples thereof include polymers and aromatic polymers.
- polyesters, polyamides or cycloolefin polymers are preferred, and polyesters or cycloolefin polymers are more preferred because of their excellent transparency and versatility.
- polyester examples include polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polyarylate, and the like, and polyethylene terephthalate is preferable.
- polyamide examples include wholly aromatic polyamide, nylon 6, nylon 66, nylon copolymer, and the like.
- cycloolefin polymers include norbornene polymers, monocyclic olefin polymers, cyclic conjugated diene polymers, vinyl alicyclic hydrocarbon polymers, and hydrides thereof. Specific examples thereof include Apel (an ethylene-cycloolefin copolymer manufactured by Mitsui Chemicals), Arton (a norbornene polymer manufactured by JSR), Zeonoa (a norbornene polymer manufactured by Nippon Zeon), and the like. .
- Apel an ethylene-cycloolefin copolymer manufactured by Mitsui Chemicals
- Arton a norbornene polymer manufactured by JSR
- Zeonoa a norbornene polymer manufactured by Nippon Zeon
- the resin film may contain various additives as long as the effects of the present invention are not hindered.
- the additive include an ultraviolet absorber, an antistatic agent, a stabilizer, an antioxidant, a plasticizer, a lubricant, and a coloring pigment. What is necessary is just to determine suitably content of these additives according to the objective.
- the resin film can be obtained by preparing a resin composition containing a resin component and optionally various additives, and molding the resin composition into a film.
- the molding method is not particularly limited, and a known method such as a casting method or a melt extrusion method can be used.
- the thickness of the base film is not particularly limited, and may be determined according to the purpose of the gas barrier film.
- the thickness of the base film is usually 0.5 to 500 ⁇ m, preferably 1 to 100 ⁇ m.
- the light transmittance at 380 to 780 nm of the base film is preferably 80% or more, and more preferably 85% or more.
- the gas barrier layer constituting the gas barrier film of the present invention is obtained by modifying a polysilazane layer.
- the gas barrier layer refers to a layer derived from a polysilazane layer and having gas barrier properties (characteristics for suppressing permeation of gas such as oxygen and water vapor).
- gas barrier properties characteristics for suppressing permeation of gas such as oxygen and water vapor.
- the gas barrier layer of the present invention is composed of both a modified region and an unmodified region.
- the polysilazane compound contained in the polysilazane layer is a compound having a repeating unit containing —Si—N— bond (silazane bond) in the molecule. Specifically, the formula (1)
- the compound which has a repeating unit represented by these is preferable.
- the number average molecular weight of the polysilazane compound to be used is not particularly limited, but is preferably 100 to 50,000.
- n represents an arbitrary natural number.
- Rx, Ry, and Rz each independently represent a hydrogen atom, an unsubstituted or substituted alkyl group, an unsubstituted or substituted cycloalkyl group, an unsubstituted or substituted alkenyl group, unsubstituted or substituted Represents a non-hydrolyzable group such as an aryl group having a group or an alkylsilyl group;
- alkyl group of the unsubstituted or substituted alkyl group examples include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, a sec-butyl group, a t-butyl group, Examples thereof include alkyl groups having 1 to 10 carbon atoms such as n-pentyl group, isopentyl group, neopentyl group, n-hexyl group, n-heptyl group and n-octyl group.
- Examples of the unsubstituted or substituted cycloalkyl group include cycloalkyl groups having 3 to 10 carbon atoms such as a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a cycloheptyl group.
- alkenyl group of an unsubstituted or substituted alkenyl group examples include, for example, a vinyl group, 1-propenyl group, 2-propenyl group, 1-butenyl group, 2-butenyl group, 3-butenyl group and the like having 2 to 2 carbon atoms. 10 alkenyl groups are mentioned.
- substituents for the alkyl group, cycloalkyl group and alkenyl group include halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom; hydroxyl group; thiol group; epoxy group; glycidoxy group; (meth) acryloyloxy group
- halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom
- hydroxyl group such as hydroxyl group; thiol group; epoxy group; glycidoxy group; (meth) acryloyloxy group
- An unsubstituted or substituted aryl group such as a phenyl group, a 4-methylphenyl group, and a 4-chlorophenyl group;
- Examples of the aryl group of the unsubstituted or substituted aryl group of Rx, Ry, and Rz include aryl groups having 6 to 10 carbon atoms such as a phenyl group, a 1-naphthyl group, and a 2-naphthyl group.
- substituent of the aryl group examples include halogen atoms such as fluorine atom, chlorine atom, bromine atom and iodine atom; alkyl groups having 1 to 6 carbon atoms such as methyl group and ethyl group; carbon numbers such as methoxy group and ethoxy group 1-6 alkoxy groups; nitro groups; cyano groups; hydroxyl groups; thiol groups; epoxy groups; glycidoxy groups; (meth) acryloyloxy groups; unsubstituted phenyl groups, 4-methylphenyl groups, 4-chlorophenyl groups, etc.
- alkylsilyl group examples include trimethylsilyl group, triethylsilyl group, triisopropylsilyl group, tri-t-butylsilyl group, methyldiethylsilyl group, dimethylsilyl group, diethylsilyl group, methylsilyl group, and ethylsilyl group.
- Rx, Ry, and Rz a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or a phenyl group is preferable, and a hydrogen atom is particularly preferable.
- Examples of the polysilazane compound having a repeating unit represented by the formula (1) include inorganic polysilazanes in which Rx, Ry, and Rz are all hydrogen atoms, and organic polysilazanes in which at least one of Rx, Ry, and Rz is not a hydrogen atom. It may be.
- a modified polysilazane compound can also be used as the polysilazane compound.
- the modified polysilazane include, for example, JP-A-62-195024, JP-A-2-84437, JP-A-63-81122, JP-A-1-138108, and JP-A-2-175726.
- JP-A-5-238827, JP-A-5-238827, JP-A-6-122852, JP-A-6-306329, JP-A-6-299118, JP-A-9-31333 Examples thereof include those described in Kaihei 5-345826 and JP-A-4-63833.
- the polysilazane compound perhydropolysilazane in which Rx, Ry, and Rz are all hydrogen atoms is preferable from the viewpoint of easy availability and the ability to form an ion-implanted layer having excellent gas barrier properties.
- a polysilazane compound a commercially available product as a glass coating material or the like can be used as it is.
- the polysilazane compounds can be used alone or in combination of two or more.
- the polysilazane layer may contain other components in addition to the above-described polysilazane compound as long as the object of the present invention is not impaired.
- examples of other components include a curing agent, an anti-aging agent, a light stabilizer, and a flame retardant.
- the content of the polysilazane compound in the polysilazane layer is preferably 50% by mass or more and more preferably 70% by mass or more because a gas barrier layer having more excellent gas barrier properties can be obtained.
- the thickness of the polysilazane layer is not particularly limited, but is usually 10 nm to 1 ⁇ m, preferably 10 to 500 nm. In the present invention, even if the polysilazane layer is nano-order, a gas barrier laminate having a sufficient gas barrier property can be obtained.
- the method for forming the polysilazane layer is not particularly limited.
- a solution for forming a polysilazane layer containing at least one polysilazane compound, optionally other components, a solvent, etc. is prepared, and then this polysilazane layer forming solution is applied by a known method.
- a dried polysilazane layer can be formed by drying the coated film.
- Solvents used for the polysilazane layer forming solution include aromatic hydrocarbon solvents such as benzene and toluene; ester solvents such as ethyl acetate and butyl acetate; ketone solvents such as acetone, methyl ethyl ketone, and methyl isobutyl ketone; n-pentane And aliphatic hydrocarbon solvents such as n-hexane and n-heptane; and alicyclic hydrocarbon solvents such as cyclopentane and cyclohexane. These solvents can be used alone or in combination of two or more.
- the coating method of the polysilazane layer forming solution includes a bar coating method, a spin coating method, a dipping method, a roll coating method, a gravure coating method, a knife coating method, an air knife coating method, a roll knife coating method, a die coating method, and a screen printing method. , Spray coating method, gravure offset method and the like.
- the polysilazane compound in the coating film obtained by coating the polysilazane layer forming solution is sufficiently brought into contact with moisture.
- the polysilazane compound in the coating film By sufficiently bringing the polysilazane compound in the coating film into contact with moisture, it is possible to efficiently form a gas barrier layer that generates a small amount of outgas even when a small amount of water vapor enters.
- the contact between the polysilazane compound in the coating film and moisture can be performed, for example, by allowing a laminate having a coating film containing the polysilazane compound to stand for a predetermined time under conditions of predetermined humidity and temperature. .
- the humidity, temperature, and time at this time can be appropriately set according to the purpose.
- the humidity when the laminated body having the coating film is allowed to stand can be usually between 0% and 100% relative humidity. Even when the relative humidity is 0%, other layers such as the base material contain a minute amount of moisture, so that this minute amount of moisture can be used. However, in this case, it is preferable to carry out at a high temperature in order to efficiently contact the polysilazane compound and moisture.
- the temperature at which the laminate having the coating film is allowed to stand is usually 5 to 150 ° C., preferably 10 to 130 ° C.
- the relative humidity is low (for example, 30% or less)
- the polysilazane compound and water are sufficiently brought into contact with each other by leaving the laminate under a higher temperature condition (for example, 100 ° C. or higher). Can do.
- the time for standing the laminate having the coating film is usually 10 minutes to 1 week, preferably 30 minutes to 48 hours. What is necessary is just to determine this time suitably according to the humidity conditions and temperature conditions to employ
- the time for standing the laminated body having the coating film is short (for example, 15 minutes or less)
- the polysilazane can be obtained by standing the laminated body under a higher temperature condition (for example, 130 ° C. or more).
- the system compound and moisture can be sufficiently brought into contact with each other.
- the conditions for bringing the polysilazane compound in the coating film into contact with moisture are optimized in accordance with the film thickness of the coating film. That is, as the coating film becomes thicker, the contact between the polysilazane compound and moisture tends to be insufficient, and the amount of outgas generated from the formed gas barrier layer tends to increase.
- the humidity is preferably 50% or more
- the temperature is 100 ° C. or more
- the laminate standing time is preferably 24 hours or more.
- the humidity is less than 50%
- the temperature is less than 25 ° C.
- the standing time of the laminate is about 1 hour.
- the coating film is dried as necessary, and then the polysilazane layer is subjected to a modification treatment.
- modification treatment for the polysilazane layer include ion implantation treatment, plasma treatment, ultraviolet irradiation treatment, and heat treatment.
- the ion implantation process is a method of modifying the polysilazane layer by implanting ions into the polysilazane layer, as will be described later.
- the plasma treatment is a method for modifying the polysilazane layer by exposing the polysilazane layer to plasma.
- plasma treatment can be performed according to the method described in Japanese Patent Application Laid-Open No. 2012-106421.
- the ultraviolet irradiation treatment is a method for modifying the polysilazane layer by irradiating the polysilazane layer with ultraviolet rays.
- the ultraviolet modification treatment can be performed according to the method described in JP2013-226757A.
- the ion implantation treatment is preferable because a gas barrier layer that can be efficiently modified to the inside without roughening the surface of the polysilazane layer and more excellent in gas barrier properties can be formed.
- ions to be injected into the polysilazane layer ions of rare gases such as argon, helium, neon, krypton, and xenon; ions such as fluorocarbon, hydrogen, nitrogen, oxygen, carbon dioxide, chlorine, fluorine, and sulfur; methane, ethane, and the like Ions of alkane gases; ions of alkenes such as ethylene and propylene; ions of alkadiene gases such as pentadiene and butadiene; ions of alkyne gases such as acetylene; aromatic hydrocarbons such as benzene and toluene Ions of a system gas; ions of a cycloalkane gas such as cyclopropane; ions of a cycloalkene gas such as cyclopentene; a metal ion; an ion of an organosilicon compound; These ions can be used alone or in combination of two or more. Among these, ions of rare gases such
- the ion implantation amount can be appropriately determined according to the purpose of use of the gas barrier film (necessary gas barrier properties, transparency, etc.).
- Examples of the method of implanting ions include a method of irradiating ions accelerated by an electric field (ion beam), a method of implanting ions in plasma, and the like.
- the latter method of implanting plasma ions is preferable because the target gas barrier layer can be easily formed.
- plasma is generated in an atmosphere containing a plasma generating gas such as a rare gas, and a negative high voltage pulse is applied to the polysilazane layer, whereby ions (positive ions) in the plasma are converted into polysilazane. It can be performed by injecting into the surface of the layer.
- a plasma generating gas such as a rare gas
- the thickness of the region into which ions are implanted can be controlled by implantation conditions such as ion type, applied voltage, and processing time, and is determined according to the thickness of the polysilazane layer and the purpose of use of the gas barrier film. Usually, it is 10 to 400 nm.
- the gas barrier film of the present invention has a base film and a gas barrier layer formed by modifying a layer containing a polysilazane compound formed on the base film.
- the gas barrier film of the present invention may have a layer other than the base film and the gas barrier layer.
- layers other than the base film and the gas barrier layer include a primer layer, a conductor layer, a shock absorbing layer, an adhesive layer, a hard coat layer, and a process sheet.
- the process sheet has a role of protecting the gas barrier film when storing or transporting the gas barrier film, and is peeled off when the gas barrier film is used.
- Examples of the layer structure of the gas barrier film of the present invention include, but are not limited to, the following.
- the thickness of the gas barrier film of the present invention is not particularly limited, but is preferably 1 to 1000 ⁇ m, more preferably 10 to 500 ⁇ m, and still more preferably 40 to 100 ⁇ m.
- the gas barrier film of the present invention the temperature 40 ° C., 90% relative humidity, the water vapor permeability, 0.100g / (m 2 ⁇ day ) or less, preferably 0.050g / (m 2 ⁇ day) or less, more preferably Is 0.030 g / (m 2 ⁇ day) or less.
- the water vapor transmission rate can be measured by the method described in the examples.
- the amount of hydrogen gas released from the gas barrier layer in an argon gas atmosphere at 60 ° C. and a relative humidity of 90% is 5.5 ⁇ g or less, preferably 5.0 ⁇ g per cm 2 of the gas barrier film. Or less, more preferably 4.5 ⁇ g or less. There is no particular lower limit, and the lower the better, the better, but it is usually 0.1 ⁇ g or more.
- the amount of hydrogen gas released can be measured by the method described in the examples.
- a polysilazane compound reacts with moisture to generate hydrogen gas or ammonia gas.
- a gas barrier film is used as a sealing material for an electronic device or the like, a small amount of moisture that has entered the gas barrier layer of the gas barrier film reacts with the polysilazane compound, thereby generating these gases.
- the gas barrier layer constituting the gas barrier film of the present invention is such that the above reaction of the polysilazane compound is unlikely to occur, the gas barrier film of the present invention is released from the gas barrier layer when water vapor enters the gas barrier layer. The amount of outgas is small.
- the gas barrier film of this invention has a gas barrier layer which is excellent in gas barrier property and has little outgas generation amount, it is suitably used as a member for electronic devices.
- the electronic device member of the present invention comprises the gas barrier film of the present invention. Therefore, since the electronic device member of the present invention has excellent gas barrier properties, it is possible to prevent deterioration of the element due to gas such as water vapor.
- the electronic device member of the present invention is suitable as a display member for liquid crystal displays, EL displays, and the like because it generates less outgas and is less likely to cause failure or deterioration of the appearance of the electronic device.
- the electronic device of the present invention includes the electronic device member of the present invention.
- Specific examples include a liquid crystal display, an organic EL display, an inorganic EL display, electronic paper, and a solar battery. Since the electronic device of the present invention includes the electronic device member comprising the gas barrier film of the present invention, the electronic device has excellent gas barrier properties and is less prone to failure and appearance deterioration of the electronic device due to outgassing. is there.
- Water vapor transmission rate The water vapor transmission rate of the gas barrier film was measured using “AQUATRAN” manufactured by mocon. The measurement was performed in an atmosphere of 40 ° C. and 90% relative humidity.
- the gas barrier film was placed in a quartz chamber, and argon gas adjusted to a temperature of 60 ° C. and a relative humidity of 90% was allowed to flow there.
- the gas passing through the quartz chamber was analyzed with an atmospheric pressure ionization / mass spectrometer (API-MS), and the amount of hydrogen gas contained therein was quantified.
- the amount of hydrogen gas is an integrated amount from when the argon gas starts to flow until the hydrogen detection peak becomes equal to the background.
- a device having the same structure as that of the organic EL element disclosed in Example 16 of JP-A-2007-197517 was produced except that a gas barrier film was used as the substrate. This was allowed to stand for 24 hours in an environment of 60 ° C. and relative humidity of 90%, and then the appearance was observed.
- Example 1 On a polyethylene terephthalate film (hereinafter referred to as “PET film”) having a thickness of 50 ⁇ m (Toyobo Co., Ltd., Cosmo Shine A-4100), a coating agent mainly composed of perhydropolysilazane (manufactured by Merck Performance Materials Co., Ltd., “ AZNN110-20 ”) was applied to form a coating film, and the resulting coated PET film was heated at 120 ° C. for 2 minutes to form a polysilazane layer having a thickness of 25 nm on the PET film.
- PET film polyethylene terephthalate film having a thickness of 50 ⁇ m
- AZNN110-20 perhydropolysilazane
- Plasma generation gas Argon gas flow rate: 100 sccm Duty ratio: 0.5% Repeat frequency: 1000Hz Applied voltage: -10kV RF output: 1000W RF power supply: (frequency) 13.56 MHz, (applied power) 1000 W Chamber internal pressure: 0.2 Pa Pulse width: 5 ⁇ sec Processing time (ion implantation time): 5 minutes Conveying speed: 0.2 m / min
- Example 2 A gas barrier film was obtained in the same manner as in Example 1 except that the thickness of the polysilazane layer was changed to 50 nm in Example 1, and various measurements were performed. The measurement results are shown in Table 1.
- Example 3 A gas barrier film was obtained in the same manner as in Example 1 except that the thickness of the polysilazane layer was changed to 100 nm in Example 1, and various measurements were performed. The measurement results are shown in Table 1.
- Example 4 A gas barrier film was obtained in the same manner as in Example 1 except that the thickness of the polysilazane layer was changed to 200 nm in Example 1, and various measurements were performed. The measurement results are shown in Table 1.
- Example 5 In Example 1, a gas barrier film was obtained in the same manner as in Example 1 except that the thickness of the polysilazane layer was changed to 300 nm, and various measurements were performed. The measurement results are shown in Table 1.
- Example 6 In Example 1, except that the film thickness of the polysilazane layer was changed to 400 nm, and after applying the coating agent, this was left to stand in an environment of 23 ° C. and 50% relative humidity for 24 hours. In the same manner as above, a gas barrier film was obtained and subjected to various measurements. The measurement results are shown in Table 1.
- Example 7 In Example 1, except that the film thickness of the polysilazane layer was changed to 400 nm, and after applying the coating agent, this was allowed to stand in an environment of 80 ° C. and 50% relative humidity for 3 hours. In the same manner as above, a gas barrier film was obtained and subjected to various measurements. The measurement results are shown in Table 1.
- Example 8 In Example 1, except that the film thickness of the polysilazane layer was changed to 400 nm, and after applying the coating agent, this was left to stand in an environment of 120 ° C. and 0% relative humidity for 1 hour. In the same manner as above, a gas barrier film was obtained and subjected to various measurements. The measurement results are shown in Table 1.
- Example 9 In Example 1, instead of performing plasma ion implantation processing on the polysilazane layer, the same procedure as in Example 1 was performed except that the polysilazane layer was subjected to plasma treatment under the following conditions using a roll electrode type plasma discharge processing apparatus. A gas barrier film was obtained and various measurements were performed. The measurement results are shown in Table 1.
- [Plasma treatment conditions] A plurality of rod-shaped electrodes facing the roll electrode were installed in parallel to the film transport direction, gas and power were supplied to each electrode portion, and the surface of the polysilazane layer was irradiated with plasma for 20 seconds.
- Discharge gas Ar gas Reaction gas: Oxygen gas 7% of the total gas
- High frequency side power supply power 13.56 MHz 8 W / cm 2
- Example 10 In Example 1, instead of performing plasma ion implantation on the polysilazane layer, an excimer irradiation device (MCL-M-1-200, wavelength 172 nm, lamp-filled gas Xe) manufactured by M.D. A gas barrier film was obtained in the same manner as in Example 1 except that the polysilazane layer was subjected to excimer treatment under conditions, and various measurements were performed. The measurement results are shown in Table 1. [Excimer processing conditions] The film fixed on the movable stage was modified under the following conditions.
- Excimer light intensity 130 mW / cm 2 (172 nm)
- Distance between film and light source 1mm
- Stage heating temperature 70 ° C
- Oxygen concentration in the irradiation device 0.5%
- Excimer irradiation time 3 seconds
- Example 1 A gas barrier film was obtained in the same manner as in Example 1 except that the thickness of the polysilazane layer was changed to 400 nm in Example 1, and various measurements were performed. The measurement results are shown in Table 1.
- Example 2 A gas barrier film was obtained in the same manner as in Example 1 except that the thickness of the polysilazane layer was changed to 500 nm in Example 1, and various measurements were performed. The measurement results are shown in Table 1.
- the gas barrier films obtained in Examples 1 to 10 have sufficient gas barrier properties, and the gas barrier layer generates little hydrogen gas even when it comes into contact with water vapor.
- the device provided with this gas barrier film had no appearance problem.
- the gas barrier layers of the gas barrier films obtained in Comparative Examples 1 and 2 generated a large amount of hydrogen gas when contacted with water vapor, and the devices including this gas barrier film were swollen.
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Nonlinear Science (AREA)
- Mathematical Physics (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Laminated Bodies (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Abstract
Description
ガスバリア層の形成方法としては、ポリシラザン系化合物を含有する層にイオンを注入したり、その層の表面をプラズマに曝したりすることにより、ポリシラザン系化合物を含有する層を改質する方法が知られている。
しかしながら、このような方法で得られたガスバリアフィルムは、微量の水蒸気がガスバリア層に浸入すると、ガスバリア層から微量の水素ガス等が発生することがあった。そして、このようなガスバリアフィルムが電子デバイスの部材として用いられている場合、発生したガスが、電子デバイスの故障や外観劣化を引き起こす場合があった。
(1)基材フィルムと、該基材フィルム上に形成されたポリシラザン系化合物を含有する層を改質してなるガスバリア層とを有するガスバリアフィルムであって、水蒸気透過率が0.100g/(m2・day)以下であり、かつ、60℃、相対湿度90%のアルゴンガス雰囲気下において、前記ガスバリア層から放出される水素ガスの量が、ガスバリアフィルム1cm2あたり5.5μg以下であることを特徴とするガスバリアフィルム。
(2)前記ガスバリア層の厚みが10nmから1μmである、(1)に記載のガスバリアフィルム。
(3)前記ガスバリア層が、ポリシラザン系化合物を含む層を、イオン注入処理、プラズマ処理、紫外線照射処理又は加熱処理することにより改質された層である、(1)に記載のガスバリアフィルム。
(4)前記(1)~(3)のいずれかに記載のガスバリアフィルムからなる電子デバイス用部材。
(5)前記(4)に記載の電子デバイス用部材を備える電子デバイス。
本発明のガスバリアフィルムは、基材フィルムと、該基材フィルム上に形成されたポリシラザン系化合物を含有する層(以下、「ポリシラザン層」ということがある。)を改質してなるガスバリア層とを有するものであって、水蒸気透過率が0.100g/(m2・day)以下であり、かつ、60℃、相対湿度90%のアルゴンガス雰囲気下において、前記ガスバリア層から放出される水素ガスの量が、ガスバリアフィルム1cm2あたり5.5μg以下であることを特徴とする。
本発明のガスバリアフィルムを構成する基材フィルムは、ガスバリアフィルムの基材として十分な強度を有するものであれば特に制限されない。
樹脂フィルムの樹脂成分としては、ポリイミド、ポリアミド、ポリアミドイミド、ポリフェニレンエーテル、ポリエーテルケトン、ポリエーテルエーテルケトン、ポリオレフィン、ポリエステル、ポリカーボネート、ポリスルフォン、ポリエーテルスルフォン、ポリフェニレンスルフィド、アクリル系樹脂、シクロオレフィン系ポリマー、芳香族系重合体等が挙げられる。
ポリアミドとしては、全芳香族ポリアミド、ナイロン6、ナイロン66、ナイロン共重合体等が挙げられる。
基材フィルムの380~780nmにおける光線透過率は、80%以上が好ましく、85%以上がより好ましい。
本発明のガスバリアフィルムを構成するガスバリア層は、ポリシラザン層を改質してなるものである。
なお、本発明において、ガスバリア層とは、ポリシラザン層に由来する層であって、ガスバリア性(酸素や水蒸気等のガスの透過を抑制する特性)を有する層をいう。例えば、ポリシラザン層の表面部のみが改質されている場合、本発明のガスバリア層は、改質された領域と、未改質の領域の両方により構成される。
これらの中でも、ポリシラザン系化合物としては、入手容易性、及び優れたガスバリア性を有するイオン注入層を形成できる観点から、Rx、Ry、Rzが全て水素原子であるペルヒドロポリシラザンが好ましい。
また、ポリシラザン系化合物としては、ガラスコーティング材等として市販されている市販品をそのまま使用することもできる。
ポリシラザン系化合物は、1種単独で、あるいは2種以上を組み合わせて用いることができる。
ポリシラザン層中のポリシラザン系化合物の含有量は、より優れたガスバリア性を有するガスバリア層が得られることから、50質量%以上が好ましく、70質量%以上がより好ましい。
本発明においては、ポリシラザン層がナノオーダーであっても、充分なガスバリア性を有するガスバリア性積層体を得ることができる。
これらの溶媒は、1種単独で、あるいは2種以上を組み合わせて用いることができる。
一般的に、塗膜が厚いとき(200nmから1μm)は、湿度は50%以上、温度は、100℃以上、積層体静置時間は、24時間以上とすることが好ましい。
一方、膜厚が薄い場合(200nm未満)には、湿度は50%未満、温度は25℃未満、積層体の静置時間は、1時間程度で十分である。
ポリシラザン層の改質処理としては、イオン注入処理、プラズマ処理、紫外線照射処理、熱処理等が挙げられる。
イオン注入処理は、後述するように、ポリシラザン層にイオンを注入して、ポリシラザン層を改質する方法である。
プラズマ処理は、ポリシラザン層をプラズマ中に晒して、ポリシラザン層を改質する方法である。例えば、特開2012-106421号公報に記載の方法に従って、プラズマ処理を行うことができる。
紫外線照射処理は、ポリシラザン層に紫外線を照射してポリシラザン層を改質する方法である。例えば、特開2013-226757号公報に記載の方法に従って、紫外線改質処理を行うことができる。
これらの中でも、ポリシラザン層の表面を荒らすことなく、その内部まで効率よく改質し、よりガスバリア性に優れるガスバリア層を形成できることから、イオン注入処理が好ましい。
これらのイオンは、1種単独で、あるいは2種以上を組み合わせて用いることができる。
これらの中でも、より簡便にイオンを注入することができ、より優れたガスバリア性を有するガスバリア層を形成できることから、アルゴン、ヘリウム、ネオン、クリプトン、キセノン等の希ガスのイオンが好ましい。
本発明のガスバリアフィルムは、基材フィルムと、該基材フィルム上に形成されたポリシラザン系化合物を含有する層を改質してなるガスバリア層とを有するものである。
本発明のガスバリアフィルムは、基材フィルム、ガスバリア層以外の層を有するものであってもよい。
基材フィルム、ガスバリア層以外の層としては、プライマー層、導電体層、衝撃吸収層、粘着剤層、ハードコート層、工程シート等が挙げられる。なお、工程シートは、ガスバリアフィルムを保存、運搬等する際に、ガスバリアフィルムを保護する役割を有し、ガスバリアフィルムが使用される際には剥離されるものである。
(i)基材フィルム/ガスバリア層
(ii)ハードコート層/基材フィルム/ガスバリア層
(iii)基材フィルム/プライマー層/ガスバリア層
(iv)ハードコート層/基材フィルム/プライマー層/ガスバリア層
水蒸気透過率は、実施例に記載の方法により測定することができる。
水素ガスの放出量は、実施例に記載される方法により測定することができる。
本発明のガスバリアフィルムを構成するガスバリア層は、ポリシラザン系化合物の上記反応が起こり難いものであるため、本発明のガスバリアフィルムは、ガスバリア層内に水蒸気が浸入したときに、ガスバリア層から放出されるアウトガスの量が少ない。
このように、本発明のガスバリアフィルムは、ガスバリア性に優れ、かつ、アウトガスの発生量が少ないガスバリア層を有するものであるため、電子デバイス用部材として好適に用いられる。
本発明の電子デバイス用部材は、本発明のガスバリアフィルムからなることを特徴とする。従って、本発明の電子デバイス用部材は、優れたガスバリア性を有しているので、水蒸気等のガスによる素子の劣化を防ぐことができる。また、本発明の電子デバイス用部材は、アウトガスの発生量が少なく、電子デバイスの故障や外観劣化が引き起こされるおそれが少ないため、液晶ディスプレイ、ELディスプレイ等のディスプレイ部材;等として好適である。
本発明の電子デバイスは、本発明のガスバリアフィルムからなる電子デバイス用部材を備えているので、優れたガスバリア性を有し、かつ、アウトガスの発生による電子デバイスの故障や外観劣化が起きにくいものである。
各例中の部及び%は、特に断りのない限り、質量基準である。
ガスバリアフィルムの水蒸気透過率を、mocon社製、「AQUATRAN」を用いて測定した。測定は40℃、相対湿度90%雰囲気下で行った。
ガスバリアフィルムを石英チャンバーに入れ、ここに、温度60℃、相対湿度を90%に調湿したアルゴンガスを流した。石英チャンバー内を通過したガスを大気圧イオン化・質量分析計(API-MS)で分析し、その中に含まれる水素ガスの量を定量した。なお、水素ガスの量は、アルゴンガスを流し始めたときから、水素の検出ピークがバックグラウンドと同等になるまでの積算量である。
基板としてガスバリアフィルムを使用した点を除き、特開2007-197517号公報の実施例16で開示されている有機EL素子と同様の構造を有するデバイスを作製した。
これを、60℃、相対湿度90%の環境下に24時間静置した後、外観を観察した。
厚みが50μmのポリエチレンテレフタレートフィルム(以下、「PETフィルム」という。)(東洋紡社製、コスモシャインA-4100)上に、ペルヒドロポリシラザンを主成分とするコーティング剤(メルクパフォーマンスマテリアルズ社製、「AZNN110-20」)を塗布して塗膜を形成し、得られた塗膜付PETフィルムを120℃で2分間加熱することにより、PETフィルム上に、厚みが25nmのポリシラザン層を形成した。
次いで、上記のポリシラザン層に、プラズマイオン注入装置を用いて、下記条件にてプラズマイオン注入を行い、ポリシラザン層の表面を改質し、ガスバリアフィルムを得た。このガスバリアフィルムについて各種測定を行った。測定結果を第1表に示す。
プラズマ生成ガス:アルゴン
ガス流量:100sccm
Duty比:0.5%
繰り返し周波数:1000Hz
印加電圧:-10kV
RF出力:1000W
RF電源:(周波数)13.56MHz、(印加電力)1000W
チャンバー内圧:0.2Pa
パルス幅:5μsec
処理時間(イオン注入時間):5分間
搬送速度:0.2m/min
実施例1において、ポリシラザン層の膜厚を50nmに変更したことを除き、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
実施例1において、ポリシラザン層の膜厚を100nmに変更したことを除き、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
実施例1において、ポリシラザン層の膜厚を200nmに変更したことを除き、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
実施例1において、ポリシラザン層の膜厚を300nmに変更したことを除き、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
実施例1において、ポリシラザン層の膜厚を400nmに変更したことと、コーティング剤を塗布した後、これを23℃、相対湿度50%の環境下に24時間静置したこと以外は、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
実施例1において、ポリシラザン層の膜厚を400nmに変更したことと、コーティング剤を塗布した後、これを80℃、相対湿度50%の環境下に3時間静置したこと以外は、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
実施例1において、ポリシラザン層の膜厚を400nmに変更したことと、コーティング剤を塗布した後、これを120℃、相対湿度0%の環境下に1時間静置したこと以外は、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
実施例1において、ポリシラザン層にプラズマイオン注入処理をする代わりに、ロール電極型プラズマ放電処理装置を用いて、下記条件にてポリシラザン層にプラズマ処理を行ったこと以外は、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
[プラズマ処理の条件]
ロール電極に対向する棒状電極を複数個、フィルムの搬送方向に対して平行に設置し、各電極部にガス及び電力を投入し、ポリシラザン層の表面を20秒間プラズマ照射した。
放電ガス:Arガス
反応ガス:酸素ガスを全ガスに対し7%
高周波側電源電力:13.56MHzを8W/cm2
実施例1において、ポリシラザン層にプラズマイオン注入処理をする代わりに、エキシマ照射装置(エム・ディ・コム社製、MECL-M-1-200、波長172nm、ランプ封入ガス Xe)を用いて、下記条件にてポリシラザン層にエキシマ処理を行ったこと以外は、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
[エキシマ処理の条件]
可動ステージ上に固定したフィルムに対して、以下の条件で改質処理を行った。
エキシマ光強度:130mW/cm2(172nm)
フィルムと光源の距離:1mm
ステージ加熱温度:70℃
照射装置内の酸素濃度:0.5%
エキシマ照射時間:3秒
実施例1において、ポリシラザン層の膜厚を400nmに変更したことを除き、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
実施例1において、ポリシラザン層の膜厚を500nmに変更したことを除き、実施例1と同様にしてガスバリアフィルムを得、各種測定を行った。測定結果を第1表に示す。
実施例1~10で得られたガスバリアフィルムは、十分なガスバリア性を有し、かつ、そのガスバリア層は水蒸気と接触しても水素ガスの発生量が少ない。このガスバリアフィルムを備えるデバイスは外観上の問題が生じなかった。
一方、比較例1、2で得られたガスバリアフィルムのガスバリア層は水蒸気と接触したときの水素ガスの発生量が多く、このガスバリアフィルムを備えるデバイスは、膨れが生じた。
Claims (5)
- 基材フィルムと、該基材フィルム上に形成されたポリシラザン系化合物を含有する層を改質してなるガスバリア層とを有するガスバリアフィルムであって、
水蒸気透過率が0.100g/(m2・day)以下であり、かつ、
60℃、相対湿度90%のアルゴンガス雰囲気下において、前記ガスバリア層から放出される水素ガスの量が、ガスバリアフィルム1cm2あたり5.5μg以下であることを特徴とするガスバリアフィルム。 - 前記ガスバリア層の厚みが10nmから1μmである、請求項1に記載のガスバリアフィルム。
- 前記ガスバリア層が、ポリシラザン系化合物を含む層を、イオン注入処理、プラズマ処理、紫外線照射処理又は加熱処理することにより改質された層である、請求項1に記載のガスバリアフィルム。
- 請求項1~3のいずれかに記載のガスバリアフィルムからなる電子デバイス用部材。
- 請求項4に記載の電子デバイス用部材を備える電子デバイス。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017514169A JPWO2016171184A1 (ja) | 2015-04-22 | 2016-04-20 | ガスバリアフィルム、電子デバイス用部材、および電子デバイス |
EP16783205.4A EP3287274A4 (en) | 2015-04-22 | 2016-04-20 | Gas barrier film, electronic device member, and electronic device |
CN201680023244.9A CN107531014A (zh) | 2015-04-22 | 2016-04-20 | 阻气膜、电子器件用部件及电子器件 |
US15/568,222 US20180141308A1 (en) | 2015-04-22 | 2016-04-20 | Gas barrier film, electronic device member, and electronic device |
KR1020177032371A KR20170139567A (ko) | 2015-04-22 | 2016-04-20 | 가스 배리어 필름, 전자 디바이스용 부재, 및 전자 디바이스 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015-087371 | 2015-04-22 | ||
JP2015087371 | 2015-04-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2016171184A1 true WO2016171184A1 (ja) | 2016-10-27 |
Family
ID=57143124
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2016/062544 WO2016171184A1 (ja) | 2015-04-22 | 2016-04-20 | ガスバリアフィルム、電子デバイス用部材、および電子デバイス |
Country Status (7)
Country | Link |
---|---|
US (1) | US20180141308A1 (ja) |
EP (1) | EP3287274A4 (ja) |
JP (1) | JPWO2016171184A1 (ja) |
KR (1) | KR20170139567A (ja) |
CN (1) | CN107531014A (ja) |
TW (1) | TW201707978A (ja) |
WO (1) | WO2016171184A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109863019A (zh) * | 2016-10-28 | 2019-06-07 | 琳得科株式会社 | 层合膜、电子器件用部件和电子器件 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002222691A (ja) * | 2000-07-24 | 2002-08-09 | Tdk Corp | 発光素子 |
WO2011007543A1 (ja) * | 2009-07-17 | 2011-01-20 | 三井化学株式会社 | 積層体およびその製造方法 |
WO2013161809A1 (ja) * | 2012-04-26 | 2013-10-31 | コニカミノルタ株式会社 | ガスバリア性フィルム、およびこれを用いる電子デバイス |
JP2014240462A (ja) * | 2013-06-12 | 2014-12-25 | コニカミノルタ株式会社 | ガスバリアーフィルム、ガスバリアーフィルムの製造方法及びガスバリアーフィルムの製造装置 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2357078A4 (en) * | 2008-12-12 | 2012-10-10 | Lintec Corp | LAMINATE, METHOD FOR THE PRODUCTION THEREOF, ELECTRONIC DEVICE AND ELECTRONIC DEVICE |
US8906492B2 (en) * | 2009-03-17 | 2014-12-09 | LÌNTEC Corporation | Formed article, method for producing the formed article, member for electronic device, and electronic device |
JP5445179B2 (ja) * | 2010-02-01 | 2014-03-19 | コニカミノルタ株式会社 | ガスバリア性フィルム、ガスバリア性フィルムの製造方法、有機電子デバイス |
CN103998230B (zh) * | 2011-12-16 | 2015-11-25 | 柯尼卡美能达株式会社 | 气体阻隔膜 |
EP2805817A4 (en) * | 2012-01-20 | 2015-09-23 | Lintec Corp | BARRIER FILM AGAINST GAS AND METHOD FOR PRODUCING BARRIER FILM AGAINST GAS |
CN104903089A (zh) * | 2013-01-11 | 2015-09-09 | 东丽株式会社 | 阻气性膜 |
US20160059261A1 (en) * | 2013-05-01 | 2016-03-03 | Konica Minolta, Inc. | Gas barrier film and method for producing the same |
-
2016
- 2016-04-20 KR KR1020177032371A patent/KR20170139567A/ko unknown
- 2016-04-20 JP JP2017514169A patent/JPWO2016171184A1/ja active Pending
- 2016-04-20 US US15/568,222 patent/US20180141308A1/en not_active Abandoned
- 2016-04-20 CN CN201680023244.9A patent/CN107531014A/zh active Pending
- 2016-04-20 WO PCT/JP2016/062544 patent/WO2016171184A1/ja active Application Filing
- 2016-04-20 EP EP16783205.4A patent/EP3287274A4/en not_active Withdrawn
- 2016-04-21 TW TW105112385A patent/TW201707978A/zh unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002222691A (ja) * | 2000-07-24 | 2002-08-09 | Tdk Corp | 発光素子 |
WO2011007543A1 (ja) * | 2009-07-17 | 2011-01-20 | 三井化学株式会社 | 積層体およびその製造方法 |
WO2013161809A1 (ja) * | 2012-04-26 | 2013-10-31 | コニカミノルタ株式会社 | ガスバリア性フィルム、およびこれを用いる電子デバイス |
JP2014240462A (ja) * | 2013-06-12 | 2014-12-25 | コニカミノルタ株式会社 | ガスバリアーフィルム、ガスバリアーフィルムの製造方法及びガスバリアーフィルムの製造装置 |
Non-Patent Citations (1)
Title |
---|
See also references of EP3287274A4 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109863019A (zh) * | 2016-10-28 | 2019-06-07 | 琳得科株式会社 | 层合膜、电子器件用部件和电子器件 |
EP3533602A4 (en) * | 2016-10-28 | 2020-08-19 | Lintec Corporation | LAMINATE FILM, ELEMENT OF ELECTRONIC DEVICE AND ELECTRONIC DEVICE |
CN109863019B (zh) * | 2016-10-28 | 2021-11-23 | 琳得科株式会社 | 层合膜、电子器件用部件和电子器件 |
Also Published As
Publication number | Publication date |
---|---|
JPWO2016171184A1 (ja) | 2018-02-15 |
KR20170139567A (ko) | 2017-12-19 |
EP3287274A1 (en) | 2018-02-28 |
EP3287274A4 (en) | 2018-09-05 |
US20180141308A1 (en) | 2018-05-24 |
CN107531014A (zh) | 2018-01-02 |
TW201707978A (zh) | 2017-03-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6690034B2 (ja) | ガスバリア性積層体、電子デバイス用部材及び電子デバイス | |
JP6719631B2 (ja) | ガスバリア性積層体及びその製造方法、電子デバイス用部材、並びに電子デバイス | |
JP5808747B2 (ja) | 成形体、その製造方法、電子デバイス用部材及び電子デバイス | |
JP2020073358A (ja) | 長尺のガスバリア性積層体およびその製造方法 | |
JP6850285B2 (ja) | プライマー層形成用硬化性組成物、ガスバリア性積層フィルムおよびガスバリア性積層体 | |
JP7080180B2 (ja) | ガスバリア性積層シート、ガスバリア性積層シートの製造方法、及び電子部材又は光学部材 | |
WO2011122547A1 (ja) | 成形体、その製造方法、電子デバイス用部材及び電子デバイス | |
JP2014019056A (ja) | フィルムロール梱包体およびその製造方法 | |
JP6995111B2 (ja) | ガスバリア性積層体 | |
WO2016171184A1 (ja) | ガスバリアフィルム、電子デバイス用部材、および電子デバイス | |
WO2015152076A1 (ja) | 長尺のガスバリア性積層体及びその製造方法、電子デバイス用部材、並びに電子デバイス | |
JP6544832B2 (ja) | ガスバリア性積層体、電子デバイス用部材および電子デバイス | |
WO2016158613A1 (ja) | ガスバリア性積層体、電子デバイス用部材、および電子デバイス | |
JP2016172244A (ja) | 塗工液供給装置、塗工液供給方法、積層体の製造方法、ガスバリアフィルムの製造方法、積層体、およびガスバリアフィルム |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 16783205 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2017514169 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 15568222 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 20177032371 Country of ref document: KR Kind code of ref document: A |