WO2016046925A1 - Dispositif de production de micro-émulsion - Google Patents

Dispositif de production de micro-émulsion Download PDF

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Publication number
WO2016046925A1
WO2016046925A1 PCT/JP2014/075340 JP2014075340W WO2016046925A1 WO 2016046925 A1 WO2016046925 A1 WO 2016046925A1 JP 2014075340 W JP2014075340 W JP 2014075340W WO 2016046925 A1 WO2016046925 A1 WO 2016046925A1
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WO
WIPO (PCT)
Prior art keywords
oil
water
power supply
pipe
potential
Prior art date
Application number
PCT/JP2014/075340
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English (en)
Japanese (ja)
Inventor
正行 松尾
Original Assignee
株式会社ワールドビジネス
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社ワールドビジネス filed Critical 株式会社ワールドビジネス
Priority to SG11201603096UA priority Critical patent/SG11201603096UA/en
Priority to PCT/JP2014/075340 priority patent/WO2016046925A1/fr
Publication of WO2016046925A1 publication Critical patent/WO2016046925A1/fr
Priority to PH12016500800A priority patent/PH12016500800A1/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/40—Mixing liquids with liquids; Emulsifying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23K—FEEDING FUEL TO COMBUSTION APPARATUS
    • F23K5/00—Feeding or distributing other fuel to combustion apparatus
    • F23K5/02—Liquid fuel
    • F23K5/08—Preparation of fuel
    • F23K5/10—Mixing with other fluids
    • F23K5/12—Preparing emulsions

Definitions

  • the present invention relates to a microemulsion generator that generates a microemulsion by mixing two kinds of liquids.
  • FIG. 3 is a diagram showing such a conventional liquid mixing apparatus.
  • 201 and 202 are piping
  • 203 is a mixing part
  • 204 is a stirring drive part
  • 205 is a tank
  • 206 is a liquid mixture
  • 207 is a stirring blade
  • 208 and 209 are pipings
  • 210 is a water softening part.
  • the mixing unit 203 includes a tank 205 that contains a liquid to be mixed, a stirring blade 207 that stirs the mixed solution in the tank 205, and a stirring drive unit 204 that rotates the stirring blade 207.
  • water hard water
  • oil fuel oil
  • the oil is sent to the tank 205 of the mixing unit 203 through the pipe 202. Since water is not mixed well with oil in the form of hard water, it is first sent to the water softening unit 210 where it is softened. The softened water is sent to the tank 205 through the pipe 208.
  • the emulsifier surfactant
  • the mixed solution to which the emulsifier is added is emulsified (white turbidity), and by vigorously stirring it with the stirring blade 207, the mixing becomes gradually uniform and eventually becomes an emulsion.
  • the mixed fuel in an emulsion state is taken out from the pipe 209 and used. Note that the liquid mixture becomes cloudy because the mixed liquid has a large particle size, and the scattered visible light is much scattered. In the emulsion, the particle size of the mixed liquid is about 0.1 ⁇ m even if it is small.
  • the liquid mixture produced by the conventional liquid mixing apparatus described above has the following problems. 1. Although an emulsifier is required, this is relatively expensive and expensive. 2. Because of the emulsifier, the color of the mixed liquid becomes milky white (white turbidity). For example, when mixed fuel is produced, it does not look like fuel oil. 3. The diameter (particle size) of the mixed liquid particles is still large and the viscosity is large. Therefore, it separates with the passage of time. 4). When mixed fuel is produced, the calorific value is less than that of the original fuel oil. An object of the present invention is to solve such problems.
  • the present invention provides a microemulsion generating apparatus in which a mixed solution is in a microemulsion state.
  • Microemulsion refers to a liquid mixture in which the particle size of the mixed liquid is 0.05 ⁇ m or less. It can be said that it is no longer a single liquid phase.
  • the microemulsion generator of the present invention includes a water softening unit (2) for softening water to be mixed, a pure water purification unit (3) for purifying soft water from the water softening unit, and the pure water.
  • a potential applying unit (6) for applying a positive potential to the positive ionized oil from the oil ionizing unit, the oil from the potential applying unit being charged to a positive potential and sprayed again, and from the water ionizing unit
  • the water is charged with a negative potential and sprayed, and the sprays are mixed with each other so that the mixed solution (7) is mixed so that the mixed liquid is in a microemulsion state.
  • the water ionization unit (4) is a tank that stores pure water sent from the pure water purification unit, and a redox potential reducing material and water quality that reduce the redox potential of water.
  • a first pulse power supply (45) for supplying a first pulse power supply for ionization.
  • the oil ionization section (5) includes a second tank (51) that contains oil to be mixed, a second pump (53) and a second pipe for circulating the oil. (52), a second liquid magnetic processing apparatus (54) that is installed on the outer periphery in the middle of the second pipe and applies an electromagnetic field to the oil flowing through the second pipe, A second pulse power supply device (55) for supplying a second pulse power supply for positively ionizing oil to the two liquid magnetic processing apparatuses.
  • the potential applying section (6) includes a third tank (61) for storing oil sent from the oil ionization section, and a third pump (63) for circulating the oil. ) And the third pipe (62), the first nozzle (64) attached to the end of the third pipe drawn into the upper part of the third tank and spraying the oil, and the first pipe
  • a first DC high voltage power supply device (65) for supplying a positive first DC high voltage to the first nozzle is provided. I can do it.
  • the mixing unit (7) includes a fifth tank (71) that contains the mixed solution, and a fourth pipe (in which water from the water ionization unit is drawn into the upper part of the fifth tank ( 20) attached to the end of the second nozzle (73) for spraying the water, and at the end of the fifth pipe (22) for drawing oil from the potential applying section into the upper part of the fifth tank.
  • a third nozzle (72) that is attached and sprays the oil, and applies a negative potential to the water sprayed from the second nozzle and also applies a positive potential to the oil sprayed from the third nozzle
  • the second direct current high voltage power supply device (75) for supplying the second direct current high voltage can be provided.
  • the first pulse power supply and the second pulse power supply can be supplied from one pulse power supply apparatus, or the first DC high voltage power supply and the second DC high power supply can be supplied.
  • the voltage power supply may be supplied from one DC high voltage power supply device.
  • the microemulsion generator of the present invention has the following effects. 1. Cost can be reduced. Since the mixing of the two liquids is performed without using an emulsifier, the production cost can be greatly reduced. 2. The color of the liquid mixture remains the color of the liquid used for production. In the present invention, since no emulsifier is added, it does not become milky white and remains the color of the liquid used for production. For example, in the case of a microemulsion in which fuel oil and water are mixed, since water is transparent, it eventually becomes the same color as the fuel oil and has a fuel oil-like appearance. 3. The diameter (particle diameter) of the mixed liquid droplets is small and the viscosity is small. Therefore, it does not separate over time. 4). The calorific value of the mixed fuel microemulsion is comparable to that of the original fuel oil.
  • generation apparatus of this invention The figure explaining a liquid magnetic processing apparatus Diagram showing a conventional liquid mixing device
  • FIG. 1 is a diagram showing an example of a microemulsion generator of the present invention.
  • water and oil fuel oil: kerosene, heavy oil, light oil, etc.
  • 1 is a microemulsion generator
  • 2 is a water softening unit
  • 3 is a pure water purification unit
  • 4 is a water ionization unit
  • 5 is an oil ionization unit
  • 6 is a potential application unit
  • 7 is a mixing unit
  • 8 is an addition unit.
  • Temperature storage unit 20 to 24, piping, 41, tank, 42, piping, 43, pump, 44, liquid magnetic processing device, 45, pulse power supply, 46, wiring, 51, tank, 52, piping, 53 , 54 is a liquid magnetic processing device, 55 is a pulse power supply device, 56 is wiring, 61 is a tank, 62 is piping, 63 is a pump, 64 is a nozzle, 65 is a direct current high voltage power supply device, 66 is wiring, 71 is a tank, Reference numerals 72 and 73 are nozzles, 74 is a stirring blade, 75 is a DC high-voltage power supply device, 76 and 77 are wiring, 81 is a tank, and 82 is a heater.
  • the structure for pretreatment of water is a water softening unit 2, a pure water purification unit 3, and a water ionization unit 4.
  • the oil pretreatment is the oil ionization unit 5 and the potential application unit 6.
  • the water ionization unit 4 includes a tank 41, a pipe 42, a pump 43, a liquid magnetic processing device 44, a pulse power supply device 45, a wiring 46, and the like.
  • a redox potential lowering material for example, special ceramic
  • a water quality stabilizing material for example, tourmaline
  • the pipe 42 and the pump 43 are arranged so as to circulate pure water in the tank 41, and a liquid magnetic processing device 44 is provided in the middle of the pipe 42.
  • the liquid magnetic processing device 44 is for subjecting pure water flowing through the pipe 42 to magnetic processing and ionization.
  • the pulse power supply device 45 is a power supply for operating the liquid magnetic processing device 44.
  • FIG. 2 is a diagram illustrating a liquid magnetic processing apparatus.
  • 100 is a pipe
  • 101 is a liquid magnetic processing apparatus
  • 102 is an electromagnetic field generator
  • 103 is a pulse power supply apparatus.
  • the electromagnetic field generator 102 is provided along the outer periphery of the pipe 100 and generates an electromagnetic field that acts on the liquid flowing in the pipe 100.
  • an electromagnetic field acts on the liquid flowing in the pipe 100
  • the element is ionized and eluted when the frequency of the electromagnetic field is a frequency suitable for ionization of the element constituting the liquid.
  • the liquid magnetic processing apparatus 101 is supplied with pulse power from the pulse power supply apparatus 103.
  • the polarity application method and pulse frequency are appropriately selected according to the type of liquid (elements) to be ionized. .
  • the liquid magnetic processing device 44 of the water ionization unit 4 performs a process such that negative ions are generated from pure water.
  • the type and number of frequencies and the method of applying the polarity are selected so that such processing is performed efficiently there. .
  • the pure water containing negative ions generated here has a lower oxidation-reduction degree (eg, ⁇ 300 mV).
  • the pure water in the tank 41 is strongly alkaline due to the action of the redox potential reducing material.
  • the pure water ionized as described above in the water ionization section 4 is sent to the mixing section 7 through the pipe 20 (it is sent by a pump not shown. The same applies to the following pipes).
  • the oil pre-treatment is first performed by the oil ionization unit 5 and then by the potential applying unit 6.
  • the oil ionization unit 5 includes a tank 51, a pipe 52, a pump 53, a liquid magnetic processing device 54, a pulse power supply device 55, a wiring 56, and the like.
  • the pipe 52 and the pump 53 are arranged to circulate oil in the tank 51, and a liquid magnetic processing device 54 is provided in the middle of the pipe 52.
  • the liquid magnetic processing device 54 performs magnetic processing on the oil flowing through the pipe 52 and ionizes the oil.
  • the pulse power supply device 55 is a power supply for operating the liquid magnetic processing device 54.
  • processing is performed so that positive ions are generated from the oil.
  • the type and number of frequencies and the method of applying the polarity are selected so that such processing is performed efficiently.
  • the oil containing positive ions generated here has an increased redox degree (eg, +150 mV).
  • the oil ionized by the oil ionization unit 5 is sent to the potential applying unit 6 through the pipe 21.
  • the potential applying unit 6 includes a tank 61, a pipe 62, a pump 63, a nozzle 64, a direct current high voltage power supply device 65, a wiring 66, and the like.
  • the pipe 62 and the pump 63 are arranged to circulate the oil in the tank 61.
  • the nozzle 64 is attached to the upper end of the pipe 62, and circulates the oil that is circulated and returned to the tank 61 into a spray form as fine as possible. Therefore, as the pump 63, a pump having a supply pressure sufficient to make the oil finely sprayed is used. Further, a positive potential is applied to the nozzle 64 from the DC high-voltage power supply device 65 through the wiring 66. This is to impart a positive potential to the oil to be sprayed. This potential application is to further improve the mixing with water.
  • the electric potential provision part equivalent to the electric potential provision part 6 is not provided about the pretreatment of water, it is necessary to provide about the pretreatment of oil. Although the reason has not yet been elucidated, an experimental result has been obtained that the mixed liquid does not become a microemulsion unless the potential applying unit 6 is provided in the oil pretreatment.
  • the oil ionized by the oil ionization unit 5 and given a positive potential by the potential application unit 6 is sent to the mixing unit 7 via the pipe 22.
  • the mixing unit 7 includes a tank 71, nozzles 72 and 73, stirring blades 74, a direct current high voltage power supply device 75, wirings 76 and 77, and the like.
  • the pipe 20 for supplying the pretreated water is drawn into the mixing unit 7, and a nozzle 73 is attached to the tip thereof.
  • a negative potential is applied to the nozzle 73 from the DC high voltage power supply device 75 through the wiring 77. Water is strongly sprayed from the nozzle 73, and the water particles in a fine mist are further negatively charged.
  • the pipe 22 for supplying the pretreated oil is drawn into the mixing unit 7, and a nozzle 72 is attached to the tip of the pipe 22.
  • a positive potential is applied to the nozzle 72 from the DC high voltage power supply device 75 through the wiring 76.
  • the oil is strongly sprayed from the nozzle 72 and the fine mist of oil particles is further positively charged.
  • the intervals and directions of the nozzles 72 and 73 are set such that the sprays produced from the nozzles 72 and 73 are mixed in the air.
  • the pretreated water and oil are sprayed into the tank 71 so as to mix with each other from the nozzles 73 and 72, respectively, but the sprayed water and oil particles are charged to opposite polarities. Therefore, a strong suction force acts between the two, and they mix very well when they are floating in the air.
  • the stirring blade 74 is for accelerating the mixing of the mixed liquid that has fallen and accumulated. However, since the mixing blade 74 is mixed very well when it is dropped, the stirring blade 74 only needs to be lightly stirred. In the mixed liquid thus produced, the particle diameter of the mixed liquid is as small as 0.05 ⁇ m or less, and the mixed liquid is in a microemulsion state.
  • microemulsion since the particle size of the mixed liquid is small, the scattering of visible light hitting it is small. Therefore, the color of the microemulsion does not become cloudy and maintains the original liquid color. For example, in the case of a microemulsion of water and kerosene, since the water is transparent, the microemulsion retains the kerosene color. Therefore, the appearance is a kerosene-like appearance, which is preferable.
  • the mixed liquid (microemulsion) obtained in the mixing unit 7 is sent to the warm storage unit 8 through the pipe 23.
  • the warming storage unit 8 includes a tank 81, a heater 82, and the like.
  • the heater 82 is for keeping the microemulsion in a stable state.
  • the heater for such a purpose can also be provided in places other than the warm storage part 8.
  • the tanks 41 and 61 may be provided.
  • the pulse power supply devices 45 and 55 are shown as separate devices, but may be configured as one device, and a required pulse power supply may be supplied from each device.
  • the DC high-voltage power supply devices 65 and 75 may be configured as one device, and a required high-voltage power supply may be supplied to each from there.
  • the microemulsion generator of the present invention the following effects can be obtained.
  • the cost is reduced accordingly.
  • the mixed particle size is very small, it does not separate and return to the original liquid.
  • the calorific value of the microemulsion of water and fuel oil was examined, it was almost the same as the original fuel oil. Therefore, the microemulsion produced from water and gasoline can be used for an internal combustion engine such as an automobile (conventional mixed fuel cannot be used for an internal combustion engine).
  • the demand for mixing two types of liquids as finely as possible to a fine particle level is not limited to the field of mixed fuels but also in various fields (for example, paints, cosmetics, foods, etc.). Needless to say, the present invention is applicable to such a field.
  • DC high voltage power supply device 66 ... wiring, 71 ... tank, 72, 73 ... Nozzle, 74 ... stirring blade, 75 ...
  • DC high voltage power supply device 76, 77 ... wiring, 81 ... tank, 82 ... heater, 100 ... piping, 101 ... liquid magnetic processing device, 102 ... electromagnetic field generator, 103 ... pulse Power supply, 201 202 ... pipe, 203 ... mixer, 204 ... stirring drive unit, 205 ... tank, 206 ... liquid mixture, 207 ... stirring blades, 208, 209 ... pipe, 210 ... water softening unit

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

Conventionnellement, les combustibles mixtes produits par ajout d'un émulsifiant à un carburant et de l'eau sont non seulement coûteux en raison du coût élevé de l'émulsifiant, mais sont également blanc laiteux et ne ressemblent pas à des carburants. Afin d'éliminer de tels problèmes, la présente invention concerne un dispositif dans lequel : de l'eau destinée à être mélangée est prétraitée dans une partie d'adoucissement d'eau (2), une partie de purification d'eau (3), et une partie d'ionisation d'eau (4) pour rendre l'eau fortement alcaline et avoir une valeur négative de potentiel d'oxydo-réduction, et cette eau est envoyée à une partie de mélange (7) ; une huile destinée à être mélangée est prétraitée dans une partie d'ionisation d'huile (5) et une partie de transmission de potentiel (6) pour rendre l'huile positivement chargée et avoir une valeur positive de potentiel d'oxydo-réduction, et cette huile est envoyée à la partie de mélange (7) ; et dans la partie de mélange (7), l'eau est négativement chargée et pulvérisée et l'huile positivement chargée est pulvérisée de sorte que ces pulvérisations se rassemblent pour mélanger l'eau et l'huile. Le liquide mixte est dans un état de micro-émulsion et a la même couleur que l'huile originale. Une réduction de coût est obtenue grâce à la non-utilisation d'un émulsifiant.
PCT/JP2014/075340 2014-09-25 2014-09-25 Dispositif de production de micro-émulsion WO2016046925A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
SG11201603096UA SG11201603096UA (en) 2014-09-25 2014-09-25 Apparatus for producing microemulsion
PCT/JP2014/075340 WO2016046925A1 (fr) 2014-09-25 2014-09-25 Dispositif de production de micro-émulsion
PH12016500800A PH12016500800A1 (en) 2014-09-25 2016-04-28 Apparatus for producing microemulsion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2014/075340 WO2016046925A1 (fr) 2014-09-25 2014-09-25 Dispositif de production de micro-émulsion

Publications (1)

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WO2016046925A1 true WO2016046925A1 (fr) 2016-03-31

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PCT/JP2014/075340 WO2016046925A1 (fr) 2014-09-25 2014-09-25 Dispositif de production de micro-émulsion

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PH (1) PH12016500800A1 (fr)
SG (1) SG11201603096UA (fr)
WO (1) WO2016046925A1 (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001019983A (ja) * 1999-07-06 2001-01-23 Shigemi Sawada 水と油との混合物であるエマルジョンの製造装置およびエマルジョンの製造方法
JP2009046645A (ja) * 2006-08-22 2009-03-05 Accord System:Kk 低濃度排ガス燃料系エマルション生成前処理法とその付属装置
JP2010013598A (ja) * 2008-07-07 2010-01-21 Kono:Kk エマルション燃料製造装置
JP2011256321A (ja) * 2010-06-11 2011-12-22 Yoshisuke Nagao 加水燃料の製造方法及び製造装置

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001019983A (ja) * 1999-07-06 2001-01-23 Shigemi Sawada 水と油との混合物であるエマルジョンの製造装置およびエマルジョンの製造方法
JP2009046645A (ja) * 2006-08-22 2009-03-05 Accord System:Kk 低濃度排ガス燃料系エマルション生成前処理法とその付属装置
JP2010013598A (ja) * 2008-07-07 2010-01-21 Kono:Kk エマルション燃料製造装置
JP2011256321A (ja) * 2010-06-11 2011-12-22 Yoshisuke Nagao 加水燃料の製造方法及び製造装置

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PH12016500800B1 (en) 2016-06-13
SG11201603096UA (en) 2016-05-30
PH12016500800A1 (en) 2016-06-13

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