WO2015130088A1 - Composition for fabric softener - Google Patents

Composition for fabric softener Download PDF

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Publication number
WO2015130088A1
WO2015130088A1 PCT/KR2015/001844 KR2015001844W WO2015130088A1 WO 2015130088 A1 WO2015130088 A1 WO 2015130088A1 KR 2015001844 W KR2015001844 W KR 2015001844W WO 2015130088 A1 WO2015130088 A1 WO 2015130088A1
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WO
WIPO (PCT)
Prior art keywords
fabric softener
softener composition
weight
acid
vinegar
Prior art date
Application number
PCT/KR2015/001844
Other languages
French (fr)
Korean (ko)
Inventor
조윤진
차경온
김세훈
심연수
Original Assignee
주식회사 엘지생활건강
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020140102214A external-priority patent/KR20150125520A/en
Priority claimed from KR1020140102206A external-priority patent/KR20150100464A/en
Priority claimed from KR1020140102211A external-priority patent/KR20150125517A/en
Priority claimed from KR1020140102207A external-priority patent/KR20150100465A/en
Priority claimed from KR1020150025438A external-priority patent/KR102067701B1/en
Priority claimed from KR1020150025439A external-priority patent/KR102067702B1/en
Application filed by 주식회사 엘지생활건강 filed Critical 주식회사 엘지생활건강
Priority to JP2016554281A priority Critical patent/JP6817067B2/en
Priority to CN201580010357.0A priority patent/CN106029858B/en
Publication of WO2015130088A1 publication Critical patent/WO2015130088A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups

Definitions

  • the present invention relates to a fabric softener composition.
  • Fabric softeners are widely used in homes to prevent static electricity generated in clothing and to give the flexibility of the fiber, the amount of use is increasing gradually.
  • the desire for hygiene and cleanliness is increased, and the pursuit of a more comfortable medical life, there is a growing interest in preventing the growth of microorganisms that can occur in clothing and removing odors.
  • the altered odor that occurs in fibers is caused by the reaction of organic compounds, such as sweat odors, with volatile organic compounds such as unsaturated lower fatty acids and ammonia, which are produced by decomposition of skin flora, or with residual components of laundry detergents or fabric softeners.
  • organic compounds such as sweat odors
  • volatile organic compounds such as unsaturated lower fatty acids and ammonia, which are produced by decomposition of skin flora, or with residual components of laundry detergents or fabric softeners.
  • drying time is delayed when drying indoors, and it is known that the odor caused by Morxella asloensis is more likely to occur.
  • a conventional softening agent composition containing an antimicrobial agent was used, but the antimicrobial agent included in the conventional softening agent is harmful to the human body.
  • the use of such antimicrobial agents has been avoided due to the fact that the use of synthetic antimicrobial agents is reported to be harmful to the human body.
  • the fabric softener has been using a cationic surfactant as a flexible component for more than 60 years since it was commercialized worldwide in the 1950s [Korea Patent Publication No. 10-2007-0090861].
  • a cationic surfactant as a flexible component for more than 60 years since it was commercialized worldwide in the 1950s [Korea Patent Publication No. 10-2007-0090861].
  • the human hazard of such cationic surfactants has been revealed, and the desire to avoid them is increasing.
  • the fabric softener has a disadvantage that the high viscosity of the organic acid in the wash water is slow (diffusion) can not fully exhibit the effect of the organic acid.
  • the present invention does not use a cationic surfactant, which is included as a flexible component in the conventional fabric softener composition, but adds an organic acid, improves the loosening property of the organic acid by using a thickening polymer, and calcium carbonate, which is a detergent insoluble component remaining in the garment.
  • An object of the present invention is to provide a fabric softener composition having excellent dissolution and removal effect.
  • the present invention provides a fabric softener composition
  • a fabric softener composition comprising an organic acid and a thickening polymer, the viscosity of 1 to 250 cPs measured at 25 °C, 60 rpm with a rotating viscometer.
  • the present invention does not include a cationic surfactant, and includes a cationic polymer; Organic acid; And it provides a resilient fiber softener composition comprising a fragrance.
  • the fabric softener composition according to the present invention uses an organic acid, but adds a polymer for thickening to improve the loosening property of the organic acid in a short washing / rinsing time, and is very effective in dissolving and removing calcium carbonate, which is a detergent insoluble component remaining in the garment. .
  • the fabric softener composition according to the present invention uses cationic polymer and organic acid instead of cationic surfactant which acts as a conventional fragrance carrier and affects reverberation, which is harmful to human body, and is not harmful to human body. It can enhance reverberation more than fabric softeners.
  • the present invention relates to a fabric softener composition (hereinafter referred to as a first fabric softener composition) comprising an organic acid and a thickening polymer and having a viscosity of 1 to 250 cPs measured at 25 ° C. and 60 rpm with a rotating viscometer.
  • a fabric softener composition hereinafter referred to as a first fabric softener composition
  • the fabric softener composition of the present invention adds a polymer for thickening to the organic acid, thereby loosening the organic acid in a short washing / rinsing time It is characterized by an improved one.
  • the organic acid serves to remove detergent residues, specifically calcium carbonate.
  • the organic acid serves as a softener intrinsic (to soften the cloth and to feel good).
  • the organic acid may be, for example, citric acid, acetic acid, tartaric acid, succinic acid, malic acid or lactic acid or the like, but is not particularly limited thereto.
  • the organic acid may be citric acid. Since citric acid has a low unit cost of raw material costs, it is possible to reduce the production cost of the fabric softener composition.
  • the content of the organic acid is not particularly limited and may be included in an amount of 5 to 30 wt%, more specifically, 10 to 25 wt%, and more specifically 15 to 20 wt%, based on 100 wt% of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even when the content of the organic acid exceeds 30% by weight exhibits excellent calcium carbonate removal effect, the higher the content of the organic acid, the lower the pH of the rinsing water, it is better to use less than 30% by weight.
  • the fabric softener composition of the present invention includes a thickening polymer capable of adjusting the viscosity to improve the loosening property of the organic acid.
  • the thickening polymer is calcium-carboxymethyl cellulose, methyl cellulose / hydroxypropylmethylcellulose, hydroxyethyl cellulose, carbopol 934, carbopol 941, xanthan gum, sodium Alginate, guar gum, carrageenan, pectin, acrylic polymer, etc. can be used.
  • at least one acrylic polymer selected from the group consisting of acrylic acid polymers, acrylic copolymers, and acrylic acrylates is preferable.
  • the content of the thickening polymer is not particularly limited and may be included as 0.01 to 1.2% by weight, more specifically, 0.05 to 1% by weight based on 100% by weight of the fabric softener composition. Within the above range, the loosening property of the organic acid is improved and the calcium carbonate removal effect is excellent.
  • the thickening polymer is a factor for controlling the viscosity of the fabric softener composition of the present invention, and more specifically, when measured at 25 ° C. and 60 rpm with a rotatable viscometer, the viscosity may be 1 to 250 cPs. When the viscosity is greater than 250 cPs, the loosening of the diffusion of the organic acid in the washing / rinsing water may be poor, and thus it may not be easy to remove the remaining calcium carbonate in the garment.
  • composition according to the present invention is excellent in detergent debris removal effect without using a cationic surfactant by using an organic acid and a polymer for thickening, and can be easily used as a fabric softener.
  • the calcium carbonate remaining in the garment is completely removed.
  • the present invention does not include a cationic surfactant, and includes a cationic polymer; Organic acid; And a reverberation reinforcing fiber softener composition (hereinafter referred to as a second fabric softener composition) comprising a fragrance.
  • a cationic surfactant includes a cationic polymer; Organic acid; And a reverberation reinforcing fiber softener composition (hereinafter referred to as a second fabric softener composition) comprising a fragrance.
  • Cationic polymer in the present invention serves to enhance the reverberation.
  • the cationic polymer may be one or more selected from the group consisting of glucose-based polymers and acrylic polymers, but any cationic polymer having a role of reverberation strengthening may be used without limitation within a range that does not impair the effects of the present invention.
  • the glucose-based polymer may be one or more selected from the group consisting of polyquiternium, guar, starch and locust bean, but is not limited thereto.
  • the acrylic polymer may be at least one selected from the group consisting of an acrylic acid polymer, an acrylic copolymer, and silicon acrylate, but is not limited thereto.
  • the content of the cationic polymer is not particularly limited and may be included in 0.1 to 3% by weight, 0.2 to 2% by weight or 0.3 to 1% by weight relative to 100% by weight of the fabric softener composition. It serves as an excellent reverberation strengthening within the above range, and is also effective in increasing the viscosity.
  • the organic acid plays a role of removing deodorant and detergent residues.
  • the organic acid serves as a softener intrinsic (to soften the cloth and to feel good).
  • the type of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid, and lactic acid.
  • citric acid is suitable for use as an organic acid because the cost of raw materials is low.
  • the content of the organic acid is not particularly limited and may be included in 1 to 20% by weight, 5 to 15% by weight or 8 to 12% by weight based on 100% by weight of the fabric softener composition. Within the above range, it is possible to exhibit an excellent detergent insoluble component removal effect of the laundry. Even if the content of the organic acid is 20% by weight or more, the detergent residue removal effect of the excellent insoluble component of the laundry is removed, but as the content of the organic acid increases, the pH of the rinsing water is lowered, so it is better to use it at 20% by weight or less.
  • the fragrance may include, for example, floral fragrance, citrus fragrance, etc., but may be used without limitation within the range that does not impair the effects of the present invention if it can be used as a fabric softener.
  • the content is not particularly limited and may be included in 0.1 to 3% by weight, 0.2 to 2% by weight or 0.3 to 1% by weight relative to 100% by weight of the fabric softener composition. Out of the range there is a problem that the reverberation is too low or too high.
  • Vinegar may further be used in the fabric softener composition (first fabric softener composition or second fabric softener composition) of the present invention.
  • Vinegar is a sour and slightly sweet seasoning that contains acetic acid as its main ingredient, and contains dozens of organic acids such as acetic acid, citric acid and various amino acids, which helps to increase metabolism and remove body wastes, and is a powerful preservative. It serves as a powerful fungicide. In addition, vinegar may serve to remove detergent residues.
  • the content of the vinegar is not particularly limited and may be included in 0.1 to 10% by weight, 0.5 to 5% by weight or 1 to 3% by weight relative to 100% by weight of the fabric softener composition. It has a bactericidal effect and an effect of removing detergent residues within the above range.
  • the fabric softener composition (the first fabric softener composition or the second fabric softener composition) according to the present invention may further include a flower fermentation vinegar that plays a role of strong deodorization in addition to the above-mentioned composition.
  • the flower fermentation vinegar may be obtained by washing the petals with water, dried and mixed with excess vinegar and sugar fermentation for 3 to 7 days.
  • the vinegar may be commercially available vinegar, it is preferable to use 5 to 30 parts by weight based on 1 part by weight of the petals.
  • the sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup.
  • the sugar serves to alcohol ferment the flower extract, it is preferred to use 5 to 30 parts by weight based on 1 part by weight of the petals.
  • the flower fermentation vinegar is sterilized with the original flower, hot water extracted for 10 to 30 minutes at 100 to 150 °C and then mixed with the hot water extract and vinegar and sugar and fermentation process at 20 to 40 °C for 72 to 96 hours Can be obtained through
  • the vinegar refers to fermented by propagating wild vinegar isolated from vinegar, odorless ( ⁇ ) produced in the traditional manner, the seed vinegar by the acetic acid bacteria Acetobacter sp. Anything that can be produced can be used.
  • the amount of the seed may be added in 5 to 30% by weight based on 100% by weight of the hydrothermal extract flowers.
  • the added amount of the vinegar is less than 5% by weight, it is difficult to induce vinegar fermentation of the aged hydrothermal extract, and when it exceeds 30% by weight, the efficiency of vinegar fermentation does not increase any more.
  • the sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup.
  • the sugar serves to ferment the flower hydrothermal extract alcohol, and may be added in an amount of 5 to 30% by weight based on 100% by weight of the hydrothermal extract flower.
  • Flower fermentation vinegar prepared by the above method may have a pH of 2.70 to 3.30, the acidity of 3 to 7.
  • Types of flowers used for the flower fermentation vinegar can be used without limitation.
  • a peach blossom, an apricot blossom, an acacia blossom, a chamomile blossom, a jasmine blossom or a lotus blossom can be used.
  • the content of the flower fermentation vinegar is not particularly limited and may be included in 0.001 to 10% by weight, 0.05 to 5% by weight or 0.1 to 2% by weight relative to 100% by weight of the fabric softener composition. It has an effect of removing bactericidal action and odor within the above range.
  • the fabric softener composition (first or second fabric softener composition) according to the present invention may further include ethanol for the phase stability of the contents.
  • the content of the ethanol is not particularly limited, and may be included in 0.1 to 10% by weight, 0.5 to 8% by weight or 1 to 7% by weight relative to 100% by weight of the fabric softener composition. It has a phase stability effect of excellent contents within the above range.
  • the fabric softener composition (first or second fabric softener composition) according to the present invention may further use a fragrance.
  • the fragrance may include, for example, a floral fragrance, a citrus fragrance, or the like, but may be used without limitation within a range that does not impair the effects of the present invention if it can be used as a fabric softener.
  • the amount of the perfume is not particularly limited and may be included in 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fabric softener composition.
  • the fabric softener composition (the first fabric softener composition or the second fabric softener composition) according to the present invention may further use a fragrance solubilizer, the fragrance solubilizer to relieve odor of vinegar softening by fermentation vinegar, etc. Improve satisfaction Its content is not particularly limited and may be included in 0.1 to 10% by weight or 1 to 7% by weight relative to 100% by weight of the fabric softener composition.
  • the fabric softener composition (first fabric softener composition or the second fabric softener composition) according to the present invention may further include a plant extract to improve the odor removal effect such as vinegar odor.
  • the plant extract may include one or more selected from the group consisting of persimmon leaves, green tea and dermis.
  • the fabric softener composition (first fabric softener composition or the second fabric softener composition) according to the present invention may further include a small amount of additives within the scope of the present invention.
  • the additive may be an antimicrobial component for further improving the antimicrobial effect.
  • the additive may be a pigment, a preservative, an antioxidant, an antifoaming agent, and the like.
  • the content of the additive is not particularly limited, and may be included in an amount of 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fabric softener composition.
  • composition (first fabric softener composition or second fabric softener composition) of the present invention is generally formulated into the fabric softener in addition to the components described above in each formulation, water, surfactant, humectant, lower alcohol, thickener. , Chelating agent, dye, preservative, etc. can be suitably blended and used as needed.
  • the content thereof is not particularly limited, and may be included in an amount of 55 to 90 wt% or 60 to 85 wt% based on 100 wt% of the fabric softener composition.
  • composition (first fabric softener composition or second fabric softener composition) according to the present invention may be used by powder, granulation using methods known in the art, and may be prepared in a liquid state.
  • Vinegar was used brewed vinegar (natural food).
  • the concentration of calcium carbonate remaining in the garment after washing was measured using the fabric softener compositions of Examples and Comparative Examples.
  • Washing test conditions were based on the test method in EL306 (Fiber Softener) among the environmental label certification criteria of the Korea Environmental Industry and Technology Institute.
  • the amount of the composition was 0.67 mL / L at the last rinsing.
  • Table 2 shows the measurement results of the residual calcium carbonate concentration in the garment.
  • the viscosity of the composition was measured at 25 degreeC and 60 rpm with the Brookfield rotary viscometer.
  • a cationic polymer a flower fermentation vinegar, vinegar, and citric acid were added to purified water, followed by stirring for 30 minutes, and a solution containing ethanol, a flavoring agent, a fragrance solubilizer, and an antifoaming agent was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition. .
  • glucose-based polymer used commercially available polyquaternium [Polymer Polymer LR30M from DOW Chemical Co., Ltd.]
  • acrylic polymer used a commercially available acrylic copolymer [Rheovis FRC from BASF].
  • vinegar used brewed vinegar (natural food).
  • the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.
  • An indicator fiber softener was used instead of the fabric softener composition.
  • the surface fiber softener composition was the same as the surface fiber softener composition of the EL306 (fiber softener) test method of the environmental label certification criteria of the Korea Environmental Industry and Technology Institute.
  • a cationic surfactant was added to purified water and stirred for 30 minutes, and then a solution containing ethanol, a perfume, a solubilizer, and an antifoam was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition.
  • the cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).
  • Example 10 Cationic surfactant 5 - - - - - Glucose-based polymer - 0.5 - 0.5 0.5 Acrylic Polymer - - 0.5 - - Flower Fermented Vinegar - - - 0.5 0.5 vinegar - - - - One ethanol 5 Citric acid 10 Fragrance Solubilizer 5 Antifoam 0.05 Spices 0.5 Purified water Up to 100% by weight
  • Reverberation intensity was evaluated by sensory evaluation for 10 professional monitors, with one point having the weakest reverberation intensity and five points having the highest reverberation intensity.
  • Example 10 Reverberation intensity after drying (5-point scale) 2.0 3.2 3.7 3.6 3.8 3.9
  • the fiber softener composition contains only a cationic surfactant that serves as a fragrance carrier, and the indicator fiber softener of Comparative Example 3 without fragrance has almost no fragrance after drying.
  • compositions of Examples 7 to 10 according to the present invention showed excellent reverberation strength by exhibiting more than equivalent reverberation strength even when a cationic polymer was used without using a cationic surfactant.

Abstract

The present invention relates to a composition for a fabric softener, and more specifically, which uses an organic acid and a viscosity-increasing polymer, improves loosening of the organic acid by controlling viscosity, and which can effectively remove calcium carbonate remaining in clothes when washing. Also, a composition for a fabric softener for enhancing remaining scent, according to the present invention, can further enhance remaining scent in clothes compared to existing fabric softeners by using a cationic polymer instead of a cationic surfactant, which is harmful to the body.

Description

섬유유연제 조성물Fabric softener composition
본 발명은 섬유유연제 조성물에 관한 것이다. The present invention relates to a fabric softener composition.
섬유유연제는 의류에 발생하는 정전기를 방지하고 섬유의 유연성을 부여하기 위하여 가정에서 널리 사용하고 있으며, 그 사용량이 점차 증가하고 있는 추세이다. 최근에는 소비자의 생활 수준이 향상되고, 위생 및 청결에 대한 욕구가 증가하며, 보다 쾌적한 의생활을 추구하려 함에 따라, 의류에 발생할 수 있는 미생물의 증식방지 및 악취제거에 대한 관심이 늘고 있다. Fabric softeners are widely used in homes to prevent static electricity generated in clothing and to give the flexibility of the fiber, the amount of use is increasing gradually. In recent years, as consumer's living standard is improved, the desire for hygiene and cleanliness is increased, and the pursuit of a more comfortable medical life, there is a growing interest in preventing the growth of microorganisms that can occur in clothing and removing odors.
일반적으로 섬유에 발생하는 꿉꿉한 냄새는 땀냄새 등의 성분인 유기화합물이 피부 상재균이 분해되어 생성된 불포화 저급 지방산 및 암모니아 등의 휘발성 유기화합물과 반응하거나 세탁세제 또는 섬유유연제 잔류성분과 반응하여 발생될 수 있다. 특히 장마철의 경우, 실내 건조시 건조시간이 지연되므로 악취균인 Morxella asloensis로 인해 꿉꿉한 냄새가 더 발생하고 있는 것으로 알려졌다. In general, the altered odor that occurs in fibers is caused by the reaction of organic compounds, such as sweat odors, with volatile organic compounds such as unsaturated lower fatty acids and ammonia, which are produced by decomposition of skin flora, or with residual components of laundry detergents or fabric softeners. Can be. In particular, in the rainy season, drying time is delayed when drying indoors, and it is known that the odor caused by Morxella asloensis is more likely to occur.
이러한 꿉꿉한 냄새 등을 제거하기 위하여, 종래에는 항균제를 포함하는 섬유유연제 조성물을 사용했는데, 종래 섬유유연제에 포함되는 항균제는 인체에 유해하다. 최근에는 합성 항균제 사용시 인체에 유해하다는 내용이 보도됨에 따라 이러한 항균제의 사용이 기피되고 있는 실정이다. In order to remove such a odor, a conventional softening agent composition containing an antimicrobial agent was used, but the antimicrobial agent included in the conventional softening agent is harmful to the human body. Recently, the use of such antimicrobial agents has been avoided due to the fact that the use of synthetic antimicrobial agents is reported to be harmful to the human body.
또한 섬유유연제는 1950년 대에 전 세계적으로 상용화된 이후로 60년이 넘도록 유연성분으로 양이온 계면활성제를 사용하고 있다[한국공개특허 제10-2007-0090861호]. 그러나, 근래에 들어 이러한 양이온 계면활성제의 인체 유해성이 밝혀져 이를 기피하고자 하는 욕구가 증가하고 있다.In addition, the fabric softener has been using a cationic surfactant as a flexible component for more than 60 years since it was commercialized worldwide in the 1950s [Korea Patent Publication No. 10-2007-0090861]. However, recently, the human hazard of such cationic surfactants has been revealed, and the desire to avoid them is increasing.
아울러, 섬유유연제는 점도가 높으면 세탁수에서 유기산의 확산(풀어짐)이 늦어져 충분히 유기산의 효력을 발휘할 수 없는 단점이 있다.In addition, the fabric softener has a disadvantage that the high viscosity of the organic acid in the wash water is slow (diffusion) can not fully exhibit the effect of the organic acid.
본 발명은 종래 섬유유연제 조성물에 유연성분으로 포함되던 양이온 계면활성제를 사용하지 않고, 유기산을 첨가하되, 증점용 폴리머를 사용하여 유기산의 풀림성을 향상시키고, 의류 내 잔존하는 세제 불용성 성분인 탄산칼슘의 용해 및 제거 효과가 우수한 섬유유연제 조성물을 제공하는 것을 목적으로 한다.The present invention does not use a cationic surfactant, which is included as a flexible component in the conventional fabric softener composition, but adds an organic acid, improves the loosening property of the organic acid by using a thickening polymer, and calcium carbonate, which is a detergent insoluble component remaining in the garment. An object of the present invention is to provide a fabric softener composition having excellent dissolution and removal effect.
또한, 본 발명은 종래 섬유유연제 조성물에 통상 향 캐리어로 포함되던 양이온성 계면활성제를 사용하지 않고, 양이온성 폴리머를 사용하여 잔향을 강화시킨 섬유유연제 조성물을 제공하는 것을 목적으로 한다.It is also an object of the present invention to provide a fiber softener composition in which reverberation is enhanced by using a cationic polymer without using a cationic surfactant that is usually included as a fragrance carrier in a conventional fabric softener composition.
상기 목적을 달성하기 위하여, 본 발명은 유기산과 증점용 폴리머를 포함하고, 회전용 점도계로 25℃, 60 rpm에서 측정된 점도가 1 내지 250 cPs인 섬유유연제 조성물을 제공한다.In order to achieve the above object, the present invention provides a fabric softener composition comprising an organic acid and a thickening polymer, the viscosity of 1 to 250 cPs measured at 25 ℃, 60 rpm with a rotating viscometer.
또한, 본 발명은 양이온성 계면활성제를 포함하지 않으며, 양이온성 폴리머; 유기산; 및 향료를 포함하는 잔향 강화용 섬유 유연제 조성물을 제공한다.In addition, the present invention does not include a cationic surfactant, and includes a cationic polymer; Organic acid; And it provides a resilient fiber softener composition comprising a fragrance.
본 발명에 따른 섬유유연제 조성물은 유기산을 사용하되, 증점용 폴리머를 부가하여 짧은 세탁/헹굼 시간에 유기산의 풀림성을 향상시켜 의류 내 잔존하는 세제 불용성 성분인 탄산칼슘의 용해 및 제거에 매우 효과적이다.The fabric softener composition according to the present invention uses an organic acid, but adds a polymer for thickening to improve the loosening property of the organic acid in a short washing / rinsing time, and is very effective in dissolving and removing calcium carbonate, which is a detergent insoluble component remaining in the garment. .
본 발명에 따른 섬유유연제 조성물은 통상의 향 캐리어로 작용하여 잔향에 영향을 주면서 인체에 유해한 양이온성 계면활성제 대신, 양이온성 폴리머 및 유기산을 사용하여 인체에 유해하지 않으면서 기존 양이온성 계면활성제를 사용한 섬유유연제 보다 잔향을 강화시킬 수 있다. The fabric softener composition according to the present invention uses cationic polymer and organic acid instead of cationic surfactant which acts as a conventional fragrance carrier and affects reverberation, which is harmful to human body, and is not harmful to human body. It can enhance reverberation more than fabric softeners.
본 발명은 유기산과 증점용 폴리머를 포함하고, 회전용 점도계로 25℃, 60 rpm에서 측정된 점도가 1 내지 250 cPs인 섬유유연제 조성물(이하, 제 1 섬유유연제 조성물)에 관한 것이다.The present invention relates to a fabric softener composition (hereinafter referred to as a first fabric softener composition) comprising an organic acid and a thickening polymer and having a viscosity of 1 to 250 cPs measured at 25 ° C. and 60 rpm with a rotating viscometer.
점도가 높으면 세탁수에 유기산의 확산(풀어짐)이 늦어져 충분히 유기산의 효력을 발휘할 수 없는바 본 발명의 섬유유연제 조성물은 유기산에 증점용 폴리머를 부가하여 짧은 세탁/헹굼 시간에 유기산의 풀림성을 향상시킨 것임을 특징으로 한다.If the viscosity is high, the diffusion (relaxing) of the organic acid in the wash water is delayed, and thus the effect of the organic acid cannot be sufficiently exerted. The fabric softener composition of the present invention adds a polymer for thickening to the organic acid, thereby loosening the organic acid in a short washing / rinsing time It is characterized by an improved one.
본 발명에서 유기산은 세제 찌꺼기, 구체적으로 탄산칼슘 제거 역할을 수행한다. 또한, 상기 유기산은 유연제 본연의(옷감을 부드럽게 하고 촉감을 좋게 하는) 역할을 수행한다.In the present invention, the organic acid serves to remove detergent residues, specifically calcium carbonate. In addition, the organic acid serves as a softener intrinsic (to soften the cloth and to feel good).
상기 유기산은 예를 들어, 구연산, 초산, 주석산, 호박산, 사과산 또는 젖산 등을 하나 이상 사용할 수 있으나, 이에 특별히 제한하는 것은 아니다. 바람직하게는, 유기산은 구연산일 수 있다. 상기 구연산은 원재료비의 단가가 낮으므로 섬유유연제 조성물의 생산 단가를 절감할 수 있다.The organic acid may be, for example, citric acid, acetic acid, tartaric acid, succinic acid, malic acid or lactic acid or the like, but is not particularly limited thereto. Preferably, the organic acid may be citric acid. Since citric acid has a low unit cost of raw material costs, it is possible to reduce the production cost of the fabric softener composition.
상기 유기산의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 5 내지 30 중량%, 더 구체적으로, 10 내지 25 중량%, 보다 구체적으로, 15 내지 20 중량%로 포함될 수 있다. 상기 범위 내에서 우수한 탄산칼슘 제거 효과를 나타낼 수 있다. 유기산의 함량이 30 중량%를 초과하는 경우에서도 우수한 탄산칼슘 제거 효과를 나타내나, 유기산의 함량이 높아질수록 헹굼수의 pH가 낮아지므로, 30 중량% 이하로 사용하는 것이 좋다.The content of the organic acid is not particularly limited and may be included in an amount of 5 to 30 wt%, more specifically, 10 to 25 wt%, and more specifically 15 to 20 wt%, based on 100 wt% of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even when the content of the organic acid exceeds 30% by weight exhibits excellent calcium carbonate removal effect, the higher the content of the organic acid, the lower the pH of the rinsing water, it is better to use less than 30% by weight.
본 발명의 섬유유연제 조성물은 유기산의 풀림성을 향상시킬 수 있도록 점도를 조절할 수 있는 증점용 폴리머를 포함한다. 본 발명에 있어서, 상기 증점용 폴리머로 칼슘-카르복시메틸 셀룰로스, 메틸 셀룰로스/하이드록시프로필메틸셀룰로스, 하이드록시 에틸 셀룰로스, 카보폴 934(carbopol 934), 카보폴 941(carbopol 941), 잔탄검, 소듐 알기네이트, 구아검, 카라기난, 펙틴, 아크릴계 폴리머 등을 사용할 수 있다. 바람직하게는, 아크릴산폴리머류 및 아크릴코폴리머, 아크릴화실리콘계로 이루어진 군에서 선택된 하나 이상의 아크릴계 폴리머가 좋다. The fabric softener composition of the present invention includes a thickening polymer capable of adjusting the viscosity to improve the loosening property of the organic acid. In the present invention, the thickening polymer is calcium-carboxymethyl cellulose, methyl cellulose / hydroxypropylmethylcellulose, hydroxyethyl cellulose, carbopol 934, carbopol 941, xanthan gum, sodium Alginate, guar gum, carrageenan, pectin, acrylic polymer, etc. can be used. Preferably, at least one acrylic polymer selected from the group consisting of acrylic acid polymers, acrylic copolymers, and acrylic acrylates is preferable.
상기 증점용 폴리머의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 0.01 내지 1.2 중량%, 보다 구체적으로, 0.05 내지 1 중량%로 포함될 수 있다. 상기 범위 내에서 유기산의 풀림성이 향상되어 탄산칼슘 제거 효과가 우수하다. The content of the thickening polymer is not particularly limited and may be included as 0.01 to 1.2% by weight, more specifically, 0.05 to 1% by weight based on 100% by weight of the fabric softener composition. Within the above range, the loosening property of the organic acid is improved and the calcium carbonate removal effect is excellent.
아울러, 상기 증점용 폴리머는 본 발명의 섬유유연제 조성물의 점도를 제어하는 요인이 되며, 보다 구체적으로 회전형 점도계로 25℃, 60 rpm에서 측정할 경우, 점도는 1 내지 250 cPs일 수 있다. 상기 점도가 250 cPs를 초과한 경우, 세탁/헹굼수 내에서 유기산의 확산 풀림성이 떨어져 의류 내 잔존 탄산칼슘의 제거가 용이하지 않을 수 있다. In addition, the thickening polymer is a factor for controlling the viscosity of the fabric softener composition of the present invention, and more specifically, when measured at 25 ° C. and 60 rpm with a rotatable viscometer, the viscosity may be 1 to 250 cPs. When the viscosity is greater than 250 cPs, the loosening of the diffusion of the organic acid in the washing / rinsing water may be poor, and thus it may not be easy to remove the remaining calcium carbonate in the garment.
본 발명에 따른 조성물은 유기산과 증점용 폴리머를 사용함으로써 양이온 계면활성제를 포함하지 않아도 세제 찌꺼기 제거 효과가 우수하여, 섬유유연제로 용이하게 사용할 수 있다. The composition according to the present invention is excellent in detergent debris removal effect without using a cationic surfactant by using an organic acid and a polymer for thickening, and can be easily used as a fabric softener.
일 구체예에서, 본 발명에 따른 섬유유연제 조성물을 세탁/헹굼 수에 제공할 경우, 의류에 잔존하는 탄산칼슘을 완전히 제거하였다.In one embodiment, when providing the fabric softener composition according to the present invention to wash / rinse water, the calcium carbonate remaining in the garment is completely removed.
또한, 본 발명은 양이온성 계면활성제를 포함하지 않으며, 양이온성 폴리머; 유기산; 및 향료를 포함하는 잔향 강화용 섬유 유연제 조성물(이하, 제 2 섬유유연제 조성물)에 관한 것이다.In addition, the present invention does not include a cationic surfactant, and includes a cationic polymer; Organic acid; And a reverberation reinforcing fiber softener composition (hereinafter referred to as a second fabric softener composition) comprising a fragrance.
본 발명에서 양이온성 폴리머는 잔향을 강화시키는 역할을 수행한다. 상기 양이온성 폴리머는 글루코오스계 폴리머, 아크릴계 폴리머로 이루어진 군에서 선택된 하나 이상일 수 있으나, 잔향 강화 역할을 하는 양이온성 폴리머라면 본 발명의 효과를 저해하지 않는 범위 내에서 제한 없이 사용될 수 있다. 상기 글루코오스계 폴리머는 폴리퀴터늄, 구아, 스타치 및 로커스트빈계로 이루어진 군에서 선택된 하나 이상일 수 있으나, 이에 제한되지 않는다. 상기 아크릴계 폴리머는 아크릴산폴리머, 아크릴코폴리머 및 아크릴화실리콘으로 이루어진 군에서 선택된 하나 이상일 수 있으나, 이에 제한되지 않는다.Cationic polymer in the present invention serves to enhance the reverberation. The cationic polymer may be one or more selected from the group consisting of glucose-based polymers and acrylic polymers, but any cationic polymer having a role of reverberation strengthening may be used without limitation within a range that does not impair the effects of the present invention. The glucose-based polymer may be one or more selected from the group consisting of polyquiternium, guar, starch and locust bean, but is not limited thereto. The acrylic polymer may be at least one selected from the group consisting of an acrylic acid polymer, an acrylic copolymer, and silicon acrylate, but is not limited thereto.
상기 양이온성 폴리머의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 0.1 내지 3 중량%, 0.2 내지 2 중량% 또는 0.3 내지 1 중량%로 포함될 수 있다. 상기 범위 내에서 우수한 잔향 강화 역할을 하며, 점도 상승 효과에도 효율적이다.The content of the cationic polymer is not particularly limited and may be included in 0.1 to 3% by weight, 0.2 to 2% by weight or 0.3 to 1% by weight relative to 100% by weight of the fabric softener composition. It serves as an excellent reverberation strengthening within the above range, and is also effective in increasing the viscosity.
본 발명에서 유기산은 탈취제 및 세제 찌꺼기 제거의 역할을 수행한다. 또한, 상기 유기산은 유연제 본연의(옷감을 부드럽게 하고 촉감을 좋게 하는) 역할을 수행한다. 이러한 유기산의 종류는 특별히 제한되지 않으며, 예를 들어, 구연산, 초산, 주석산, 호박산, 사과산 및 젖산으로 이루어진 군에서 선택된 하나 이상을 포함할 수 있다. 특히, 구연산은 원재료비의 단가가 낮으므로 유기산으로 사용하기에 적합하다.In the present invention, the organic acid plays a role of removing deodorant and detergent residues. In addition, the organic acid serves as a softener intrinsic (to soften the cloth and to feel good). The type of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid, and lactic acid. In particular, citric acid is suitable for use as an organic acid because the cost of raw materials is low.
상기 유기산의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 1 내지 20 중량%, 5 내지 15 중량% 또는 8 내지 12 중량%로 포함될 수 있다. 상기 범위 내에서 우수한 세탁 불용분 성분의 세제 찌꺼기 제거 효과를 나타낼 수 있다. 유기산의 함량이 20 중량% 이상에서도 우수한 세탁 불용분 성분의 세제 찌꺼기 제거 효과를 나타내나, 유기산의 함량이 높아질수록 헹굼수의 pH가 낮아지므로, 20 중량% 이하로 사용하는 것이 좋다. The content of the organic acid is not particularly limited and may be included in 1 to 20% by weight, 5 to 15% by weight or 8 to 12% by weight based on 100% by weight of the fabric softener composition. Within the above range, it is possible to exhibit an excellent detergent insoluble component removal effect of the laundry. Even if the content of the organic acid is 20% by weight or more, the detergent residue removal effect of the excellent insoluble component of the laundry is removed, but as the content of the organic acid increases, the pH of the rinsing water is lowered, so it is better to use it at 20% by weight or less.
본 발명에서 향료는 예를 들어 플로랄계 향료, 시트러스계 향료 등을 포함할 수 있으나, 이외에 섬유유연제로 사용할 수 있는 것이라면 본 발명의 효과를 저해하지 않는 범위 내에서 제한 없이 사용될 수 있다, 상기 향료의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 0.1 내지 3 중량%, 0.2 내지 2 중량% 또는 0.3 내지 1 중량%로 포함될 수 있다. 상기 범위를 벗어나면 잔향이 너무 낮거나 너무 높은 문제점이 있다. In the present invention, the fragrance may include, for example, floral fragrance, citrus fragrance, etc., but may be used without limitation within the range that does not impair the effects of the present invention if it can be used as a fabric softener. The content is not particularly limited and may be included in 0.1 to 3% by weight, 0.2 to 2% by weight or 0.3 to 1% by weight relative to 100% by weight of the fabric softener composition. Out of the range there is a problem that the reverberation is too low or too high.
본 발명의 섬유유연제 조성물(제 1 섬유유연제 조성물 또는 제 2 섬유유연제 조성물)에 식초가 추가로 사용될 수 있다. Vinegar may further be used in the fabric softener composition (first fabric softener composition or second fabric softener composition) of the present invention.
식초는 주성분으로 초산을 함유하여 시고 약간 단맛이 있는 조미료로서, 초산, 구연산 및 각종 아미노산 등 수십여 가지 유기산이 들어 있어, 신진대사를 활발하게 하고, 체내 노폐물을 없애는데 도움을 줄 뿐만 아니라, 강력한 방부제이자 강력한 살균제로서의 역할을 수행한다. 또한, 식초는 세제 찌꺼기 제거 역할을 수행할 수 있다.Vinegar is a sour and slightly sweet seasoning that contains acetic acid as its main ingredient, and contains dozens of organic acids such as acetic acid, citric acid and various amino acids, which helps to increase metabolism and remove body wastes, and is a powerful preservative. It serves as a powerful fungicide. In addition, vinegar may serve to remove detergent residues.
상기 식초의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 0.1 내지 10 중량%, 0.5 내지 5 중량% 또는 1 내지 3 중량%로 포함될 수 있다. 상기 범위 내에서 살균 효과 및 세제 찌꺼기를 제거하는 효과를 가진다.The content of the vinegar is not particularly limited and may be included in 0.1 to 10% by weight, 0.5 to 5% by weight or 1 to 3% by weight relative to 100% by weight of the fabric softener composition. It has a bactericidal effect and an effect of removing detergent residues within the above range.
본 발명에 따른 섬유유연제 조성물(제 1 섬유유연제 조성물 또는 제 2 섬유유연제 조성물)은 전술한 조성성분 외에 강력한 탈취의 역할을 담당하는 꽃 발효식초를 추가로 포함할 수 있다.The fabric softener composition (the first fabric softener composition or the second fabric softener composition) according to the present invention may further include a flower fermentation vinegar that plays a role of strong deodorization in addition to the above-mentioned composition.
상기 꽃 발효식초는 꽃잎을 수세 및 건조하고 과량의 식초 및 당물과 혼합하여 3일 내지 7일 동안 발효시켜 얻은 것일 수 있다. The flower fermentation vinegar may be obtained by washing the petals with water, dried and mixed with excess vinegar and sugar fermentation for 3 to 7 days.
상기 식초는 시판되는 양조식초일 수 있으며, 꽃잎 1 중량부에 대하여 5 내지 30 중량부 사용하는 것이 바람직하다. 또한, 상기 당물을 포도당, 설탕, 과당, 올리고당, 또는 물엿 등 각종 당을 포함하는 것일 수 있다. 상기 당물은 꽃 추출물을 알코올 발효시키는 역할을 하며, 꽃잎 1 중량부에 대하여 5 내지 30 중량부를 사용하는 것이 바람직하다.The vinegar may be commercially available vinegar, it is preferable to use 5 to 30 parts by weight based on 1 part by weight of the petals. In addition, the sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup. The sugar serves to alcohol ferment the flower extract, it is preferred to use 5 to 30 parts by weight based on 1 part by weight of the petals.
또는, 상기 꽃 발효식초는 꽃 원물을 멸균하고, 100 내지 150℃에서 10 내지 30분 동안 열수 추출한 후 상기의 열수 추출물과 종초 및 당물을 혼합한 후 20 내지 40℃에서 72 내지 96시간 동안 발효 과정을 거쳐 얻을 수 있다.Alternatively, the flower fermentation vinegar is sterilized with the original flower, hot water extracted for 10 to 30 minutes at 100 to 150 ℃ and then mixed with the hot water extract and vinegar and sugar and fermentation process at 20 to 40 ℃ for 72 to 96 hours Can be obtained through
상기 종초는 전통방식으로 제조된 이미(異味), 이취(異臭)가 없는 양조식초에서 분리된 야생식초균을 증식시켜 발효시킨 것을 말하며, 상기 종초는 야생초산균 아세토박터균(Acetobacter sp.)에 의하여 제조될 수 있는 것이면, 모두 사용될 수 있다. 이때, 상기 종초의 첨가량은 꽃 열수 추출물 100 중량%에 대하여 5 내지 30 중량%로 첨가될 수 있다. 상기 종초의 첨가량이 5 중량% 미만일 경우, 상기 숙성된 꽃 열수 추출물의 식초 발효를 유도하기 어렵고, 30 중량%를 초과할 경우 첨가량에 비하여, 식초 발효의 효율이 더 이상 증가하지 않는다. The vinegar refers to fermented by propagating wild vinegar isolated from vinegar, odorless (이미) produced in the traditional manner, the seed vinegar by the acetic acid bacteria Acetobacter sp. Anything that can be produced can be used. At this time, the amount of the seed may be added in 5 to 30% by weight based on 100% by weight of the hydrothermal extract flowers. When the added amount of the vinegar is less than 5% by weight, it is difficult to induce vinegar fermentation of the aged hydrothermal extract, and when it exceeds 30% by weight, the efficiency of vinegar fermentation does not increase any more.
상기 당물을 포도당, 설탕, 과당, 올리고당, 또는 물엿 등 각종 당을 포함하는 것일 수 있다. 상기 당물은 꽃 열수 추출물을 알코올 발효시키는 역할을 하며, 꽃 열수 추출물 100 중량%에 대하여 5 내지 30 중량%로 첨가될 수 있다. The sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup. The sugar serves to ferment the flower hydrothermal extract alcohol, and may be added in an amount of 5 to 30% by weight based on 100% by weight of the hydrothermal extract flower.
상기 방법을 통하여 제조된 꽃 발효식초는 pH가 2.70 내지 3.30, 산도는 3 내지 7을 가질 수 있다.Flower fermentation vinegar prepared by the above method may have a pH of 2.70 to 3.30, the acidity of 3 to 7.
상기 꽃 발효식초 제조에 사용하는 꽃의 종류는 제한 없이 사용할 수 있다. 일예로, 도화꽃, 살구꽃, 아카시아꽃, 카모마일꽃, 자스민꽃 또는 연꽃 등을 사용할 수 있다.Types of flowers used for the flower fermentation vinegar can be used without limitation. For example, a peach blossom, an apricot blossom, an acacia blossom, a chamomile blossom, a jasmine blossom or a lotus blossom can be used.
상기 꽃 발효식초의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 0.001 내지 10 중량%, 0.05 내지 5 중량% 또는 0.1 내지 2 중량%로 포함될 수 있다. 상기 범위 내에서 살균 작용 및 냄새를 제거하는 효과를 가진다.The content of the flower fermentation vinegar is not particularly limited and may be included in 0.001 to 10% by weight, 0.05 to 5% by weight or 0.1 to 2% by weight relative to 100% by weight of the fabric softener composition. It has an effect of removing bactericidal action and odor within the above range.
또한, 본 발명에 따른 섬유유연제 조성물(제 1 또는 제 2 섬유유연제 조성물)은 내용물의 상 안정성을 위해 에탄올을 추가로 포함할 수 있다. In addition, the fabric softener composition (first or second fabric softener composition) according to the present invention may further include ethanol for the phase stability of the contents.
상기 에탄올의 함량은 특별히 제한되지 않으며, 섬유유연제 조성물 100 중량%에 대하여 0.1 내지 10 중량%, 0.5 내지 8 중량% 또는 1 내지 7 중량%로 포함될 수 있다. 상기 범위 내에서 우수한 내용물의 상 안정성 효과를 가진다.The content of the ethanol is not particularly limited, and may be included in 0.1 to 10% by weight, 0.5 to 8% by weight or 1 to 7% by weight relative to 100% by weight of the fabric softener composition. It has a phase stability effect of excellent contents within the above range.
또한, 본 발명에 따른 섬유유연제 조성물(제 1 또는 제 2 섬유유연제 조성물)은 향료를 추가로 사용할 수 있다. 상기 향료는 예를 들어 플로랄계 향료, 시트러스계 향료 등을 포함할 수 있으나, 이외에 섬유유연제로 사용할 수 있는 것이라면 본 발명의 효과를 저해하지 않는 범위 내에서 제한 없이 사용될 수 있다. 상기 향료의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 0.01 내지 5 중량% 또는 0.1 내지 3 중량%로 포함될 수 있다.In addition, the fabric softener composition (first or second fabric softener composition) according to the present invention may further use a fragrance. The fragrance may include, for example, a floral fragrance, a citrus fragrance, or the like, but may be used without limitation within a range that does not impair the effects of the present invention if it can be used as a fabric softener. The amount of the perfume is not particularly limited and may be included in 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fabric softener composition.
또한, 본 발명에 따른 섬유유연제 조성물(제 1 섬유유연제 조성물 또는 제 2 섬유유연제 조성물)은 향가용화제를 추가로 사용할 수 있으며, 향가용화제는 발효식초 등에 의한 식초취를 완화시켜 섬유유연제의 향취 만족도를 향상시킨다. 이의 함량은 특별히 제한되지 않으며, 섬유유연제 조성물 100 중량%에 대하여 0.1 내지 10 중량% 또는 1 내지 7 중량%로 포함될 수 있다.In addition, the fabric softener composition (the first fabric softener composition or the second fabric softener composition) according to the present invention may further use a fragrance solubilizer, the fragrance solubilizer to relieve odor of vinegar softening by fermentation vinegar, etc. Improve satisfaction Its content is not particularly limited and may be included in 0.1 to 10% by weight or 1 to 7% by weight relative to 100% by weight of the fabric softener composition.
또한, 본 발명에 따른 섬유유연제 조성물(제 1 섬유유연제 조성물 또는 제 2 섬유유연제 조성물)은 식초취 등의 악취제거 효과를 향상시키기 위하여 식물추출물을 추가로 포함할 수 있다. 상기 식물추출물은 감잎, 녹차 및 진피로 이루어진 그룹으로부터 선택된 하나 이상을 포함할 수 있다. In addition, the fabric softener composition (first fabric softener composition or the second fabric softener composition) according to the present invention may further include a plant extract to improve the odor removal effect such as vinegar odor. The plant extract may include one or more selected from the group consisting of persimmon leaves, green tea and dermis.
또한, 본 발명에 따른 섬유유연제 조성물(제 1 섬유유연제 조성물 또는 제 2 섬유유연제 조성물)에는 본 발명의 목적범위 내에서 소량의 첨가제가 더 포함될 수 있다. 상기 첨가제로는 항균 효과를 더욱 향상시키기 위한 항균 성분일 수 있으며, 이외에도, 색소, 방부제, 산화방지제, 소포제 등일 수 있다. 첨가제의 함량은 특별히 제한되지 않으며, 섬유유연제 조성물 100 중량%에 대하여 0.01 내지 5 중량% 또는 0.1 내지 3 중량%로 포함될 수 있다.In addition, the fabric softener composition (first fabric softener composition or the second fabric softener composition) according to the present invention may further include a small amount of additives within the scope of the present invention. The additive may be an antimicrobial component for further improving the antimicrobial effect. In addition, the additive may be a pigment, a preservative, an antioxidant, an antifoaming agent, and the like. The content of the additive is not particularly limited, and may be included in an amount of 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fabric softener composition.
또한, 본 발명의 조성물(제 1 섬유유연제 조성물 또는 제 2 섬유유연제 조성물)은 각각의 제형에 상기 기재한 성분들 이외에 일반적으로 섬유유연제에 배합되는 유분, 물, 계면활성제, 보습제, 저급알코올, 증점제, 킬레이트제, 색소, 방부제 등을 필요에 따라 적절히 배합하여 사용할 수 있다. 이의 함량은 특별히 제한되지 않으며, 섬유유연제 조성물 100 중량%에 대하여 55 내지 90 중량% 또는 60 내지 85 중량%로 포함될 수 있다.In addition, the composition (first fabric softener composition or second fabric softener composition) of the present invention is generally formulated into the fabric softener in addition to the components described above in each formulation, water, surfactant, humectant, lower alcohol, thickener. , Chelating agent, dye, preservative, etc. can be suitably blended and used as needed. The content thereof is not particularly limited, and may be included in an amount of 55 to 90 wt% or 60 to 85 wt% based on 100 wt% of the fabric softener composition.
본 발명에 따른 조성물(제 1 섬유유연제 조성물 또는 제 2 섬유유연제 조성물)은 당업계에 공지된 방법을 이용하여 분말, 과립화하여 사용할 수 있으며, 액체상태로 제조하여 사용할 수도 있다.The composition (first fabric softener composition or second fabric softener composition) according to the present invention may be used by powder, granulation using methods known in the art, and may be prepared in a liquid state.
실시예 1 ~ 6 및 비교예 1~2Examples 1-6 and Comparative Examples 1-2
하기 표 1의 조성 및 함량을 갖는 섬유유연제 조성물을 제조하였다.To prepare a fabric softener composition having the composition and content of Table 1.
먼저, 정제수에 증점용 폴리머를 넣어 완전 용해 시까지 교반한 다음 여기에 구연산, 꽃 발효식초 및 식초를 넣은 후 30분간 교반하고, 여기에 에탄올, 향료, 첨가제를 미리 용해한 용액을 투입해 30분 교반하여 제조하였다. First, add the thickening polymer to purified water and stir until complete dissolution, add citric acid, flower fermentation vinegar and vinegar to it, and stir for 30 minutes, add ethanol, fragrance and additives in advance, and stir for 30 minutes. It was prepared by.
상기 첨가제로 향가용화제(5중량%)와 소포제(0.05중량%)의 혼합을 사용하였고, 증점용 폴리머로는 아크릴코폴리머(BASF사의 Rheovis FRC)를 사용하였으며, 유기산으로 구연산을 사용하였다. A mixture of a fragrance solubilizer (5 wt%) and an antifoaming agent (0.05 wt%) was used as the additive, and an acrylic copolymer (Rheovis FRC, BASF) was used as a thickening polymer, and citric acid was used as an organic acid.
식초는 양조식초(천연식품)을 사용하였다.Vinegar was used brewed vinegar (natural food).
꽃 발효식초는 자스민 꽃잎을 수세하고 건조한 후 꽃잎 1 중량부 대비 식초 15 중량부 및 당물 15 중량부를 상기 건조된 꽃잎과 혼합하고 약 7일 동안 자연 발효 과정을 거쳐 얻은 것을 사용하였다.Flower fermented vinegar was washed with jasmine petals and dried, and then mixed with 15 parts by weight of vinegar and 15 parts by weight of the dried petals compared to 1 part by weight of the petals and was obtained through a natural fermentation process for about 7 days.
세탁의류로 KS K 0905에 규정된 백색 표준면포(10×10 cm) 3장을 사용하였고, 사용된 세탁세제는 LG 생활건강 테크를 사용하였다. Three white standard cotton cloths (10 × 10 cm) specified in KS K 0905 were used as laundry clothes, and the laundry detergent used was LG H & H Tech.
표 1
조성(중량%) 비교예 1 비교예 2 실시예 1 실시예 2 실시예 3 실시예 4 실시예 5 실시예 6
증점용 폴리머 1.5 2 0.05 0.5 0.8 1.0 1.0 1.0
구연산 20 20 20 20 20 20 20 20
향료 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
에탄올 5 5 5 5 5 5 5 5
향가용화제 5 5 5 5 5 5 5 5
소포제 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05
식초 - - - - - - - 1.0
꽃 발효식초 - - - - - - 0.5 0.5
정제수 100 중량% 까지 100 중량% 까지 100 중량% 까지 100 중량% 까지 100 중량% 까지 100 중량% 까지 100 중량% 까지 100 중량% 까지
Table 1
Composition (% by weight) Comparative Example 1 Comparative Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6
Thickening Polymer 1.5 2 0.05 0.5 0.8 1.0 1.0 1.0
Citric acid 20 20 20 20 20 20 20 20
Spices 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
ethanol 5 5 5 5 5 5 5 5
Fragrance Solubilizer 5 5 5 5 5 5 5 5
Antifoam 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05
vinegar - - - - - - - 1.0
Flower Fermented Vinegar - - - - - - 0.5 0.5
Purified water Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight
실험예 1: 세탁 후 의류 내 잔존 탄산칼슘의 농도 측정Experimental Example 1: Determination of the concentration of calcium carbonate remaining in the garment after washing
상기 제조된 실시예 및 비교예의 섬유유연제 조성물을 사용하여 세탁 후 의류내 잔존 탄산칼슘의 농도를 측정하였다. The concentration of calcium carbonate remaining in the garment after washing was measured using the fabric softener compositions of Examples and Comparative Examples.
세탁실험 조건은 한국환경산업기술원의 환경표지인증기준 중 EL306(섬유유연제) 내 시험방법에 준하며, 마지막 헹굼 시 조성물의 사용량은 0.67 mL/L였다. Washing test conditions were based on the test method in EL306 (Fiber Softener) among the environmental label certification criteria of the Korea Environmental Industry and Technology Institute. The amount of the composition was 0.67 mL / L at the last rinsing.
세탁 후 의류 내 탄산칼슘 잔류량에 대한 분석방법은 상기 세탁시험조건에서 진행된 시험포를 0.5g 분취해 염산/불산/질산/붕산의 혼합액으로 산 처리한 후, 24시간 추출해 ICP(고주파 유도 결합 플라스마)를 이용해 분석하였다. Analysis method for the residual amount of calcium carbonate in the garment after washing is 0.5g aliquots of the test cloth proceeded under the washing test conditions, acid treated with a mixture of hydrochloric acid / hydrofluoric acid / nitric acid / boric acid, and extracted for 24 hours to extract ICP (high frequency inductively coupled plasma) The analysis was carried out.
상기 의류 내 잔존 탄산칼슘 농도 측정 결과를 하기 표 2에 나타냈다. Table 2 shows the measurement results of the residual calcium carbonate concentration in the garment.
또한, 조성물의 점도는 Brookfield 회전형 점도계로 25℃, 60 rpm에서 측정하였다. In addition, the viscosity of the composition was measured at 25 degreeC and 60 rpm with the Brookfield rotary viscometer.
표 2
비교예/실시예 비교예 1 비교예 2 실시예 1 실시예 2 실시예 3 실시예 4 실시예 5 실시예 6
의류내 잔존 탄산칼슘 함량(ppm) 40 60 0 0 0 0 0 00
점도(cPs) 300 1000 5 50 150 200 200 200
TABLE 2
Comparative Example / Example Comparative Example 1 Comparative Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6
Residual calcium carbonate content in clothing (ppm) 40 60 0 0 0 0 0 00
Viscosity (cPs) 300 1000 5 50 150 200 200 200
표 2에 나타난 바와 같이, 증점용 폴리머 사용 함량에 따라 점도가 약 250 cPs를 초과하는 경우, 세탁/헹굼수 내에서 유효성분의 확산 풀림성이 떨어져 의류 내 잔존 탄산칼슘의 제거가 용이하지 않음을 알 수 있었다.As shown in Table 2, if the viscosity exceeds about 250 cPs depending on the amount of the polymer used for thickening, it is difficult to remove the remaining calcium carbonate in the garment due to the loosening of the active ingredient in the washing / rinsing water. Could know.
실시예 7 ~ 10Examples 7-10
하기 표 3의 조성 및 함량을 갖는 섬유유연제 조성물을 제조하였다. To prepare a fabric softener composition having the composition and content of Table 3.
먼저, 정제수에 양이온성 폴리머, 꽃 발효식초, 식초, 구연산을 넣고 30분간 교반한 후, 여기에 에탄올, 향료, 향가용화제 및 소포제를 용해한 용액을 투입하고 30분간 교반하여 섬유유연제 조성물을 제조하였다.First, a cationic polymer, a flower fermentation vinegar, vinegar, and citric acid were added to purified water, followed by stirring for 30 minutes, and a solution containing ethanol, a flavoring agent, a fragrance solubilizer, and an antifoaming agent was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition. .
또한, 글루코오스계 폴리머는 시중에서 구입 가능한 폴리쿼터늄[DOW Chemical사의 Polymer LR30M]을, 아크릴계 폴리머는 시중에 판매되는 아크릴코폴리머[BASF사의 Rheovis FRC]를 사용하였다.In addition, a glucose-based polymer used commercially available polyquaternium [Polymer Polymer LR30M from DOW Chemical Co., Ltd.], and an acrylic polymer used a commercially available acrylic copolymer [Rheovis FRC from BASF].
또한, 식초는 양조식초(천연식품)를 사용하였다.In addition, vinegar used brewed vinegar (natural food).
또한, 꽃 발효식초는 자스민 꽃잎을 수세하고 건조한 후, 꽃잎 1 중량부 대비 식초 15 중량부 및 당물 15 중량부를 상기 건조된 꽃잎과 혼합하고 약 7일 동안 자연 발효 과정을 거쳐 얻은 것을 사용하였다.In addition, the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.
비교예 3 Comparative Example 3
섬유유연제 조성물 대신 지표섬유유연제를 사용하였다.An indicator fiber softener was used instead of the fabric softener composition.
상기 지표섬유유연제 조성물은 한국환경산업기술원의 환경표지인증기준 중 EL306(섬유유연제) 시험방법 중 지표섬유유연제 조성물과 동일하였다.The surface fiber softener composition was the same as the surface fiber softener composition of the EL306 (fiber softener) test method of the environmental label certification criteria of the Korea Environmental Industry and Technology Institute.
비교예 4Comparative Example 4
하기 표 3의 조성 및 함량을 갖는 섬유유연제 조성물을 제조하였다. To prepare a fabric softener composition having the composition and content of Table 3.
먼저, 정제수에 양이온성 계면활성제를 넣고 30분간 교반한 후, 여기에 에탄올, 향료, 향가용화제 및 소포제를 용해한 용액을 투입하고 30분간 교반하여 섬유유연제 조성물을 제조하였다.First, a cationic surfactant was added to purified water and stirred for 30 minutes, and then a solution containing ethanol, a perfume, a solubilizer, and an antifoam was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition.
양이온성 계면활성제는 TEA Ester Quaternary(INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%)를 사용하였다.The cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).
표 3
구분(중량%) 비교예 4 실시예 7 실시예 8 실시예 9 실시예 10
양이온성 계면활성제 5 - - - -
글루코오스계 폴리머 - 0.5 - 0.5 0.5
아크릴계폴리머 - - 0.5 - -
꽃발효식초 - - - 0.5 0.5
식초 - - - - 1
에탄올 5
구연산 10
향가용화제 5
소포제 0.05
향료 0.5
정제수 100 중량% 까지
TABLE 3
Division (weight%) Comparative Example 4 Example 7 Example 8 Example 9 Example 10
Cationic surfactant 5 - - - -
Glucose-based polymer - 0.5 - 0.5 0.5
Acrylic Polymer - - 0.5 - -
Flower Fermented Vinegar - - - 0.5 0.5
vinegar - - - - One
ethanol 5
Citric acid 10
Fragrance Solubilizer 5
Antifoam 0.05
Spices 0.5
Purified water Up to 100% by weight
실험예 2: 세탁 후 잔향 강도 평가Experimental Example 2: Evaluation of Reverberation Strength After Washing
상기 제조된 실시예 및 비교예의 섬유유연제 조성물을 사용하여 세탁 후 의류 내 잔향 강도를 평가하였다. Reverberation strength in the garment was evaluated after washing using the fabric softener compositions of Examples and Comparative Examples prepared above.
세탁의류로 타올 3장을 사용하였고, 세탁세제는 LG생활건강 테크를 사용하였으며, 세탁실험 조건은 한국환경산업기술원의 환경표지인증기준 중 EL306(섬유유연제) 내 시험방법에 준하며, 마지막 헹굼 시 조성물 시료의 사용량은 0.67mL/L이고, 세탁 후 12시간 25℃, 20% 조건 항온실에서 건조하였다.Three towels were used as laundry clothes, and LG H & H was used as the laundry detergent, and the test conditions for washing were in accordance with the test method in EL306 (Fiber Softener) among the environmental label certification standards of Korea Environmental Industry and Technology Institute. The usage-amount of the sample was 0.67 mL / L, and it dried at 25 degreeC and 20% conditions constant temperature room after washing for 12 hours.
잔향 강도 평가는 전문모니터요원 10명에 대해 관능평가로 진행했으며, 1점이 가장 잔향 강도가 약하고 5점이 가장 잔향 강도가 큰 것으로 평가하였다.Reverberation intensity was evaluated by sensory evaluation for 10 professional monitors, with one point having the weakest reverberation intensity and five points having the highest reverberation intensity.
상기 의류 내 잔향 강도 평가 결과를 하기 표 4에 나타내었다. The reverberation intensity evaluation results in the garments are shown in Table 4 below.
표 4
구분 비교예 3 비교예 4 실시예 7 실시예 8 실시예 9 실시예 10
건조 후 잔향 강도(5점 척도) 2.0 3.2 3.7 3.6 3.8 3.9
Table 4
division Comparative Example 3 Comparative Example 4 Example 7 Example 8 Example 9 Example 10
Reverberation intensity after drying (5-point scale) 2.0 3.2 3.7 3.6 3.8 3.9
상기 표 4에 나타난 바와 같이, 섬유유연제 조성물에 향 캐리어 역할의 양이온성 계면활성제만 들어있고, 향이 없는 비교예 3의 지표섬유 유연제는 건조 후 향이 거의 없다.As shown in Table 4, the fiber softener composition contains only a cationic surfactant that serves as a fragrance carrier, and the indicator fiber softener of Comparative Example 3 without fragrance has almost no fragrance after drying.
일반적인 섬유유연제(비교예 4)에는 향 캐리어로 양이온 계면활성제가 사용되어 잔향 강도가 어느 정도 유지되었다. In general fabric softeners (Comparative Example 4), cationic surfactants were used as the fragrance carriers to maintain some reverberation strength.
하지만, 본 발명에 따른 실시예 7~10 조성물은 양이온성 계면활성제를 사용하지 않고 양이온성 폴리머를 사용하여도 동등 이상의 잔향 강도를 나타내어 잔향 강도가 우수함을 확인할 수 있었다.However, the compositions of Examples 7 to 10 according to the present invention showed excellent reverberation strength by exhibiting more than equivalent reverberation strength even when a cationic polymer was used without using a cationic surfactant.

Claims (18)

  1. 유기산과 증점용 폴리머를 포함하고, 회전용 점도계로 25℃, 60 rpm에서 측정된 점도가 1 내지 250 cPs인 섬유유연제 조성물.A fabric softener composition comprising an organic acid and a thickening polymer and having a viscosity of 1 to 250 cPs measured at 25 ° C. and 60 rpm with a rotating viscometer.
  2. 제1항에 있어서,The method of claim 1,
    유기산은 구연산, 초산, 주석산, 호박산, 사과산 및 젖산으로 이루어진 그룹으로부터 선택되는 하나 이상을 포함하는 섬유유연제 조성물.The organic softener composition includes at least one selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
  3. 제1항에 있어서,The method of claim 1,
    유기산은 섬유유연제 조성물 100 중량%에 대하여 5 내지 30 중량%로 포함되는 섬유유연제 조성물.An organic acid is 5 to 30% by weight relative to 100% by weight of the fabric softener composition.
  4. 제1항에 있어서,The method of claim 1,
    증점용 폴리머는 칼슘-카르복시메틸 셀룰로스, 메틸 셀룰로스/하이드록시프로필메틸셀룰로스, 하이드록시 에틸 셀룰로스, 카보폴 934(carbopol 934), 카보폴 941(carbopol 941), 잔탄검, 소듐 알기네이트, 구아검, 카라기난, 펙틴 및 아크릴계 폴리머로 이루어진 그룹으로부터 선택되는 하나 이상을 포함하는 섬유유연제 조성물.Thickening polymers include calcium-carboxymethyl cellulose, methyl cellulose / hydroxypropylmethylcellulose, hydroxy ethyl cellulose, carbopol 934, carbopol 9934, xanthan gum, sodium alginate, guar gum, A fabric softener composition comprising at least one selected from the group consisting of carrageenan, pectin and acrylic polymer.
  5. 제1항에 있어서,The method of claim 1,
    증점용 폴리머는 섬유유연제 조성물 100 중량%에 대하여 0.01 내지 1.2 중량%로 포함되는 섬유유연제 조성물.The thickener polymer is contained in 0.01 to 1.2% by weight relative to 100% by weight of the fabric softener composition.
  6. 양이온성 계면활성제를 포함하지 않는, 양이온성 폴리머; 유기산; 및 향료를 포함하는 섬유 유연제 조성물.Cationic polymers, not including cationic surfactants; Organic acid; And fragrances.
  7. 제 6 항에 있어서,The method of claim 6,
    양이온성 폴리머는 글루코오스계 폴리머 및 아크릴계 폴리머로 이루어진 군에서 선택된 하나 이상인 섬유 유연제 조성물.And the cationic polymer is at least one selected from the group consisting of glucose-based polymers and acrylic polymers.
  8. 제 7 항에 있어서,The method of claim 7, wherein
    글루코오스계 폴리머는 폴리쿼터늄, 구아, 스타치 및 로커스트빈계로 이루어진 군에서 선택된 하나 이상인 섬유 유연제 조성물.The glucose-based polymer is at least one selected from the group consisting of polyquaternium, guar, starch and locust bean.
  9. 제 7 항에 있어서,The method of claim 7, wherein
    아크릴계 폴리머는 아크릴산폴리머, 아크릴코폴리머 및 아크릴화실리콘으로 이루어진 군에서 선택된 하나 이상인 섬유 유연제 조성물.The acrylic polymer is at least one fabric softener composition selected from the group consisting of acrylic acid polymers, acrylic copolymers and acrylated silicones.
  10. 제 6 항에 있어서,The method of claim 6,
    양이온성 폴리머는 섬유 유연제 조성물 100 중량%에 대하여 0.1 내지 3 중량%로 포함되는 섬유 유연제 조성물.The cationic polymer comprises 0.1 to 3% by weight relative to 100% by weight of the fabric softener composition.
  11. 제 6 항에 있어서,The method of claim 6,
    유기산은 구연산, 초산, 주석산, 호박산, 사과산 및 젖산으로 이루어진 군에서 선택된 하나 이상인 섬유 유연제 조성물.The organic acid is at least one fabric softener composition selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
  12. 제 6 항에 있어서,The method of claim 6,
    유기산은 섬유 유연제 조성물 100 중량%에 대하여 1 내지 20 중량%로 포함되는 섬유 유연제 조성물.The organic softener composition is 1 to 20% by weight relative to 100% by weight of the fabric softener composition.
  13. 제 6 항에 있어서,The method of claim 6,
    향료는 섬유 유연제 조성물 100 중량%에 대하여 0.1 내지 3 중량%로 포함되는 섬유 유연제 조성물.Perfume is contained in 0.1 to 3% by weight relative to 100% by weight of the fabric softener composition.
  14. 제 1 항 또는 제 6 항에 있어서,The method according to claim 1 or 6,
    꽃 발효식초를 추가로 포함하는 섬유 유연제 조성물.Fabric softener composition further comprising a flower fermented vinegar.
  15. 제 14 항에 있어서,The method of claim 14,
    꽃 발효식초는 도화꽃, 살구꽃, 아카시아꽃, 카모마일꽃, 자스민꽃 및 연꽃으로 이루어진 그룹에서 선택된 하나 이상의 꽃잎을 수세 및 건조하고 식초 및 당물과 혼합하여 3일 내지 7일 동안 발효시켜 얻은 것인 섬유 유연제 조성물.Flower fermentation vinegar is obtained by washing and drying one or more petals selected from the group consisting of peach, apricot, acacia, chamomile, jasmine and lotus, fermentation for 3-7 days by mixing with vinegar and sugar Fabric softener composition.
  16. 제 14 항에 있어서,The method of claim 14,
    꽃 발효식초는 섬유 유연제 조성물 100 중량%에 대하여 0.001 내지 10 중량%로 포함되는 섬유 유연제 조성물.Flower softener vinegar is contained in 0.001 to 10% by weight relative to 100% by weight of the fabric softener composition.
  17. 제 1 항 또는 제 6 항에 있어서,The method according to claim 1 or 6,
    식초를 추가로 포함하는 섬유 유연제 조성물.A fabric softener composition further comprising vinegar.
  18. 제 17 항에 있어서,The method of claim 17,
    식초는 섬유 유연제 조성물 100 중량%에 대하여 0.1 내지 10 중량%로 포함되는 섬유 유연제 조성물.Vinegar is 0.1 to 10% by weight relative to 100% by weight of the fabric softener composition.
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