WO2015104700A2

WO2015104700A2 - Combination of novel nitrification inhibitors and insecticides and/or nematicides as well as combination of (thio)phosphoric acid triamides and insecticides and/or nematicides

Info

Publication number: WO2015104700A2
Application number: PCT/IB2015/052774
Authority: WO
Inventors: Barbara Nave; Joachim Dickhaut; Mihiret Tekeste SISAY; Alexander Wissemeier; Wolfram Zerulla; Gregor Pasda; Markus Schmid
Original assignee: Basf Se; Basf (China) Company Limited
Priority date: 2014-04-17
Filing date: 2015-04-16
Publication date: 2015-07-16
Also published as: WO2015104700A3

Abstract

A composition comprising a) at least one (thio)phosphoric acid triamide (T) according to the general formula (Ia) R^a1 R^a2 N–P(X)(NH₂)₂ (Ia) wherein X is oxygen or sulfur; R^a1 is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl, or dialkylaminocarbonyl group; R^a2 is H, or R^a1 and R^a2 together with the nitrogen atom linking them define a 5-or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur,1 and b)at least one specific insecticide and/or nematicide.

Description

Combination of novel nitrification inhibitors and insecticides and/or nematicides as well as combination of (thio)phosphoric acid triamides and insecticides and/or nematicides

Description

The present invention relates to the combination of novel nitrification inhibitors of formula I and insecticides and/or nematicides as well as to the combination of (thio)phosphoric acid tri- amide(s) and insecticides and/or nematicides. Moreover, the invention relates to the use of this combination of novel nitrification inhibitors and insecticides and/or nematicides for increasing the health of a plant, and to the use of the combination of (thio)phosphoric acid triamide(s) and insecticides and/or nematicides for increasing the health of a plant, as well as compositions comprising the nitrification inhibitor and an insecticide and/or nematicide, and compositions comprising (thio)phosphoric acid triamide(s) and an insecticide and/or nematicide. Further encompassed by the present invention are methods for increasing the health of a plant comprising the treatment of plants, soil and/or loci with said combination of the novel nitrification inhibitor or (thio)phosphoric acid triamide(s) and an insecticide and/or nematicide.

Nitrogen is an essential element for plant growth, plant health and reproduction. About 25% of the plant available nitrogen in soils (ammonium and nitrate) originate from decomposition pro- cesses (mineralization) of organic nitrogen compounds such as humus, plant and animal residues and organic fertilizers. Approximately 5% derive from rainfall. On a global basis, the biggest part (70%), however, are supplied to the plant by inorganic nitrogen fertilizers. The mainly used nitrogen fertilizers comprise ammonium compounds or derivatives thereof, i.e. nearly 90% of the nitrogen fertilizers applied worldwide is in the NH₄ ⁺ form (Subbarao et al., 2012, Advances in Agronomy, 114, 249-302). This is, inter alia, due to the fact that Nh assimilation is energetically more efficient than assimilation of other nitrogen sources such as NO3^".

Moreover, being a cation, NH₄ ⁺ is held electrostatically by the negatively charged clay surfaces and functional groups of soil organic matter. This binding is strong enough to limit NH₄ ⁺-loss by leaching to groundwater. By contrast, NO3^", being negatively charged, does not bind to the soil and is liable to be leached out of the plants' root zone. In addition, nitrate may be lost by denitri- fication which is the microbiological conversion of nitrate and nitrite (NO2 ) to gaseous forms of nitrogen such as nitrous oxide (N₂0) and molecular nitrogen (N₂). However, ammonium (N H₄ ⁺) compounds are converted by soil microorganisms to nitrates (NO3^" ) in a relatively short time in a process known as nitrification. The nitrification is carried out primarily by two groups of chemolithotrophic bacteria, ammonia-oxidizing bacteria (AOB) of the genus Nitrosomonas and Nitrobacter, which are ubiquitous component of soil bacteria populations. The enzyme, which is essentially responsible for nitrification is ammonia monooxygenase (AMO), which was also found in ammonia-oxidizing archaea (Subbarao et al., 2012, Advances in Agronomy, 114, 249-302).

The nitrification process typically leads to nitrogen leakage and environmental pollution. As a result of the various losses, approximately 50% of the applied nitrogen fertilizers is lost during the year following fertilizer addition (see Nelson and Huber; Nitrification inhibitors for corn production (2001 ), National Corn Handbook, Iowa State University).

As countermeasures the use of nitrification inhibitors, mostly together with fertilizers, was sug- gested. Suitable nitrification inhibitors include biological nitrification inhibitors (BNIs) such as linoleic acid, alpha-linolenic acid, methyl p-coumarate, methyl ferulate, MHPP, Karanjin, brachi- alacton or the p-benzoquinone sorgoleone (Subbarao et al., 2012, Advances in Agronomy, 1 14, 249-302), or are based on neem-extract, including various compounds such as neemoil-coated fertilizers, neem-coated fertilizers, nimin-coated fertilizers and fertilizers with neem cake from the Indian neem tree (Azadirachta indica). Further suitable nitrification inhibitors are synthetic chemical inhibitors such as Nitrapyrin, dicyandiamide (DCD), 3,4-dimethyl pyrazole phosphate (DMPP), 4-amino-1 ,2,4-triazole hydrochloride (ATC), 1-amido-2-thiourea (ASU), 2-amino-4- chloro-6-methylpyrimidine (AM), 5-ethoxy-3-trichloromethyl-1 ,2,4-thiodiazole (terrazole), or 2- sulfanilamidothiazole (ST) (Slangen and Kerkhoff, 1984, Fertilizer research, 5(1), 1 -76).

EP 0 917 526 further mentions the use of polyacids to treat mineral fertilizers containing a nitrification inhibitor in order to improve the fixation of the nitrification inhibitors in the inorganic fertilizer. Moreover, the volatility of the nitrification inhibitor can be reduced. However, many of these inhibitors only work sub-optimal or have undesirable side effects.

In view of this situation there is hence a continuous need for compositions that increase the health of plants. Healthier plants are desirable since they result among other in better crop yields and/or a better quality of the plants or crops. Healthier plants also better resist to biotic and abiotic stress. A better resistance to stress in turn allows reducing the quantity of pesticides, which also helps avoiding the development of resistances against the respective pesticides.

One object of the present invention is to provide a composition containing a nitrification inhibitor which increases the health of plants, and/or provides better crop yields and/or a better quality of the plants or crops, and/or shows a better resistance to stress, and/or allows the reduction of the quantity of pesticides used, and/or helps avoiding the development of resistances against the respective pesticides Another object of the present invention is to provide a composition containing the

(thio)phosphoric acid triamide(s) (T) which - each preferably through a synergistic action -

(i) enhances the stability of the (thio)phosphoric acid triamide(s), and/or

(ii) enhances the urease inhibiting effect of the (thio)phosphoric acid triamide(s), and/or

(iii) enhances the yield increase effect of the (thio)phosphoric acid triamide(s), and/or (iv) has a relatively long storage life, particularly before being applied to or coated on nitrogen- containing fertilizers, and/or

(v) reduces the emission of nitrous oxide from soils, and/or

(vi) reduces the ammonia emission from soils, particularly when applied with urea-containing fertilizer on the same locus, (vii) is toxicologically unobjectionable, and/or

(viii) does not adversely affect the urease-inhibiting effect and/or activity of the (thio)phosphoric acid triamide, and/or

(ix) can be easily and safely packaged, transported and shipped, even in large quantities, and/or

(x) can be easily and safely handled and applied for soil treatment, even in large quantities, and/or

(xi) improves the nutrient use efficiency, and/or

(xii) improves the delivery of the insecticide and/or nematicide to the plant, and/or

(xiii) improves the plant growth (e.g. biomass, yield, root branching and length; compact growth in case of ornamental plants), and/or

(xiv) enables a better developed root system, a larger leaf area, greener leaves, stronger shoots and/or

(xv) improves the plant defense of the plants, and/or

(xvi) improves the plant health of the plants, and/or

(xvii) improves the quality of the plants, and/or

(xviii) improves the storage or survivability of the insecticide and/or nematicide and/or prolong the availability of insecticides and/or nematicides to the plants, and/or

(xix) enhances the insecticidal and/or nematicidal effect of the insecticide and/or nematicide, and/or

(xx) allows the reduction of the quantity of insecticides and/or nematicides used, and/or

(xxi) increase the survivability rate of seedlings, for example transplanted seedlings, and/or

(xxii) reduce or avoid unfavorable environmental or toxicological effects whilst still allowing effective pest control, and/or

(xxiii) enable earlier seed germination and/or blooming.

The objects (xiii), (xiv), (xv), (xvi), (xvii) and (xxi) particularly pertains to such plants or seedlings wherein such plants or seedlings were, or the soil in which the such plants or seedlings were placed was subject to the application of compositon of the present invention.

The preferred objects of the present invention are (i), (ii), (v), (vi), (vii), (xi), (xii), (xiii), (xiv), (xv),

(xvi) , (xvii), (xviii), (xix), (xx), the more preferred objects of the present invention are (ii), (vi), (xii), (xiii), (xv), (xvi), (xix), and/or (xx), the most preferred objects of the present invention are (ii), (vi), (xvi), and/or (xix), the particularly preferred objects of the present invention are (xvi) and/or (xix).

The term "in a synergistic way" means that the composition comprising the (thio)phosphoric acid triamide (T) and a further compound can fulfil the one or more of the objects (i) to (xxvii) significantly better than the individual compounds - i.e. the (thio)phosphoric acid triamide (T) or said further compound - alone can do, and preferably, this better fulfilment of the objects by said composition compared to the individual compounds is evidenced by calculations according to Colby' s formula, see Colby, S. R. (Calculating synergistic and antagonistic responses of herbicide Combinations", Weeds, 15, pp. 20-22, 1967). The present invention addresses this need and relates to a combination of a novel nitrification inhibitor of formula I

or a stereoisomer, salt, tautomer or N-oxide thereof, wherein A is aryl or hetaryl, wherein the aromatic ring may in each case be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^A;

R¹ and R² are independently of each other selected from H and Ci-C₂-alkyl; and

R³ is H, Ci-C₄-haloalkyl, Ci-C₄-hydroxyalkyl, ethynylhydroxym ethyl, phenylhydroxymethyl, or aryl, wherein the aromatic ring may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^B; and wherein

R^A is

(i) halogen, CN, NR^aR^b, OR^c, SR^C, C(=Y¹)R^C, C(=Y¹)OR^c, C(=Y¹)SR^C, C(=Y¹)NR^aR^b, Y²C(=Y )R^C, Y²C(=Y )OR^c, Y²C(=Y )SR^C, Y²C(=Y¹)NR^aR , Y³Y²C(=Y )R^C, NR9N=C(R^d)(R^e), C(=N-OR^c)R9, C(=N-OR^B)Ro, C(=N-SR^C)R9, C(=N-NR^aR^b)R9, S(=0)₂R^f,

NR9S(=0)₂R^f, S(=0)₂Y²C(=Y¹)R^c, S(=0)₂Y²C(=Y¹)OR^c, S(=0)₂Y²C(=Y¹)SR^c, S(=0)₂Y²C(=Y¹)NR^aR^b, N0₂, NON-CN, Ci-C₆-alkyl, C₂-C₆-alkenyl, C₂-C₆-alkynyl, Ci-C₄- haloalkyl, Ci-C₄-cyanoalkyl, Ci-C₄-hydroxyalkyl, Ci-C₄-alkoxy, C₂-C₄-alkynyl-Ci-C₂- hydroxyalkyl, C₂-C₄-alkynyloxy;

Ci-C -alkylene-Y²- C(=Y )R^C, C₂-C₄-alkenylene-Y²-C(=Y¹)R^c, Ci-C₄-alkylene-NR^aR , C₂-C₄-alkenylene- NR^aR , Ci-C₄-alkylene-OR^c, C₂-C₄-alkenylene-OR^c, CrC₄-alkylene-SR^c, C₂-C₄- alkenylene-SR^c, wherein the Ci-C₄-alkylene or C₂-C₄-alkenylene chain may in each case be unsubstituted or may be partially or fully substituted by ORa, CN, halogen or phenyl; (iii) aryl, aryl-Ci-C2-alkyl, hetaryl or hetaryl-Ci-C₂-alkyl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^b;

(iv) a 3- to 14-membered saturated or unsaturated carbocycle or heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the carbocycle or het- erocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is H, C1-C4- alkyl, C2-C4-alkenyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, or ORa; or

(v) L-B, wherein

L is -CH2-, -CH=CH- -CHC-, -C(=0)- or -CH=, and

B is aryl or hetaryl, wherein the aromatic ring of the ary or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h;

or

a 3- to 14-membered saturated or unsaturated carbocycle or heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is H, Ci-C₄-alkyl, C₂-C₄-alkenyl, Cs-Ce-cycloalkyl, Cs-Ce-cycloalkylmethyl, or ORf; or

(vi) two substituents R^A together represent a carbocyclic or heterocyclic ring, which is fused to A and may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1c, O, and S, wherein S may be oxidized and/or where- in the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1c is H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₃-C₆-cycloalkyl, C₃-C₆- cycloalkylmethyl, C3-C6-heterocyclyl, Cs-Ce-heterocyclylmethyl or ORa; and wherein

R^B is

NH-C(=0)-(C₂-C₄-alkenyl),

alkyl), NH-C(=0)-(C₃-C₆-cycloalkyl),

or N0₂; and wherein

Y¹, Y² and Y³ are independently of each other selected from O, S and NR^1a, wherein R^1a is in each case independently H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C3-Ce-cycloalkyl, C3-C6- cycloalkylmethyl, ORa, SRa or NR^mRⁿ;

R^a and R^b are independently of each other selected from

(i) H, NRR^k, OR, SR, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, Ci-C₄-hydroxyalkyl, Ci-C₄-alkoxy, C(=Y )R, C(=Y )OR, C(=Y )SR, C(=Y¹)NRR^k, C(=Y¹)C(=Y²)R, S(=0)₂R;

(ii) aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be un- substituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h; or

R^a and R^b together with the nitrogen atom to which they are bound form

(iii) a hetaryl group which may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h; or (iv) a 3- to 10-membered, saturated or unsaturated heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R'; and wherein R^1b is H , Ci-C4-alkyl, C2-C4-alkenyl, C3-C6-cycloalkyl,

C₃-C₆-cycloalkylmethyl, or ORs;

R^c is

(i) H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, C(=0)OR', C(=0)SR', C(=0)NRR^k; (ii) Ci-C₄-alkylene-C(=0)R',

wherein the Ci-C₄-alkylene chain may in each case be unsubstituted or may be partially or fully substituted by ORa, CN, halogen, or phenyl;

(iii) aryl, aryl-Ci-C₂-alkyl, hetaryl, or hetaryl-Ci-C₂-alkyl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h; or

(iv) a 3- to 10-membered saturated or unsaturated carbocycle or heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R'; and wherein R^1b is H, C₁-C4- alkyl, C₂-C₄-alkenyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, or ORa;

R^d and R^e are independently selected from d-C₄-alkyl, Ci-C₄-haloalkyl, NRiR^k, OR¹, SR¹, CN, C(=Y¹)R', C(=Y )OR', C(=Y¹)SR', or C(=Y )NRR^k;

R^f is Ci-C₄-alkyl, Ci-C₄-haloalkyl, NRR^k, OR', SR', aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h; R9 is H or Ci-C₄-alkyl;

R^h is halogen, CN, N0₂, NRR^k, OR¹, SR¹, Ci-C -alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, C1-C4- haloalkyl, Ci-C₄-alkoxy, C₂-C₄-alkynyloxy, C(=Y¹)R, C(=Y¹)OR, C(=Y¹)SR', C(=Y¹)NRR^k, aryl, aryloxy, hetaryl and hetaryloxy;

R is

(i) halogen, CN, Ci-C₄-alkyl, C₂-C -alkenyl, C₂-C₄-alkynyl, Ci-C₄-haloalkyl, C₂-C₄- haloalkenyl;

(ii) =NR^1d, wherein R^1d is H, C C₄-alkyl, C₂-C₄-alkenyl, C₃-C₆-cycloalkyl, C₃-C₆- cycloalkylmethyl, or ORa;

(iii) =0, =S, N RiR^k, OR, SR, C(=Y¹)R, C(=Y¹)OR, C(=Y¹)SR, C(=Y¹)NRR^k;

(iv) aryl, aryl-Ci-C₂-alkyl, hetaryl, or hetaryl-Ci-C₂-alkyl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from halogen, CN, C1-C4- alkyl, C C₄-haloalkyl, CrC₄-alkoxy, C₂-C₄-alkynyloxy, ORa, and SR9; or

(v) C3-C6-cycloalkyl, or 3- to 6-membered heterocyclyl, wherein the cycloalkyl ring or the heterocyclyl ring may be unsubstituted or may be partially or fully substituted by sub- stituents, which are independently of each other selected from halogen, CN, Ci-C4-alkyl,

OR^g, and SRa; and R^k are independently selected from H, ORa, SRa, C(=Y¹)Ra, C(=Y¹)ORa, C(=Y¹)SRa, C(=Y¹)NR^mRⁿ, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C -alkynyl, Ci-C -haloalkyl, aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently selected from halogen, CN, Ci-C₄-alkyl, Ci-C -haloalkyl, Ci-C₄-alkoxy, C₂-C₄-alkynyloxy, ORa, and SRa; is H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, d-C₄-haloalkyl, C(=Y¹)Ra, C(=Y )ORa, C(=Y¹)SRa, C(=Y¹)NR^mRⁿ, aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently selected from halogen, CN, Ci-C₄-alkyl, Ci-C₄-haloalkyl, Ci-C₄-alkoxy, C₂-C -alkynyloxy, ORa, and SRa; and R^m and Rⁿ are independently selected from H and Ci-C₄-alkyl;

and a insecticide and/or nematicide.

The inventors surprisingly found that by applying the compound of formula I as defined herein above and of a insecticide and/or nematicide the nitrification of ammonium to nitrate could sig- nificantly be reduced, biotic stress could be reduced and in consequence the health of a plant could be increased.

The inventors surprisingly found that by applying the (thio)phosphoric acid triamide (T) as defined herein above and of a insecticide and/or nematicide the urease inhibiting effect of the (thio)phosphoric acid triamide(s) could be enhanced, biotic stress could be reduced and in consequence the health of a plant could be increased, also the insecticidal and/or nematicidal activity of the insecticide and/or nematicide could be enhanced, and other objects as mentioned above under the list (i) to (xxviii) could be fulfilled preferably in a synergistic way. The present invention relates in another aspect to the composition (Q) comprising a insecticide and/or nematicide and a (thio)phosphoric acid triamide according to the general formula (la)

R^a R^a2N-P(X)(NH₂)₂ (la)

wherein

X is oxygen or sulfur;

R^a1 is a Ci to C₂₀ alkyl, C3 to C₂₀ cycloalkyl, C6 to C₂₀ aryl, or dialkylaminocarbonyl group;

_Ra2 is H, or R^a1 and R^a2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur,

and the present invention preferably relates to a composition (Q) comprising a insecticide and/or nematicide and a (thio)phosphoric acid triamide according to the general formula (la) and not comprising any nitrification inhibitor of the compound of formula I.

The "(thio)phosphoric acid triamide according to the general formula (la)" is also referred to as "(thio)phosphoric acid triamide (T)" or "(T)" in the present patent application, "wt.%" refers to "percent by weight".

The composition (Q) also includes kit-of-parts comprising a insecticide and/or nematicide and (T). Here, the term "kit-of-parts" is to be understood to denote a kit comprising at least two sepa- rate parts wherein each of the parts can be independently removed from the kit. A kit includes a box, a tool, a vessel, a container, a bag or any kit-like equipment. Also a kit whose separate parts are only together in this one kit for a extremely short period of time are regarded as kit-of- parts. Kit-of-parts are useful for the combined application (of the contents) of the separate parts of the kit.

The present invention relates in another aspect to the use of a composition (Q) comprising a insecticide and/or nematicide and a (thio)phosphoric acid triamide (T) for increasing the health of a plant, and the present invention preferably relates to the use of a composition (Q) comprising a insecticide and/or nematicide and a (thio)phosphoric acid triamide (T) and not comprising any nitrification inhibitor of the compound of formula I for increasing the health of a plant.

X in the general formula (la) is preferably sulfur.

R^a1 in the general formula (la) is preferably Ci-C₂o-alkyl, more preferably Ci-Cio-alkyl, most preferably C2-C7 alkyl, for example C3-C4 alkyl. Examples of alkyl groups are methyl, ethyl, pro- pyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, pentyl, isopentyl, neopentyl, tert-pentyl, hex- yl, 2-methylpentyl, heptyl, octyl, 2-ethylhexyl, isooctyl, nonyl, isononyl, decyl and isodecyl. Examples of cycloalkyl groups are cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl and cyclooctyl, examples of aryl groups are phenyl or naphthyl. Examples of heterocyclic radicals R^a1R^a2N- are piperazinyl, morpholinyl, pyrrolyl, pyrazolyl, triazolyl, oxazolyl, thiazolyl or imidazolyl groups. According to one embodiment, the (thio)phosphoric acid triamide (T) is preferably N-n- butylthiophosphoric acid triamide (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT), more preferably NBPT. According to another embodiment, (T) is preferably NPPT. According to another embodiment, (T) is preferably LIMUS, i.e. a mixture of NBPT and NPPT with about NBPT at 63% and NPPT at 22%, secondary compounds at 10%, further secondary com- pounds such as amines below 4% and dimerease derivatives below 1 %.

According to another embodiment, the composition (Q) comprises a insecticide and/or nematicide and at least two different (thio)phosphoric acid triamides (T) having structures of the gen- g

eral formula (la) and wherein said at least two different (thio)phosphoric acid triamides differ in a of radicals R^a1 or R^a2, and preferably, one of said at least two different (thio)phosphoric acid triamides is N-n-butylthiophosphoric acid triamide (NBPT), and more preferably, the other of said at least two different (thio)phosphoric acid triamides is selected from the group consisting of N-cyclohexyl-, N-pentyl-, N-isobutyl- and N-n-propylphosphoric acid triamide and - thiophosphoric acid triamide. More preferably, (Q) comprises a insecticide and/or nematicide, N BPT and NPPT. Particularly preferably, (Q) comprises a insecticide and/or nematicide, NBPT and NPPT, wherein N BPT is present in amounts of from 1 to 99.99 wt.%, more preferably from 10 to 99.9 wt.%, most preferably from 20 to 99 wt.%, particularly preferably from 30 to 98 wt.%, more particularly preferably from 40 to 95 wt.%, most particularly preferably from 50 to 90 wt.%, especially from 60 to 85 wt.%, especially preferably from 72 to 80 wt.%, for example from 74 to 77 wt.%, in each case based on the total weight of the (thio)phosphoric acid triamides (T) contained in the composition (Q).

Generally, the (thio)phosphoric acid triamides (T) can be contained in varying amounts in the composition (Q). Preferably, the amount of (T) is not more than 95 wt.% (wt.% stands for "percent by weight"), more preferably not more than 90 wt.%, most preferably not more than 85 wt.%, more particularly preferably not more than 75 wt.%, most particularly preferably not more than 65 wt.%, particularly not more than 55 wt.%, especially not more than 45 wt.% for example not more than 35 wt.%, based on the total weight of the composition (Q). Preferably, the amount of (T) is at least 1 wt.%, more preferably at least 4 wt.%, most preferably at least 14 wt.%, more particularly preferably at least 24 wt.%, most particularly preferably at least 34 wt.%, particularly at least 44 wt.%, especially at least 54 wt.%, for example at least 64 wt.%, based on the total weight of the composition (Q).

According to another embodiment, the composition (Q) preferably does not comprise any nitrifi- cation inhibitor of the compound of formula I .

Thus, in one aspect the present invention relates to the use of combination of an insecticide and/or nematicide and a nitrification inhibitor for increasing the health of a plant, wherein said nitrification inhibitor is a compound of formula I as defined herein above. In a preferred embodiment of said use, in said compound of formula I , A is phenyl or a 5- or 6- membered hetaryl, wherein the aromatic ring may in each case be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^A. In another preferred embodiment of said use, in said compound of formula I , R¹ and R² both represent hydrogen.

In yet another preferred embodiment of said use, in said compound of formula I , R³ is hydrogen, Ci-C4-haloalkyl or ethinylhydroxymethyl, and preferably R³ is hydrogen.

In still another preferred embodiment of said use, in said compound of formula I , R^A, if present, is (i) halogen, CN, NR^aR^b, OR^c, C(=Y¹)R^C, C(=Y¹)OR^c, C(=Y¹)SR^C, C(=Y¹)N ^aR^b,

S(=0)₂R^f, N0₂, Ci-C₆-alkyl, C₂-C₆- C1-C4- haloalkyl, Ci-C4-alkoxy, C₂-C4-alkynyl-Ci-C₂-hydroxyalkyl, C₂-C4-alkynyloxy;

(ii) C₂-C₄-alkenylene-C(=Y¹)R^c, C₂-C₄-alkenylene-Y²-C(=Y¹)R^c, wherein the Ci-C₄- alkylene or C₂-C4-alkenylene chain may in each case be unsubstituted or may be partially or fully substituted by CN or halogen;

(iii) aryl, wherein the aromatic ring of the aryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h; or

(iv) a 3- to 14-membered saturated or unsaturated heterocycle, which may contain 1 ,

2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R'; and wherein R¹ is H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C3-C6-cycloalkyl, C₃-C₆-cycloalkylmethyl, or OR9.

In a further preferred embodiment of said use, the insecticide is at least one insecticide selected from the group of insecticides comprising:

(i) Organo(thio)phosphates selected from acephate (B.1.1 ), azamethiphos (B.1.2), azinphos-methyl (B.1.3), chlorpyrifos (B.1.4), chlorpyrifos-methyl (B.1.5), chlorfen- vinphos (B.1.6), diazinon (B.1 J), dichlorvos (B.1.8), dicrotophos (B.1.9), dimetho- ate (B.1.10), disulfoton (B.1.1 1), ethion (B.1.12), fenitrothion (B.1 .13), fenthion (B.1.14), isoxathion (B.1 .15), malathion (B.1.16), methamidophos (B.1.17), methi- dathion (B.1.18), methyl-parathion (B.1.19), mevinphos (B.1 .20), monocrotophos (B.1.21 ), oxydemeton-methyl (B.1.22), paraoxon (B.1.23), parathion (B.1.24), phenthoate (B.1.25), phosalone (B.1.26), phosmet (B.1.27), phosphamidon (B.1.28), phorate (B.1.29), phoxim (B.1.30), pirimiphos-methyl (B.1.31 ), profenofos (B.1.32), prothiofos (B.1.33), sulprophos (B.1.34), tetrachlorvinphos (B.1.35), ter- bufos (B.1 .36), triazophos (B.1.37), trichlorfon (B.1.38);

(ii) Carbamates selected from alanycarb (B.2.1), aldicarb (B.2.2), bendiocarb (B.2.3), benfuracarb (B.2.4), carbaryl (B.2.5), carbofuran (B.2.6), carbosulfan (B.2.7), fenoxycarb (B.2.8), furathiocarb (B.2.9), methiocarb (B.2.10), methomyl (B.2.1 1), oxamyl (B.2.12), pirimicarb (B.2.13), propoxur (B.2.14), thiodicarb (B.2.15), triazamate (B.2.16);

(iii) Pyrethroids selected from allethrin (B.3.1 ), bifenthrin (B.3.2), cyfluthrin (B.3.3), cyhalothrin (B.3.4), cyphenothrin (B.3.5), cypermethrin (B.3.6), alpha-cypermethrin (B.3.7), beta-cypermethrin (B.3.8), zeta-cypermethrin (B.3.9), deltamethrin

(B.3.10), esfenvalerate (B.3.1 1), etofenprox (B.3.11 ), fenpropathrin (B.3.12), fen- valerate (B.3.13), imiprothrin (B.3.14), lambda-cyhalothrin (B.3.15), permethrin (B.3.16), prallethrin (B.3.17), pyrethrin I and II (B.3.18), resmethrin (B.3.19), silafluofen (B.3.20), tau-fluvalinate (B.3.21 ), tefluthrin (B.3.22), tetramethrin (B.3.23), tralomethrin (B.3.24), transfluthrin (B.3.25), profluthrin (B.3.26), dimefluth- rin (B.3.27); (iv) insect growth regulators such as a) chitin synthesis inhibitors selected from benzo- ylureas: chlorfluazuron (B.4.1 ), cyramazin (B.4.2), diflubenzuron (B.4.3), flu- cycloxuron (B.4.4), flufenoxuron (B.4.5), hexaflumuron (B.4.6), lufenuron (B.4.7), novaluron (B.4.8), teflubenzuron (B.4.9), triflumuron (B.4.10); buprofezin (B.4.1 1 ), diofenolan (B.4.12), hexythiazox (B.4.13), etoxazole (B.4.14), clofentazine

(B.4.15); b) ecdysone antagonists selected from halofenozide (B.4.16), methox- yfenozide (B.4.17), tebufenozide (B.4.18), azadirachtin (B.4.19); c) juvenoids selected from pyriproxyfen (B.4.20), methoprene (B.4.21 ), fenoxycarb (B.4.22); d) lipid biosynthesis inhibitors selected from spirodiclofen (B.4.23), spiromesifen (B.4.24), spirotetramat (B.4.25);

(v) nicotinic receptor agonists/antagonists compounds selected from clothianidin

(B.5.1), dinotefuran (B.5.2), flupyradifurone (B.5.3), imidacloprid (B.5.4), thiameth- oxam (B.5.5), nitenpyram (B.5.6), acetamiprid (B.5.7), thiacloprid (B.5.8), 1 -2- chloro-thiazol-5-ylmethyl)-2-nitrimino-3,5-dimethyl-[1 ,3,5]triazinane (B.5.9);

(vi) GABA antagonist compounds selected from endosulfan (B.6.1 ), ethiprole (B.6.2), fipronil (B.6.3), vaniliprole (B.6.4), pyrafluprole (B.6.5), pyriprole (B.6.6), 5-amino-1- (2,6-dichloro-4-methyl-phenyl)-4-sulfinamoyl-1 H-pyrazole-3-carbothioic acid amide (B.6.7);

(vii) macrocyclic lactone insecticides selected from abamectin (B.7.1), emamectin

(B.7.2), milbemectin (B.7.3), lepimectin (B.7.4), spinosad (B.7.5), spinetoram

(B.7.6);

(viii) mitochondrial electron transport inhibitor (METI) I acaricides selected from fena- zaquin (B.8.1 ), pyridaben (B.8.2), tebufenpyrad (B.8.3), tolfenpyrad (B.8.4), flufen- erim (B.8.5);

(ix) METI II and III compounds selected from acequinocyl (B.9.1 ), fluacyprim (B.9.2), hydramethylnon (B.9.3);

(x) Uncouplers such as chlorfenapyr (B.10.1 );

(xi) oxidative phosphorylation inhibitors selected from cyhexatin (B.11 .1 ), diafenthiuron (B.1 1.2), fenbutatin oxide (B.1 1 .3), propargite (B.1 1.4);

(xii) moulting disruptor compounds such as cryomazine (B.12.1 );

(xiii) mixed function oxidase inhibitors such as piperonyl butoxide (B.13.1);

(xiv) sodium channel blockers selected from indoxacarb (B.14.1 ), metaflumizone

(B.14.2);

(xv) ryanodine receptor inhibitors selected from chlorantraniliprole (B.15.1), cyan- traniliprole (B.15.2), flubendiamide (B.15.3), N-[4,6-dichloro-2-[(diethyl-lambda-4- sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole- 3-carboxamide (B.15.4); N-[4-chloro-2-[(diethyl-lambda-4- sulfanylidene)carbamoyl]-6-methyl-phenyl]-2-(3-chloro-2-pyridyl)-5-(triflu- oromethyl)pyrazole-3-carboxamide (B.15.5); N-[4-chloro-2-[(di-2-propyl-lambda-4- sulfanylidene)carbamoyl]-6-methyl-phenyl]-2-(3-chloro-2-pyridyl)-5-

(trifluoromethyl)pyrazole-3-carboxamide (B.15.6); N-[4,6-dichloro-2-[(di-2-propyl- lambda-4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)- 5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.7); N-[4,6-dichloro-2-[(diethyl- lambda-4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(difluorometh- yl)pyrazole-3-carboxamide (B.15.8); N-[4,6-dibromo-2-[(di-2-propyl-lambda-4-sul- fanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole- 3-carboxamide (B.15.9); N-[4-chloro-2-[(di-2-propyl-lambda-4-sulfanylidene)carba- moyl]-6-cyano-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carbox- amide (B.15.10); N-[4,6-dibromo-2-[(diethyl-lambda-4-sulfanylidene)carbamoyl]- phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.1 1); cyazypyr (B.15.12), rynaxapyr (B.15.13);

(xvi) Other insecticides such as benclothiaz (B.16.1), bifenazate (B.16.2), artap

(B.16.3), flonicamid (B.16.4), pyridalyl (B.16.5), pymetrozine (B.16.6), sulfur (B.16.7), thiocyclam (B.16.8), cyenopyrafen (B.16.9), flupyrazofos (B.16.10), cyflumetofen (B.16.11 ), amidoflumet (B.16.12), imicyafos (B.16.13), bistrifluron (B.16.14), pyrifluquinazon (B.16.15) and

1 ,1 '-[(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-4-[[(2-cyclopropylacetyl)oxy]methyl]- 1 ,3,4,4a,5,6,6a,12,12a,12b-decahydro-12-hydroxy-4,6a,12b-trimethyl-11 -oxo-9-(3- pyridinyl)-2H,1 1 H-naphtho[2,1 -b]pyrano[3,4-e]pyran-3,6-diyl] cyclopropaneacetic acid ester (B.16.16),;

and said nematicide is at least one nematicide selected from the group of nemati- cides comprising:thiodicarb (B17.2) and abamectin (B.17.1). In a particularly preferred embodiment, said insecticide is thiodicarb (B.2.15), clothianidin (B.5.1 ), imidacloprid (B.5.4), thiamethoxam (B.5.5), thiacloprid (B.5.8), fipronil (B.6.3), cyazypyr (B.15.12), rynaxapyr (B.15.13), chlorpyrifos (B.1.4) or acephate (B.1.1 ); and said nematicide is abamectin (B.17.1). In a further preferred embodiment, said combination of a nitrification inhibitor or (T) and an insecticide and/or nematicide further comprises a fertilizer.

In a further aspect the present invention relates to a composition for increasing the health of a plant comprising at least one nitrification inhibitor as defined herein above and at least one in- secticide and/or nematicide as defined herein above.

In a further aspect the present invention relates to a composition for increasing the health of a plant comprising (T) and at least one insecticide and/or nematicide as defined herein above. In a further aspect the present invention relates to a composition for increasing the insecticidal and/or nematicidal activity of the insecticide and/or nematicide comprising (T) and at least one insecticide and/or nematicide as defined herein above.

In a preferred embodiment said agriculatural compositon additionally comprises at least one carrier.

In another aspect the present invention relates to a method for increasing the health of a plant, comprising treating a plant growing on soil or soil substituents and/or the locus or soil or soil substituents where the plant is growing or is intended to grow with a combination of at least one nitrification inhibitor and at least one insecticide and/or nematicide as defined herein above, or a composition as defined herein above.

In a preferred embodiment of the method the plant and/or the locus or soil or soil substituents where the plant is growing or is intended to grow is additionally provided with a fertilizer.

In a further preferred embodiment of the method, the application of said nitrification inhibitor (A) and of said insecticide and/or nematicide (B), and optionally of said fertilizer (C) is carried out simultaneously or with a time lag.

In a further preferred embodiment of the method, the application of (T) and of said insecticide and/or nematicide (B), and optionally of said fertilizer (C) is carried out simultaneously or with a time lag. In a particularly preferred embodiment, said time lag is an interval of 1 day, 2 days, 3 days, 1 week, 2 weeks or 3 weeks.

In a further preferred embodiment of a use, composition or method of the invention as mentioned herein above, said increase of the health of a plant is reflected by an increase in growth of root and shoot, an overall increase in productivity and/or a faster and more efficient development of the plant.

In a further preferred embodiment of the use, composition or method of the invention as mentioned herein above, said plant is an agricultural plant such as wheat, barley, oat, rye, soybean, corn, oilseed rape, canola, sunflower, cotton, sugar cane, sugar beet, rice or a vegetable such as spinach, lettuce, asparagus, or cabbages; or sorghum; a silvicultural plant; an ornamental plant; or a horticultural plant, each in its natural or in a genetically modified form.

In addition, a process for treating the soil comprising applying the compositions of the invention into the soil in-furrow and/or as side dress and/or as broadcast was found.

The present invention relates in one aspect to the use of an insecticide and/or nematicide and a nitrification inhibitor for increasing the health of a plant, wherein said nitrification inhibitor is a compound of formula I as defined herein.

The present invention relates in another aspect to the use of an insecticide and/or nematicide (T) for increasing the health of a plant. The present invention relates in another aspect to the use of an insecticide and/or nematicide (T) for increasing the insecticidal and/or nematicidal activity of the insecticide and/or nematicide.

Although the present invention will be described with respect to particular embodiments, this description is not to be construed in a limiting sense. Before describing in detail exemplary embodiments of the present invention, definitions important for understanding the present invention are given. As used in this specification and in the appended claims, the singular forms of "a" and "an" also include the respective plurals unless the context clearly dictates otherwise. In the context of the present invention, the terms "about" and "approximately" denote an interval of accuracy that a person skilled in the art will understand to still ensure the technical effect of the feature in question. The term typically indicates a deviation from the indicated numerical value of ±20 %, preferably ±15 %, more preferably ±10 %, and even more preferably ±5 %. It is to be understood that the term "comprising" is not limiting. For the purposes of the present invention the term "consisting of is considered to be a preferred embodiment of the term "comprising of. If hereinafter a group is defined to comprise at least a certain number of embodiments, this is meant to also encompass a group which preferably consists of these embodiments only. Furthermore, the terms "first", "second", "third" or "(a)", "(b)", "(c)", "(d)" etc. and the like in the description and in the claims, are used for distinguishing between similar elements and not necessarily for describing a sequential or chronolog- ical order. It is to be understood that the terms so used are interchangeable under appropriate circumstances and that the embodiments of the invention described herein are capable of operation in other sequences than described or illustrated herein. In case the terms "first", "second", "third" or "(a)", "(b)", "(c)", "(d)", "i", "ii" etc. relate to steps of a method or use or assay there is no time or time interval coherence between the steps, i.e. the steps may be carried out simulta- neously or there may be time intervals of seconds, minutes, hours, days, weeks, months or even years between such steps, unless otherwise indicated in the application as set forth herein above or below. It is to be understood that this invention is not limited to the particular methodology, protocols, reagents etc. described herein as these may vary. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to limit the scope of the present invention that will be limited only by the appended claims. Unless defined otherwise, all technical and scientific terms used herein have the same meanings as commonly understood by one of ordinary skill in the art.

The term "nitrification inhibitor" is to be understood in this context as a chemical substance which slows down or stops the nitrification process. Nitrification inhibitors accordingly retard the natural transformation of ammonium into nitrate, by inhibiting the activity of bacteria such as Nitrosomonas spp.The term "nitrification" as used herein is to be understood as the biological oxidation of ammonia (N H3) or ammonium (NH₄ ⁺) with oxygen into nitrite (N0₂ ) followed by the oxidation of these nitrites into nitrates (NO3 ) by microorganisms. Besides nitrate (NO3 ) nitrous oxide is also produced though nitrification. Nitrification is an important step in the nitrogen cycle in soil. The inhibition of nitrification may thus also reduce N0₂ losses.

The term "compound(s) according to the invention", or "compounds of formula I" comprises the compound(s) as defined herein as well as a stereoisomer, salt, tautomer or N-oxide thereof. The term "compound(s) of the present invention" is to be understood as equivalent to the term "compound(s) according to the invention", therefore also comprising a stereoisomer, salt, tautomer or N-oxide thereof.

The compounds of formula I may be amorphous or may exist in one or more different crystalline states (polymorphs) which may have different macroscopic properties such as stability or show different biological properties such as activities. The present invention relates to amorphous and crystalline compounds of formula I, mixtures of different crystalline states of the respective compound I, as well as amorphous or crystalline salts thereof.

Salts of the compounds of the formula I are preferably agriculturally acceptable salts. They can be formed in a customary manner, e.g. by reacting the compound with an acid of the anion in question if the compound of formula I has a basic functionality. Agriculturally useful salts of the compounds of formula I encompass especially the acid addition salts of those acids whose cati- ons and anions, respectively, have no adverse effect on the mode of action of the compounds of formula I. Anions of useful acid addition salts are primarily chloride, bromide, fluoride, hydro- gensulfate, sulfate, dihydrogenphosphate, hydrogenphosphate, phosphate, nitrate, bicarbonate, carbonate, hexafluorosilicate, hexafluorophosphate, benzoate, and the anions of Ci-C₄-alkanoic acids, preferably formate, acetate, propionate and butyrate. They can be formed by reacting compounds of formula I with an acid of the corresponding anion, preferably of hydrochloric acid, hydrobromic acid, sulfuric acid, phosphoric acid or nitric acid.

The term "N-oxide" includes any compound of formula I which has at least one tertiary nitrogen atom that is oxidized to an N-oxide moiety.

The organic moieties mentioned in the above definitions of the variables are - like the term halogen - collective terms for individual listings of the individual group members. The prefix C_n-C_m indicates in each case the possible number of carbon atoms in the group. The term "halogen" denotes in each case fluorine, bromine, chlorine or iodine, in particular fluorine, chlorine or bromine.

The term "alkyl" as used herein denotes in each case a straight-chain or branched alkyl group having usually from 1 to 10 carbon atoms, frequently from 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms, more preferably from 1 to 3 carbon atoms. Examples of an alkyl group are methyl, ethyl, n-propyl, iso-propyl, n-butyl, 2-butyl, iso-butyl, tert-butyl, n-pentyl, 1 -methylbutyl, 2-methylbutyl, 3-methylbutyl, 2, 2-di methyl propyl, 1 -ethyl propyl, n-hexyl, 1 ,1 -dimethylpropyl, 1 ,2- di methyl propyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1 ,1 -dimethyl- butyl, 1 ,2-dimethylbutyl, 1 ,3-dimethylbutyl, 2, 2-di methyl butyl, 2,3-dimethylbutyl, 3,3-dimethyl- butyl, 1-ethylbutyl, 2-ethylbutyl, 1 ,1 ,2-trimethylpropyl, 1 ,2,2-trimethylpropyl, 1-ethyl-1 -methyl- propyl, and 1-ethyl-2-methylpropyl.

The term "haloalkyl" as used herein denotes in each case a straight-chain or branched alkyl group having usually from 1 to 10 carbon atoms, frequently from 1 to 6 carbon atoms, preferably from 1 to 4 carbon atoms, wherein the hydrogen atoms of this group are partially or totally replaced with halogen atoms. Preferred haloalkyl moieties are selected from Ci-C₄-haloalkyl, more preferably from Ci-C3-haloalkyl or Ci-C2-haloalkyl, in particular from Ci-C2-fluoroalkyl such as fluoromethyl, difluoromethyl, trifluoromethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, pentafluoroethyl, and the like. The term "cyanoalkyl" as used herein denotes in each case a straight-chain or branched alkyl group having usually from 1 to 10 carbon atoms, frequently from 1 to 6 carbon atoms, preferably from 1 to 4 carbon atoms, wherein the hydrogen atoms of this group are partially or totally re- placed with cyano groups. Preferred cyanoalkyl moieties are selected from Ci-C4-cyanoalkyl, more preferably from Ci-C3-cyanooalkyl or Ci-C₂-cyanoalkyl.

The term "hydroxyalkyl" as used herein denotes in each case a straight-chain or branched alkyl group having usually from 1 to 10 carbon atoms, frequently from 1 to 6 carbon atoms, preferably from 1 to 4 carbon atoms, wherein the hydrogen atoms of this group are partially or totally replaced with hydroxy groups. Preferred hydroxyalkyl moieties are selected from Ci-C₄-hydroxy- alkyl, more preferably from Ci-C-hydroxyalkyl or Ci-C2-hydroxyalkyl. Preferred hydroxyalkyl moieties are selected from hydroxy methyl, dihydroxymethyl, trihydroxymethyl,1 -hydroxyethyl and 2-hydroxyethyl.

The term "ethynylhydroxymethyl" as used herein refers to the following substituent.

The term "phenylhydroxymethyl" as used herein refers to the following substituent.

The term "alkoxy" as used herein denotes in each case a straight-chain or branched alkyl group which is bound via an oxygen atom and has usually from 1 to 10 carbon atoms, frequently from 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms. Examples of an alkoxy group are methoxy, ethoxy, n-propoxy, iso-propoxy, n-butyloxy, 2-butyloxy, iso-butyloxy, tert-butyloxy, and the like. The term "alkoxyalkyl" as used herein refers to alkyl usually comprising 1 to 10, frequently 1 to 4, preferably 1 to 2 carbon atoms, wherein 1 carbon atom carries an alkoxy radical usually comprising 1 to 4, preferably 1 or 2 carbon atoms as defined above. Examples are CH2OCH3, CH2-OC2H5, 2-(methoxy)ethyl, and 2-(ethoxy)ethyl. The term "alkylene" as used herein and in the moieties of e.g.

C1-C4- alkylene-C(=Y¹)OR^c, d-C₄-alkylene-C(=Y¹)SR^c, C C₄-alkylene-C(=Y¹)NR^aNR^b, C C₄-alkylene- Y²-C(=Y¹)R^C, Ci-C₄-alkylene-NR^aR^b, Ci-C₄-alkylene-OR^c, and Ci-C₄-alkylene-S ^c refers to a straight-chain or branched alkylene group having usually from 1 to 10 carbon atoms, frequently from 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms, more preferably from 1 to 3 carbon atoms. Preferably, said alkenylene group connects a substituent, such as C(=Y¹)R^C, C(=Y¹)OR^c, C(=Y¹)SR^C, C(=Y¹)NR^aNR^b, Y²-C(=Y )R^C, NR^aR^b, OR^c,SR^c, with the remainder of the molecule.

The term "alkenyl" as used herein denotes in each case an at least singly unsaturated hydrocarbon radical, i.e. a hydrocarbon radical having at least one carbon-carbon double bond, hav- ing usually 2 to 10, frequently 2 to 6, preferably 2 to 4 carbon atoms, e.g. vinyl, allyl (2-propen- 1-yl), 1 -propen-1 -yl, 2-propen-2-yl, methallyl (2-methylprop-2-en-1 -yl), 2-buten-1 -yl, 3-buten-1- yl, 2-penten-1 -yl, 3-penten-1 -yl, 4-penten-1-yl, 1-methylbut-2-en-1-yl, 2-ethylprop-2-en-1-yl and the like.

The term "haloalkenyl" as used herein refers to an alkenyl group as defined above, wherein the hydrogen atoms are partially or totally replaced with halogen atoms.

The term "alkenylene" as used herein and in the moieties of e.g. C2-C₄-alkenylene-C(=Y¹)R^c, C₂-C₄-alkenylene-C(=Y¹)OR^c, C₂-C -alkenylene-C(=Y )SR^c, C₂-C₄-alkenylene-C(=Y¹)NR^aNR^b, C₂-C₄-alkenylene-Y²-C(=Y¹)R^c, C₂-C₄-alkenylene-NR^aR^b, C₂-C₄-alkenylene-OR^c, and C₂-C₄- alkenylene-SR^c refers to a straight-chain or branched alkenylene group, which is at least singly unsaturated, and has usually from 2 to 10 carbon atoms, frequently from 2 to 6 carbon atoms, preferably 2 to 4 carbon atoms, more preferably from 2 to 3 carbon atoms. Preferably, said alkenylene group connects a substituent, such as C(=Y¹)R^C, C(=Y¹)OR^c, C(=Y¹)SR^C,

C(=Y¹)NR^aNR^b, Y²-C(=Y¹)R^C, N R^aR^b, OR^c,SR^c, with the remainder of the molecule.

The term "alkynyl" as used herein denotes in each case a hydrocarbon radical having at least one carbon-carbon triple bond and having usually 2 to 10, frequently 2 to 6, preferably 2 to 4 carbon atoms, e.g. ethynyl, propargyl (2-propyn-1-yl), 1 -propyn-1 -yl, 1 -methylprop-2-yn-1 -yl), 2- butyn-1 -yl, 3-butyn-1 -yl, 1 -pentyn-1 -yl, 3-pentyn-1-yl, 4-pentyn-1 -yl, 1 -methylbut-2-yn-1 -yl, 1 - ethyl prop-2-yn-1 -yl and the like.

The term "haloalkynyl" as used herein refers to an alkynyl group as defined above, wherein the hydrogen atoms are partially or totally replaced with halogen atoms. The term "alkynylalkyl" as used herein refers to alkyl usually comprising 1 to 10, frequently 1 to 4, preferably 1 to 2 carbon atoms, wherein 1 carbon atom carries an alkynyl radical usually comprising 2 to 4, preferably 2 or 3 carbon atoms as defined above.

The term "alkynylhydroxyalkyi" as used herein refers to an hydroxyalkyi as defined above usual- ly comprising 1 to 10, frequently 1 to 4, preferably 1 to 2 carbon atoms, wherein 1 carbon atom carries an alkynyl radical usually comprising 2 to 4, preferably 2 or 3 carbon atoms as defined above. An exemplary alkynylhydroxyalkyi is ethynyl hydroxy methyl.

The term "alkynyloxy" as used herein denotes in each case an alkynyl group which is bound to the remainder of the molecule via an oxygen atom and has usually from 2 to 6 carbon atoms, frequently from 2 to 4 carbon atoms, preferably 2 to 3 carbon atoms.

The term "cycloalkyl" as used herein and in the cycloalkyl moieties of cycloalkoxy and cycloal- kylmethyl denotes in each case a monocyclic cycloaliphatic radical having usually from 3 to 10 or from 3 to 6 carbon atoms, such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohep- tyl, cyclooctyl, cyclononyl and cyclodecyl or cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl. The term "cycloalkylalkyl" refers to a cycloalkyl group as defined above which is bound via an alkyl group, such as a CrC₅-alkyl group or a CrC₄-alkyl group, in particular a methyl group (= cycloalkylmethyl), to the remainder of the molecule. The term "cycloalkenyl" as used herein denotes in each case a monocyclic singly unsaturated non-aromatic radical having usually from 5 to 10 or from 3 to 8 carbon atoms, including e.g. cy- cloheptenyl or cyclooctenyl.

The term "heterocyclyl" or "heterocycle" includes in general 3- to 14-membered, preferably 3- to 10-membered, more preferably 5-, or 6-membered non-aromatic radicals with at least one het- eroatom. The term "heterocyclyl" or "heterocycle" refers to monocyclic, bicyclic or tricyclic heterocyclic non-aromatic radicals. The term "heterocyclyl" or "heterocycle" also includes bicyclic or tricyclic radicals, which comprise a non-aromatic ring and a fused aryl or hetaryl ring. Particularly preferred are 5- and 6-membered monocyclic heterocyclic non-aromatic radicals. The het- erocyclic radicals usually comprise 1 , 2, 3, 4 or 5, preferably 1 , 2 or 3 heteroatoms selected from N, O and S as ring members, where S-atoms as ring members may be present as S, SO or SO2. Examples of 5- or 6-membered heterocyclic radicals comprise saturated or unsaturated, non-aromatic heterocyclic rings, such as oxiranyl, oxetanyl, thietanyl, thietanyl-S-oxid (S- oxothietanyl), thietanyl-S-dioxid (S-dioxothiethanyl), pyrrolidinyl, pyrrolinyl, pyrazolinyl, tetrahy- drofuranyl, dihydrofuranyl, 1 ,3-dioxolanyl, thiolanyl, S-oxothiolanyl, S-dioxothiolanyl, dihy- drothienyl, S-oxodihydrothienyl, S-dioxodihydrothienyl, oxazolidinyl, oxazolinyl, thiazolinyl, ox- athiolanyl, piperidinyl, piperazinyl, pyranyl, dihydropyranyl, tetrahydropyranyl, 1 ,3- and 1 ,4- dioxanyl, thiopyranyl, S.oxothiopyranyl, S-dioxothiopyranyl, dihydrothiopyranyl, S- oxodihydrothiopyranyl, S-dioxodihydrothiopyranyl, tetrahydrothiopyranyl, S-oxotetra- hydrothiopyranyl, S-dioxotetrahydrothiopyranyl, morpholinyl, thiomorpholinyl, S-oxothiomorpho- linyl, S-dioxothiomorpholinyl, thiazinyl and the like. Examples for heterocyclic rings also comprising 1 or 2 carbonyl groups as ring members comprise pyrrolidin-2-onyl, pyrrolidin-2,5-dionyl, imidazolidin-2-onyl, oxazolidin-2-onyl, thiazolidin-2-onyl and the like. Particularly preferred are also bicyclic 8- to 10-membered heterocyclic radicals comprising as ring members 1 , 2, 3, 4 or 5, preferably 1 , 2 or 3 heteroatoms selected from N, O and S members, where S-atoms as ring members may be present as S, SO or S0₂. Preferably, said bicyclic 8- to 10-membered heterocyclic radicals comprise a 5- or 6-membered non-aromatic ring as defined above, which is fused to an aryl or hetaryl ring or to another heterocyclic ring. These fused heterocyclyl radicals may be bound to the remainder of the molecule via any ring atom of the 5- or 6-membered ring or the fused ring.

The term "heterocyclylalkyl" refers to heterocyclyl as defined above, which is bound via a C1-C5- alkyl group or a Ci-C₄-alkyl group, in particular a methyl group (= heterocyclylmethyl), to the remainder of the molecule.

The term "carbocyclyl" or "carbocycle" includes in general 3- to 14-membered, preferably 3- to 10-membered, more preferably 5- or 6-membered non-aromatic radicals. The term "carbocyclyl" or "carbocycle" may refer to monocyclic, bicyclic or tricyclic carbocyclic non-aromatic radicals. Preferred carbocycles are cycloalkyl and cycloalkenyl groups having from 3 to 10, preferably 5 or 6 carbon atoms.

Particularly preferred are also bicyclic 8- to 10-membered carbocyclic radicals, wherein a 5- or 6-membered non-aromatic ring is fused to an aryl ring or another carbocyclic ring. These fused carbocyclyl radicals may be bonded to the remainder of the molecule via any ring atom of the 5- or 6-membered ring or the fused ring.

The term "carbocyclylalkyl" refers to carbocyclyl as defined above which is bound via a CrC₅- alkyl group or a Ci-C4-alkyl group, in particular a methyl group (= carbocyclylmethyl), to the remainder of the molecule.

The term "hetaryl" includes monocyclic 5- or 6-membered heteroaromatic radicals comprising as ring members 1 , 2, 3 or 4 heteroatoms selected from N, O and S. Examples of 5- or 6-membered heteroaromatic radicals include pyridyl, i.e. 2-, 3-, or 4-pyridyl, pyrimidinyl, i.e. 2-, 4- or 5-pyrimidinyl, pyrazinyl, pyridazinyl, i.e. 3- or 4-pyridazinyl, thienyl, i.e. 2- or 3-thienyl, furyl, i.e. 2-or 3-furyl, pyrrolyl, i.e. 2- or 3-pyrrolyl, oxazolyl, i.e. 2-, 3- or 5-oxazolyl, isoxazolyl, i.e. 3-, 4- or 5-isoxazolyl, thiazolyl, i.e. 2-, 3- or 5-thiazolyl, isothiazolyl, i.e. 3-, 4- or

5-isothiazolyl, pyrazolyl, i.e. 1 -, 3-, 4- or 5-pyrazolyl, i.e. 1 -, 2-, 4- or 5-imidazolyl, oxadiazolyl, e.g. 2- or 5-[1 ,3,4]oxadiazolyl, 4- or 5-(1 ,2,3-oxadiazol)yl, 3- or 5-(1 ,2,4-oxadiazol)yl, 2- or 5-(1 ,3,4-thiadiazol)yl, thiadiazolyl, e.g. 2- or 5-(1 ,3,4-thiadiazol)yl, 4- or 5-(1 ,2,3-thiadiazol)yl, 3- or 5-(1 ,2,4-thiadiazol)yl, triazolyl, e.g. 1 H-, 2H- or 3H-1 ,2,3-triazol-4-yl, 2H-triazol-3-yl, 1 H-, 2H-, or 4H-1 ,2,4-triazolyl and tetrazolyl, i.e. 1 H- or 2H-tetrazolyl. The term "hetaryl" also includes bicyclic 8 to 13-membered, preferably 8- to 10 membered heteroaromatic radicals comprising as ring members 1 , 2 or 3 heteroatoms selected from N, O and S, wherein a 5- or 6-membered heteroaromatic ring is fused to a phenyl ring or to a 5- or 6-membered heteroaromatic radical. Examples of a 5- or 6-membered heteroaromatic ring fused to a phenyl ring or to a 5- or 6- membered heteroaromatic radical include benzofuranyl, benzothienyl, indolyl, indazolyl, ben- zimidazolyl, benzoxathiazolyl, benzoxadiazolyl, benzothiadiazolyl, benzoxazinyl, chinolinyl, iso- chinolinyl, purinyl, 1 ,8-naphthyridyl, pteridyl, pyrido[3,2-d]pyrimidyl or pyridoimidazolyl and the like. These fused hetaryl radicals may be bonded to the remainder of the molecule via any ring atom of 5- or 6-membered heteroaromatic ring or via a carbon atom of the fused phenyl moiety.

The term "hetarylalkyi" refers to hetaryl as defined above which is bound via a Ci-Cs-alkyl group or a Ci-C₄-alkyl group, in particular a methyl group (= hetarylmethyl), to the remainder of the molecule.

The term "heteraryloxy" refers to heteraryl as defined above, which is bound via an oxygen atom to the remainder of the molecule.

The term "aryl" includes monocyclic, bicyclic or tricyclic aromatic radicals comprising 6 to 14 carbon atoms, preferably 6 or 10 carbon atoms, more preferably 6 carbon atoms. Exemplary aryl radicals include anthracenyl, naphthalenyl and phenyl. A preferred aryl radical is phenyl. The term "arylalkyl" refers to aryl as defined above which is bound via a Ci-C₅-alkyl group or a CrC₄-alkyl group, in particular a methyl group (=arylmethyl), to the remainder of the molecule. A preferred arylalkyl group is phenylmethyl, i.e. benzyl. The term "aryloxy" refers to aryl as defined above, which is bound via an oxygen atom to the remainder of the molecule. A preferred aryloxy group is e.g. benzyloxy.

As has been set out above, the present invention concerns in one aspect the use of a nitrification inhibitor for reducing nitrification, wherein said nitrification inhibitor is a compound of formu- la I

or a stereoisomer, salt, tautomer or N-oxide thereof, wherein

A is aryl or hetaryl, wherein the aromatic ring may in each case be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other se- lected from R^A;

R¹ and R² are independently of each other selected from H and CrC₂-alkyl; and

R³ is H , Ci-C₄-haloalkyl, Ci-C₄-hydroxyalkyl, ethynylhydroxym ethyl, phenylhydroxymethyl, or aryl, wherein the aromatic ring may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^B; and wherein R^A is

(i) halogen, CN , N R^aR^b, OR^c, SR^C, C(=Y¹)R^C, C(=Y¹)OR^c, C(=Y¹)SR^C, C(=Y¹)N R^aR , Y²C(=Y¹)R^C, Y²C(=Y¹)OR^c, Y²C(=Y¹)SR^C, Y²C(=Y¹)N R^aR^b, Y³Y²C(=Y¹)R^C, N R9N=C(R^d)(R^e), C(=N-OR^c)R9, C(=N-OR^c)R9, C(=N-SR^C)R9, C(=N-N R^aR^b)Ra, S(=0)₂R^f, N RaS(=0)₂R^f, S(=0)₂Y²C(=Y )R^c, S(=0)₂Y²C(=Y )OR^c, S(=0)₂Y C(=Y )SR^c, S(=0)₂Y²C(=Y )N R^aR , N0₂, NON-CN, Ci-C₆-alkyl, C₂-C₆-alkenyl, C₂-C₆-alkynyl, C1-C4- haloalkyl, Ci-C₄-cyanoalkyl, Ci-C₄-hydroxyalkyl, Ci-C -alkoxy, C₂-C₄-alkynyl-Ci-C₂- hydroxyalkyl, C₂-C₄-alkynyloxy;

R^aN R , Ci-C -alkylene-Y²-

C(=Y¹)R^C, C₂-C₄-alkenylene-Y²-C(=Y¹)R^c, Ci-C₄-alkylene-N R^aR , C₂-C₄-alkenylene- N R^aR^b, Ci-C₄-alkylene-OR^c, C₂-C₄-alkenylene-OR^c, Ci-C₄-alkylene-SR^c, C₂-C₄- alkenylene-SR^c, wherein the Ci-C₄-alkylene or C₂-C₄-alkenylene chain may in each case be unsubstituted or may be partially or fully substituted by ORa, CN, halogen or phenyl;

(iii) aryl, aryl-Ci-C₂-alkyl, hetaryl or hetaryl-Ci-C₂-alkyl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by sub- stituents, which are independently of each other selected from R^h;

(iv) a 3- to 14-membered saturated or unsaturated carbocycle or heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is H , Ci-C₄- alkyl, C₂-C₄-alkenyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, or ORa; or

(v) L-B, wherein

L is -CH2-, -CH=CH-, -C≡C-, -C(=0)- or -CH= and

B is aryl or hetaryl, wherein the aromatic ring of the ary or hetaryl group may be un- substituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h;

or

a 3- to 14-membered saturated or unsaturated carbocycle or heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are select- ed from NR^1b, O, and S, wherein S may be oxidized and/or wherein the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is H , Ci-C₄-alkyl, C₂-C₄-alkenyl, C3-Ce-cycloalkyl, C3-C6-cycloalkylmethyl, or ORa; or

(vi) two substituents R^A together represent a carbocyclic or heterocyclic ring, which is fused to A and may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1c, O, and S, wherein S may be oxidized and/or wherein the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1c is H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₃-C₆-cycloalkyl, C₃-C₆- cycloalkylmethyl, C3-Ce-heterocyclyl, C3-C6-heterocyclylmethyl or ORa; and wherein R^B is

NH-C(=0)-(C₂-C₄-alkenyl),

alkyl), NH-C(=0)-(C₃-C₆-cycloalkyl),

or N0₂; and wherein Y¹, Y² and Y³ are independently of each other selected from O, S and NR^1a, wherein R^1a is in each case independently H, Ci-C -alkyl, C₂-C₄-alkenyl, C3-C6-cycloalkyl, C3-C6- cycloalkylmethyl, ORa, SRa or NR^mRⁿ;

R^a and R^b are independently of each other selected from (i) H, NRiR^k, OR¹, SR, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, Ci-C₄-hydroxyalkyl, CrC₄-alkoxy, C(=Y )R, C(=Y )OR, C(=Y )SR, C(=Y¹)NRR^k, C(=Y¹)C(=Y²)R, S(=0)₂R^f;

(ii) aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are inde- pendently of each other selected from R^h; or

R^a and R^b together with the nitrogen atom to which they are bound form

(iii) a hetaryl group which may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h; or

(iv) a 3- to 10-membered, saturated or unsaturated heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and

S, wherein S may be oxidized and/or wherein the heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is H , Ci-C₄-alkyl, C₂-C₄-alkenyl, C3-C6-cycloalkyl, C₃-C₆-cycloalkylmethyl, or ORa;

R^c is

(i) H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, C(=0)OR, C(=0)SR, C(=0)NRR^k;

(ii)

wherein the Ci-C -alkylene chain may in each case be unsubstituted or may be partially or fully substituted by ORa, CN, halogen, or phenyl;

(iv) a 3- to 10-membered saturated or unsaturated carbocycle or heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is H , Ci-C₄- alkyl, C₂-C₄-alkenyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, or ORa;

R^e are independently selected from d-C₄-alkyl, Ci-C₄-haloalkyl, NRR^k, OR, SR, CN, C(=Y )R, C(=Y¹)OR, C(=Y )SR, or C(=Y )NRR^k;

R^f is CrC₄-alkyl, Ci-C₄-haloalkyl, NRR^k, OR', SR', aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h;

Ra is H or Ci-C -alkyl; R^h is halogen, CN, N0₂, NRR^k, OR, SR, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, C₁-C4- haloalkyl, Ci-C₄-alkoxy, C₂-C₄-alkynyloxy, C(=Y¹)R, C(=Y¹)OR, C(=Y¹)SR, C(=Y¹)NRR^k, aryl, aryloxy, hetaryl and hetaryloxy;

R is (i) halogen, CN, d-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, Ci-C₄-haloalkyl, C₂-C₄- haloalkenyl ;

(ii) =NR^1d, wherein R^1d is H, Ci-C -alkyl, C₂-C₄-alkenyl, C₃-C₆-cycloalkyl, C₃-C₆- cycloalkylmethyl, or ORa;

(iii) =0, =S, N RiR^k, OR', SR', C(=Y¹)R', C(=Y¹)OR, C(=Y¹)SR', C(=Y )NRR^k;

(iv) aryl, aryl-Ci-C₂-alkyl, hetaryl, or hetaryl-Ci-C₂-alkyl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from halogen, CN, C1-C4- alkyl, Ci-C₄-haloalkyl, Ci-C₄-alkoxy, C₂-C₄-alkynyloxy, ORa, and SRs; or

(v) C3-C6-cycloalkyl , or 3- to 6-membered heterocyclyl , wherein the cycloalkyl ring or the heterocyclyl ring may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from halogen, CN, Ci-C₄-alkyl, ORa, and SRa; Ri and R^k are independently selected from H, ORa, SRs, C(=Y¹)Ra, C(=Y¹)ORa, C(=Y¹)SRa, C(=Y¹)NR^mRⁿ, Ci-C₄-alkyl , C₂-C₄-alkenyl, C₂-C₄-alkynyl, Ci-C₄-haloalkyl, aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently selected from halogen, CN, Ci-C₄-alkyl, Ci-C₄-haloalkyl , Ci-C₄-alkoxy, C₂-C₄-alkynyloxy, ORa, and SRa;

R' is H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, Ci-C₄-haloalkyl, C(=Y¹)Ra, C(=Y¹)ORa, C(=Y¹)SRa, C(=Y¹)NR^mRⁿ, aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently selected from halogen, CN, Ci-C -alkyl , Ci-C -haloalkyl, Ci-C -alkoxy, C₂-C₄-alkynyloxy, ORa, and SRa; and

R^m and Rⁿ are independently selected from H and Ci-C₄-alkyl.

I n a preferred embodiment of said compound of formula I , A is phenyl or a 5- or 6-membered hetaryl , wherein the aromatic ring may in each case be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^A. These compounds correspond to compounds of formula 1.1 , wherein A' represents phenyl or a 5- or 6- membered hetaryl, wherein the aromatic ring may in each case be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^A.

I n a further preferred embodiment of said compound of formula I , R¹ and R² both represent hydrogen. These compounds corresp ds of formula I . A.

I . A In another preferred embodiment of said compound of formula I, R³ is hydrogen, Ci-C₄-haloalkyl or ethynylhydroxymethyl. It is even more preferred that R³ is hydrogen. These compounds correspond to compounds of formula I.X.

In a particularly preferred embodiment of said compound of formula I, A is A', i.e. phenyl or a 5- or 6-membered hetaryl, wherein the aromatic ring may in each case be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^A, and R¹ and R² are both hydrogen. These compounds correspond to compounds of formula I.1.A.

In another more preferred embodiment of said compound of formula I, A is A', i.e. phenyl or a 5- or 6-membered hetaryl, wherein the aromatic ring may in each case be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from

R^A, and R³ is hydrogen. These compounds correspond to compounds of formula I.1.X.

In another more preferred embodiment of said compound of formula I, R¹ and R² are both hydrogen, and R³ is hydrogen. These compounds correspond to compounds of formula I.A.X.

In the most preferred embodiment of said compound of formula I, A is A', i.e. phenyl or a 5- or

6-membered hetaryl, wherein the aromatic ring may in each case be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from

R^A, R¹ and R² are both hydrogen, a

Further preferred embodiments of said compound of formula I relate to the substituents R^A, with which A may be partially or fully substituted.

In a preferred embodiment of the compound of formula I, R^A, if present, is

(i) halogen, CN, NR^aR^b, OR^c, C(=Y¹)R^C, C(=Y¹)OR^c, C(=Y¹)SR^C, C(=Y¹)NR^aR^b, Y²C(=Y¹)R^C, Y²C(=Y¹)NR^aR^b, NRaN=C(R^d)(R^e), S(=0)₂R^f, N0₂, Ci-C₆-alkyl, C₂-C₆- Ci-C₄- haloalkyl, Ci-C₄-alkoxy, C₂-C4-alkynyl-Ci-C₂-hydroxyalkyl, C2-C₄-alkynyloxy; (ii) C₂-C₄-alkenylene-C(=Y¹)R^c, C₂-C₄-alkenylene-Y²-C(=Y¹)R^c, wherein the C1-C4- alkylene or C₂-C₄-alkenylene chain may in each case be unsubstituted or may be partially or fully substituted by CN or halogen;

(iv) a 3- to 14-membered saturated or unsaturated heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C3-C6-cycloalkyl, C3-C₆-cycloalkylmethyl, or OR .

In a particularly preferred embodiment of the present invention, the compound of formula I, is a compound of formula 1.1 , I .A, I.X, 1.1 A 1.1 -X, I AX or 1.1. A.X, wherein R^A, if present, is

(i) halogen, CN, NR^aR^b, OR^c, C(=Y¹)R^C, C(=Y¹)OR^c, C(=Y¹)SR^C, C(=Y¹)NR^aR^b,

S(=0)₂R^f, N0₂, Ci-C₆-alkyl, C₂-C₆- Ci-C₄- haloalkyl, Ci-C₄-alkoxy, C₂-C₄-alkynyl-Ci-C₂-hydroxyalkyl, C₂-C₄-alkynyloxy;

(ii) C₂-C₄-alkenylene-C(=Y¹)R^c, C₂-C₄-alkenylene-Y²-C(=Y¹)R^c, wherein the Ci-C₄- alkylene or C₂-C₄-alkenylene chain may in each case be unsubstituted or may be partially or fully substituted by CN or halogen;

2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R'; and wherein R^1b is H, Ci-C -alkyl, C₂-C -alkenyl, C3-C6-cycloalkyl, C₃-C₆-cycloalkylmethyl, or ORa.

If R^A is present in the compounds of formula I or a compound of any one of formulae 1.1 , LA, I 1.1.A, 1.1.X, I.A.X or 1.1.A.X, and preferably if R^A is selected as indicated above, the following substituent definitions are particularly preferred according to the present invention.

Preferably, Y¹, Y² and Y³ are independently of each other selected from O, S and N R^1a, wherein preferably R^1a is in each case independently H, Ci-C₄-alkyl, ORs, or NR^mRⁿ.

Preferably, R^a and R^b are independently of each other selected from

(i) H, NRiR^k, Ci-C₄-alkyl, Ci-C₄-hydroxyalkyl, C(=Y¹)R; or

R^a and R^b together with the nitrogen atom to which they are bound form

(iv) a 3- to 10-membered, saturated or unsaturated heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is preferably H , CrC₄-alkyl, or ORa.

Preferably, R^c is

(i) H, Ci-C₄-alkyl; or

(iv) a 3- to 10-membered saturated or unsaturated carbocycle or heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is preferably H, Ci-C₄-alkyl, or ORa.

Preferably, R^d and R^e are independently selected from NRiR^k and C(=Y¹)OR; Preferably, R^f is Ci-C₄-alkyl. Preferably, Ra is H.

Preferably, R^h is halogen or Ci-C₄-alkoxy.

Preferably, R' is

(i) Ci-C4-alkyl, Ci-C4-haloalkyl, C2-C4-haloalkenyl; or

(Hi) =0. Preferably, Ri and R^k are both H . Preferably, R' is H. Preferably, R^m and Rⁿ are both H.

Preferred compounds of the present invention are listed in the following Table 1 :

Entry Entry

(No. (No.

Compound structure Compound structure

comp. comp.

A) A)

1 109

o

In a central aspect the present invention thus relates to the use of a combination of a nitrification inhibitor or (T) and an insecticide and/or nematicide as defined herein above, or of a composition comprising said combination of a nitrification inhibitor or (T) and an insecticide and/or ne- maticide as defined herein for increasing the health of a plant. The nitrification inhibitor or derivatives or salts thereof as defined herein above in combination with an insecticide and/or nematicide, in particular compounds of formula I and/or salts or suitable derivatives thereof in combination with an insecticide and/or nematicide, as well as compositions comprising said nitrification inhibitor or (T) and an insecticide and/or nematicide as defined herein may be used for in- creasing the health of a plant.

The use may be based on an application of the combination of the nitrification inhibitor or (T) and an insecticide and/or nematicide, the or the composition as defined herein to a plant growing on soil and/or the locus where the plant is growing or is intended to grow, or the application of the combination of the nitrification inhibitor or (T) and an insecticide and/or nematicide, or the composition as defined herein to soil where a plant is growing or is intended to grow or to soil substituents. In specific embodiments, the combination of the nitrification inhibitor or (T) and an insecticide and/or nematicide may be used in the absence of plants, e.g. as preparatory activity for subsequent agricultural activity.

The use may further include the application of a combination of an insecticide and/or nematicide and (T) or the nitrification inhibitor r or derivatives or salts thereof as defined herein above, in particular compounds of formula I and/or salts or suitable derivatives thereof, as well as compositions comprising said combination of an insecticide and/or nematicide and (T) or the nitrification inhibitor,as defined herein above to environments, areas or zones, where nitrification takes place or is assumed or expected to take place. Such environments, areas or zones may, in specific embodiments, not comprise plants or soil, but be planned for subsequent growth of plants. Examples of such environments are laboratory environments or green houses or similar indoor facilities.

The term "plant health" as used herein is intended to mean a condition of the plant which is de- termined by several aspects alone or in combination with each other. One indicator (indicator 1 ) for the condition of the plant is the crop yield. "Crop" and "fruit" are to be understood as any plant product which is further utilized after harvesting, e.g. fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants), flowers (e.g. in the case of gardening plants, ornamentals) etc., that is anything of economic value that is produced by the plant. Another indicator (indicator 2) for the condition of the plant is the plant vigor. The plant vigor becomes manifest in several aspects, too, some of which are visual appearance, e.g. leaf color, fruit color and aspect, amount of dead basal leaves and/or extent of leaf blades, plant weight, plant height, extent of plant verse (lodging), number, strong ness and productivity of tillers, panicles' length, extent of root system, strongness of roots, extent of nodulation, in par- ticular of rhizobial nodulation, point of time of germination, emergence, flowering, grain maturity and/or senescence, protein content, sugar content and the like. Another indicator (indicator 3) for an increase of a plant's health is the reduction of biotic or abiotic stress factors.

The three above mentioned indicators for the health condition of a plant may be interdependent and may result from each other. For example, a reduction of biotic stress may lead to a better plant vigor, e.g. to better and bigger crops, and thus to an increased yield.

Biotic stress, especially over longer terms, can have harmful effects on plants. The term "biotic stress" as used in the context of the present invention refers in particular to stress caused by living organisms, such as insects, arachnids or nematodes. As a result, the quantity and the quality of the stressed plants, their crops and fruits decrease. As far as quality is concerned, reproductive development is usually severely affected with consequences on the crops which are important for fruits or seeds. Growth may be slowed by the stresses; polysaccharide synthesis, both structural and storage, may be reduced or modified: these effects may lead to a decrease in biomass and to changes in the nutritional value of the product. A reduction of biotic stress factors may, for example, be due to an insecticidal effect to insects, arachnids or nematodes of an insecticide and/or nematicide as defined herein. Abiotic stress includes drought, cold, increased UV, increased heat, or other changes in the environment of the plant, that leads to sub-optimal growth conditions. A reduction of abiotic stress factors may, for example, be due to a reduction of nitrification and a corresponding improvement of uptake of nitrogen nutrients.

The term "increased yield" of a plant as used herein means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the composition of the invention. According to the present invention, it is preferred that the yield be increased by at least 0,5 %, more preferred at least 1 %, even more preferred at least 2 %, still more preferred at least 4 %. An increased yield may, for example, be due to a reduction of nitrification and a corresponding improvement of uptake of nitrogen nutrients, as well as an insecticidal effect to insects, arachnids or nematodes of an insecticide and/or nematicide as defined herein.

The term "improved plant vigor" as used herein means that certain crop characteristics are in- creased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the composition of the present invention. Improved plant vigor can be characterized, among others, by following improved properties of a plant:

(a) improved vitality of the plant,

(b) improved quality of the plant and/or of the plant products, e.g.

(b) enhanced protein content,

(c) improved visual appearance,

(d) delay of senescence,

(e) enhanced root growth and/or more developed root system (e.g. determined by the dry mass of the root),

(f) enhanced nodulation, in particular rhizobial nodulation,

(g) longer panicles,

(h) bigger leaf blade,

(i) less dead basal leaves,

(j) increased chlorophyll content

(k) prolonged photosynthetically active period

The improvement of the plant vigor according to the present invention particularly means that the improvement of anyone or several or all of the above mentioned plant characteristics are improved. It further means that if not all of the above characteristics are improved, those which are not improved are not worsened as compared to plants which were not treated according to the invention or are at least not worsened to such an extent that the negative effect exceeds the positive effect of the improved characteristic (i.e. there is always an overall positive effect which preferably results in an improved crop yield). An improved plant vigor may, for example, be due to a reduction of nitrification and a corresponding improvement of uptake of nitrogen nutrients, as well an insecticidal effect to insects, arachnids or nematodes of an insecticide and/or nematicide as defined herein. It is particularly preferred that said increase of the health of a plant is reflected by an increase in growth of root and shoot and/or an overall increase in productivity and/or a faster and more efficient development of the plant. The term "reducing nitrification" or "reduction of nitrification" as used herein refers to a slowing down or stopping of nitrification processes, e.g. by retarding or eliminating the natural transformation of ammonium into nitrate. Such reduction may be a complete or partial elimination of nitrification at the plant or locus where the inhibitor or composition comprising said inhibitor is applied. For example, a partial elimination may result in a residual nitrification on or in the plant, or in or on the soil or soil substituents where a plant grows or is intended to grow of about 90% to 1 %, e.g. 90%, 85%, 80%, 70%, 60%, 50%, 40%, 30%, 20%, 10% or less than 10%, e.g. 5% or less than 5% in comparison to a control situation where the nitrification inhibitor is not used. In certain embodiments, a partial elimination may result in a residual nitrification on or in the plant or in or on the soil or soil substituents where a plant grows or is intended to grow of below 1 %, e.g. at 0.5%, 0.1 % or less in comparison to a control situation where the nitrification inhibitor is not used.

An "insecticide" as mentioned herein above may be any insecticide known to the skilled person. An insecticide typically shows an outstanding effectiveness against biotic stresses caused by a broad spectrum of insects or arachnids, in particular phytopathogenic insects or arachnids.

An "nematicide" as mentioned herein above may be any insecticide known to the skilled person. A nematicide typically shows an outstanding effectiveness against biotic stresses caused by a broad spectrum of nematodes, in particular phytopathogenic nematodes.

In one embodiment, the insecticide an organo(thio)phosphate.

Suitable examples of an organo(thio)phosphate insecticides to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combi- nation with (T) - according to the present invention are acephate (B.1.1 ), azamethiphos (B.1.2), azinphos-methyl (B.1.3), chlorpyrifos (B.1 .4), chlorpyrifos-methyl (B.1.5), chlorfenvinphos (B.1.6), diazinon (B.1 .7), dichlorvos (B.1.8), dicrotophos (B.1.9), dimethoate (B.1.10), disulfoton (B.1.11 ), ethion (B.1.12), fenitrothion (B.1.13), fenthion (B.1.14), isoxathion (B.1.15), malathion (B.1.16), methamidophos (B.1.17), methidathion (B.1.18), methyl-parathion (B.1.19), mevinphos (B.1.20), monocrotophos (B.1 .21 ), oxydemeton-methyl (B.1.22), paraoxon (B.1.23), parathion (B.1.24), phenthoate (B.1.25), phosalone (B.1.26), phosmet (B.1.27), phosphamidon (B.1.28), phorate (B.1.29), phoxim (B.1.30), pirimiphos-methyl (B.1.31), profenofos (B.1.32), prothiofos (B.1.33), sulprophos (B.1 .34), tetrachlorvinphos (B.1.35), terbufos (B.1.36), triazophos (B.1 .37), and trichlorfon (B.1.38).

In a further embodiment, the insecticide is a carbamate. Suitable examples of carbamate insecticides to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are alanycarb (B.2.1 ), aldicarb (B.2.2), bendiocarb (B.2.3), benfuracarb (B.2.4), carbaryl (B.2.5), carbofuran (B.2.6), carbosulfan (B.2.7), fenoxycarb (B.2.8), furathiocarb (B.2.9), methiocarb (B.2.10), methomyl (B.2.11 ), oxamyl (B.2.12), pirimicarb (B.2.13), propoxur (B.2.14), thiodicarb (B.2.15), and triazamate (B.2.16). In a further embodiment, the insecticide is a pyrethroid. Suitable examples of pyrethroid insecticides to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are allethrin (B.3.1 ), bifenthrin (B.3.2), cyfluthrin (B.3.3), cyhalothrin (B.3.4), cyphenothrin (B.3.5), cypermethrin (B.3.6), alpha-cypermethrin (B.3.7), beta-cypermethrin (B.3.8), zeta-cypermethrin (B.3.9), deltamethrin (B.3.10), esfenvalerate (B.3.11 ), etofenprox (B.3.28), fenpropathrin (B.3.12), fenvalerate (B.3.13), imiprothrin (B.3.14), lambda-cyhalothrin (B.3.15), permethrin (B.3.16), prallethrin (B.3.17), pyrethrin I and II (B.3.18), resmethrin (B.3.19), silafluofen (B.3.20), tau-fluvalinate (B.3.21 ), tefluthrin (B.3.22), tetramethrin (B.3.23), tralomethrin (B.3.24), trans- fluthrin (B.3.25), profluthrin (B.3.26), and dimefluthrin (B.3.27).

In a further embodiment, the insecticide is an insect growth regulator.

Suitable examples insect growth regulator insecticides to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are chitin synthesis inhibitors, ecdysone antago- nists, juvenoids and lipid biosynthesis inhibitors.

Suitable examples of insect growth regulator insecticides of the class of chitin synthesis inhibitors to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are benzoylureas, chlorfluazuron (B.4.1 ), cyramazin (B.4.2), diflubenzuron (B.4.3), flucycloxuron (B.4.4), flufenoxuron (B.4.5), hexaflumuron (B.4.6), lufenuron (B.4.7), novaluron (B.4.8), teflubenzuron (B.4.9), triflumuron (B.4.10); buprofezin (B.4.11 ), diofenolan (B.4.12), hexythiazox (B.4.13), etoxazole (B.4.14), and clofentazine (B.4.15). Suitable examples of insect growth regulator insecticides of the class of ecdysone antagonists to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are halofenozide (B.4.16), methoxyfenozide (B.4.17), tebufenozide (B.4.18) and azadirachtin (B.4.19).

Suitable examples of insect growth regulator insecticides of the class of juvenoids to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are pyriproxyfen (B.4.20), methoprene (B.4.21), and fenoxycarb (B.4.22).

Suitable examples of insect growth regulator insecticides of the class of lipid biosynthesis inhibitors to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are spirodiclofen (B.4.23), spiromesifen (B.4.24), and spirotetramat (B.4.25). In a further embodiment, the insecticide is nicotinic receptor agonists/antagonists compound. Suitable examples nicotinic receptor agonists/antagonists compound insecticides to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are clothianidin (B.5.1 ), dinotefuran (B.5.2), flupyradifurone (B.5.3), imidacloprid (B.5.4), thiamethoxam (B.5.5), nitenpyram (B.5.6), acetamiprid (B.5.7), thiacloprid (B.5.8), and 1-2-chloro-thiazol-5-ylmethyl)-2- nitrimino-3,5-dimethyl-[1 ,3,5]triazinane (B.5.9). In a further embodiment, the insecticide is a GABA antagonist compound. Suitable examples of GABA antagonist compound insecticides to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are endosulfan (B.6.1 ), ethiprole (B.6.2), fipronil (B.6.3), vaniliprole (B.6.4), pyrafluprole (B.6.5), pyriprole (B.6.6), and 5-amino-1-(2,6-dichloro-4-methyl- phenyl)-4-sulfinamoyl-1 H-pyrazole-3-carbothioic acid amide (B.6.7).

In a further embodiment, the insecticide is macrocyclic lactone. Suitable examples of macrocy- clic lactone insecticides to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are abamectin (B.7.1 ), emamectin (B.7.2), milbemectin (B.7.3), lepimectin (B.7.4), spinosad (B.7.5), spinetoram (B.7.6).

In a further embodiment, the insecticide is a mitochondrial electron transport inhibitor (METI) I acaricide. Suitable examples of mitochondrial electron transport inhibitor (METI) I acaricide insecticides to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are fenazaquin (B.8.1 ), pyridaben (B.8.2), tebufenpyrad (B.8.3), tolfenpyrad (B.8.4), and flufen- erim (B.8.5).

In a further embodiment, the insecticide is a M ETI I and III compounds. Suitable examples of METI I and III compound insecticides to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are acequinocyl (B.9.1 ), fluacyprim (B.9.2), and hydramethyl- non (B.9.3). In a further embodiment, the insecticide is an uncoupler. A suitable example of an uncoupler insecticide to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention is chlorfenapyr (B.10.1 ). In a further embodiment, the insecticide is an oxidative phosphorylation inhibitor. Suitable examples of such oxidative phosphorylation inhibitors to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are cyhexatin (B.11.1 ), diafenthiuron (B.1 1.2), fenbu- tatin oxide (B.1 1.3), and propargite (B.1 1.4). In a further embodiment, the insecticide is an moulting disruptor compound. A suitable example of such moulting disruptor compounds to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - ac- cording to the present invention is cryomazine (B.12.1 ).

In a further embodiment, the insecticide is a mixed function oxidase inhibitor. A suitable example of such mixed function oxidase inhibitor to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - ac- cording to the present invention is piperonyl butoxide (B.13.1).

In a further embodiment, the insecticide is a sodium channel blocker. Suitable examples of such sodium channel blockers to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are indoxacarb (B.14.1), and metaflumizone (B.14.2).

In a further embodiment, the insecticide is a ryanodine receptor inhibitor. Suitable examples of such ryanodine receptor inhibitors to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention are chlorantraniliprole (B.15.1), cyantraniliprole (B.15.2), flubendiamide (B.15.3), N-[4,6-dichloro-2-[(diethyl-lambda-4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro- 2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.4); N-[4-chloro-2-[(diethyl-lambda-4- sulfanylidene)carbamoyl]-6-methyl-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3- carboxamide (B.15.5); N-[4-chloro-2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]-6-methyl- phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.6); N-[4,6-di- chloro-2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)- 5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.7); N-[4,6-dichloro-2-[(diethyl-lambda- 4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(difluoromethyl)pyrazole-3- carboxamide (B.15.8); N-[4,6-dibromo-2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]- phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.9); N-[4-chloro-2- [(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]-6-cyano-phenyl]-2-(3-chloro-2-pyridyl)-5- (trifluoromethyl)pyrazole-3-carboxamide (B.15.10); N-[4,6-dibromo-2-[(diethyl-lambda-4- sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3- carboxamide (B.15.11 ); cyazypyr (B.15.12), and rynaxapyr (B.15.13).

In a further embodiment, the insecticide to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention is benclothiaz (B.16.1 ), bifenazate (B.16.2), artap (B.16.3), flonicamid (B.16.4), pyridalyl (B.16.5), pymetrozine (B.16.6), sulfur (B.16.7), thiocyclam (B.16.8), cyenopyrafen (B.16.9), flupyrazofos (B.16.10), cyflumetofen (B.16.11 ), amidoflumet (B.16.12), imicyafos (B.16.13), bistrifluron (B.16.14), pyrifluquinazon (B.16.15) and 1 , 1 '-[(3S,4R,4aR,6S,6aS, 12R, 12aS, 12bS)-4-[[(2-cyclopropylacetyl)oxy]methyl]- 1 ,3,4,4a,5,6,6a, 12,12a, 12b-decahydro-12-hydroxy-4,6a, 12b-trimethyl-11 -oxo-9-(3-pyridinyl)- 21-1 ,1 1 H-naphtho[2,1 -b]pyrano[3,4-e]pyran-3,6-diyl] cyclopropaneacetic acid ester (B.16.16). In a further embodiment, the nematicide to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention is thiodicarb or abamectin (B.17.1 ).

In preferred embodiments, the insecticide may be selected from the following group of insecticides:

- organo(thio)phosphate: acephate (B.1.1)

- carbamates: methiocarb (B.2.10), thiodicarb (B.2.15),

- pyrethroids: bifenthrin (B.3.2), cypermethrin (B.3.6), alpha-cypermethrin (B.3.7), beta- cypermethrin (B.3.8), zeta-cypermethrin (B.3.9), deltamethrin (B.3.10), tefluthrin (B.3.22),

- nicotinic receptor agonists/antagonists compounds: clothianidin (B.5.1 ), dinotefuran (B.5.2), imidacloprid (B.5.4), thiamethoxam (B.5.5), acetamiprid (B.5.7), thiacloprid (B.5.8),

- GABA antagonist compounds: fipronil (B.6.3), and

- ryanodine receptor inhibitors: cyazypyr (B.15.12), and rynaxapyr (B.15.13)

In preferred embodiments, the nematicide may be selected from the following group of nemati- cides: thiodicarb or abamectin (B.17.1). In a particularly preferred embodiment, the insecticide to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention is thiodicarb (B.2.15), clothianidin (B.5.1), imidacloprid (B.5.4), thiamethoxam (B.5.5), thiacloprid (B.5.8), fipronil (B.6.3), cyazypyr (B.15.12), rynaxapyr (B.15.13), chlorpyrifos (B.1.4) or acephate (B.1.1); and the nematicide to be used in combination with a nitrification inhibitor and/or with a (thio)phosphoric acid triamide (T) - preferably used in combination with (T) - according to the present invention is abamectin (B.17.1 ).

Accordingly, the present invention furthermore relates to compositions comprising as compound I (component A) a nitrification inhibitor as defined herein above and as compound II (component B) an insecticide and/or a nematicide as defined herein, i.e. a combination of component A and B. In preferred embodiments, such compositions may be selected from the component A of Table 2 in column 2 (Com. A) and from component B of Table 2 in column 3 (Com. B). The number of component A of Table 2 corresponds to the number of component A as shown in Table 1 , supra ("Entry"). Preferred embodiments thus include the specified combinations or compositions comprising component A and B as defined inCb-1 to Cb-2365 of the following Table 2:

Com. Com. Com.

Comb. Com. B Comb. Com. B Comb. Com. B

A A A

Cb-1 1 B.2.15 Cb-216 1 B.5.1 Cb-431 1 B.5.4

Cb-2 2 B.2.15 Cb-217 2 B.5.1 Cb-432 2 B.5.4

Cb-3 3 B.2.15 Cb-218 3 B.5.1 Cb-433 3 B.5.4

Cb-4 4 B.2.15 Cb-219 4 B.5.1 Cb-434 4 B.5.4

Cb-5 5 B.2.15 Cb-220 5 B.5.1 Cb-435 5 B.5.4 Cb-6 6 B.2.15 Cb-221 6 B.5.1 Cb-436 6 B.5.4

Cb-7 7 B.2.15 Cb-222 7 B.5.1 Cb-437 7 B.5.4

Cb-8 8 B.2.15 Cb-223 8 B.5.1 Cb-438 8 B.5.4

Cb-9 9 B.2.15 Cb-224 9 B.5.1 Cb-439 9 B.5.4

Cb-10 10 B.2.15 Cb-225 10 B.5.1 Cb-440 10 B.5.4

Cb-1 1 1 1 B.2.15 Cb-226 1 1 B.5.1 Cb-441 1 1 B.5.4

Cb-12 12 B.2.15 Cb-227 12 B.5.1 Cb-442 12 B.5.4

Cb-13 13 B.2.15 Cb-228 13 B.5.1 Cb-443 13 B.5.4

Cb-14 14 B.2.15 Cb-229 14 B.5.1 Cb-444 14 B.5.4

Cb-15 15 B.2.15 Cb-230 15 B.5.1 Cb-445 15 B.5.4

Cb-16 16 B.2.15 Cb-231 16 B.5.1 Cb-446 16 B.5.4

Cb-17 17 B.2.15 Cb-232 17 B.5.1 Cb-447 17 B.5.4

Cb-18 18 B.2.15 Cb-233 18 B.5.1 Cb-448 18 B.5.4

Cb-19 19 B.2.15 Cb-234 19 B.5.1 Cb-449 19 B.5.4

Cb-20 20 B.2.15 Cb-235 20 B.5.1 Cb-450 20 B.5.4

Cb-21 21 B.2.15 Cb-236 21 B.5.1 Cb-451 21 B.5.4

Cb-22 22 B.2.15 Cb-237 22 B.5.1 Cb-452 22 B.5.4

Cb-23 23 B.2.15 Cb-238 23 B.5.1 Cb-453 23 B.5.4

Cb-24 24 B.2.15 Cb-239 24 B.5.1 Cb-454 24 B.5.4

Cb-25 25 B.2.15 Cb-240 25 B.5.1 Cb-455 25 B.5.4

Cb-26 26 B.2.15 Cb-241 26 B.5.1 Cb-456 26 B.5.4

Cb-27 27 B.2.15 Cb-242 27 B.5.1 Cb-457 27 B.5.4

Cb-28 28 B.2.15 Cb-243 28 B.5.1 Cb-458 28 B.5.4

Cb-29 29 B.2.15 Cb-244 29 B.5.1 Cb-459 29 B.5.4

Cb-30 30 B.2.15 Cb-245 30 B.5.1 Cb-460 30 B.5.4

Cb-31 31 B.2.15 Cb-246 31 B.5.1 Cb-461 31 B.5.4

Cb-32 32 B.2.15 Cb-247 32 B.5.1 Cb-462 32 B.5.4

Cb-33 33 B.2.15 Cb-248 33 B.5.1 Cb-463 33 B.5.4

Cb-34 34 B.2.15 Cb-249 34 B.5.1 Cb-464 34 B.5.4

Cb-35 35 B.2.15 Cb-250 35 B.5.1 Cb-465 35 B.5.4

Cb-36 36 B.2.15 Cb-251 36 B.5.1 Cb-466 36 B.5.4

Cb-37 37 B.2.15 Cb-252 37 B.5.1 Cb-467 37 B.5.4

Cb-38 38 B.2.15 Cb-253 38 B.5.1 Cb-468 38 B.5.4

Cb-39 39 B.2.15 Cb-254 39 B.5.1 Cb-469 39 B.5.4

Cb-40 40 B.2.15 Cb-255 40 B.5.1 Cb-470 40 B.5.4

Cb-41 41 B.2.15 Cb-256 41 B.5.1 Cb-471 41 B.5.4

Cb-42 42 B.2.15 Cb-257 42 B.5.1 Cb-472 42 B.5.4

Cb-43 43 B.2.15 Cb-258 43 B.5.1 Cb-473 43 B.5.4

Cb-44 44 B.2.15 Cb-259 44 B.5.1 Cb-474 44 B.5.4

Cb-45 45 B.2.15 Cb-260 45 B.5.1 Cb-475 45 B.5.4

Cb-46 46 B.2.15 Cb-261 46 B.5.1 Cb-476 46 B.5.4

Cb-47 47 B.2.15 Cb-262 47 B.5.1 Cb-477 47 B.5.4

Cb-48 48 B.2.15 Cb-263 48 B.5.1 Cb-478 48 B.5.4 Cb-49 49 B.2.15 Cb-264 49 B.5.1 Cb-479 49 B.5.4

Cb-50 50 B.2.15 Cb-265 50 B.5.1 Cb-480 50 B.5.4

Cb-51 51 B.2.15 Cb-266 51 B.5.1 Cb-481 51 B.5.4

Cb-52 52 B.2.15 Cb-267 52 B.5.1 Cb-482 52 B.5.4

Cb-53 53 B.2.15 Cb-268 53 B.5.1 Cb-483 53 B.5.4

Cb-54 54 B.2.15 Cb-269 54 B.5.1 Cb-484 54 B.5.4

Cb-55 55 B.2.15 Cb-270 55 B.5.1 Cb-485 55 B.5.4

Cb-56 56 B.2.15 Cb-271 56 B.5.1 Cb-486 56 B.5.4

Cb-57 57 B.2.15 Cb-272 57 B.5.1 Cb-487 57 B.5.4

Cb-58 58 B.2.15 Cb-273 58 B.5.1 Cb-488 58 B.5.4

Cb-59 59 B.2.15 Cb-274 59 B.5.1 Cb-489 59 B.5.4

Cb-60 60 B.2.15 Cb-275 60 B.5.1 Cb-490 60 B.5.4

Cb-61 61 B.2.15 Cb-276 61 B.5.1 Cb-491 61 B.5.4

Cb-62 62 B.2.15 Cb-277 62 B.5.1 Cb-492 62 B.5.4

Cb-63 63 B.2.15 Cb-278 63 B.5.1 Cb-493 63 B.5.4

Cb-64 64 B.2.15 Cb-279 64 B.5.1 Cb-494 64 B.5.4

Cb-65 65 B.2.15 Cb-280 65 B.5.1 Cb-495 65 B.5.4

Cb-66 66 B.2.15 Cb-281 66 B.5.1 Cb-496 66 B.5.4

Cb-67 67 B.2.15 Cb-282 67 B.5.1 Cb-497 67 B.5.4

Cb-68 68 B.2.15 Cb-283 68 B.5.1 Cb-498 68 B.5.4

Cb-69 69 B.2.15 Cb-284 69 B.5.1 Cb-499 69 B.5.4

Cb-70 70 B.2.15 Cb-285 70 B.5.1 Cb-500 70 B.5.4

Cb-71 71 B.2.15 Cb-286 71 B.5.1 Cb-501 71 B.5.4

Cb-72 72 B.2.15 Cb-287 72 B.5.1 Cb-502 72 B.5.4

Cb-73 73 B.2.15 Cb-288 73 B.5.1 Cb-503 73 B.5.4

Cb-74 74 B.2.15 Cb-289 74 B.5.1 Cb-504 74 B.5.4

Cb-75 75 B.2.15 Cb-290 75 B.5.1 Cb-505 75 B.5.4

Cb-76 76 B.2.15 Cb-291 76 B.5.1 Cb-506 76 B.5.4

Cb-77 77 B.2.15 Cb-292 77 B.5.1 Cb-507 77 B.5.4

Cb-78 78 B.2.15 Cb-293 78 B.5.1 Cb-508 78 B.5.4

Cb-79 79 B.2.15 Cb-294 79 B.5.1 Cb-509 79 B.5.4

Cb-80 80 B.2.15 Cb-295 80 B.5.1 Cb-510 80 B.5.4

Cb-81 81 B.2.15 Cb-296 81 B.5.1 Cb-511 81 B.5.4

Cb-82 82 B.2.15 Cb-297 82 B.5.1 Cb-512 82 B.5.4

Cb-83 83 B.2.15 Cb-298 83 B.5.1 Cb-513 83 B.5.4

Cb-84 84 B.2.15 Cb-299 84 B.5.1 Cb-514 84 B.5.4

Cb-85 85 B.2.15 Cb-300 85 B.5.1 Cb-515 85 B.5.4

Cb-86 86 B.2.15 Cb-301 86 B.5.1 Cb-516 86 B.5.4

Cb-87 87 B.2.15 Cb-302 87 B.5.1 Cb-517 87 B.5.4

Cb-88 88 B.2.15 Cb-303 88 B.5.1 Cb-518 88 B.5.4

Cb-89 89 B.2.15 Cb-304 89 B.5.1 Cb-519 89 B.5.4

Cb-90 90 B.2.15 Cb-305 90 B.5.1 Cb-520 90 B.5.4

Cb-91 91 B.2.15 Cb-306 91 B.5.1 Cb-521 91 B.5.4 Cb-92 92 B.2.15 Cb-307 92 B.5.1 Cb-522 92 B.5.4

Cb-93 93 B.2.15 Cb-308 93 B.5.1 Cb-523 93 B.5.4

Cb-94 94 B.2.15 Cb-309 94 B.5.1 Cb-524 94 B.5.4

Cb-95 95 B.2.15 Cb-310 95 B.5.1 Cb-525 95 B.5.4

Cb-96 96 B.2.15 Cb-31 1 96 B.5.1 Cb-526 96 B.5.4

Cb-97 97 B.2.15 Cb-312 97 B.5.1 Cb-527 97 B.5.4

Cb-98 98 B.2.15 Cb-313 98 B.5.1 Cb-528 98 B.5.4

Cb-99 99 B.2.15 Cb-314 99 B.5.1 Cb-529 99 B.5.4

Cb-100 100 B.2.15 Cb-315 100 B.5.1 Cb-530 100 B.5.4

Cb-101 101 B.2.15 Cb-316 101 B.5.1 Cb-531 101 B.5.4

Cb-102 102 B.2.15 Cb-317 102 B.5.1 Cb-532 102 B.5.4

Cb-103 103 B.2.15 Cb-318 103 B.5.1 Cb-533 103 B.5.4

Cb-104 104 B.2.15 Cb-319 104 B.5.1 Cb-534 104 B.5.4

Cb-105 105 B.2.15 Cb-320 105 B.5.1 Cb-535 105 B.5.4

Cb-106 106 B.2.15 Cb-321 106 B.5.1 Cb-536 106 B.5.4

Cb-107 107 B.2.15 Cb-322 107 B.5.1 Cb-537 107 B.5.4

Cb-108 108 B.2.15 Cb-323 108 B.5.1 Cb-538 108 B.5.4

Cb-109 109 B.2.15 Cb-324 109 B.5.1 Cb-539 109 B.5.4

Cb-1 10 110 B.2.15 Cb-325 1 10 B.5.1 Cb-540 1 10 B.5.4

Cb-1 1 1 11 1 B.2.15 Cb-326 1 11 B.5.1 Cb-541 1 11 B.5.4

Cb-1 12 112 B.2.15 Cb-327 1 12 B.5.1 Cb-542 1 12 B.5.4

Cb-1 13 113 B.2.15 Cb-328 1 13 B.5.1 Cb-543 1 13 B.5.4

Cb-1 14 114 B.2.15 Cb-329 1 14 B.5.1 Cb-544 1 14 B.5.4

Cb-1 15 115 B.2.15 Cb-330 1 15 B.5.1 Cb-545 1 15 B.5.4

Cb-1 16 116 B.2.15 Cb-331 1 16 B.5.1 Cb-546 1 16 B.5.4

Cb-1 17 117 B.2.15 Cb-332 1 17 B.5.1 Cb-547 1 17 B.5.4

Cb-1 18 118 B.2.15 Cb-333 1 18 B.5.1 Cb-548 1 18 B.5.4

Cb-1 19 119 B.2.15 Cb-334 1 19 B.5.1 Cb-549 1 19 B.5.4

Cb-120 120 B.2.15 Cb-335 120 B.5.1 Cb-550 120 B.5.4

Cb-121 121 B.2.15 Cb-336 121 B.5.1 Cb-551 121 B.5.4

Cb-122 122 B.2.15 Cb-337 122 B.5.1 Cb-552 122 B.5.4

Cb-123 123 B.2.15 Cb-338 123 B.5.1 Cb-553 123 B.5.4

Cb-124 124 B.2.15 Cb-339 124 B.5.1 Cb-554 124 B.5.4

Cb-125 125 B.2.15 Cb-340 125 B.5.1 Cb-555 125 B.5.4

Cb-126 126 B.2.15 Cb-341 126 B.5.1 Cb-556 126 B.5.4

Cb-127 127 B.2.15 Cb-342 127 B.5.1 Cb-557 127 B.5.4

Cb-128 128 B.2.15 Cb-343 128 B.5.1 Cb-558 128 B.5.4

Cb-129 129 B.2.15 Cb-344 129 B.5.1 Cb-559 129 B.5.4

Cb-130 130 B.2.15 Cb-345 130 B.5.1 Cb-560 130 B.5.4

Cb-131 131 B.2.15 Cb-346 131 B.5.1 Cb-561 131 B.5.4

Cb-132 132 B.2.15 Cb-347 132 B.5.1 Cb-562 132 B.5.4

Cb-133 133 B.2.15 Cb-348 133 B.5.1 Cb-563 133 B.5.4

Cb-134 134 B.2.15 Cb-349 134 B.5.1 Cb-564 134 B.5.4 Cb-135 135 B.2.15 Cb-350 135 B.5.1 Cb-565 135 B.5.4

Cb-136 136 B.2.15 Cb-351 136 B.5.1 Cb-566 136 B.5.4

Cb-137 137 B.2.15 Cb-352 137 B.5.1 Cb-567 137 B.5.4

Cb-138 138 B.2.15 Cb-353 138 B.5.1 Cb-568 138 B.5.4

Cb-139 139 B.2.15 Cb-354 139 B.5.1 Cb-569 139 B.5.4

Cb-140 140 B.2.15 Cb-355 140 B.5.1 Cb-570 140 B.5.4

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Cb-147 147 B.2.15 Cb-362 147 B.5.1 Cb-577 147 B.5.4

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Cb-149 149 B.2.15 Cb-364 149 B.5.1 Cb-579 149 B.5.4

Cb-150 150 B.2.15 Cb-365 150 B.5.1 Cb-580 150 B.5.4

Cb-151 151 B.2.15 Cb-366 151 B.5.1 Cb-581 151 B.5.4

Cb-152 152 B.2.15 Cb-367 152 B.5.1 Cb-582 152 B.5.4

Cb-153 153 B.2.15 Cb-368 153 B.5.1 Cb-583 153 B.5.4

Cb-154 154 B.2.15 Cb-369 154 B.5.1 Cb-584 154 B.5.4

Cb-155 155 B.2.15 Cb-370 155 B.5.1 Cb-585 155 B.5.4

Cb-156 156 B.2.15 Cb-371 156 B.5.1 Cb-586 156 B.5.4

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Cb-167 167 B.2.15 Cb-382 167 B.5.1 Cb-597 167 B.5.4

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Cb-169 169 B.2.15 Cb-384 169 B.5.1 Cb-599 169 B.5.4

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Cb-173 173 B.2.15 Cb-388 173 B.5.1 Cb-603 173 B.5.4

Cb-174 174 B.2.15 Cb-389 174 B.5.1 Cb-604 174 B.5.4

Cb-175 175 B.2.15 Cb-390 175 B.5.1 Cb-605 175 B.5.4

Cb-176 176 B.2.15 Cb-391 176 B.5.1 Cb-606 176 B.5.4

Cb-177 177 B.2.15 Cb-392 177 B.5.1 Cb-607 177 B.5.4 Cb-178 178 B.2.15 Cb-393 178 B.5.1 Cb-608 178 B.5.4

Cb-179 179 B.2.15 Cb-394 179 B.5.1 Cb-609 179 B.5.4

Cb-180 180 B.2.15 Cb-395 180 B.5.1 Cb-610 180 B.5.4

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Cb-187 187 B.2.15 Cb-402 187 B.5.1 Cb-617 187 B.5.4

Cb-188 188 B.2.15 Cb-403 188 B.5.1 Cb-618 188 B.5.4

Cb-189 189 B.2.15 Cb-404 189 B.5.1 Cb-619 189 B.5.4

Cb-190 190 B.2.15 Cb-405 190 B.5.1 Cb-620 190 B.5.4

Cb-191 191 B.2.15 Cb-406 191 B.5.1 Cb-621 191 B.5.4

Cb-192 192 B.2.15 Cb-407 192 B.5.1 Cb-622 192 B.5.4

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Cb-194 194 B.2.15 Cb-409 194 B.5.1 Cb-624 194 B.5.4

Cb-195 195 B.2.15 Cb-410 195 B.5.1 Cb-625 195 B.5.4

Cb-196 196 B.2.15 Cb-41 1 196 B.5.1 Cb-626 196 B.5.4

Cb-197 197 B.2.15 Cb-412 197 B.5.1 Cb-627 197 B.5.4

Cb-198 198 B.2.15 Cb-413 198 B.5.1 Cb-628 198 B.5.4

Cb-199 199 B.2.15 Cb-414 199 B.5.1 Cb-629 199 B.5.4

Cb-200 200 B.2.15 Cb-415 200 B.5.1 Cb-630 200 B.5.4

Cb-201 201 B.2.15 Cb-416 201 B.5.1 Cb-631 201 B.5.4

Cb-202 202 B.2.15 Cb-417 202 B.5.1 Cb-632 202 B.5.4

Cb-203 203 B.2.15 Cb-418 203 B.5.1 Cb-633 203 B.5.4

Cb-204 204 B.2.15 Cb-419 204 B.5.1 Cb-634 204 B.5.4

Cb-205 205 B.2.15 Cb-420 205 B.5.1 Cb-635 205 B.5.4

Cb-206 206 B.2.15 Cb-421 206 B.5.1 Cb-636 206 B.5.4

Cb-207 207 B.2.15 Cb-422 207 B.5.1 Cb-637 207 B.5.4

Cb-208 208 B.2.15 Cb-423 208 B.5.1 Cb-638 208 B.5.4

Cb-209 209 B.2.15 Cb-424 209 B.5.1 Cb-639 209 B.5.4

Cb-210 210 B.2.15 Cb-425 210 B.5.1 Cb-640 210 B.5.4

Cb-21 1 21 1 B.2.15 Cb-426 211 B.5.1 Cb-641 211 B.5.4

Cb-212 212 B.2.15 Cb-427 212 B.5.1 Cb-642 212 B.5.4

Cb-213 213 B.2.15 Cb-428 213 B.5.1 Cb-643 213 B.5.4

Cb-214 214 B.2.15 Cb-429 214 B.5.1 Cb-644 214 B.5.4

Cb-215 215 B.2.15 Cb-430 215 B.5.1 Cb-645 215 B.5.4

Cb-646 1 B.5.5 Cb-861 1 B.5.8 Cb-1076 1 B. 6.3

Cb-647 2 B.5.5 Cb-862 2 B.5.8 Cb-1077 2 B. 6.3

Cb-648 3 B.5.5 Cb-863 3 B.5.8 Cb-1078 3 B. 6.3

Cb-649 4 B.5.5 Cb-864 4 B.5.8 Cb-1079 4 B. 6.3

Cb-650 5 B.5.5 Cb-865 5 B.5.8 Cb-1080 5 B. 6.3 Cb-651 6 B.5.5 Cb-866 6 B.5.8 Cb-1081 6 B. 6.3

Cb-652 7 B.5.5 Cb-867 7 B.5.8 Cb-1082 7 B. 6.3

Cb-653 8 B.5.5 Cb-868 8 B.5.8 Cb-1083 8 B. 6.3

Cb-654 9 B.5.5 Cb-869 9 B.5.8 Cb-1084 9 B. 6.3

Cb-655 10 B.5.5 Cb-870 10 B.5.8 Cb-1085 10 B. 6.3

Cb-656 1 1 B.5.5 Cb-871 1 1 B.5.8 Cb-1086 1 1 B. 6.3

Cb-657 12 B.5.5 Cb-872 12 B.5.8 Cb-1087 12 B. 6.3

Cb-658 13 B.5.5 Cb-873 13 B.5.8 Cb-1088 13 B. 6.3

Cb-659 14 B.5.5 Cb-874 14 B.5.8 Cb-1089 14 B. 6.3

Cb-660 15 B.5.5 Cb-875 15 B.5.8 Cb-1090 15 B. 6.3

Cb-661 16 B.5.5 Cb-876 16 B.5.8 Cb-1091 16 B. 6.3

Cb-662 17 B.5.5 Cb-877 17 B.5.8 Cb-1092 17 B. 6.3

Cb-663 18 B.5.5 Cb-878 18 B.5.8 Cb-1093 18 B. 6.3

Cb-664 19 B.5.5 Cb-879 19 B.5.8 Cb-1094 19 B. 6.3

Cb-665 20 B.5.5 Cb-880 20 B.5.8 Cb-1095 20 B. 6.3

Cb-666 21 B.5.5 Cb-881 21 B.5.8 Cb-1096 21 B. 6.3

Cb-667 22 B.5.5 Cb-882 22 B.5.8 Cb-1097 22 B. 6.3

Cb-668 23 B.5.5 Cb-883 23 B.5.8 Cb-1098 23 B. 6.3

Cb-669 24 B.5.5 Cb-884 24 B.5.8 Cb-1099 24 B. 6.3

Cb-670 25 B.5.5 Cb-885 25 B.5.8 Cb-1 100 25 B. 6.3

Cb-671 26 B.5.5 Cb-886 26 B.5.8 Cb-1 101 26 B. 6.3

Cb-672 27 B.5.5 Cb-887 27 B.5.8 Cb-1 102 27 B. 6.3

Cb-673 28 B.5.5 Cb-888 28 B.5.8 Cb-1 103 28 B. 6.3

Cb-674 29 B.5.5 Cb-889 29 B.5.8 Cb-1 104 29 B. 6.3

Cb-675 30 B.5.5 Cb-890 30 B.5.8 Cb-1 105 30 B. 6.3

Cb-676 31 B.5.5 Cb-891 31 B.5.8 Cb-1 106 31 B. 6.3

Cb-677 32 B.5.5 Cb-892 32 B.5.8 Cb-1 107 32 B. 6.3

Cb-678 33 B.5.5 Cb-893 33 B.5.8 Cb-1 108 33 B. 6.3

Cb-679 34 B.5.5 Cb-894 34 B.5.8 Cb-1 109 34 B. 6.3

Cb-680 35 B.5.5 Cb-895 35 B.5.8 Cb-1 1 10 35 B. 6.3

Cb-681 36 B.5.5 Cb-896 36 B.5.8 Cb-1 1 11 36 B. 6.3

Cb-682 37 B.5.5 Cb-897 37 B.5.8 Cb-1 1 12 37 B. 6.3

Cb-683 38 B.5.5 Cb-898 38 B.5.8 Cb-1 1 13 38 B. 6.3

Cb-684 39 B.5.5 Cb-899 39 B.5.8 Cb-1 1 14 39 B. 6.3

Cb-685 40 B.5.5 Cb-900 40 B.5.8 Cb-1 1 15 40 B. 6.3

Cb-686 41 B.5.5 Cb-901 41 B.5.8 Cb-1 1 16 41 B. 6.3

Cb-687 42 B.5.5 Cb-902 42 B.5.8 Cb-1 1 17 42 B. 6.3

Cb-688 43 B.5.5 Cb-903 43 B.5.8 Cb-1 1 18 43 B. 6.3

Cb-689 44 B.5.5 Cb-904 44 B.5.8 Cb-1 1 19 44 B. 6.3

Cb-690 45 B.5.5 Cb-905 45 B.5.8 Cb-1 120 45 B. 6.3

Cb-691 46 B.5.5 Cb-906 46 B.5.8 Cb-1 121 46 B. 6.3

Cb-692 47 B.5.5 Cb-907 47 B.5.8 Cb-1 122 47 B. 6.3

Cb-693 48 B.5.5 Cb-908 48 B.5.8 Cb-1 123 48 B. 6.3 Cb-694 49 B.5.5 Cb-909 49 B.5.8 Cb-1124 49 B.6.3

Cb-695 50 B.5.5 Cb-910 50 B.5.8 Cb-1125 50 B.6.3

Cb-696 51 B.5.5 Cb-911 51 B.5.8 Cb-1126 51 B.6.3

Cb-697 52 B.5.5 Cb-912 52 B.5.8 Cb-1127 52 B.6.3

Cb-698 53 B.5.5 Cb-913 53 B.5.8 Cb-1128 53 B.6.3

Cb-699 54 B.5.5 Cb-914 54 B.5.8 Cb-1129 54 B.6.3

Cb-700 55 B.5.5 Cb-915 55 B.5.8 Cb-1130 55 B.6.3

Cb-701 56 B.5.5 Cb-916 56 B.5.8 Cb-1131 56 B.6.3

Cb-702 57 B.5.5 Cb-917 57 B.5.8 Cb-1132 57 B.6.3

Cb-703 58 B.5.5 Cb-918 58 B.5.8 Cb-1133 58 B.6.3

Cb-704 59 B.5.5 Cb-919 59 B.5.8 Cb-1134 59 B.6.3

Cb-705 60 B.5.5 Cb-920 60 B.5.8 Cb-1135 60 B.6.3

Cb-706 61 B.5.5 Cb-921 61 B.5.8 Cb-1136 61 B.6.3

Cb-707 62 B.5.5 Cb-922 62 B.5.8 Cb-1137 62 B.6.3

Cb-708 63 B.5.5 Cb-923 63 B.5.8 Cb-1138 63 B.6.3

Cb-709 64 B.5.5 Cb-924 64 B.5.8 Cb-1139 64 B.6.3

Cb-710 65 B.5.5 Cb-925 65 B.5.8 Cb-1140 65 B.6.3

Cb-711 66 B.5.5 Cb-926 66 B.5.8 Cb-1141 66 B.6.3

Cb-712 67 B.5.5 Cb-927 67 B.5.8 Cb-1142 67 B.6.3

Cb-713 68 B.5.5 Cb-928 68 B.5.8 Cb-1143 68 B.6.3

Cb-714 69 B.5.5 Cb-929 69 B.5.8 Cb-1144 69 B.6.3

Cb-715 70 B.5.5 Cb-930 70 B.5.8 Cb-1145 70 B.6.3

Cb-716 71 B.5.5 Cb-931 71 B.5.8 Cb-1146 71 B.6.3

Cb-717 72 B.5.5 Cb-932 72 B.5.8 Cb-1147 72 B.6.3

Cb-718 73 B.5.5 Cb-933 73 B.5.8 Cb-1148 73 B.6.3

Cb-719 74 B.5.5 Cb-934 74 B.5.8 Cb-1149 74 B.6.3

Cb-720 75 B.5.5 Cb-935 75 B.5.8 Cb-1150 75 B.6.3

Cb-721 76 B.5.5 Cb-936 76 B.5.8 Cb-1151 76 B.6.3

Cb-722 77 B.5.5 Cb-937 77 B.5.8 Cb-1152 77 B.6.3

Cb-723 78 B.5.5 Cb-938 78 B.5.8 Cb-1153 78 B.6.3

Cb-724 79 B.5.5 Cb-939 79 B.5.8 Cb-1154 79 B.6.3

Cb-725 80 B.5.5 Cb-940 80 B.5.8 Cb-1155 80 B.6.3

Cb-726 81 B.5.5 Cb-941 81 B.5.8 Cb-1156 81 B.6.3

Cb-727 82 B.5.5 Cb-942 82 B.5.8 Cb-1157 82 B.6.3

Cb-728 83 B.5.5 Cb-943 83 B.5.8 Cb-1158 83 B.6.3

Cb-729 84 B.5.5 Cb-944 84 B.5.8 Cb-1159 84 B.6.3

Cb-730 85 B.5.5 Cb-945 85 B.5.8 Cb-1160 85 B.6.3

Cb-731 86 B.5.5 Cb-946 86 B.5.8 Cb-1161 86 B.6.3

Cb-732 87 B.5.5 Cb-947 87 B.5.8 Cb-1162 87 B.6.3

Cb-733 88 B.5.5 Cb-948 88 B.5.8 Cb-1163 88 B.6.3

Cb-734 89 B.5.5 Cb-949 89 B.5.8 Cb-1164 89 B.6.3

Cb-735 90 B.5.5 Cb-950 90 B.5.8 Cb-1165 90 B.6.3

Cb-736 91 B.5.5 Cb-951 91 B.5.8 Cb-1166 91 B.6.3 Cb-737 92 B.5.5 Cb-952 92 B.5.8 Cb-1167 92 B.6.3

Cb-738 93 B.5.5 Cb-953 93 B.5.8 Cb-1168 93 B.6.3

Cb-739 94 B.5.5 Cb-954 94 B.5.8 Cb-1169 94 B.6.3

Cb-740 95 B.5.5 Cb-955 95 B.5.8 Cb-1170 95 B.6.3

Cb-741 96 B.5.5 Cb-956 96 B.5.8 Cb-1171 96 B.6.3

Cb-742 97 B.5.5 Cb-957 97 B.5.8 Cb-1172 97 B.6.3

Cb-743 98 B.5.5 Cb-958 98 B.5.8 Cb-1173 98 B.6.3

Cb-744 99 B.5.5 Cb-959 99 B.5.8 Cb-1174 99 B.6.3

Cb-745 100 B.5.5 Cb-960 100 B.5.8 Cb-1175 100 B.6.3

Cb-746 101 B.5.5 Cb-961 101 B.5.8 Cb-1176 101 B.6.3

Cb-747 102 B.5.5 Cb-962 102 B.5.8 Cb-1177 102 B.6.3

Cb-748 103 B.5.5 Cb-963 103 B.5.8 Cb-1178 103 B.6.3

Cb-749 104 B.5.5 Cb-964 104 B.5.8 Cb-1179 104 B.6.3

Cb-750 105 B.5.5 Cb-965 105 B.5.8 Cb-1180 105 B.6.3

Cb-751 106 B.5.5 Cb-966 106 B.5.8 Cb-1181 106 B.6.3

Cb-752 107 B.5.5 Cb-967 107 B.5.8 Cb-1182 107 B.6.3

Cb-753 108 B.5.5 Cb-968 108 B.5.8 Cb-1183 108 B.6.3

Cb-754 109 B.5.5 Cb-969 109 B.5.8 Cb-1184 109 B.6.3

Cb-755 110 B.5.5 Cb-970 110 B.5.8 Cb-1185 110 B.6.3

Cb-756 111 B.5.5 Cb-971 111 B.5.8 Cb-1186 111 B.6.3

Cb-757 112 B.5.5 Cb-972 112 B.5.8 Cb-1187 112 B.6.3

Cb-758 113 B.5.5 Cb-973 113 B.5.8 Cb-1188 113 B.6.3

Cb-759 114 B.5.5 Cb-974 114 B.5.8 Cb-1189 114 B.6.3

Cb-760 115 B.5.5 Cb-975 115 B.5.8 Cb-1190 115 B.6.3

Cb-761 116 B.5.5 Cb-976 116 B.5.8 Cb-1191 116 B.6.3

Cb-762 117 B.5.5 Cb-977 117 B.5.8 Cb-1192 117 B.6.3

Cb-763 118 B.5.5 Cb-978 118 B.5.8 Cb-1193 118 B.6.3

Cb-764 119 B.5.5 Cb-979 119 B.5.8 Cb-1194 119 B.6.3

Cb-765 120 B.5.5 Cb-980 120 B.5.8 Cb-1195 120 B.6.3

Cb-766 121 B.5.5 Cb-981 121 B.5.8 Cb-1196 121 B.6.3

Cb-767 122 B.5.5 Cb-982 122 B.5.8 Cb-1197 122 B.6.3

Cb-768 123 B.5.5 Cb-983 123 B.5.8 Cb-1198 123 B.6.3

Cb-769 124 B.5.5 Cb-984 124 B.5.8 Cb-1199 124 B.6.3

Cb-770 125 B.5.5 Cb-985 125 B.5.8 Cb-1200 125 B.6.3

Cb-771 126 B.5.5 Cb-986 126 B.5.8 Cb-1201 126 B.6.3

Cb-772 127 B.5.5 Cb-987 127 B.5.8 Cb-1202 127 B.6.3

Cb-773 128 B.5.5 Cb-988 128 B.5.8 Cb-1203 128 B.6.3

Cb-774 129 B.5.5 Cb-989 129 B.5.8 Cb-1204 129 B.6.3

Cb-775 130 B.5.5 Cb-990 130 B.5.8 Cb-1205 130 B.6.3

Cb-776 131 B.5.5 Cb-991 131 B.5.8 Cb-1206 131 B.6.3

Cb-777 132 B.5.5 Cb-992 132 B.5.8 Cb-1207 132 B.6.3

Cb-778 133 B.5.5 Cb-993 133 B.5.8 Cb-1208 133 B.6.3

Cb-779 134 B.5.5 Cb-994 134 B.5.8 Cb-1209 134 B.6.3 Cb-780 135 B.5.5 Cb-995 135 B.5.8 Cb-1210 135 B. 6.3

Cb-781 136 B.5.5 Cb-996 136 B.5.8 Cb-1211 136 B. 6.3

Cb-782 137 B.5.5 Cb-997 137 B.5.8 Cb-1212 137 B. 6.3

Cb-783 138 B.5.5 Cb-998 138 B.5.8 Cb-1213 138 B. 6.3

Cb-784 139 B.5.5 Cb-999 139 B.5.8 Cb-1214 139 B. 6.3

Cb-785 140 B.5.5 Cb-1000 140 B.5.8 Cb-1215 140 B. 6.3

Cb-786 141 B.5.5 Cb-1001 141 B.5.8 Cb-1216 141 B. 6.3

Cb-787 142 B.5.5 Cb-1002 142 B.5.8 Cb-1217 142 B. 6.3

Cb-788 143 B.5.5 Cb-1003 143 B.5.8 Cb-1218 143 B. 6.3

Cb-789 144 B.5.5 Cb-1004 144 B.5.8 Cb-1219 144 B. 6.3

Cb-790 145 B.5.5 Cb-1005 145 B.5.8 Cb-1220 145 B. 6.3

Cb-791 146 B.5.5 Cb-1006 146 B.5.8 Cb-1221 146 B. 6.3

Cb-792 147 B.5.5 Cb-1007 147 B.5.8 Cb-1222 147 B. 6.3

Cb-793 148 B.5.5 Cb-1008 148 B.5.8 Cb-1223 148 B. 6.3

Cb-794 149 B.5.5 Cb-1009 149 B.5.8 Cb-1224 149 B. 6.3

Cb-795 150 B.5.5 Cb-1010 150 B.5.8 Cb-1225 150 B. 6.3

Cb-796 151 B.5.5 Cb-1011 151 B.5.8 Cb-1226 151 B. 6.3

Cb-797 152 B.5.5 Cb-1012 152 B.5.8 Cb-1227 152 B. 6.3

Cb-798 153 B.5.5 Cb-1013 153 B.5.8 Cb-1228 153 B. 6.3

Cb-799 154 B.5.5 Cb-1014 154 B.5.8 Cb-1229 154 B. 6.3

Cb-800 155 B.5.5 Cb-1015 155 B.5.8 Cb-1230 155 B. 6.3

Cb-801 156 B.5.5 Cb-1016 156 B.5.8 Cb-1231 156 B. 6.3

Cb-802 157 B.5.5 Cb-1017 157 B.5.8 Cb-1232 157 B. 6.3

Cb-803 158 B.5.5 Cb-1018 158 B.5.8 Cb-1233 158 B. 6.3

Cb-804 159 B.5.5 Cb-1019 159 B.5.8 Cb-1234 159 B. 6.3

Cb-805 160 B.5.5 Cb-1020 160 B.5.8 Cb-1235 160 B. 6.3

Cb-806 161 B.5.5 Cb-1021 161 B.5.8 Cb-1236 161 B. 6.3

Cb-807 162 B.5.5 Cb-1022 162 B.5.8 Cb-1237 162 B. 6.3

Cb-808 163 B.5.5 Cb-1023 163 B.5.8 Cb-1238 163 B. 6.3

Cb-809 164 B.5.5 Cb-1024 164 B.5.8 Cb-1239 164 B. 6.3

Cb-810 165 B.5.5 Cb-1025 165 B.5.8 Cb-1240 165 B. 6.3

Cb-81 1 166 B.5.5 Cb-1026 166 B.5.8 Cb-1241 166 B. 6.3

Cb-812 167 B.5.5 Cb-1027 167 B.5.8 Cb-1242 167 B. 6.3

Cb-813 168 B.5.5 Cb-1028 168 B.5.8 Cb-1243 168 B. 6.3

Cb-814 169 B.5.5 Cb-1029 169 B.5.8 Cb-1244 169 B. 6.3

Cb-815 170 B.5.5 Cb-1030 170 B.5.8 Cb-1245 170 B. 6.3

Cb-816 171 B.5.5 Cb-1031 171 B.5.8 Cb-1246 171 B. 6.3

Cb-817 172 B.5.5 Cb-1032 172 B.5.8 Cb-1247 172 B. 6.3

Cb-818 173 B.5.5 Cb-1033 173 B.5.8 Cb-1248 173 B. 6.3

Cb-819 174 B.5.5 Cb-1034 174 B.5.8 Cb-1249 174 B. 6.3

Cb-820 175 B.5.5 Cb-1035 175 B.5.8 Cb-1250 175 B. 6.3

Cb-821 176 B.5.5 Cb-1036 176 B.5.8 Cb-1251 176 B. 6.3

Cb-822 177 B.5.5 Cb-1037 177 B.5.8 Cb-1252 177 B. 6.3 Cb-823 178 B.5.5 Cb-1038 178 B.5.8 Cb-1253 178 B. 6.3

Cb-824 179 B.5.5 Cb-1039 179 B.5.8 Cb-1254 179 B. 6.3

Cb-825 180 B.5.5 Cb-1040 180 B.5.8 Cb-1255 180 B. 6.3

Cb-826 181 B.5.5 Cb-1041 181 B.5.8 Cb-1256 181 B. 6.3

Cb-827 182 B.5.5 Cb-1042 182 B.5.8 Cb-1257 182 B. 6.3

Cb-828 183 B.5.5 Cb-1043 183 B.5.8 Cb-1258 183 B. 6.3

Cb-829 184 B.5.5 Cb-1044 184 B.5.8 Cb-1259 184 B. 6.3

Cb-830 185 B.5.5 Cb-1045 185 B.5.8 Cb-1260 185 B. 6.3

Cb-831 186 B.5.5 Cb-1046 186 B.5.8 Cb-1261 186 B. 6.3

Cb-832 187 B.5.5 Cb-1047 187 B.5.8 Cb-1262 187 B. 6.3

Cb-833 188 B.5.5 Cb-1048 188 B.5.8 Cb-1263 188 B. 6.3

Cb-834 189 B.5.5 Cb-1049 189 B.5.8 Cb-1264 189 B. 6.3

Cb-835 190 B.5.5 Cb-1050 190 B.5.8 Cb-1265 190 B. 6.3

Cb-836 191 B.5.5 Cb-1051 191 B.5.8 Cb-1266 191 B. 6.3

Cb-837 192 B.5.5 Cb-1052 192 B.5.8 Cb-1267 192 B. 6.3

Cb-838 193 B.5.5 Cb-1053 193 B.5.8 Cb-1268 193 B. 6.3

Cb-839 194 B.5.5 Cb-1054 194 B.5.8 Cb-1269 194 B. 6.3

Cb-840 195 B.5.5 Cb-1055 195 B.5.8 Cb-1270 195 B. 6.3

Cb-841 196 B.5.5 Cb-1056 196 B.5.8 Cb-1271 196 B. 6.3

Cb-842 197 B.5.5 Cb-1057 197 B.5.8 Cb-1272 197 B. 6.3

Cb-843 198 B.5.5 Cb-1058 198 B.5.8 Cb-1273 198 B. 6.3

Cb-844 199 B.5.5 Cb-1059 199 B.5.8 Cb-1274 199 B. 6.3

Cb-845 200 B.5.5 Cb-1060 200 B.5.8 Cb-1275 200 B. 6.3

Cb-846 201 B.5.5 Cb-1061 201 B.5.8 Cb-1276 201 B. 6.3

Cb-847 202 B.5.5 Cb-1062 202 B.5.8 Cb-1277 202 B. 6.3

Cb-848 203 B.5.5 Cb-1063 203 B.5.8 Cb-1278 203 B. 6.3

Cb-849 204 B.5.5 Cb-1064 204 B.5.8 Cb-1279 204 B. 6.3

Cb-850 205 B.5.5 Cb-1065 205 B.5.8 Cb-1280 205 B. 6.3

Cb-851 206 B.5.5 Cb-1066 206 B.5.8 Cb-1281 206 B. 6.3

Cb-852 207 B.5.5 Cb-1067 207 B.5.8 Cb-1282 207 B. 6.3

Cb-853 208 B.5.5 Cb-1068 208 B.5.8 Cb-1283 208 B. 6.3

Cb-854 209 B.5.5 Cb-1069 209 B.5.8 Cb-1284 209 B. 6.3

Cb-855 210 B.5.5 Cb-1070 210 B.5.8 Cb-1285 210 B. 6.3

Cb-856 21 1 B.5.5 Cb-1071 211 B.5.8 Cb-1286 211 B. 6.3

Cb-857 212 B.5.5 Cb-1072 212 B.5.8 Cb-1287 212 B. 6.3

Cb-858 213 B.5.5 Cb-1073 213 B.5.8 Cb-1288 213 B. 6.3

Cb-859 214 B.5.5 Cb-1074 214 B.5.8 Cb-1289 214 B. 6.3

Cb-860 215 B.5.5 Cb-1075 215 B.5.8 Cb-1290 215 B. 6.3

Cb-1291 1 B.15.12 Cb-1506 1 B.15.13 Cb-1721 1 B.17.1

Cb-1292 2 B.15.12 Cb-1507 2 B.15.13 Cb-1722 2 B.17.1

Cb-1293 3 B.15.12 Cb-1508 3 B.15.13 Cb-1723 3 B.17.1

Cb-1294 4 B.15.12 Cb-1509 4 B.15.13 Cb-1724 4 B.17.1

Cb-1295 5 B.15.12 Cb-1510 5 B.15.13 Cb-1725 5 B.17.1 Cb-1296 6 B.15.12 Cb-1511 6 B.15.13 Cb-1726 6 B.17.1

Cb-1297 7 B.15.12 Cb-1512 7 B.15.13 Cb-1727 7 B.17.1

Cb-1298 8 B.15.12 Cb-1513 8 B.15.13 Cb-1728 8 B.17.1

Cb-1299 9 B.15.12 Cb-1514 9 B.15.13 Cb-1729 9 B.17.1

Cb-1300 10 B.15.12 Cb-1515 10 B.15.13 Cb-1730 10 B.17.1

Cb-1301 1 1 B.15.12 Cb-1516 1 1 B.15.13 Cb-1731 1 1 B.17.1

Cb-1302 12 B.15.12 Cb-1517 12 B.15.13 Cb-1732 12 B.17.1

Cb-1303 13 B.15.12 Cb-1518 13 B.15.13 Cb-1733 13 B.17.1

Cb-1304 14 B.15.12 Cb-1519 14 B.15.13 Cb-1734 14 B.17.1

Cb-1305 15 B.15.12 Cb-1520 15 B.15.13 Cb-1735 15 B.17.1

Cb-1306 16 B.15.12 Cb-1521 16 B.15.13 Cb-1736 16 B.17.1

Cb-1307 17 B.15.12 Cb-1522 17 B.15.13 Cb-1737 17 B.17.1

Cb-1308 18 B.15.12 Cb-1523 18 B.15.13 Cb-1738 18 B.17.1

Cb-1309 19 B.15.12 Cb-1524 19 B.15.13 Cb-1739 19 B.17.1

Cb-1310 20 B.15.12 Cb-1525 20 B.15.13 Cb-1740 20 B.17.1

Cb-131 1 21 B.15.12 Cb-1526 21 B.15.13 Cb-1741 21 B.17.1

Cb-1312 22 B.15.12 Cb-1527 22 B.15.13 Cb-1742 22 B.17.1

Cb-1313 23 B.15.12 Cb-1528 23 B.15.13 Cb-1743 23 B.17.1

Cb-1314 24 B.15.12 Cb-1529 24 B.15.13 Cb-1744 24 B.17.1

Cb-1315 25 B.15.12 Cb-1530 25 B.15.13 Cb-1745 25 B.17.1

Cb-1316 26 B.15.12 Cb-1531 26 B.15.13 Cb-1746 26 B.17.1

Cb-1317 27 B.15.12 Cb-1532 27 B.15.13 Cb-1747 27 B.17.1

Cb-1318 28 B.15.12 Cb-1533 28 B.15.13 Cb-1748 28 B.17.1

Cb-1319 29 B.15.12 Cb-1534 29 B.15.13 Cb-1749 29 B.17.1

Cb-1320 30 B.15.12 Cb-1535 30 B.15.13 Cb-1750 30 B.17.1

Cb-1321 31 B.15.12 Cb-1536 31 B.15.13 Cb-1751 31 B.17.1

Cb-1322 32 B.15.12 Cb-1537 32 B.15.13 Cb-1752 32 B.17.1

Cb-1323 33 B.15.12 Cb-1538 33 B.15.13 Cb-1753 33 B.17.1

Cb-1324 34 B.15.12 Cb-1539 34 B.15.13 Cb-1754 34 B.17.1

Cb-1325 35 B.15.12 Cb-1540 35 B.15.13 Cb-1755 35 B.17.1

Cb-1326 36 B.15.12 Cb-1541 36 B.15.13 Cb-1756 36 B.17.1

Cb-1327 37 B.15.12 Cb-1542 37 B.15.13 Cb-1757 37 B.17.1

Cb-1328 38 B.15.12 Cb-1543 38 B.15.13 Cb-1758 38 B.17.1

Cb-1329 39 B.15.12 Cb-1544 39 B.15.13 Cb-1759 39 B.17.1

Cb-1330 40 B.15.12 Cb-1545 40 B.15.13 Cb-1760 40 B.17.1

Cb-1331 41 B.15.12 Cb-1546 41 B.15.13 Cb-1761 41 B.17.1

Cb-1332 42 B.15.12 Cb-1547 42 B.15.13 Cb-1762 42 B.17.1

Cb-1333 43 B.15.12 Cb-1548 43 B.15.13 Cb-1763 43 B.17.1

Cb-1334 44 B.15.12 Cb-1549 44 B.15.13 Cb-1764 44 B.17.1

Cb-1335 45 B.15.12 Cb-1550 45 B.15.13 Cb-1765 45 B.17.1

Cb-1336 46 B.15.12 Cb-1551 46 B.15.13 Cb-1766 46 B.17.1

Cb-1337 47 B.15.12 Cb-1552 47 B.15.13 Cb-1767 47 B.17.1

Cb-1338 48 B.15.12 Cb-1553 48 B.15.13 Cb-1768 48 B.17.1 Cb-1339 49 B.15.12 Cb-1554 49 B.15.13 Cb-1769 49 B.17.1

Cb-1340 50 B.15.12 Cb-1555 50 B.15.13 Cb-1770 50 B.17.1

Cb-1341 51 B.15.12 Cb-1556 51 B.15.13 Cb-1771 51 B.17.1

Cb-1342 52 B.15.12 Cb-1557 52 B.15.13 Cb-1772 52 B.17.1

Cb-1343 53 B.15.12 Cb-1558 53 B.15.13 Cb-1773 53 B.17.1

Cb-1344 54 B.15.12 Cb-1559 54 B.15.13 Cb-1774 54 B.17.1

Cb-1345 55 B.15.12 Cb-1560 55 B.15.13 Cb-1775 55 B.17.1

Cb-1346 56 B.15.12 Cb-1561 56 B.15.13 Cb-1776 56 B.17.1

Cb-1347 57 B.15.12 Cb-1562 57 B.15.13 Cb-1777 57 B.17.1

Cb-1348 58 B.15.12 Cb-1563 58 B.15.13 Cb-1778 58 B.17.1

Cb-1349 59 B.15.12 Cb-1564 59 B.15.13 Cb-1779 59 B.17.1

Cb-1350 60 B.15.12 Cb-1565 60 B.15.13 Cb-1780 60 B.17.1

Cb-1351 61 B.15.12 Cb-1566 61 B.15.13 Cb-1781 61 B.17.1

Cb-1352 62 B.15.12 Cb-1567 62 B.15.13 Cb-1782 62 B.17.1

Cb-1353 63 B.15.12 Cb-1568 63 B.15.13 Cb-1783 63 B.17.1

Cb-1354 64 B.15.12 Cb-1569 64 B.15.13 Cb-1784 64 B.17.1

Cb-1355 65 B.15.12 Cb-1570 65 B.15.13 Cb-1785 65 B.17.1

Cb-1356 66 B.15.12 Cb-1571 66 B.15.13 Cb-1786 66 B.17.1

Cb-1357 67 B.15.12 Cb-1572 67 B.15.13 Cb-1787 67 B.17.1

Cb-1358 68 B.15.12 Cb-1573 68 B.15.13 Cb-1788 68 B.17.1

Cb-1359 69 B.15.12 Cb-1574 69 B.15.13 Cb-1789 69 B.17.1

Cb-1360 70 B.15.12 Cb-1575 70 B.15.13 Cb-1790 70 B.17.1

Cb-1361 71 B.15.12 Cb-1576 71 B.15.13 Cb-1791 71 B.17.1

Cb-1362 72 B.15.12 Cb-1577 72 B.15.13 Cb-1792 72 B.17.1

Cb-1363 73 B.15.12 Cb-1578 73 B.15.13 Cb-1793 73 B.17.1

Cb-1364 74 B.15.12 Cb-1579 74 B.15.13 Cb-1794 74 B.17.1

Cb-1365 75 B.15.12 Cb-1580 75 B.15.13 Cb-1795 75 B.17.1

Cb-1366 76 B.15.12 Cb-1581 76 B.15.13 Cb-1796 76 B.17.1

Cb-1367 77 B.15.12 Cb-1582 77 B.15.13 Cb-1797 77 B.17.1

Cb-1368 78 B.15.12 Cb-1583 78 B.15.13 Cb-1798 78 B.17.1

Cb-1369 79 B.15.12 Cb-1584 79 B.15.13 Cb-1799 79 B.17.1

Cb-1370 80 B.15.12 Cb-1585 80 B.15.13 Cb-1800 80 B.17.1

Cb-1371 81 B.15.12 Cb-1586 81 B.15.13 Cb-1801 81 B.17.1

Cb-1372 82 B.15.12 Cb-1587 82 B.15.13 Cb-1802 82 B.17.1

Cb-1373 83 B.15.12 Cb-1588 83 B.15.13 Cb-1803 83 B.17.1

Cb-1374 84 B.15.12 Cb-1589 84 B.15.13 Cb-1804 84 B.17.1

Cb-1375 85 B.15.12 Cb-1590 85 B.15.13 Cb-1805 85 B.17.1

Cb-1376 86 B.15.12 Cb-1591 86 B.15.13 Cb-1806 86 B.17.1

Cb-1377 87 B.15.12 Cb-1592 87 B.15.13 Cb-1807 87 B.17.1

Cb-1378 88 B.15.12 Cb-1593 88 B.15.13 Cb-1808 88 B.17.1

Cb-1379 89 B.15.12 Cb-1594 89 B.15.13 Cb-1809 89 B.17.1

Cb-1380 90 B.15.12 Cb-1595 90 B.15.13 Cb-1810 90 B.17.1

Cb-1381 91 B.15.12 Cb-1596 91 B.15.13 Cb-1811 91 B.17.1 Cb-1382 92 B.15.12 Cb-1597 92 B.15.13 Cb-1812 92 B.17.1

Cb-1383 93 B.15.12 Cb-1598 93 B.15.13 Cb-1813 93 B.17.1

Cb-1384 94 B.15.12 Cb-1599 94 B.15.13 Cb-1814 94 B.17.1

Cb-1385 95 B.15.12 Cb-1600 95 B.15.13 Cb-1815 95 B.17.1

Cb-1386 96 B.15.12 Cb-1601 96 B.15.13 Cb-1816 96 B.17.1

Cb-1387 97 B.15.12 Cb-1602 97 B.15.13 Cb-1817 97 B.17.1

Cb-1388 98 B.15.12 Cb-1603 98 B.15.13 Cb-1818 98 B.17.1

Cb-1389 99 B.15.12 Cb-1604 99 B.15.13 Cb-1819 99 B.17.1

Cb-1390 100 B.15.12 Cb-1605 100 B.15.13 Cb-1820 100 B.17.1

Cb-1391 101 B.15.12 Cb-1606 101 B.15.13 Cb-1821 101 B.17.1

Cb-1392 102 B.15.12 Cb-1607 102 B.15.13 Cb-1822 102 B.17.1

Cb-1393 103 B.15.12 Cb-1608 103 B.15.13 Cb-1823 103 B.17.1

Cb-1394 104 B.15.12 Cb-1609 104 B.15.13 Cb-1824 104 B.17.1

Cb-1395 105 B.15.12 Cb-1610 105 B.15.13 Cb-1825 105 B.17.1

Cb-1396 106 B.15.12 Cb-1611 106 B.15.13 Cb-1826 106 B.17.1

Cb-1397 107 B.15.12 Cb-1612 107 B.15.13 Cb-1827 107 B.17.1

Cb-1398 108 B.15.12 Cb-1613 108 B.15.13 Cb-1828 108 B.17.1

Cb-1399 109 B.15.12 Cb-1614 109 B.15.13 Cb-1829 109 B.17.1

Cb-1400 110 B.15.12 Cb-1615 1 10 B.15.13 Cb-1830 1 10 B.17.1

Cb-1401 11 1 B.15.12 Cb-1616 1 11 B.15.13 Cb-1831 1 11 B.17.1

Cb-1402 112 B.15.12 Cb-1617 1 12 B.15.13 Cb-1832 1 12 B.17.1

Cb-1403 113 B.15.12 Cb-1618 1 13 B.15.13 Cb-1833 1 13 B.17.1

Cb-1404 114 B.15.12 Cb-1619 1 14 B.15.13 Cb-1834 1 14 B.17.1

Cb-1405 115 B.15.12 Cb-1620 1 15 B.15.13 Cb-1835 1 15 B.17.1

Cb-1406 116 B.15.12 Cb-1621 1 16 B.15.13 Cb-1836 1 16 B.17.1

Cb-1407 117 B.15.12 Cb-1622 1 17 B.15.13 Cb-1837 1 17 B.17.1

Cb-1408 118 B.15.12 Cb-1623 1 18 B.15.13 Cb-1838 1 18 B.17.1

Cb-1409 119 B.15.12 Cb-1624 1 19 B.15.13 Cb-1839 1 19 B.17.1

Cb-1410 120 B.15.12 Cb-1625 120 B.15.13 Cb-1840 120 B.17.1

Cb-141 1 121 B.15.12 Cb-1626 121 B.15.13 Cb-1841 121 B.17.1

Cb-1412 122 B.15.12 Cb-1627 122 B.15.13 Cb-1842 122 B.17.1

Cb-1413 123 B.15.12 Cb-1628 123 B.15.13 Cb-1843 123 B.17.1

Cb-1414 124 B.15.12 Cb-1629 124 B.15.13 Cb-1844 124 B.17.1

Cb-1415 125 B.15.12 Cb-1630 125 B.15.13 Cb-1845 125 B.17.1

Cb-1416 126 B.15.12 Cb-1631 126 B.15.13 Cb-1846 126 B.17.1

Cb-1417 127 B.15.12 Cb-1632 127 B.15.13 Cb-1847 127 B.17.1

Cb-1418 128 B.15.12 Cb-1633 128 B.15.13 Cb-1848 128 B.17.1

Cb-1419 129 B.15.12 Cb-1634 129 B.15.13 Cb-1849 129 B.17.1

Cb-1420 130 B.15.12 Cb-1635 130 B.15.13 Cb-1850 130 B.17.1

Cb-1421 131 B.15.12 Cb-1636 131 B.15.13 Cb-1851 131 B.17.1

Cb-1422 132 B.15.12 Cb-1637 132 B.15.13 Cb-1852 132 B.17.1

Cb-1423 133 B.15.12 Cb-1638 133 B.15.13 Cb-1853 133 B.17.1

Cb-1424 134 B.15.12 Cb-1639 134 B.15.13 Cb-1854 134 B.17.1 Cb-1425 135 B.15.12 Cb-1640 135 B.15.13 Cb-1855 135 B.17.1

Cb-1426 136 B.15.12 Cb-1641 136 B.15.13 Cb-1856 136 B.17.1

Cb-1427 137 B.15.12 Cb-1642 137 B.15.13 Cb-1857 137 B.17.1

Cb-1428 138 B.15.12 Cb-1643 138 B.15.13 Cb-1858 138 B.17.1

Cb-1429 139 B.15.12 Cb-1644 139 B.15.13 Cb-1859 139 B.17.1

Cb-1430 140 B.15.12 Cb-1645 140 B.15.13 Cb-1860 140 B.17.1

Cb-1431 141 B.15.12 Cb-1646 141 B.15.13 Cb-1861 141 B.17.1

Cb-1432 142 B.15.12 Cb-1647 142 B.15.13 Cb-1862 142 B.17.1

Cb-1433 143 B.15.12 Cb-1648 143 B.15.13 Cb-1863 143 B.17.1

Cb-1434 144 B.15.12 Cb-1649 144 B.15.13 Cb-1864 144 B.17.1

Cb-1435 145 B.15.12 Cb-1650 145 B.15.13 Cb-1865 145 B.17.1

Cb-1436 146 B.15.12 Cb-1651 146 B.15.13 Cb-1866 146 B.17.1

Cb-1437 147 B.15.12 Cb-1652 147 B.15.13 Cb-1867 147 B.17.1

Cb-1438 148 B.15.12 Cb-1653 148 B.15.13 Cb-1868 148 B.17.1

Cb-1439 149 B.15.12 Cb-1654 149 B.15.13 Cb-1869 149 B.17.1

Cb-1440 150 B.15.12 Cb-1655 150 B.15.13 Cb-1870 150 B.17.1

Cb-1441 151 B.15.12 Cb-1656 151 B.15.13 Cb-1871 151 B.17.1

Cb-1442 152 B.15.12 Cb-1657 152 B.15.13 Cb-1872 152 B.17.1

Cb-1443 153 B.15.12 Cb-1658 153 B.15.13 Cb-1873 153 B.17.1

Cb-1444 154 B.15.12 Cb-1659 154 B.15.13 Cb-1874 154 B.17.1

Cb-1445 155 B.15.12 Cb-1660 155 B.15.13 Cb-1875 155 B.17.1

Cb-1446 156 B.15.12 Cb-1661 156 B.15.13 Cb-1876 156 B.17.1

Cb-1447 157 B.15.12 Cb-1662 157 B.15.13 Cb-1877 157 B.17.1

Cb-1448 158 B.15.12 Cb-1663 158 B.15.13 Cb-1878 158 B.17.1

Cb-1449 159 B.15.12 Cb-1664 159 B.15.13 Cb-1879 159 B.17.1

Cb-1450 160 B.15.12 Cb-1665 160 B.15.13 Cb-1880 160 B.17.1

Cb-1451 161 B.15.12 Cb-1666 161 B.15.13 Cb-1881 161 B.17.1

Cb-1452 162 B.15.12 Cb-1667 162 B.15.13 Cb-1882 162 B.17.1

Cb-1453 163 B.15.12 Cb-1668 163 B.15.13 Cb-1883 163 B.17.1

Cb-1454 164 B.15.12 Cb-1669 164 B.15.13 Cb-1884 164 B.17.1

Cb-1455 165 B.15.12 Cb-1670 165 B.15.13 Cb-1885 165 B.17.1

Cb-1456 166 B.15.12 Cb-1671 166 B.15.13 Cb-1886 166 B.17.1

Cb-1457 167 B.15.12 Cb-1672 167 B.15.13 Cb-1887 167 B.17.1

Cb-1458 168 B.15.12 Cb-1673 168 B.15.13 Cb-1888 168 B.17.1

Cb-1459 169 B.15.12 Cb-1674 169 B.15.13 Cb-1889 169 B.17.1

Cb-1460 170 B.15.12 Cb-1675 170 B.15.13 Cb-1890 170 B.17.1

Cb-1461 171 B.15.12 Cb-1676 171 B.15.13 Cb-1891 171 B.17.1

Cb-1462 172 B.15.12 Cb-1677 172 B.15.13 Cb-1892 172 B.17.1

Cb-1463 173 B.15.12 Cb-1678 173 B.15.13 Cb-1893 173 B.17.1

Cb-1464 174 B.15.12 Cb-1679 174 B.15.13 Cb-1894 174 B.17.1

Cb-1465 175 B.15.12 Cb-1680 175 B.15.13 Cb-1895 175 B.17.1

Cb-1466 176 B.15.12 Cb-1681 176 B.15.13 Cb-1896 176 B.17.1

Cb-1467 177 B.15.12 Cb-1682 177 B.15.13 Cb-1897 177 B.17.1 Cb-1468 178 B.15.12 Cb-1683 178 B.15.13 Cb-1898 178 B.17.1

Cb-1469 179 B.15.12 Cb-1684 179 B.15.13 Cb-1899 179 B.17.1

Cb-1470 180 B.15.12 Cb-1685 180 B.15.13 Cb-1900 180 B.17.1

Cb-1471 181 B.15.12 Cb-1686 181 B.15.13 Cb-1901 181 B.17.1

Cb-1472 182 B.15.12 Cb-1687 182 B.15.13 Cb-1902 182 B.17.1

Cb-1473 183 B.15.12 Cb-1688 183 B.15.13 Cb-1903 183 B.17.1

Cb-1474 184 B.15.12 Cb-1689 184 B.15.13 Cb-1904 184 B.17.1

Cb-1475 185 B.15.12 Cb-1690 185 B.15.13 Cb-1905 185 B.17.1

Cb-1476 186 B.15.12 Cb-1691 186 B.15.13 Cb-1906 186 B.17.1

Cb-1477 187 B.15.12 Cb-1692 187 B.15.13 Cb-1907 187 B.17.1

Cb-1478 188 B.15.12 Cb-1693 188 B.15.13 Cb-1908 188 B.17.1

Cb-1479 189 B.15.12 Cb-1694 189 B.15.13 Cb-1909 189 B.17.1

Cb-1480 190 B.15.12 Cb-1695 190 B.15.13 Cb-1910 190 B.17.1

Cb-1481 191 B.15.12 Cb-1696 191 B.15.13 Cb-1911 191 B.17.1

Cb-1482 192 B.15.12 Cb-1697 192 B.15.13 Cb-1912 192 B.17.1

Cb-1483 193 B.15.12 Cb-1698 193 B.15.13 Cb-1913 193 B.17.1

Cb-1484 194 B.15.12 Cb-1699 194 B.15.13 Cb-1914 194 B.17.1

Cb-1485 195 B.15.12 Cb-1700 195 B.15.13 Cb-1915 195 B.17.1

Cb-1486 196 B.15.12 Cb-1701 196 B.15.13 Cb-1916 196 B.17.1

Cb-1487 197 B.15.12 Cb-1702 197 B.15.13 Cb-1917 197 B.17.1

Cb-1488 198 B.15.12 Cb-1703 198 B.15.13 Cb-1918 198 B.17.1

Cb-1489 199 B.15.12 Cb-1704 199 B.15.13 Cb-1919 199 B.17.1

Cb-1490 200 B.15.12 Cb-1705 200 B.15.13 Cb-1920 200 B.17.1

Cb-1491 201 B.15.12 Cb-1706 201 B.15.13 Cb-1921 201 B.17.1

Cb-1492 202 B.15.12 Cb-1707 202 B.15.13 Cb-1922 202 B.17.1

Cb-1493 203 B.15.12 Cb-1708 203 B.15.13 Cb-1923 203 B.17.1

Cb-1494 204 B.15.12 Cb-1709 204 B.15.13 Cb-1924 204 B.17.1

Cb-1495 205 B.15.12 Cb-1710 205 B.15.13 Cb-1925 205 B.17.1

Cb-1496 206 B.15.12 Cb-1711 206 B.15.13 Cb-1926 206 B.17.1

Cb-1497 207 B.15.12 Cb-1712 207 B.15.13 Cb-1927 207 B.17.1

Cb-1498 208 B.15.12 Cb-1713 208 B.15.13 Cb-1928 208 B.17.1

Cb-1499 209 B.15.12 Cb-1714 209 B.15.13 Cb-1929 209 B.17.1

Cb-1500 210 B.15.12 Cb-1715 210 B.15.13 Cb-1930 210 B.17.1

Cb-1501 21 1 B.15.12 Cb-1716 211 B.15.13 Cb-1931 211 B.17.1

Cb-1502 212 B.15.12 Cb-1717 212 B.15.13 Cb-1932 212 B.17.1

Cb-1503 213 B.15.12 Cb-1718 213 B.15.13 Cb-1933 213 B.17.1

Cb-1504 214 B.15.12 Cb-1719 214 B.15.13 Cb-1934 214 B.17.1

Cb-1505 215 B.15.12 Cb-1720 215 B.15.13 Cb-1935 215 B.17.1

Cb-1936 1 B.1.1 Cb-2151 1 B.1.4

Cb-1937 2 B.1.1 Cb-2152 2 B.1.4

Cb-1938 3 B.1.1 Cb-2153 3 B.1.4

Cb-1939 4 B.1.1 Cb-2154 4 B.1.4

Cb-1940 5 B.1.1 Cb-2155 5 B.1.4 Cb-1941 6 B.1.1 Cb-2156 6 B.1.4

Cb-1942 7 B.1.1 Cb-2157 7 B.1.4

Cb-1943 8 B.1.1 Cb-2158 8 B.1.4

Cb-1944 9 B.1.1 Cb-2159 9 B.1.4

Cb-1945 10 B.1.1 Cb-2160 10 B.1.4

Cb-1946 11 B.1.1 Cb-2161 11 B.1.4

Cb-1947 12 B.1.1 Cb-2162 12 B.1.4

Cb-1948 13 B.1.1 Cb-2163 13 B.1.4

Cb-1949 14 B.1.1 Cb-2164 14 B.1.4

Cb-1950 15 B.1.1 Cb-2165 15 B.1.4

Cb-1951 16 B.1.1 Cb-2166 16 B.1.4

Cb-1952 17 B.1.1 Cb-2167 17 B.1.4

Cb-1953 18 B.1.1 Cb-2168 18 B.1.4

Cb-1954 19 B.1.1 Cb-2169 19 B.1.4

Cb-1955 20 B.1.1 Cb-2170 20 B.1.4

Cb-1956 21 B.1.1 Cb-2171 21 B.1.4

Cb-1957 22 B.1.1 Cb-2172 22 B.1.4

Cb-1958 23 B.1.1 Cb-2173 23 B.1.4

Cb-1959 24 B.1.1 Cb-2174 24 B.1.4

Cb-1960 25 B.1.1 Cb-2175 25 B.1.4

Cb-1961 26 B.1.1 Cb-2176 26 B.1.4

Cb-1962 27 B.1.1 Cb-2177 27 B.1.4

Cb-1963 28 B.1.1 Cb-2178 28 B.1.4

Cb-1964 29 B.1.1 Cb-2179 29 B.1.4

Cb-1965 30 B.1.1 Cb-2180 30 B.1.4

Cb-1966 31 B.1.1 Cb-2181 31 B.1.4

Cb-1967 32 B.1.1 Cb-2182 32 B.1.4

Cb-1968 33 B.1.1 Cb-2183 33 B.1.4

Cb-1969 34 B.1.1 Cb-2184 34 B.1.4

Cb-1970 35 B.1.1 Cb-2185 35 B.1.4

Cb-1971 36 B.1.1 Cb-2186 36 B.1.4

Cb-1972 37 B.1.1 Cb-2187 37 B.1.4

Cb-1973 38 B.1.1 Cb-2188 38 B.1.4

Cb-1974 39 B.1.1 Cb-2189 39 B.1.4

Cb-1975 40 B.1.1 Cb-2190 40 B.1.4

Cb-1976 41 B.1.1 Cb-2191 41 B.1.4

Cb-1977 42 B.1.1 Cb-2192 42 B.1.4

Cb-1978 43 B.1.1 Cb-2193 43 B.1.4

Cb-1979 44 B.1.1 Cb-2194 44 B.1.4

Cb-1980 45 B.1.1 Cb-2195 45 B.1.4

Cb-1981 46 B.1.1 Cb-2196 46 B.1.4

Cb-1982 47 B.1.1 Cb-2197 47 B.1.4

Cb-1983 48 B.1.1 Cb-2198 48 B.1.4 Cb-1984 49 B.1.1 Cb-2199 49 B.1.4

Cb-1985 50 B.1.1 Cb-2200 50 B.1.4

Cb-1986 51 B.1.1 Cb-2201 51 B.1.4

Cb-1987 52 B.1.1 Cb-2202 52 B.1.4

Cb-1988 53 B.1.1 Cb-2203 53 B.1.4

Cb-1989 54 B.1.1 Cb-2204 54 B.1.4

Cb-1990 55 B.1.1 Cb-2205 55 B.1.4

Cb-1991 56 B.1.1 Cb-2206 56 B.1.4

Cb-1992 57 B.1.1 Cb-2207 57 B.1.4

Cb-1993 58 B.1.1 Cb-2208 58 B.1.4

Cb-1994 59 B.1.1 Cb-2209 59 B.1.4

Cb-1995 60 B.1.1 Cb-2210 60 B.1.4

Cb-1996 61 B.1.1 Cb-2211 61 B.1.4

Cb-1997 62 B.1.1 Cb-2212 62 B.1.4

Cb-1998 63 B.1.1 Cb-2213 63 B.1.4

Cb-1999 64 B.1.1 Cb-2214 64 B.1.4

Cb-2000 65 B.1.1 Cb-2215 65 B.1.4

Cb-2001 66 B.1.1 Cb-2216 66 B.1.4

Cb-2002 67 B.1.1 Cb-2217 67 B.1.4

Cb-2003 68 B.1.1 Cb-2218 68 B.1.4

Cb-2004 69 B.1.1 Cb-2219 69 B.1.4

Cb-2005 70 B.1.1 Cb-2220 70 B.1.4

Cb-2006 71 B.1.1 Cb-2221 71 B.1.4

Cb-2007 72 B.1.1 Cb-2222 72 B.1.4

Cb-2008 73 B.1.1 Cb-2223 73 B.1.4

Cb-2009 74 B.1.1 Cb-2224 74 B.1.4

Cb-2010 75 B.1.1 Cb-2225 75 B.1.4

Cb-2011 76 B.1.1 Cb-2226 76 B.1.4

Cb-2012 77 B.1.1 Cb-2227 77 B.1.4

Cb-2013 78 B.1.1 Cb-2228 78 B.1.4

Cb-2014 79 B.1.1 Cb-2229 79 B.1.4

Cb-2015 80 B.1.1 Cb-2230 80 B.1.4

Cb-2016 81 B.1.1 Cb-2231 81 B.1.4

Cb-2017 82 B.1.1 Cb-2232 82 B.1.4

Cb-2018 83 B.1.1 Cb-2233 83 B.1.4

Cb-2019 84 B.1.1 Cb-2234 84 B.1.4

Cb-2020 85 B.1.1 Cb-2235 85 B.1.4

Cb-2021 86 B.1.1 Cb-2236 86 B.1.4

Cb-2022 87 B.1.1 Cb-2237 87 B.1.4

Cb-2023 88 B.1.1 Cb-2238 88 B.1.4

Cb-2024 89 B.1.1 Cb-2239 89 B.1.4

Cb-2025 90 B.1.1 Cb-2240 90 B.1.4

Cb-2026 91 B.1.1 Cb-2241 91 B.1.4 Cb-2027 92 B.1.1 Cb-2242 92 B.1.4

Cb-2028 93 B.1.1 Cb-2243 93 B.1.4

Cb-2029 94 B.1.1 Cb-2244 94 B.1.4

Cb-2030 95 B.1.1 Cb-2245 95 B.1.4

Cb-2031 96 B.1.1 Cb-2246 96 B.1.4

Cb-2032 97 B.1.1 Cb-2247 97 B.1.4

Cb-2033 98 B.1.1 Cb-2248 98 B.1.4

Cb-2034 99 B.1.1 Cb-2249 99 B.1.4

Cb-2035 100 B.1.1 Cb-2250 100 B.1.4

Cb-2036 101 B.1.1 Cb-2251 101 B.1.4

Cb-2037 102 B.1.1 Cb-2252 102 B.1.4

Cb-2038 103 B.1.1 Cb-2253 103 B.1.4

Cb-2039 104 B.1.1 Cb-2254 104 B.1.4

Cb-2040 105 B.1.1 Cb-2255 105 B.1.4

Cb-2041 106 B.1.1 Cb-2256 106 B.1.4

Cb-2042 107 B.1.1 Cb-2257 107 B.1.4

Cb-2043 108 B.1.1 Cb-2258 108 B.1.4

Cb-2044 109 B.1.1 Cb-2259 109 B.1.4

Cb-2045 110 B.1.1 Cb-2260 110 B.1.4

Cb-2046 111 B.1.1 Cb-2261 111 B.1.4

Cb-2047 112 B.1.1 Cb-2262 112 B.1.4

Cb-2048 113 B.1.1 Cb-2263 113 B.1.4

Cb-2049 114 B.1.1 Cb-2264 114 B.1.4

Cb-2050 115 B.1.1 Cb-2265 115 B.1.4

Cb-2051 116 B.1.1 Cb-2266 116 B.1.4

Cb-2052 117 B.1.1 Cb-2267 117 B.1.4

Cb-2053 118 B.1.1 Cb-2268 118 B.1.4

Cb-2054 119 B.1.1 Cb-2269 119 B.1.4

Cb-2055 120 B.1.1 Cb-2270 120 B.1.4

Cb-2056 121 B.1.1 Cb-2271 121 B.1.4

Cb-2057 122 B.1.1 Cb-2272 122 B.1.4

Cb-2058 123 B.1.1 Cb-2273 123 B.1.4

Cb-2059 124 B.1.1 Cb-2274 124 B.1.4

Cb-2060 125 B.1.1 Cb-2275 125 B.1.4

Cb-2061 126 B.1.1 Cb-2276 126 B.1.4

Cb-2062 127 B.1.1 Cb-2277 127 B.1.4

Cb-2063 128 B.1.1 Cb-2278 128 B.1.4

Cb-2064 129 B.1.1 Cb-2279 129 B.1.4

Cb-2065 130 B.1.1 Cb-2280 130 B.1.4

Cb-2066 131 B.1.1 Cb-2281 131 B.1.4

Cb-2067 132 B.1.1 Cb-2282 132 B.1.4

Cb-2068 133 B.1.1 Cb-2283 133 B.1.4

Cb-2069 134 B.1.1 Cb-2284 134 B.1.4 Cb-2070 135 B.1.1 Cb-2285 135 B.1.4

Cb-2071 136 B.1.1 Cb-2286 136 B.1.4

Cb-2072 137 B.1.1 Cb-2287 137 B.1.4

Cb-2073 138 B.1.1 Cb-2288 138 B.1.4

Cb-2074 139 B.1.1 Cb-2289 139 B.1.4

Cb-2075 140 B.1.1 Cb-2290 140 B.1.4

Cb-2076 141 B.1.1 Cb-2291 141 B.1.4

Cb-2077 142 B.1.1 Cb-2292 142 B.1.4

Cb-2078 143 B.1.1 Cb-2293 143 B.1.4

Cb-2079 144 B.1.1 Cb-2294 144 B.1.4

Cb-2080 145 B.1.1 Cb-2295 145 B.1.4

Cb-2081 146 B.1.1 Cb-2296 146 B.1.4

Cb-2082 147 B.1.1 Cb-2297 147 B.1.4

Cb-2083 148 B.1.1 Cb-2298 148 B.1.4

Cb-2084 149 B.1.1 Cb-2299 149 B.1.4

Cb-2085 150 B.1.1 Cb-2300 150 B.1.4

Cb-2086 151 B.1.1 Cb-2301 151 B.1.4

Cb-2087 152 B.1.1 Cb-2302 152 B.1.4

Cb-2088 153 B.1.1 Cb-2303 153 B.1.4

Cb-2089 154 B.1.1 Cb-2304 154 B.1.4

Cb-2090 155 B.1.1 Cb-2305 155 B.1.4

Cb-2091 156 B.1.1 Cb-2306 156 B.1.4

Cb-2092 157 B.1.1 Cb-2307 157 B.1.4

Cb-2093 158 B.1.1 Cb-2308 158 B.1.4

Cb-2094 159 B.1.1 Cb-2309 159 B.1.4

Cb-2095 160 B.1.1 Cb-2310 160 B.1.4

Cb-2096 161 B.1.1 Cb-2311 161 B.1.4

Cb-2097 162 B.1.1 Cb-2312 162 B.1.4

Cb-2098 163 B.1.1 Cb-2313 163 B.1.4

Cb-2099 164 B.1.1 Cb-2314 164 B.1.4

Cb-2100 165 B.1.1 Cb-2315 165 B.1.4

Cb-2101 166 B.1.1 Cb-2316 166 B.1.4

Cb-2102 167 B.1.1 Cb-2317 167 B.1.4

Cb-2103 168 B.1.1 Cb-2318 168 B.1.4

Cb-2104 169 B.1.1 Cb-2319 169 B.1.4

Cb-2105 170 B.1.1 Cb-2320 170 B.1.4

Cb-2106 171 B.1.1 Cb-2321 171 B.1.4

Cb-2107 172 B.1.1 Cb-2322 172 B.1.4

Cb-2108 173 B.1.1 Cb-2323 173 B.1.4

Cb-2109 174 B.1.1 Cb-2324 174 B.1.4

Cb-2110 175 B.1.1 Cb-2325 175 B.1.4

Cb-2111 176 B.1.1 Cb-2326 176 B.1.4

Cb-2112 177 B.1.1 Cb-2327 177 B.1.4 Cb-21 13 178 B.1.1 Cb-2328 178 B.1.4

Cb-21 14 179 B.1.1 Cb-2329 179 B.1.4

Cb-21 15 180 B.1.1 Cb-2330 180 B.1.4

Cb-21 16 181 B.1.1 Cb-2331 181 B.1.4

Cb-21 17 182 B.1.1 Cb-2332 182 B.1.4

Cb-21 18 183 B.1.1 Cb-2333 183 B.1.4

Cb-21 19 184 B.1.1 Cb-2334 184 B.1.4

Cb-2120 185 B.1.1 Cb-2335 185 B.1.4

Cb-2121 186 B.1.1 Cb-2336 186 B.1.4

Cb-2122 187 B.1.1 Cb-2337 187 B.1.4

Cb-2123 188 B.1.1 Cb-2338 188 B.1.4

Cb-2124 189 B.1.1 Cb-2339 189 B.1.4

Cb-2125 190 B.1.1 Cb-2340 190 B.1.4

Cb-2126 191 B.1.1 Cb-2341 191 B.1.4

Cb-2127 192 B.1.1 Cb-2342 192 B.1.4

Cb-2128 193 B.1.1 Cb-2343 193 B.1.4

Cb-2129 194 B.1.1 Cb-2344 194 B.1.4

Cb-2130 195 B.1.1 Cb-2345 195 B.1.4

Cb-2131 196 B.1.1 Cb-2346 196 B.1.4

Cb-2132 197 B.1.1 Cb-2347 197 B.1.4

Cb-2133 198 B.1.1 Cb-2348 198 B.1.4

Cb-2134 199 B.1.1 Cb-2349 199 B.1.4

Cb-2135 200 B.1.1 Cb-2350 200 B.1.4

Cb-2136 201 B.1.1 Cb-2351 201 B.1.4

Cb-2137 202 B.1.1 Cb-2352 202 B.1.4

Cb-2138 203 B.1.1 Cb-2353 203 B.1.4

Cb-2139 204 B.1.1 Cb-2354 204 B.1.4

Cb-2140 205 B.1.1 Cb-2355 205 B.1.4

Cb-2141 206 B.1.1 Cb-2356 206 B.1.4

Cb-2142 207 B.1.1 Cb-2357 207 B.1.4

Cb-2143 208 B.1.1 Cb-2358 208 B.1.4

Cb-2144 209 B.1.1 Cb-2359 209 B.1.4

Cb-2145 210 B.1.1 Cb-2360 210 B.1.4

Cb-2146 21 1 B.1.1 Cb-2361 211 B.1.4

Cb-2147 212 B.1.1 Cb-2362 212 B.1.4

Cb-2148 213 B.1.1 Cb-2363 213 B.1.4

Cb-2149 214 B.1.1 Cb-2364 214 B.1.4

Cb-2150 215 B.1.1 Cb-2365 215 B.1.4

Accordingly, the present invention furthermore relates to compositions comprising as compound I (component 1 , referrred to as "Co.1 ") a (thio)phosphoric acid triamide (T) as defined herein above and as compound II (component 2, referred to as "Co. 2") an insecticide and/or nemati- cide as defined herein, i.e. a combination of component 1 and 2. In preferred embodiments, such compositions may be selected from the component 1 of Table 3 in the column titled "Co. 1 " and from component 2 of Table 3 in the column titled "Co. 2". N-n-butylthiophosphoric acid tri- amide (NBPT) is referred to as "(W)". N-(n-propyl) thiophosphoric acid triamide (NPPT) or any mixtures comprising NBPT and NPPT, wherein N BPT is present in amounts of from 1 to 99.99 wt.%, more preferably from 10 to 99.9 wt.%, most preferably from 20 to 99 wt.%, particularly preferably from 30 to 98 wt.%, more particularly preferably from 40 to 95 wt.%, most particularly preferably from 50 to 90 wt.%, especially from 60 to 85 wt.%, especially preferably from 72 to 80 wt.%, for example from 74 to 77 wt.%, in each case based on the total weight of the

(thio)phosphoric acid triamides (T) contained in the composition (Q), is referred to as (Y). N-n- butylthiophosphoric acid triamide (NBPT) but not comprising any nitrification inhibitor of the compound of formula I is referred to as (Z), thus, all compositions or mixtures i355 to i531 do not comprise any nitrification inhibitor of the compound of formula I. NBPT and/or NPPT and additionally comprising a urea-containing fertilizer is referred to as "(U)", wherein such urea- containing fertilizer is preferably urea, formaldehyde urea, UAN, urea sulfur, stabilized urea, urea based NPK-fertilizers, or urea ammonium sulfate and is most preferably UAN. The application of the compositions or mixtures i1 to i708 can be carried out in a way that its individual components (for example Co. 1 and Co. 2, in case of i532 to i708 NBPT/NPPT and the urea- containing fertilizer and Co. 2) are applied either simultaneously or with a time lag as further specified below. Preferred embodiments thus include the specified combinations or composi- tions comprising component 1 and 2 as defined in the compositions or mixtures X1 to X708 of the following Table 3:

Mixt. Co.1 Co. 2 Mixt. Co.1 Co. 2 Mixt. Co.1 Co. 2 Mixt. Co.1 Co. 2

i1 (W) B.1.1 i178 CO B.1.1 Ϊ355 (Z) B.1.1 Ϊ532 (U) B.1.1 i2 (W) B.1.2 i179 00 B.1.2 Ϊ356 (Z) B.1.2 Ϊ533 (U) B.1.2 i3 (W) B.1.3 i180 00 B.1.3 Ϊ357 (Z) B.1.3 Ϊ534 (U) B.1.3 i4 (W) B.1.4 i181 (Y) B.1.4 Ϊ358 (Z) B.1.4 Ϊ535 (U) B.1.4 i5 (W) B.1.5 i182 (Y) B.1.5 Ϊ359 (Z) B.1.5 Ϊ536 (U) B.1.5 i6 (W) B.1.6 i183 (Y) B.1.6 Ϊ360 (Z) B.1.6 Ϊ537 (U) B.1.6 i7 (W) B.1.7 i184 (Y) B.1.7 i361 (Z) B.1.7 Ϊ538 (U) B.1.7 i8 (W) B.1.8 i185 (Y) B.1.8 Ϊ362 (Z) B.1.8 Ϊ539 (U) B.1.8 i9 (W) B.1.9 i186 (Y) B.1.9 Ϊ363 (Z) B.1.9 Ϊ540 (U) B.1.9

10 (W) B.1.10 i187 (Y) B.1.10 Ϊ364 (Z) B.1.10 Ϊ541 (U) B.1.10

1 1 (W) B.1.1 1 i188 (Y) B.1.11 Ϊ365 (Z) B.1.11 Ϊ542 (U) B.1.11

12 (W) B.1.12 i189 (Y) B.1.12 Ϊ366 (Z) B.1.12 Ϊ543 (U) B.1.12

13 (W) B.1.13 i190 (Y) B.1.13 Ϊ367 (Z) B.1.13 Ϊ544 (U) B.1.13

14 (W) B.1.14 i191 (Y) B.1.14 Ϊ368 (Z) B.1.14 Ϊ545 (U) B.1.14

15 (W) B.1.15 i192 (Y) B.1.15 Ϊ369 (Z) B.1.15 Ϊ546 (U) B.1.15

16 (W) B.1.16 i193 (Y) B.1.16 Ϊ370 (Z) B.1.16 Ϊ547 (U) B.1.16

17 (W) B.1.17 i194 (Y) B.1.17 Ϊ371 (Z) B.1.17 Ϊ548 (U) B.1.17

18 (W) B.1.18 i195 (Y) B.1.18 Ϊ372 (Z) B.1.18 Ϊ549 (U) B.1.18

19 (W) B.1.19 i196 (Y) B.1.19 Ϊ373 (Z) B.1.19 Ϊ550 (U) B.1.19

20 (W) B.1.20 i197 00 B.1.20 Ϊ374 (Z) B.1.20 i551 (U) B.1.20

21 (W) B.1.21 i198 (Y) B.1.21 Ϊ375 (Z) B.1.21 Ϊ552 (U) B.1.21 (W) B.1.22 i199 00 B.1.22 Ϊ376 (Z) B.1.22 Ϊ553 (U) B.1.22

(W) B.1.23 Ϊ200 00 B.1.23 Ϊ377 (Z) B.1.23 Ϊ554 (U) B.1.23

(W) B.1.24 i201 00 B.1.24 Ϊ378 (Z) B.1.24 Ϊ555 (U) B.1.24

(W) B.1.25 Ϊ202 00 B.1.25 Ϊ379 (Z) B.1.25 Ϊ556 (U) B.1.25

(W) B.1.26 Ϊ203 00 B.1.26 Ϊ380 (Z) B.1.26 Ϊ557 (U) B.1.26

(W) B.1.27 Ϊ204 oo B.1.27 Ϊ381 (Z) B.1.27 Ϊ558 (U) B.1.27

(W) B.1.28 Ϊ205 (Y) B.1.28 Ϊ382 (Z) B.1.28 Ϊ559 (U) B.1.28

(W) B.1.29 Ϊ206 (Y) B.1.29 Ϊ383 (Z) B.1.29 Ϊ560 (U) B.1.29

(W) B.1.30 Ϊ207 oo B.1.30 Ϊ384 (Z) B.1.30 Ϊ561 (U) B.1.30

(W) B.1.31 Ϊ208 (Y) B.1.31 Ϊ385 (Z) B.1.31 Ϊ562 (U) B.1.31

(W) B.1.32 Ϊ209 (Y) B.1.32 Ϊ386 (Z) B.1.32 Ϊ563 (U) B.1.32

(W) B.1.33 i210 (Y) B.1.33 Ϊ387 (Z) B.1.33 Ϊ564 (U) B.1.33

(W) B.1.34 i211 (Y) B.1.34 Ϊ388 (Z) B.1.34 Ϊ565 (U) B.1.34

(W) B.1.35 i212 (Y) B.1.35 Ϊ389 (Z) B.1.35 Ϊ566 (U) B.1.35

(W) B.1.36 i213 (Y) B.1.36 Ϊ390 (Z) B.1.36 Ϊ567 (U) B.1.36

(W) B.1.37 i214 00 B.1.37 Ϊ391 (Z) B.1.37 Ϊ568 (U) B.1.37

(W) B.1.38 i215 00 B.1.38 Ϊ392 (Z) B.1.38 Ϊ569 (U) B.1.38

(W) B.2.1 i216 (Y) B.2.1 Ϊ393 (Z) B.2.1 Ϊ570 (U) B.2.1

(W) B.2.2 i217 00 B.2.2 Ϊ394 (Z) B.2.2 Ϊ571 (U) B.2.2

(W) B.2.3 i218 (Y) B.2.3 Ϊ395 (Z) B.2.3 Ϊ572 (U) B.2.3

(W) B.2.4 i219 00 B.2.4 Ϊ396 (Z) B.2.4 Ϊ573 (U) B.2.4

(W) B.2.5 Ϊ220 00 B.2.5 Ϊ397 (Z) B.2.5 Ϊ574 (U) B.2.5

(W) B.2.6 i221 (Y) B.2.6 Ϊ398 (Z) B.2.6 Ϊ575 (U) B.2.6

(W) B.2.7 Ϊ222 00 B.2.7 Ϊ399 (Z) B.2.7 Ϊ576 (U) B.2.7

(W) B.2.8 Ϊ223 00 B.2.8 Ϊ400 (Z) B.2.8 Ϊ577 (U) B.2.8

(W) B.2.9 Ϊ224 00 B.2.9 Ϊ401 (Z) B.2.9 Ϊ578 (U) B.2.9

(W) B.2.10 Ϊ225 00 B.2.10 Ϊ402 (Z) B.2.10 Ϊ579 (U) B.2.10

(W) B.2.1 1 Ϊ226 00 B.2.11 Ϊ403 (Z) B.2.11 Ϊ580 (U) B.2.11

(W) B.2.12 Ϊ227 00 B.2.12 Ϊ404 (Z) B.2.12 Ϊ581 (U) B.2.12

(W) B.2.13 Ϊ228 00 B.2.13 Ϊ405 (Z) B.2.13 Ϊ582 (U) B.2.13

(W) B.2.14 Ϊ229 00 B.2.14 Ϊ406 (Z) B.2.14 Ϊ583 (U) B.2.14

(W) B.2.15 Ϊ230 00 B.2.15 Ϊ407 (Z) B.2.15 Ϊ584 (U) B.2.15

(W) B.2.16 Ϊ231 00 B.2.16 Ϊ408 (Z) B.2.16 Ϊ585 (U) B.2.16

(W) B.3.1 Ϊ232 00 B.3.1 Ϊ409 (Z) B.3.1 Ϊ586 (U) B.3.1

(W) B.3.2 Ϊ233 oo B.3.2 Ϊ410 (Z) B.3.2 Ϊ587 (U) B.3.2

(W) B.3.3 Ϊ234 00 B.3.3 Ϊ411 (Z) B.3.3 Ϊ588 (U) B.3.3

(W) B.3.4 Ϊ235 00 B.3.4 Ϊ412 (Z) B.3.4 Ϊ589 (U) B.3.4

(W) B.3.5 Ϊ236 oo B.3.5 Ϊ413 (Z) B.3.5 Ϊ590 (U) B.3.5

(W) B.3.6 Ϊ237 00 B.3.6 Ϊ414 (Z) B.3.6 Ϊ591 (U) B.3.6

(W) B.3.7 Ϊ238 00 B.3.7 Ϊ415 (Z) B.3.7 Ϊ592 (U) B.3.7

(W) B.3.8 Ϊ239 oo B.3.8 Ϊ416 (Z) B.3.8 Ϊ593 (U) B.3.8

(W) B.3.9 Ϊ240 00 B.3.9 Ϊ417 (Z) B.3.9 Ϊ594 (U) B.3.9

(W) B.3.10 i241 00 B.3.10 Ϊ418 (Z) B.3.10 Ϊ595 (U) B.3.10

(W) B.3.1 1 Ϊ242 (Y) B.3.11 Ϊ419 (Z) B.3.11 Ϊ596 (U) B.3.11

(W) B.3.12 Ϊ243 00 B.3.12 Ϊ420 (Z) B.3.12 Ϊ597 (U) B.3.12 67 (W) B.3.13 Ϊ244 00 B.3.13 Ϊ421 (Z) B.3.13 Ϊ598 (U) B.3.13

68 (W) B.3.14 Ϊ245 00 B.3.14 Ϊ422 (Z) B.3.14 Ϊ599 (U) B.3.14

69 (W) B.3.15 Ϊ246 OO B.3.15 Ϊ423 (Z) B.3.15 Ϊ600 (U) B.3.15

70 (W) B.3.16 Ϊ247 00 B.3.16 Ϊ424 (Z) B.3.16 Ϊ601 (U) B.3.16

71 (W) B.3.17 Ϊ248 (Y) B.3.17 Ϊ425 (Z) B.3.17 Ϊ602 (U) B.3.17

72 (W) B.3.18 Ϊ249 oo B.3.18 Ϊ426 (Z) B.3.18 Ϊ603 (U) B.3.18

73 (W) B.3.19 Ϊ250 (Y) B.3.19 Ϊ427 (Z) B.3.19 i604 (U) B.3.19

74 (W) B.3.20 i251 (Y) B.3.20 Ϊ428 (Z) B.3.20 Ϊ605 (U) B.3.20

75 (W) B.3.21 Ϊ252 oo B.3.21 Ϊ429 (Z) B.3.21 Ϊ606 (U) B.3.21

76 (W) B.3.22 Ϊ253 (Y) B.3.22 Ϊ430 (Z) B.3.22 Ϊ607 (U) B.3.22

77 (W) B.3.23 Ϊ254 (Y) B.3.23 Ϊ431 (Z) B.3.23 Ϊ608 (U) B.3.23

78 (W) B.3.24 Ϊ255 00 B.3.24 Ϊ432 (Z) B.3.24 Ϊ609 (U) B.3.24

79 (W) B.3.25 Ϊ256 (Y) B.3.25 Ϊ433 (Z) B.3.25 Ϊ610 (U) B.3.25

80 (W) B.3.26 Ϊ257 (Y) B.3.26 Ϊ434 (Z) B.3.26 Ϊ61 1 (U) B.3.26

81 (W) B.3.27 Ϊ258 CO B.3.27 Ϊ435 (Z) B.3.27 Ϊ612 (U) B.3.27

82 (W) B.3.28 Ϊ259 00 B.3.28 Ϊ436 (Z) B.3.28 Ϊ613 (U) B.3.28

83 (W) B.4.1 Ϊ260 (Y) B.4.1 Ϊ437 (Z) B.4.1 Ϊ614 (U) B.4.1

84 (W) B.4.2 Ϊ261 00 B.4.2 Ϊ438 (Z) B.4.2 Ϊ615 (U) B.4.2

85 (W) B.4.3 Ϊ262 00 B.4.3 Ϊ439 (Z) B.4.3 Ϊ616 (U) B.4.3

86 (W) B.4.4 Ϊ263 00 B.4.4 Ϊ440 (Z) B.4.4 Ϊ617 (U) B.4.4

87 (W) B.4.5 Ϊ264 00 B.4.5 i441 (Z) B.4.5 Ϊ618 (U) B.4.5

88 (W) B.4.6 Ϊ265 00 B.4.6 Ϊ442 (Z) B.4.6 Ϊ619 (U) B.4.6

89 (W) B.4.7 Ϊ266 (Y) B.4.7 Ϊ443 (Z) B.4.7 Ϊ620 (U) B.4.7

90 (W) B.4.8 Ϊ267 00 B.4.8 Ϊ444 (Z) B.4.8 Ϊ621 (U) B.4.8

91 (W) B.4.9 Ϊ268 00 B.4.9 Ϊ445 (Z) B.4.9 Ϊ622 (U) B.4.9

92 (W) B.4.10 Ϊ269 (Y) B.4.10 Ϊ446 (Z) B.4.10 Ϊ623 (U) B.4.10

93 (W) B.4.1 1 Ϊ270 00 B.4.11 Ϊ447 (Z) B.4.1 1 Ϊ624 (U) B.4.11

94 (W) B.4.12 i271 00 B.4.12 Ϊ448 (Z) B.4.12 Ϊ625 (U) B.4.12

95 (W) B.4.13 Ϊ272 (Y) B.4.13 Ϊ449 (Z) B.4.13 Ϊ626 (U) B.4.13

96 (W) B.4.14 Ϊ273 00 B.4.14 Ϊ450 (Z) B.4.14 Ϊ627 (U) B.4.14

97 (W) B.4.15 Ϊ274 00 B.4.15 Ϊ451 (Z) B.4.15 Ϊ628 (U) B.4.15

98 (W) B.4.16 Ϊ275 (Y) B.4.16 Ϊ452 (Z) B.4.16 Ϊ629 (U) B.4.16

99 (W) B.4.17 Ϊ276 00 B.4.17 Ϊ453 (Z) B.4.17 Ϊ630 (U) B.4.17

M OO (W) B.4.18 Ϊ277 00 B.4.18 Ϊ454 (Z) B.4.18 Ϊ631 (U) B.4.18 i101 (W) B.4.19 Ϊ278 oo B.4.19 Ϊ455 (Z) B.4.19 Ϊ632 (U) B.4.19 i102 (W) B.4.20 Ϊ279 00 B.4.20 Ϊ456 (Z) B.4.20 Ϊ633 (U) B.4.20 i103 (W) B.4.21 Ϊ280 00 B.4.21 Ϊ457 (Z) B.4.21 Ϊ634 (U) B.4.21 i104 (W) B.4.22 i281 oo B.4.22 Ϊ458 (Z) B.4.22 Ϊ635 (U) B.4.22 i105 (W) B.4.23 Ϊ282 00 B.4.23 Ϊ459 (Z) B.4.23 Ϊ636 (U) B.4.23 i106 (W) B.4.24 Ϊ283 00 B.4.24 Ϊ460 (Z) B.4.24 Ϊ637 (U) B.4.24 i107 (W) B.4.25 Ϊ284 oo B.4.25 Ϊ461 (Z) B.4.25 Ϊ638 (U) B.4.25 i108 (W) B.5.1 Ϊ285 00 B.5.1 Ϊ462 (Z) B.5.1 Ϊ639 (U) B.5.1 i109 (W) B.5.2 Ϊ286 00 B.5.2 Ϊ463 (Z) B.5.2 Ϊ640 (U) B.5.2 i1 10 (W) B.5.3 Ϊ287 00 B.5.3 Ϊ464 (Z) B.5.3 Ϊ641 (U) B.5.3 i1 1 1 (W) B.5.4 Ϊ288 00 B.5.4 Ϊ465 (Z) B.5.4 Ϊ642 (U) B.5.4 M 12 (W) B.5.5 Ϊ289 00 B.5.5 Ϊ466 (Z) B.5.5 Ϊ643 (U) B.5.5

Ϊ113 (W) B.5.6 Ϊ290 00 B.5.6 Ϊ467 (Z) B.5.6 Ϊ644 (U) B.5.6

Ϊ114 (W) B.5.7 i291 OO B.5.7 Ϊ468 (Z) B.5.7 Ϊ645 (U) B.5.7 i115 (W) B.5.8 Ϊ292 00 B.5.8 Ϊ469 (Z) B.5.8 i646 (U) B.5.8

Ϊ116 (W) B.5.9 Ϊ293 (Y) B.5.9 Ϊ470 (Z) B.5.9 Ϊ647 (U) B.5.9

Ϊ117 (W) B.6.1 Ϊ294 oo B.6.1 Ϊ471 (Z) B.6.1 Ϊ648 (U) B.6.1 i118 (W) B.6.2 Ϊ295 (Y) B.6.2 Ϊ472 (Z) B.6.2 Ϊ649 (U) B.6.2

Ϊ119 (W) B.6.3 Ϊ296 (Y) B.6.3 Ϊ473 (Z) B.6.3 Ϊ650 (U) B.6.3 i120 (W) B.6.4 Ϊ297 oo B.6.4 Ϊ474 (Z) B.6.4 Ϊ651 (U) B.6.4

Ϊ121 (W) B.6.5 Ϊ298 (Y) B.6.5 Ϊ475 (Z) B.6.5 Ϊ652 (U) B.6.5 i122 (W) B.6.6 Ϊ299 (Y) B.6.6 Ϊ476 (Z) B.6.6 Ϊ653 (U) B.6.6 i123 (W) B.6.7 Ϊ300 00 B.6.7 Ϊ477 (Z) B.6.7 Ϊ654 (U) B.6.7 i124 (W) B.7.1 Ϊ301 (Y) B.7.1 Ϊ478 (Z) B.7.1 Ϊ655 (U) B.7.1 i125 (W) B.7.2 Ϊ302 (Y) B.7.2 Ϊ479 (Z) B.7.2 Ϊ656 (U) B.7.2 i126 (W) B.7.3 Ϊ303 CO B.7.3 Ϊ480 (Z) B.7.3 Ϊ657 (U) B.7.3

Ϊ127 (W) B.7.4 Ϊ304 00 B.7.4 Ϊ481 (Z) B.7.4 Ϊ658 (U) B.7.4 i128 (W) B.7.5 Ϊ305 (Y) B.7.5 Ϊ482 (Z) B.7.5 Ϊ659 (U) B.7.5 i129 (W) B.7.6 Ϊ306 00 B.7.6 Ϊ483 (Z) B.7.6 i660 (U) B.7.6 i130 (W) B.8.1 Ϊ307 00 B.8.1 Ϊ484 (Z) B.8.1 Ϊ661 (U) B.8.1 i131 (W) B.8.2 Ϊ308 00 B.8.2 Ϊ485 (Z) B.8.2 Ϊ662 (U) B.8.2 i132 (W) B.8.3 Ϊ309 00 B.8.3 i486 (Z) B.8.3 Ϊ663 (U) B.8.3 i133 (W) B.8.4 Ϊ310 00 B.8.4 Ϊ487 (Z) B.8.4 i664 (U) B.8.4 i134 (W) B.8.5 i311 (Y) B.8.5 Ϊ488 (Z) B.8.5 Ϊ665 (U) B.8.5 i135 (W) B.9.1 i312 00 B.9.1 Ϊ489 (Z) B.9.1 i666 (U) B.9.1 i136 (W) B.9.2 Ϊ313 00 B.9.2 Ϊ490 (Z) B.9.2 Ϊ667 (U) B.9.2 i137 (W) B.9.3 Ϊ314 (Y) B.9.3 Ϊ491 (Z) B.9.3 Ϊ668 (U) B.9.3 i138 (W) B.10.1 Ϊ315 00 B.10.1 Ϊ492 (Z) B.10.1 Ϊ669 (U) B.10.1 i139 (W) B.1 1.1 i316 00 B.11.1 Ϊ493 (Z) B.11.1 Ϊ670 (U) B.11.1 i140 (W) B.1 1.2 i317 (Y) B.11.2 Ϊ494 (Z) B.11.2 Ϊ671 (U) B.11.2 i141 (W) B.1 1.3 Ϊ318 00 B.11.3 Ϊ495 (Z) B.11.3 Ϊ672 (U) B.11.3 i142 (W) B.1 1.4 i319 00 B.11.4 Ϊ496 (Z) B.11.4 Ϊ673 (U) B.11.4 i143 (W) B.12.1 Ϊ320 (Y) B.12.1 Ϊ497 (Z) B.12.1 Ϊ674 (U) B.12.1 i144 (W) B.13.1 Ϊ321 00 B.13.1 Ϊ498 (Z) B.13.1 Ϊ675 (U) B.13.1 i145 (W) B.14.1 Ϊ322 00 B.14.1 Ϊ499 (Z) B.14.1 Ϊ676 (U) B.14.1 i146 (W) B.14.2 Ϊ323 oo B.14.2 Ϊ500 (Z) B.14.2 Ϊ677 (U) B.14.2 i147 (W) B.15.1 Ϊ324 00 B.15.1 Ϊ501 (Z) B.15.1 Ϊ678 (U) B.15.1 i148 (W) B.15.2 Ϊ325 00 B.15.2 Ϊ502 (Z) B.15.2 Ϊ679 (U) B.15.2 i149 (W) B.15.3 Ϊ326 oo B.15.3 Ϊ503 (Z) B.15.3 Ϊ680 (U) B.15.3 i150 (W) B.15.4 Ϊ327 00 B.15.4 Ϊ504 (Z) B.15.4 Ϊ681 (U) B.15.4 i151 (W) B.15.5 Ϊ328 00 B.15.5 Ϊ505 (Z) B.15.5 Ϊ682 (U) B.15.5 i152 (W) B.15.6 Ϊ329 oo B.15.6 Ϊ506 (Z) B.15.6 Ϊ683 (U) B.15.6 i153 (W) B.15.7 Ϊ330 00 B.15.7 Ϊ507 (Z) B.15.7 Ϊ684 (U) B.15.7 i154 (W) B.15.8 i331 00 B.15.8 Ϊ508 (Z) B.15.8 Ϊ685 (U) B.15.8 i155 (W) B.15.9 Ϊ332 00 B.15.9 Ϊ509 (Z) B.15.9 Ϊ686 (U) B.15.9 i156 (W) B.15.10 Ϊ333 00 B.15.10 Ϊ510 (Z) B.15.10 Ϊ687 (U) B.15.10 M57 (W) B.15.11 Ϊ334 00 B.15.11 i511 (Z) B.15.11 Ϊ688 (U) B.15.1 1 i158 (W) B.15.12 Ϊ335 00 B.15.12 i512 (Z) B.15.12 Ϊ689 (U) B.15.12 i159 (W) B.15.13 Ϊ336 00 B.15.13 i513 (Z) B.15.13 Ϊ690 (U) B.15.13 i160 (W) B.16.1 Ϊ337 00 B.16.1 Ϊ514 (Z) B.16.1 Ϊ691 (U) B.16.1 i161 (W) B.16.2 Ϊ338 (Y) B.16.2 i515 (Z) B.16.2 Ϊ692 (U) B.16.2 i162 (W) B.16.3 Ϊ339 oo B.16.3 i516 (Z) B.16.3 Ϊ693 (U) B.16.3 i163 (W) B.16.4 Ϊ340 (Y) B.16.4 i517 (Z) B.16.4 Ϊ694 (U) B.16.4 i164 (W) B.16.5 i341 (Y) B.16.5 i518 (Z) B.16.5 Ϊ695 (U) B.16.5 i165 (W) B.16.6 Ϊ342 oo B.16.6 i519 (Z) B.16.6 Ϊ696 (U) B.16.6 i166 (W) B.16.7 Ϊ343 (Y) B.16.7 Ϊ520 (Z) B.16.7 Ϊ697 (U) B.16.7 i167 (W) B.16.8 Ϊ344 (Y) B.16.8 i521 (Z) B.16.8 Ϊ698 (U) B.16.8 i168 (W) B.16.9 Ϊ345 00 B.16.9 Ϊ522 (Z) B.16.9 Ϊ699 (U) B.16.9 i169 (W) B.16.10 Ϊ346 (Y) B.16.10 Ϊ523 (Z) B.16.10 Ϊ700 (U) B.16.10 i170 (W) B.16.11 Ϊ347 (Y) B.16.11 Ϊ524 (Z) B.16.11 Ϊ701 (U) B.16.1 1 i171 (W) B.16.12 Ϊ348 CO B.16.12 Ϊ525 (Z) B.16.12 Ϊ702 (U) B.16.12 i172 (W) B.16.13 Ϊ349 00 B.16.13 Ϊ526 (Z) B.16.13 Ϊ703 (U) B.16.13 i173 (W) B.16.14 Ϊ350 (Y) B.16.14 Ϊ527 (Z) B.16.14 Ϊ704 (U) B.16.14 i174 (W) B.16.15 i351 00 B.16.15 Ϊ528 (Z) B.16.15 Ϊ705 (U) B.16.15 i175 (W) B.16.16 Ϊ352 00 B.16.16 Ϊ529 (Z) B.16.16 Ϊ706 (U) B.16.16 i176 (W) B.17.1 Ϊ353 00 B.17.1 Ϊ530 (Z) B.17.1 Ϊ707 (U) B.17.1 i177 (W) B.17.2 Ϊ354 00 B.17.2 Ϊ531 (Z) B.17.2 Ϊ708 (U) B.17.2

In further specific embodiments, the present invention relates to compositions comprising as compound I (component A) at least one nitrification inhibitor as defined in Table 1 , i.e. at least one of compound A #1 to #215 and as compound II (component B) at least one insecticide and/or nematicide selected from, B.1.1 , B.1.2, B.1.3, B.1.4, B.1 .5, B.1.6, B.1.7, B.1.8, B.1.9, B.1.10, B.1.1 1 , B.1.12, B.1.13, B.1.14, B.1.15, B.1 .16, B.1 .17, B.1.18, B.1.19, B.1.20, B.1.21 , B.1.22, B.1.23, B.1.24, B.1.25, B.1.26, B.1.27, B.1 .28, B.1 .29, B.1.30, B1 .31 ,B.1.32, B.1.33, B.1.34, B.1.35, B1.36, B.1.37, B.1.38, B.1.39; B.2.1 , B.2.2, B.2.3, B.2.4, B.2.5, B.2.6, B.2.7, B.2.8, B.2.9, B.2.10, B.2.1 1 , B.2.12, B.2.13, B.2.14, B.3.1 , B.3.2, B.3.3, B.3.4, B.3.5, B.3.6, B.3.7, B.3.8, B.3.9, B.3.10, B.3.1 1 , B.3.12, B.3.13, B.3.14, B.3.15, B.3.16, B.3.17, B.3.18, B.3.19, B.3.20, B.3.21 , B.3.22, B.3.23, B.3.24, B.3.25, B.3.26, B.3.27, B.3.28, B.4.1 , B.4.2, B.4.3, B.4.4, B.4.5, B.4.6, B.4.7, B.4.8, B.4.9, B.4.10, B.4.11 , B.4.12, B.4.13, B.4.14, B.4.15, B.4.16, B.4.17, B.4.18, B.4.19, B.4.20, B.4.21 , B.4.22, B.4.23, B.4.24, B.4.25, B.5.2, B.5.3, B.5.6, B.5.7, B.5.9, B.6.1 , B.6.2, B.6.4, B.6.5, B.6.6, B.7.1 , B.7.2, B.7.3, B7.4, B.7.5, B.7.6, B.8.1 , B.8.2, B.8.3, B.8.4, B.8.5, B.9.1 , B.9.2, B.9.3, B.10.1 , B.11.1 , B.1 1.2, B.1 1.3, B.1 1 .4, B.12.1 , B.13.1 , B.14.1 , B.14.2, B.15.1 , B.15.2, B.15.3, B.15.4, B.15.5, B.15.6, B.15.7, B.15.8, B.15.9, B.15.10, B.15.1 1 , B.16.1 , B.16.2, B.16.3, B.16.4, B.16.5, B.16.6, B.16.7, B.16.8, B.16.9, B.16.10, B.16.1 1 , B.16.12, B.16.13, B.16.14, B.16.15, B.16.16, as defined herein above. In further specific embodiments, the present invention relates to the use of compositions for increasing the health of a plant, which comprise the combination of an insecticide and/or nematicide and a nitrification inhibitor as defined herein and additionally a fertilizer. Such compositions may be used and provided as agricultural mixtures. The use of a combination as defined herein above, in particular of a combination of a nitrification inhibitor as defined herein above and an insecticide and/or nematicide as defined herein above, or of a composition as defined herein for increasing the health of a plant may be a single use, or it may be a repeated use. As single use, the combination or corresponding compositions may be provided to their target sites, e.g. soil or loci, or objects, e.g. plants, only once in a physiologically relevant time interval, e.g. once a year, or once every 2 to 5 years, or once during the lifetime of a plant.

In other embodiments, the use may be repeated at least once per time period, e.g. the combina- tion as defined herein above, or a composition as defined herein may be used for increasing the health of a plant two times within a time interval of days, weeks or months. The term "at least once" as used in the context of a use of the combination means that the combination may be used two times, or several times, i.e. that a repetition or multiple repetitions of an application or treatment with the combinationmay be envisaged. Such a repetition may a 2 times, 3 times, 4 times, 5 times, 6 times, 7 times, 8 times, 9 times, 10 times or more frequent repetition of the use.

The combination according to the present invention or its components may be used in any suitable form. For example, it may be used as coated or uncoated granule, in liquid or semi-liquid form, as sprayable entity, or in irrigation approaches etc. In further embodiments, the compo- nents may be used in different forms. In specific embodiments, the components may be applied or used as such, i.e.without formulations, fertilizer, additional water, coatings, or any further ingredient.

The term "irrigation" as used herein refers to the watering of plants or loci or soils or soil substit- uents where a plant grows or is intended to grow, wherein said watering includes the provision of the combination or a corresponding composition according to the present invention together with water.

In a further aspect the invention relates to a composition for increasing the health of a plant comprising (T) or at least one nitrification inhibitor wherein said nitrification inhibitor is a compound of formula I or a derivative as defined herein above; and at least one insecticide and/or nematicide as defined herein above. In a preferred embodiment, the composition comprises the combination of nitrification inhibitor and insecticide and/or nematicide as defined in Table 2, supra. In another preferred embodiment, the composition comprises the combination of a (thio)phosphoric acid triamide (T) and insecticide and/or nematicide as defined in Table 3, supra. In another preferred embodiment, the composition for increasing the health of a plant comprises the combination of a (thio)phosphoric acid triamide (T) and insecticide and/or nematicide as defined in Table 3, supra. In another preferred embodiment, the composition for increasing the insectidical and/or nematicidal activity of an insecticide and/or nematicide comprises the combination of a (thio)phosphoric acid triamide (T) and insecticide and/or nematicide as defined in Table 3, supra.

In further specific embodiments, the agricultural compositon further comprises acarrier. The term " composition for increasing the health of a plant" as used herein refers to a composition which is suitable, e.g. comprises effective concentrations and amounts of ingredients such as (T) or nitrification inhibitors, in particular compounds of formula I or derivatives as defined herein, and insecticides and/or nematicides for increasing the health of a plant. This includes the reduction of nitrification in any context or environment in which nitrification may occur and the reduction of biotic stress factors due to an insecticidal or nematicidal effect toinsects or nematodes, respectively. In one embodiment, the nitrification and biotic stress may be reduced in or on or at the locus of a plant. Typically, the nitrification may be reduced in the root zone of a plant. In specific embodiments, the composition may be an agricultural composition, i.e. a com- position adapated to the use in the agricultural field. "Effective amounts" or "effective concentrations" of (T) or nitrification inhibitors and insecticides and/or nematicides as defined herein may be determined according to suitable in vitro and in vivo testings known to the skilled person. These amounts and concentrations may be adjusted to the locus, plant, soil, climate conditions or any other suitable parameter which may have an influence on nitrification processes, and/or on competitive plant growth.

An "carrier" as used herein is a substance or composition which facilitates the delivery and/or release of the ingredients to the place or lcous of destination. The term includes, for instance, agrochemical carriers which facilitate the delivery and/or release of agrochemicals in their field of use, in particular on or into plants.

Examples of suitable carriers include solid carriers such as phytogels, or hydrogels, or mineral earths e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, bole, loess, clays, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, e.g. urea, urea based NPK, UAN, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers. Further suitable examples of carriers include fumed silica or precipitated silica, which may, for instance, be used in solid formulations as flow aid, anti-caking aid, milling aid and as carrier for liquid active ingredients. Additional examples of suitable carriers are microparticles, for instance microparticles which stick to plant leaves and release their content over a certain period of time. In specific embodiments, agrochemical carriers such as composite gel microparticles that can be used to deliver plant-protection active principles, e.g. as described in US 6,180,141 ; or compositions comprising at least one phytoactive compound and an encapsulating adjuvant, where- in the adjuvant comprises a fungal cell or a fragment thereof, e.g. as described in WO

2005/102045; or carrier granules, coated with a lipophilic tackifier on the surface, wherein the carrier granule adheres to the surface of plants, grasses and weeds, e.g. as disclosed in US 2007/0280981 may be used. In further specific embodiments, such carriers may include specific, strongly binding molecule which assure that the carrier sticks to the plant till its content is completely delivered. For instance, the carrier may be or comprise cellulose binding domains (CBDs) have been described as useful agents for attachment of molecular species to cellulose (see US 6,124,1 17); or direct fusions between a CBD and an enzyme; or a multifunctional fusion protein which may be used for delivery of encapsulated agents, wherein the multifunctional fusion proteins may consist of a first binding domain which is a carbohydrate binding domain and a second binding domain, wherein either the first binding domain or the second binding domain can bind to a microparticle (see also WO 03/031477). Further suitable examples of carriers include bifunctional fusion proteins consisting of a CBD and an anti-RR6 antibody fragment binding to a microparticle, which complex may be deposited onto treads or cut grass (see also WO 03/031477). In another specific embodiment the carrier may be active ingredient carrier granules that adhere to the surface of plants, grasses and weeds etc. using a moisture-active coating, for instance including gum arabic, guar gum, gum karaya, gum tragacanth and locust bean gum. Upon application of the inventive granule onto a plant surface, water from precipitation, irrigation, dew, co-application with the granules from special application equipment, or gut- tation water from the plant itself may provide sufficient moisture for adherence of the granule to the plant surface (see also US 2007/0280981 ).

In another specific embodiment the carrier, e.g. an agrochemical carrier may be or comprise polyaminoacids. Polyaminoacids may be obtained according to any suitable process, e.g. by polymerization of single or multiple amino acids such as glycine, alanine, valine, leucine, isoleu- cine, phenylalanine, proline, tryptophan, serine, tyrosine, cysteine, methionine, asparagine, glu- tamine, threonine, aspartic acid, glutamic acid, lysine, arginine, histidine and/or ornithine. Polyaminoacids may be combined with a combination of a nitrification inhibitor or (T) and an insecticide and/or nematicide according to the present invention and, in certain embodiments, also with further carriers, e.g. agrochemical carriers, as mentioned herein above, or other nitrification inhibitors as mentioned herein in any suitable ratio. For example, polyaminoacids may be combined with (T) or a nitrification inhibitor according to the present invention in a ratio of 1 to 10 (polyaminoacids) vs. 0.5 to 2 (combination according to the present invention, or nitrification inhibitor according to the present invention).

For compositions (including kits-of parts) according to the invention comprising nitrification inhibitor as defined herein above and an insecticide and/or nematicide, the weight ratio of the nitrification inhibitor as defined herein above and the insecticide and/or nematicide generally depends from the properties of the active substances used, usually it is in the range of from 1 :1000 to 1000:1 , regularly in the range of from 1 :500 to 500:1 , preferably in the range of from 1 :250 to 250:1 , more preferably in the range of from 1 :100 to 100:1 , most preferably in the range of from 1 :70 to 70:1 , particularly preferably in the range of from 1 :50 to 50:1 , particularly more preferably in the range of from 1 :30 to 30:1 , particularly most preferably in the range from 1 :20 to 20:1 , particularly in the range of from 1 :15 to 15:1 , especially preferably in the range of from 1 :10 to 10:1 , especially more preferably in the range of from 1 :8 to 8:1 , especially most preferably in the range of from 1 :6.5 to 6.5:1 , especially in the range of from 1 :5 to 5: 1 , in particular preferably in the range of 1 :4 to 4:1 , in particular more preferably in the range of from 1 :3 to 3:1 , in particular most preferably in the range of from 2.5:1 to 1 :2.5, in particular in the range of from 1 :2 to 2:1 , for example in the range of from 1 :1.5 to 1 .5:1. For compositions (including kits- of parts) according to the invention, the weight ratio of the nitrification inhibitor as defined herein above and the insecticide and/or nematicide generally depends from the properties of the active substances used, usually it is not more than 1000:1 , regularly not more than 250:1 , preferably not more than 100:1 , more preferably not more than 50:1 , most preferably not more than 30:1 , particularly preferably not more than 15:1 , particularly more preferably not more than 8:1 , par- ticularly most preferably not more than 4:1 , particularly not more than 2:1 , especially preferably not more than 1 :1 , especially more preferably not more than 1 :2, especially most preferably not more than 1 :4, especially not more than 1 :8, in particular preferably not more than 1 :15, in particular more preferably not more than 1 :30, in particular most preferably not more than 1 :50, in particular not more than 1 : 100, for example preferably not more than 1 :250, for example not more than 1 :1000. For compositions (including kits-of parts) according to the invention, the weight ratio of the nitrification inhibitor as defined herein above and the insecticide and/or ne- maticide generally depends from the properties of the active substances used, usually it is at least 1000:1 , regularly at least 250:1 , preferably at least 100:1 , more preferably at least 50:1 , most preferably at least 30:1 , particularly preferably at least 15:1 , particularly more preferably at least 8:1 , particularly most preferably at least 4:1 , particularly at least 2:1 , especially preferably at least 1 :1 , especially more preferably at least 1 :2, especially most preferably at least 1 :4, especially at least 1 :8, in particular preferably at least 1 :15, in particular more preferably at least 1 :30, in particular most preferably at least 1 :50, in particular at least 1 :100, for example prefera- bly at least 1 :250, for example at least 1 :1000.

For compositions (including kits-of parts) according to the invention comprising (T) and an insecticide and/or nematicide, the weight ratio of (T) and the insecticide and/or nematicide generally depends from the properties of the active substances used, usually it is in the range of from 1 :1000 to 1000:1 , regularly in the range of from 1 :500 to 500:1 , preferably in the range of from 1 :250 to 250:1 , more preferably in the range of from 1 :100 to 100:1 , most preferably in the range of from 1 :70 to 70:1 , particularly preferably in the range of from 1 :50 to 50:1 , particularly more preferably in the range of from 1 :30 to 30:1 , particularly most preferably in the range from 1 :20 to 20:1 , particularly in the range of from 1 :15 to 15:1 , especially preferably in the range of from 1 :10 to 10:1 , especially more preferably in the range of from 1 :8 to 8:1 , especially most preferably in the range of from 1 :6.5 to 6.5:1 , especially in the range of from 1 :5 to 5:1 , in particular preferably in the range of 1 :4 to 4: 1 , in particular more preferably in the range of from 1 :3 to 3:1 , in particular most preferably in the range of from 2.5:1 to 1 :2.5, in particular in the range of from 1 :2 to 2:1 , for example in the range of from 1 :1.5 to 1.5:1. For compositions (including kits- of parts) according to the invention, the weight ratio of (T) and the insecticide and/or nematicide generally depends from the properties of the active substances used, usually it is not more than 1000:1 , regularly not more than 250:1 , preferably not more than 100:1 , more preferably not more than 50:1 , most preferably not more than 30:1 , particularly preferably not more than 15:1 , particularly more preferably not more than 8:1 , particularly most preferably not more than 4:1 , particularly not more than 2:1 , especially preferably not more than 1 :1 , especially more preferably not more than 1 :2, especially most preferably not more than 1 :4, especially not more than 1 :8, in particular preferably not more than 1 :15, in particular more preferably not more than 1 :30, in particular most preferably not more than 1 :50, in particular not more than 1 :100, for example preferably not more than 1 :250, for example not more than 1 : 1000. For compositions (including kits-of parts) according to the invention, the weight ratio of (T) and the insecticide and/or nematicide generally depends from the properties of the active substances used, usually it is at least 1000:1 , regularly at least 250:1 , preferably at least 100:1 , more preferably at least 50:1 , most preferably at least 30:1 , particularly preferably at least 15:1 , particularly more preferably at least 8: 1 , particularly most preferably at least 4:1 , particularly at least 2: 1 , especially preferably at least 1 :1 , especially more preferably at least 1 :2, especially most preferably at least 1 :4, especially at least 1 :8, in particular preferably at least 1 :15, in particular more preferably at least 1 :30, in particular most preferably at least 1 :50, in particular at least 1 : 100, for example preferably at least 1 :250, for example at least 1 :1000.

The composition for increasing the health of a plant comprising (T) or at least one nitrification inhibitor as defined herein may further comprise additional ingredients, for example at least one pesticidal compound. For example, the composition may additionally comprise at least one her- bicidal compound and/or at least one fungicidal compound and/or at least one biopesticide and/or at least one biostimulant.

In further embodiments, the composition may, in addition to the above indicated ingredients, in particular in addition to (T) or the nitrification inhibitor of the compound of formula I, further comprise one or more alternative or additional nitrification inhibitors. Examples of envisaged alterna- tive or additional nitrification inhibitors are linoleic acid, alpha-linolenic acid, methyl p- coumarate, methyl ferulate, methyl 3-(4-hydroxyphenyl) propionate (MH PP), Karanjin, neem- extract, including various compounds such as neemoil-coated fertilizers, neem-coated fertilizers, nimin-coated fertilizers and fertilizers with neem cake from the Indian neem tree (Aza- dirachta indica), brachialacton, p-benzoquinone sorgoleone, 2-chloro-6-(trichloromethyl)- pyridine (nitrapyrin or N-serve), dicyandiamide (DCD, Dl DIN), 3,4-dimethyl pyrazole phosphate (DMPP, ENTEC), 4-amino-1 ,2,4-triazole hydrochloride (ATC), 1-amido-2-thiourea (ASU), 2- amino-4-chloro-6-methylpyrimidine (AM), 2-mercapto-benzothiazole (M BT), 5-ethoxy-3- trichloromethyl-1 ,2,4-thiodiazole (terrazole, etridiazole), 2-sulfanilamidothiazole (ST), ammoni- umthiosulfate (ATU), 3-methylpyrazol (3-MP), 3,5-dimethylpyrazole (DM P), 1 ,2,4-triazole, thiou- rea (TU), N-(1 H-pyrazolyl-methyl)acetamides such as N-((3(5)-methyl-1 H-pyrazole-1- yl)methyl)acetamide, and N-(1 H-pyrazolyl-methyl)formamides such as N-((3(5)-methyl-1 H- pyrazole-1 -yl)methyl formamide, N-(4-chloro-3(5)-methyl-pyrazole-1-ylmethyl)-formamide, N- (3(5),4-dimethyl-pyrazole-1-ylmethyl)-formamide, mixtures of 3,4-dimethylpyrazole phospate succinic acid and 4,5-dimethylpyrazole phosphate succinic acid, neem, products based on in- gredients of neem, cyan amide, melamine, zeolite powder, catechol, benzoquinone, sodium tetra borate, and zinc sulfate.

In a preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrifica- tion inhibitor of the compound of formula I and 2-chloro-6-(trichloromethyl)-pyridine (nitrapyrin or N-serve).

In a further preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and 5-ethoxy-3-trichloromethyl-1 ,2,4- thiodiazole (terrazole, etridiazole). In a further preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and dicyandiamide (DCD, DIDIN). In a further preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and 3,4-dimethyl pyrazole phosphate (DMPP, ENTEC). In a further preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and 2-amino-4-chloro-6-methylpyrimidine (AM). In a further preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and 2-mercapto-benzothiazole (MBT).

In a further preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and 2-sulfanilamidothiazole (ST).

In a further preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and 3-methylpyrazol (3-MP).

In a further preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and 3,5-dimethylpyrazole (DMP).

In a further preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and 1 ,2,4-triazol. In a further preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and thiourea (TU).

In yet another preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and linoleic acid. In yet another preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and alpha-linolenic acid. In yet another preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and methyl p-coumarate.

In yet another preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and methyl 3-(4-hydroxyphenyl) propionate (MHPP).

In yet another preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and methyl ferulate.

In yet another preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and Karanjin.

In a further preferred embodiment, the composition according to the present invention may comprise a combination of (T) or the nitrification inhibitor of the compound of formula I and neem-extract.

In a further preferred embodiment, the composition according to the present invention may comprise a combination of (T) or the nitrification inhibitor of the compound of formula I and neemoil-coated fertilizers. In a further preferred embodiment, the composition according to the present invention may comprise a combination of (T) or the nitrification inhibitor of the compound of formula I and neem-coated fertilizers.

In a further preferred embodiment, the composition according to the present invention may comprise a combination of (T) or the nitrification inhibitor of the compound of formula I and ni- min-coated fertilizers.

In a further preferred embodiment, the composition according to the present invention may comprise a combination of (T) or the nitrification inhibitor of the compound of formula I and ferti- lizers with neem cake.

In yet another preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and brachialacton. In yet another preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and p-benzoquinone sorgoleone.

In yet another preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and 4-amino-1 ,2,4-triazole hydrochloride (ATC).

In yet another preferred embodiment, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and 1-amido-2-thiourea (ASU). In further embodiments, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and two entities selected from the group comprising: linoleic acid, alpha-linolenic acid, methyl p-coumarate, methyl ferulate, methyl 3-(4- hydroxyphenyl) propionate (MHPP), Karanjin, brachialacton, p-benzoquinone sorgoleone, 2- chloro-6-(trichloromethyl)-pyridine (nitrapyrin or N-serve), dicyandiamide (DCD, DIDIN), 3,4- dimethyl pyrazole phosphate (DMPP, ENTEC), 4-amino-1 ,2,4-triazole hydrochloride (ATC), 1- amido-2-thiourea (ASU), 2-amino-4-chloro-6-methylpyrimidine (AM), 2-mercapto-benzothiazole (MBT), 5-ethoxy-3-trichloromethyl-1 ,2,4-thiodiazole (terrazole, etridiazole), 2- sulfanilamidothiazole (ST), ammoniumthiosulfate (ATU), 3-m ethyl pyrazol (3-MP), 3,5- dimethyl pyrazole (DMP), 1 ,2,4-triazol and thiourea (TU).

In yet another group of embodiments, the composition according to the present invention may comprise a combination of an insecticide and/or nematicide as defined herein above, of (T) or the nitrification inhibitor of the compound of formula I and three, four or more entities selected from the group comprising: linoleic acid, alpha-linolenic acid, methyl p-coumarate, methyl ferulate, methyl 3-(4-hydroxyphenyl) propionate (M HPP), Karanjin, brachialacton, p-benzoquinone sorgoleone, 2-chloro-6-(trichloromethyl)-pyridine (nitrapyrin or N-serve), dicyandiamide (DCD, DIDIN), 3,4-dimethyl pyrazole phosphate (DMPP, ENTEC), 4-amino-1 ,2,4-triazole hydrochloride (ATC), 1 -amido-2-thiourea (ASU), 2-amino-4-chloro-6-methylpyrimidine (AM), 2-mercapto- benzothiazole (MBT), 5-ethoxy-3-trichloromethyl-1 ,2,4-thiodiazole (terrazole, etridiazole), 2- sulfanilamidothiazole (ST), ammoniumthiosulfate (ATU), 3-methylpyrazol (3-MP), 3,5- di methyl pyrazole (DMP), 1 ,2,4-triazol and thiourea (TU).

In further specific embodiments, the composition may comprise the combination of a nitrification inhibitor and an insecticide and/or nematicide as defined in Table 2 and at least one element selected from the group comprising: linoleic acid, alpha-linolenic acid, methyl p-coumarate, methyl ferulate, methyl 3-(4-hydroxyphenyl) propionate (M HPP), Karanjin, brachialacton, p- benzoquinone sorgoleone, 2-chloro-6-(trichloromethyl)-pyridine (nitrapyrin or N-serve), dicyandiamide (DCD, DIDIN), 3,4-dimethyl pyrazole phosphate (DMPP, ENTEC), 4-amino-1 ,2,4- triazole hydrochloride (ATC), 1 -amido-2-thiourea (ASU), 2-amino-4-chloro-6-methylpyrimidine (AM), 2-mercapto-benzothiazole (MBT), 5-ethoxy-3-trichloromethyl-1 ,2,4-thiodiazole (terrazole, etridiazole), 2-sulfanilamidothiazole (ST), ammoniumthiosulfate (ATU), 3-methylpyrazol (3-MP), 3,5-dimethylpyrazole (DMP), 1 ,2,4-triazole, thiourea (TU), N-(1 H-pyrazolyl-methyl)acetamides such as N-((3(5)-methyl-1 H-pyrazole-1-yl)methyl)acetamide, and N-(1 H-pyrazolyl- methyl)formamides such as N-((3(5)-methyl-1 H-pyrazole-1-yl)methyl formamide, N-(4-chloro- 3(5)-methyl-pyrazole-1 -ylmethyl)-formamide, N-(3(5),4-dimethyl-pyrazole-1 -ylmethyl)- formamide, mixtures of 3,4-dimethylpyrazole phospate succinic acid and 4,5-dimethylpyrazole phosphate succinic acid, neem, products based on ingredients of neem, cyan amide, melamine, zeolite powder, catechol, benzoquinone, sodium tetra borate, and zinc sulfate.

In further specific embodiments, the composition may comprise the combination of (T) and an insecticide and/or nematicide as defined in Table 3 and at least one element selected from the group comprising: linoleic acid, alpha-linolenic acid, methyl p-coumarate, methyl ferulate, methyl 3-(4-hydroxyphenyl) propionate (MHPP), Karanjin, brachialacton, p-benzoquinone sorgoleone, 2-chloro-6-(trichloromethyl)-pyridine (nitrapyrin or N-serve), dicyandiamide (DCD, DIDIN), 3,4- dimethyl pyrazole phosphate (DMPP, ENTEC), 4-amino-1 ,2,4-triazole hydrochloride (ATC), 1- amido-2-thiourea (ASU), 2-amino-4-chloro-6-methylpyrimidine (AM), 2-mercapto-benzothiazole (MBT), 5-ethoxy-3-trichloromethyl-1 ,2,4-thiodiazole (terrazole, etridiazole), 2- sulfanilamidothiazole (ST), ammoniumthiosulfate (ATU), 3-methylpyrazol (3-MP), 3,5- dimethylpyrazole (DMP), 1 ,2,4-triazole, thiourea (TU), N-(1 H-pyrazolyl-methyl)acetamides such as N-((3(5)-methyl-1 H-pyrazole-1 -yl)methyl)acetamide, and N-(1 H-pyrazolyl-methyl)formamides such as N-((3(5)-methyl-1 H-pyrazole-1-yl)methyl formamide, N-(4-chloro-3(5)-methyl-pyrazole- 1-ylmethyl)-formamide, N-(3(5),4-dimethyl-pyrazole-1 -ylmethyl)-formamide, mixtures of 3,4- dimethylpyrazole phospate succinic acid and 4,5-dimethylpyrazole phosphate succinic acid, neem, products based on ingredients of neem, cyan amide, melamine, zeolite powder, catechol, benzoquinone, sodium tetra borate, and zinc sulfate.

In further embodiments, the composition may, in addition to the above indicated ingredients, in particular in addition to an insecticide and/or nematicide as defined herein above, and to the nitrification inhibitor of the compound of formula I, further comprise one or more urease inhibitors. Examples of envisaged urease inhibitors include N-(n-butyl) thiophosphoric acid triamide (NBPT, Agrotain), N-(n-propyl) thiophosphoric acid triamide (NPPT), 2-nitrophenyl phosphoric triamide (2-NPT), further NXPTs known to the skilled person, phenylphosphorodiamidate (PPD/PPDA), hydroquinone, ammonium thiosulfate, and LIMUS, i.e. a mixture of N BPT and NPPT with about NBTP at 63% and NPPT at 22%, secondary compounds at 10%, further secondary compounds such as amines below 4% and dimerease derivatives below 1 %.

In a preferred embodiment, the composition according to the present invention may comprise an insecticide and/or nematicide as defined herein above and a combination of the nitrification inhibitor of the compound of formula I and N-(n-butyl) thiophosphoric acid triamide (NBPT, Agro- tain). In a further preferred embodiment, the composition according to the present invention may comprise an insecticide and/or nematicide as defined herein above and a combination of (T) or the nitrification inhibitor of the compound of formula I and phenylphosphorodiamidate

(PPD/PPDA).

In a further preferred embodiment, the composition according to the present invention may comprise an insecticide and/or nematicide as defined herein above and a combination of the nitrification inhibitor of the compound of formula I and N-(n-propyl) thiophosphoric acid triamide (NPPT).

In a further preferred embodiment, the composition according to the present invention may comprise an insecticide and/or nematicide as defined herein above and a combination of the nitrification inhibitor of the compound of formula I and 2-nitrophenyl phosphoric triamide (2- N PT).

In a further preferred embodiment, the composition according to the present invention may comprise an insecticide and/or nematicide as defined herein above and a combination of (T) or the nitrification inhibitor of the compound of formula I and hydroquinone. In a further preferred embodiment, the composition according to the present invention may comprise an insecticide and/or nematicide as defined herein above and a combination of (T) or the nitrification inhibitor of the compound of formula I and ammonium thiosulfate.

In a further preferred embodiment, the composition according to the present invention may comprise an insecticide and/or nematicide as defined herein above and a combination of the nitrification inhibitor of the compound of formula I and LIM US.

In further embodiments, the composition according to the present invention may comprise an insecticide and/or nematicide as defined herein above and a combination of the nitrification in- hibitor of the compound of formula I and two or more entities selected from the group comprising: N-(n-butyl) thiophosphoric acid triamide (NBPT, Agrotain), N-(n-propyl) thiophosphoric acid triamide (NPPT), 2-nitrophenyl phosphoric triamide (2-N PT), further NXPTs known to the skilled person, phenylphosphorodiamidate (PPD/PPDA), hydroquinone, ammonium thiosulfate, and LIM US.

In further embodiments, the composition may, in addition to one, more or all of the above indicated ingredients, in particular in addition to (T) or the nitrification inhibitor of the compound of formula I and an insecticide and/or nematicide, further comprise one or more plant growth regulators. Examples of envisaged plant growth regulators are antiauxins, auxins, cytokinins, defoli- ants, ethylene modulators, ethylene releasers, gibberellins, growth inhibitors, morphactins, growth retardants, growth stimulators, and further unclassified plant growth regulators.

In a preferred embodiment, the composition according to the present invention may comprise a combination of the nitrification inhibitor of the compound of formula I and an insecticide and/or nematicide and at least one compound selected from the group comprising: abscisic acid, ami- dochlor, ancymidol, 6-benzylaminopurine (= N-6 benzyladenine), brassinolide, butralin, chlormequat (chlormequat chloride), choline chloride, cyclanilide, daminozide, diflufenzopyr, dikegulac, dimethipin, 2,6-dimethylpyridine, ethephon, flumetralin, flurprimidol, fluthiacet, forchlorfenuron, gibberellic acid, inabenfide, indole-3-acetic acid, maleic hydrazide, mefluidide, mepiquat (mepiquat chloride), 1-methylcyclopropene (1 -MCP), naphthaleneacetic acid, N-6 benzyladenine, paclobutrazol, prohexadione (prohexadione calcium), prohydrojasmon, thidi- azuron, triapenthenol, tributyl phosphorotrithioate, 2,3,5-tri-iodobenzoic acid, trinexapac-ethyl, and uniconazole. In a preferred embodiment, the composition according to the present invention may comprise a combination of (T) and an insecticide and/or nematicide as defined herein above and at least one compound selected from the group comprising: abscisic acid, amidochlor, ancymidol, 6- benzylaminopurine (= N-6 benzyladenine), brassinolide, butralin, chlormequat (chlormequat chloride), choline chloride, cyclanilide, daminozide, diflufenzopyr, dikegulac, dimethipin, 2,6- dim ethyl pyridine, ethephon, flumetralin, flurprimidol, fluthiacet, forchlorfenuron, gibberellic acid, inabenfide, indole-3-acetic acid, maleic hydrazide, mefluidide, mepiquat (mepiquat chloride), 1- methylcyclopropene (1 -MCP), naphthaleneacetic acid, N-6 benzyladenine, paclobutrazol, prohexadione (prohexadione calcium), prohydrojasmon, thidiazuron, triapenthenol, tributyl phosphorotrithioate, 2,3,5-tri-iodobenzoic acid, trinexapac-ethyl, and uniconazole.

In further specific embodiments, the agricultural compositon as defined herein above may additionally comprises an fertilizer. In case the combination of insecticides and/or nematicides and (T) or nitrification inhibitors is used together with a fertilizer, or when a composition is provided in combination with a fertilizer, such mixtures may be provided or used as agrochemical mix- tures.

In the terms of the present invention "agrochemical mixture" means a combination of at three or more compounds. The term is, however, not restricted to a physical mixture comprising three or more compounds, but refers to any preparation form of said compounds, the use of which many be time- and/or locus-related.

The agrochemical mixtures may, for example, be formulated separately but applied in a temporal relationship, i.e. simultaneously or subsequently, the subsequent application having a time interval which allows a combined action of the compounds.

Furthermore, the individual compounds of the agrochemical mixtures according to the invention such as parts of a kit or parts of the mixture may be mixed by the user himself in a suitable mixing device. In specific embodiments further auxiliaries may be added, if appropriate. The term "fertilizers" is to be understood as chemical compounds applied to promote plant and fruit growth. Fertilizers are typically applied either through the soil (for uptake by plant roots), through soil substituents (also for uptake by plant roots), or by foliar feeding (for uptake through leaves). The term also includes mixtures of one or more different types of fertilizers as mentioned below. The term "fertilizers" can be subdivided into several categories including: a) organic fertilizers (composed of decayed plant/animal matter), b) inorganic fertilizers (composed of chemicals and minerals) and c) urea-containing fertilizers.

Organic fertilizers include manure, e.g. liquid manure, semi-liquid manure, biogas manure, stable manure or straw manure, slurry, liquid dungwater, sewage sludge, worm castings, peat, seaweed, sewage, and guano. Green manure crops are also regularly grown to add nutrients (especially nitrogen) to the soil. Manufactured organic fertilizers include compost, blood meal, bone meal and seaweed extracts. Further examples are enzyme digested proteins, fish meal, and feather meal. The decomposing crop residue from prior years is another source of fertility.

Inorganic fertilizers are usually manufactured through chemical processes (such as the Haber- Bosch process), also using naturally occurring deposits, while chemically altering them (e.g. concentrated triple superphosphate). Naturally occurring inorganic fertilizers include Chilean sodium nitrate, mine rock phosphate, limestone, sulfate of potash, muriate of potash, and raw potash fertilizers.

Typical solid fertilizers are in a crystalline, prilled or granulated form. Typical nitrogen containing inorganic fertilizers are ammonium nitrate, calcium ammonium nitrate, ammonium sulfate, ammonium sulfate nitrate, calcium nitrate, diammonium phosphate, monoammonium phosphate, ammonium thio sulfate and calcium cyanamide.

The inorganic fertilizer may be an NPK fertilizer. "NPK fertilizers" are inorganic

fertilizers formulated in appropriate concentrations and combinations comprising the three main nutrients nitrogen (N), phosphorus (P) and potassium (K) as well as

typically S, Mg, Ca, and trace elements. "NK fertilizers" comprise the two main

nutrients nitrogen (N) and potassium (K) as well as typically S, Mg, Ca, and trace

elements. "NP fertilizers" comprise the two main nutrients nitrogen (N) and phosphorus (P) as well as typically S, Mg, Ca, and trace elements.

Urea-containing fertilizer may, in specific embodiments, be formaldehyde urea, UAN, urea sulfur, stabilized urea, urea based NPK-fertilizers, or urea ammonium sulfate. Also envisaged is the use of urea as fertilizer. In case urea-containing fertilizers or urea are used or provided, it is particularly preferred that urease inhibitors as defined herein above may be added or additionally be present, or be used at the same time or in connection with the urea-containing fertilizers.

Fertilizers may be provided in any suitable form, e.g. as coated or uncoated granules, in liquid or semi-liquid form, as sprayable fertilizer, or via fertigation etc.

Coated fertilizers may be provided with a wide range of materials. Coatings may, for example, be applied to granular or prilled nitrogen (N) fertilizer or to multi-nutrient fertilizers. Typically, urea is used as base material for most coated fertilizers. The present invention, however, also relates to the use of other base materials for coated fertilizers, any one of the fertilizer materials defined herein. In certain embodiments, elemental sulfur may be used as fertilizer coating. The coating may be performed by spraying molten S over urea granules, followed by an application of sealant wax to close fissures in the coating. In a further embodiment, the S layer may be covered with a layer of organic polymers, preferably a thin layer of organic polymers. In another embodiment, the coated fertilizers are preferably physical mixtures of coated and non-coated fertilizers.

Further envisaged coated fertilizers may be provided by reacting resin-based polymers on the surface of the fertilizer granule. A further example of providing coated fertilizers includes the use of low permeability polyethylene polymers in combination with high permeability coatings.

In specific embodiments the composition and/or thickness of the fertilizer coating may be adjusted to control, for example, the nutrient release rate for specific applications. The duration of nutrient release from specific fertilizers may vary, e.g. from several weeks to many months. The presence of (T) or nitrification inhibitors and insecticides and/or nematicides in a mixture with coated fertilizers may accordingly be adapted. It is, in particular, envisaged that the nutrient release involves or is accompanied by the release of a nitrification inhibitor or (T) and an insecticide and/or nematicide according to the present invention. Coated fertilizers may be provided as controlled release fertilizers (CRFs). In specific embodiments these controlled release fertilizers are fully coated N-P-K fertilizers, which are homogeneous and which typically show a pre-defined longevity of release. In further embodiments, the CRFs may be provided as blended controlled release fertilizer products which may contain coated, uncoated and/or slow release components. In certain embodiments, these coated ferti- lizers may additionally comprise micronutrients. In specific embodiments these fertilizers may show a pre-defined longevity, e.g. in case of N-P-K fertilizers.

Additionally envisaged examples of CRFs include patterned release fertilizers. These fertilizers typically show a pre-defined release patterns (e.g. hi/standard/lo) and a pre-defined longevity. In exemplary embodiments fully coated N-P-K, Mg and micronutrients may be delivered in a patterned release manner.

Also envisaged are double coating approaches or coated fertilizers based on a programmed release.

In further embodiments the fertilizer mixture may be provided as, or may comprise or contain a slow release fertilizer. The fertilizer may, for example, be released over any suitable period of time, e.g. over a period of 1 to 5 months, preferably up to 3 months. Typical examples of ingredients of slow release fertilizers are IBDU (isobutylidenediurea), e.g. containing about 31-32 % nitrogen, of which 90% is water insoluble; or UF, i.e. an urea-formaldehyde product which contains about 38 % nitrogen of which about 70 % may be provided as water insoluble nitrogen; or CDU (crotonylidene diurea) containing about 32 % nitrogen; or MU (methylene urea) containing about 38 to 40% nitrogen, of which 25-60 % is typically cold water insoluble nitrogen; or MDU (methylene diurea) containing about 40% nitrogen, of which less than 25 % is cold water insolu- ble nitrogen; or MO (methylol urea) containing about 30% nitrogen, which may typically be used in solutions; or DMTU (diimethylene triurea) containing about 40% nitrogen, of which less than 25% is cold water insoluble nitrogen; or TMTU (tri methylene tetraurea), which may be provided as component of UF products; or TMPU (tri methylene pentaurea), which may also be provided as component of UF products; or UT (urea triazone solution) which typically contains about 28 % nitrogen.

Any of the above mentioned fertilizers or fertilizer forms may suitably be combined. For instance, slow release fertilizers may be provided as coated fertilizers. They may also be com- bined with other fertilizers or fertilizer types. The same applies to the presence of (T) or a nitrification inhibitor or an insecticide and/or nematicide according to the present invention, which may be adapted to the form and chemical nature of the fertilizer and accordingly be provided such that its release accompanies the release of the fertilizer, e.g. is released at the same time or with the same frequency. The present invention further relates to fertilizer or fertilizer forms as defined herein above in combination with nitrification inhibitors as defined herein above and insecticides and/or nematicides and further in combination with urease inhibitors as defined herein above. Such combinations may be provided as coated or uncaoted forms and/or as slow or fast release forms. Preferred are combinations with slow release fertilizers including a coating. In further embodiments, also different release schemes are envisaged, e.g. a slower or a faster release.

The term "fertigation" as used herein refers to the application of fertilizers, optionally soil amendments, and optionally other water-soluble products together with water through an irrigation system to a plant or to the locus where a plant is growing or is intended to grow, or to a soil substituent as defined herein below. For example, liquid fertilizers or dissolved fertilizers may be provided via fertigation directly to a plant or a locus where a plant is growing or is intended to grow. Likewise, (T) or nitrification inhibitors according to the present invention, or in combination with additional nitrification inhibitors, may be provided via fertigation to plants or to a locus where a plant is growing or is intended to grow. Fertilizers and (T) or nitrification inhibitors ac- cording to the present invention, or in combination with additional nitrification inhibitors, may be provided together, e.g. dissolved in the same charge or load of material (typically water) to be irrigated. In further embodiments, fertilizers and (T) or nitrification inhibitors may be provided at different points in time. For example, the fertilizer may be fertigated first, followed by (T) or the nitrification inhibitor, or preferably, (T) or the nitrification inhibitor may be fertigated first, followed by the fertilizer. The time intervals for these activities follow the herein above outlined time intervals for the application of fertilizers and (T) or nitrification inhibitors. Also envisaged is a repeated fertigation of fertilizers and (T) or nitrification inhibitors according to the present invention, either together or intermittently, e.g. every 2 hours, 6 hours, 12 hours, 24 hours, 2 days, 3 days, 4 days, 5 days, 6 days or more.

In particularly preferred embodiments, the fertilizer is an ammonium-containing fertilizer.

The agrochemical mixture according to the present invention may comprise one fertilizer as defined herein above and (T) or one nitrification inhibitor of formula I as defined herein above and one insecticide and/or nematicide as defined herein above. In further embodiments, the agrochemical mixture according to the present invention may comprise at least one or more than one fertilizer as defined herein above, e.g. 2, 3, 4, 5, 6, 6, 7, 8, 9, 10 or more different fertilizers (including inorganic, organic and urea-containing fertilizers) and (T) or at least one nitrifi- cation inhibitor of formula I and at least one insecticide and/or nematicide as defined herein above, preferably a combination as defined in Table 2 or Table 3.

In another group of embodiments the agrochemical mixture according to the present invention may comprise at least one or more than one (thio)phosphoric acid triamide (T) or nitrification inhibitor of formula I as defined herein above, preferably more than one (thio)phosphoric acid triamide (T) or nitrification inhibitor of formula I selected from Table 1 , e.g. 2, 3, 4, 5, 6, 6, 7, 8, 9, 10 or more different (thio)phosphoric acid triamides (T) or nitrification inhibitors as defined herein above or as provided in Table 1 and at least one fertilizer as defined herein above and at least one insecticide and/or nematicide as defined herein above.

The term "at least one" is to be understood as 1 , 2, 3 or more of the respective compound selected from the group consisting of fertilizers as defined herein above (also designated as compound C), and (T) or nitrification inhibitors of formula I as defined herein above (also designated as compound A), and insecticides and/or nematicides (also designated as compound B).

In addition to at least one fertilizer and (T) or at least one nitrification inhibitor as defined herein above and at least one insecticide and/or nematicide, an agrochemical mixture may comprise further ingredients, compounds, active compounds or compositions or the like. For example, the agrochemical mixture may additionally comprise or composed with or on the basis of a carrier, e.g. an agrochemical carrier, preferably as defined herein. In further embodiments, the agrochemical mixture may further comprise at least one additional pesticidal compound. For example, the agrochemical mixture may additionally comprise at least one fungicidal compound and/or at least one insecticidal compound. In further embodiments, the agrochemical mixture may, in addition to the above indicated ingre- dientsfurther comprise alternative or additional nitrification inhibitors such as linoleic acid, alpha- linolenic acid, methyl p-coumarate, methyl ferulate, MHPP, Karanjin, brachialacton, p- benzoquinone sorgoleone, nitrapyrin, dicyandiamide (DCD), 3,4-dimethyl pyrazole phosphate (DMPP), 4-amino-1 ,2,4-triazole hydrochloride (ATC), 1-amido-2-thiourea (ASU), 2-amino-4- chloro-6-methylpyrimidine (AM), 5-ethoxy-3-trichloromethyl-1 ,2,4-thiodiazole (terrazole), ammo- niumthiosulfate (ATU), 3-methylpyrazol (3-MP), 3,5-dimethylpyrazole (DM P), 1 ,2,4-triazol, thiourea (TU) and/or sulfathiazole (ST).

Furthermore, the invention relates to a method for increasing the health of a plant, comprising treating a plant growing on soil and/or the locus where the plant is growing or is intended to grow with a combination of (T) or at least one nitrification inhibitor and at least one insecticide and/or nematicide as defined herein above, preferably with a combination as defined in Table 2 or Table 3, or a composition comprising said combination. The term "plant" is to be understood as a plant of economic importance and/or men-grown plant. In certain embodiments, the term may also be understood as plants which have no or no significant economic importance. The plant is preferably selected from agricultural, silvicultural and horticultural (including ornamental) plants. The term also relates to genetically modified plants.

The term "plant" as used herein further includes all parts of a plant such as germinating seeds, emerging seedlings, plant propagules, herbaceous vegetation as well as established woody plants including all belowground portions (such as the roots) and aboveground portions.

Within the context of the method for increasing the health of plant it is assumed that the plant is growing on soil. In specific embodiments, the plant may also grow differently, e.g. in synthetic laboratory environments or on soil substituents, or be supplemented with nutrients, water etc. by artificial or technical means. In such scenarios, the invention relates to a treatment of the zone or area where the nutrients, water etc. are provided to the plant. Also envisaged is that the plant grows in green houses or similar indoor facilities.

The term "locus" is to be understood as any type of environment, soil, soil substituents, area or material where the plant is growing or intended to grow. Preferably, the term relates to soil or soil substituent on which a plant is growing.

In one embodiment, the plant to be treated according to the method of the invention is an agricultural plant. "Agricultural plants" are plants of which a part (e.g. seeds) or all is harvested or cultivated on a commercial scale or which serve as an important source of feed, food, fibres (e.g. cotton, linen), combustibles (e.g. wood, bioethanol, biodiesel, biomass) or other chemical compounds. Preferred agricultural plants are for example cereals, e.g. wheat, rye, barley, tritica- le, oats, sorghum or rice, beet, e.g. sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, e.g. apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries, blackberries or gooseberries; leguminous plants, such as lentils, peas, alfalfa or soybeans; oil plants, such as rape, oil-seed rape, canola, linseed, mustard, olives, sunflowers, coconut, cocoa beans, castor oil plants, oil palms, ground nuts or soybeans; cucurbits, such as squashes, cucumber or melons; fiber plants, such as cotton, flax, hemp or jute; citrus fruit, such as oranges, lemons, grapefruits or mandarins; vegetables, such as spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, cucurbits or paprika; lauraceous plants, such as avocados, cinnamon or camphor; energy and raw material plants, such as corn, soybean, rape, canola, sugar cane or oil palm; tobacco; nuts; coffee; tea; bananas; vines (table grapes and grape juice grape vines); hop; turf; natural rubber plants.

In a further embodiment, the plant to be treated according to the method of the invention is a horticultural plant. The term "horticultural plants" are to be understood as plants which are commonly used in horticulture, e.g. the cultivation of ornamentals, vegetables and/or fruits. Examples for ornamentals are turf, geranium, pelargonia, petunia, begonia and fuchsia. Examples for vegetables are potatoes, tomatoes, peppers, cucurbits, cucumbers, melons, watermelons, garlic, onions, carrots, cabbage, beans, peas and lettuce and more preferably from tomatoes, onions, peas and lettuce. Examples for fruits are apples, pears, cherries, strawberry, citrus, peaches, apricots and blueberries.

In a further embodiment, the plant to be treated according to the method of the invention is an ornamental plants. "Ornamental plants" are plants which are commonly used in gardening, e.g. in parks, gardens and on balconies. Examples are turf, geranium, pelargonia, petunia, begonia and fuchsia.

In another embodiment of the present invention, the plant to be treated according to the method of the invention is a silvicultural plants. The term "silvicultural plant" is to be understood as trees, more specifically trees used in reforestation or industrial plantations. Industrial plantations generally serve for the commercial production of forest products, such as wood, pulp, paper, rubber tree, Christmas trees, or young trees for gardening purposes. Examples for silvicultural plants are conifers, like pines, in particular Pinus spec, fir and spruce, eucalyptus, tropical trees like teak, rubber tree, oil palm, willow (Salix), in particular Salix spec, poplar (cottonwood), in particular Populus spec, beech, in particular Fagus spec, birch, oil palm, and oak.

The term "plant propagation material" is to be understood to denote all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e.g. pota- toes), which can be used for the multiplication of the plant. This includes seeds, grains, roots, fruits, tubers, bulbs, rhizomes, cuttings, spores, offshoots, shoots, sprouts and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil, meristem tissues, single and multiple plant cells and any other plant tissue from which a complete plant can be obtained.

The term "genetically modified plants" is to be understood as plants, which genetic material has been modified by the use of recombinant DNA techniques in a way that under natural circumstances it cannot readily be obtained by cross breeding, mutations or natural recombination. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant. Such genetic modifications also include but are not limited to targeted post-translational modification of protein(s), oligo- or polypeptides e. g. by glycosylation or polymer additions such as prenylated, acetylated or farne- sylated moieties or PEG moieties. Plants that have been modified by breeding, mutagenesis or genetic engineering, e. g. have been rendered tolerant to applications of specific classes of herbicides, such as auxin herbicides such as dicamba or 2,4-D; bleacher herbicides such as hydroxylphenylpyruvate dioxy- genase (H PPD) inhibitors or phytoene desaturase (PDS) inhibitors; acetolactate synthase (ALS) inhibitors such as sulfonyl ureas or imidazolinones; enolpyruvylshikimate-3-phosphate synthase (EPSPS) inhibitors, such as glyphosate; glutamine synthetase (GS) inhibitors such as glufosinate; protoporphyrinogen-IX oxidase inhibitors; lipid biosynthesis inhibitors such as acetyl CoA carboxylase (ACCase) inhibitors; or oxynil (i. e. bromoxynil or ioxynil) herbicides as a result of conventional methods of breeding or genetic engineering. Furthermore, plants have been made resistant to multiple classes of herbicides through multiple genetic modifications, such as resistance to both glyphosate and glufosinate or to both glyphosate and a herbicide from another class such as ALS inhibitors, HPPD inhibitors, auxin herbicides, or ACCase inhibitors. These herbicide resistance technologies are e. g. described in Pest Managem. Sci. 61 , 2005, 246; 61 , 2005, 258; 61 , 2005, 277; 61 , 2005, 269; 61 , 2005, 286; 64, 2008, 326; 64, 2008, 332; Weed Sci. 57, 2009, 108; Austral. J. Agricult. Res. 58, 2007, 708; Science 316, 2007, 1 185; and references quoted therein. Several cultivated plants have been rendered tolerant to herbicides by conventional methods of breeding (mutagenesis), e. g. Clearfield^® summer rape (Canola, BASF SE, Germany) being tolerant to imidazolinones, e. g. imazamox, or ExpressSun^® sunflowers (DuPont, USA) being tolerant to sulfonyl ureas, e. g. tribenuron. Genetic engineering methods have been used to render cultivated plants such as soybean, cotton, corn, beets and rape, tolerant to herbicides such as glyphosate and glufosinate, some of which are commercially available under the trade names RoundupReady^® (glyphosate-tolerant, Monsanto, U.S.A.), Cul- tivance^® (imidazolinone tolerant, BASF SE, Germany) and LibertyLink^® (glufosinate-tolerant, Bayer CropScience, Germany).

Furthermore, plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly from Bacillus thuringiensis, such as δ-endotoxins, e. g. CrylA(b), CrylA(c), CrylF, CrylF(a2), CryllA(b), CrylllA, CrylllB(bl ) or Cry9c; vegetative insecticidal pro- teins (VIP), e. g. VIP1 , VIP2, VIP3 or VIP3A; insecticidal proteins of bacteria colonizing nematodes, e. g. P 'h otorh a bd 'us spp. or Xenorhabdus spp.; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins; toxins produced by fungi, such Streptomycetes toxins, plant lectins, such as pea or barley lectins; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors; ribosome-inactivating proteins (RIP), such as ricin, maize-RIP, abrin, luffin, saporin or bryodin; steroid metabolism enzymes, such as 3-hydroxysteroid oxidase, ecdyster- oid-IDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase; ion channel blockers, such as blockers of sodium or calcium channels; juvenile hormone esterase; diuretic hormone receptors (helicokinin receptors); stilbene synthase, bibenzyl synthase, chitinases or glucanases. In the context of the present invention these insecticidal proteins or toxins are to be understood expressly also as pre-toxins, hybrid proteins, truncated or otherwise modified proteins. Hybrid proteins are characterized by a new combination of protein domains, (see, e. g. WO 02/015701). Further examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, e. g., in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/18810 und WO 03/52073.

The methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, e. g. in the publications mentioned above. These insecticidal proteins contained in the genetically modified plants impart to the plants producing these proteins tolerance to harmful pests from all taxonomic groups of arthropods, especially to beetles (Coeloptera), two-winged insects (Diptera), and moths (Lepidoptera) and to nematodes (Nema- toda). Genetically modified plants capable to synthesize one or more insecticidal proteins are, e. g., described in the publications mentioned above, and some of which are commercially available such as YieldGard^® (corn cultivars producing the Cry1 Ab toxin), YieldGard^® Plus (corn culti- vars producing Cry1 Ab and Cry3Bb1 toxins), Starlink^® (corn cultivars producing the Cry9c tox- in), Herculex^® RW (com cultivars producing Cry34Ab1 , Cry35Ab1 and the enzyme phosphino- thricin-N-acetyltransferase [PAT]); NuCOTN^® 33B (cotton cultivars producing the Cry1 Ac toxin), Bollgard^® I (cotton cultivars producing the Cryl Ac toxin), Bollgard^® II (cotton cultivars producing Cry1 Ac and Cry2Ab2 toxins); VIPCOT^® (cotton cultivars producing a VIP-toxin); NewLeaf^® (po- tato cultivars producing the Cry3A toxin); Bt-Xtra^®, NatureGard^®, KnockOut^®, BiteGard^®, Pro- tecta^®, Bt1 1 (e. g. Agrisure^® CB) and Bt176 from Syngenta Seeds SAS, France, (corn cultivars producing the Cryl Ab toxin and PAT enyzme), M IR604 from Syngenta Seeds SAS, France (corn cultivars producing a modified version of the Cry3A toxin, c.f. WO 03/018810), MON 863 from Monsanto Europe S.A., Belgium (corn cultivars producing the Cry3Bb1 toxin), IPC 531 from Monsanto Europe S.A., Belgium (cotton cultivars producing a modified version of the

Cryl Ac toxin) and 1507 from Pioneer Overseas Corporation, Belgium (corn cultivars producing the Cry1 F toxin and PAT enzyme).

Furthermore, plants are also covered that are by the use of recombinant DNA techniques capa- ble to synthesize one or more proteins to increase the resistance or tolerance of those plants to bacterial, viral or fungal pathogens. Examples of such proteins are the so-called "pathogenesis- related proteins" (PR proteins, see, e. g. EP-A 392 225), plant disease resistance genes (e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the Mexican wild potato Solarium bulbocastanum) or T4-lysozym (e. g. potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Er- winia amylvora). The methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, e. g. in the publications mentioned above. Furthermore, plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the productivity (e. g. bio mass production, grain yield, starch content, oil content or protein content), tolerance to drought, salinity or other growth-limiting environmental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants.

Furthermore, plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve human or animal nutrition, e. g. oil crops that produce health-promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e. g. Nexera^® rape, DOW Agro Sciences, Cana- da).

Furthermore, plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve raw material production, e. g. potatoes that produce increased amounts of amylopectin (e. g. Amflora^® potato, BASF SE, Germany).

The term "soil substituent" as used herein refers to a substrate which is able to allow the growth of a plant and does not comprise usual soil ingredients. This substrate is typically an anorganic substrate which may have the function of an inert medium. It may, in certain embodiments, also comprise organic elements or portions. Soil substituents may, for example, be used in hydrocul- ture or hydroponic approaches, i.e. wherein plants are grown in soilless medium and/or aquatic based environments. Examples of suitable soil substituents, which may be used in the context of the present invention, are perlite, gravel, biochar, mineral wool, coconut husk, phyllosilicates, i.e. sheet silicate minerals, typically formed by parallel sheets of silicate tetrahedra with Si₂0₅ or a 2:5 ratio, or clay aggregates, in particular expanded clay aggregates with a diameter of about 10 to 40 mm. Particularly preferred is the employment of vermiculite, i.e. a phyllosilicate with 2 tetrahedral sheets for every one octahedral sheet present.

The use of soil substituents may, in specific embodiments, be combined with fertigation or irri- gation as defined herein.

In specific embodiments, the treatment may be carried out during all suitable growth stages of a plant as defined herein. For example, the treatment may be carried out during the BBCH principle growth stages. The term "BBCH principal growth stage" refers to the extended BBCH-scale which is a system for a uniform coding of phenologically similar growth stages of all mono- and dicotyledonous plant species in which the entire developmental cycle of the plants is subdivided into clearly recognizable and distinguishable longer-lasting developmental phases. The BBCH-scale uses a decimal code system, which is divided into principal and secondary growth stages. The abbre- viation BBCH derives from the Federal Biological Research Centre for Agriculture and Forestry (Germany), the Bundessortenamt (Germany) and the chemical industry.

In one embodiment the invention relates to a method for increasing the health of a plant comprising treating a plant growing on soil or soil substituents and/or the locus where the plant is growing with a combination as defined herein above, or a corresponding composition or agricultural composition as defined herein above at a growth stage (GS) between GS 00 and GS 65 BBCH of the plant.

In one embodiment the invention relates to a method for increasing the health of a plant com- prising treating a plant growing on soil or soil substituents and/or the locus where the plant is growing with a combination as defined herein above, or a corresponding composition or agricultural composition as defined herein above at a growth stage (GS) between GS 00 to GS 33 BBCH of the plant. In a preferred embodiment the invention relates to a method for increasing the health of a plant comprising treating a plant growing on soil or soil substituents and/or the locus where the plant is growing with a combination as defined herein above, or a corresponding composition or agricultural composition as defined herein aboveat an early growth stage (GS), in particular a GS 00 to GS 05, or GS 00 to GS 10, or GS 00 to GS 15, or GS 00 to GS 20, or GS 00 to GS 25 or GS 00 to GS 33 BBCH of the plant. In particularly preferred embodiments, the method comprises treating a plant growing on soil or soil substituents and/or the locus where the plant is growing with a combination as defined herein above, or a corresponding composition or agricultural composition as defined herein above during growth stages including GS 00. In a further, specific embodiment of the invention a combination as defined herein above, or a corresponding composition or agricultural composition as defined herein above is applied to a plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow at a growth stage between GS 00 and GS 55 BBCH, or of the plant.

In a further embodiment of the invention a combination as defined herein above, or a corresponding composition or agricultural composition as defined herein above is applied to a plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow at the growth stage between GS 00 and GS 47 BBCH of the plant.

In one embodiment of the invention a combination as defined herein above, or a corresponding composition or agricultural composition as defined herein above is applied to a plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow before and at sowing, before emergence, and until harvest (GS 00 to GS 89 BBCH), or at a growth stage (GS) between GS 00 and GS 65 BBCH of the plant.

In a preferred embodiment the invention relates to a method for increasing the health of a plant comprising treating a plant growing on soil or soil substituents and/or the locus where the plant is growing with a combination as defined herein above, or a corresponding composition or agri- cultural composition as defined herein above wherein the plant and/or the locus where plant is growing or is intended to grow is additionally provided with at least one fertilizer. The fertilizer may be any suitable fertilizer, preferably a fertilizer as defined herein above. Also envisaged is the application of more than one fertilizer, e.g. 2, 3, 4, 5, 6, 7, 8, 9, 10 fertilizers, or of different fertilizer classes or categories.

In specific embodiments of the invention, a combination as defined herein above, or a corresponding composition or agricultural composition as defined herein above and at least one fertilizer is applied to a plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow at a growth stage between GS OOand GS 33 BBCH of the plant.

In specific embodiments of the invention a combination as defined herein above, or a corresponding composition or agricultural composition as defined herein above is applied to a plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow at a growth stage between GS 00 and GS 55 BBCH of the plant.

In further specific embodiments of the invention a combination as defined herein above, or a corresponding composition or agricultural composition as defined herein aboveand at least one fertilizer is applied to a plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow at sowing, before emergence, or at a growth stage (GS) between GS 00 and GS 65 BBCH of the plant.

According to a preferred embodiment of the present invention the application of (T) or said nitrification inhibitor as defined herein (component A) and of said insecticide and/or nematicide (component B) is carried out simultaneously or with a time lag. The term "time lag" as used herein means that either (T) or the nitrification inhibitor is applied before the insecticide and/or nematicide to the plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow; or the insecticide and/or nematicide is applied before (T) or the nitrification inhibitor to the plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow. Such time lag may be any suitable period of time which still allows to provide a nitrification inhibiting effect in the context of insecticide and/or nematicide usage, or which provides for a reduction in growth of phytopathogenic insects or arachnids or nematodes in the context of the usage of (T) or a nitrification inhibitor. For example, the time lag may be a time period of 1 day, 2 days, 3 days, 4 days, 5 days, 6 days, 7 days, 8 days, 9 days, 10 days, 1 1 days, 12 days, 13 days, 14 days, 3 weeks 4 weeks, 5 weeks, 6 weeks, 7 weeks, 8 weeks , 9 weeks, 10 weeks, 1 1 weeks, 12 weeks, 4 months, 5 months, 6 months, 7 months, 8 months, 9 months, 10 months or more or any time period in between the mentioned time periods. Preferably, the time lag is an interval of 1 day, 2 days, 3 days, 1 week, 2 weeks or 3 weeks. The time lag preferably refers to situations in which (T) or the nitrification inhibitor as defined above is provided 1 day, 2 days, 3 days, 4 days, 5 days, 6 days, 7 days, 8 days, 9 days, 10 days, 11 days, 12 days, 13 days, 14 days, 3 weeks 4 weeks, 5 weeks, 6 weeks, 7 weeks, 8 weeks , 9 weeks, 10 weeks, 11 weeks, 12 weeks, 4 months, 5 months, 6 months, 7 months, 8 months, 9 months, 10 months or more or any time period in between the mentioned time periods before the application of an insecticide and/or nematicide as defined herein above. According to a preferred embodiment of the present invention the application of said combination of a nitrification inhibitor or (T) and an insecticide and/or nematicide as defined herein above, or a corresponding composition or agricultural composition as defined herein above and of said fertilizer (component C) as defined herein above is carried out simultaneously or with a time lag. The term "time lag" as used herein means that either (T) or the nitrification inhibitor and/or insecticide and/or nematicide is applied before the fertilizer to the plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow; or the fertilizer is applied before (T) or the nitrification inhibitor and/or insecticide and/or nematicide to the plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow. Such time lag may be any suitable period of time which still allows to provide a nitrification inhibiting effect in the context of fertilizer usage, or which provides for a reduction in growth of or elimination of phytopathogenic insects, arachnids or nematodes in the context of the usage of (T) or nitrification inhibitor. For example, the time lag may be a time period of 1 day, 2 days, 3 days, 4 days, 5 days, 6 days, 7 days, 8 days, 9 days, 10 days, 1 1 days, 12 days, 13 days, 14 days, 3 weeks 4 weeks, 5 weeks, 6 weeks, 7 weeks, 8 weeks , 9 weeks, 10 weeks, 11 weeks, 12 weeks, 4 months, 5 months, 6 months, 7 months, 8 months, 9 months, 10 months or more or any time period in between the mentioned time periods. Preferably, the time lag is an interval of 1 day, 2 days, 3 days, 1 week, 2 weeks or 3 weeks. The time lag preferably refers to situations in which (T) or the nitrification inhibitor as defined above is provided 1 day, 2 days, 3 days, 4 days, 5 days, 6 days, 7 days, 8 days, 9 days, 10 days, 1 1 days, 12 days, 13 days, 14 days, 3 weeks 4 weeks, 5 weeks, 6 weeks, 7 weeks, 8 weeks , 9 weeks, 10 weeks, 11 weeks, 12 weeks, 4 months, 5 months, 6 months, 7 months, 8 months, 9 months, 10 months or more or any time period in between the mentioned time periods before the application of a fertilizer as defined herein above. In another specific embodiment of the invention one component of a combination as defined herein above, or of a corresponding composition or agricultural composition as defined herein above is applied between GS 00 to GS 33 BBCH of the plant, or between GS 00 and GS 65 BBCH of the plant, provided that the application of the other component of said combination as defined herein above, or a of corresponding composition or agricultural composition as defined herein above is carried out with a time lag of at least 1 day, e.g. a time lag of 1 day, 2 days, 3 days, 4 days, 5 days, 6 days, 7 days, 8 days, 9 days, 10 days, 1 1 days, 12 days, 13 days, 14 days, 3 weeks 4 weeks, 5 weeks, 6 weeks, 7 weeks, 8 weeks , 9 weeks, 10 weeks, or more or any time period in between the mentioned time periods. It is preferred that one component of thecombination as defined herein above, or of a corresponding composition or agricultural composition as defined herein above, which is applied between GS 00 to GS 33 BBCH of the plant, is provided 1 day, 2 days, 3 days, 4 days, 5 days, 6 days, 7 days, 8 days, 9 days, 10 days, 1 1 days, 12 days, 13 days, 14 days, 3 weeks 4 weeks, 5 weeks, 6 weeks, 7 weeks, 8 weeks , 9 weeks, 10 weeks, 1 1 weeks, or 12 weeks before the application of the other component.

In another specific embodiment of the invention, at least one fertilizer as defined herein above is applied between GS 00 to GS 33 BBCH of the plant or between GS 00 and GS 65 BBCH of the plant, provided that the application of a combination as defined herein above, or of at least one component of said combination, or a corresponding composition or agricultural composition as defined herein above, is carried out with a time lag of at least 1 day, e.g. a time lag of 1 day, 2 days, 3 days, 4 days, 5 days, 6 days, 7 days, 8 days, 9 days, 10 days, 1 1 days, 12 days, 13 days, 14 days, 3 weeks 4 weeks, 5 weeks, 6 weeks, 7 weeks, 8 weeks , 9 weeks, 10 weeks or more or any time period in between the mentioned time periods. According to a specific embodiment of the present invention a plant growing on soil or soil sub- stituents and/or the locus where the plant is growing or is intended to grow is treated at least once with at least one component of a combination as defined herein above or of a corresponding composition or agricultural composition as defined herein above, or with said combination. In a further specific embodiment of the present invention a plant growing on soil or soil substitu- ents and/or the locus where the plant is growing or is intended to grow is treated at least once with a combination as defined herein above, or one of its components, or a corresponding composition or agricultural composition as defined herein above, and at least once with a fertilizer as defined herein above. The term "at least once" means that the application may be performed one time, or several times, i.e. that a repetition of the treatment with (T) or a nitrification inhibitor and/or a fertilizer may be envisaged. Such a repetition may a 2 times, 3 times, 4 times, 5 times, 6 times, 7 times, 8 times, 9 times, 10 times or more frequent repetition of the treatment with a combination as defined herein above, or one of its components, or a corresponding composition or agricultural composition as defined herein above and/or a fertilizer. The repetition of treatment with a combination as defined herein above, or one of its components, or a corresponding composition or agricultural composition as defined herein above and a fertilizer may further be different. For example, while the fertilizer may be applied only once, the a combination as defined herein above, or one of its components, or a corresponding composition or agricultural composition as defined herein above may be applied 2 times, 3 times, 4 times etc. Alternatively, while (T) or the nitrification inhibitor may be applied only once, the fertilizer may be applied 2 times, 3 times, 4 times etc. Further envisaged are all combinations of numerical different numbers of repetitions for the application of a combination as defined herein above, or one of its components, or a cor- responding composition or agricultural composition as defined herein above and opitonally a fertilizer as defined herein above.

Such a repeated treatment may further be combined with a time lag between the treatment of the combination as defined herein above, or one of its components, or a corresponding composition or agricultural composition as defined herein above and optionally a fertilizer as described above.

The time interval between a first application and second or subsequent application of a combination as defined herein above, or one of its components or a corresponding composition or agricultural composition as defined herein above and/or a fertilizer may be any suitable interval. This interval may range from a few seconds up to 3 months, e.g. from a few seconds up to 1 month, or from a few seconds up to 2 weeks. In further embodiments, the time interval may range from a few seconds up to 3 days or from 1 second up to 24 hours.

In further specific embodiments, a method for increasing the health of a plant as described above is carried out by treating a plant growing on soil or soil substituents and/or the locus where the plant is growing or is intended to grow with at least one agricultural mixture as defined herein above.

In another embodiment of the invention, an agrochemical mixture comprising an ammonium or urea-containing fertilizer and (T) or at least one nitrification inhibitor as defined herein above is applied before and at sowing, before emergence, and until shooting/shoot development (GS 00 to GS 33 BBCH) of the plant. In case the agricultural mixture is provided as kit of parts or as non-physical mixture, it may be applied with a time lag between the application of (T) or the nitrification inhibitor and the fertilizer or between the application of (T) or the nitrification inhibitor a secondary or further ingredient, e.g. a pesticidal compound as mentioned herein above.

In a further embodiment plant propagules are preferably treated simultaneously (together or separately) or subsequently. The term "propagules" or "plant propagules" is to be understood to denote any structure with the capacity to give rise to a new plant, e.g. a seed, a spore, or a part of the vegetative body capable of independent growth if detached from the parent. In a preferred embodiment, the term "propagules" or "plant propagules" denotes for seed. For a method as described above, or for a use according to the invention, the application rates of (T) or nitrification inhibitors, i.e. of the compound of formula I are between 0,01 g and 5 kg of active ingredient per hectare, preferably between 1 g and 1 kg of active ingredient per hectare, especially preferred between 50 g and 300 g of active ingredient per hectare depending on different parameters such as the specific active ingredient applied and the plant species treated. In the treatment of seed, amounts of from 0.001 g to 20 g per kg of seed, preferably from 0.01 g to 10 g per kg of seed, more preferably from 0.05 to 2 g per kg of seed of (T) or nitrification inhibitors may be generally required. As a matter of course, if (T) or nitrification inhibitors and fertilizers (or other ingredients), or if mixtures thereof are employed, the compounds may be used in an effective and non-phytotoxic amount. This means that they are used in a quantity which allows to obtain the desired effect but which does not give rise to any phytotoxic symptoms on the treated plant or on the plant raised from the treated propagule or treated soil. For the use according to the invention, the application rates of fertilizers may be between 10 kg and 300 kg per hectare, preferably between 50 kg and 250 kg per hectare.

(T) or the nitrification inhibitor compounds according to the invention, e.g. compound I as defined herein above, or derivative thereof as defined herein above can be present in different structural or chemical modifications whose biological activity may differ. They are likewise subject matter of the present invention.

(T) or the nitrification inhibitor compounds according to the invention, their N-oxides and/or salts etc. may be converted into customary types of compositions, e.g. agrochemical or agricultural compositons such as solutions, emulsions, suspensions, dusts, powders, pastes and granules.

The composition type depends on the particular intended purpose; in each case, it should ensure a fine and uniform distribution of the compound according to the invention. Examples for composition types are suspensions (SC, 00, FS), emulsifiable concentrates (EC), emulsions (EW, EO, ES), microemulsions (M E), pastes, pastilles, wettable powders or dusts (WP, SP, SS, WS, OP, OS) or granules (GR, FG, GG, MG), which can be watersoluble or wettable, as well as gel formulations for the treatment of plant propagation materials such as seeds (GF). Usually the composition types (e.g. SC, 00, FS, EC, WG, SG, WP, SP, SS, WS, GF) are employed diluted. Composition types such as OP, OS, GR, FG, GG and MG are usually used undiluted.

The compositions are prepared in a known manner (see, for example, US 3,060,084, EP 707 445 (for liquid concentrates), Browning: "Agglomeration", Chemical Engineering, Dec. 4, 1967, 147- 48, Perry's Chemical Engineer's Handbook, 4th Ed., McGraw-Hili, New York, 1963, S. 8-57 und ff. WO 91/13546, US 4,172,714, US 4,144,050, US 3,920,442, US 5,180,587, US

5,232,701 , US 5,208,030, GB 2,095,558, US 3,299,566, Klingman: Weed Control as a Science (J. Wiley & Sons, New York, 1961), Hance et al.: Weed Control Handbook (8th Ed., Blackwell Scientific, Oxford, 1989) and Mollet, H . and Grubemann, A.: Formulation technology (Wiley VCH Verlag, Weinheim, 2001 ). Agrochemical compositions or mixtgures may also comprise auxiliaries which are customary in agrochemical compositions. The auxiliaries used depend on the particular application form and active substance, respectively.

Examples for suitable auxiliaries are solvents, solid carriers, dispersants or emulsifiers (such as further solubilizers, protective colloids, surfactants and adhesion agents), organic and anorganic thickeners, bactericides, anti-freezing agents, anti-foaming agents, if appropriate colorants and tackifiers or binders (e.g. for seed treatment formulations). Suitable solvents are water, organic solvents such as mineral oil fractions of medium to high boiling point, such as kerosene or die- sel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, e.g. toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphtha- lenes or their derivatives, alcohols such as methanol, ethanol, propanol, butanol and cyclohex- anol, glycols, ketones such as cyclohexanone and gamma-butyrolactone, fatty acid dimethyla- mides, fatty acids and fatty acid esters and strongly polar solvents, e.g. amines such as N- methylpyrrolidone. Suitable surfactants (adjuvants, wetters, tackifiers, dispersants or emulsifiers) are alkali metal, alkaline earth metal and ammonium salts of aromatic sulfonic acids, such as ligninsoulfonic acid (Borresperse® types, Borregard, Norway) phenolsulfonic acid, naphthalenesulfonic acid (Mor- wet® types, Akzo Nobel, U.S.A.), dibutylnaphthalene-sulfonic acid (Nekal® types, BASF, Ger- manY), and fatty acids, alkylsulfonates, alkylarylsulfonates, alkyl sulfates, laurylether sulfates, fatty alcohol sulfates, and sulfated hexa-, hepta- and octadecanolates, sulfated fatty alcohol glycol ethers, furthermore condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, polyoxy-ethylene octylphenyl ether, ethoxylated isooctylphenol, oc- tylphenol, nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tri- stearylphenyl polyglycol ether, alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxy- propylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignin-sulfite waste liquors and proteins, denatured proteins, polysaccharides (e. g. methylcellulose), hydrophobically modified starches, polyvinyl alcohols (Mowiol® types, Clariant, Switzerland), polycarboxylates (Sokolan® types, BASF, Germany), polyalkoxylates, polyvinylamines (Lupasol® types, BASF, Germany), polyvinylpyrrolidone and the copolymers thereof. Examples of suitable thickeners (i.e. compounds that impart a modified flowability to compositions, i.e. high viscosity under static conditions and low viscosity during agitation) are polysaccharides and organic and anorganic clays such as Xanthan gum (Kelzan®, CP Kelco, U.S.A.), Rhodopol® 23 (Rhodia, France), Veegum® (R.T. Vanderbilt, U.S.A.) or Attaclay® (Engelhard Corp., NJ, USA).

In specific embodiments, bactericides may be added for preservation and stabilization of the composition. Examples for suitable bactericides are those based on dichlorophene and benzyl alcohol hemi formal (Proxel® from ICI or Acticide® RS from Thor Chemie and Kathon® M K from Rohm & Haas) and isothiazolinone derivatives such as alkylisothiazolinones and benziso- thiazolinones (Acticide® MBS from Thor Chemie).

Examples for suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin. Examples for anti-foaming agents are silicone emulsions (such as e.g. Silikon® SRE, Wacker, Germany or Rhodorsil®, Rhodia, France), long chain alcohols, fatty acids, salts of fatty acids, fluoroorganic compounds and mixtures thereof.

Suitable colorants are pigments of low water solubility and water-soluble dyes, e.g. rhodamin B, C. I. pigment red 1 12, C. I. solvent red 1 , pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15: 1 , pigment blue 80, pigment yellow 1 , pigment yellow 13, pigment red 112, pigment red 48:2, pigment red 48:1 , pigment red 57:1 , pigment red 53:1 , pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51 , acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108.

Examples for tackifiers or binders are polyvinylpyrrolidons, polyvinylacetates, polyvinyl alcohols and cellulose ethers (Tylose®, Shin-Etsu, Japan).

Powders, materials for spreading and dusts can be prepared by mixing or concomitantly grind- ing compound of formula I and, if appropriate, further active substances, with at least one solid carrier. Granules, e.g. coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active substances to solid carriers. Examples of such suitable solid carriers are mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers.

Examples for composition types are: i) Water-soluble concentrates (SL, LS) 10 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention are dissolved in 90 parts by weight of water or in a water-soluble solvent. As an alternative, wetting agents or other auxiliaries are added. The active substance dissolves upon dilution with water. In this way, a composition hav- ing a content of 10% by weight of active substance is obtained. ii) Dispersible concentrates (DC) 20 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention are dissolved in 70 parts by weight of cyclo- hexanone with addition of 10 parts by weight of a dispersant, e.g. polyvinylpyrrolidone. Dilution with water gives a dispersion. The active substance content is 20% by weight. iii) Emulsifiable concentrates (EC) 15 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention are dissolved in 75 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). Dilution with water gives an emulsion. The composition has an active substance content of 15% by weight. iv) Emulsions (EW, EO, ES) 25 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). This mixture is introduced into 30 parts by weight of water by means of an emulsifying machine (Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion. The composition has an active substance content of 25% by weight. v) Suspensions (SC, 00, FS) In an agitated ball mill, 20 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention are comminuted with addition of 10 parts by weight of dispersants and wetting agents and 70 parts by weight of water or an organic solvent to give a fine active substance suspension. Dilution with water gives a stable suspension of the active substance. The active substance content in the composition is 20% by weight. vi) Water-dispersible granules and water-soluble granules (WG, SG) 50 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention are ground finely with addition of 50 parts by weight of dispersants and wetting agents and prepared as water-dispersible or water-soluble granules by means of technical appliances (e.g. extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance. The composition has an active substance content of 50% by weight. vii) Water-dispersible powders and water-soluble powders (WP, SP, SS, WS) 75 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention are ground in a rotor-stator mill with addition of 25 parts by weight of dispersants, wetting agents and silica gel. Dilution with water gives a stable dispersion or solution of the active substance. The active substance content of the composition is 75% by weight. viii) Gel (GF) In an agitated ball mill, 20 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention are comminuted with addition of 10 parts by weight of dispersants, 1 part by weight of a gelling agent wetters and 70 parts by weight of water or of an organic solvent to give a fine suspension of the active substance. Dilution with water gives a stable suspension of the active substance, whereby a composition with 20% (w/w) of active substance is obtained. 2. Composition types to be applied undiluted ix) Oustable powders (OP, OS) 5 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention are ground finely and mixed intimately with 95 parts by weight of finely divided kaolin. This gives a dustable composition having an active substance content of 5% by weight. x) Granules (GR, FG, GG, MG) 0.5 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention is ground finely and associated with 99.5 parts by weight of carriers. Current methods are extrusion, spray-drying or the fluidized bed. This gives granules to be applied undiluted having an active substance content of 0.5% by weight. xi) ULV solutions (UL) 10 parts by weight of (T) or a nitrification inhibitor such as a compound of formula I according to the invention are dissolved in 90 parts by weight of an organic solvent, e.g. xylene. This gives a composition to be applied undiluted having an active substance content of 10% by weight.

The agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, most preferably between 0.5 and 90%, by weight of active substance. The active substances are employed in a purity offrom 90% to 100%, preferably from 95% to 100% (according to NMR spectrum).

Water-soluble concentrates (LS), flowable concentrates (FS), powders for dry treatment (OS), water-dispersible powders for slurry treatment (WS), water-soluble powders (SS), emulsions (ES) emulsifiable concentrates (EC) and gels (GF) are usually employed for the purposes of treatment of plant propagation materials, particularly seeds.

These compositions can be applied to plant propagation materials, particularly seeds, diluted or undiluted.

The compositions in question give, after two-to-tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40% by weight, in the ready-to-use preparations. Application can be carried out before or during sowing.

Methods for applying or treating agrochemical or agricultural compounds or mixtures, or compositions as defined herein, respectively, on to plant propagation material, especially seeds, are known in the art, and include dressing, coating, pelleting, dusting, soaking and in-furrow application methods of the propagation material. In a preferred embodiment, the compounds or the compositions thereof, respectively, are applied on to the plant propagation material by a method such that germination is not induced, e.g. by seed dressing, pelleting, coating and dusting.

In a preferred embodiment, a suspension-type (FS) composition may be used. Typically, a FS composition may comprise 1 -800 g/l of active substance, 1 200 g/l surfactant, o to 200 g/l anti- freezing agent, 0 to 400 g/l of binder, 0 to 200 g/l of a pigment and up to 1 liter of a solvent, preferably water.

The active substances can be used as such or in the form of their compositions, e.g. in the form of directly sprayable solutions, powders, suspensions, dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading, or granules, by means of spraying, atomizing, dusting, spreading, brushing, immersing or pouring.

The application forms depend entirely on the intended purposes; it is intended to ensure in each case the finest possible distribution of the active substances according to the invention. Aque- ous application forms can be prepared from emulsion concentrates, pastes or wettable powders (sprayable powders, oil dispersions) by adding water.

To prepare emulsions, pastes or oil dispersions, the substances, as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetter, tackifier, dispersant or emulsifi- er. Alternatively, it is possible to prepare concentrates composed of active substance, wetter, tackifier, dispersant or emulsifier and, if appropriate, solvent or oil, and such concentrates are suitable for dilution with water. The active substance concentrations in the ready-to-use preparations can be varied within relatively wide ranges. In general, they are from 0.0001 to 10%, preferably from 0.001 to 1 % by weight of active substance. The active substances may also be used successfully in the ultra- low-volume process (ULV), it being possible to apply compositions comprising over 95% by weight of active substance, or even to apply the active substance without additives.

Various types of oils, wetters, adjuvants, herbicides, bactericides, and/or pesticides may be added to the active substances or the compositions comprising them, if appropriate not until immediately prior to use (tank mix). These agents can be admixed with the compositions ac- cording to the invention in a weight ratio of 1 : 100 to 100 : 1 , preferably 1 : 10 to 10 : 1.

Adjuvants which can be used are in particular organic modified polysiloxanes such as Break Thru S 240®; alcohol alkoxylates such as Atplus 245®, Atplus MBA 1303®, Plurafac LF 300® and Lutensol ON 30®; EO/PO block polymers, e.g. Pluronic RPE 2035® and Genapol B®; al- cohol ethoxylates such as Lutensol XP 80®; and dioctyl sulfosuccinate sodium such as Leo- phen RA®.

In a further specific embodiment, the present invention relates to a method for treating seed or plant propagation material. The term "seed treatment" as used herein refers to or involves steps towards the control of biotic or abiotic stresses on or in seed and the improvement of shooting and development of plants from seeds. For seed treatment it is evident that a plant suffering from biotic stresses such as insect attacks or which has difficulties obtaining sufficient suitable nitrogen-sources shows reduced germination and emergence leading to poorer plant or crop establishment and vigor, and consequently, to a reduced yield as compared to a plant propagation material which has been subjected to curative or preventive treatment against the relevant pest and which can grow without the damage caused by the biotic stress factor. Abiotic stress includes drought, cold, increased UV, increased heat, or other changes in the environment of the plant, that leads to sub-optimal growth conditions. Methods for treating seed or plant proga- tion material according to the invention thus lead, among other advantages, to an enhanced plant health, a better protection against biotic stresses and an increased plant yield.

Seed treatment methods for applying or treating inventive mixtures and compositions thereof, e.g. compositons or agrochemical composisitions as defined herein above, and in particular combinations of nitirificaiton inhibitors as defined herein above and insecticides and/or nemati- cides to plant propagation material, especially seeds, are known in the art, and include dressing, coating, filmcoating, pelleting and soaking application methods of the propagation material. Such methods are also applicable to the combinations or compositions according to the invention.

In preferred embodiments, the seed treatment may be performed with combinations of (T) or nitrification inhibitors and insecticides and/or nematicides as defined herein above, or with composition comprising said combinations, e.g. the combinations mentioned in Table 2 or Table 3. In specific embodiments these compositions as mentioned in Table 2 or Table 3 may additionally comprise further pesticides, e.g. fungicides and/or biopesticides and/or biostimulants. In a preferred embodiment, the compositon or combination comprising (T) or a nitrification inhibitor according to the present invention and an insecticide and/or nematicide, e.g. as defined herein above, is applied or treated on to the plant propagation material by a method such that the germination is not negatively impacted. Accordingly, examples of suitable methods for applying (or treating) a plant propagation material, such as a seed, is seed dressing, seed coating or seed pelleting and alike. It is preferred that the plant propagation material is a seed, seed piece (i.e. stalk) or seed bulb. Although it is believed that the present method can be applied to a seed in any physiological state, it is preferred that the seed be in a sufficiently durable state that it incurs no damage during the treatment process. Typically, the seed would be a seed that had been harvested from the field; removed from the plant; and separated from any cob, stalk, outer husk, and surrounding pulp or other non-seed plant material. The seed would preferably also be biologically stable to the extent that the treatment would cause no biological damage to the seed. It is believed that the treatment can be applied to the seed at any time between harvest of the seed and sowing of the seed or during the sowing process (seed directed applications). The seed may also be primed either before or after the treatment. Even distribution of the ingredients in compositions or mixtures as defined herein and adherence thereof to the seeds is desired during propagation material treatment. Treatment could vary from a thin film (dressing) of the formulation containing the combination, for example, a mixture of active ingredient(s), on a plant propagation material, such as a seed, where the original size and/or shape are recognizable to an intermediary state (such as a coating) and then to a thicker film (such as pelleting with many layers of different materials (such as carriers, for example, clays; different formulations, such as of other active ingredients; polymers; and colourants) where the original shape and/or size of the seed is no longer recognizable.

An aspect of the present invention includes application of the composition, e.g. agricultural composition or combination comprising (T) or a nitrification inhibitor according to the present invention and an insecticides and/or nematicide, e.g. as defined herein above, onto the plant propagation material in a targeted fashion, including positioning the ingredients in the combination onto the entire plant propagation material or on only parts thereof, including on only a single side or a portion of a single side. One of ordinary skill in the art would understand these applica- tion methods from the description provided in EP954213B1 and WO06/1 12700.

The composition, e.g. agricultural composition or combination comprising (T) or a nitrification inhibitor according to the present invention and an insecticides and/or nematicide, e.g. as defined herein above, can also be used in form of a "pill" or "pellet" or a suitable substrate and placing, or sowing, the treated pill, or substrate, next to a plant propagation material. Such techniques are known in the art, particularly in EP1 124414, WO07/67042, and WO07/67044. Application of the composition, e.g. agricultural composition or combination comprising (T) or a nitrification inhibitor according to the present invention and an insecticide and/or nematicide, e.g. as defined herein above, onto plant propagation material also includes protecting the plant propa- gation material treated with the combination of the present invention by placing one or more insecticide and/or nematicide- and (T)- or nitrification inhibitor (Nl)-containing particles next to a insecticide and/or nematicide- and Nl-treated seed, wherein the amount of insecticides and/or nematicides is such that the pesticide-treated seed and the pesticide- containing particles to- gether contain an Effective Dose of the insecticides and/or nematicides and the insecticide and/or nematicide dose contained in the insecticids and/or nematicide -treated seed is less than or equal to the Maximal Non-Phytotoxic Dose of the pesticide. Such techniques are known in the art, particularly in WO2005/120226. Application of the combinations onto the seed also includes controlled release coatings on the seeds, wherein the ingredients of the combinations are incorporated into materials that release the ingredients over time. Examples of controlled release seed treatment technologies are generally known in the art and include polymer films, waxes, or other seed coatings, wherein the ingredients may be incorporated into the controlled release material or applied between layers of materials, or both.

Seed can be treated by applying thereto the compound s present in the inventive mixtures in any desired sequence or simultaneously.

The seed treatment occurs to an unsown seed, and the term "unsown seed" is meant to include seed at any period between the harvest of the seed and the sowing of the seed in the ground for the purpose of germination and growth of the plant.

Treatment to an unsown seed is not meant to include those practices in which the active ingredient is applied to the soil or soil substituents but would include any application practice that would target the seed during the planting process.

Preferably, the treatment occurs before sowing of the seed so that the sown seed has been pre- treated with the combination. In particular, seed coating or seed pelleting are preferred in the treatment of the combinations according to the invention. As a result of the treatment, the ingre- dients in each combination are adhered on to the seed and therefore available for pest control. The treated seeds can be stored, handled, sowed and tilled in the same manner as any other active ingredient treated seed.

Solutions for seed treatment (LS), suspoemulsions (SE), flowable concentrates (FS), powders for dry treatment (DS), water-dispersible powders for slurry treatment (WS), water-soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are usually employed for the purposes of treatment of plant propagation materials, particularly seeds. Preferred examples of seed treatment formulation types or soil application for pre-mix compositions are of WS, LS, ES, FS, WG or CS-type.

The compositions in question give, after two-to-tenfold dilution, active components concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40%, in the ready-to-use preparations. Application can be carried out before or during sowing. Methods for applying or treating compositions or combinations comprising (T) or a nitrification inhibitor according to the present invention, e.g. as defined herein above on to plant propagation material, especially seeds include dressing, coating, pelleting, dusting, soaking and in-furrow application methods of the propagation material. Preferably, compositions or combinations comprising (T) or a nitrification inhibitor according to the present invention, e.g. as defined herein above are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.

Typically, a pre-mix formulation for seed treatment application comprises 0.5 to 99.9 percent, especially 1 to 95 percent, of the desired ingredients, and 99.5 to 0.1 percent, especially 99 to 5 percent, of a solid or liquid adjuvant (including, for example, a solvent such as water), where the auxiliaries can be a surfactant in an amount of 0 to 50 percent, especially 0.5 to 40 percent, based on the pre-mix formulation. Whereas commercial products will preferably be formulated as concentrates (e.g., pre- mix composition (formulation)), the end user will normally employ dilute formulations (e.g., tank mix composition).

When employed in plant protection, the total amounts of active components applied are, depending on the kind of effect desired, from 0.001 to 10 kg per ha, preferably from 0.005 to 2 kg per ha, more preferably from 0.05 to 0.9 kg per ha, in particular from 0.1 to 0.75 kg per ha. The application rates may range from about 1 x 10⁶ to 5 x 10¹⁵ (or more) CFU/ha. Preferably, the spore concentration is about 1 x 10⁷ to about 1 x 10¹¹ CFU/ha. In the case of (entomopathogen- ic) nematodes as microbial pesticides (e.g. Steinernema feltiae), the application rates preferably range inform about 1 x 10⁵ to 1 x 10¹² (or more), more preferably from 1 x 10⁸ to 1 x 10¹¹, even more preferably from 5 x 10⁸ to 1 x 10¹⁰ individuals (e.g. in the form of eggs, juvenile or any other live stages, preferably in an infetive juvenile stage) per ha.

When employed in plant protection by seed treatment, the amount of compositions or combinations comprising (T) or a nitrification inhibitor according to the present invention and an insecticide and/or nematicide, e.g. as defined herein above (based on total weight of active components) is in the range from 0.01 -10 kg, preferably from 0.1-1000 g, more preferably from 1 -100 g per 100 kilogram of plant propagation material (preferably seeds). The application rates with respect to plant propagation material preferably may range from about 1 x 10⁶ to 1 x 10¹² (or more) CFU/seed. Preferably, the concentration is about 1 x 10^s to about 1 x 10¹¹ CFU/seed. Alternatively, the application rates with respect to plant propagation material may range from about 1 x 10⁷ to 1 x 10¹⁴ (or more) CFU per 100 kg of seed, preferably from 1 x 10⁹ to about 1 x 10¹¹ CFU per 100 kg of seed.

The following example is provided for illustrative purposes. It is thus understood that the example is not to be construed as limiting. The skilled person in the art will clearly be able to envisage further modifications of the principles laid out herein.

Example 1 Soil was sampled fresh from a field (e.g. Limburgerhof), dried and sieved through a 500μηι sieve. Approximately 200 mg of soil were placed into each well of a 48 well plate. Compounds, or DMSO alone, were added at a concentration of 10 ppm, dissolved in 1 % DMSO. 6 μιηοΙ ammonium sulfate was added per well as well as 4.8 mg NaCIC>3.

Subsequently, the samples were incubated at room temperature for up to 72 hrs. After the incubation period 64mg KCI were added and mixed. 25 μΙ of the supernatant were placed into a fresh plate and 260μΙ of a color reaction solution (from Merck Nr 1.11799.0100) were added.

Measurements were taken with a Tecan plate Reader at 540nm wavelength.

The results of the measurements (with a dose of 10 ppm) were that all compounds #1 to #215 as shown in Table 1 , supra demonstrated an inhibition of > 10% compared to a control (DMSO only).

Example 2

Synergism can be described as an interaction where the combined effect of two or more compounds is greater than the sum of the individual effects of each of the compounds. The pres- ence of a synergistic effect in terms of percent control, between two mixing partners (X and Y) can be calculated using the Colby equation (Colby, S. R., 1967, Calculating Synergistic and Antagonistic Responses in Herbicide Combinations, Weeds, 15, 20-22):

XY

E = X + Y

100

When the observed combined control effect is greater than the expected combined control effect (E), then the combined effect is synergistic.

The following tests demonstrate the control efficacy of compounds, mixtures or compositions of this invention on specific pests. However, the pest control protection afforded by the compounds, mixtures or compositions is not limited to these species. In certain instances, combinations of a compound of this invention with other invertebrate pest control compounds or agents are found to exhibit synergistic effects against certain important invertebrate pests.

The analysis of synergism or antagonism between the mixtures or compositions was determined using Colby's equation.

Biological Examples of the Invention Test 1 : Rice brown plant hopper (Nilaparvata lugens)

A field trial was conducted to evaluate the control of rice brown plant hopper (Nilaparvata lugens). Each treatment was applied to three 16 m2 plots transplanted with rice seedlings (Oryza sp. Variety Situbagendit. The plots were sprayed 35 days after transplanting (first application), using a knapsack sprayer with a single nozzle and a spray volume of 400l/ha. The active compounds were combined in a tank mix at different concentrations and ratios diluted in water.

Brown Plant hopper Nymphal counts were assessed 7 days after the first application. Percent mortality was calculated for each treatment using the Abbotts calculation. Synergistic effects, according to Colby, were identified.

Claims

Claims:

1. A composition comprising a) at least one (thio)phosphoric acid triamide (T) according to the general formula (la)

R^a1R^a2N-P(X)(NH₂)₂ (la)

wherein

X is oxygen or sulfur;

R^a1 is a Ci to C20 alkyl, C3 to C20 cycloalkyl, C , to C20 aryl, or dialkyla- minocarbonyl group;

R^a2 is H . or

R^a1 and R^a2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitro- gen, oxygen, and sulfur,

and

b) at least one insecticide selected from the group of insecticides comprising:

(i) Organo(thio)phosphates selected from acephate (B.1.1), azamethiphos (B.1.2), azinphos-methyl (B.1.3), chlorpyrifos (B.1 .4), chlorpyrifos-methyl (B.1.5), chlorfenvinphos

(B.1.6), diazinon (B.1.7), dichlorvos (B.1.8), dicrotophos (B.1.9), dimethoate (B.1.10), di- sulfoton (B.1.1 1 ), ethion (B.1.12), fenitrothion (B.1.13), fenthion (B.1 .14), isoxathion (B.1.15), malathion (B.1.16), methamidophos (B.1.17), methidathion (B.1 .18), methyl- parathion (B.1.19), mevinphos (B.1.20), monocrotophos (B.1.21), oxydemeton-methyl (B.1.22), paraoxon (B.1 .23), parathion (B.1.24), phenthoate (B.1.25), phosalone (B.1.26), phosmet (B.1.27), phosphamidon (B.1.28), phorate (B.1.29), phoxim (B.1 .30), pirimiphos- methyl (B.1.31 ), profenofos (B.1.32), prothiofos (B.1.33), sulprophos (B.1 .34), tetrachlor- vinphos (B.1.35), terbufos (B.1 .36), triazophos (B.1.37), trichlorfon (B.1 .38);

(ii) Carbamates selected from alanycarb (B.2.1), aldicarb (B.2.2), bendiocarb (B.2.3), benfuracarb (B.2.4), carbaryl (B.2.5), carbofuran (B.2.6), carbosulfan (B.2.7), fenoxycarb

(B.2.8), furathiocarb (B.2.9), methiocarb (B.2.10), methomyl (B.2.1 1), oxamyl (B.2.12), pi- rimicarb (B.2.13), propoxur (B.2.14), thiodicarb (B.2.15), triazamate (B.2.16);

(iii) Pyrethroids selected from allethrin (B.3.1 ), bifenthrin (B.3.2), cyfluthrin (B.3.3), cyhalothrin (B.3.4), cyphenothrin (B.3.5), cypermethrin (B.3.6), alpha-cypermethrin (B.3.7), beta-cypermethrin (B.3.8), zeta-cypermethrin (B.3.9), deltamethrin (B.3.10), esfenvalerate (B.3.1 1 ), etofenprox (B.3.28), fenpropathrin (B.3.12), fenvalerate (B.3.13), imiprothrin (B.3.14), lambda-cyhalothrin (B.3.15), permethrin (B.3.16), prallethrin (B.3.17), pyrethrin I and II (B.3.18), resmethrin (B.3.19), silafluofen (B.3.20), tau-fluvalinate (B.3.21 ), tefluthrin (B.3.22), tetramethrin (B.3.23), tralomethrin (B.3.24), transfluthrin (B.3.25), profluthrin (B.3.26), dimefluthrin (B.3.27); insect growth regulators such as a) chitin synthesis inhibitors selected from benzo- ylureas: chlorfluazuron (B.4.1 ), cyramazin (B.4.2), diflubenzuron (B.4.3), flucycloxuron (B.4.4), flufenoxuron (B.4.5), hexaflumuron (B.4.6), lufenuron (B.4.7), novaluron (B.4.8), teflubenzuron (B.4.9), triflumuron (B.4.10); buprofezin (B.4.1 1), diofenolan (B.4.12), hex- ythiazox (B.4.13), etoxazole (B.4.14), clofentazine (B.4.15); b) ecdysone antagonists selected from halofenozide (B.4.16), methoxyfenozide (B.4.17), tebufenozide (B.4.18), aza- dirachtin (B.4.19); c) juvenoids selected from pyriproxyfen (B.4.20), methoprene (B.4.21 ), fenoxycarb (B.4.22); d) lipid biosynthesis inhibitors selected from spirodiclofen (B.4.23), spiromesifen (B.4.24), spirotetramat (B.4.25);

nicotinic receptor agonists/antagonists compounds selected from clothianidin (B.5.1 ), dinotefuran (B.5.2), flupyradifurone (B.5.3), imidacloprid (B.5.4), thiamethoxam (B.5.5), nitenpyram (B.5.6), acetamiprid (B.5.7), thiacloprid (B.5.8), 1-2-chloro-thiazol-5- ylmethyl)-2-nitrimino-3,5-dimethyl-[1 ,3,5]triazinane (B.5.9);

GABA antagonist compounds selected from endosulfan (B.6.1 ), ethiprole (B.6.2), fipronil (B.6.3), vaniliprole (B.6.4), pyrafluprole (B.6.5), pyriprole (B.6.6), 5-amino-1-(2,6- dichloro-4-methyl-phenyl)-4-sulfinamoyl-1 H-pyrazole-3-carbothioic acid amide (B.6.7); macrocyclic lactone insecticides selected from abamectin (B.7.1), emamectin (B.7.2), milbemectin (B.7.3), lepimectin (B.7.4), spinosad (B.7.5), spinetoram (B.7.6); mitochondrial electron transport inhibitor (METI) I acaricides selected from fena- zaquin (B.8.1 ), pyridaben (B.8.2), tebufenpyrad (B.8.3), tolfenpyrad (B.8.4), flufenerim (B.8.5);

METI II and III compounds selected from acequinocyl (B.9.1 ), fluacyprim (B.9.2), hydramethylnon (B.9.3);

Uncouplers such as chlorfenapyr (B.10.1 );

oxidative phosphorylation inhibitors selected from cyhexatin (B.11 .1 ), diafenthiuron (B.1 1.2), fenbutatin oxide (B.11.3), propargite (B.1 1.4);

moulting disruptor compounds such as cryomazine (B.12.1 );

mixed function oxidase inhibitors such as piperonyl butoxide (B.13.1);

sodium channel blockers selected from indoxacarb (B.14.1 ), metaflumizone (B.14.2);

ryanodine receptor inhibitors selected from chlorantraniliprole (B.15.1 ), cyan- traniliprole (B.15.2), flubendiamide (B.15.3), N-[4,6-dichloro-2-[(diethyl-lambda-4- sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3- carboxamide (B.15.4); N-[4-chloro-2-[(diethyl-lambda-4-sulfanylidene)carbamoyl]- 6-methyl-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide

(B.15.5); N-[4-chloro-2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]-6-methyl-phenyl]- 2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.6); N-[4,6-dichloro- 2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)- 5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.7); N-[4,6-dichloro-2-[(diethyl-lambda- 4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(difluoromethyl)pyrazole-3- carboxamide (B.15.8); N-[4,6-dibromo-2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]- phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.9); N-[4- chloro-2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]-6-cyano-phenyl]-2-(3-chloro-2- pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.10); N-[4,6-dibromo-2-[(diethyl- lambda-4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(tri- fluoromethyl)pyrazole-3-carboxamide (B.15.1 1 ); cyazypyr B.15.12, or rynaxapyr (B.15.12).

Other insecticides such as benclothiaz (B.16.1), bifenazate (B.16.2), artap

(B.16.3), flonicamid (B.16.4), pyridalyl (B.16.5), pymetrozine (B.16.6), sulfur (B.16.7), thio- cyclam (B.16.8), cyenopyrafen (B.16.9), flupyrazofos (B.16.10), cyflumetofen (B.16.1 1 ), amidoflumet (B.16.12), imicyafos (B.16.13), bistrifluron (B.16.14), pyrifluquinazon

(B.16.15) and 1 ,1 '-[(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-4-[[(2-cyclopropylacetyl)- oxy]methyl]-1 ,3,4,4a,5,6,6a,12,12a, 12b-decahydro-12-hydroxy-4,6a, 12b-trimethyl-1 1 -oxo- 9-(3-pyridinyl)-2H ,1 1 H-naphtho[2,1-b]pyrano[3,4-e]pyran-3,6-diyl] cyclopropaneacetic acid ester (B.16.16);

or

) at least one nematicide selected from the group of nematicides comprising: thi- odicarb and abamectin (B.17.1 ).

2. The composition according to claim 1 , wherein in the general formula (la) of (T) X is sulfur.

3. The composition according to claim 1 or 2, wherein in the general formula (la) of (T) R^a1 is C1-C20 alkyl and R^a2 is H.

4. The composition according to anyone of the claims 1 to 3, wherein the (thio)phosphoric acid triamide (T) is N-n-butylthiophosphoric acid triamide (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT).

5. The composition according to anyone of the claims 1 to 4, wherein the insecticide is thiodicarb (B.2.15), clothianidin (B.5.1 ), imidacloprid (B.5.4), thiamethoxam (B.5.5), thi- acloprid (B.5.8), fipronil (B.6.3), cyazypyr (B.15.12), or rynaxapyr (B.15.13), chlorpyrifos (B.1.4) or acephate (B.1.1); and wherein said nematicide is abamectin (B.17.1 ).

6. A method for increasing the health of a plant and/or for increasing the insecticidal and/or nematicidal activity of an insecticide and/or nematicide, comprising treating a plant growing on soil or soil substituents and/or the locus or soil or soil substituents where the plant is growing or is intended to grow with

) at least one (thio)phosphoric acid triamide (T) according to the general formula (la)

R^a R^a2N-P(X)(NH₂)₂ (la) wherein

X is oxygen or sulfur; R^a1 is a Ci to C₂o alkyl, C3 to C20 cycloalkyl, C6 to C20 aryl, or dialkyla- minocarbonyl group;

R^a2 is H . or

R^a1 and R^a2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur,

and

b) at least one insecticide selected from the group of insecticides comprising:

Organo(thio)phosphates selected from acephate (B.1.1 ), azamethiphos (B.1.2), azinphos-methyl (B.1.3), chlorpyrifos (B.1 .4), chlorpyrifos-methyl (B.1.5), chlorfenvinphos (B.1.6), diazinon (B.1.7), dichlorvos (B.1.8), dicrotophos (B.1.9), dimethoate (B.1.10), di- sulfoton (B.1.1 1 ), ethion (B.1.12), fenitrothion (B.1.13), fenthion (B.1 .14), isoxathion (B.1.15), malathion (B.1.16), methamidophos (B.1.17), methidathion (B.1 .18), methyl- parathion (B.1.19), mevinphos (B.1.20), monocrotophos (B.1.21), oxydemeton-methyl (B.1.22), paraoxon (B.1.23), parathion (B.1.24), phenthoate (B.1 .25), phosalone (B.1.26), phosmet (B.1.27), phosphamidon (B.1.28), phorate (B.1.29), phoxim (B.1 .30), pirimiphos- methyl (B.1.31 ), profenofos (B.1.32), prothiofos (B.1.33), sulprophos (B.1 .34), tetrachlor- vinphos (B.1.35), terbufos (B.1 .36), triazophos (B.1.37), trichlorfon (B.1.38);

Carbamates selected from alanycarb (B.2.1), aldicarb (B.2.2), bendiocarb (B.2.3), benfuracarb (B.2.4), carbaryl (B.2.5), carbofuran (B.2.6), carbosulfan (B.2.7), fenoxycarb (B.2.8), furathiocarb (B.2.9), methiocarb (B.2.10), methomyl (B.2.1 1), oxamyl (B.2.12), pi- rimicarb (B.2.13), propoxur (B.2.14), thiodicarb (B.2.15), triazamate (B.2.16);

Pyrethroids selected from allethrin (B.3.1 ), bifenthrin (B.3.2), cyfluthrin (B.3.3), cyhalothrin (B.3.4), cyphenothrin (B.3.5), cypermethrin (B.3.6), alpha-cypermethrin (B.3.7), beta-cypermethrin (B.3.8), zeta-cypermethrin (B.3.9), deltamethrin (B.3.10), esfenvalerate (B.3.1 1 ), etofenprox (B.3.28), fenpropathrin (B.3.12), fenvalerate (B.3.13), imiprothrin (B.3.14), lambda-cyhalothrin (B.3.15), permethrin (B.3.16), prallethrin (B.3.17), pyrethrin I and II (B.3.18), resmethrin (B.3.19), silafluofen (B.3.20), tau-fluvalinate

(B.3.21 ), tefluthrin (B.3.22), tetramethrin (B.3.23), tralomethrin (B.3.24), transfluthrin (B.3.25), profluthrin (B.3.26), dimefluthrin (B.3.27);

insect growth regulators such as a) chitin synthesis inhibitors selected from benzo- ylureas: chlorfluazuron (B.4.1 ), cyramazin (B.4.2), diflubenzuron (B.4.3), flucycloxuron (B.4.4), flufenoxuron (B.4.5), hexaflumuron (B.4.6), lufenuron (B.4.7), novaluron (B.4.8), teflubenzuron (B.4.9), triflumuron (B.4.10); buprofezin (B.4.1 1), diofenolan (B.4.12), hex- ythiazox (B.4.13), etoxazole (B.4.14), clofentazine (B.4.15); b) ecdysone antagonists selected from halofenozide (B.4.16), methoxyfenozide (B.4.17), tebufenozide (B.4.18), aza- dirachtin (B.4.19); c) juvenoids selected from pyriproxyfen (B.4.20), methoprene (B.4.21 ), fenoxycarb (B.4.22); d) lipid biosynthesis inhibitors selected from spirodiclofen (B.4.23), spiromesifen (B.4.24), spirotetramat (B.4.25);

Uncouplers such as chlorfenapyr (B.10.1 );

moulting disruptor compounds such as cryomazine (B.12.1 );

mixed function oxidase inhibitors such as piperonyl butoxide (B.13.1);

ryanodine receptor inhibitors selected from chlorantraniliprole (B.15.1), cyan- traniliprole (B.15.2), flubendiamide (B.15.3), N-[4,6-dichloro-2-[(diethyl-lambda-4- sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3- carboxamide (B.15.4); N-[4-chloro-2-[(diethyl-lambda-4-sulfanylidene)carbamoyl]- 6-methyl-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide

Other insecticides such as benclothiaz (B.16.1), bifenazate (B.16.2), artap

(B.16.3), flonicamid (B.16.4), pyridalyl (B.16.5), pymetrozine (B.16.6), sulfur (B.16.7), thio- cyclam (B.16.8), cyenopyrafen (B.16.9), flupyrazofos (B.16.10), cyflumetofen (B.16.1 1 ), amidoflumet (B.16.12), imicyafos (B.16.13), bistrifluron (B.16.14), pyrifluquinazon (B.16.15) and 1 ,1 '-[(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-4-[[(2-cyclopropylacetyl)- oxy]methyl]-1 ,3,4,4a,5,6,6a,12,12a, 12b-decahydro-12-hydroxy-4,6a, 12b-trimethyl-1 1 -oxo- 9-(3-pyridinyl)-2H ,1 1 H-naphtho[2,1-b]pyrano[3,4-e]pyran-3,6-diyl] cyclopropaneacetic acid ester (B.16.16);

or c) at least one nematicide selected from the group of nematicides comprising: thiodi- carb and abamectin (B.17.1 ).

7. The method according to claim 6, wherein the plant is additionally provided with a urea-containing fertilizer selected from the group consisting of urea, formaldehyde urea, UAN, urea sulfur, stabilized urea, urea based NPK-fertilizers, and urea ammonium sulfate.

8. The method according to claim 6 or 7, wherein the insecticide is thiodicarb (B.2.15), clothianidin (B.5.1), imidacloprid (B.5.4), thiamethoxam (B.5.5), thiacloprid (B.5.8), fipronil (B.6.3), cyazypyr (B.15.12), or rynaxapyr (B.15.13), chlorpyrifos (B.1 .4) or acephate (B.1.1 ); and wherein said nematicide is abamectin (B.17.1 ).

9. The method according to anyone of the claims 6 to 8, wherein the application of the (thio)phosphoric acid triamide (T), of the insecticide and/or nematicide, and optionally of the urea-containing fertilizer is carried out simultaneously or with a time lag, preferably an interval of 1 day, 2 days, 3 days, 1 week, 2 weeks or 3 weeks.

10. Use of the compositions as defined in claims 1 to 5 for increasing the health of a plant or for increasing the insecticidal and/or nematicidal activity of the insecticide and/or nematicide.

1 1. Use of a nitrification inhibitor

wherein said nitrification inhibitor is a compound of formula I

or a stereoisomer, salt, tautomer or N-oxide thereof, wherein is aryl or hetaryl, wherein the aromatic ring may in each case be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^A; R¹ and R² are independently of each other selected from H and Ci-C₂-alkyl; and

R³ is H , Ci-C4-haloalkyl, Ci-C4-hydroxyalkyl, ethynylhydroxymethyl, phenylhydroxymethyl, or aryl, wherein the aromatic ring may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^B; and wherein

R^A is

(i) halogen, CN , N R^aR^b, OR^c, SR^C, C(=Y¹)R^C, C(=Y¹)OR^c, C(=Y¹)SR^C, C(=Y¹)N R^aR^b, Y²C(=Y¹)R^C, Y²C(=Y¹)OR^c, Y²C(=Y¹)SR^C, Y²C(=Y¹)N R^aR^b, Y³Y²C(=Y¹)R^C, N RaN =C(R^d)(R^e),

C(=N-N R^aR )R9, S(=0)₂R^f, NR9S(=0)₂R^f, S(=0)₂Y²C(=Y¹)R^c, S(=0)₂Y C(=Y¹)OR^c, S(=0)₂Y²C(=Y¹)SR^c, S(=0)₂Y²C(=Y¹)N R^aR , N0₂, NON-CN, d-Ce-alkyl, C₂-C₆-alkenyl, C₂-C₆-alkynyl, Ci-C₄-haloalkyl, C1-C4- cyanoalkyl, Ci-C4-hydroxyalkyl, Ci-C4-alkoxy, C₂-C4-alkynyl-Ci-C₂-hydroxyalkyl, C2-C4- alkynyloxy;

R^aN R^b, Ci-C₄-alkylene-Y²- C(=Y¹)R^C, C₂-C₄-alkenylene-Y²-C(=Y¹)R^c, Ci-C₄-alkylene-N R^aR^b, C₂-C₄-alkenylene-N R^aR^b, Ci-C₄-alkylene-OR^c, C₂-C₄-alkenylene-OR^c, Ci-C₄-alkylene-SR^c, C₂-C₄-alkenylene-SR^c, wherein the Ci-C4-alkylene or C₂-C4-alkenylene chain may in each case be unsubstituted or may be partially or fully substituted by OR9, CN , halogen or phenyl;

(iii) aryl, aryl-Ci-C₂-alkyl, hetaryl or hetaryl-Ci-C₂-alkyl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h;

(iv) a 3- to 14-membered saturated or unsaturated carbocycle or heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from N R^{1 b}, O, and S, wherein S may be oxidized and/or wherein the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R'; and wherein R^{1 b} is H , Ci-C₄-alkyl, C₂-C₄- alkenyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, or OR9; or

(v) L-B, wherein

Lis -CH2-, -CH =CH-, -C≡C-, -C(=0)- or -CH=, and

or

a 3- to 14-membered saturated or unsaturated carbocycle or heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from N R¹ , O, and S, wherein S may be oxidized and/or wherein the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, inde- pendently of each other, are selected from R; and wherein R^1b is H, Ci-C₄-alkyl, C₂-C₄- alkenyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, or ORa; or

(vi) two substituents R^A together represent a carbocyclic or heterocyclic ring, which is fused to A and may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1c, O, and S, wherein S may be oxidized and/or wherein the carbocycle or het- erocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from ; and wherein R^1c is H, Ci-C₄- alkyl, C2-C₄-alkenyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, C3-C6-heterocyclyl, C3-C6- heterocyclylmethyl or ORa; and wherein

R^B is

NH-C(=0)-(C₂-C₄-alkenyl),

alkyl), NH-C(=0)-(C₃-C₆-cycloalkyl),

or N0₂; and wherein

Y¹, Y² and Y³ are independently of each other selected from O, S and NR^1a, wherein R^1a is in each case independently H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C3-C6-cycloalkyl, C3-C6- cycloalkylmethyl, ORa, SRa or NR^mRⁿ;

R^a and R^b are independently of each other selected from

(i) H, NRR^k, OR, SR, Ci-C₄-alkyl, C₂-C -alkenyl, C₂-C₄-alkynyl, Ci-C₄-hydroxyalkyl, Ci-C₄-alkoxy, C(=Y )R', C(=Y )OR', C(=Y )SR, C(=Y )NRR^k, C(=Y )C(=Y²)R, S(=0)₂R^f;

(ii) aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h; or

R^a and R^b together with the nitrogen atom to which they are bound form

(iv) a 3- to 10-membered, saturated or unsaturated heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from NR^1b, O, and S, wherein S may be oxidized and/or wherein the heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is H , Ci-C₄-alkyl, C₂-C4-alkenyl, C3-C6-cycloalkyl, C3-C6- cycloalkylmethyl, or ORa;

R^c is

(i) H, CrC₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, C(=0)OR, C(=0)SR, C(=0)NRR^k; (ii)

wherein the Ci-C₄-alkylene chain may in each case be unsubstituted or may be partially or fully substituted by ORa, CN, halogen, or phenyl; (iii) aryl, aryl-Ci-C₂-alkyl, hetaryl, or hetaryl-Ci-C₂-alkyl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h; or

(iv) a 3- to 10-membered saturated or unsaturated carbocycle or heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from

N R^1b, O, and S, wherein S may be oxidized and/or wherein the carbocycle or heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is H , Ci-C4-alkyl, C₂-C₄- alkenyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, or ORa;

R^d and R^e are independently selected from d-C₄-alkyl, Ci-C₄-haloalkyl, N R^k, OR, SR, CN , C(=Y¹)R, C(=Y¹)OR, C(=Y¹)SR, or C(=Y¹)N RR^k; is CrC₄-alkyl, Ci-C₄-haloalkyl, N RR^k, OR', SR', aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^h; is H or Ci-C₄-alkyl; is halogen, CN , N0₂, N RR^k, OR, SR, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, C1-C4- haloalkyl, Ci-C₄-alkoxy, C₂-C₄-alkynyloxy, C(=Y¹)R, C(=Y¹)OR, C(=Y¹)SR, C(=Y¹)N RR^k, aryl, aryloxy, hetaryl and hetaryloxy; is

(i) halogen, CN , Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, Ci-C₄-haloalkyl, C₂-C₄- haloalkenyl;

(ii) =N R^1d, wherein R^1d is H , Ci-C₄-alkyl, C₂-C₄-alkenyl, C₃-C₆-cycloalkyl, C₃-C₆- cycloalkylmethyl, or ORa;

(iii) =0, =S, N R^k, OR, SR, C(=Y¹)R, C(=Y¹)OR, C(=Y¹)SR, C(=Y )N RR^k;

(iv) aryl, aryl-Ci-C₂-alkyl, hetaryl, or hetaryl-Ci-C₂-alkyl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from halogen, CN , C1-C4- alkyl, Ci-C₄-haloalkyl, Ci-C -alkoxy, C₂-C₄-alkynyloxy, ORa, and SRa; or

(v) C3-C6-cycloalkyl, or 3- to 6-membered heterocyclyl, wherein the cycloalkyl ring or the heterocyclyl ring may be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from halogen, CN , Ci-C₄-alkyl, ORa, and SRa; and R^k are independently selected from H , ORa, SRa, C(=Y¹)Ra, C(=Y¹)ORa, C(=Y¹)SRa, C(=Y¹)N R^mRⁿ, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, Ci-C₄-haloalkyl, aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently selected from halogen, CN , Ci-C₄-alkyl, Ci-C₄-haloalkyl, Ci-C₄-alkoxy, C₂-C₄-alkynyloxy, ORa, and SRa; R is H, Ci-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, Ci-C₄-haloalkyl,

C(=Y¹)SR9, C(=Y¹)N R^mRⁿ, aryl or hetaryl, wherein the aromatic ring of the aryl or hetaryl group may be unsubstituted or may be partially or fully substituted by substituents, which are independently selected from halogen, CN , Ci-C4-alkyl, Ci-C4-haloalkyl, Ci-C4-alkoxy, C₂-C₄-alkynyloxy, OR9, and SRs; and

R^m and Rⁿ are independently selected from H and Ci-C₄-alkyl;

and an insecticide and/or nematicide for increasing the health of a plant.

12. The use of claim 1 1 , wherein in said compound of formula I , A is phenyl or a 5- or 6-membered hetaryl, wherein the aromatic ring may in each case be unsubstituted or may be partially or fully substituted by substituents, which are independently of each other selected from R^A.

13. The use of claim 1 1 or 12, wherein in said compound of formula I, R¹ and R² both represent hydrogen.

14. The use of any one of claims 11 to 13, wherein in said compound of formula I, R³ is hydrogen, Ci-C4-haloalkyl or ethinylhydroxymethyl, and preferably R³ is hydrogen.

15. The use of any one of claims 1 1 to 13, wherein in said compound of formula I, R^A, if present, is

(i) halogen, CN , N R^aR^b, OR^c, C(=Y¹)R^C, C(=Y¹)OR^c, C(=Y¹)SR^C, C(=Y¹)N R^aR^b, Y²C(=Y¹)R^C, Y²C(=Y¹)N R^aR , N RaN =C(R^d)(R^e), S(=0)₂R^f, N0₂, Ci-C₆-alkyl, C₂-C₆- C1-C4- haloalkyl, Ci-C4-alkoxy, C₂-C4-alkynyl-Ci-C₂-hydroxyalkyl, C₂-C4-alkynyloxy;

(ii) C₂-C₄-alkenylene-C(=Y¹)R^c, C₂-C₄-alkenylene-Y²-C(=Y¹)R^c, wherein the C1-C4- alkylene or C₂-C₄-alkenylene chain may in each case be unsubstituted or may be partially or fully substituted by CN or halogen;

(iv) a 3- to 14-membered saturated or unsaturated heterocycle, which may contain 1 , 2, or 3 heteroatoms which, independently of each other, are selected from N R^1b, O, and S, wherein S may be oxidized and/or wherein the heterocycle may be unsubstituted or may be partially or fully substituted by substituents which, independently of each other, are selected from R; and wherein R^1b is H , Ci-C₄-alkyl, C₂-C₄-alkenyl, C3-C6-cycloalkyl, C3-C6- cycloalkylmethyl, or ORa.

16. The use of any one of claims 1 1 to 15, wherein said insecticide is at least one insecticide selected from the group of insecticides comprising: (xvii) Organo(thio)phosphates selected from acephate (B.1.1 ), azamethiphos (B.1.2), azinphos-methyl (B.1.3), chlorpyrifos (B.1 .4), chlorpyrifos-methyl (B.1.5), chlorfenvinphos (B.1.6), diazinon (B.1.7), dichlorvos (B.1.8), dicrotophos (B.1.9), dimethoate (B.1.10), di- sulfoton (B.1.1 1 ), ethion (B.1.12), fenitrothion (B.1.13), fenthion (B.1 .14), isoxathion (B.1.15), malathion (B.1.16), methamidophos (B.1.17), methidathion (B.1 .18), methyl- parathion (B.1.19), mevinphos (B.1.20), monocrotophos (B.1.21), oxydemeton-methyl (B.1.22), paraoxon (B.1.23), parathion (B.1.24), phenthoate (B.1 .25), phosalone (B.1.26), phosmet (B.1.27), phosphamidon (B.1.28), phorate (B.1.29), phoxim (B.1 .30), pirimiphos- methyl (B.1.31 ), profenofos (B.1.32), prothiofos (B.1.33), sulprophos (B.1 .34), tetrachlor- vinphos (B.1.35), terbufos (B.1 .36), triazophos (B.1.37), trichlorfon (B.1 .38);

(xviii) Carbamates selected from alanycarb (B.2.1), aldicarb (B.2.2), bendiocarb (B.2.3), benfuracarb (B.2.4), carbaryl (B.2.5), carbofuran (B.2.6), carbosulfan (B.2.7), fenoxycarb (B.2.8), furathiocarb (B.2.9), methiocarb (B.2.10), methomyl (B.2.1 1), oxamyl (B.2.12), pi- rimicarb (B.2.13), propoxur (B.2.14), thiodicarb (B.2.15), triazamate (B.2.16);

(xix) Pyrethroids selected from allethrin (B.3.1 ), bifenthrin (B.3.2), cyfluthrin (B.3.3), cyhalothrin (B.3.4), cyphenothrin (B.3.5), cypermethrin (B.3.6), alpha-cypermethrin (B.3.7), beta-cypermethrin (B.3.8), zeta-cypermethrin (B.3.9), deltamethrin (B.3.10), esfenvalerate (B.3.1 1 ), etofenprox (B.3.28), fenpropathrin (B.3.12), fenvalerate (B.3.13), imiprothrin (B.3.14), lambda-cyhalothrin (B.3.15), permethrin (B.3.16), prallethrin (B.3.17), pyrethrin I and II (B.3.18), resmethrin (B.3.19), silafluofen (B.3.20), tau-fluvalinate

(xx) insect growth regulators such as a) chitin synthesis inhibitors selected from benzo- ylureas: chlorfluazuron (B.4.1 ), cyramazin (B.4.2), diflubenzuron (B.4.3), flucycloxuron (B.4.4), flufenoxuron (B.4.5), hexaflumuron (B.4.6), lufenuron (B.4.7), novaluron (B.4.8), teflubenzuron (B.4.9), triflumuron (B.4.10); buprofezin (B.4.11 ), diofenolan (B.4.12), hex- ythiazox (B.4.13), etoxazole (B.4.14), clofentazine (B.4.15); b) ecdysone antagonists selected from halofenozide (B.4.16), methoxyfenozide (B.4.17), tebufenozide (B.4.18), aza- dirachtin (B.4.19); c) juvenoids selected from pyriproxyfen (B.4.20), methoprene (B.4.21 ), fenoxycarb (B.4.22); d) lipid biosynthesis inhibitors selected from spirodiclofen (B.4.23), spiromesifen (B.4.24), spirotetramat (B.4.25);

(xxi) nicotinic receptor agonists/antagonists compounds selected from clothianidin

(B.5.1 ), dinotefuran (B.5.2), flupyradifurone (B.5.3), imidacloprid (B.5.4), thiamethoxam (B.5.5), nitenpyram (B.5.6), acetamiprid (B.5.7), thiacloprid (B.5.8), 1-2-chloro-thiazol-5- ylmethyl)-2-nitrimino-3,5-dimethyl-[1 ,3,5]triazinane (B.5.9);

(xxii) GABA antagonist compounds selected from endosulfan (B.6.1), ethiprole (B.6.2), fipronil (B.6.3), vaniliprole (B.6.4), pyrafluprole (B.6.5), pyriprole (B.6.6), 5-amino-1-(2,6- dichloro-4-methyl-phenyl)-4-sulfinamoyl-1 H-pyrazole-3-carbothioic acid amide (B.6.7);

(xxiii) macrocyclic lactone insecticides selected from abamectin (B.7.1), emamectin

(B.7.2), milbemectin (B.7.3), lepimectin (B.7.4), spinosad (B.7.5), spinetoram (B.7.6);

(xxiv) mitochondrial electron transport inhibitor (METI) I acaricides selected from fena- zaquin (B.8.1 ), pyridaben (B.8.2), tebufenpyrad (B.8.3), tolfenpyrad (B.8.4), flufenerim (B.8.5); (xxv) METI II and III compounds selected from acequinocyl (B.9.1 ), fluacyprim (B.9.2), hydramethylnon (B.9.3);

(xxvi) Uncouplers such as chlorfenapyr (B.10.1 );

(xxvii) oxidative phosphorylation inhibitors selected from cyhexatin (B.1 1.1 ), diafenthiuron (B.1 1.2), fenbutatin oxide (B.11.3), propargite (B.1 1.4);

(xxviii) moulting disruptor compounds such as cryomazine (B.12.1 );

(xxix) mixed function oxidase inhibitors such as piperonyl butoxide (B.13.1);

(xxx) sodium channel blockers selected from indoxacarb (B.14.1 ), metaflumizone

(B.14.2);

(xxxi) ryanodine receptor inhibitors selected from chlorantraniliprole (B.15.1), cyan- traniliprole (B.15.2), flubendiamide (B.15.3), N-[4,6-dichloro-2-[(diethyl-lambda-4- sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3- carboxamide (B.15.4); N-[4-chloro-2-[(diethyl-lambda-4-sulfanylidene)carbamoyl]- 6-methyl-phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide

(B.15.5); N-[4-chloro-2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]-6-methyl-phenyl]-

2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.6); N-[4,6-dichloro- 2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)- 5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.7); N-[4,6-dichloro-2-[(diethyl-lambda- 4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(difluoromethyl)pyrazole-3- carboxamide (B.15.8); N-[4,6-dibromo-2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]- phenyl]-2-(3-chloro-2-pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.9); N-[4- chloro-2-[(di-2-propyl-lambda-4-sulfanylidene)carbamoyl]-6-cyano-phenyl]-2-(3-chloro-2- pyridyl)-5-(trifluoromethyl)pyrazole-3-carboxamide (B.15.10); N-[4,6-dibromo-2-[(diethyl- lambda-4-sulfanylidene)carbamoyl]-phenyl]-2-(3-chloro-2-pyridyl)-5-(tri- fluoromethyl)pyrazole-3-carboxamide (B.15.1 1 ); cyazypyr B.15.12, or rynaxapyr (B.15.12).

(xxxii) Other insecticides such as benclothiaz (B.16.1), bifenazate (B.16.2), artap

and wherein said nematicide is at least one nematicide selected from the group of nematicides comprising:thiodicarb and abamectin (B.17.1 ).

17. The use of claim 16, wherein said insecticide is thiodicarb (B.2.15), clothianidin (B.5.1 ), imidacloprid (B.5.4), thiamethoxam (B.5.5), thiacloprid (B.5.8), fipronil (B.6.3), cyazypyr (B.15.12), or rynaxapyr (B.15.13), chlorpyrifos (B.1.4) or acephate (B.1.1); and wherein said nematicide is abamectin (B.17.1 ).

18. The use of any one of claims 1 1 to 17, wherein said combination of a nitrification inhibitor and an insecticide and/or nematicide further comprises a fertilizer.

19. A composition for increasing the health of a plant comprising at least one nitrification inhibitor as defined in any one of claims 1 1 to 15 and at least one insecticide and/or nematicide as defined in claim 16 or 17.

20. The composition of claim 19, which additionally comprises at least one carrier.

21. A method for increasing the health of a plant, comprising treating a plant growing on soil or soil substituents and/or the locus or soil or soil substituents where the plant is growing or is intended to grow with a combination of at least one nitrification inhibitor and at least one insecticide and/or nematicide as defined in any one of claims 1 1 to 17, or a composition as defined in claim 19 or 20.

22. The method of claim 21 , wherein the plant and/or the locus or soil or soil substituents where the plant is growing or is intended to grow is additionally provided with a fertilizer.

23. The method of claim 21 or 22, wherein the application of said nitrification inhibitor (A) and of said insecticide and/or nematicide (B), and optionally of said fertilizer (C) is carried out simultaneously or with a time lag, preferably an interval of 1 day, 2 days, 3 days, 1 week, 2 weeks or 3 weeks.

24. The use of any one claims 11 to 18, the composition of claim 19 or 20, or the method of any one claims 21 to 23, wherein said increase of the health of a plant is reflected by an increase in growth of root and shoot, an overall increase in productivity and/or a faster and more efficient development of the plant.

25. The use of any one claims 11 to 18 or 24, the composition of claim 19, 20 or 24, or the method of any one claims 21 to 24, wherein said plant is an agricultural plant such as wheat, barley, oat, rye, soybean, corn, oilseed rape, canola, sunflower, cotton, sugar cane, sugar beet, rice, or a vegetable such as spinach, lettuce, asparagus, or cabbages; or sorghum; a silvicultural plant; an ornamental plant; or a horticultural plant, each in its natural or in a genetically modified form.