WO2015092929A1 - 熱間プレス鋼板部材、その製造方法及び熱間プレス用鋼板 - Google Patents
熱間プレス鋼板部材、その製造方法及び熱間プレス用鋼板 Download PDFInfo
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- WO2015092929A1 WO2015092929A1 PCT/JP2013/084333 JP2013084333W WO2015092929A1 WO 2015092929 A1 WO2015092929 A1 WO 2015092929A1 JP 2013084333 W JP2013084333 W JP 2013084333W WO 2015092929 A1 WO2015092929 A1 WO 2015092929A1
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 234
- 239000010959 steel Substances 0.000 title claims abstract description 234
- 238000007731 hot pressing Methods 0.000 title claims description 53
- 238000004519 manufacturing process Methods 0.000 title claims description 22
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 51
- 229910000734 martensite Inorganic materials 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 31
- 239000000126 substance Substances 0.000 claims abstract description 30
- 238000001816 cooling Methods 0.000 claims description 79
- 238000010438 heat treatment Methods 0.000 claims description 51
- 239000012535 impurity Substances 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- 230000000694 effects Effects 0.000 description 13
- 229910052761 rare earth metal Inorganic materials 0.000 description 13
- 150000002910 rare earth metals Chemical class 0.000 description 13
- 230000009466 transformation Effects 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- 229910001566 austenite Inorganic materials 0.000 description 8
- 230000001965 increasing effect Effects 0.000 description 8
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- 230000009471 action Effects 0.000 description 6
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- 238000009864 tensile test Methods 0.000 description 6
- 239000010960 cold rolled steel Substances 0.000 description 5
- 238000005097 cold rolling Methods 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 229910052758 niobium Inorganic materials 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 238000005422 blasting Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
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- 229910001563 bainite Inorganic materials 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052747 lanthanoid Inorganic materials 0.000 description 2
- 150000002602 lanthanoids Chemical class 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910001122 Mischmetal Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910001567 cementite Inorganic materials 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
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- 238000009616 inductively coupled plasma Methods 0.000 description 1
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
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- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B15/00—Details of, or accessories for, presses; Auxiliary measures in connection with pressing
- B30B15/06—Platens or press rams
- B30B15/062—Press plates
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D7/00—Modifying the physical properties of iron or steel by deformation
- C21D7/13—Modifying the physical properties of iron or steel by deformation by hot working
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/02—Stamping using rigid devices or tools
- B21D22/022—Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/004—Dispersions; Precipitations
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Definitions
- the present invention relates to a hot-pressed steel sheet member used for machine structural parts and the like, a manufacturing method thereof, and a hot-press steel sheet.
- Patent Documents 1 to 4 describe a method called hot pressing for the purpose of obtaining high formability in a high-strength steel sheet. According to hot pressing, a high-strength hot-pressed steel plate member can be obtained by forming a high-strength steel plate with high accuracy.
- Patent Documents 5 to 7 describe hot-pressed steel sheet members for the purpose of improving ductility, but it is difficult to achieve both strength and ductility with these conventional hot-pressed steel sheet members.
- Patent Document 8 also describes a hot-pressed steel sheet member for the purpose of improving ductility.
- the manufacture of the hot-pressed steel sheet member requires complicated control, and there are other problems such as a decrease in productivity and an increase in manufacturing cost.
- An object of the present invention is to provide a hot-pressed steel sheet member capable of obtaining excellent strength and ductility without complicated control, a manufacturing method thereof, and a hot-press steel sheet.
- the present inventor has a chemical composition containing a predetermined amount of C and Mn and a relatively large amount of Ti, and having a predetermined steel structure.
- the steel structure includes a multiphase structure containing ferrite and martensite without performing complicated control as described in Patent Document 8. It was found that a hot-pressed steel sheet member was obtained.
- the inventor of the present application has also found that the hot-pressed steel sheet member has a high tensile strength of 980 MPa or more and also has excellent ductility. And this inventor came up with the aspect of the invention shown below.
- the chemical composition is mass%, Nb: 0.003% to 0.20%, V: 0.003% to 0.20%, Cr: 0.005% to 1.0%, Mo: 0.005% to 0.15%, Cu: 0.005% to 1.0%, and Ni: 0.005% to 1.0%
- the hot-pressed steel sheet member according to (1) containing one or more selected from the group consisting of:
- the chemical composition is mass%, Ca: 0.0003% to 0.01%, Mg: 0.0003% to 0.01%, REM: 0.0003% to 0.01%, and Zr: 0.0003% to 0.01%
- the chemical composition is mass%, Nb: 0.003% to 0.20%, V: 0.003% to 0.20%, Cr: 0.005% to 1.0%, Mo: 0.005% to 0.15%, Cu: 0.005% to 1.0%, and Ni: 0.005% to 1.0%
- the hot-press steel plate according to (6) which contains one or more selected from the group consisting of:
- the chemical composition is mass%, Ca: 0.0003% to 0.01%, Mg: 0.0003% to 0.01%, REM: 0.0003% to 0.01%, and Zr: 0.0003% to 0.01%
- Drawing 1 is a figure showing the metallographic photograph of the hot press steel plate member concerning an embodiment.
- Embodiments of the present invention relate to a hot-pressed steel sheet member having a tensile strength of 980 MPa or more.
- % which is a unit of content of each element contained in a steel plate member or a hot-press steel plate, means “% by mass” unless otherwise specified.
- the chemical composition of the steel plate member according to the present embodiment and the hot-press steel plate used for the production thereof is mass%, C: 0.10% to 0.24%, Si: 0.001% to 2.0%. , Mn: 1.2% to 2.3%, sol. Al: 0.001% to 1.0%, Ti: 0.060% to 0.20%, P: 0.05% or less, S: 0.01% or less, N: 0.01% or less, Nb: 0% to 0.20%, V: 0% to 0.20%, Cr: 0% to 1.0%, Mo: 0% to 0.15%, Cu: 0% to 1.0%, Ni: 0% to 1.0%, Ca: 0% to 0.01%, Mg: 0% to 0.01%, REM: 0% to 0.01%, Zr: 0% to 0.01%, B: 0% to 0.005%, Bi: 0% to 0.01%, balance: Fe and impurities.
- the impurities include those contained in raw materials such as ore and scrap and those contained in the manufacturing process.
- C (C: 0.10% to 0.24%) C is a very important element that enhances the hardenability of the steel sheet for hot pressing and mainly determines the strength of the steel sheet member. If the C content of the steel sheet member is less than 0.10%, it is difficult to ensure a tensile strength of 980 MPa or more. Therefore, the C content is 0.10% or more. When the C content of the steel sheet for hot pressing exceeds 0.24%, the steel structure of the steel sheet member becomes a martensite single phase, and the ductility deterioration is remarkable. Therefore, the C content is 0.24% or less. From the viewpoint of weldability, the C content of the steel sheet member is preferably 0.21% or less, more preferably 0.18% or less.
- Si is an element effective in improving the strength and ductility of the steel plate member. If the Si content is less than 0.001%, it is difficult to obtain the above effect. Therefore, the Si content is 0.001% or more. When the Si content exceeds 2.0%, the effects of the above action are saturated and disadvantageous economically, and the plating wettability is significantly reduced, resulting in frequent non-plating. Therefore, the Si content is 2.0% or less. From the viewpoint of further improving ductility, the Si content is preferably 0.05% or more. From the viewpoint of improving weldability, the Si content is preferably 0.2% or more.
- the Si content is preferably 0.6% or less. If this temperature is relatively low, effects such as shortening of the heating time, improvement of productivity, reduction of manufacturing costs, and suppression of damage to the heating furnace can be obtained.
- Mn is an element that is extremely effective in improving the hardenability of the steel sheet for hot pressing and ensuring the strength of the steel sheet member. If the Mn content is less than 1.2%, it is difficult to obtain the above effect. Therefore, the Mn content is 1.2% or more. When the Mn content exceeds 2.3%, the steel structure of the steel sheet member becomes a martensite single phase, and the deterioration of ductility is remarkable. Therefore, the Mn content is 2.3% or less. From the viewpoint of setting the temperature for obtaining an austenite single phase during hot pressing to a relatively low temperature (for example, 860 ° C. or less), the Mn content is preferably 1.4% or more. The Mn content is preferably 2.2% or less, more preferably 2.1% or less, from the viewpoint of obtaining a good bendability by suppressing the steel structure of the steel plate member from becoming a remarkable band. .
- Al is an element having an action of deoxidizing steel to make the steel material sound. Al also has the effect
- Ti 0.060% to 0.20%
- Ti is an element that promotes ferrite transformation during hot pressing.
- the ductility of the steel sheet member is remarkably improved by promoting the ferrite transformation.
- Ti precipitates finely as carbide, nitride, or carbonitride, and refines the steel structure of the steel plate member.
- the Ti content is 0.060% or more. From the viewpoint of further improving ductility, the Ti content is preferably 0.075% or more.
- the Ti content exceeds 0.20%, coarse carbonitrides are formed during casting and hot rolling to obtain a steel sheet for hot pressing, and the deterioration of toughness becomes remarkable. Therefore, the Ti content is 0.20% or less. From the viewpoint of securing excellent toughness, the Ti content is preferably 0.18% or less, more preferably 0.15% or less.
- P is not an essential element but is contained as an impurity in steel, for example. From the viewpoint of weldability, the lower the P content, the better. In particular, when the P content exceeds 0.05%, the weldability is remarkably reduced. Therefore, the P content is 0.05% or less. In order to ensure better weldability, the P content is preferably 0.018% or less. On the other hand, P has the effect
- S is not an essential element but is contained as an impurity in steel, for example. From the viewpoint of weldability, the lower the S content, the better. In particular, when the S content exceeds 0.01%, the weldability is significantly reduced. Therefore, the S content is 0.01% or less. In order to ensure better weldability, the S content is preferably 0.003% or less, more preferably 0.0015% or less.
- N is not an essential element but is contained as an impurity in steel, for example. From the viewpoint of weldability, the lower the N content, the better. In particular, when the N content exceeds 0.01%, the weldability is significantly reduced. Therefore, the N content is 0.01% or less. In order to ensure better weldability, the N content is preferably 0.006% or less.
- Nb, V, Cr, Mo, Cu, Ni, Ca, Mg, REM, Zr, B, and Bi are not essential elements, and are appropriately contained in steel plate members and hot-press steel plates up to a predetermined amount. It is also an optional element.
- Nb, V, Cr, Mo, Cu, and Ni are all elements that are effective in enhancing the hardenability of the steel sheet for hot pressing and ensuring stable strength of the steel sheet member. Therefore, 1 type (s) or 2 or more types selected from the group which consists of these elements may contain.
- 1 type (s) or 2 or more types selected from the group which consists of these elements may contain.
- Nb and V if either content exceeds 0.20%, not only hot rolling and cold rolling for obtaining a hot-pressed steel sheet become difficult, but also the The steel structure becomes a martensite single phase, and the ductility deterioration is remarkable.
- the Nb content and the V content are both 0.20% or less.
- the Cr content is 1.0% or less.
- the content of Mo is more than 0.15%, the steel structure of the steel sheet member becomes a martensite single phase, and ductility deterioration is remarkable. Therefore, the Mo content is 0.15% or less.
- the Cu content and the Ni content are both 1.0% or less.
- the Nb content and the V content are preferably 0.003% or more, and the Cr content, the Mo content, the Cu content, and the Ni content are , Both are preferably 0.005% or more. That is, “Nb: 0.003% to 0.20%”, “V: 0.003% to 0.20%”, “Cr: 0.005% to 1.0%”, “Mo: 0.005” % To 0.15% ”,“ Cu: 0.005% to 1.0% ”, and“ Ni: 0.005% to 1.0% ”are preferably satisfied.
- Ca, Mg, REM, and Zr are all elements that contribute to the control of inclusions, in particular, to fine dispersion of inclusions, and to increase toughness. Therefore, 1 type (s) or 2 or more types selected from the group which consists of these elements may contain. However, if the content of any of them is more than 0.01%, the deterioration of the surface properties may become obvious. Therefore, the Ca content, the Mg content, the REM content, and the Zr content are all 0.01% or less.
- the Ca content, the Mg content, the REM content, and the Zr content are all preferably 0.0003% or more. That is, “Ca: 0.0003% to 0.01%”, “Mg: 0.0003% to 0.01%”, “REM: 0.0003% to 0.01%”, and “Zr: 0.0. Preferably, at least one of “0003% to 0.01%” is satisfied.
- REM rare earth metal
- REM content means the total content of these 17 elements.
- Lanthanoids are added industrially, for example, in the form of misch metal.
- B is an element having an effect of increasing the toughness of the steel sheet. Therefore, B may be contained. However, if the B content is more than 0.005%, the steel structure of the steel sheet member becomes a martensite single phase, and the ductility is significantly deteriorated. Moreover, hot workability may deteriorate and the hot rolling for obtaining the steel plate for hot press may become difficult. Therefore, the B content is 0.005% or less. In order to improve toughness, the B content is preferably 0.0003% or more. That is, the B content is preferably 0.0003% to 0.005%.
- Bi 0% to 0.01%
- Bi is an element that has the effect of making the steel structure uniform and increasing ductility. Therefore, Bi may be contained. However, if the Bi content is more than 0.01%, the hot workability is deteriorated, and hot rolling for obtaining a hot-press steel sheet becomes difficult. Therefore, the Bi content is 0.01% or less. In order to improve ductility, the Bi content is preferably 0.0003% or more. That is, the Bi content is preferably 0.0003% to 0.01%.
- This steel plate member has a steel structure in which area% is ferrite: 10% to 70%, martensite: 30% to 90%, and the total area ratio of ferrite and martensite: 90% to 100%. Moreover, 90% or more of all Ti in steel has precipitated.
- the numerical value regarding steel structure is the average value of the whole thickness direction of a steel plate member, for example, the depth from the surface of a steel plate member is 1/4 (thus, this point is hereafter). It can be represented by a numerical value related to the steel structure at “1/4 depth position”.
- the thickness of the steel plate member is 2.0 mm, it can be represented by a numerical value at a point where the depth from the surface is 0.50 mm. This is because the steel structure at the 1/4 depth position shows an average steel structure in the thickness direction of the steel plate member.
- the ferrite precipitated in a network shape contributes to improving the ductility of the steel sheet member. If the area ratio of the ferrite is less than 10%, the ferrite hardly forms a network, and sufficient ductility cannot be obtained. Therefore, the area ratio of ferrite is 10% or more. When the area ratio of ferrite exceeds 70%, the area ratio of martensite is inevitably less than 30%, and it is difficult to secure a tensile strength of 980 MPa or more for the steel sheet member. Therefore, the area ratio of ferrite is set to 70% or less.
- Martensite is important for increasing the strength of steel sheet members.
- the area ratio of martensite is less than 30%, it is difficult to ensure a tensile strength of 980 MPa or more for the steel plate member. Therefore, the area ratio of martensite is 30% or more.
- the area ratio of martensite exceeds 90%, the area ratio of ferrite is inevitably less than 10%, and sufficient ductility cannot be obtained. Therefore, the area ratio of martensite is 90% or less.
- the steel structure of the hot-pressed steel sheet member according to this embodiment is preferably composed of ferrite and martensite, that is, the total area ratio of ferrite and martensite is preferably 100%.
- the phase or structure other than ferrite and martensite may include one or more selected from the group consisting of bainite, retained austenite, cementite, and pearlite.
- the area ratio of the phase or structure other than ferrite and martensite is 10% or less. That is, the total area ratio of ferrite and martensite is 90% or more.
- Ti precipitates contribute to securing a stable tensile strength of the steel sheet member.
- the steel plate member contains 0.060% to 0.20% Ti, and when the proportion of Ti precipitated is less than 90%, the above-described effect can be obtained. Have difficulty. Therefore, in the steel plate member, the ratio of the precipitated Ti among all Ti in the steel is 90% or more.
- Ti precipitates are contained in the steel plate member as carbides, nitrides, or carbonitrides, for example.
- the amount of Ti deposited in the steel plate member can be specified by inductively coupled plasma (ICP) analysis of the residue obtained by electrolytic extraction of the steel plate member.
- ICP inductively coupled plasma
- Such a steel plate member can be manufactured by processing a predetermined hot-press steel plate under predetermined conditions.
- the steel sheet for hot pressing used for manufacturing the steel sheet member according to the present embodiment will be described.
- 70% or more of all Ti in the steel is precipitated.
- the steel structure of the steel sheet for hot pressing is not particularly limited. This is because, as will be described later, the hot-press steel sheet is heated to a temperature of Ac 3 or higher during hot pressing.
- the manufacturing method of the steel plate member which concerns on this embodiment ie, the method of processing the steel plate for hot presses.
- the hot pressing steel plate is heated in a temperature range of Ac 3 points to Ac 3 points + 100 ° C. for 1 to 10 minutes, and after this heating, hot pressing is performed.
- the first cooling is performed in a temperature range of 600 ° C. to 750 ° C.
- the second cooling is performed in a temperature range of 150 ° C. to 600 ° C.
- the average cooling rate is 3 ° C./second to 200 ° C./second
- ferrite starts to precipitate in the temperature range of 600 ° C. to 750 ° C.
- the average cooling rate is 10 ° C./second to 500 ° C./second.
- Heating temperature of steel sheet for hot pressing Ac 3 points to Ac 3 points + 100 ° C temperature range
- Heating of the steel sheet used for hot pressing is performed in a temperature range of Ac 3 points or more and Ac 3 points + 100 ° C. or less.
- Ac 3 point is the temperature (unit: ° C.) at which the austenite single phase is defined by the following empirical formula (i).
- the heating temperature is Ac 3 points or more.
- the heating temperature is higher than Ac 3 point + 100 ° C., the stability of the austenite grain boundary is excessively increased, and the ferrite transformation is hardly promoted.
- the steel structure of the steel plate member becomes a martensite single phase, and the ductility is significantly deteriorated.
- the Ti content is less than 0.08%, Ti precipitates are easily dissolved. Therefore, the heating temperature is set to Ac 3 points + 100 ° C. or less.
- the heating temperature is preferably 860 ° C. or lower from the viewpoint of suppressing damage to the heating furnace and improving productivity.
- an austenite single phase can be obtained at a temperature of 860 ° C. or lower.
- Heating time for hot press steel sheet 1 to 10 minutes
- the heating time is 1 minute or longer. If the heating time exceeds 10 minutes, ferrite transformation is less likely to occur during subsequent cooling, and the steel structure of the steel sheet member becomes a martensite single phase, and ductility deterioration may become prominent. In addition, the decrease in productivity becomes significant. Accordingly, the heating time is 10 minutes or less.
- the heating time is the time from the time when the temperature of the steel sheet reaches Ac 3 point to the end of heating.
- the end of heating is when the steel plate is taken out of the heating furnace in the case of furnace heating, and when the energization or the like is ended in the case of energization heating or induction heating.
- Average heating rate in the heating up Ac 3 point or more Ac 3 point + 100 ° C. below the temperature range is preferably set to 0.2 ° C. / sec or higher 100 ° C. / sec or less. By setting the average heating rate to 0.2 ° C./second or more, higher productivity can be secured.
- the heating temperature can be easily controlled in the case of heating using a normal furnace. However, in the case of performing high-frequency heating or current heating, since the heating temperature can be easily controlled even if the average heating rate exceeds 100 ° C./second, the average heating rate may exceed 100 ° C./second. .
- the temperature at which ferrite starts to precipitate can be controlled by adjusting the average cooling rate in hot pressing.
- the ferrite precipitation start temperature can be controlled by adjusting the average cooling rate in hot pressing.
- the ferrite precipitation start temperature is in the range of 600 ° C. to 750 ° C.
- the average cooling rate in the first cooling is less than 3 ° C./second, the ferrite transformation proceeds excessively, and the steel plate member
- the area ratio of martensite in is difficult to be 30% or more, and a tensile strength of 980 MPa or more may not be obtained.
- the average cooling rate in the first cooling is set to 3 ° C./second or more. This average cooling rate is preferably 6 ° C./second or more. Even when the ferrite precipitation start temperature is in the range of 600 ° C. to 750 ° C., if the average cooling rate in the first cooling exceeds 200 ° C./second, the area ratio of ferrite in the steel sheet member is 10% or more. It is difficult to obtain good ductility. Therefore, the average cooling rate in the first cooling is set to 200 ° C./second or less. This average cooling rate is preferably 60 ° C./second or less.
- the average cooling rate in the temperature range of 600 ° C. to 750 ° C. is 3 If it is °C / second or more and 200 °C / second or less, ferrite begins to precipitate in the temperature range of 600 °C or more and 750 °C or less.
- Average cooling rate in the second cooling 10 ° C./second to 500 ° C./second
- the average cooling rate in this temperature range is less than 10 ° C./second, a bainite transformation which is a diffusion type transformation is likely to occur, and it is difficult to make the martensite area ratio in the steel plate member 30% or more, and a tensile strength of 980 MPa or more. It is difficult to ensure strength. Therefore, the average cooling rate in the second cooling is 10 ° C./second or more.
- This average cooling rate is preferably 15 ° C./second or more from the viewpoint of ensuring a high area ratio of martensite more reliably.
- the average cooling rate in this temperature range is 500 ° C./second or less. From the viewpoint of realizing more stable cooling, this average cooling rate is preferably 200 ° C./second or less.
- the second cooling after the temperature reaches 600 ° C., heat generated by the phase transformation tends to become very large. For this reason, when cooling in a temperature range of less than 600 ° C. is performed by the same method as cooling in a temperature range of 600 ° C. or higher, a sufficient average cooling rate may not be ensured. Therefore, it is preferable to perform the second cooling from 600 ° C. to 150 ° C. more strongly than the first cooling to 600 ° C. For example, it is preferable to employ the following method.
- the cooling in the hot press is performed by previously setting a steel mold used for forming a heated steel sheet to room temperature or a temperature of about several tens of degrees Celsius, and the steel sheet comes into contact with the mold. . Therefore, the average cooling rate can be controlled by, for example, a change in heat capacity accompanying a change in the dimensions of the mold.
- the average cooling rate can also be controlled by changing the material of the mold to a different metal (such as Cu).
- the average cooling rate can also be controlled by using a water-cooled mold and changing the amount of cooling water flowing through the mold.
- the average cooling rate can also be controlled by forming a plurality of grooves in the mold in advance and passing water through the grooves during hot pressing.
- the average cooling rate can also be controlled by raising the hot press machine in the middle of hot pressing and flowing water during that time.
- the average cooling rate can also be controlled by adjusting the mold clearance and changing the contact area of the mold with the steel plate.
- Examples of the method for increasing the cooling rate in the temperature range of 600 ° C. or lower include the following three types.
- B) Use a water-cooled mold and increase the amount of flowing water in the mold immediately after reaching 600 ° C.
- the cooling rate may be increased by increasing the amount of water according to the temperature.
- the form of molding in the hot press in this embodiment is not particularly limited.
- Examples of the form of molding include bending, drawing, overhang molding, hole expansion molding, and flange molding. What is necessary is just to select the form of shaping
- molding suitably with the kind of target steel plate member.
- Representative examples of the steel plate member include a door guard bar and a bumper reinforcement which are reinforcing parts for automobiles.
- hot forming is not limited to hot pressing as long as the steel sheet can be cooled simultaneously with or immediately after forming. For example, roll forming may be performed as hot forming.
- a steel sheet member according to the present embodiment is manufactured by applying such a series of treatments to the above-described predetermined hot-press steel sheet, that is, a hot-press steel sheet in which the contents of C, Mn, and Ti are appropriate. be able to. That is, a hot-pressed steel sheet member having a desired steel structure, a tensile strength of 980 MPa, and excellent strength and ductility can be obtained without performing complicated control.
- the ductility can be evaluated by the total elongation (EL) of the tensile test, and in this embodiment, the total elongation of the tensile test is preferably 10% or more. The total elongation is more preferably 14% or more.
- ⁇ Shot blasting may be performed after hot pressing and cooling.
- the scale can be removed by shot blasting. Shot blasting also has the effect of introducing compressive stress into the surface of the steel sheet member, so that delayed fracture is suppressed and fatigue strength is improved.
- the hot pressing steel sheet is heated to a temperature range of Ac 3 points or higher and Ac 3 points + 100 ° C. or lower to cause austenite transformation and then forming. Therefore, the mechanical properties of the steel sheet for hot pressing at room temperature before heating are not important. For this reason, a hot-rolled steel plate, a cold-rolled steel plate, a plated steel plate, etc. can be used as a hot-press steel plate, for example.
- the cold-rolled steel sheet include a full hard material and an annealed material.
- the plated steel sheet include an aluminum-based plated steel sheet and a zinc-based plated steel sheet. These production methods are not particularly limited.
- the steel plate member according to the present embodiment can also be manufactured through hot pressing with pre-forming.
- the hot-press steel sheet is pre-formed by pressing with a mold having a predetermined shape, put into the same mold, and pressing pressure is applied.
- a hot-pressed steel sheet member may be manufactured by rapid cooling.
- the type of steel sheet for hot pressing and its steel structure are not limited, but it is preferable to use a steel sheet that is as soft and ductile as possible in order to facilitate preforming.
- the tensile strength is preferably 700 MPa or less.
- the coiling temperature after hot rolling in the hot-rolled steel plate is preferably 450 ° C.
- annealing temperature shall be Ac 1 point temperature or more and 900 degrees C or less.
- the average cooling rate to room temperature after annealing is below an upper critical cooling rate.
- test materials having a thickness of 1.2 mm shown in Table 2 were prepared using 23 types of steel materials having chemical compositions shown in Table 1. The balance of each steel material is Fe and impurities.
- a steel piece having a thickness of 1.2 mm, a width of 100 mm, and a length of 200 mm was cut out from each specimen, and heat treatment (heating and cooling) under the conditions shown in Table 2 was performed. Went.
- a thermocouple was attached to the steel piece, and the average cooling rate in the first cooling and the average cooling rate in the second cooling were measured.
- the ferrite precipitation start temperature was calculated
- a tensile test and observation of the steel structure were performed for each of the steel pieces.
- tensile strength (TS) and total elongation (EL) were measured.
- JIS No. 5 tensile test specimens collected from each steel piece were used.
- the area ratio of ferrite and the area ratio of martensite were obtained. These area ratios are average values of values calculated by performing an image analysis of an electron microscope observation image of a cross section orthogonal to the rolling direction and a cross section orthogonal to the sheet width direction (direction orthogonal to the rolling direction). .
- test material No. 1, no. 4, no. 6, no. 8, no. 11, no. 15, no. 16, no. 18, no. 20, no. 22, no. 24, no. 26, no. 27, and no. 29 is an example of the present invention and showed excellent tensile strength and ductility.
- Specimen No. In No. 7 since the chemical composition of the steel material was outside the range of the present invention, sufficient ductility was not obtained.
- the manufacturing conditions were outside the scope of the present invention, and the steel structure after heat treatment was also outside the scope of the present invention, so that sufficient ductility was not obtained.
- Specimen No. 25 the chemical composition of the steel was outside the scope of the present invention, and the steel structure after the heat treatment was also outside the scope of the present invention, so that sufficient tensile strength could not be obtained.
- the present invention can be used, for example, in the manufacturing industry and the use industry of automobile body structural parts and the like in which excellent tensile strength and ductility are regarded as important.
- the present invention can also be used in other industries such as manufacturing and using industries of machine structural parts.
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Abstract
Description
質量%で、
C :0.10%~0.24%、
Si:0.001%~2.0%、
Mn:1.2%~2.3%、
sol.Al:0.001%~1.0%、
Ti:0.060%~0.20%、
P :0.05%以下、
S :0.01%以下、
N :0.01%以下、
Nb:0%~0.20%、
V :0%~0.20%、
Cr:0%~1.0%、
Mo:0%~0.15%、
Cu:0%~1.0%、
Ni:0%~1.0%
Ca:0%~0.01%、
Mg:0%~0.01%、
REM:0%~0.01%、
Zr:0%~0.01%、
B :0%~0.005%、
Bi:0%~0.01%、
残部:Fe及び不純物
で表される化学組成を有し、
面積%で、フェライト:10%~70%、マルテンサイト:30%~90%、フェライト及びマルテンサイトの合計面積率:90%~100%である鋼組織を有し、
鋼中の全Tiのうちの90%以上が析出し、
引張強度が980MPa以上であることを特徴とする熱間プレス鋼板部材。
前記化学組成が、質量%で、
Nb:0.003%~0.20%、
V :0.003%~0.20%、
Cr:0.005%~1.0%、
Mo:0.005%~0.15%、
Cu:0.005%~1.0%、及び
Ni:0.005%~1.0%
からなる群から選択された1種又は2種以上を含有することを特徴とする(1)に記載の熱間プレス鋼板部材。
前記化学組成が、質量%で、
Ca:0.0003%~0.01%、
Mg:0.0003%~0.01%、
REM:0.0003%~0.01%、及び
Zr:0.0003%~0.01%
からなる群から選択された1種又は2種以上を含有することを特徴とする(1)又は(2)に記載の熱間プレス鋼板部材。
前記化学組成が、質量%で、B:0.0003%~0.005%を含有することを特徴とする(1)~(3)のいずれかに記載の熱間プレス鋼板部材。
前記化学組成が、質量%で、Bi:0.0003%~0.01%を含有することを特徴とする(1)~(4)のいずれかに記載の熱間プレス鋼板部材。
質量%で、
C :0.10%~0.24%、
Si:0.001%~2.0%、
Mn:1.2%~2.3%、
sol.Al:0.001%~1.0%、
Ti:0.060%~0.20%、
P :0.05%以下、
S :0.01%以下、
N :0.01%以下、
Nb:0%~0.20%、
V :0%~0.20%、
Cr:0%~1.0%、
Mo:0%~0.15%、
Cu:0%~1.0%、
Ni:0%~1.0%、
Ca:0%~0.01%、
Mg:0%~0.01%、
REM:0%~0.01%、
Zr:0%~0.01%、
B :0%~0.005%、
Bi:0%~0.01%、
残部:Fe及び不純物
で表される化学組成を有し、
鋼中の全Tiのうちの70%以上が析出していることを特徴とする熱間プレス用鋼板。
前記化学組成が、質量%で、
Nb:0.003%~0.20%、
V :0.003%~0.20%、
Cr:0.005%~1.0%、
Mo:0.005%~0.15%、
Cu:0.005%~1.0%、及び
Ni:0.005%~1.0%
からなる群から選択された1種又は2種以上を含有することを特徴とする(6)に記載の熱間プレス用鋼板。
前記化学組成が、質量%で、
Ca:0.0003%~0.01%、
Mg:0.0003%~0.01%、
REM:0.0003%~0.01%、及び
Zr:0.0003%~0.01%
からなる群から選択された1種又は2種以上を含有することを特徴とする(6)又は(7)に記載の熱間プレス用鋼板。
前記化学組成が、質量%で、B:0.0003%~0.005%を含有することを特徴とする(6)~(8)のいずれかに記載の熱間プレス用鋼板。
前記化学組成が、質量%で、Bi:0.0003%~0.01%を含有することを特徴とする(6)~(9)のいずれかに記載の熱間プレス用鋼板。
(6)~(10)のいずれかに記載の熱間プレス用鋼板を、Ac3点~Ac3点+100℃の温度域に1分間~10分間加熱する工程と、
前記加熱の後に、熱間プレスを行う工程と、
を有し、
前記熱間プレスを行う工程は、
600℃~750℃の温度域で第1の冷却を行う工程と、
150℃~600℃の温度域で第2の冷却を行う工程と、
を有し、
前記第1の冷却では、平均冷却速度を3℃/秒~200℃/秒として600℃~750℃の温度域でフェライトを析出し始めさせ、
前記第2の冷却では、平均冷却速度を10℃/秒~500℃/秒とすることを特徴とする熱間プレス鋼板部材の製造方法。
Cは、熱間プレス用鋼板の焼入れ性を高め、かつ鋼板部材の強度を主に決定する非常に重要な元素である。鋼板部材のC含有量が0.10%未満では、980MPa以上の引張強度を確保することが困難である。従って、C含有量は0.10%以上とする。熱間プレス用鋼板のC含有量が0.24%超では、鋼板部材の鋼組織がマルテンサイト単相となり、延性の劣化が顕著である。従って、C含有量は0.24%以下とする。溶接性の観点から、鋼板部材のC含有量は好ましくは0.21%以下であり、より好ましくは0.18%以下である。
Siは、鋼板部材の強度及び延性の向上に効果のある元素である。Si含有量が0.001%未満では、上記作用を得ることが困難である。従って、Si含有量は0.001%以上とする。Si含有量が2.0%超では、上記作用による効果は飽和して経済的に不利となるうえに、めっき濡れ性の低下が著しくなり、不めっきが多発する。従って、Si含有量は2.0%以下とする。延性の更なる向上の観点から、Si含有量は好ましくは0.05%以上である。溶接性を向上させる観点から、Si含有量は好ましくは0.2%以上である。熱間プレス時にオーステナイト単相とするための温度を比較的低温とする観点から、Si含有量は好ましくは0.6%以下である。この温度が比較的低温であれば、加熱時間の短縮、生産性の向上、製造コストの低減、及び加熱炉の損傷の抑制等の効果が得られる。
Mnは、熱間プレス用鋼板の焼入れ性の向上及び鋼板部材の強度の確保に非常に効果のある元素である。Mn含有量が1.2%未満では、上記作用を得ることが困難である。従って、Mn含有量は1.2%以上とする。Mn含有量が2.3%超では、鋼板部材の鋼組織がマルテンサイト単相となり、延性の劣化が顕著である。従って、Mn含有量は2.3%以下とする。熱間プレス時にオーステナイト単相とするための温度を比較的低温(例えば860℃以下)とする観点から、Mn含有量は好ましくは1.4%以上である。鋼板部材の鋼組織が顕著なバンド状になることを抑制して良好な曲げ性を得る観点から、Mn含有量は好ましくは2.2%以下であり、より好ましくは2.1%以下である。
Alは、鋼を脱酸して鋼材を健全化する作用を有する元素である。Alは、Ti等の炭窒化物形成元素の歩留まりを向上させる作用も有する。sol.Al含有量が0.001%未満では、上記作用を得ることが困難である。従って、sol.Al含有量は0.001%以上とする。上記作用をより確実に得るために、sol.Al含有量は好ましくは0.015%以上である。sol.Al含有量が1.0%超では、溶接性の低下が著しくなるとともに、酸化物系介在物が増加し、表面性状の劣化が著しくなる。従って、sol.Al含有量は1.0%以下とする。より良好な表面性状を得るために、sol.Al含有量は好ましくは0.080%以下である。
Tiは、熱間プレス時のフェライト変態を促進する元素である。フェライト変態の促進により鋼板部材の延性が著しく向上する。また、Tiは炭化物、窒化物、又は炭窒化物として微細に析出し、鋼板部材の鋼組織を微細化する。Ti含有量が0.060%未満では、フェライト変態が十分に促進されず、鋼板部材の鋼組織がマルテンサイト単相になりやすく、十分な延性が得られない。従って、Ti含有量は0.060%以上とする。延性の更なる向上の観点から、Ti含有量は好ましくは0.075%以上である。Ti含有量が0.20%超では、熱間プレス用鋼板を得るための鋳造時及び熱間圧延時に粗大な炭窒化物が形成されてしまい、靭性の劣化が顕著となる。従って、Ti含有量は0.20%以下とする。優れた靱性の確保の観点から、Ti含有量は好ましくは0.18%以下であり、より好ましくは0.15%以下である。
Pは、必須元素ではなく、例えば鋼中に不純物として含有される。溶接性の観点から、P含有量は低ければ低いほどよい。特にP含有量が0.05%超で、溶接性の低下が著しい。従って、P含有量は0.05%以下とする。より良好な溶接性を確保するために、P含有量は好ましくは0.018%以下である。その一方で、Pは、固溶強化により鋼の強度を高める作用を有する。この作用を得るために、0.003%以上のPが含有されていてもよい。
Sは、必須元素ではなく、例えば鋼中に不純物として含有される。溶接性の観点から、S含有量は低ければ低いほどよい。特にS含有量が0.01%超で、溶接性の低下が著しい。従って、S含有量は0.01%以下とする。より良好な溶接性を確保するために、S含有量は好ましくは0.003%以下であり、より好ましくは0.0015%以下である。
Nは、必須元素ではなく、例えば鋼中に不純物として含有される。溶接性の観点から、N含有量は低ければ低いほどよい。特にN含有量が0.01%超で、溶接性の低下が著しい。従って、N含有量は0.01%以下とする。より良好な溶接性を確保するために、N含有量は好ましくは0.006%以下である。
Nb、V、Cr、Mo、Cu、及びNiは、いずれも熱間プレス用鋼板の焼入れ性を高め、鋼板部材の強度の安定した確保に効果のある元素である。従って、これらの元素からなる群から選択された1種又は2種以上が含有されていてもよい。しかし、Nb及びVについては、いずれかの含有量が0.20%超であると、熱間プレス用鋼板を得るための熱間圧延及び冷間圧延が困難になるだけでなく、鋼板部材の鋼組織がマルテンサイト単相となり、延性の劣化が顕著である。従って、Nb含有量及びV含有量は、いずれも0.20%以下とする。Crについては、その含有量が1.0%超であると、安定した強度の確保が困難になる。従って、Cr含有量は1.0%以下とする。Moについては、その含有量が0.15%超であると、鋼板部材の鋼組織がマルテンサイト単相となり、延性の劣化が顕著である。従って、Mo含有量は0.15%以下とする。Cu及びNiについては、いずれかの含有量が1.0%であると、上記作用による効果は飽和して経済的に不利となるうえに、熱間プレス用鋼板を得るための熱間圧延及び冷間圧延が困難になる。従って、Cu含有量及びNi含有量は、いずれも1.0%以下とする。鋼板部材の強度の安定した確保のために、Nb含有量及びV含有量は、いずれも好ましくは0.003%以上であり、Cr含有量、Mo含有量、Cu含有量、及びNi含有量は、いずれも好ましくは0.005%以上である。つまり、「Nb:0.003%~0.20%」、「V:0.003%~0.20%」、「Cr:0.005%~1.0%」、「Mo:0.005%~0.15%」、「Cu:0.005%~1.0%」、及び「Ni:0.005%~1.0%」のうちの少なくとも一つが満たされることが好ましい。
Ca、Mg、REM、及びZrは、いずれも介在物の制御、特に、介在物の微細分散化に寄与し、靭性を高める作用を有する元素である。従って、これらの元素からなる群から選択された1種又は2種以上が含有されていてもよい。しかし、いずれかの含有量が0.01%超であると、表面性状の劣化が顕在化する場合がある。従って、Ca含有量、Mg含有量、REM含有量、及びZr含有量は、いずれも0.01%以下とする。靭性の向上のために、Ca含有量、Mg含有量、REM含有量、及びZr含有量は、いずれも好ましくは0.0003%以上である。つまり、「Ca:0.0003%~0.01%」、「Mg:0.0003%~0.01%」、「REM:0.0003%~0.01%」、及び「Zr:0.0003%~0.01%」のうちの少なくとも一つが満たされることが好ましい。
Bは、鋼板の靭性を高める作用を有する元素である。従って、Bが含有されていてもよい。しかし、B含有量が0.005%超であると、鋼板部材の鋼組織がマルテンサイト単相となり、延性の劣化が顕著である。また、熱間加工性が劣化して、熱間プレス用鋼板を得るための熱間圧延が困難になることがある。従って、B含有量は0.005%以下とする。靭性の向上のために、B含有量は好ましくは0.0003%以上である。つまり、B含有量は0.0003%~0.005%であることが好ましい。
Biは、鋼組織を均一にし、延性を高める作用を有する元素である。従って、Biが含有されていてもよい。しかし、Bi含有量が0.01%超であると、熱間加工性が劣化して、熱間プレス用鋼板を得るための熱間圧延が困難になる。従って、Bi含有量は0.01%以下とする。延性の向上のために、Bi含有量は好ましくは0.0003%以上である。つまり、Bi含有量は0.0003%~0.01%であることが好ましい。
ネットワーク状に析出したフェライトが鋼板部材の延性を向上に寄与する。フェライトの面積率が10%未満では、フェライトがネットワークを構成しにくく、十分な延性を得ることができない。従って、フェライトの面積率は10%以上とする。フェライトの面積率が70%超では、必然的にマルテンサイトの面積率が30%未満となり、980MPa以上の引張強度を鋼板部材に確保することが困難である。従って、フェライトの面積率は70%以下とする。
マルテンサイトは鋼板部材の高強度化に重要である。マルテンサイトの面積率が30%未満では、980MPa以上の引張強度を鋼板部材に確保することが困難である。従って、マルテンサイトの面積率は30%以上とする。マルテンサイトの面積率が90%超では、必然的にフェライトの面積率が10%未満となり、十分な延性を得ることができない。従って、マルテンサイトの面積率は90%以下とする。
本実施形態に係る熱間プレス鋼板部材の鋼組織は、フェライト及びマルテンサイトからなること、つまり、フェライト及びマルテンサイトの合計面積率が100%であることが好ましい。しかし、製造条件によっては、フェライト及びマルテンサイト以外の相又は組織として、ベイナイト、残留オーステナイト、セメンタイト、及びパーライトからなる群から選択された1種又は2種以上が含まれることもある。この場合、フェライト及びマルテンサイト以外の相又は組織の面積率が10%超であると、これらの相又は組織の影響により、目的とする特性が得られないことがある。従って、フェライト及びマルテンサイト以外の相又は組織の面積率は10%以下とする。すなわち、フェライト及びマルテンサイトの合計面積率は90%以上とする。
Tiの析出物は鋼板部材の安定した引張強度の確保に寄与する。上記のように、鋼板部材には0.060%~0.20%のTiが含有されているが、そのうちで析出しているTiの割合が90%未満であると、上記作用を得ることが困難である。従って、鋼板部材では、鋼中の全Tiのうちで析出しているものの割合は90%以上とする。Tiの析出物は、例えば炭化物、窒化物又は炭窒化物として鋼板部材に含まれている。鋼板部材の電解抽出により得られた残渣の誘導結合プラズマ(ICP:inductively coupled plasma)分析により、当該鋼板部材中に析出していたTiの量を特定することができる。
熱間プレス用鋼板に含まれている全Tiのうちで析出しているものの割合が70%未満であると、熱間プレス時にフェライト変態が生じにくく、所望の鋼組織を備えた鋼板部材を得ることが困難である。従って、熱間プレス用鋼板では、鋼中の全Tiのうちで析出しているものの割合は70%以上とする。
熱間プレスに供する鋼板、つまり熱間プレス用鋼板の加熱は、Ac3点以上Ac3点+100℃以下の温度域において行う。Ac3点は、下記実験式(i)により規定されるオーステナイト単相になる温度(単位:℃)である。
-11×Cr-20×Cu+700×P+400×Al+50×Ti ・・・ (i)
ここで、上記式中における元素記号は、鋼板の化学組成における各元素の含有量(単位:質量%)を示す。
加熱時間が1分間未満では、オーステナイトの単相組織が不均一になりやすく、安定した強度の確保が困難である。従って、加熱時間は1分間以上とする。加熱時間が10分間超では、その後の冷却の際にフェライト変態が生じにくくなり、鋼板部材の鋼組織がマルテンサイト単相となって延性の劣化が顕著となることがある。また、生産性の低下が顕著となる。従って、加熱時間は10分間以下とする。
熱間プレスにおけるフェライトの析出開始温度は、フェライトの性質に影響を及ぼす。フェライトが750℃超で析出し始めると、フェライトが粗大化し、靭性が劣化する。フェライトが600℃未満で析出し始めると、フェライト中の転位密度が高くなり、延性が劣化する。従って、第1の冷却では、600℃~750℃の温度域でフェライトを析出し始めさせる。
フェライトを析出し始めさせる温度、すなわちフェライトの析出開始温度は、熱間プレスにおける平均冷却速度の調整により制御することができる。例えば、熱膨張曲線の解析により求めた条件下で第1の冷却を行うことが好ましい。しかし、フェライトの析出開始温度が600℃~750℃の範囲内にあっても、第1の冷却での平均冷却速度が3℃/秒未満であると、フェライト変態が過度に進行し、鋼板部材におけるマルテンサイトの面積率を30%以上としにくく、980MPa以上の引張強度が得られないことがある。また、空冷又は強制空冷のみによって平均冷却速度を3℃/秒未満に制御しにくい。従って、第1の冷却での平均冷却速度は3℃/秒以上とする。この平均冷却速度は、好ましくは6℃/秒以上である。また、フェライトの析出開始温度が600℃~750℃の範囲内にあっても、第1の冷却での平均冷却速度が200℃/秒超では、鋼板部材におけるフェライトの面積率を10%以上としにくく、良好な延性が得られないことがある。従って、第1の冷却での平均冷却速度は200℃/秒以下とする。この平均冷却速度は、好ましくは60℃/秒以下である。
150℃以上600℃以下の温度域における冷却では拡散型変態を生じにくくすることが重要である。この温度域における平均冷却速度が10℃/秒未満では、拡散型変態であるベイナイト変態が生じやすく、鋼板部材におけるマルテンサイトの面積率を30%以上とすることが困難であり、980MPa以上の引張強度を確保することが困難である。従って、第2の冷却での平均冷却速度は10℃/秒以上とする。より確実にマルテンサイトの面積率を高く確保する観点から、この平均冷却速度は好ましくは15℃/秒以上である。第2の冷却での平均冷却速度を500℃/秒超とすることは通常の設備においては困難である。従って、この温度域における平均冷却速度は500℃/秒以下とする。より安定した冷却を実現する観点から、この平均冷却速度は好ましくは200℃/秒以下である。
(a)600℃到達直後に、熱容量の異なる金型又は室温状態の金型に鋼板を移動させる。
(b)水冷金型を用い、600℃到達直後に金型中の流水量を増加させる。
(c)600℃到達直後に、金型と鋼板との間に水を流す。この方法では、温度に応じて水量を増加させることでより冷却速度を高めてもよい。
Claims (11)
- 質量%で、
C :0.10%~0.24%、
Si:0.001%~2.0%、
Mn:1.2%~2.3%、
sol.Al:0.001%~1.0%、
Ti:0.060%~0.20%、
P :0.05%以下、
S :0.01%以下、
N :0.01%以下、
Nb:0%~0.20%、
V :0%~0.20%、
Cr:0%~1.0%、
Mo:0%~0.15%、
Cu:0%~1.0%、
Ni:0%~1.0%、
Ca:0%~0.01%、
Mg:0%~0.01%、
REM:0%~0.01%、
Zr:0%~0.01%、
B :0%~0.005%、
Bi:0%~0.01%、
残部:Fe及び不純物
で表される化学組成を有し、
面積%で、フェライト:10%~70%、マルテンサイト:30%~90%、フェライト及びマルテンサイトの合計面積率:90%~100%である鋼組織を有し、
鋼中の全Tiのうちの90%以上が析出し、
引張強度が980MPa以上であることを特徴とする熱間プレス鋼板部材。 - 前記化学組成が、質量%で、
Nb:0.003%~0.20%、
V :0.003%~0.20%、
Cr:0.005%~1.0%、
Mo:0.005%~0.15%、
Cu:0.005%~1.0%、及び
Ni:0.005%~1.0%
からなる群から選択された1種又は2種以上を含有することを特徴とする請求項1に記載の熱間プレス鋼板部材。 - 前記化学組成が、質量%で、
Ca:0.0003%~0.01%、
Mg:0.0003%~0.01%、
REM:0.0003%~0.01%、及び
Zr:0.0003%~0.01%
からなる群から選択された1種又は2種以上を含有することを特徴とする請求項1又は2に記載の熱間プレス鋼板部材。 - 前記化学組成が、質量%で、B:0.0003%~0.005%を含有することを特徴とする請求項1乃至3のいずれか1項に記載の熱間プレス鋼板部材。
- 前記化学組成が、質量%で、Bi:0.0003%~0.01%を含有することを特徴とする請求項1乃至4のいずれか1項に記載の熱間プレス鋼板部材。
- 質量%で、
C :0.10%~0.24%、
Si:0.001%~2.0%、
Mn:1.2%~2.3%、
sol.Al:0.001%~1.0%、
Ti:0.060%~0.20%、
P :0.05%以下、
S :0.01%以下、
N :0.01%以下、
Nb:0%~0.20%、
V :0%~0.20%、
Cr:0%~1.0%、
Mo:0%~0.15%、
Cu:0%~1.0%、
Ni:0%~1.0%、
Ca:0%~0.01%、
Mg:0%~0.01%、
REM:0%~0.01%、
Zr:0%~0.01%、
B :0%~0.005%、
Bi:0%~0.01%、
残部:Fe及び不純物
で表される化学組成を有し、
鋼中の全Tiのうちの70%以上が析出していることを特徴とする熱間プレス用鋼板。 - 前記化学組成が、質量%で、
Nb:0.003%~0.20%、
V :0.003%~0.20%、
Cr:0.005%~1.0%、
Mo:0.005%~0.15%、
Cu:0.005%~1.0%、及び
Ni:0.005%~1.0%
からなる群から選択された1種又は2種以上を含有することを特徴とする請求項6に記載の熱間プレス用鋼板。 - 前記化学組成が、質量%で、
Ca:0.0003%~0.01%、
Mg:0.0003%~0.01%、
REM:0.0003%~0.01%、及び
Zr:0.0003%~0.01%
からなる群から選択された1種又は2種以上を含有することを特徴とする請求項6又は7に記載の熱間プレス用鋼板。 - 前記化学組成が、質量%で、B:0.0003%~0.005%を含有することを特徴とする請求項6乃至8のいずれか1項に記載の熱間プレス用鋼板。
- 前記化学組成が、質量%で、Bi:0.0003%~0.01%を含有することを特徴とする請求項6乃至9のいずれか1項に記載の熱間プレス用鋼板。
- 請求項6乃至10のいずれか1項に記載の熱間プレス用鋼板を、Ac3点~Ac3点+100℃の温度域に1分間~10分間加熱する工程と、
前記加熱の後に、熱間プレスを行う工程と、
を有し、
前記熱間プレスを行う工程は、
600℃~750℃の温度域で第1の冷却を行う工程と、
150℃~600℃の温度域で第2の冷却を行う工程と、
を有し、
前記第1の冷却では、平均冷却速度を3℃/秒~200℃/秒として600℃~750℃の温度域でフェライトを析出し始めさせ、
前記第2の冷却では、平均冷却速度を10℃/秒~500℃/秒とすることを特徴とする熱間プレス鋼板部材の製造方法。
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US15/104,689 US10344351B2 (en) | 2013-12-20 | 2013-12-20 | Hot-pressed steel sheet member, method of manufacturing the same, and steel sheet for hot pressing |
ZA2016/04074A ZA201604074B (en) | 2013-12-20 | 2016-06-15 | Hot-pressed steel sheet member and method for producing same, and steel sheet for hot pressing |
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JPWO2021145442A1 (ja) * | 2020-01-16 | 2021-07-22 | ||
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CA2933435A1 (en) | 2015-06-25 |
CA2933435C (en) | 2020-03-24 |
RU2650233C1 (ru) | 2018-04-13 |
KR101825859B1 (ko) | 2018-02-05 |
CN105829562A (zh) | 2016-08-03 |
BR112016014036B1 (pt) | 2019-11-19 |
ZA201604074B (en) | 2020-05-27 |
EP3085801A1 (en) | 2016-10-26 |
CN105829562B (zh) | 2019-09-20 |
PL3085801T3 (pl) | 2020-04-30 |
MX2016007799A (es) | 2016-09-07 |
US10344351B2 (en) | 2019-07-09 |
US20160312330A1 (en) | 2016-10-27 |
EP3085801B1 (en) | 2019-10-02 |
RU2016129453A (ru) | 2018-01-25 |
EP3085801A4 (en) | 2017-08-16 |
JP6288108B2 (ja) | 2018-03-07 |
ES2759851T3 (es) | 2020-05-12 |
JPWO2015092929A1 (ja) | 2017-03-16 |
KR20160085312A (ko) | 2016-07-15 |
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