WO2014204196A1 - Method of manufacturing decoration for shoe - Google Patents

Method of manufacturing decoration for shoe Download PDF

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Publication number
WO2014204196A1
WO2014204196A1 PCT/KR2014/005341 KR2014005341W WO2014204196A1 WO 2014204196 A1 WO2014204196 A1 WO 2014204196A1 KR 2014005341 W KR2014005341 W KR 2014005341W WO 2014204196 A1 WO2014204196 A1 WO 2014204196A1
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WO
WIPO (PCT)
Prior art keywords
coating layer
shoe
decoration
vacuum
manufacturing
Prior art date
Application number
PCT/KR2014/005341
Other languages
French (fr)
Korean (ko)
Inventor
유흥상
Original Assignee
Yu Heung Sang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020130070723A external-priority patent/KR101402459B1/en
Priority claimed from KR1020130138829A external-priority patent/KR101467120B1/en
Priority claimed from KR1020140002216A external-priority patent/KR101457841B1/en
Application filed by Yu Heung Sang filed Critical Yu Heung Sang
Publication of WO2014204196A1 publication Critical patent/WO2014204196A1/en

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    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B3/00—Footwear characterised by the shape or the use
    • A43B3/0036—Footwear characterised by the shape or the use characterised by a special shape or design
    • A43B3/0078—Footwear characterised by the shape or the use characterised by a special shape or design provided with logos, letters, signatures or the like decoration
    • A43B3/0084—Arrangement of flocked decoration on shoes
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00—Footwear characterised by the material
    • A43B1/0027—Footwear characterised by the material made at least partially from a material having special colours
    • A43B1/0036—Footwear characterised by the material made at least partially from a material having special colours with fluorescent or phosphorescent parts
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
    • A43B23/24—Ornamental buckles; Other ornaments for shoes without fastening function
    • A43B23/25—Arrangement of ribbons on footwear

Definitions

  • the present invention relates to a shoe manufacturing method of the shoe, and more particularly to a shoe manufacturing method of emphasizing aesthetics by forming a coating layer by the vacuum coating method on the outer portion of the shoe that is easy to be seen by people in the shoe.
  • the present invention relates to a method of manufacturing a decoration of the shoe, and more particularly, the decoration is attached to the exterior portion of the outsole or midsole that is easy to be seen by people in the shoe, the decoration forms a coating layer by a vacuum coating method on the surface
  • the present invention relates to a manufacturing method of a shoe that emphasizes aesthetics.
  • Patent Publication No. 1998-083407 adopts a vacuum method or a semi-vacuum method, and vacuum forming.
  • the device (A) and the hermetic molding device (B) are made of leather and a transparent resin film or a leather material with a sponge to complete a decoration in which a pressurized or atmospheric pressure space is formed in the depression, or the original thickness is applied to the depression.
  • the method of manufacturing a decoration attached to the surface of a shoe or a bag characterized in that the solution is solved by a method of manufacturing a decorative member formed with a sponge extruded sponge parts are formed on the edge thereof is produced by the manufacturing method
  • the ornament is open to the public.
  • Korean Utility Model Publication No. 2000-0018205 discloses a shoe, such as a shoe, slippers, sandals, and sneakers, wherein the shoe is provided with a detachable means at a contact portion where the instep of the shoe is in contact with a decoration.
  • the decoration is characterized in that the plate-shaped or high-frequency heat fusion of the print or figure of the character, or a doll, such as a variety of animals, plants or toys, and the removable means is a snap button, a button or a magic tape Decorative removable shoes are featured.
  • Korean Utility Model Registration No. 20-0341093 discloses a shoe ornament characterized in that the ornament detachably attached to the side of the shoe by the coupling means.
  • the surface of the shoe decorative band is produced by mixing the pigment in the material for aesthetics in this case, the color is monotonous and turbid, even if the coating has a disadvantage that the coating state is not good and the aesthetics are poor.
  • the conventional shoe outsole is a constituent member constituting the lower part of the shoe, and the thickness of the midsole is usually used as a means for mainly protecting the lower part of the foot when wearing shoes.
  • these outsoles are usually one of the major components supporting the underside of a shoe.
  • Patent Publication No. 10-0356717 is a technical gist of the shoe outsole (1) in claim 1;
  • the outsole 1 is formed with a concave chamber 2 and sealed with a cushion cover 3 at the upper portion thereof to form an air chamber 4, which is detachable by an opening and closing means 7 in the air chamber 4.
  • An antibacterial air freshener interior room 5 is formed by the built-in wall 12 so that the antimicrobial air freshener 6 can be incorporated therein;
  • An air inflow hole 13 is formed in the upper portion of the antibacterial air freshener interior chamber 5 so that air introduced through the air induction groove 15 and the air discharge hole 14 formed by the interior wall 12 is cushioned.
  • a plurality of auxiliary inlet chamber 11 is formed in the urine inlet chamber 2, and the cushion cover 3 is a shoe outsole is characterized in that a plurality of buffer projections 16 are formed.
  • Korean Patent Laid-Open Publication No. 10-2011-0056806 discloses a shoe outsole divided into a soft part and a hard part to have a length ratio of 4: 6 with respect to the total length, and the soft part corresponds to the front heel of the outsole.
  • the hard part of the outsole corresponds to the heel of the outsole, and the soft part and the hard part are configured to be integrated through the joining by pressure molding, wherein the soft part comprises: rubber raw material 100: accelerator 2: activator 5: staric acid 10: carbon black 30: Graphite 20 is mixed and molded at a weight ratio of lubricant 1, wherein the hard part is mixed and molded at a weight ratio of rubber material 100: accelerator 2: activator 5: stannic acid 10: carbon black 50: lubricant 1
  • the shoe outsole for improving the convenience of walking is disclosed.
  • the outsole surface has a disadvantage in that the color is monotonous and turbid when the pigment is mixed with the material, and the coating state is not good and the aesthetics are poor even when coated.
  • a conventional shoe 5 is composed of an upper 1, an insole 2, a midsole 3 and an outsole 4.
  • the upper 1 is directly coupled to the upper portion of the outsole 4 to manufacture the shoe 5, or the upper 1 is directly coupled to the midsole 3 without the outsole 4 to form the shoe 5. It may be, which will vary depending on the function and use of the shoe (1).
  • various kinds of shoes (5) are produced, for example, in order to be used as jogging shoes 3) and the outsole (4) and the upper (1) is made of a material that is shock-absorbing and lightweight material, and in addition to the midsole (3) in the shoe (5) that requires a function for wear resistance and anti-slip Outsole (4) attached to the bottom of the) is to produce a shoe (5) using a rubber material.
  • the price and price of the shoe 5 as well as the type and function of the shoe 5 are determined according to how the structures, shapes, and materials of the midsole 3 and the outsole 4 forming the sole are configured. Will be.
  • the outsole 4 and the midsole 3 forming the sole as described above are usually manufactured separately so that the outsole 4 is attached to the bottom of the midsole 3. This is because the soles of the soles and the midsoles of the midsole play different roles in the shoe.
  • the outsole (4) is mainly made of rubber or non-foamed polyurethane because the material is configured to perform such a function because the main function is to prevent the slip and landing wear due to long time use.
  • the midsole 3 is made of ethylene vinyl acetate or a foamed polyurethane material of a relatively light material because the main purpose is to absorb shock and lighten the weight of the shoe.
  • the midsole in the ordinary shoes (5) composed of the upper (1), the insole (2), the midsole (3) and the outsole (4) with respect to the midsole.
  • Health shoes Beauty having a midsole structure of a triple structure is characterized by consisting of an EVA (EVA) layer surrounding the outer shell of the polyurethane layer is disclosed.
  • EVA EVA
  • Korean Patent Laid-Open Publication No. 10-2013-0096660 discloses a method for manufacturing a shoe midsole, comprising: preparing an upper midsole sheet, a lower midsole sheet, and an insertion member; Grind the receiving groove by using a grinding wheel on at least one surface of the upper midsole sheet and the lower midsole sheet so that the insertion member is received between the corresponding surface where the upper midsole sheet and the lower midsole sheet are in contact with each other. Forming; And inserting the insertion member into the receiving groove and laminating the upper midsole sheet and the lower midsole sheet to obtain a midsole.
  • the conventional midsole surface has a disadvantage in that the color is monotonous and turbid when the pigment is mixed with the material, and the coating state is not good and the aesthetics are poor even when coated.
  • the present invention has been made to solve the above problems, and to provide a shoe manufacturing method of the shoe layer to improve the gloss and aesthetics by forming a coating layer on the shoe decorative band by a vacuum coating method.
  • the present invention has been made to solve the above problems, the decoration is attached to the shoe outsole or midsole, the decoration is formed by a vacuum coating method of a metallic coating layer on the pad of polyester material to refraction of light And it is to provide a method of manufacturing a decoration of the shoe that can be polished by the reflection and improve the aesthetics.
  • the present invention relates to a shoe manufacturing method of the shoe, the method of forming a vacuum coating layer of the shoe decorative band, the coating layer is formed on the outer surface of the shoe decorative band, characterized in that the coating layer is formed by a vacuum coating method.
  • the present invention relates to a method of manufacturing a shoe ornament, in the shoe manufacturing method of the shoe manufacturing a decoration that is attached to the outer surface of the shoe outsole or midsole, the decoration is a coating layer formed on a polyester pad, the coating layer is spatter It is characterized by being formed by the vacuum coating method of the turing method or the evaporating method.
  • the present invention has a remarkable effect that the coating layer is formed on the decorative band of the shoe by a vacuum coating method so that the coating layer is glossy and improves aesthetics.
  • the present invention is a decoration attached to the shoe outsole or midsole, the decoration is formed by coating a metallic coating layer on the pad of the polyester material by vacuum coating method, the coating layer is glossy and aesthetical by refraction and reflection of light There is a significant effect that can be improved.
  • FIG. 1 is a perspective view of the decorative band for shoes according to the present invention
  • FIG. 2 is a layout view of a vacuum coating apparatus used in the present invention
  • FIG. 3 is a schematic diagram of a vacuum coating apparatus installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention.
  • Figure 4 is a schematic cutaway view of the vacuum coating apparatus installed Sputte rmodule, Linear ion source and Thermal evaporation source used in the present invention
  • FIG. 5 is an exploded schematic view of a vacuum coating apparatus installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention.
  • Figure 6 is a schematic plan view of a vacuum coating apparatus installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention
  • FIG. 7 is an enlarged partial view of FIG. 6.
  • FIG. 8 is a perspective view of a conventional shoe outsole
  • Figure 9 is a polyester material decorative pads produced by the method for manufacturing a decoration of the present invention shoes
  • FIG. 11 is a perspective view of a conventional shoe
  • Figure 13 is a plan view of the midsole used in the present invention.
  • sputter 110 resistance heating type evaporation source
  • the present invention relates to a method of manufacturing a shoe ornament, the method of forming a vacuum coating layer of the shoe decorative band, forming a coating layer on the outer surface of the shoe decorative band, the coating layer by a vacuum coating method of the sputtering method or evaporating method It is characterized by being formed.
  • the coating layer is made of a base layer and a multilayer coating layer
  • the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn
  • the multilayer coating layer is a sputtering method In the case of Ti, Zr, Ag, Au, Cu, Si, it is characterized in that formed by selecting two or more components of the even number.
  • the coating layer is made of a base layer and a multilayer coating layer
  • the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn
  • the multilayer coating layer is evaporating In the case of the method, it is formed by selecting two or more components of SiO 2, Nb 2 O 3 , Nb 2 O 5 , SiO, SiO 2 , Z 2 O, ZrO 2 , TiO, TiO 2 in even units. .
  • the present invention relates to a shoe ornament manufacturing method of manufacturing a shoe that is attached to the outer surface of the shoe sole or midsole, the decoration is a coating layer formed on a polyester pad, the coating layer is a sputtering method or vacuum evaporation method It is characterized by being formed by a coating method.
  • the coating layer is made of a base coating layer and a multilayer coating layer
  • the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn
  • the multilayer coating layer is a sputtering method In the case of Ti, Zr, Ag, Au, Cu, Si, It is characterized in that formed by selecting two components of Sn.
  • C 2 H 2 , N 2 , O 2 , or Ar gas is injected into the vacuum chamber as a reactive gas.
  • the coating layer is made of a base coating layer and a multilayer coating layer
  • the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn
  • the multilayer coating layer is evaporating
  • the method is characterized in that formed by selecting two components of SiO 2, Nb 2 O 3 , Nb 2 O 5 , SiO, SiO 2 , Z 2 O, ZrO 2 , TiO, TiO 2 .
  • the decoration is a coating layer is formed on a microfiber cloth made of polyester microfiber, the coating layer is characterized in that formed by the vacuum coating method of the sputtering method or evaporator writing method.
  • FIG. 1 is a perspective view of the decorative band for shoes according to the present invention
  • FIG. 2 is a layout view of a vacuum coating device used in the present invention
  • FIG. 3 is a schematic diagram illustrating a vacuum coating device installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention
  • 4 is a schematic cutaway view of a vacuum coating apparatus installed with a sputte rmodule, a linear ion source and a thermal evaporation source used in the present invention
  • FIG. 5 is an exploded schematic view of a vacuum coating apparatus installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention.
  • 6 is a schematic plan view of a vacuum coating apparatus installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention
  • FIG. 7 is a partially enlarged view of FIG. 6
  • FIG. 8 is a perspective view of a conventional shoe outsole
  • FIG. 9 is the present invention.
  • Decorative pad made of polyester material produced by the shoe manufacturing method of the shoe is a polyester produced by the manufacturing method of the shoe of the present invention Terex microfiber cloth
  • Figure 11 is a conventional shoe perspective view
  • Figure 12 is a midsole side photograph used in the present invention
  • Figure 13 is a midsole planar photograph used in the present invention.
  • the present invention is to form a vacuum coating layer on the outer surface of the decorative band for shoes.
  • the coating layer is formed on the outer surface of the decorative band for shoes is excellent in aesthetics.
  • the shoe decorative band is injection-molded with synthetic resins such as PP and PE, and a coating layer is formed on the surface of the injection-molded product by a vacuum coating method.
  • the shoe decorative band of the present invention is a length of about 4 ⁇ 6cm, a width of about 1cm band, injection-molded with synthetic resin, such as PP, PE, there is flexibility.
  • the left and right side surfaces of the band are inclined to form an aesthetic sense.
  • the upper and lower sides of the decorative band for shoes to form a plurality of triangular teeth in the longitudinal direction to have a more aesthetic sense.
  • the left side protrudes in the lateral direction, but the end is formed in the vertical direction with the end, and the right side protruding in the lateral direction, but the end is formed in the direction inclined to the side.
  • the vacuum coating layer is formed on the surface of the band manufactured as described above, it is attached to the left and right sides of the shoe upper surface or the front instep using a sewing or adhesive.
  • the vacuum coating method is to easily form a vacuum coating layer on the shoe decorative band or the outsole or midsole synthetic resin material using a sputtering method or an evaporating method.
  • the coating layer is composed of a base layer and a multilayer coating layer
  • the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn
  • the multilayer coating layer is a sputtering method Is formed by selecting two components of Ti, Zr, Ag, Au, Cu, Si, Sn. When three or more components of the multilayer coating layer are glossy, the gloss becomes dark and dark. And by selecting the two components to sequentially form a coating layer on the base layer, it is possible to form a more coating layer by repeating the multilayer coating layer operation.
  • the base layer component may be formed of Al
  • the multilayer coating layer may be formed by selecting Ti and Zr.
  • the multilayer coating layer forming operation may be repeated.
  • the base layer component may be formed of Al
  • the multilayer coating layer may be sequentially formed of Ti, Zr, Ti, or Zr.
  • C 2 H 2 or O 2 gas which is a reactive gas
  • N 2 or Ar gas which is an inert gas
  • the base layer reflects light, and the multilayer coating layer refracts the light, so that the coating layer has an aesthetic gloss as a whole.
  • the base coating layer is a layer formed of any one of Al, Cr, Cu, Ni, Si, W, and Sn
  • the multilayer coating layer is SiO 2, Nb 2 O. It is formed by selecting two components of 3 , Nb 2 O 5 , SiO, SiO 2 , Z 2 O, ZrO 2 , TiO, TiO 2 .
  • the gloss becomes dark and dark.
  • a multilayer coating layer having two components may be repeatedly formed on one base coating layer.
  • the base layer component may be formed of Al, and the multilayer coating layer may be formed by selecting SiO 2 and Nb 2 O 3 .
  • the multilayer coating layer forming operation may be repeated, for example, the base layer component may be formed of Al, and the multilayer coating layer may be sequentially formed of SiO 2, Nb 2 O 3, SiO 2, and Nb 2 O 3 . will be.
  • the vacuum coating apparatus used in the present invention can be efficiently implemented by mounting a resistive heating evaporation source (thermal evaporation source) in the center of the chamber in the conventional sputter vacuum coating method.
  • a linear ion source is installed on the chamber wall to perform pre-treatment and cleaning of samples using Ar.
  • the sputtering method used in the present invention refers to conventional sputtering technology.
  • sputtering refers to an electric field applied to a cathode in which an ar cation (positive ion) formed in a plasma state is mounted on a sputter module. It accelerates toward the target on the cathode and collides with it, causing the atoms that make up the target to pop out.
  • sputtering does not have a heating process, it is possible to deposit even a solid solution metal such as tungsten.
  • a solid solution metal such as tungsten.
  • the metal is heated to a high temperature to evaporate, in the case of an alloy, the vapor pressure of each of the component metals are different, causing problems.
  • sputtering can easily make a thin film not only metal but also inorganic materials such as quartz.
  • the sputtering apparatus is composed of a simple two-pole electrode and causes a glow discharge while flowing argon (Ar) gas.
  • Ar argon
  • Sputtering has a high adhesion strength between the thin film and the substrate because the velocity of the flying target atoms is about 100 times faster than the evaporation method.
  • the basic principle of the sputtering method and the resistance heating method is described in the registration number 20-0185068, which is a pre-applied application, the basic principle of the sputtering method and the resistance heating method.
  • the sputtered target is clamped to the cathode of the sputter module.
  • the evaporator is coated by melting and evaporating the coating material in a resistive heating or electron beam method, and the sputtering target sputters and scatters the coating material to deposit the deposit.
  • the resistance heating method uses a heating method using a current to flow through the resistor to generate Joule heat.
  • a direct method of heating a current directly through an object and an indirect method of transferring heat from a heating element to a heated object by radiative convection conduction can be adopted.
  • the plasma or glow discharge zone is formed by the spark of high pressure voltage supplied from the inert injection gas and the power supply device between the above discharge means.
  • the inner cylinder is rotated and the etching is performed while the discharge zone is applied to the coating portion of the coated body seated on the jig, and at the same time, the coating material melted by the sputtering target and the evaporator is scattered or sputtered. As a result, a multilayer thin film is formed on the deposit.
  • the vacuum deposition chamber is evacuated through the vacuum exhaust device, and when the inside of the chamber reaches a constant vacuum state, the jig is It is a common method that the deposition material in which the portion to be deposited to be deposited is melted or sputtered from the sputtering target or evaporator is uniformly deposited on the surface of the deposit.
  • the present invention has a remarkable effect that the coating layer of the metallic material formed on the decorative band for the shoe by vacuum coating method to improve the glossiness and improve the aesthetics by the refraction and reflection of light.
  • a decoration is mounted on an outer surface of a shoe outsole or a midsole, and the decoration is a polyester pad, and a vacuum coating layer is formed on a surface thereof. After the vacuum coating layer is formed on the polyester pad, it is cut and cut into a desired shape, or after cutting into a desired shape in advance, a vacuum coating layer may be formed.
  • the polyester pad coating layer is formed on the shoe outsole or the midsole outer surface is excellent in aesthetics.
  • the shoe outsole or midsole is made of synthetic resin such as rubber or PVC, and a decoration having a coating layer formed on a polyester pad on the outsole or midsole is attached by an adhesive or the like.
  • the present invention is the decoration is a coating layer formed on a microfiber cloth made of conventional polyester microfiber, the coating layer is formed by a vacuum coating method of the sputtering method or evaporating method.
  • the polyester pad or polyester microfiber cloth is a polyester microfiber cloth that can be easily purchased on the market and a detailed description thereof will be omitted.
  • the present invention is to be able to further form a water repellent coating layer by the conventional water repellent coating method on the coating layer is formed for the vacuum coating method, the conventional well-known water repellent coating method.
  • the water-repellent coating solution is a patent application No. 10-2004-018569 (name: coating composition for forming a non-tacky coating film, a preparation method thereof and a surface treatment method using the same), and a patent application agent It is preferable to use the water-repellent coating liquid described in 10-2004-018570 (name: composition for sol-gel coating, preparation method thereof and surface treatment method using the same), but other water-repellent coating liquid may also be used.
  • the coating method may be dipping, flowing, spraying, brushing, or the like.
  • the substrate coated with the coating solution is heat-treated at a temperature range of 50 to 250 degrees Celsius for 1 minute to 24 hours. Cool to room temperature after heat treatment.
  • the temperature increase rate and the cooling rate may be in the range of 0.5 to 500 degrees per minute.
  • it may proceed with a multi-step and various temperature change rates.
  • the present invention is attached to the shoe outsole or midsole, the decoration is formed by a vacuum coating method of a metallic coating layer on the pad of polyester material, the coating layer is glossy and aesthetics by the refraction and reflection of light There is a significant effect that can be improved.

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  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The present invention relates to a method of manufacturing a decoration for a shoe. A method of forming a vacuum-adhered coating layer for a decorative band for a shoe forms a coating layer on the outer surface of a decorative band for a shoe, wherein the coating layer is formed through a vacuum coating method. The present invention forms a coating layer on a decorative band for a shoe through a vacuum coating method so as to have the outstanding effects of providing a sheen for the coating layer and improving appearances. The present invention relates to a method of manufacturing a decoration for a shoe. The method of manufacturing a decoration for a shoe outsole or midsole, with respect to a method for manufacturing a decoration for a shoe in which a decoration is manufactured that is attached to the outer surface of a shoe outsole or midsole, forms a coating layer on a pad made of a polyester material as a decoration. The coating layer is formed through a vacuum coating method such as a sputtering method or an evaporating method. The present invention attaches a decoration to the outsole or midsole of a shoe, and the decoration has a coating layer of a metal material formed on a pad made of a polyester material through a vacuum coating method, so as to have the outstanding effects of providing a sheen for the coating layer and improving appearances through the refraction and reflection of light.

Description

신발의 장식물 제조방법How to make shoe decorations
본발명은 신발의 장식물 제조방법에 관한 것으로, 보다 상세하게는 신발에서 사람들 눈에 드러나기 쉬운 아웃솔의 외관부분에 진공코팅방법에 의한 코팅층을 형성하여 미관을 강조하는 신발의 장식물 제조방법에 관한 것이다.The present invention relates to a shoe manufacturing method of the shoe, and more particularly to a shoe manufacturing method of emphasizing aesthetics by forming a coating layer by the vacuum coating method on the outer portion of the shoe that is easy to be seen by people in the shoe.
또한, 본발명은 신발의 장식물 제조방법에 관한 것으로, 보다 상세하게는 신발에서 사람들 눈에 드러나기 쉬운 아웃솔 또는 미드솔의 외관부분에 장식물을 부착하되, 상기 장식물은 표면에 진공코팅방법에 의한 코팅층을 형성하여 미관을 강조하는 신발의 장식물 제조방법에 관한 것이다.In addition, the present invention relates to a method of manufacturing a decoration of the shoe, and more particularly, the decoration is attached to the exterior portion of the outsole or midsole that is easy to be seen by people in the shoe, the decoration forms a coating layer by a vacuum coating method on the surface The present invention relates to a manufacturing method of a shoe that emphasizes aesthetics.
신발에는 다양한 종류의 장식물이 부착되는데, 상기 장식물을 부착하는 방법에 있어서 종래기술들이 개발되어 왔고, 일례로서 공개특허공보 공개번호 특1998-083407호에는 진공방식 또는 반진공방식을 채택하며, 진공성형장치(A)와 밀폐성형장치(B)를 통해 가죽과 투명수지필름 또는 스폰지가 부착된 가죽 소재를 사용하여 함몰부에 가압공간이나 대기압공간이 형성된 장식물을 완성하거나, 함몰부에는 원래의 두께를 가지는 스폰지파트가 형성되며 그 가장자리에는 열압출된 스폰지파트가 형성된 장식물을 제조하는 방법을 통해 해결하는 것을 특징으로 하는 신발이나 가방등의 표면에 부착되는 장식물의 제조방법 및 이 제조방법에 의해 생산된 장식물이 공개되어 있다.Various kinds of ornaments are attached to the shoes, and conventional techniques have been developed in the method of attaching the ornaments. As an example, Patent Publication No. 1998-083407 adopts a vacuum method or a semi-vacuum method, and vacuum forming. The device (A) and the hermetic molding device (B) are made of leather and a transparent resin film or a leather material with a sponge to complete a decoration in which a pressurized or atmospheric pressure space is formed in the depression, or the original thickness is applied to the depression. The method of manufacturing a decoration attached to the surface of a shoe or a bag, characterized in that the solution is solved by a method of manufacturing a decorative member formed with a sponge extruded sponge parts are formed on the edge thereof is produced by the manufacturing method The ornament is open to the public.
공개실용신안공보 공개번호 실2000-0018205호에는 청구항 1 구두, 슬리퍼, 샌들 및 운동화와 같은 신발에 있어서, 신발의 발등부와 장식물이 닿는 접촉부분에 착탈수단을 구비하여서 착탈시킬 수 있도록 된 것을 특징으로 하며, 또한, 장식물은 캐릭터의 인쇄물 또는 그림 모양을 고주파열융착시킨 판형이거나, 각종 동·식물 또는 완구 등의 인형인 것을 특징으로 하며, 또한, 착탈수단은 스냅단추, 단추 또는 매직테이프인 것을 특징으로 하는 장식물 착탈형 신발이 공개되어 있다.Korean Utility Model Publication No. 2000-0018205 discloses a shoe, such as a shoe, slippers, sandals, and sneakers, wherein the shoe is provided with a detachable means at a contact portion where the instep of the shoe is in contact with a decoration. In addition, the decoration is characterized in that the plate-shaped or high-frequency heat fusion of the print or figure of the character, or a doll, such as a variety of animals, plants or toys, and the removable means is a snap button, a button or a magic tape Decorative removable shoes are featured.
또한, 등록실용신안공보 등록번호 20-0341093호에는 결합수단에 의해 신발 측면에 착탈가능하게 부착되는 장식물을 특징으로 하는 신발용 장식물이 공개되어 있다.In addition, Korean Utility Model Registration No. 20-0341093 discloses a shoe ornament characterized in that the ornament detachably attached to the side of the shoe by the coupling means.
한편, 상기 장식물로서 합성수지재질을 밴드(띠)모양으로 사출형성하여 신발표면에 접착제로 부착하거나 봉제하여 부착하는 방법이 있었다.On the other hand, as a decoration, there was a method of injection molding a synthetic resin material into a band shape to attach or sew to the shoe surface with an adhesive.
그러나 상기 신발 장식용 밴드의 표면은 미관을 위하여 재료에 안료를 섞어 제작하는데 이 경우 색상이 단조롭고 혼탁하며, 코팅을 하더라도 코팅상태가 양호하지 않고 미감이 떨어지는 단점이 있었다.However, the surface of the shoe decorative band is produced by mixing the pigment in the material for aesthetics in this case, the color is monotonous and turbid, even if the coating has a disadvantage that the coating state is not good and the aesthetics are poor.
등록특허공보 등록번호 10-0356717호에 종래기술로 기재된 바와 같이, 종래 신발용 아웃솔은 신발의 하부를 구성하는 구성부재로서, 신발을 착용시 발의 하부를 주로 보호하기 위한 수단으로서 그 두께가 통상 미드솔이나 인솔보다는 두껍게 제조되고, 이러한 아웃솔은 통상 신발의 하부를 지지하는 주요한 구성부재중 하나이다.As described in the prior art in Korean Patent Publication No. 10-0356717, the conventional shoe outsole is a constituent member constituting the lower part of the shoe, and the thickness of the midsole is usually used as a means for mainly protecting the lower part of the foot when wearing shoes. Manufactured thicker than insoles, these outsoles are usually one of the major components supporting the underside of a shoe.
그리고 상기 등록특허공보 등록번호 10-0356717호는 그 기술적 요지로, 청구항 1에 신발용 아웃솔(1)에 있어서; 상기 아웃솔(1)에는 요입실(2)을 형성하여 이의 상부에서 쿳션커버(3)로 밀폐시켜 에어챔버(4)를 형성하되, 상기 에어챔버(4) 내에는 개폐수단(7)에 의해 착탈가능한 항균방향제(6)를 내입할 수 있도록 항균방향제내장실(5)을 내장벽(12)에 의하여 형성하고; 상기 항균방향제내장실(5)의 상부에는 공기유입공(13)을 형성하여 내장벽(12)에 의해 형성되는 공기유도홈(15)과 공기배출공(14)을 통하여 유입된 공기가 쿳션커버(3)의 전측에 형성된 하나 이상의 배출공(17)상으로 배출될 수 있도록 하며; 상기 요입실(2)에는 다수개의 보조요입실(11)이 형성되고, 쿳션커버(3)에는 다수개의 완충돌기(16)가 형성된 것을 특징으로 하는 신발용 아웃솔이 공개되어 있다.And the Patent Publication No. 10-0356717 is a technical gist of the shoe outsole (1) in claim 1; The outsole 1 is formed with a concave chamber 2 and sealed with a cushion cover 3 at the upper portion thereof to form an air chamber 4, which is detachable by an opening and closing means 7 in the air chamber 4. An antibacterial air freshener interior room 5 is formed by the built-in wall 12 so that the antimicrobial air freshener 6 can be incorporated therein; An air inflow hole 13 is formed in the upper portion of the antibacterial air freshener interior chamber 5 so that air introduced through the air induction groove 15 and the air discharge hole 14 formed by the interior wall 12 is cushioned. To be discharged onto at least one discharge hole 17 formed at the front side of (3); A plurality of auxiliary inlet chamber 11 is formed in the urine inlet chamber 2, and the cushion cover 3 is a shoe outsole is characterized in that a plurality of buffer projections 16 are formed.
또한, 공개특허공보 공개번호 10-2011-0056806호에는 신발용 아웃솔을 전체 길이에 대하여 4:6의 길이 비율을 갖도록 연질부와 경질부로 구분 형성하고, 상기의 연질부는 아웃솔의 앞꿈치에 해당되고 상기의 경질부는 아웃솔의 뒤꿈치에 해당되어 이들 연질부와 경질부는 가압 성형에 의한 접합을 통해 일체화되게 구성하되, 상기의 연질부는, 고무원료 100 : 촉진제 2 : 활성제 5 : 스타린산 10 : 카본블랙 30 : 흑연 20 : 윤활유 1의 중량 비율로 혼합 성형되어 이루어지고, 상기의 경질부는, 고무원료 100 : 촉진제 2 : 활성제 5 : 스타린산 10 : 카본블랙 50 : 윤활유 1의 중량 비율로 혼합 성형되어 이루어짐을 특징으로 하는 보행 편리성이 향상되게 한 신발용 아웃솔이 공개되어 있다.In addition, Korean Patent Laid-Open Publication No. 10-2011-0056806 discloses a shoe outsole divided into a soft part and a hard part to have a length ratio of 4: 6 with respect to the total length, and the soft part corresponds to the front heel of the outsole. The hard part of the outsole corresponds to the heel of the outsole, and the soft part and the hard part are configured to be integrated through the joining by pressure molding, wherein the soft part comprises: rubber raw material 100: accelerator 2: activator 5: staric acid 10: carbon black 30: Graphite 20 is mixed and molded at a weight ratio of lubricant 1, wherein the hard part is mixed and molded at a weight ratio of rubber material 100: accelerator 2: activator 5: stannic acid 10: carbon black 50: lubricant 1 The shoe outsole for improving the convenience of walking is disclosed.
그러나 상기 아웃솔표면은 재료에 안료를 섞어 제작할 경우 색상이 단조롭고 혼탁하며, 코팅을 하더라도 코팅상태가 양호하지 않고 미감이 떨어지는 단점이 있었다.However, the outsole surface has a disadvantage in that the color is monotonous and turbid when the pigment is mixed with the material, and the coating state is not good and the aesthetics are poor even when coated.
등록특허공보 등록번호 10-0828908호에 배경기술로 기재된 바와 같이, 통상의 신발(5)은 갑피(1), 깔창(2), 미드솔(3) 및 아웃솔(4)로 구성된다.As described in the background art in Korean Patent Publication No. 10-0828908, a conventional shoe 5 is composed of an upper 1, an insole 2, a midsole 3 and an outsole 4.
그러나, 모든 신발(5)이 미드솔(3)과 아웃솔(4)을 구비하는 것은 아니며, 각 신발(5)의 용도와 기능에 따라 어느 부위만 있을 수도 있다. 즉, 아웃솔(4)의 상부에 바로 갑피(1)가 결합되어 신발(5)이 제조되거나, 또는 아웃솔(4)없이 미드솔(3)에 바로 갑피(1)가 결합되어 신발(5)이 형성되기도 하는데, 이는 어디까지나 신발(1)의 기능 및 용도에 따라 다르게 되는 것이다.However, not all shoes 5 are provided with the midsole 3 and the outsole 4, and may have only any part depending on the use and function of each shoe 5. That is, the upper 1 is directly coupled to the upper portion of the outsole 4 to manufacture the shoe 5, or the upper 1 is directly coupled to the midsole 3 without the outsole 4 to form the shoe 5. It may be, which will vary depending on the function and use of the shoe (1).
그리고, 상기 밑창을 구성하는 미드솔(3)과 아웃솔(4) 및 갑피(1)의 구조 및 재질에 따라 다양한 종류의 신발(5)이 제작되는데, 일예를 들어, 조깅화로 사용되기 위해서는 상기 미드솔(3)과 아웃솔(4) 및 갑피(1)를 이루는 재질은 충격흡수력이 있으면서 가벼운 재료를 사용하여 제작하게 되고, 또한, 내마모성과 미끄럼 방지를 위한 기능이 요구되는 신발(5)에서는 상기 미드솔(3)의 저면에 부착되는 아웃솔(4)은 고무재질을 이용하여 신발(5)을 제작하게 되는 것이다. 이와 같이, 신발(1)에서는 상기 밑창을 이루는 미드솔(3)과 아웃솔(4)의 구조, 형상 및 재질을 어떻게 구성하느냐에 따라 신발(5)의 종류 및 기능뿐만 아니라 신발(5)의 가격이 결정되게 된다.And, according to the structure and material of the midsole (3) and the outsole (4) and upper (1) constituting the sole, various kinds of shoes (5) are produced, for example, in order to be used as jogging shoes 3) and the outsole (4) and the upper (1) is made of a material that is shock-absorbing and lightweight material, and in addition to the midsole (3) in the shoe (5) that requires a function for wear resistance and anti-slip Outsole (4) attached to the bottom of the) is to produce a shoe (5) using a rubber material. As described above, in the shoe 1, the price and price of the shoe 5 as well as the type and function of the shoe 5 are determined according to how the structures, shapes, and materials of the midsole 3 and the outsole 4 forming the sole are configured. Will be.
상기와 같이 밑창을 이루는 아웃솔(4)과 미드솔(3)은 대개 따로 따로 제작하여 미드솔(3)의 저면에 아웃솔(4)이 부착되도록 하여 제작된다. 이는 밑창을 이루는 아웃솔과 중창을 이루는 미드솔이 신발에서 수행하는 역활이 다르기 때문이다.The outsole 4 and the midsole 3 forming the sole as described above are usually manufactured separately so that the outsole 4 is attached to the bottom of the midsole 3. This is because the soles of the soles and the midsoles of the midsole play different roles in the shoe.
즉, 아웃솔(4)은 착지시 미끄럼방지 및 장시간 사용에 따른 마모의 방지 등이 그 주 기능이므로 이러한 기능을 수행할수 있도록 그 재질이 구성되므로 주로 고무 또는 미발포 폴리우레탄을 재료로 이용하게 된다. 이에 반하여 미드솔(3)은 충격흡수 및 신발무게의 경량화가 주목적이므로 비교적 가벼운 재질의 에틸렌비닐아세테이트 또는 발포 폴리우레탄 재질을 사용하게 된다.That is, the outsole (4) is mainly made of rubber or non-foamed polyurethane because the material is configured to perform such a function because the main function is to prevent the slip and landing wear due to long time use. On the contrary, the midsole 3 is made of ethylene vinyl acetate or a foamed polyurethane material of a relatively light material because the main purpose is to absorb shock and lighten the weight of the shoe.
한편, 상기 등록번호 10-0828908호에는 상기 미드솔에 대하여, 갑피(1), 깔창(2), 미드솔(3) 및 아웃솔(4)로 구성된 통상의 신발(5)에 있어서, 상기 미드솔은, 경질의 나일론 사출피스층과; 상기 나일론 사출피스층의 외각을 감싸는 폴리 우레탄층과; 상기 폴리 우레탄층의 외각을 감싸는 에바(EVA)층으로 이루어짐을 특징으로 하는 3중 구조물의 미드솔 구조를 갖는 건강신발리 공개되어 있다.On the other hand, in the registration number 10-0828908, the midsole, in the ordinary shoes (5) composed of the upper (1), the insole (2), the midsole (3) and the outsole (4) with respect to the midsole. Nylon injection piece layer of; A polyurethane layer surrounding the outer shell of the nylon injection piece layer; Health shoes Bali having a midsole structure of a triple structure is characterized by consisting of an EVA (EVA) layer surrounding the outer shell of the polyurethane layer is disclosed.
또한, 공개특허공보 공개번호 10-2013-0096660호에는 신발의 미드솔 제조 방법에 있어서, 상부미드솔 시트, 하부미드솔 시트 및 삽입부재를 준비하는 단계; 상기 상부미드솔 시트와 상기 하부미드솔 시트가 상호 접촉하는 대응 표면 사이에 상기 삽입부재가 수용될 수 있도록 상기 상부미드솔 시트와 상기 하부미드솔 시트 중 적어도 어느 하나의 표면에 연삭휠을 사용하여 수용그루브를 연삭 형성하는 단계; 및 상기 수용그루브에 상기 삽입부재를 삽입하고 상기 상부미드솔 시트 및 상기 하부미드솔 시트를 적층 접합하여 미드솔을 얻는 단계를 포함하는 것을 특징으로 하는 신발의 미드솔 제조 방법이 공개되어 있다. In addition, Korean Patent Laid-Open Publication No. 10-2013-0096660 discloses a method for manufacturing a shoe midsole, comprising: preparing an upper midsole sheet, a lower midsole sheet, and an insertion member; Grind the receiving groove by using a grinding wheel on at least one surface of the upper midsole sheet and the lower midsole sheet so that the insertion member is received between the corresponding surface where the upper midsole sheet and the lower midsole sheet are in contact with each other. Forming; And inserting the insertion member into the receiving groove and laminating the upper midsole sheet and the lower midsole sheet to obtain a midsole.
그러나 상기 종래의 미드솔 표면은 재료에 안료를 섞어 제작할 경우 색상이 단조롭고 혼탁하며, 코팅을 하더라도 코팅상태가 양호하지 않고 미감이 떨어지는 단점이 있었다.However, the conventional midsole surface has a disadvantage in that the color is monotonous and turbid when the pigment is mixed with the material, and the coating state is not good and the aesthetics are poor even when coated.
따라서 본 발명은 상기와 같은 문제점을 해결하고자 안출된 것으로서, 신발 장식용 밴드에 코팅층을 진공코팅방법에 의해 형성하여 코팅층이 광택이 나고 심미감을 향상시킬 수 있는 신발의 장식물 제조방법을 제공하고자 하는 것이다.Accordingly, the present invention has been made to solve the above problems, and to provide a shoe manufacturing method of the shoe layer to improve the gloss and aesthetics by forming a coating layer on the shoe decorative band by a vacuum coating method.
또한, 본 발명은 상기와 같은 문제점을 해결하고자 안출된 것으로서, 신발 아웃솔 또는 미드솔에 장식물이 부착되되, 상기 장식물은 폴리에스테르 재질의 패드위에 금속재질의 코팅층을 진공코팅방법에 의해 형성되어 빛의 굴절 및 반사에 의해 코팅층이 광택이 나고 심미감을 향상시킬 수 있는 신발의 장식물 제조방법을 제공하고자 하는 것이다.In addition, the present invention has been made to solve the above problems, the decoration is attached to the shoe outsole or midsole, the decoration is formed by a vacuum coating method of a metallic coating layer on the pad of polyester material to refraction of light And it is to provide a method of manufacturing a decoration of the shoe that can be polished by the reflection and improve the aesthetics.
본발명은 신발의 장식물 제조방법에 관한 것으로, 신발 장식용 밴드의 진공코팅층 형성방법은, 신발 장식용 밴드 외부면에 코팅층을 형성하되, 상기 코팅층은 진공코팅방법에 의해 형성되는 것을 특징으로 한다.The present invention relates to a shoe manufacturing method of the shoe, the method of forming a vacuum coating layer of the shoe decorative band, the coating layer is formed on the outer surface of the shoe decorative band, characterized in that the coating layer is formed by a vacuum coating method.
본발명은 신발의 장식물 제조방법에 관한 것으로, 신발 아웃솔 또는 미드솔 외부면에 부착되는 장식물을 제조하는 신발의 장식물 제조방법에 있어서, 상기 장식물은 폴리에스테르 재질 패드에 코팅층이 형성된 것이며, 상기 코팅층은 스패터링방법 또는 이베퍼라이팅방법의 진공코팅방법에 의해 형성되는 것을 특징으로 한다.The present invention relates to a method of manufacturing a shoe ornament, in the shoe manufacturing method of the shoe manufacturing a decoration that is attached to the outer surface of the shoe outsole or midsole, the decoration is a coating layer formed on a polyester pad, the coating layer is spatter It is characterized by being formed by the vacuum coating method of the turing method or the evaporating method.
따라서 본발명은 신발 장식용 밴드에 코팅층을 진공코팅방법에 의해 형성하여 코팅층이 광택이 나고 심미감을 향상시킬 수 있는 현저한 효과가 있다.Therefore, the present invention has a remarkable effect that the coating layer is formed on the decorative band of the shoe by a vacuum coating method so that the coating layer is glossy and improves aesthetics.
또한, 본발명은 신발 아웃솔 또는 미드솔에 장식물이 부착되되, 상기 장식물은 폴리에스테르 재질의 패드위에 금속재질의 코팅층을 진공코팅방법에 의해 형성되어 빛의 굴절 및 반사에 의해 코팅층이 광택이 나고 심미감을 향상시킬 수 있는 현저한 효과가 있다.In addition, the present invention is a decoration attached to the shoe outsole or midsole, the decoration is formed by coating a metallic coating layer on the pad of the polyester material by vacuum coating method, the coating layer is glossy and aesthetical by refraction and reflection of light There is a significant effect that can be improved.
도 1은 본발명 신발 장식용 밴드 사시도1 is a perspective view of the decorative band for shoes according to the present invention
도 2는 본발명에 사용되는 진공코팅장치 배치도2 is a layout view of a vacuum coating apparatus used in the present invention
도 3은 본발명에 사용되는 Sputter module, Linear ion source 및 Thermal evaporation source가 설치된 진공코팅장치 내부개략도3 is a schematic diagram of a vacuum coating apparatus installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention.
도 4는 본발명에 사용되는 Sputte rmodule, Linear ion source 및 Thermal evaporation source가 설치된 진공코팅장치 절개개략도Figure 4 is a schematic cutaway view of the vacuum coating apparatus installed Sputte rmodule, Linear ion source and Thermal evaporation source used in the present invention
도 5는 본발명에 사용되는 Sputter module, Linear ion source 및 Thermal evaporation source가 설치된 진공코팅장치 분해개략도5 is an exploded schematic view of a vacuum coating apparatus installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention.
도 6은 본발명에 사용되는 Sputter module, Linear ion source 및 Thermal evaporation source가 설치된 진공코팅장치 평면개략도Figure 6 is a schematic plan view of a vacuum coating apparatus installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention
도 7은 도 6의 부분확대도7 is an enlarged partial view of FIG. 6.
도 8은 종래 신발 아웃솔 사시도8 is a perspective view of a conventional shoe outsole
도 9는 본발명 신발의 장식물 제조방법에 의해 제조된 폴리에스테르 재질 장식물 패드Figure 9 is a polyester material decorative pads produced by the method for manufacturing a decoration of the present invention shoes
도 10은 본발명 신발의 장식물 제조방법에 의해 제조된 폴리에스테르 재질 극세사 천10 is a polyester material microfiber cloth prepared by the method for manufacturing a decoration of the present invention shoes
도 11은 종래 신발 사시도11 is a perspective view of a conventional shoe
도 12는 본발명에 사용되는 미드솔 측면사진12 is a side view of the midsole used in the present invention
도 13은 본발명에 사용되는 미드솔 평면사진Figure 13 is a plan view of the midsole used in the present invention
<도면의 주요 부분에 대한 부호의 설명><Explanation of symbols for the main parts of the drawings>
400 : 챔버 400: chamber
500 : 선형 이온 소스(Linear ion source) 500: linear ion source
100 : 스퍼터 110 : 저항가열식 증발원100: sputter 110: resistance heating type evaporation source
본발명은 신발의 장식물 제조방법에 관한 것으로, 신발 장식용 밴드의 진공코팅층 형성방법은, 신발 장식용 밴드 외부면에 코팅층을 형성하되, 상기 코팅층은 스패터링방법 또는 이베퍼라이팅방법의 진공코팅방법에 의해 형성되는 것을 특징으로 한다.The present invention relates to a method of manufacturing a shoe ornament, the method of forming a vacuum coating layer of the shoe decorative band, forming a coating layer on the outer surface of the shoe decorative band, the coating layer by a vacuum coating method of the sputtering method or evaporating method It is characterized by being formed.
또한, 상기 코팅층은 베이스층과 멀티레이어코팅층으로 이루어지되, 상기 베이스코팅층은 Al, Cr, Cu, Ni, Si, W, Sn중 어느 하나의 성분으로 형성된 층이며, 상기 멀티레이어코팅층은 스패터링방법의 경우에는 Ti, Zr, Ag, Au, Cu, Si, Sn중 두 개 이상의 성분을 짝수로 선택하여 형성되는 것을 특징으로 한다.In addition, the coating layer is made of a base layer and a multilayer coating layer, the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn, the multilayer coating layer is a sputtering method In the case of Ti, Zr, Ag, Au, Cu, Si, it is characterized in that formed by selecting two or more components of the even number.
또한, 상기 스패터링방법의 경우에는 반응성가스(reactive gas)인 C2H2 또는 O2를 진공챔버 내부에 주입하거나, 불활성가스인 N2 또는 Ar가스를 진공챔버 내부에 주입하는 것을 특징으로 한다.In addition, in the case of the sputtering method C 2 H 2 or a reactive gas (reactive gas) or O 2 is injected into the vacuum chamber or N 2 or Ar gas, which is an inert gas, is injected into the vacuum chamber.
또한, 상기 코팅층은 베이스층과 멀티레이어코팅층으로 이루어지되, 상기 베이스코팅층은 Al, Cr, Cu, Ni, Si, W, Sn중 어느 하나의 성분으로 형성된 층이며, 상기 멀티레이어코팅층은 이베퍼라이팅방법의 경우에는 SiO2, Nb2O3, Nb2O5, SiO, SiO2, Z2O, ZrO2, TiO, TiO2중 두 개 이상의 성분을 짝수단위로 선택하여 형성되는 것을 특징으로 한다.In addition, the coating layer is made of a base layer and a multilayer coating layer, the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn, the multilayer coating layer is evaporating In the case of the method, it is formed by selecting two or more components of SiO 2, Nb 2 O 3 , Nb 2 O 5 , SiO, SiO 2 , Z 2 O, ZrO 2 , TiO, TiO 2 in even units. .
본발명은 신발 아웃솔 또는 미드솔 외부면에 부착되는 장식물을 제조하는 신발의 장식물 제조방법에 있어서, 상기 장식물은 폴리에스테르 재질 패드 위에 코팅층이 형성된 것이며, 상기 코팅층은 스패터링방법 또는 이베퍼라이팅방법의 진공코팅방법에 의해 형성되는 것을 특징으로 한다.The present invention relates to a shoe ornament manufacturing method of manufacturing a shoe that is attached to the outer surface of the shoe sole or midsole, the decoration is a coating layer formed on a polyester pad, the coating layer is a sputtering method or vacuum evaporation method It is characterized by being formed by a coating method.
또한, 상기 코팅층은 베이스코팅층과 멀티레이어코팅층으로 이루어지되, 상기 베이스코팅층은 Al, Cr, Cu, Ni, Si, W, Sn중 어느 하나의 성분으로 형성된 층이며, 상기 멀티레이어코팅층은 스패터링방법의 경우에는 Ti, Zr, Ag, Au, Cu, Si, Sn중 두 개 성분을 선택하여 형성되는 것을 특징으로 한다.In addition, the coating layer is made of a base coating layer and a multilayer coating layer, the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn, the multilayer coating layer is a sputtering method In the case of Ti, Zr, Ag, Au, Cu, Si, It is characterized in that formed by selecting two components of Sn.
또한, 상기 스패터링방법의 경우에는 반응성가스(reactive gas)로서 C2H2, N2, O2, 또는 Ar가스를 진공챔버내부에 주입하는 것을 특징으로 한다.In the case of the sputtering method, C 2 H 2 , N 2 , O 2 , or Ar gas is injected into the vacuum chamber as a reactive gas.
또한, 상기 코팅층은 베이스코팅층과 멀티레이어코팅층으로 이루어지되, 상기 베이스코팅층은 Al, Cr, Cu, Ni, Si, W, Sn중 어느 하나의 성분으로 형성된 층이며, 상기 멀티레이어코팅층은 이베퍼라이팅방법의 경우에는 SiO2, Nb2O3, Nb2O5, SiO, SiO2, Z2O, ZrO2, TiO, TiO2중 두 개 성분을 선택하여 형성되는 것을 특징으로 한다.In addition, the coating layer is made of a base coating layer and a multilayer coating layer, the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn, the multilayer coating layer is evaporating The method is characterized in that formed by selecting two components of SiO 2, Nb 2 O 3 , Nb 2 O 5 , SiO, SiO 2 , Z 2 O, ZrO 2 , TiO, TiO 2 .
또한, 상기 장식물은 폴리에스테르 재질 극세사로 만들어진 극세사 천에 코팅층이 형성된 것이며, 상기 코팅층은 스패터링방법 또는 이베퍼라이팅방법의 진공코팅방법에 의해 형성되는 것을 특징으로 한다.In addition, the decoration is a coating layer is formed on a microfiber cloth made of polyester microfiber, the coating layer is characterized in that formed by the vacuum coating method of the sputtering method or evaporator writing method.
본발명을 첨부도면에 의해 상세히 설명하면 다음과 같다. 도 1은 본발명 신발 장식용 밴드 사시도, 도 2는 본발명에 사용되는 진공코팅장치 배치도, 도 3은 본발명에 사용되는 Sputter module, Linear ion source 및 Thermal evaporation source가 설치된 진공코팅장치 내부개략도, 도 4는 본발명에 사용되는 Sputte rmodule, Linear ion source 및 Thermal evaporation source가 설치된 진공코팅장치 절개개략도, 도 5는 본발명에 사용되는 Sputter module, Linear ion source 및 Thermal evaporation source가 설치된 진공코팅장치 분해개략도, 도 6은 본발명에 사용되는 Sputter module, Linear ion source 및 Thermal evaporation source가 설치된 진공코팅장치 평면개략도, 도 7은 도 6의 부분확대도, 도 8은 종래 신발 아웃솔 사시도, 도 9는 본발명 신발의 장식물 제조방법에 의해 제조된 폴리에스테르 재질 장식물 패드, 도 10은 본발명 신발의 장식물 제조방법에 의해 제조된 폴리에스테르 재질 극세사 천, 도 11은 종래 신발 사시도, 도 12는 본발명에 사용되는 미드솔 측면사진, 도 13은 본발명에 사용되는 미드솔 평면사진이다.The present invention is described in detail by the accompanying drawings as follows. 1 is a perspective view of the decorative band for shoes according to the present invention, FIG. 2 is a layout view of a vacuum coating device used in the present invention, and FIG. 3 is a schematic diagram illustrating a vacuum coating device installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention. 4 is a schematic cutaway view of a vacuum coating apparatus installed with a sputte rmodule, a linear ion source and a thermal evaporation source used in the present invention, and FIG. 5 is an exploded schematic view of a vacuum coating apparatus installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention. 6 is a schematic plan view of a vacuum coating apparatus installed with a sputter module, a linear ion source and a thermal evaporation source used in the present invention, FIG. 7 is a partially enlarged view of FIG. 6, FIG. 8 is a perspective view of a conventional shoe outsole, and FIG. 9 is the present invention. Decorative pad made of polyester material produced by the shoe manufacturing method of the shoe, Figure 10 is a polyester produced by the manufacturing method of the shoe of the present invention Terex microfiber cloth, Figure 11 is a conventional shoe perspective view, Figure 12 is a midsole side photograph used in the present invention, Figure 13 is a midsole planar photograph used in the present invention.
본발명은 신발 장식용 밴드 외부면에 진공코팅층을 형성하는 것이다. 상기 코팅층은 신발 장식용 밴드 외부면에 형성되므로 심미감이 뛰어나다. 상기 신발 장식용 밴드는 PP, PE등의 합성수지로 사출제작되며, 상기 사출성형된 제품 표면에 코팅층이 진공코팅방법에 의해 형성되는 것이다.The present invention is to form a vacuum coating layer on the outer surface of the decorative band for shoes. The coating layer is formed on the outer surface of the decorative band for shoes is excellent in aesthetics. The shoe decorative band is injection-molded with synthetic resins such as PP and PE, and a coating layer is formed on the surface of the injection-molded product by a vacuum coating method.
본발명의 상기 신발 장식용 밴드는 길이 4∼6cm이며, 폭은 1cm 정도인 밴드이며, PP, PE등의 합성수지로 사출제작되어 유연성이 있다. 그리고 상기 밴드의 좌우측면은 경사가 지게 하여 심미감을 형성한다. 그리고 상기 신발 장식용 밴드의 상하에는 삼각톱니를 다수개 길이방향으로 형성하여 심미감을 더욱 갖게 한다. 한편 좌측면은 네모진 돌기를 측면방향으로 돌출형성하되 끝단이 측면과 수직방향으로 형성하고, 우측에도 네모진 돌기를 측면방향으로 돌출형성하되 끝단이 측면과 경사진 방향으로 형성한다.The shoe decorative band of the present invention is a length of about 4 ~ 6cm, a width of about 1cm band, injection-molded with synthetic resin, such as PP, PE, there is flexibility. The left and right side surfaces of the band are inclined to form an aesthetic sense. And the upper and lower sides of the decorative band for shoes to form a plurality of triangular teeth in the longitudinal direction to have a more aesthetic sense. On the other hand, the left side protrudes in the lateral direction, but the end is formed in the vertical direction with the end, and the right side protruding in the lateral direction, but the end is formed in the direction inclined to the side.
상기와 같이 제조되는 밴드의 표면에 진공코팅층을 형성한 후, 봉제나 접착제를 이용하여 신발 갑피 표면 좌우측이나 전방 발등부에 부착한다.After the vacuum coating layer is formed on the surface of the band manufactured as described above, it is attached to the left and right sides of the shoe upper surface or the front instep using a sewing or adhesive.
상기 진공코팅방법은 스패터링방법 또는 이베퍼라이팅방법을 사용하여 신발 장식용 밴드 또는 아웃솔 또는 미드솔 합성수지재질위에 용이하게 진공코팅층을 형성하는 것이다.The vacuum coating method is to easily form a vacuum coating layer on the shoe decorative band or the outsole or midsole synthetic resin material using a sputtering method or an evaporating method.
상기 코팅층은 베이스층과 멀티레이어코팅층으로 이루어지되, 상기 베이스코팅층은 Al, Cr, Cu, Ni, Si, W, Sn중 어느 하나의 성분으로 형성된 층이며, 상기 멀티레이어코팅층은 스패터링방법의 경우에는 Ti, Zr, Ag, Au, Cu, Si, Sn중 두 개 성분을 선택하여 형성되는 것이다. 멀티레이어코팅층의 성분이 3개이상 되면 광택이 혼탁하고 어둡게되므로 2개 성분으로 한다. 그리고 두 개 성분을 선택하여 순차적으로 베이스층위에 코팅층을 형성하되, 멀티레이어코팅층 작업을 반복하여 보다 많은 코팅층을 형성할 수 있다. 곧, 일례로서 베이스층 성분을 Al으로 형성하고 멀티레이어코팅층을 Ti, Zr을 선택하여 형성할 수 있다. 그리고 멀티레이어코팅층 형성작업을 반복할 수 있는 것으로, 예를 들어 베이스층 성분을 Al으로 형성하고 멀티레이어코팅층을 Ti, Zr, Ti, Zr로 순차적으로 형성할 수 있다. The coating layer is composed of a base layer and a multilayer coating layer, the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn, the multilayer coating layer is a sputtering method Is formed by selecting two components of Ti, Zr, Ag, Au, Cu, Si, Sn. When three or more components of the multilayer coating layer are glossy, the gloss becomes dark and dark. And by selecting the two components to sequentially form a coating layer on the base layer, it is possible to form a more coating layer by repeating the multilayer coating layer operation. In other words, as an example, the base layer component may be formed of Al, and the multilayer coating layer may be formed by selecting Ti and Zr. In addition, the multilayer coating layer forming operation may be repeated. For example, the base layer component may be formed of Al, and the multilayer coating layer may be sequentially formed of Ti, Zr, Ti, or Zr.
*또한, 상기 스패터링방법의 경우에는 반응성가스(reactive gas)인C2H2 또는 O2 가스를 진공챔버내부에 주입하거나, 불활성가스인 N2 또는 Ar 가스를 진공챔버내부에 주입하게 된다.In addition, in the case of the sputtering method, C 2 H 2 or O 2 gas, which is a reactive gas, is injected into the vacuum chamber, or N 2 or Ar gas, which is an inert gas, is injected into the vacuum chamber.
상기와 같이 형성되는 코팅층중 베이스층은 빛을 반사하게 되고, 멀티레이어코팅층은 빛을 굴절하게 되어, 코팅층이 전체적으로 심미감 있는 광택이 나는 것이다.Among the coating layers formed as described above, the base layer reflects light, and the multilayer coating layer refracts the light, so that the coating layer has an aesthetic gloss as a whole.
한편, 본발명은 이베퍼라이팅방법의 경우에는 상기 베이스코팅층은 Al, Cr, Cu, Ni, Si, W, Sn중 어느 하나의 성분으로 형성된 층이며, 상기 멀티레이어코팅층은 SiO2, Nb2O3, Nb2O5, SiO, SiO2, Z2O, ZrO2, TiO, TiO2중 두 개 성분을 선택하여 형성되는 것이다. 멀티레이어코팅층의 성분이 3개이상 되면 광택이 혼탁하고 어둡게되므로 2개 성분으로 한다. 그리고 스패터링방법과 마찬가지로 하나의 베이스코팅층 위에 두 개 성분을 가진 멀티레이어코팅층을 반복적으로 형성할 수 있다. 곧, 일례로서베이스층 성분을 Al으로 형성하고 멀티레이어코팅층을 SiO2, Nb2O3을 선택하여 형성할 수 있다. 그리고 멀티레이어코팅층 형성작업을 반복할 수 있는 것으로, 예를 들어 베이스층 성분을 Al으로 형성하고 멀티레이어코팅층을 SiO2, Nb2O3, SiO2, Nb2O3로 순차적으로 형성할 수 있는 것이다.In the present invention, in the case of the evaporating method, the base coating layer is a layer formed of any one of Al, Cr, Cu, Ni, Si, W, and Sn, and the multilayer coating layer is SiO 2, Nb 2 O. It is formed by selecting two components of 3 , Nb 2 O 5 , SiO, SiO 2 , Z 2 O, ZrO 2 , TiO, TiO 2 . When three or more components of the multilayer coating layer are glossy, the gloss becomes dark and dark. As in the sputtering method, a multilayer coating layer having two components may be repeatedly formed on one base coating layer. That is, as an example, the base layer component may be formed of Al, and the multilayer coating layer may be formed by selecting SiO 2 and Nb 2 O 3 . In addition, the multilayer coating layer forming operation may be repeated, for example, the base layer component may be formed of Al, and the multilayer coating layer may be sequentially formed of SiO 2, Nb 2 O 3, SiO 2, and Nb 2 O 3 . will be.
한편, 본 발명에서 사용되는 진공코팅장치는 기존의 sputter 진공코팅 방식에 chamber 중앙에 저항가열식 증발원(thermal evaporation source)을 장착함으로써 증착을 효율적으로 구현 할 수 있다.On the other hand, the vacuum coating apparatus used in the present invention can be efficiently implemented by mounting a resistive heating evaporation source (thermal evaporation source) in the center of the chamber in the conventional sputter vacuum coating method.
Linear ion source는 chamber 벽면에 설치하여 Ar을 이용한 sample의 전처리 (pre - treatment) 공정과 클리닝 공정을 수행한다.      A linear ion source is installed on the chamber wall to perform pre-treatment and cleaning of samples using Ar.
그리고 본 발명에서 사용되는 스퍼터링 방법은 관용의 스퍼터링(sputtering) 기술을 말하는 것으로, 구체적으로 설명하면 스퍼터링(sputtering)이란 plasma 상태에서 형성된 Ar 양이온(positive ion)이 sputter module에 장착된 cathode에 인가된 전기장에 의해 cathode 위에 놓여있는 target 쪽으로 가속되어 target과 충돌함으로써 target을 구성하고 있는 원자가 튀어나오는 현상이다.     In addition, the sputtering method used in the present invention refers to conventional sputtering technology. Specifically, sputtering refers to an electric field applied to a cathode in which an ar cation (positive ion) formed in a plasma state is mounted on a sputter module. It accelerates toward the target on the cathode and collides with it, causing the atoms that make up the target to pop out.
이 스퍼터링은 가열과정이 없기 때문에 텅스텐과 같은 고용점 금속이라도 증착이 가능하다. 일반적인 진공증착에서는 금속을 고온으로 가열하여 증발시키기 때문에 합금인 경우 그 성분 금속 각각의 증기압이 서로 달라 문제가 생긴다. 그러나 스퍼터링은 금속뿐만 아니라 석영 등 무기물이라도 박막을 용이하게 만들 수 있다.     Since sputtering does not have a heating process, it is possible to deposit even a solid solution metal such as tungsten. In general vacuum deposition, since the metal is heated to a high temperature to evaporate, in the case of an alloy, the vapor pressure of each of the component metals are different, causing problems. However, sputtering can easily make a thin film not only metal but also inorganic materials such as quartz.
스퍼터링 장치는 간단한 2극 전극으로 구성되어 있으며 아르곤(Ar) 가스를 흘리면서 글로우(glow) 방전을 시킨다. 증착하고자하는 물질을 원형 또는 직사각형의 타겟(target)으로 만들어 여기에 음의 고전압을 인가하면 Ar+ ion의 충돌에 의해 튀어나온 타겟 원자가 마주 보고 있는 기판에 쌓여 박막이 형성된다.      The sputtering apparatus is composed of a simple two-pole electrode and causes a glow discharge while flowing argon (Ar) gas. When the material to be deposited is made into a circular or rectangular target and a negative high voltage is applied thereto, a thin film is formed by stacking target atoms protruding by the collision of Ar + ions on the facing substrate.
스퍼터링은 진공증착방법인 이베퍼레이션(Evaporation) 과 비교하면 날아가는 타깃 원자의 속도가 100배 정도 빠르기 때문에 박막과 기판의 부착강도가 크다. 2극 스퍼터링 이외에 기판과 타깃 사이에서 음극과 양극으로 플라즈마를 발생시키는 4극 스퍼터링 방식, 그리고 고주파를 이용하는 RF 방식, 최근에는 전기장 이외에 자기장을 이용한 마그네트론 스퍼터링 방식 등이 있다.     Sputtering has a high adhesion strength between the thin film and the substrate because the velocity of the flying target atoms is about 100 times faster than the evaporation method. In addition to the two-pole sputtering, there is a four-pole sputtering method for generating a plasma between the substrate and the target to the cathode and the anode, an RF method using a high frequency, and recently a magnetron sputtering method using a magnetic field in addition to an electric field.
그리고 상기 스퍼터링방식과 저항가열방식에 대한 기본원리는 본출원인인 기 출원하여 등록받은 등록번호 20-0185068에는 스퍼터링방식과 저항가열방식의 기본 원리에 대하여 기재되어 있다. 그 구성을 인용하면, 스퍼터링되는 타겟은 sputter module의 cathode에 clamp로 장착되어 있다.     In addition, the basic principle of the sputtering method and the resistance heating method is described in the registration number 20-0185068, which is a pre-applied application, the basic principle of the sputtering method and the resistance heating method. To quote the configuration, the sputtered target is clamped to the cathode of the sputter module.
여기서 상기 이베퍼레이터는 저항가열식 또는 전자빔 방식으로 코팅물질을 용융증발시켜 코팅하고, 상기 스퍼터링 타겟은 코팅물질을 스퍼터하여 비산시켜 피증착물을 증착하게 된다.     Here, the evaporator is coated by melting and evaporating the coating material in a resistive heating or electron beam method, and the sputtering target sputters and scatters the coating material to deposit the deposit.
상기 저항 가열방식은 저항체에 전류를 흘려 주울열을 발생하는것을 이용한 가열방식을 사용한다. 여기서는 물체에 직접 전류를 흘려서 가열하는 직접식과 발열체의 열을 복사 대류 전도 등으로 피가열물에 전달하는 간접식의 양자 방식을 모두 채택할 수 있다.     The resistance heating method uses a heating method using a current to flow through the resistor to generate Joule heat. In this case, both a direct method of heating a current directly through an object and an indirect method of transferring heat from a heating element to a heated object by radiative convection conduction can be adopted.
플라즈마 또는 글로우 방전은 상기한 방전 수단 사이에서 상기한 불활성 주입가스와 전원 공급장치으로부터 공급된 고압 전압의 스파크에 의해서 플라즈마 또는 글로우 방전대가 형성된다. 이러한 상태에서 상기 내통이 회전하면서 치구에 안착되어 있는 피코팅체의 코팅부위에 상기한 방전대를 거치면서 에칭이 이루어지고, 이와 동시에 스퍼터링 타겟 및 이베퍼레이터에 의해서 용융된 코팅물질이 비산 또는 스퍼터되어 상기한 피증착물에 다층의 박막이 형성되게 된다.     In the plasma or glow discharge, the plasma or glow discharge zone is formed by the spark of high pressure voltage supplied from the inert injection gas and the power supply device between the above discharge means. In this state, the inner cylinder is rotated and the etching is performed while the discharge zone is applied to the coating portion of the coated body seated on the jig, and at the same time, the coating material melted by the sputtering target and the evaporator is scattered or sputtered. As a result, a multilayer thin film is formed on the deposit.
피증착물의 증착 공정을 요약하면, 증착하고자 하는 기판(피증착물)을 내통의 치구에 장착한 후, 진공배기 장치를 통하여 진공증착 챔버를 진공배기하고, 챔버 내부가 일정한 진공상태에 도달하면 치구가 장착된 내통을 회전시켜 피증착물의 증착할 부분이 상기 스퍼터링 타겟 또는 이베퍼레이터로부터 용융 비산 또는 스퍼터되는 증착물질이 피증착물 표면에 균일하게 증착이 이루어지는 것이 일반적인 방법이다.     Summarizing the deposition process of the deposit, after mounting the substrate (deposit) to be deposited on the jig of the inner cylinder, the vacuum deposition chamber is evacuated through the vacuum exhaust device, and when the inside of the chamber reaches a constant vacuum state, the jig is It is a common method that the deposition material in which the portion to be deposited to be deposited is melted or sputtered from the sputtering target or evaporator is uniformly deposited on the surface of the deposit.
따라서, 본발명은 신발 장식용 밴드에 금속재질의 코팅층을 진공코팅방법에 의해 형성하여 빛의 굴절 및 반사에 의해 코팅층이 광택이 나고 심미감을 향상시킬 수 있는 현저한 효과가 있다.Therefore, the present invention has a remarkable effect that the coating layer of the metallic material formed on the decorative band for the shoe by vacuum coating method to improve the glossiness and improve the aesthetics by the refraction and reflection of light.
본발명은 신발 아웃솔 또는 미드솔 외부면에 장식물을 장착하되, 상기 장식물은 폴리에스테르(pet) 재질 패드로서, 그 표면에 진공코팅층이 형성된 것이다. 상기 폴리에스테르 패드에 진공코팅층을 형성한 후 재단하여 원하는 모양으로 잘라내거나, 미리 원하는 모양으로 잘라낸 후, 진공코팅층을 형성할 수 있다.According to the present invention, a decoration is mounted on an outer surface of a shoe outsole or a midsole, and the decoration is a polyester pad, and a vacuum coating layer is formed on a surface thereof. After the vacuum coating layer is formed on the polyester pad, it is cut and cut into a desired shape, or after cutting into a desired shape in advance, a vacuum coating layer may be formed.
그리고 상기 폴리에스테르 패드 코팅층은 신발 아웃솔 또는 미드솔 외부면에 형성되므로 심미감이 뛰어나다. 상기 신발 아웃솔 또는 미드솔은 고무나 PVC등의 합성수지로 제작되며, 상기 아웃솔 또는 미드솔에 폴리에스테르 재질 패드위에 코팅층이 형성된 장식물이 접착제 등에 의해 부착되는 것이다.And the polyester pad coating layer is formed on the shoe outsole or the midsole outer surface is excellent in aesthetics. The shoe outsole or midsole is made of synthetic resin such as rubber or PVC, and a decoration having a coating layer formed on a polyester pad on the outsole or midsole is attached by an adhesive or the like.
한편, 본발명은 상기 장식물은 관용의 폴리에스테르 재질 극세사로 만들어진 극세사 천에 코팅층이 형성된 것이며, 상기 코팅층은 스패터링방법 또는 이베퍼라이팅방법의 진공코팅방법에 의해 형성되는 것이다. 상기 폴리에스테르 재질 패드 또는 폴리에스테르 재질 극세사천은 시중에서 쉽게 구매할 수 있는 폴리에스테르 재질 극세사천으로 자세한 설명은 생략한다.On the other hand, the present invention is the decoration is a coating layer formed on a microfiber cloth made of conventional polyester microfiber, the coating layer is formed by a vacuum coating method of the sputtering method or evaporating method. The polyester pad or polyester microfiber cloth is a polyester microfiber cloth that can be easily purchased on the market and a detailed description thereof will be omitted.
한편, 본발명은 상기 진공코팅방법에 위해 코팅층이 형성된 위에 관용의 발수코팅방법에 의해 발수코팅층을 더 형성할 수 있는 것으로, 상기 관용의 널리 알려진 발수코팅방법은 공개특허공보 공개번호 10-2005-0095459호에 기재된 바와 같이, 발수성 코팅액은 본원이 선출원한 특허출원 제10-2004-018569호(명칭 : 비점착성 코팅막 형성을 위한 코팅 조성물, 이의 제조방법 및 이를 이용하는 표면 처리방법), 그리고 특허출원 제10-2004-018570호(명칭: 졸-겔 코팅용 조성물, 이의 제조방법 및 이를 이용한 표면 처리방법)에 설명되어 있는 발수성 코팅액을 이용하는 것이 바람직하나, 이외에 다른 발수성 코팅액도 이용할 수 있다.On the other hand, the present invention is to be able to further form a water repellent coating layer by the conventional water repellent coating method on the coating layer is formed for the vacuum coating method, the conventional well-known water repellent coating method. As described in 0095459, the water-repellent coating solution is a patent application No. 10-2004-018569 (name: coating composition for forming a non-tacky coating film, a preparation method thereof and a surface treatment method using the same), and a patent application agent It is preferable to use the water-repellent coating liquid described in 10-2004-018570 (name: composition for sol-gel coating, preparation method thereof and surface treatment method using the same), but other water-repellent coating liquid may also be used.
도포방법은 침지법(dipping), 유수법(flowing), 스프레이법, 붓질 (brushing)등이 무방하다.The coating method may be dipping, flowing, spraying, brushing, or the like.
도포가 끝난 후 건조단계에서는 1분에서 48시간동안 건조 시킨다. 건조과정은 경우에 따라서 생략해도 무방하다.In the drying step after the application is finished for 1 to 48 hours. The drying process may be omitted in some cases.
건조가 끝난 후 코팅액이 도포된 기판을 1분에서 24시간동안 섭씨50도에서 250도의 온도범위에서 열처리를 한다. 열처리 후 상온으로 냉각시킨다. 승온 속도와 냉각속도는 분당 0.5도에서 500도의 범위에서 어떻게 해도 무방하다. 또한 승온 및 냉각시 하나의 온도변화율로 진행하는 것이 아니고 다단계 및 다양한 온도변화율로 진행할 수도 있다.After drying, the substrate coated with the coating solution is heat-treated at a temperature range of 50 to 250 degrees Celsius for 1 minute to 24 hours. Cool to room temperature after heat treatment. The temperature increase rate and the cooling rate may be in the range of 0.5 to 500 degrees per minute. In addition, instead of proceeding with a single temperature change rate at the time of temperature increase and cooling, it may proceed with a multi-step and various temperature change rates.
그러므로 상기 발수코팅방법에 대한 자세한 기재는 생략한다.Therefore, detailed description of the water repellent coating method is omitted.
따라서, 본발명은 신발 아웃솔 또는 미드솔에 장식물이 부착되되, 상기 장식물은 폴리에스테르 재질의 패드위에 금속재질의 코팅층을 진공코팅방법에 의해 형성되어 빛의 굴절 및 반사에 의해 코팅층이 광택이 나고 심미감을 향상시킬 수 있는 현저한 효과가 있다.Therefore, the present invention is attached to the shoe outsole or midsole, the decoration is formed by a vacuum coating method of a metallic coating layer on the pad of polyester material, the coating layer is glossy and aesthetics by the refraction and reflection of light There is a significant effect that can be improved.

Claims (8)

  1. 신발 장식용 밴드에 코팅층을 형성하되, 상기 코팅층은 스패터링방법 또는 이베퍼라이팅방법의 진공코팅방법에 의해 형성되는 신발의 장식물 제조방법에 있어서,In the shoe decorative band is formed on the coating layer, the coating layer in the method of manufacturing a shoe ornaments formed by the vacuum coating method of the sputtering method or evaporating method,
    상기 코팅층은 베이스층과 멀티레이어코팅층으로 이루어지되, 상기 베이스코팅층은 Al, Cr, Cu, Ni, Si, W, Sn중 어느 하나의 성분으로 형성된 층이며, 상기 멀티레이어코팅층은 스패터링방법의 경우에는 Ti, Zr, Ag, Au, Cu, Si, Sn중 두 개 성분을 선택하여 형성되는 것을 특징으로 하는 신발의 장식물 제조방법The coating layer is composed of a base layer and a multilayer coating layer, the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn, the multilayer coating layer is a sputtering method Method of manufacturing a decoration of the shoe, characterized in that formed by selecting two components of Ti, Zr, Ag, Au, Cu, Si, Sn
  2. 제1항에 있어서, 상기 스패터링방법의 경우에는 반응성가스(reactive gas)인 C2H2 또는 O2를 진공챔버 내부에 주입하거나, 불활성가스인 N2 또는 Ar가스를 진공챔버 내부에 주입하는 것을 특징으로 하는 신발 장식용 밴드의 진공코팅층 형성방법The method of claim 1, wherein the sputtering method is C 2 H 2 or a reactive gas (reactive gas) or Method of forming a vacuum coating layer of a shoe decorative band, characterized in that the O 2 is injected into the vacuum chamber or inert gas N 2 or Ar gas into the vacuum chamber.
  3. 제1항에 있어서, 상기 멀티레이어코팅층은 이베퍼라이팅방법의 경우에는 SiO2, Nb2O3, Nb2O5, SiO, SiO2, Z2O, ZrO2, TiO, TiO2중 두 개 성분을 선택하여 형성되는 것을 특징으로 하는 신발 장식용 밴드의 진공코팅층 형성방법The method of claim 1, wherein the multilayer coating layer is two of SiO 2 , Nb 2 O 3 , Nb 2 O 5 , SiO, SiO 2 , Z 2 O, ZrO 2 , TiO, TiO 2 in the evaporation method. Vacuum coating layer forming method of the decorative band for shoes, characterized in that formed by selecting the component
  4. 신발 아웃솔 또는 미드솔 외부면에 부착되는 장식물을 제조하는 신발의 장식물 제조방법에 있어서, 상기 장식물은 폴리에스테르 재질 패드 위에 코팅층이 형성된 것이며, 상기 코팅층은 스패터링방법 또는 이베퍼라이팅방법의 진공코팅방법에 의해 형성되는 것을 특징으로 하는 신발의 장식물 제조방법In the shoe ornament manufacturing method of manufacturing a shoe that is attached to the shoe outsole or the outer surface of the midsole, the decoration is a coating layer is formed on a polyester pad, the coating layer is in the vacuum coating method of the sputtering method or evaporating method Decorative material manufacturing method of the shoe, characterized in that formed by
  5. 제4항에 있어서, 상기 코팅층은 베이스코팅층과 멀티레이어코팅층으로 이루어지되, 상기 베이스코팅층은 Al, Cr, Cu, Ni, Si, W, Sn중 어느 하나의 성분으로 형성된 층이며, 상기 멀티레이어코팅층은 스패터링방법의 경우에는 Ti, Zr, Ag, Au, Cu, Si, Sn중 두 개 성분을 선택하여 형성되는 것을 특징으로 하는 신발의 장식물 제조방법The method of claim 4, wherein the coating layer is made of a base coating layer and a multilayer coating layer, the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn, the multilayer coating layer In the case of the silver sputtering method, the method of manufacturing a shoe ornament, characterized in that formed by selecting two components of Ti, Zr, Ag, Au, Cu, Si, Sn
  6. 제4항에 있어서, 상기 스패터링방법의 경우에는 반응성가스(reactive gas)로서 C2H2, N2, O2, 또는 Ar가스를 진공챔버내부에 주입하는 것을 특징으로 하는 신발의 장식물 제조방법The method of claim 4, wherein in the case of the sputtering method, C 2 H 2 , N 2 , O 2 , or Ar gas is injected into the vacuum chamber as a reactive gas.
  7. 제4항에 있어서, 상기 코팅층은 베이스코팅층과 멀티레이어코팅층으로 이루어지되, 상기 베이스코팅층은 Al, Cr, Cu, Ni, Si, W, Sn중 어느 하나의 성분으로 형성된 층이며, 상기 멀티레이어코팅층은 이베퍼라이팅방법의 경우에는 SiO2, Nb2O3, Nb2O5, SiO, SiO2, Z2O, ZrO2, TiO, TiO2중 두 개 성분을 선택하여 형성되는 것을 특징으로 하는 신발의 장식물 제조방법The method of claim 4, wherein the coating layer is made of a base coating layer and a multilayer coating layer, the base coating layer is a layer formed of any one component of Al, Cr, Cu, Ni, Si, W, Sn, the multilayer coating layer In the case of silver evaporating method, it is formed by selecting two components of SiO 2, Nb 2 O 3 , Nb 2 O 5 , SiO, SiO 2 , Z 2 O, ZrO 2 , TiO, TiO 2 . How to make shoe ornaments
  8. 제4항에 있어서, 상기 장식물은 폴리에스테르 재질 관용의 극세사로 만들어진 극세사 천에 코팅층이 형성된 것이며, 상기 코팅층은 스패터링방법 또는 이베퍼라이팅방법의 진공코팅방법에 의해 형성되는 것을 특징으로 하는 신발의 장식물 제조방법The method of claim 4, wherein the decorative material is a coating layer formed on a microfiber cloth made of polyester microfiber yarn, the coating layer is formed by a vacuum coating method of the sputtering method or evaporating method of the shoe Decoration method
PCT/KR2014/005341 2013-06-20 2014-06-18 Method of manufacturing decoration for shoe WO2014204196A1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
KR1020130070723A KR101402459B1 (en) 2013-06-20 2013-06-20 Vacuum coating layer formation method of shoe decoration band
KR10-2013-0070723 2013-06-20
KR1020130138829A KR101467120B1 (en) 2013-11-15 2013-11-15 decorating material product method method of shoe outsole
KR10-2013-0138829 2013-11-15
KR10-2014-0002216 2014-01-08
KR1020140002216A KR101457841B1 (en) 2014-01-08 2014-01-08 decorating layer product method of shoe midsole

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WO2014204196A1 true WO2014204196A1 (en) 2014-12-24

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WO (1) WO2014204196A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070004606A (en) * 2003-12-30 2007-01-09 제옥스 에스. 뻬.아. Waterproof vapor-permeable multilayer article
KR20070005581A (en) * 2003-12-30 2007-01-10 제옥스 에스. 뻬.아. Breathable waterproof sole for shoes
JP2008212529A (en) * 2007-03-07 2008-09-18 Matsushita Electric Ind Co Ltd Footwear
KR20100054802A (en) * 2007-07-17 2010-05-25 피2아이 리미티드 Waterproof plasma treated footwear with liquid absorbing footbed

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070004606A (en) * 2003-12-30 2007-01-09 제옥스 에스. 뻬.아. Waterproof vapor-permeable multilayer article
KR20070005581A (en) * 2003-12-30 2007-01-10 제옥스 에스. 뻬.아. Breathable waterproof sole for shoes
JP2008212529A (en) * 2007-03-07 2008-09-18 Matsushita Electric Ind Co Ltd Footwear
KR20100054802A (en) * 2007-07-17 2010-05-25 피2아이 리미티드 Waterproof plasma treated footwear with liquid absorbing footbed

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