WO2014156804A1 - 美容剤用磁性粉 - Google Patents
美容剤用磁性粉 Download PDFInfo
- Publication number
- WO2014156804A1 WO2014156804A1 PCT/JP2014/057247 JP2014057247W WO2014156804A1 WO 2014156804 A1 WO2014156804 A1 WO 2014156804A1 JP 2014057247 W JP2014057247 W JP 2014057247W WO 2014156804 A1 WO2014156804 A1 WO 2014156804A1
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- WO
- WIPO (PCT)
- Prior art keywords
- magnetic powder
- particles
- cosmetics
- particle size
- magnetic
- Prior art date
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- 239000006247 magnetic powder Substances 0.000 title claims abstract description 105
- 239000002537 cosmetic Substances 0.000 title claims abstract description 90
- 239000002245 particle Substances 0.000 claims abstract description 138
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 24
- 238000009826 distribution Methods 0.000 claims abstract description 18
- 230000005415 magnetization Effects 0.000 claims abstract description 15
- 238000000790 scattering method Methods 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 35
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 11
- 238000002834 transmittance Methods 0.000 claims description 8
- 239000006228 supernatant Substances 0.000 claims description 7
- 230000005307 ferromagnetism Effects 0.000 claims description 4
- 230000003796 beauty Effects 0.000 description 55
- 239000000523 sample Substances 0.000 description 55
- 239000000047 product Substances 0.000 description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 14
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 11
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 229910052595 hematite Inorganic materials 0.000 description 9
- 239000011019 hematite Substances 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- 239000002002 slurry Substances 0.000 description 9
- 230000001276 controlling effect Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000001179 sorption measurement Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000011049 filling Methods 0.000 description 5
- 238000010304 firing Methods 0.000 description 5
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000003607 modifier Substances 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000007885 magnetic separation Methods 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000008406 cosmetic ingredient Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910001172 neodymium magnet Inorganic materials 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 229910052596 spinel Inorganic materials 0.000 description 3
- 239000011029 spinel Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910001035 Soft ferrite Inorganic materials 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- -1 Polyoxyethylene Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000012496 blank sample Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009500 colour coating Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
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- 239000012530 fluid Substances 0.000 description 1
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- 230000004927 fusion Effects 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011656 manganese carbonate Substances 0.000 description 1
- 229940093474 manganese carbonate Drugs 0.000 description 1
- 235000006748 manganese carbonate Nutrition 0.000 description 1
- 150000002697 manganese compounds Chemical class 0.000 description 1
- KVGMATYUUPJFQL-UHFFFAOYSA-N manganese(2+) oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[Mn++].[Mn++].[Mn++] KVGMATYUUPJFQL-UHFFFAOYSA-N 0.000 description 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000010378 sodium ascorbate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 1
- 229960005055 sodium ascorbate Drugs 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/022—Powders; Compacted Powders
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/022—Powders; Compacted Powders
- A61K8/0225—Granulated powders
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/04—Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/0018—Mixed oxides or hydroxides
- C01G49/0072—Mixed oxides or hydroxides containing manganese
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/02—Oxides; Hydroxides
- C01G49/08—Ferroso-ferric oxide [Fe3O4]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/34—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials non-metallic substances, e.g. ferrites
- H01F1/36—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials non-metallic substances, e.g. ferrites in the form of particles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/47—Magnetic materials; Paramagnetic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/42—Magnetic properties
Definitions
- the present invention relates to a magnetic powder for a cosmetic used in a cosmetic applied to the skin.
- a cosmetic agent that becomes a film after application can be easily separated from the skin by grasping and peeling off a part thereof.
- a method of removing from the skin what remains in the paste state even after application a method of wiping with cotton or the like, or washing off with warm water or the like is common.
- Patent Document 1 proposes a method in which a cosmetic agent mixed with iron powder and a remover provided with a magnet in the main body are used in combination. By using this method, it is possible to remove the used beauty agent applied to the skin by magnetic force.
- Patent Documents 2 to 3 disclose examples of beauty agents that can be adsorbed and removed from the skin by magnetic force.
- the magnetic powder contained in these cosmetics iron powder, iron oxide, or iron powder with a color coating is shown.
- the present invention has been made in view of such a background, and an object of the present invention is to provide an optimal magnetic powder for a cosmetic agent that can be adsorbed and removed from the cosmetic agent applied to the skin.
- One aspect of the present invention is a magnetic powder for cosmetics configured to be adsorbed and removed from a cosmetic applied to the skin, Made of ferrite showing ferromagnetism,
- the volume average particle size obtained from the particle size distribution obtained by the laser diffraction scattering method is 50 to 75 ⁇ m,
- the magnetic powder for cosmetics is composed of ferrite exhibiting ferromagnetism. Since ferrite has been oxidized in advance, it is less susceptible to further oxidation after being mixed with a cosmetic agent. Therefore, the beauty agent mixed with the magnetic powder for beauty agent is likely to suppress variation in performance. In addition, since the magnetic properties and color tone are less likely to change, the above-described beauty agent has a small change in performance even when stored for a long time.
- the magnetic powder for cosmetics has a particle size distribution in the specific range, and in particular, not only controls the volume average particle size, but also the content of large particles larger than the specific particle size. And the content of small-diameter particles smaller than the specific particle size are regulated.
- the magnetic powder for cosmetics after controlling the volume average particle size of the magnetic powder for cosmetics to 75 ⁇ m or less, and further controlling the content of the large particles to the specific amount or less, the magnetic powder for cosmetics is Roughness at the time of contact with the skin can be reduced. As a result, the beauty agent using the magnetic powder for beauty agent exhibits a smooth touch.
- the volume average particle size of the magnetic powder for cosmetics is controlled to 50 ⁇ m or more, and the content of the small-diameter particles is further controlled to be equal to or less than the specific amount, thereby acting on the entire magnetic powder for cosmetics.
- the magnetic force can be increased.
- the user can efficiently adsorb and remove the magnetic powder for cosmetics from the skin.
- the said magnetic powder for cosmetics is hard to remain on the skin surface, it is not necessary to separately wash the face for removing the magnetic powder for cosmetics, and the convenience for the user can be improved.
- the magnetic powder for cosmetics has optimum characteristics as a cosmetic agent to be adsorbed and removed from the skin.
- the magnetic powder for beauty agent is used by being mixed with a fluid beauty agent such as paste or liquid.
- the beauty agent contains various beauty components, and is configured to have a beauty effect such as replenishing nutrients to the skin or raising the dirt component of the skin.
- the cosmetic agent may be configured so that at least a part thereof remains on the skin surface when the magnetic powder for cosmetic agent is adsorbed and removed from the skin by a magnetic force according to the beauty effect to be obtained.
- the magnetic powder for beauty agent may be configured so that almost all is removed from the skin surface.
- the volume average particle diameter is calculated as the cumulative 50% particle diameter (median diameter) obtained by the volume distribution mode and display under the sieve in the particle diameter distribution obtained by the laser diffraction scattering method. Can do.
- the content of particles having a particle size of less than 37 ⁇ m is measured, for example, as the amount of particles that can pass through a standard sieve having a nominal size of 37 ⁇ m (400 mesh). Can do.
- the content of particles having a particle size of 105 ⁇ m or more is measured, for example, as the amount of particles that cannot pass through a standard sieve having a nominal size of 105 ⁇ m (145 mesh). be able to.
- the volume average particle size is less than 50 ⁇ m
- the particle size distribution tends to have a large content of particles having an excessively small particle size.
- the magnetic force acting on individual particles becomes weaker as the particle size is smaller. Therefore, when many particles having an excessively small particle size are contained, the magnetic force acting on the entire beauty powder magnetic powder tends to be weakened, and the beauty powder magnetic powder may be difficult to be adsorbed and removed from the skin.
- the volume average particle size exceeds 75 ⁇ m
- the particle size distribution has a large content of particles having an excessively large particle size. Therefore, in this case, there is a possibility that the feeling of use is deteriorated, for example, the feel of the beauty agent mixed with the magnetic powder for beauty agent becomes worse.
- the volume average particle diameter of the magnetic powder for cosmetics is controlled within the above specific range, and further, by controlling both the content of the small particle and the content of the large particle, an appropriate size can be obtained. An optimal particle size distribution with an increased content of particles can be realized. As a result, it is possible to optimize both the adsorption and removal performance of the magnetic powder for cosmetics and the touch characteristics.
- Examples of the ferrite constituting the magnetic powder for cosmetics include spinel ferrite, magnetoplumbite ferrite, garnet ferrite, and perovskite ferrite.
- the cosmetic magnetic powder may be composed of only one kind of compound selected from compounds classified as ferrite, or may contain two or more kinds of compounds.
- soft ferrite As the ferrite used in the magnetic powder for cosmetics, it is preferable to use soft ferrite having high saturation magnetization and low both residual magnetization and coercive force.
- the spinel ferrites it is more preferable to use a ferrite having high saturation magnetization. From the viewpoint of increasing the saturation magnetization, it is more preferable to contain as a main component magnetite (Fe 3 O 4 ) in which M in the above general formula is Fe.
- the magnetic powder for beauty agents has a saturation magnetization of 80 Am 2 / kg or more.
- the magnetization of the magnetic powder for beauty agent can be sufficiently increased, and the magnetic force acting on the magnetic powder for beauty agent can be further increased.
- the magnetic powder for cosmetics can perform adsorption removal from the skin more efficiently.
- the above-described magnetic powder for cosmetics has a transmittance of 90% or more at a wavelength of 474 nm of a supernatant obtained by dispersing it in methanol.
- the transmittance of the supernatant liquid is a value serving as an index of the content of particles having a very small particle diameter, and the higher the transmittance, the smaller the content of such particles.
- the transmittance of the supernatant liquid is 90% or more, the magnetic powder for cosmetics has a smaller content of such particles. As a result, the magnetic powder for cosmetics can perform adsorption removal from the skin more efficiently.
- the cosmetic magnetic powder preferably has an apparent density of 1.95 to 2.65 g / cm 3 .
- the apparent density of the magnetic powder for beauty agents is a value used as an index of the average shape of the particles constituting the magnetic powder for beauty agents.
- the magnetic powder for cosmetics having a high apparent density tends to have a larger mass of individual particles than the magnetic powder for cosmetics having a low apparent density. Therefore, the magnetic force which acts on the whole magnetic powder for beauty agents tends to become large. As this cause, for example, when the apparent density is increased, the volume of the cavity existing inside the particle is decreased.
- the apparent density of the magnetic powder for beauty agents exceeds 2.65 g / cm 3 , the content of excessively large particles may increase. Therefore, there is a possibility that it is difficult to disperse uniformly in a state of being mixed in the cosmetic agent, and in some cases, the magnetic powder for cosmetic agent may settle during storage.
- the apparent density is less than 1.95 g / cm 3
- the uneven shape of the particles may become excessively large.
- the viscosity of the beauty agent may be increased, and in some cases, it may be difficult to apply to the skin.
- the particles are likely to be fused excessively, and the unevenness of the particles may be excessively increased by the fusion as described above. Further, along with this, when the fused particles are crushed, the unevenness of the particles generated by the pulverization may become excessively large. Therefore, in this case, the ease of spreading when applying the cosmetic agent to the skin may be deteriorated, or the touch when applying the beauty agent may be deteriorated.
- the beauty powder magnetic powder preferably has a specific surface area of 200 to 450 cm 2 / g as measured using an air permeation method.
- the specific surface area of the magnetic powder for beauty agent is an index of the fine structure such as pores formed on the surface of the particles, and the larger the specific surface area value, the more pores and the like are formed.
- the specific surface area of the magnetic powder for beauty agents is less than 200 cm 2 / g, there is a possibility that fine structures such as pores are not sufficiently formed. Therefore, it is difficult for the cosmetic agent to be held on the surface of the particles, and it may be difficult to disperse in the cosmetic agent.
- the specific surface area of the cosmetic agent for the magnetic powder exceeds 450 cm 2 / g, there is a possibility that the fine structure is excessively formed, there is a possibility that cosmetic ingredients from entering the fine structure. Therefore, the amount of cosmetic ingredients that can act directly on the skin is reduced, and the cosmetic effect may be reduced.
- the magnetic powder for beauty agent may be configured such that the magnetic powder for beauty agent can exhibit another function by a technique such as binding a cosmetic ingredient to the surface or applying a coating.
- functions to be applied to the magnetic powder for beauty agents include improving the dispersibility of the magnetic powder for beauty agents using a surfactant, etc., and using the magnetic powder for beauty agents using a resin component that adsorbs sebum For example, it is possible to absorb and remove sebum from the skin.
- the magnetic powder for cosmetics when the surface of the magnetic powder for cosmetics is modified with a surface modifier such as a coating agent, it is preferable that the magnetic powder for cosmetics contains a large number of particles with an appropriately large uneven shape. . Particles having a reasonably large uneven shape have a larger surface area than when the uneven shape is small, so that it is easy to retain the surface modifier. Therefore, the magnetic powder for cosmetics containing a large amount of such particles can more easily obtain the effect of surface modification by the surface modifier. On the other hand, when a large amount of particles such as a substantially spherical shape having a small concavo-convex shape are contained, the surface modifier is difficult to adhere to the individual particles, which may make it difficult to obtain the effect of surface modification.
- the magnetic powder for cosmetics contains inevitable impurities derived from raw materials and manufacturing processes in addition to ferrite.
- Inevitable impurities include, for example, lead and arsenic, but their content is usually regulated to lead: 40 ppm or less and arsenic: 10 ppm or less.
- a method for producing the magnetic powder for cosmetics will be described.
- a method for producing the magnetic powder for beauty agent a conventionally known method can be employed.
- a method for performing classification treatment is mentioned.
- raw material for the magnetic powder for beauty agents natural ores containing ferrite, industrially produced metal compounds, and the like can be used.
- magnetite Fe 3 O 4
- natural ore containing magnetite can be used as a raw material.
- magnetite may be used as the raw material obtained by reducing the industrially produced hematite (Fe 2 O 3).
- the purity and composition of the obtained magnetite can be easily adjusted. As a result, the quality of the magnetic powder for beauty agents can be more easily stabilized.
- hematite is reduced to magnetite by heating in a state where it coexists with a carbon component.
- This reaction theoretically follows the following reaction formula. 6Fe 2 O 3 + C ⁇ 4Fe 3 O 4 + CO 2 Therefore, in order to completely reduce hematite to magnetite, at least 1.25 parts by mass of carbon is required for 100 parts by mass of hematite. Under actual production conditions, hematite may not be completely reduced by blending according to the above reaction formula, so it is preferable to blend more than 1.25 parts by mass of carbon.
- ferrite other than magnetite When ferrite other than magnetite is used, a method of mixing hematite manufactured industrially and a metal compound selected according to desired properties and then reacting at the time of firing or the like can be used. Specifically, when producing Mn ferrite, a manganese compound such as manganese carbonate or trimanganese tetraoxide can be used as the metal compound. Moreover, when manufacturing Mg ferrite, magnesium compounds, such as magnesium hydroxide and magnesium oxide, can be used.
- the method of preparing the granulated product from the pulverized and mixed raw materials may be a dry method or a wet method.
- the wet method for example, the raw material and water are mixed and pulverized with a ball mill or the like, and then a dispersant, a binder or the like is added as necessary to adjust the viscosity to obtain a slurry-like mixture. Thereafter, the mixture can be granulated using a spray dryer.
- the granulated product is usually fired by heating at a temperature of 1100 to 1400 ° C. for 1 to 24 hours.
- a known furnace such as a rotary electric furnace, a batch electric furnace, a tunnel electric furnace, or the like can be used.
- the atmosphere during firing can be appropriately selected in consideration of the target degree of oxidation and magnetic characteristics.
- a known method such as air classification, mesh filtration, or sedimentation can be used.
- dry recovery it is also possible to recover with a cyclone or the like. It is also possible to combine a plurality of these classification methods. By performing the classification process using these methods, the particle size distribution of the magnetic powder for beauty agents can be adjusted to a desired distribution.
- magnetic separation may be performed as necessary. By performing magnetic separation, particles having a low magnetic susceptibility can be removed.
- the magnetic powder for cosmetics of this example is formed from ferrite exhibiting ferromagnetism. Further, as shown in Table 1, the magnetic powder for cosmetics of this example has a volume average particle size determined from the particle size distribution obtained by the laser diffraction scattering method of 50 to 75 ⁇ m and a particle size of less than 37 ⁇ m. The content of a certain particle (small particle) is 15% by mass or less, and the content of a particle (large particle) having a particle size of 105 ⁇ m or more is 5% by mass or less.
- the magnetic powder for beauty agent is used by being mixed with a paste-like beauty agent 1 applied to the skin as shown in FIG.
- the cosmetic agent 1 of this example is configured such that after the magnetic powder for cosmetic agent is adsorbed and removed from the skin by the magnetic force generated from the magnetic force generating surface 20 of the remover 2, the cosmetic components remain on the skin surface.
- various cosmetic magnetic powders (samples No. 1 to No. 14) shown in Table 1 were prepared by the following manufacturing method.
- ⁇ Method for producing magnetic powder for beauty agent mainly composed of magnetite> Water was added to the powder obtained by pulverizing hematite (Fe 2 O 3 ) so that the solid content was 55% by mass to prepare a slurry. Subsequently, after adding 1 mass% polyvinyl alcohol, 0.9 mass% carbon black, and 0.5 mass% polycarboxylic acid salt with respect to solid content of the obtained slurry, it is an attritor. The resulting slurry was stirred for 1 hour. Thereafter, the slurry was granulated into a spherical shape using a spray dryer, and the particle size of the granulated product obtained using a gyro shifter was adjusted.
- the spherical granulated product whose particle size was adjusted was heated at 1320 ° C. for 3 hours to reduce the raw material hematite, and a fired product containing magnetite as a main component was obtained.
- the granulated product was heated in a nitrogen atmosphere using a tunnel electric furnace.
- a classification treatment was performed by using a combination of a gyro shifter and an air classifier to adjust the particle size distribution. Thereafter, magnetic separation was carried out to select particles having a high magnetic susceptibility, and a magnetic powder for cosmetics (sample No. 1) containing magnetite as a main component was obtained.
- Sample No. 1 In the production method of No. 1, sample No. 1 was changed by appropriately changing the amount of carbon black to be added, heating conditions, and classification conditions. 3 to No. 12 was obtained.
- the spherical granulated product whose particle size was adjusted was heated at 1310 ° C. for 3 hours to react hematite and trimanganese tetroxide to obtain a fired product mainly composed of Mn ferrite.
- the granulated product was heated in a nitrogen atmosphere using a tunnel electric furnace.
- a classification treatment was performed by using a combination of a gyro shifter and an air classifier to adjust the particle size distribution. Thereafter, magnetic separation was performed to select particles having a large magnetic susceptibility, and magnetic powders for cosmetics (samples No. 2 and No. 14) mainly composed of Mn ferrite were obtained.
- ⁇ Volume average particle diameter> After adding 0.2% sodium hexametaphosphate aqueous solution to the sample, ultrasonic treatment is performed for 1 minute using an ultrasonic homogenizer (UH-3C, manufactured by Ultrasonic Industry Co., Ltd.) to obtain a magnetic powder dispersion for cosmetics. Prepared. This dispersion was introduced into a Microtrac particle size analyzer (manufactured by Nikkiso Co., Ltd., Model 9320-X100) and measured under conditions of a refractive index of 1.81, a temperature of 25 ⁇ 5 ° C., and a humidity of 55 ⁇ 15%, and laser diffraction. The particle size distribution by the scattering method was obtained. From the obtained particle size distribution, the 50% cumulative particle size in the volume distribution mode and under the sieve display was calculated, and this was defined as the volume average particle size (median diameter).
- UH-3C Ultrasonic Industry Co., Ltd.
- ⁇ Apparent density> In accordance with the apparent density test method for metal powder specified in JIS Z 2504, measurement was performed by the following method.
- a device comprising a funnel, a cup, a funnel support, a support bar and a support base having an orifice with a pore diameter of 2.5 + 0.2 / 0 mm was used.
- a horizontal spatula formed of a nonmagnetic material was moved horizontally along the opening surface of the cup, and the sample raised on the cup was scraped off. Thereafter, the side of the cup was lightly tapped to stabilize the sample, and the sample adhering to the side of the cup was wiped off, and then the weight of the sample in the cup was weighed using a balance having a weight of 200 g and a sensitivity of 50 mg.
- the value obtained by multiplying the obtained weight value by 0.04 and rounding this value to the second decimal place using the rounding method defined in JIS Z 8401 is the apparent density (g / cm 3 ). did.
- Saturation magnetization, residual magnetization and coercive force were read from this hysteresis loop. Saturation magnetization, residual magnetization, and coercive force were measured by filling a cell having an inner diameter of 7 mm ⁇ ⁇ 0.02 mm and a height of 10 mm ⁇ 0.1 mm with a sample of about 1 g, 4 ⁇ I coil: 30 turns, applied magnetic field: 3000 oersted. Performed under conditions.
- ⁇ in the equation (1) is the porosity of the sample packed layer obtained by the following equation (2).
- Table 1 shows various properties of the magnetic powder for cosmetics evaluated by the above methods.
- -Magnetic powder for beauty agents 60.0% by mass ⁇ Glycerin 20.0% by mass ⁇ Methylparaben 0.38% by mass ⁇ Decamethylcyclopentasiloxane 1.3% by mass ⁇ Trioctylglyceryl 3.8% by mass ⁇ Cetyl 2-ethylhexanoate 3.8% by mass ⁇ Bentonite 0.19% by mass ⁇ Polyoxyethylene / methylpolysiloxane copolymer 2.25% by mass ⁇ Polyglyceryl monolaurate 0.25% by mass -Sodium polyacrylate 0.01% by mass ⁇ Sodium hydroxide 0.03% by mass ⁇ Sodium ascorbate 0.13 mass% ⁇ Perfume 0.13 mass% ⁇ Water balance
- a beauty agent mixed with magnetic powder for beauty agent was applied to a flat plate placed on a horizontal surface.
- the height from the flat plate to the test head when the magnetic powder for cosmetics was adsorbed on the test head was measured from the top of the cosmetic applied with the test head containing the neodymium magnet. It is shown in the column of “Adsorption distance”.
- the value described in Table 2 indicates that the larger the magnetic powder for cosmetic agent is, the easier it is to remove by adsorption.
- the neodymium magnet built in the test head was a cylinder having a diameter of 25 mm and a height of about 8 mm, and the surface magnetic flux density of the magnet alone was 266 mT. Further, a 2 mm-thick yoke material having a disk shape was disposed on the end face facing upward of the neodymium magnet.
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Abstract
Description
強磁性を示すフェライトよりなり、
レーザー回折散乱法により得られる粒径分布から求めた体積平均粒径が50~75μmであり、
粒径が37μm未満である粒子の含有量が15質量%以下であり、かつ、粒径が105μm以上である粒子の含有量が5質量%以下であることを特徴とする美容剤用磁性粉にある。
6Fe2O3 + C → 4Fe3O4 + CO2
従って、ヘマタイトを完全にマグネタイトに還元するためには、100質量部のヘマタイトに対して少なくとも1.25質量部の炭素が必要となる。実際の製造条件においては、上記の反応式に従った配合ではヘマタイトが完全には還元されない場合があるため、炭素を1.25質量部よりも多く配合することが好ましい。
ヘマタイト(Fe2O3)を粉砕した粉末に対し、固形分が55質量%となるように水を加えてスラリーを調製した。次いで、得られたスラリーの固形分に対して1質量%のポリビニルアルコールと、0.9質量%のカーボンブラックと、0.5質量%のポリカルボン酸塩とをスラリーに加えた後、アトライターを用いて得られたスラリーを1時間攪拌した。その後、スプレードライヤーを用いてスラリーを球状に造粒し、ジャイロシフターを用いて得られた造粒物の粒度調整を行った。
ヘマタイト及び四酸化三マンガンをMnO:20mol%、Fe2O3:80mol%となるように秤量し、湿式のメディアミルで1時間粉砕してスラリーを得た。得られたスラリーをスプレードライヤーにて乾燥し、球状の造粒物を得た。次いで、ジャイロシフターを用いて得られた造粒物の粒度調整を行った後、950℃で2時間加熱することにより仮焼成を行った。
試料に0.2%ヘキサメタリン酸ナトリウム水溶液を加えた後、ウルトラソニックホモジナイザー(超音波工業社製、UH-3C)を用いて1分間の超音波処理を行って美容剤用磁性粉の分散液を調製した。この分散液をマイクロトラック粒度分析計(日機装株式会社製、Model9320-X100)に導入し、屈折率1.81、温度25±5℃、湿度55±15%の条件下で測定を行い、レーザー回折散乱法による粒径分布を得た。得られた粒径分布から、体積分布モード、ふるい下表示での累積50%粒子径を算出し、これを体積平均粒径(メジアン径)とした。
JIS Z 8801に規定される標準ふるいを用いて、JIS H 2601に準じた方法により試料の分級を行った。これにより、呼び寸法37μm(400メッシュ)の標準ふるいを通過した粒子(小径粒子)の含有量及び呼び寸法105μm(145メッシュ)の標準ふるいを通過しなかった粒子(大径粒子)の含有量を測定した。
JIS Z 2504に規定される金属粉の見掛密度試験方法に準じて、以下の方法により測定を行った。見掛密度の測定装置は、孔径2.5+0.2/0mmのオリフィスを有する漏斗、コップ、漏斗支持器、支持棒及び支持台からなるものを用いた。まず、少なくとも150gの試料を漏斗に注ぎ、漏斗から流れ出す試料を漏斗の下方に設置したコップに直接流し入れた。コップが試料で満たされた後、試料がコップからあふれ出した時点で直ちに試料の流入を止めた。
積分型B-Hトレーサー((株)理研電子製、BHU-60型)を使用して以下の手順で測定した。まず、電磁石間に磁場測定用Hコイル及び磁化測定用4πIコイルを入れ、試料を4πIコイル内に入れる。次いで、電磁石の電流を変化させ磁場Hを変化させたHコイル及び4πIコイルの出力をそれぞれ積分し、X軸にH出力をとり、Y軸に4πIコイルの出力をとったヒステリシスループを記録紙に描く。このヒステリシスループから飽和磁化、残留磁化及び保磁力を読み取った。飽和磁化、残留磁化及び保磁力の測定は、内径7mmφ±0.02mm、高さ10mm±0.1mmのセルに約1gの試料を充填し、4πIコイル:巻数30回、印加磁場:3000エルステッドの条件で行った。
15gの試料を秤量し、これを50mlのサンプル瓶に入れた。このサンプル瓶に20mlのメタノールを加えて蓋をした後、回転式撹拌機を用いて150rpmで20分間撹拌を行った。撹拌が完了した後、サンプル瓶の底に磁石を当接させて試料を吸着させ、この状態でサンプル瓶を手で3回振り混ぜた。その後、サンプル瓶の上澄み液を3ml採取し、可視分光光度計(オガワ精機社製、Model6100)を用いて波長474nmにおける上澄み液の透過率を測定した。なお、透過率の測定におけるブランクサンプルとしては、メタノールを用いた。
試料をプラスチック製試料筒に充填した後、粉体比表面積測定装置(島津製作所製、SS-100型)を用いて空気透過法による比表面積を測定した。より具体的な試料の充填方法及び測定手順は、以下の通りである。
プラスチック製試料筒にふるい板を入れ、更にその上にろ紙を1枚敷いた状態で試料筒をパウダーテスター(ホソカワミクロン社製)のタップ架台に設置した。次いで、試料を試料筒の1/3程度まで注ぎ入れ、パウダーテスターを作動させて試料筒を60秒間タップした。タップ後、試料筒の2/3程度まで試料を注ぎ足し、再度パウダーテスターを作動させて試料筒を60秒間タップした。その後、試料筒を満たすまで試料を注ぎ足し、パウダーテスターを作動させて試料筒を60秒間タップした。3回目のタップが完了した後、試料筒に付着した余分な試料を刷毛やワイパー等を用いて除去し、試料の充填を完了した。
試料筒の下部にワセリンを塗布し、この部分を測定管に接続した後、測定管に純水を注入した。次いで、測定装置の下部流出口のコックを開いて純水を測定管から流出させ、測定管内の水位が20cc分だけ低下するまでの時間tを測定した。これにより得られた、20ccの空気が試料充填層を透過するまでに要する時間t(sec)と、試料管内に充填した試料の重量W(g)とをKozeny-Carmanの式(下記式(1)参照)に代入し、試料の比表面積Swを求めた。
試料の比表面積:Sw(cm2/g)
試料の密度:ρ(g/cm3)
空気の粘性係数:η(g/cm・sec)
試料充填層の厚さ:L(cm)
試料充填層を透過した空気の体積:Q(cc)
試料充填層の両端間の圧力差:ΔP(g/cm2)
試料充填層の断面積:A(cm2)
・美容剤用磁性粉 60.0質量%
・グリセリン 20.0質量%
・メチルパラベン 0.38質量%
・デカメチルシクロペンタシロキサン 1.3質量%
・トリオクチルグリセリル 3.8質量%
・2-エチルヘキサン酸セチル 3.8質量%
・ベントナイト 0.19質量%
・ポリオキシエチレン・メチルポリシロキサン共重合体 2.25質量%
・モノラウリン酸ポリグリセリル 0.25質量%
・ポリアクリル酸ナトリウム 0.01質量%
・水酸化ナトリウム 0.03質量%
・アスコルビン酸リン酸ナトリウム 0.13質量%
・香料 0.13質量%
・水 残部
水平面に載置した平板状に美容剤用磁性粉を混合した美容剤を塗布した。ネオジム磁石を内蔵した試験ヘッドを塗布した美容剤の上方から近づけ、美容剤用磁性粉が試験ヘッドに吸着された時点における平板から試験ヘッドまでの高さを測定し、その値を表2中の「吸着距離」の欄に示した。表2に記載した値は、大きいほど美容剤用磁性粉が吸着除去されやすいことを示す。なお、試験ヘッドに内蔵したネオジム磁石は、直径25mm、高さ約8mmの円筒状であり、磁石単体での表面磁束密度は266mTであった。また、ネオジム磁石の上方を向いた端面に円板状を呈する厚さ2mmのヨーク材を配して用いた。
美容剤を手の甲に塗布したときの肌触りを評価し、表2に示した。なお、表2に示す各記号の意味は、以下の通りである。
A:ざらつき感は全く感じられない
B:ざらつき感はほとんど感じられない
C:ざらつき感を感じるが、塗り広げることはできる
D:ざらつき感を感じ、塗り広げることができない
測色色差計(日本電色工業株式会社製、型式「ZE 2000」)を用いて美容剤用磁性粉のL値(明度)、a値(緑~赤の色度)、b値(青~黄の色度)を測定し、各々の値を表2に示した。なお、測定には、5gの美容剤用磁性粉を用いた。
Claims (5)
- 肌に塗布された美容剤から磁力により吸着除去可能に構成された美容剤用磁性粉であって、
強磁性を示すフェライトよりなり、
レーザー回折散乱法により得られる粒径分布から求めた体積平均粒径が50~75μmであり、
粒径が37μm未満である粒子の含有量が15質量%以下であり、かつ、粒径が105μm以上である粒子の含有量が5質量%以下であることを特徴とする美容剤用磁性粉。 - 請求項1に記載の美容剤用磁性粉において、飽和磁化が80Am2/kg以上であることを特徴とする美容剤用磁性粉。
- 請求項1または2に記載の美容剤用磁性粉において、該美容剤用磁性粉をメタノールに分散させて得られる上澄み液の、波長474nmにおける透過率が90%以上であることを特徴とする美容剤用磁性粉。
- 請求項1~3のいずれか1項に記載の美容剤用磁性粉において、見掛密度が1.95~2.65g/cm3であることを特徴とする美容剤用磁性粉。
- 請求項1~4のいずれか1項に記載の美容剤用磁性粉において、空気透過法を用いて測定したときの比表面積が200~450cm2/gであることを特徴とする美容剤用磁性粉。
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EP (1) | EP2980025A4 (ja) |
JP (1) | JP6363062B2 (ja) |
KR (1) | KR20150134329A (ja) |
CN (1) | CN105189362B (ja) |
HK (1) | HK1216507A1 (ja) |
SG (1) | SG11201506941XA (ja) |
TW (1) | TWI631959B (ja) |
WO (1) | WO2014156804A1 (ja) |
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WO2015079942A1 (ja) * | 2013-11-29 | 2015-06-04 | 株式会社 Mtg | 水系スキンケア剤 |
JP2015120649A (ja) * | 2013-12-20 | 2015-07-02 | 株式会社 Mtg | スキンケア剤 |
JPWO2014156805A1 (ja) * | 2013-03-29 | 2017-02-16 | 株式会社 Mtg | 美容剤用磁性粉 |
JP2021031527A (ja) * | 2019-08-20 | 2021-03-01 | タイガースポリマー株式会社 | 樹脂組成物および樹脂組成物による芳香発生方法 |
JP2021519274A (ja) * | 2018-03-21 | 2021-08-10 | ラッシュライナー・インコーポレイテッドLashliner Inc. | 磁気皮膚用接着剤、アクセサリー、及び関連方法 |
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JPWO2015098895A1 (ja) * | 2013-12-26 | 2017-03-23 | 株式会社 Mtg | スキンケア剤 |
US10919779B2 (en) | 2016-12-12 | 2021-02-16 | Powdertech Co., Ltd. | Iron oxide powder for brake friction material |
CN107822941A (zh) * | 2017-11-20 | 2018-03-23 | 广东旭睿美医疗科技有限公司 | 美容护肤剂 |
JP6944431B2 (ja) * | 2018-11-16 | 2021-10-06 | Dowaエレクトロニクス株式会社 | 磁気記録媒体用磁性粉およびその製造方法 |
CN110934753A (zh) * | 2019-12-20 | 2020-03-31 | 广州市蔻萝生物科技有限公司 | 一种眼线液及其制作方法 |
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Also Published As
Publication number | Publication date |
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EP2980025A1 (en) | 2016-02-03 |
US20160038383A1 (en) | 2016-02-11 |
TW201532619A (zh) | 2015-09-01 |
JPWO2014156804A1 (ja) | 2017-02-16 |
SG11201506941XA (en) | 2015-10-29 |
CN105189362A (zh) | 2015-12-23 |
TWI631959B (zh) | 2018-08-11 |
US9713581B2 (en) | 2017-07-25 |
EP2980025A4 (en) | 2016-12-14 |
HK1216507A1 (zh) | 2016-11-18 |
KR20150134329A (ko) | 2015-12-01 |
JP6363062B2 (ja) | 2018-07-25 |
CN105189362B (zh) | 2017-12-12 |
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