WO2014125309A3 - Metal catalyst supported on mesoporous material - Google Patents

Metal catalyst supported on mesoporous material Download PDF

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Publication number
WO2014125309A3
WO2014125309A3 PCT/GB2014/050475 GB2014050475W WO2014125309A3 WO 2014125309 A3 WO2014125309 A3 WO 2014125309A3 GB 2014050475 W GB2014050475 W GB 2014050475W WO 2014125309 A3 WO2014125309 A3 WO 2014125309A3
Authority
WO
WIPO (PCT)
Prior art keywords
mesoporous material
precipitate
metal catalyst
catalyst supported
mixture
Prior art date
Application number
PCT/GB2014/050475
Other languages
French (fr)
Other versions
WO2014125309A2 (en
Inventor
Maria OLEA
Simon Nicholas Hodgson
Rawaz Abdulrahman AHMED
Original Assignee
Teesside University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teesside University filed Critical Teesside University
Publication of WO2014125309A2 publication Critical patent/WO2014125309A2/en
Publication of WO2014125309A3 publication Critical patent/WO2014125309A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B01J35/393—
    • B01J35/615—
    • B01J35/635—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

The invention discloses a method of making a mesoporous material with hexagonaily arranged mesopores comprising the following steps: a) dissolving a surfactant in water to form a surfactant solution; b) adding an acid to the surfactant solution to form a mixture having pH less than 2; c) adding a silica precursor to said mixture to form a precipitate; d) aging the precipitate; e) filtering, washing and drying the aged precipitate of step d) and subjecting said precipitate to calcination. An alternative method of making the mesoporous material is also disclosed. The mesoporous material is suitable for supporting a catalyst. Furthermore, the invention describes a supported metal catalyst incorporating such a mesoporous material.
PCT/GB2014/050475 2013-02-18 2014-02-18 Supported metal catalyst WO2014125309A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1302778.4 2013-02-18
GBGB1302778.4A GB201302778D0 (en) 2013-02-18 2013-02-18 Supported mteal catalyst

Publications (2)

Publication Number Publication Date
WO2014125309A2 WO2014125309A2 (en) 2014-08-21
WO2014125309A3 true WO2014125309A3 (en) 2014-10-16

Family

ID=48048535

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2014/050475 WO2014125309A2 (en) 2013-02-18 2014-02-18 Supported metal catalyst

Country Status (2)

Country Link
GB (1) GB201302778D0 (en)
WO (1) WO2014125309A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105381818B (en) * 2015-06-15 2018-10-02 清华大学 A kind of preparation method for synthesizing gas by reforming methane with co 2 high dispersive Ni catalyst
CN104909383B (en) * 2015-06-19 2017-11-24 山东理工大学 The method of the mesopore molecular sieves of synthesizing multilayer shape high-ratio surface SBA 15
CN107866261B (en) * 2017-11-14 2020-10-27 北京赛诺时飞石化科技有限公司 Hydrocarbon reforming catalyst of modified SBA-15 molecular sieve and preparation method and application thereof
CN110330026A (en) * 2019-07-01 2019-10-15 大连工业大学 A method of utilizing the synthesising mesoporous material SBA-15 of natural diatomaceous earth
WO2022008942A1 (en) * 2020-07-07 2022-01-13 Sorbonne Universite Ni-silica-based catalysts with highly dispersed nickel particles
CN113893857B (en) * 2021-11-04 2024-02-02 南京诚志清洁能源有限公司 Cobalt-based catalyst for reforming carbon dioxide methane and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020197206A1 (en) * 2001-04-26 2002-12-26 Balkus Kenneth J. Mesoporous compositions and method of preparation
WO2003037511A1 (en) * 2001-11-01 2003-05-08 Silicycle Inc. Method of preparing highly ordered mesoporous molecular sieves

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020197206A1 (en) * 2001-04-26 2002-12-26 Balkus Kenneth J. Mesoporous compositions and method of preparation
WO2003037511A1 (en) * 2001-11-01 2003-05-08 Silicycle Inc. Method of preparing highly ordered mesoporous molecular sieves

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
JIN-KWON LEE: "Catalytic behaviour of nickel particles embedded in three-dimensional mesoporous SBA-15", BULLETIN OF THE KOREAN CHEMICAL SOCIETY, KOREAN CHEMICAL SOCIETY, KR, vol. 28, 1 January 2007 (2007-01-01), pages 121 - 124, XP009177925, ISSN: 0253-2964 *
KATIYAR A ET AL: "Synthesis of ordered large pore SBA-15 spherical particles for adsorption of biomolecules", JOURNAL OF CHROMATOGRAPHY, ELSEVIER SCIENCE PUBLISHERS B.V, NL, vol. 1122, no. 1-2, 28 July 2006 (2006-07-28), pages 13 - 20, XP024967794, ISSN: 0021-9673, [retrieved on 20060728], DOI: 10.1016/J.CHROMA.2006.04.055 *
WANG W ET AL: "Photocatalytic activity of titania-containing mesoporous SBA-15 silica", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER SCIENCE PUBLISHING, NEW YORK, US, vol. 96, no. 1-3, 26 November 2006 (2006-11-26), pages 255 - 261, XP028038809, ISSN: 1387-1811, [retrieved on 20061126], DOI: 10.1016/J.MICROMESO.2006.07.001 *
ZHANG M ET AL: "Structural Characterization of Highly Stable Ni/SBA-15 Catalyst and Its Catalytic Performance for Methane Reforming with CO2", CHINESE JOURNAL OF CATALYSIS / DALIAN INSTITUTE OF CHEMICAL PHYSICS, ELSEVIER, AMSTERDAM, NL, vol. 27, no. 9, 1 September 2006 (2006-09-01), pages 777 - 781, XP022857557, ISSN: 1872-2067, [retrieved on 20060901], DOI: 10.1016/S1872-2067(06)60043-0 *

Also Published As

Publication number Publication date
GB201302778D0 (en) 2013-04-03
WO2014125309A2 (en) 2014-08-21

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