WO2014111579A2 - Procédé de mise en pli des cheveux avec application d'une composition coiffante particulière puis rinçage - Google Patents

Procédé de mise en pli des cheveux avec application d'une composition coiffante particulière puis rinçage Download PDF

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Publication number
WO2014111579A2
WO2014111579A2 PCT/EP2014/051045 EP2014051045W WO2014111579A2 WO 2014111579 A2 WO2014111579 A2 WO 2014111579A2 EP 2014051045 W EP2014051045 W EP 2014051045W WO 2014111579 A2 WO2014111579 A2 WO 2014111579A2
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composition
polymers
hair
styling composition
process according
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PCT/EP2014/051045
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English (en)
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WO2014111579A3 (fr
Inventor
Valérie Favreau
Xavier JOSEPH
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L'oreal
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Priority to EP14701035.9A priority Critical patent/EP2945598A2/fr
Publication of WO2014111579A2 publication Critical patent/WO2014111579A2/fr
Publication of WO2014111579A3 publication Critical patent/WO2014111579A3/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A61K2800/884—Sequential application

Definitions

  • the present invention relates to a hair shaping process in which is applied a particular styling composition, which is rinsed out with an aqueous composition, and also to a kit comprising the compositions used in the process.
  • hair compositions are generally provided in the form of hair gels, lotions, foams or sprays.
  • Documents FR 2 729 563, EP 754 026, EP 1 532 966 and EP 1 629 827 describe, for example, hair styling compositions.
  • compositions are generally applied to wet hair, in particular after it has been washed and superficially dried, for example after a shower and superficial drying.
  • the use of these compositions requires an application time additional to the time spent under the shower.
  • styling compositions generally leave, after hair styling, a tactile feeling of residual products in the hands, in particular a phenomenon of residual tackiness which remains on the hands, which requires that the hands be washed after the application of these compositions. Residual tackiness may also remain on the hair.
  • One subject of the present invention is thus especially a hair shaping process in which:
  • a styling composition comprising one or more organic solvents and one or more fixing polymers is applied to hair, preferably wet hair, the fixing polymer(s) being at least partially soluble in the styling composition and being capable of precipitating on the hair when the styling composition is diluted with an aqueous composition, and then
  • the hair is rinsed with the aqueous composition so as to precipitate the fixing polymer on the hair.
  • the hair shaping process allows quick and easy styling. This process also makes it possible to obtain a good level of fixing, long-lasting hairstyle hold and a clean, non- tacky feel of the hair, with little or no residues.
  • the process according to the invention in particular makes it possible to use the styling composition directly in the shower.
  • the present invention relates to a kit comprising:
  • washing composition comprising one or more surfactants;
  • a care composition comprising at least one conditioning agent
  • a styling composition comprising one or more organic solvents and one or more fixing polymers, the fixing polymer(s) being at least partially soluble in the styling composition and being capable of precipitating on the hair when the styling composition is diluted with an aqueous composition.
  • Styling composition is understood to mean a composition which makes it possible to give a shape to a head of hair and/or to retain the acquired shape of the head of hair.
  • the styling composition according to the invention comprises at least one fixing polymer.
  • fixing polymer is understood to mean any polymer that is capable, by application to the hair, of giving a shape to the head of hair or of making it possible to retain an already acquired shape.
  • the fixing polymer(s) used are chosen from ionic, especially anionic, cationic or amphoteric, and nonionic fixing polymers, and mixtures thereof.
  • Anionic polymers that may be mentioned include polymers comprising groups derived from carboxylic acids, sulfonic acids or phosphoric acids, and having a number-average molecular mass of between 500 and 5 000 000.
  • the carboxylic groups are provided by unsaturated monocarboxylic or dicarboxylic acid monomers such as those corresponding to the formula:
  • n is an integer from 0 to 10
  • A denotes a methylene group, optionally linked to the carbon atom of the unsaturated group or to the neighbouring methylene group when n is greater than 1 via a heteroatom such as oxygen or sulfur
  • R-i denotes a hydrogen atom or a phenyl or benzyl group
  • R 2 denotes a hydrogen atom, an alkyl group comprising from 1 to 4 carbon atoms or a carboxyl group
  • R 3 denotes a hydrogen atom, an alkyl group comprising from 1 to 4 carbon atoms or a -CH 2 -COOH, phenyl or benzyl group.
  • the alkyl group comprising from 1 to 4 carbon atoms may in particular denote methyl and ethyl groups.
  • anionic fixing polymers containing carboxylic or sulfonic groups that are preferred are:
  • A) Copolymers of acrylic or methacrylic acid or salts thereof including copolymers of acrylic acid and of acrylamide and methacrylic acid/acrylic acid/ethyl acrylate/methyl methacrylate copolymers, in particular Amerhold DR 25 sold by the company Amerchol, and the sodium salts of polyhydroxycarboxylic acids. Mention may also be made of methacrylic acid/ethyl acrylate copolymers, especially in aqueous dispersion, such as Luviflex Soft and Luvimer MAE sold by the company BASF;
  • a monoethylenic monomer such as ethylene, styrene, vinyl esters and acrylic or methacrylic acid esters
  • a polyalkylene glycol such as polyethylene glycol and optionally crosslinked.
  • Such polymers are described in particular in French patent 1 222 944 and German patent application 2 330 956, the copolymers of this type comprising an optionally N-alkylated and/or hydroxyalkylated acrylamide unit in their chain as described especially in Luxembourg patent applications 75370 and 75371 . Mention may also be made of copolymers of acrylic acid and of a Ci-C 4 alkyl methacrylate.
  • anionic fixing polymer of this family mention may also be made of the butyl acrylate/acrylic acid/methacrylic acid branched block anionic polymer sold under the name Fixate G-100 L by the company Lubrizol (I NCI name: AMP-acylates/allyl methacrylate copolymer).
  • Crotonic acid-based copolymers such as those comprising in their chain vinyl acetate or propionate units and optionally other monomers such as allylic or methallylic esters, vinyl ether or vinyl ester of a saturated, linear or branched carboxylic acid containing a long hydrocarbon-based chain such as those comprising at least 5 carbon atoms, these polymers possibly being grafted and crosslinked, or alternatively a vinyl, allylic or methallylic ester of an a- or ⁇ -cyclic carboxylic acid.
  • Such polymers are described, inter alia, in French patents 1 222 944, 1 580 545, 2 265 782, 2 265 781 , 1 564 1 10 and 2 439 798. Commercial products that fall within this category are the resins 28-29-30, 26-13-14 and 28-13-10 sold by the company National Starch.
  • Crotonic acid-based copolymers that may also be mentioned include crotonic acid/vinyl acetate/vinyl tert-butylbenzoate terpolymers and in particular Mexomer PW supplied by the company Chimex.
  • Such polymers are described in particular in US patents 2 047 398, 2 723 248 and 2 102 1 13 and GB patent 839 805, and especially those sold under the names Gantrez® AN or ES by the company ISP.
  • Polymers also falling within this category are the copolymers of maleic, citraconic or itaconic anhydrides and of an allylic or methallylic ester optionally comprising an acrylamide or methacrylamide group, an a-olefin, acrylic or methacrylic esters, acrylic or methacrylic acids or vinylpyrrolidone in their chain, the anhydride functions being monoesterified or monoamidated.
  • these polymers are described, for example, in French patents 2 350 384 and 2 357 241 by the Applicant.
  • Polymers comprising sulfonic groups. These polymers may be polymers comprising vinylsulfonic, styrenesulfonic, naphthalenesulfonic, acrylamidoalkylsulfonic or sulfoisophthalate units.
  • These polymers can be chosen in particular from:
  • polyvinylsulfonic acid salts with a molecular mass of between about 1000 and 100 000, and also copolymers with an unsaturated comonomer such as acrylic or methacrylic acids and esters thereof, and also acrylamide or derivatives thereof, vinyl ethers and vinylpyrrolidone;
  • the grafted silicone polymers used are preferably chosen from polymers containing a non-silicone organic backbone grafted with monomers containing a polysiloxane, polymers containing a polysiloxane backbone grafted with non-silicone organic monomers, and mixtures thereof.
  • Anionic polyurethanes which may comprise silicone grafts and silicones bearing hydrocarbon-based grafts.
  • fixing polyurethanes examples include the dimethylolpropionic acid/isophorone diisocyanate/neopentyl glycol/polyester diols copolymer (also known under the name polyurethane-1 , INCI name) sold under the brand name Luviset® Pur by the company BASF, and the dimethylolpropionic acid/isophorone diisocyanate/neopentyl glycol/polyester diols/silicone diamine copolymer (also known under the name polyurethane-6, INCI name) sold under the brand name Luviset® Si PUR A by the company BASF.
  • dimethylolpropionic acid/isophorone diisocyanate/neopentyl glycol/polyester diols copolymer also known under the name Luviset® Pur by the company BASF
  • Avalure UR 450 Another anionic polyurethane that may also be used is Avalure UR 450.
  • Polymers containing sulfoisophthalate groups such as the polymers AQ55 and
  • AQ48 sold by the company Eastman, may also be used.
  • the anionic polymers are preferably chosen from acrylic acid copolymers such as the acrylic acid/ethyl acrylate/N-tert-butylacrylamide terpolymer sold under the name Ultrahold Strong® by the company BASF, and methacrylic acid/ethyl acrylate copolymers, especially in aqueous dispersion, such as Luviflex Soft and Luvimer MAE sold by the company BASF.
  • acrylic acid copolymers such as the acrylic acid/ethyl acrylate/N-tert-butylacrylamide terpolymer sold under the name Ultrahold Strong® by the company BASF
  • methacrylic acid/ethyl acrylate copolymers especially in aqueous dispersion, such as Luviflex Soft and Luvimer MAE sold by the company BASF.
  • Crotonic acid-based copolymers such as vinyl acetate/vinyl tert-butylbenzoate/crotonic acid terpolymers and crotonic acid/vinyl acetate/vinyl neododecanoate terpolymers sold under the name Resin 28-29-30 by the company National Starch, polymers derived from maleic, fumaric or itaconic acids or anhydrides with vinyl esters, vinyl ethers, vinyl halides or phenylvinyl derivatives, acrylic acid and esters thereof, such as the methyl vinyl ether/monoesterified maleic anhydride copolymer sold under the name Gantrez® ES 425 by the company ISP, Luviset Si Pur, Mexomer PW, elastomeric or non-elastomeric anionic polyurethanes, and polymers containing sulfoisophthalate groups.
  • the cationic fixing polymers that can be used according to the present invention are preferably chosen from polymers comprising primary, secondary, tertiary and/or quaternary amine groups forming part of the polymer chain or directly attached thereto, and having a molecular weight of between 500 and approximately 5 000 000 and preferably between 1000 and 3 000 000.
  • R 3 denotes a hydrogen atom or a CH 3 group
  • A is a linear or branched alkyl group comprising from 1 to 6 carbon atoms or a hydroxyalkyl group comprising from 1 to 4 carbon atoms;
  • R 4 , R 5 and R 6 which are identical or different, represent an alkyl group containing from 1 to 18 carbon atoms or a benzyl group;
  • Ri and R 2 which may be identical or different, each represent a hydrogen atom or an alkyl group containing from 1 to 6 carbon atoms;
  • X denotes a methosulfate anion or a halide such as chloride or bromide.
  • the copolymers of family (1 ) also contain one or more units deriving from comonomers that may be chosen from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides and methacrylamides which are substituted on the nitrogen with C1-C4 alkyl groups, groups derived from acrylic or methacrylic acids or esters thereof, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, and vinyl esters.
  • cationic guar gums preferably containing quaternary ammonium, such as those described in US patents 3 589 578 and 4 031 307, such as guar gums containing trialkylammonium cationic groups.
  • quaternary ammonium such as those described in US patents 3 589 578 and 4 031 307
  • guar gums containing trialkylammonium cationic groups Such products are sold in particular under the trade names Jaguar C13 S, Jaguar C 15 and Jaguar C 17 by Meyhall;
  • chitosans or salts thereof are, in particular, chitosan acetate, lactate, glutamate, gluconate or pyrrolidonecarboxylate.
  • These compounds include the chitosan having a degree of deacetylation of 90.5% by weight which is sold under the name Kytan Brut Standard by the company Aber Technologies, and the chitosan pyrrolidone carboxylate which is sold under the name Kytamer® PC by the company Amerchol;
  • cationic cellulose derivatives such as copolymers of cellulose or of cellulose derivatives grafted with a water-soluble monomer comprising a quaternary ammonium, and described in particular in patent US 4 131 576, such as hydroxyalkylcelluloses, for instance hydroxymethyl-, hydroxyethyl- or hydroxypropylcelluloses grafted in particular with a methacryloyloxyethyltrimethylammonium, methacrylamidopropyltrimethylammonium or dimethyldiallylammonium salt.
  • hydroxyalkylcelluloses for instance hydroxymethyl-, hydroxyethyl- or hydroxypropylcelluloses grafted in particular with a methacryloyloxyethyltrimethylammonium, methacrylamidopropyltrimethylammonium or dimethyldiallylammonium salt.
  • the commercial products corresponding to this definition are more particularly the products sold under the name Celquat L 200 and Celquat H 100 by the company National Starch.
  • amphoteric fixing polymers that can be used in accordance with the invention can be chosen from polymers comprising units B and C distributed randomly in the polymer chain, in which B denotes a unit derived from a monomer comprising at least one basic nitrogen atom and C denotes a unit derived from an acid monomer comprising one or more carboxylic or sulfonic groups, or alternatively B and C can denote groups derived from carboxybetaine or sulfobetaine zwitterionic monomers; B and C can also denote a cationic polymer chain comprising primary, secondary, tertiary or quaternary amine groups, in which at least one of the amine groups bears a carboxylic or sulfonic group connected via a hydrocarbon group or alternatively B and C form part of a chain of a polymer containing an ethylenedicarboxylic unit in which one of the carboxylic groups has been made to react with a polyamine comprising one or more primary or secondary amine groups.
  • amphoteric polymers corresponding to the definition given above that are more particularly preferred are chosen from the following polymers:
  • a monomer derived from a vinyl compound bearing a carboxylic group such as, more particularly, acrylic acid, methacrylic acid, maleic acid, ochloroacrylic acid
  • a basic monomer derived from a substituted vinyl compound containing at least one basic atom such as, more particularly, dialkylaminoalkyl methacrylates and acrylates, dialkylaminoalkylmethacrylamides and -acrylamides.
  • the vinyl compound may also be a dialkyldiallylammonium salt such as diethyldiallylammonium chloride.
  • At least one basic comonomer such as acrylic and methacrylic acid esters containing primary, secondary, tertiary and quaternary amine substituents, and the product of quaternization of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate.
  • N-substituted acrylamides or methacrylamides that are more particularly preferred according to the invention are groups in which the alkyl groups contain from 2 to 12 carbon atoms and more particularly N-ethylacrylamide, N-tert-butylacrylamide, N- tert-octylacrylamide, N-octylacrylamide, N-decylacrylamide, N-dodecylacrylamide and the corresponding methacrylamides.
  • the acidic comonomers are chosen more particularly from acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid and fumaric acid and alkyl monoesters, having 1 to 4 carbon atoms, of maleic or fumaric acids or anhydrides.
  • the preferred basic comonomers are aminoethyl, butylaminoethyl, N,N'-dimethylaminoethyl and N-ie f-butylaminoethyl methacrylates.
  • R 4 represents a divalent group derived from a saturated dicarboxylic acid, a mono- or dicarboxylic aliphatic acid bearing an ethylenic double bond, an ester of an alcohol containing 1 to 6 carbon atoms, of these acids, or a group derived from the addition of any one of the said acids to a bis(primary) amine or bis(secondary) derivative
  • Z denotes a group derived from a bis(primary), mono- or bis(secondary) polyalkylene polyamine and preferably represents:
  • this group being derived from diethylenetriamine, triethylenetetramine or dipropylenetriamine;
  • c) in proportions of from 0 to 20 mol%, the -NH(CH2)6-NH- group derived from hexamethylenediamine, these polyamino amines being crosslinked by addition of a difunctional crosslinking agent chosen from epihalohydrins, diepoxides, dianhydrides and bis-unsaturated derivatives, using from 0.025 to 0.35 mol of crosslinking agent per amine group of the polyamino amide and alkylated by the action of acrylic acid, chloroacetic acid or an alkane sultone, or salts thereof.
  • a difunctional crosslinking agent chosen from epihalohydrins, diepoxides, dianhydrides and bis-unsaturated derivatives
  • the saturated carboxylic acids are preferably chosen from acids having 6 to 10 carbon atoms, such as adipic acid, 2,2,4-trimethyladipic acid and 2,4,4-trimethyladipic acid, terephthalic acid, acids containing an ethylenic double bond such as, for example, acrylic acid, methacrylic acid and itaconic acid.
  • the alkane sultones used in the alkylation are preferably propane sultone or butane sultone, the salts of the alkylating agents are preferably the sodium or potassium salts.
  • R 5 denotes a polymerizable unsaturated group such as an acrylate, methacrylate, acrylamide or methacrylamide group
  • y and z each represent an integer from 1 to 3
  • R 6 and R 7 represent a hydrogen atom, a methyl, ethyl or propyl group
  • R 8 and R 9 represent a hydrogen atom or an alkyl group such that the sum of the carbon atoms in R 10 and Rn does not exceed 10.
  • the polymers comprising such units can also comprise units derived from non- zwitterionic monomers such as dimethyl- or diethylaminoethyl acrylate or methacrylate or alkyl acrylates or methacrylates, acrylamides or methacrylamides or vinyl acetate.
  • Rn , R 12 and Ri 3 each represent a hydrogen atom, as well as the salts formed by these compounds with bases or acids.
  • R 14 represents a hydrogen atom, a CH 3 0, CH 3 CH 2 0 or phenyl group
  • R-I5 denotes a hydrogen atom or a Ci -4 alkyl group such as methyl or ethyl
  • R 16 denotes a hydrogen atom or a Ci -4 alkyl group such as methyl or ethyl
  • R 17 denotes a Ci -4 alkyl group such as methyl or ethyl or a group corresponding to the formula: -Ri 8 -N(Ri 6 ) 2
  • Ri 8 representing a -CH 2 -CH 2 -, -CH 2 -CH 2 -CH 2 - or -CH 2 -CH(CH 3 )- group
  • R i6 having the meanings mentioned above, and also the higher homologues of these groups, containing up to 6 carbon atoms.
  • E or E', E or E' which may be identical or different, denote a divalent group that is an alkylene group with a straight or branched chain containing up to 7 carbon atoms in the main chain, which is unsubstituted or substituted with hydroxyl groups and which can comprise, in addition, oxygen, nitrogen and sulfur atoms and 1 to 3 aromatic and/or heterocyclic rings; the oxygen, nitrogen and sulfur atoms being present in the form of ether, thioether, sulfoxide, sulfone, sulfonium, alkylamine or alkenylamine groups, hydroxyl, benzylamine, amine oxide, quaternary ammonium, amide, imide, alcohol, ester and/or urethane groups.
  • E denotes the symbol E or E' and at least once E';
  • E having the meaning given above and E' is a divalent group that is an alkylene group with a straight or branched chain having up to 7 carbon atoms in the main chain, which is unsubstituted or substituted with one or more hydroxyl groups and containing one or more nitrogen atoms, the nitrogen atom being substituted with an alkyl chain that is optionally interrupted by an oxygen atom and necessarily comprising one or more carboxyl functions or one or more hydroxyl functions and betainized by reaction with chloroacetic acid or sodium chloroacetate.
  • These copolymers can also comprise other vinyl comonomers such as vinylcaprolactam.
  • hydrophobic blocks onto which are fixed, via polyfunctional units (c), a number of more hydrophilic blocks.
  • the amphoteric polymers have at least two glass transition temperatures (Tg), at least one of which is greater than 20°C and the other is less than 20°C.
  • the preferred amphoteric polymers are polymers comprising units derived from: a) at least one monomer chosen from acrylamides and methacrylamides substituted on the nitrogen with an alkyi group,
  • At least one basic comonomer such as acrylic and methacrylic acid esters containing primary, secondary, tertiary and quaternary amine substituents, and the product of quaternization of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate.
  • the nonionic fixing polymers that may be used according to the present invention are selected, for example, from:
  • vinyl acetate copolymers for instance copolymers of vinyl acetate and acrylic ester, copolymers of vinyl acetate and ethylene, or copolymers of vinyl acetate and maleic ester, for example dibutyl maleate,
  • styrene copolymers for instance copolymers of styrene and of an alkyi (meth)acrylate, such as the products Mowilith ® LDM 691 1 , Mowilith ® DM 61 1 and Mowilith ® LDM 6070 sold by the company Hoechst, and the products Rhodopas ® SD 215 and Rhodopas ® DS 910 sold by the company Rhone-Poulenc, copolymers of styrene, of alkyi methacrylate and of alkyi acrylate, copolymers of styrene and of butadiene, or copolymers of styrene, of butadiene and of vinylpyridine,
  • an alkyi (meth)acrylate such as the products Mowilith ® LDM 691 1 , Mowilith ® DM 61 1 and Mowilith ® LDM 6070 sold by the company Hoechst, and the
  • vinyllactam homopolymers such as vinylpyrrolidone homopolymers and such as the polyvinylcaprolactam sold under the name Luviskol ® Plus by the company BASF,
  • vinyllactam copolymers such as a poly(vinylpyrrolidone/vinyllactam) copolymer sold under the trade name Luvitec ® VPC 55K65W by the company BASF, poly(vinylpyrrolidone/vinyl acetate) copolymers, such as those sold under the name PVPVA ® S630L by the company ISP, Luviskol ® VA 73, VA 64, VA 55, VA 37 and VA 28 by the company BASF; and poly(vinylpyrrolidone/vinyl acetate/vinyl propionate) terpolymers, for instance the product sold under the name Luviskol ® VAP 343 by the company BASF, and
  • the alkyi groups of the nonionic polymers mentioned above preferably have from
  • the fixing polymer is an ionic fixing polymer, preferably an anionic fixing polymer.
  • the fixing polymer is chosen from crotonic acid copolymers.
  • the fixing polymer is chosen from crotonic acid copolymers comprising, in their chain, vinyl acetate or propionate units and optionally other monomers, such as allyl or methallyl esters, vinyl ether or vinyl ester of a linear or branched saturated carboxylic acid comprising a long hydrocarbon chain.
  • the anionic fixing polymer is a vinyl acetate/crotonic acid/vinyl neodecanoate terpolymer.
  • the fixing polymer is at least partially soluble in the styling composition.
  • the fixing polymer of the invention is soluble in the styling composition at ordinary temperature (25°C) and at atmospheric pressure (760 mmHg; i.e. 1.013 * 10 5 Pa) at a weight concentration of greater than or equal to 1 %.
  • the fixing polymer of the invention is soluble in the organic solvent(s) at ordinary temperature (25°C) and at atmospheric pressure (760 mmHg; i.e. 1.013 * 10 5 Pa) at a weight concentration of greater than or equal to 5%.
  • a "fixing polymer capable of precipitating on the hair when the styling composition is diluted with an aqueous composition” is a fixing polymer which solubility in water and at spontaneous pH is less than 0,1.
  • the fixing polymer is a fixing polymer having an anionic group
  • the fixing polymer has a degree of neutralization less than 20% in the composition, that is to say that less than 20% of the anionic sites are neutralized by an alkalinisation agent.
  • the polymer is not neutralized, that is to say that the composition used in the process according to the invention does not comprise any alkalinisation agent.
  • the fixing polymer is an anionic fixing polymer having a degree of neutralization less than 20% in the composition, and more preferably an anionic fixing polymer which is not neutralized.
  • the fixing polymer(s) according to the invention are preferably present in the styling composition in an amount ranging from 0.1 % to 30%, preferably from 0.5% to 20% and more preferably from 1 % to 15% by weight relative to the total weight of the styling composition.
  • the styling composition according to the present invention also comprises one or more organic solvents.
  • the organic solvent is chosen from liquid monoalcohols or polyols.
  • liquid means a compound that is liquid at 25°C and at atmospheric pressure (760 mmHg or 1.013x10 5 Pa).
  • Liquid monoalcohols that will be mentioned in particular include Ci -4 monoalcohols such as ethanol, isopropanol, tert-butanol or n-butanol.
  • the polyols that may be used in the styling composition according to the invention are compounds consisting of a hydrocarbon-based chain optionally interrupted with one or more oxygen atoms and bearing at least two free hydroxyl groups, and having a molecular weight of less than 1000.
  • the hydrocarbon-based chain may be linear or branched and saturated or unsaturated.
  • the hydrocarbon-based chain comprises from 3 to 50 carbon atoms and better still from 3 to 20 carbon atoms.
  • the hydrocarbon-based chain is saturated.
  • the polyols of the invention comprise 2 or 3 free hydroxyl functional groups.
  • the free hydroxyl functional groups can be carried by contiguous carbon atoms or the carbon atoms carrying them can be separated by one or more other carbon atoms.
  • Use is preferably made, among these polyols, of 1 ,2-propanediol (or propylene glycol), 1 ,3-propanediol, glycerol, 3-(2-ethylhexyl)oxy-1 ,2-propanediol (or ethylhexyl glycerol), 3-methyl-1 ,3,5-pentanetriol, 1 ,2,4-butanetriol, 1 ,5-pentanediol, 2-methyl-1 ,3- propanediol, 1 ,3-butanediol, 3-methyl-1 ,5-pentanediol, neopentyl glycol (2,2-dimethyl- 1 ,3-propanediol), isoprene glycol (3-methyl-1 ,3-butanediol) and hexylene glycol (2- methyl-2,4-pentanediol), diethylene glyco
  • the organic solvent is soluble in water at ordinary temperature (25°C) and liquid at atmospheric pressure (760 mmHg; i.e. 1.013x10 5 Pa) to a weight concentration of greater than or equal to 4%.
  • the organic solvent is preferably ethanol.
  • the organic solvent content preferably ranges from 10% to 98% by weight, preferably from 20% to 98% by weight and better still from 50% to 95% by weight relative to the total weight of the styling composition.
  • the styling composition may be aqueous or anhydrous.
  • a composition is anhydrous when it has a water content of less than 2% by weight and preferably less than 1 % by weight relative to the total weight of the composition.
  • an anhydrous composition contains no water added during the preparation of the composition, the only water present corresponding to the residual water provided by the ingredients mixed. Even more preferably, the anhydrous composition is free of water.
  • it When it is aqueous, it preferably comprises from 5% to 70% by weight of water, even more preferentially from 10% to 60% by weight of water and better still from 10% to 50% by weight of water relative to the total weight of the styling composition.
  • the styling composition is anhydrous.
  • the styling composition according to the invention may also comprise a hair- conditioning agent.
  • hair-conditioning agent means any agent whose function is to improve the cosmetic properties of the hair, in particular the softness, sheen, disentangling, feel, smoothness or static electricity.
  • the conditioning agents may be in liquid, semi-solid or solid form, for instance oils, waxes or gums.
  • the conditioning agents may be chosen from fatty substances such as C 6 -Ci 6 hydrocarbons or hydrocarbons containing more than 16 carbon atoms and in particular alkanes, oils of animal origin, oils of plant origin, glycerides or fluoro oils of synthetic origin, fatty alcohols, fatty acid and/or fatty alcohol esters, non-silicone waxes, silicones, fatty amines, fatty acids, cationic polymers, amphoteric polymers, cationic proteins, cationic protein hydrolysates, compounds of ceramide type, cationic surfactants, and also mixtures of these various compounds.
  • fatty substances such as C 6 -Ci 6 hydrocarbons or hydrocarbons containing more than 16 carbon atoms and in particular alkanes, oils of animal origin, oils of plant origin, glycerides or fluoro oils of synthetic origin, fatty alcohols, fatty acid and/or fatty alcohol esters, non-silicone waxes, silicones, fatty amines,
  • the styling composition according to the invention may also comprise one or more thickeners.
  • the term "thickener” means an agent which, by virtue of its presence in the styling composition, makes it possible to increase the viscosity of the said composition by at least 10 cPs and preferably by at least 200 cPs, at 25°C and at a shear rate of 1 s ' This viscosity may be measured using a cone/plate viscometer (Haake R600 rheometer or the like).
  • the thickener(s) may be chosen from fatty acid amides obtained from Ci 0 -C 30 carboxylic acid (monoisopropanolamide, diethanolamide or monoethanolamide of coconut acids, monoethanolamide of ethoxylated carboxylic alkyl ether acid), polymeric thickeners and in particular nonionic cellulose-based polymers (hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose), starches, gum arabic, gums of microbial origin (scleroglucan gum, xanthan gum), gums of galactomannan type (guar gum, locust bean gum, fenugreek gum, tara gum) and derivatives thereof (guar phosphate, hydroxypropyl guar), glucomannans (konjac gum), crosslinked or non- crosslinked homopolymers and copolymers based on acrylic acid, methacrylic acid or acrylamidopropanesulfonic acid, and associative polymers as described below, and mixture
  • the associative polymer(s) that may be used according to the invention are water-soluble polymers that are capable, in aqueous medium, of reversibly associating with each other or with other molecules.
  • Their chemical structure comprises hydrophilic zones and hydrophobic zones characterized by at least one fatty chain preferably comprising from 10 to 30 carbon atoms.
  • the associative polymer(s) that may be used according to the invention may be of anionic, cationic, amphoteric or nonionic type, such as the polymers sold under the names Pemulen TR1 or TR2 by the company Goodrich (INCI: Acrylates/C 10-30 Alkyl Acrylate Crosspolymer), Salcare SC90 by the company Ciba, Aculyn 22, 28, 33, 44 or 46 by the company Rohm & Haas and Elfacos T210 and T212 by the company Akzo.
  • Pemulen TR1 or TR2 by the company Goodrich (INCI: Acrylates/C 10-30 Alkyl Acrylate Crosspolymer), Salcare SC90 by the company Ciba, Aculyn 22, 28, 33, 44 or 46 by the company Rohm & Haas and Elfacos T210 and T212 by the company Akzo.
  • the additional thickener(s) are preferably chosen from polymers, and better still from nonionic cellulose-based polymers, especially hydroxypropylcellulose and gum arabic.
  • the additional thickeners may be present in the styling composition in an amount ranging from 0.01 % to 20% by weight and better still from 0.1 % to 10% by weight relative to the total weight of the styling composition.
  • the pH of the styling compositions used according to the invention generally ranges from 2 to 1 1 , preferably from 3 to 6.5 and even more preferentially from 4 to 6.
  • the styling composition according to the invention may contain active agents conventionally used in non-lasting hair shaping other than those described previously, and chosen from nonionic surfactants, anionic surfactants, amphoteric surfactants, direct dyes, in particular cationic or natural dyes or oxidation dyes, organic or mineral pigments, UV-screening agents, fillers, especially nacres, Ti0 2 , clays, fragrances, peptizers, vitamins, amino acids, preserving agents, pH agents, agents for long-lasting shaping of the hair, especially thiol-based organic reducing agents, non-thiol-based organic reducing agents, etc.
  • the styling compositions are in the form of gels.
  • the styling compositions have a viscosity of greater than or equal to 4 Pa.s and better still ranging from 4 Pa.s to 500 Pa.s at a temperature of 25°C and at a shear rate of 1 s "1 (measurable, for example, with a Haake RS600 rheometer).
  • washing composition that may be used in accordance with the invention comprises one or more surfactants.
  • the surfactants may be chosen from anionic, nonionic, amphoteric or zwitterionic surfactants, and mixtures thereof.
  • nonionic surfactants that may be used in the washing compositions in accordance with the present invention are compounds that are well known per se (see in particular in this respect the Handbook of Surfactants by M.R. Porter, published by Blackie & Son (Glasgow and London), 1991 , pp. 1 16-178).
  • polyethoxylated, polypropoxylated or polyglycerolated fatty alcohols polyethoxylated, polypropoxylated or polyglycerolated a-diols, or polyethoxylated, polypropoxylated or polyglycerolated (Ci_ 2 o)alkylphenols
  • the fatty chain comprising, for example, from 10 to 20 carbon atoms and preferably from 16 to 18 carbon atoms, the number of ethylene oxide or propylene oxide groups possibly ranging especially from 1 to 150 and the number of glycerol groups possibly ranging especially from 1 to 30.
  • polyethoxylated fatty amides preferably having from 1 to 100 ethylene oxide units, polyg
  • the alkyl polyglucosides may be selected, for example, from decyl glucoside ((C 9 /C11 alkyl) (1 ,4) polyglucoside), such as the product sold under the name Mydol 10 ® by the company Kao Chemicals or the product sold under the name Plantacare 2000 UP ® by the company Henkel and the product sold under the name Oramix NS 10 ® by the company SEPPIC; caprylyl/capryl glucoside, such as the product sold under the name Plantacare KE 371 1 ® by the company Cognis or Oramix CG 1 10 ® by the company SEPPIC; lauryl glucoside, such as the product sold under the name Plantacare 1200 UP ® by the company Henkel or Plantaren 1200 N ® by the company Henkel; coco glucoside, such as the product sold under the name Plantacare 818 UP ® by the company Henkel; caprylyl glucoside, such as the product
  • alkyi sulfates alkyi ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkylsulfonates, alkylamidesulfonates, alkylarylsulfonates, oolefinsulfonates, paraffin sulfonates, alkyi sulfosuccinates, alkyi ether sulfosuccinates, alkylamide sulfosuccinates, alkyi sulfoacetates, acyl sarcosinates, acyl glutamates, alkyi ether carboxylates, alkyi sulfosuccinamates, acyl isethionates and N-acyl taurates; monoalkyl esters of polyg
  • These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units and better still from 1 to 10 ethylene oxide units.
  • the salts of C6-C24 alkyi monoesters of polyglycoside-polycarboxylic acids may be chosen from C6-C24 alkyi polyglycoside-citrates, C6-C24 alkyi polyglycoside- tartrates and C6-C24 alkyi polyglycoside-sulfosuccinates.
  • the acyl lactylates preferably have an acyl group comprising from 8 to 20 carbon atoms.
  • the anionic surfactant when in the salt form, it may be chosen from the alkali metal salts, such as the sodium salt or potassium salt, the ammonium salts, the amine salts and in particular the amino alcohol salts, or the alkaline-earth metal salts, such as the magnesium salt.
  • the alkali metal salts such as the sodium salt or potassium salt
  • the ammonium salts such as the sodium salt or potassium salt
  • the amine salts and in particular the amino alcohol salts
  • the alkaline-earth metal salts such as the magnesium salt.
  • Use is preferably made of alkali metal or alkaline-earth metal salts, in particular sodium or magnesium salts.
  • the preferred anionic surfactants are chosen from (C6-24)alkyl sulfates, (C6-
  • (C12-20)alkyl sulfates (C12-20)alkyl ether sulfates comprising from 2 to 20 ethylene oxide units, acyl glutamates or (C12- C20)alkyl ether carboxylates, especially in the form of alkali metal, ammonium, amino alcohol and alkaline-earth metal salts, or a mixture of these compounds.
  • amphoteric or zwitterionic surfactants capable of being used in the present invention can in particular be derivatives of optionally quaternized secondary or tertiary aliphatic amines comprising at least one anionic group, such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group, and in which the aliphatic group or at least one of the aliphatic groups is a linear or branched chain comprising from 8 to 22 carbon atoms.
  • C 2 o)alkylamido(Ci-C 6 )alkyl betaines such as cocoamidopropyl betaine, or (C 8 - C 2 o)alkylamido(Ci-C 6 )alkyl sulfobetaines.
  • Ra represents a C10-C30 alkyl or alkenyl group derived from an acid Ra-COOH preferably present in hydrolysed coconut oil, a heptyl group, a nonyl group or an undecyl group,
  • Rb represents a ⁇ -hydroxyethyl group
  • Rc represents a carboxymethyl group
  • X' represents the group -CH 2 -COOH, CH 2 -COOZ', -CH 2 CH 2 -COOH, -CH 2 CH 2 - COOZ', or a hydrogen atom
  • Y' represents -COOH, -COOZ', the group -CH 2 -CHOH-S0 3 H or -CH 2 -CHOH- S0 3 Z',
  • Z' represents an ion resulting from an alkali or alkaline-earth metal, such as sodium, potassium or magnesium; an ammonium ion; or an ion resulting from an organic amine and in particular from an amino alcohol, such as monoethanolamine, diethanolamine and triethanolamine, monoisopropanolamine, diisopropanolamine or triisopropanolamine, 2-amino-2-methyl-1 -propanol, 2-amino-2-methyl-1 ,3-propanediol and tris(hydroxymethyl)aminomethane,
  • an alkali or alkaline-earth metal such as sodium, potassium or magnesium
  • an ammonium ion or an ion resulting from an organic amine and in particular from an amino alcohol, such as monoethanolamine, diethanolamine and triethanolamine, monoisopropanolamine, diisopropanolamine or triisopropanolamine, 2-amino-2-methyl-1 -propanol, 2-
  • Ra' represents a C10-C30 alkyl or alkenyl group of an acid Ra'COOH preferably present in hydrolysed coconut oil or hydrolysed linseed oil, an alkyl group, in particular a C17 alkyl group, and its iso form, or an unsaturated C17 group.
  • the compounds corresponding to formula (A2) are preferred. These compounds are also classified in the CTFA dictionary, 5th edition, 1993, under the names disodium cocoamphodiacetate, disodium lauroamphodiacetate, disodium caprylamphodiacetate, disodium capryloamphodiacetate, disodium cocoamphodipropionate, disodium lauroamphodipropionate, disodium caprylamphodipropionate, disodium capryloamphodipropionate, lauroamphodipropionic acid and cocoamphodipropionic acid.
  • cocoamphodiacetate sold by the company Rhodia under the trade name Miranol ® C2M Concentrate.
  • ⁇ Y" represents the group -C(O)OH, -C(O)OZ", -CH 2 -CH(OH)-SO 3 H or the group -CH 2 -CH(OH)-SO 3 -Z";
  • Rd and Re independently of each other, represent a Ci-C 4 alkyl or hydroxyalkyl radical
  • Z represents a cationic counterion derived from an alkali metal or alkaline- earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine;
  • Ra represents a C10-C30 alkyl or alkenyl group derived from an acid, Ra"-C(0)OH preferably present in coconut oil or in hydrolysed linseed oil;
  • n and n' independently of each other, denote an integer ranging from 1 to 3.
  • the compounds of formula (A3) mention may be made of the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and sold by the company Chimex under the name Chimexane HB.
  • amphoteric or zwitterionic surfactants are chosen from (C 8 - C 2 o)alkyl betaines, (C 8 -C2o)alkylamido(Ci-C 6 )alkyl betaines and (C 8 - C 2 o)alkylamphodiacetates, and also the sodium salt of diethylaminopropyl laurylaminosuccinamate, and mixtures thereof.
  • amphoteric or zwitterionic surfactants are chosen, alone or as a mixture, from cocoylamidopropyl betaine, cocoyl betaine and cocoamphodiacetate.
  • the surfactant(s) of the washing composition are preferably chosen from anionic surfactants and amphoteric surfactants. Even more preferentially, they are chosen from anionic surfactants, preferably from alkyl ether sulfates, alkyl sulfates and acyl isethionates, the anionic surfactants optionally being combined with one or more amphoteric surfactants.
  • the surfactant(s) are preferably present in the washing composition in an amount ranging from 4% to 50% by weight, preferably from 6% to 40% by weight and more preferentially from 8% to 30% by weight relative to the total weight of the washing composition.
  • the washing composition used according to the invention may also comprise one or more conditioning agents such as those described and defined previously for the styling composition.
  • the washing composition may preferably comprise a cationic polymer and/or a silicone.
  • cationic polymer means any polymer comprising cationic groups and/or groups that can be ionized to cationic groups.
  • the cationic polymer is hydrophilic or amphiphilic.
  • the cationic polymers may be chosen from all those already known per se as improving the cosmetic properties of the hair, i.e. especially those described in documents EP 337 354, FR 2 270 846, FR 2 383 660, FR 2 598 61 1 , FR 2 470 596 and FR 2 519 863.
  • the preferred cationic polymers are chosen from those that contain units comprising primary, secondary, tertiary and/or quaternary amine groups that may either form part of the main polymer chain or may be borne by a side substituent directly connected thereto.
  • the cationic polymers that may be used preferably have a weight-average molar mass (Mw) of between 500 and 5 ⁇ 10 6 approximately and preferably between 10 3 and 3x10 6 approximately.
  • cationic polymers mention may more particularly be made of polymers of the polyamine, polyaminoamide and polyquaternary ammonium type, such as those described in FR 2 505 348 and FR 2 542 997.
  • R3 which may be identical or different, denote a hydrogen atom or a CH 3 radical
  • - A which may be identical or different, represent a linear or branched divalent alkyi group of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms, or a hydroxyalkyi group of 1 to 4 carbon atoms;
  • R4 - R4, R5 and R6, which may be identical or different, represent an alkyi group containing from 1 to 18 carbon atoms or a benzyl radical, preferably an alkyi group containing from 1 to 6 carbon atoms;
  • R1 and R2 which may be identical or different, represent a hydrogen atom or an alkyi group containing from 1 to 6 carbon atoms, preferably methyl or ethyl;
  • - X denotes an anion derived from a mineral or organic acid, such as a methosulfate anion or a halide such as chloride or bromide.
  • the copolymers of family (1 ) may also contain one or more units derived from comonomers that may be selected from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides and methacrylamides substituted on the nitrogen with lower (CrC 4 ) alkyls, acrylic or methacrylic acids or esters thereof, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, and vinyl esters.
  • comonomers may be selected from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides and methacrylamides substituted on the nitrogen with lower (CrC 4 ) alkyls, acrylic or methacrylic acids or esters thereof, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, and vinyl esters.
  • comonomers may be selected from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides
  • crosslinked polymers of methacryloyloxy(Ci-C 4 )alkyltri(Ci- C 4 )alkylammonium salts such as the polymers obtained by homopolymerization of dimethylaminoethyl methacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethyl methacrylate quaternized with methyl chloride, the homopolymerization or copolymerization being followed by crosslinking with an olefinically unsaturated compound, more particularly methylenebisacrylamide.
  • a crosslinked acrylamide/methac loyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) in the form of a dispersion containing 50% by weight of the said copolymer in mineral oil may be used more particularly.
  • This dispersion is sold under the name Salcare® SC 92 by the company Ciba.
  • a crosslinked methacryloyloxyethyltrimethylammonium chloride homopolymer containing about 50% by weight of the homopolymer in mineral oil or in a liquid ester can also be used.
  • These dispersions are sold under the names Salcare® SC 95 and Salcare® SC 96 by the company Ciba.
  • Cationic polysaccharides especially cationic celluloses and galactomannan gums.
  • cationic polysaccharides mention may be made more particularly of cellulose ether derivatives comprising quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums.
  • the cellulose ether derivatives comprising quaternary ammonium groups are especially described in French patent 1 492 597, and mention may be made of the polymers sold under the name Ucare Polymer "JR" (JR 400 LT, JR 125 and JR 30M) or "LR” (LR 400 or LR 30M) by the company Amerchol. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose that have reacted with an epoxide substituted with a trimethylammonium group.
  • Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer are described especially in US patent 4 131 576, and mention may be made of hydroxyalkylcelluloses, for instance hydroxymethyl-, hydroxyethyl- or hydroxypropylcelluloses grafted, in particular, with a methacryloylethyltrimethylammonium, methacrylamidopropyltrimethylammonium or dimethyldiallylammonium salt.
  • the commercial products corresponding to this definition are more particularly the products sold under the names Celquat L 200 and Celquat H 100 by the company National Starch.
  • guar gums comprising cationic trialkylammonium groups.
  • Use is made, for example, of guar gums modified with a 2,3- epoxypropyltrimethylammonium salt (for example, chloride).
  • a 2,3- epoxypropyltrimethylammonium salt for example, chloride.
  • Such products are especially sold under the names Jaguar C13 S, Jaguar C 15, Jaguar C 17 or Jaguar C162 by the company Rhodia.
  • Water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides can be crosslinked with an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis- unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-alkyl halide or alternatively with an oligomer resulting from the reaction of a difunctional compound which is reactive with a bis-halohydrin, a bis-azetidinium, a bis- haloacyldiamine, a bis-alkyl halide, an epihalohydrin, a diepoxide or a bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mol per amine group of the polyaminoamide; these polyaminoamide
  • Polyamino amide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation with bifunctional agents Mention may be made, for example, of adipic acid/dialkylaminohydroxyalkyldialkylenetriamine polymers in which the alkyl radical comprises from 1 to 4 carbon atoms and preferably denotes methyl, ethyl or propyl. Such polymers are described in particular in FR 1 583 363.
  • Such polymers are especially described in US 3 227 615 and US 2 961 347.
  • Polymers of this type are sold in particular under the name Hercosett 57 by the company Hercules Inc. or alternatively under the name PD 170 or Delsette 101 by the company Hercules in the case of the adipic acid/epoxypropyl/diethylenetriamine copolymer.
  • Cyclopolymers of alkyldiallylamine or of dialkyldiallylammonium such as homopolymers or copolymers containing, as main constituent of the chain, units corresponding to formula (X) or (XI):
  • R12 denotes a hydrogen atom or a methyl radical
  • R10 and R1 1 independently of each other, denote an alkyl group containing from 1 to 6 carbon atoms, a hydroxyalkyi group in which the alkyl group contains 1 to 5 carbon atoms, a C1 -C4 amidoalkyl group; or alternatively R10 and R1 1 may denote, together with the nitrogen atom to which they are attached, heterocyclic groups such as piperidinyl or morpholinyl; R10 and R1 1 , independently of each other, preferably denote an alkyl group containing from 1 to 4 carbon atoms;
  • - Y " is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate or phosphate.
  • R13, R14, R15 and R16 which may be identical or different, represent aliphatic, alicyclic or arylaliphatic radicals comprising from 1 to 20 carbon atoms, or lower hydroxyalkylaliphatic radicals, or else R13, R14, R15 and R16, together or separately, constitute, with the nitrogen atoms to which they are attached, heterocycles optionally comprising a second non-nitrogen heteroatom, or else R13, R14, R15 and R16 represent a linear or branched Ci-C 6 alkyl radical substituted with a nitrile, ester, acyl, amide or -CO-0-R17-D or -CO-NH-R17-D group in which R17 is an alkylene and D is a quaternary ammonium group;
  • A1 and B1 represent divalent polymethylene groups comprising from 2 to 20 carbon atoms, which may be linear or branched, saturated or unsaturated, and which may contain, linked to or intercalated in the main chain, one or more aromatic rings or one or more oxygen or sulfur atoms or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and
  • A1 , R13 and R15 can form, with the two nitrogen atoms to which they are attached, a piperazine ring;
  • A1 denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical
  • B1 may also denote a group (CH 2 )n-CO-D-OC-(CH2) n - in which D denotes:
  • a glycol residue of formula -0-Z-0- in which Z denotes a linear or branched hydrocarbon-based radical, or a group corresponding to one of the following formulae: -(CH 2 -CH 2 -0) x -CH 2 -CH 2 - and -[CH 2 -CH(CH 3 )-0] y -CH 2 -CH(CH 3 )-, where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from 1 to 4 representing an average degree of polymerization;
  • a bis-secondary diamine residue such as a piperazine derivative
  • X " is an anion such as chloride or bromide.
  • These polymers have a number-average molar mass (Mn) generally of between 1000 and 100 000.
  • R1 , R2, R3 and R4 which may be identical or different, denote an alkyl or hydroxyalkyi radical containing from 1 to 4 carbon atoms approximately, n and p are integers ranging from 2 to 20 approximately, and X " is an anion derived from an organic or mineral acid.
  • R18, R19, R20 and R21 which may be identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, ⁇ -hydroxyethyl, ⁇ -hydroxypropyl or - CH2CH2(OCH2CH 2 )pOH radical, in which p is equal to 0 or to an integer between 1 and 6, with the proviso that R18, R19, R20 and R21 do not simultaneously represent hydrogen atom,
  • - r and s which may be identical or different, are integers between 1 and 6,
  • X- denotes an anion such as a halide
  • - A denotes a dihalide radical or preferably represents -CH2-CH2-O-CH2-CH2-.
  • Such compounds are described in particular in patent application EP-A-122 324. Examples that may be mentioned include the products Mirapol® A15, Mirapol® AD1 , Mirapol® AZ1 and Mirapol® 175 sold by the company Miranol.
  • these polymers may be chosen especially from homopolymers or copolymers comprising one or more units derived from vinylamine and optionally one or more units derived from vinylformamide.
  • these cationic polymers are chosen from polymers comprising, in their structure, from 5 mol% to 100 mol% of units corresponding to formula (A) and from 0 to 95 mol% of units corresponding to formula (B), preferentially from 10 mol% to 100 mol% of units corresponding to formula (A) and from 0 to 90 mol% of units corresponding to formula (B).
  • These polymers may be obtained, for example, by partial hydrolysis of polyvinylformamide. This hydrolysis may be performed in an acidic or basic medium.
  • the weight-average molecular mass of the said polymer measured by light scattering, may range from 1000 to 3 000 000 g/mol, preferably from 10 000 to 1 000 000 g/mol and more particularly from 100 000 to 500 000 g/mol.
  • the cationic charge density of these polymers may range from 2 meq/g to 20 meq/g, preferably from 2.5 to 15 meq/g and more particularly from 3.5 to 10 meq/g.
  • the polymers comprising units of formula (A) and optionally units of formula (B) are sold especially under the name Lupamin by the company BASF, for instance, and in a non-limiting manner, the products sold under the names Lupamin 9095, Lupamin 5095, Lupamin 1095, Lupamin 9030 and Lupamin 9010.
  • cationic polymers that may be used in the context of the invention are cationic proteins or cationic protein hydrolysates, polyalkyleneimines, in particular polyethyleneimines, polymers comprising vinylpyridine or vinylpyridinium units, condensates of polyamines and of epichlorohydrin, quaternary polyureylenes and chitin derivatives.
  • the cationic polymers are chosen from the polymers of families (1 ), (2), (7) and (10) mentioned above.
  • cationic polysaccharides especially cationic celluloses and galactomannan gums, and in particular quaternary cellulose ether derivatives such as the products sold under the name "JR 400" by the company Amerchol
  • cationic cyclopolymers in particular dimethyldiallylammonium salt (for example chloride) homopolymers or copolymers, sold under the names Merquat 100, Merquat 550 and Merquat S by the company Nalco, and homologues thereof of low weight-average molecular weights
  • quaternary polymers of vinylpyrrolidone and of vinylimidazole optionally crosslinked homopolymers or copolymers of methacryloyloxy(Ci-C4)alkyltri(Ci-C4)alkylammonium salts, and mixtures thereof.
  • Volatile silicones These silicones have a boiling point of between 60°C and 260°C. Among the silicones of this type that are mentioned are:
  • cyclic silicones comprising from 3 to 7 and preferably 4 to 5 silicon atoms.
  • Volatile Silicone 7207® by the company Union Carbide or Silbione 70045 V2® by the company Rhone-Poulenc decamethylcyclopentasiloxane sold under the name Volatile Silicone 7158® by the company Union Carbide, and Silbione 70045 V5® by the company Rhone-Poulenc, and mixtures thereof. Mention is also made of cyclopolymers of the dimethylsiloxane/methylalkylsiloxane type, such as Volatile Silicone FZ 3109® sold by the company Union Carbide, which is a dimethylsiloxane/methyloctylsiloxane cyclocopolymer;
  • silicones are mainly constituted by polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes and organomodified polysiloxanes, and also mixtures thereof. They may be in the form of oils, gums and resins.
  • polyalkylsiloxanes mention may be made mainly of linear polydimethylsiloxanes with a viscosity of greater than 5 ⁇ 10 "6 m 2 /s, and preferably less than 2.6 m 2 /s, i.e.:
  • polyalkylsiloxanes sold by the company Goldschmidt under the names Abil Wax 9800® and Abil Wax 9801®, which are poly(C1 -20)alkylsiloxanes.
  • polyalkylarylsiloxanes mention may be made of linear and/or branched polydimethylphenylsiloxanes and polydimethyldiphenylsiloxanes, with a viscosity from 10 "5 to 5x10 "2 m 2 /s, for instance:
  • the Silbione® oils of the 70641 series from Rhone-Poulenc such as the oils Silbione 70641 V30® and Silbione 70641 V200®,
  • oils of the SF series from General Electric such as SF 1250®, SF 1265®, SF 1 154® and SF 1023®.
  • the silicone gums in accordance with the present invention are polydiorganosiloxanes with a high number-average molecular weight of between 200 000 and 1 000 000, used alone or as a mixture in a solvent chosen from volatile silicones, polydimethylsiloxane (PDMS) oils, polyphenylmethylsiloxane (PPMS) oils, isoparaffins, methylene chloride, pentane, dodecane, tridecane and tetradecane, or mixtures thereof.
  • PDMS polydimethylsiloxane
  • PPMS polyphenylmethylsiloxane
  • isoparaffins methylene chloride
  • pentane dodecane
  • tridecane and tetradecane or mixtures thereof.
  • Mention may be made of the gum Mirasil DM 300 000 from the company Rhodia.
  • the product SF 1236® is the mixture of an SE 30® gum defined above, with a viscosity of 20 m 2 /s, and of an SF 96® oil with a viscosity of 5x10 6 m 2 /s (15% SE 30® gum and 85% SF 96® oil).
  • the product CF 1241® is the mixture of an SE 30® gum (33%) and of a PDMS (67%), with a viscosity of 10 "3 m 2 /s.
  • the organopolysiloxane resins that may be used in accordance with the invention are crosslinked siloxane systems containing the following units: R2Si02/2, RSi03/2 and Si04/2 in which R represents a hydrocarbon-based group containing 1 to 6 carbon atoms or a phenyl group.
  • R represents a hydrocarbon-based group containing 1 to 6 carbon atoms or a phenyl group.
  • R denotes a lower alkyl radical or a phenyl radical.
  • organomodified silicones in accordance with the present invention are silicones as defined above, comprising in their general structure one or more organofunctional groups directly attached to the siloxane chain or attached via a hydrocarbon-based radical.
  • silicones comprising:
  • perfluoro groups such as trifluoroalkyls, for instance those sold by the company General Electric under the names FF.150 Fluorosilicone Fluid® or by the company Shin-Etsu under the names X-22-819®, X-22-82®, X-22-821 ® and X-22-822®;
  • hydroxyacylamino groups for instance those described in patent application EP 0 342 834 and in particular the silicone sold by the company Dow Corning under the name Q2-8413®;
  • non-quaternized amine groups as in GP 4 Silicone Fluid® from Genesee, GP 7100® from Genesee, Q2 8220® from Dow Corning, AFL 40® from Union Carbide or the silicone known as Amodimethicone in the CTFA dictionary; e) carboxylate groups, for instance the products described in patent EP 186 507 from Chisso Corporation;
  • hydroxylated groups such as the polyorganosiloxanes containing a C2- C18 hydroxyalkyi function, described, for example, in patent application FR 85/16334;
  • polyethyleneoxy and/or polypropyleneoxy groups optionally comprising C6-C24 alkyl groups, such as the products known as dimethicone copolyol sold by the company Dow Corning under the name DC 1248 or the oils Silwet L 722, L 7500, L 77 and L 71 1 by the company Union Carbide, and the (C12)alkylmethicone copolyol sold by the company Dow Corning under the name Q2 5200.
  • silicones comprising a polysiloxane portion and a portion formed from a non-silicone organic chain, one of the two portions forming the main chain of the polymer and the other being grafted onto the said main chain, may also be used.
  • These polymers are described, for example, in patent applications EP-A- 412 704, EP-A-412 707, EP-A-640 105 and WO 95/00578, EP-A-582 152 and WO 93/23009 and patents US 4 693 935, US 4 728 571 and US 4 972 037.
  • These polymers are preferably anionic or nonionic.
  • Such polymers are, for example, copolymers that may be obtained by free-radical polymerization from the monomer mixture formed from:
  • v being a number ranging from 5 to 700; the weight percentages being calculated relative to the total weight of the monomers.
  • grafted silicone polymers are especially polydimethylsiloxanes (PDMS) onto which are grafted, via a connecting unit of thiopropylene type, mixed polymer units of the poly(meth)acrylic acid type and of the polyalkyl (meth)acrylate type and polydimethylsiloxanes (PDMS) onto which are grafted, via a connecting unit of thiopropylene type, polymer units of the polyisobutyl (meth)acrylate type.
  • PDMS polydimethylsiloxanes
  • silicones may also be used in the form of emulsions, nanoemulsions or microemulsions.
  • the polyorganosiloxanes that are particularly preferred in accordance with the invention are:
  • non-volatile silicones chosen from the family of polydialkylsiloxanes containing trimethylsilyl end groups, such as oils with a viscosity of between 0.2 and 2.5 m 2 /s at 25°C, such as the oils of the series DC200 from Dow Corning, in particular the product with a viscosity of 60 000 cSt, of the series Silbione 70047, and more particularly the oil 70 047 V 500 000 sold by the company Rhodia Chimie, polydialkylsiloxanes containing dimethylsilanol end groups such as dimethiconols, or polyalkylarylsiloxanes such as the oil Silbione 70641 V 200 sold by the company Rhodia Chimie;
  • the viscosities of the silicones may especially be determined by the standard ASTM D445-97 (viscometry).
  • the care composition that may be used in accordance with the invention comprises one or more conditioning agents such as those described and defined previously which the washing composition may comprise.
  • the care composition may also comprise one or more cationic surfactants.
  • the cationic surfactant(s) that may be used in the care composition comprise, for example, salts of optionally polyoxyalkylenated primary, secondary or tertiary fatty amines, quaternary ammonium salts, and mixtures thereof.
  • quaternary ammonium salts examples include:
  • radicals R8 to R1 1 which may be identical or different, represent a linear or branched aliphatic radical comprising from 1 to 30 carbon atoms or an aromatic radical such as aryl or alkylaryl, at least one of the radicals R8 to R1 1 comprising from 8 to 30 carbon atoms and preferably from 12 to 24 carbon atoms.
  • the aliphatic radicals may comprise heteroatoms especially such as oxygen, nitrogen, sulfur and halogens.
  • the aliphatic radicals are chosen, for example, from C1 -C30 alkyl, C1 -C30 alkoxy, polyoxy(C2-C6)alkylene, C1 -C30 alkylamide, (C12-C22)alkylamido(C2-C6)alkyl and C1 -C30 hydroxyalkyl radicals, and X " is an anion chosen from the group of halides, phosphates, acetates, lactates, (C1 -C4)alkyl sulfates, and (C1 -C4)alkyl- or (C1 - C4)alkylaryl-sulfonates.
  • tetraalkylammonium chlorides for instance dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl radical comprises approximately from 12 to 22 carbon atoms, in particular behenyltrimethylammonium, distearyldimethylammonium, cetyltrimethylammonium, dicetyldimethylammonium and benzyldimethylstearylammonium chlorides, or else, secondly, to palmitylamidopropyltrimethylammonium chloride or stearamidopropyldimethyl(myristyl acetate)ammonium chloride, which is sold under the name Ceraphyl® 70 by the company Van Dyk.
  • R12 represents an alkyl or alkenyl radical comprising from 8 to 30 carbon atoms, for example fatty acid derivatives of tallow
  • R13 represents a hydrogen atom, a C1 -C4 alkyl radical or an alkyl or alkenyl radical comprising from 8 to 30 carbon atoms
  • R14 represents a C1 -C4 alkyl radical
  • R15 represents a hydrogen atom or a C1 -C4 alkyl radical
  • X- is an anion chosen from the group of halides, phosphates, acetates, lactates, (C1 -C4)alkyl sulfates and (C1 -C4)alkyl- or (C1 -C4)alkylaryl- sulfonates.
  • R12 and R13 denote a mixture of alkenyl or alkyl radicals comprising from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl radical and R15 denotes a hydrogen atom.
  • R12 and R13 denote a mixture of alkenyl or alkyl radicals comprising from 12 to 21 carbon atoms, for example fatty acid derivatives of tallow, R14 denotes a methyl radical and R15 denotes a hydrogen atom.
  • Such a product is sold, for example, under the name Varisoft W 575 PG N by the company Evonik Goldschmidt; - quaternary diammonium or triammonium salts, particularly of formula (XVIII) below:
  • R16 denotes an alkyl radical comprising about 16 to 30 carbon atoms, optionally hydroxylated and/or interrupted with one or more oxygen atoms
  • R17 is chosen from hydrogen, an alkyl radical comprising from 1 to 4 carbon atoms or a group -(CH2)3-N+(R16a)(R17a)(R18a);
  • R16a, R17a, R18a, R18, R19, R20 and R21 which may be identical or different, are chosen from hydrogen and an alkyl radical comprising from 1 to 4 carbon atoms
  • X- is an anion chosen from the group of halides, acetates, phosphates, nitrates, (C1 -C4)alkyl sulfates and (C1 -C4)alkyl- or (C1 - C4)alkylaryl-sulfonates, in particular methyl sulfate and ethyl sulfate.
  • Such compounds are, for example, R
  • R22 is chosen from C1 -C6 alkyl radicals and C1 -C6 hydroxyalkyl or dihydroxyalkyl radicals;
  • R23 is chosen from:
  • R25 is chosen from:
  • radical R 28 C— - saturated or unsaturated, linear or branched C1 -C6 hydrocarbon-based radicals
  • R24, R26 and R28 which are identical or different, are chosen from linear or branched, saturated or unsaturated C7-C21 hydrocarbon-based radicals,
  • r, s and t which may be identical or different, are integers ranging from 2 to 6, r1 and t1 , which may be identical or different, are equal to 0 or 1 ,
  • y is an integer ranging from 1 to 10;
  • x and z which may be identical or different, are integers ranging from 0 to 10;
  • X " is a simple or complex, organic or mineral anion; with the proviso that the sum x + y + z is from 1 to 15, that when x is 0, then R23 denotes R27 and that when z is 0, then R25 denotes R29.
  • the alkyl radicals R22 may be linear or branched, and more particularly linear.
  • R22 preferably denotes a methyl, ethyl, hydroxyethyl or dihydroxypropyl radical, and more particularly a methyl or ethyl radical.
  • the sum x + y + z is from 1 to 10.
  • R23 is a hydrocarbon-based radical R27, it may be long and may contain from 12 to 22 carbon atoms, or may be short and may contain from 1 to 3 carbon atoms.
  • R25 is a hydrocarbon-based radical R29, it preferably contains 1 to 3 carbon atoms.
  • R24, R26 and R28 which may be identical or different, are chosen from linear or branched, saturated or unsaturated C1 1 -C21 hydrocarbon-based radicals, and more particularly from linear or branched, saturated or unsaturated C1 1 - C21 alkyl and alkenyl radicals.
  • x and z which may be identical or different, are equal to 0 or 1 .
  • y is equal to 1 .
  • r, s and t which may be identical or different, are equal to 2 or 3, and even more particularly are equal to 2.
  • the anion X- is preferably a halide, preferably chloride, bromide or iodide, a (C1 - C4)alkyl sulfate or a (C1 -C4)alkyl- or (C1 -C4)alkylaryl-sulfonate.
  • a halide preferably chloride, bromide or iodide
  • a (C1 - C4)alkyl sulfate or a (C1 -C4)alkyl- or (C1 -C4)alkylaryl-sulfonate preferably a halide, preferably chloride, bromide or iodide, a (C1 - C4)alkyl sulfate or a (C1 -C4)alkyl- or (C1 -C4)alkylaryl-sulfonate.
  • methanesulfonate, phosphate, nitrate, tosylate an anion derived
  • the anion X- is even more particularly chloride, methyl sulfate or ethyl sulfate.
  • R22 denotes a methyl or ethyl radical
  • - z is equal to 0 or 1 ;
  • - R23 is chosen from:
  • - R25 is chosen from:
  • R24, R26 and R28 which may be identical or different, are selected from linear or branched, saturated or unsaturated C13-C17 hydrocarbon-based radicals, and preferably from linear or branched, saturated or unsaturated C13-C17 alkyl and alkenyl radicals.
  • hydrocarbon-based radicals are linear.
  • examples that may be mentioned include salts, especially the chloride or methyl sulfate of diacyloxyethyldimethylammonium, diacyloxyethylhydroxyethylmethylammonium,
  • acyl radicals preferably contain 14 to 18 carbon atoms and are obtained more particularly from a plant oil such as palm oil or sunflower oil. When the compound contains several acyl radicals, these radicals may be identical or different.
  • This esterification is followed by a quaternization by means of an alkylating agent such as an alkyl halide, preferably a methyl or ethyl halide, a dialkyl sulfate, preferably a methyl or ethyl sulfate, methyl methanesulfonate, methyl para- toluenesulfonate, glycol chlorohydrin or glycerol chlorohydrin.
  • an alkylating agent such as an alkyl halide, preferably a methyl or ethyl halide, a dialkyl sulfate, preferably a methyl or ethyl sulfate, methyl methanesulfonate, methyl para- toluenesulfonate, glycol chlorohydrin or glycerol chlorohydrin.
  • the care composition according to the invention may contain, for example, a mixture of quaternary ammonium monoester, diester and triester salts with a weight majority of diester salts.
  • ammonium salts containing at least one ester function that are described in patents US-A-4 874 554 and US-A-4 137 180.
  • Use may be made of behenoylhydroxypropyltrimethylammonium chloride, sold by Kao under the name Quartamin BTC 131 .
  • the ammonium salts containing at least one ester function contain two ester functions.
  • cetyltrimethylammonium behenyltrimethylammonium or dipalmitoylethylhydroxyethylmethylammonium salts, and mixtures thereof, and more particularly behenyltrimethylammonium chloride, sold for example by the company Clariant under the trade name Genamin KDMP or Genamin BTLF or by the company Evonik Goldschmidt under the name Varisoft BT 85, cetyltrimethylammonium chloride sold, for example, under the trade name Dehyquart A OR by the company Cognis or Quartamin 60 W25 by the company Kao or alternatively Genamin CTAC 25 by the company Clariant, dipalmitoylethylhydroxyethylmethylammonium methosulfate, such as the commercial product Dehyquart F 30 sold by the company Cognis, and mixtures thereof.
  • cetyltrimethylammonium sold for example by the company Clariant under the trade name Genamin KDMP or Genamin BTLF or by the company
  • the cationic surfactants are chosen from the compounds of formula (XVI) or (XIX).
  • fatty alcohol means a long-chain aliphatic alcohol comprising from 8 to 40 carbon atoms and comprising at least one hydroxyl group OH. These fatty alcohols are neither oxyalkylenated nor glycerolated.
  • the solid fatty alcohols are of structure R-OH with R denoting a linear or branched alkyl or alkenyl group, optionally substituted with one or more hydroxyl groups, comprising from 8 to 40, better still from 10 to 30, or even from 12 to 24 atoms, and even better still from 14 to 22 carbon atoms.
  • the fatty alcohols may be liquid or solid.
  • the fatty alcohols are not liquid at room temperature (25°C) and at atmospheric pressure (1 .013x 10 5 Pa; 760 mmHg). Even more preferentially, they are solid under these conditions.
  • R denotes a linear alkyl group, optionally substituted with one or more hydroxyl groups, comprising from 8 to 40, better still from 10 to 30, or even from 12 to 24 atoms, and even better still from 14 to 22 carbon atoms.
  • the fatty alcohols that may be used may be chosen, alone or as a mixture, from: - lauryl alcohol (1 -dodecanol); - myristyl alcohol (1 -tetradecanol);
  • the fatty alcohol is chosen from cetyl alcohol, stearyl alcohol and behenyl alcohol and mixtures thereof such as cetylstearyl alcohol or cetearyl alcohol.
  • the fatty alcohols may be mixtures, which means that several species may coexist in a commercial product, especially of different chain lengths, in the form of a mixture.
  • the hair shaping process consists in applying to hair, preferably wet hair, a styling composition as described previously and in rinsing the hair with an aqueous composition so as to precipitate the fixing polymer(s) on the hair.
  • the fixing is immediate and results from the rinsing with the aqueous composition.
  • the aqueous rinsing composition may have a pH ranging from 2 to 11.
  • the aqueous rinsing composition is water, especially the running water of a shower.
  • the hair is rinsed immediately after the styling composition has been applied.
  • a washing composition such as that described previously is applied and the hair is then rinsed before applying the styling composition.
  • a care composition such as that described previously is applied and the hair is then rinsed before applying the styling composition.
  • a step of shaping the hair, especially by hand, may be performed after the step of rinsing out the styling composition.
  • the hair may then optionally be dried, especially using a hairdryer. Alternatively, it may be dried in the open air.
  • the styling composition according to the invention may thus be applied directly in the shower. It may be rinsed out using the shower water, with running water. The shaping may thus take place after rinsing out the styling composition, which avoids an additional step of rinsing the hands after leaving the shower.
  • compositions were prepared. The concentrations are expressed as mass percentages of active materials in the final composition.

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Abstract

La présente invention concerne un procédé de mise en pli des cheveux dans lequel : une composition coiffante comprenant un ou plusieurs solvants organiques et un ou plusieurs polymères fixateurs sont appliqués sur les cheveux, le ou les polymère(s) fixateur(s) étant au moins partiellement solubles dans la composition coiffante et pouvant précipiter sur les cheveux lorsque la composition coiffante est diluée avec une composition aqueuse ; les cheveux sont rincés avec la composition aqueuse afin de précipiter le polymère fixant sur les cheveux.
PCT/EP2014/051045 2013-01-18 2014-01-20 Procédé de mise en pli des cheveux avec application d'une composition coiffante particulière puis rinçage WO2014111579A2 (fr)

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FR1350478A FR3001149B1 (fr) 2013-01-18 2013-01-18 Procede de mise en forme des cheveux dans lequel on applique une composition de coiffage particuliere que l'on rince
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US201361773205P 2013-03-06 2013-03-06
US61/773,205 2013-03-06

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US11622929B2 (en) 2016-03-08 2023-04-11 Living Proof, Inc. Long lasting cosmetic compositions
US11707426B2 (en) 2017-09-13 2023-07-25 Living Proof, Inc. Color protectant compositions

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