WO2014100303A3 - Recyclable buffer for the hydrothermal hydrocatalytic treatment of biomass - Google Patents

Recyclable buffer for the hydrothermal hydrocatalytic treatment of biomass Download PDF

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Publication number
WO2014100303A3
WO2014100303A3 PCT/US2013/076325 US2013076325W WO2014100303A3 WO 2014100303 A3 WO2014100303 A3 WO 2014100303A3 US 2013076325 W US2013076325 W US 2013076325W WO 2014100303 A3 WO2014100303 A3 WO 2014100303A3
Authority
WO
WIPO (PCT)
Prior art keywords
ammonia
biomass
hydrothermal
hydrothermal hydrocatalytic
hydrocatalytic treatment
Prior art date
Application number
PCT/US2013/076325
Other languages
French (fr)
Other versions
WO2014100303A2 (en
Inventor
Joseph Broun Powell
Glenn Charles Komplin
John Anthony Smegal
Kim Ann JOHNSON
Original Assignee
Shell Oil Company
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Oil Company, Shell Internationale Research Maatschappij B.V. filed Critical Shell Oil Company
Priority to CN201380066742.8A priority Critical patent/CN104903425B/en
Priority to EP13818620.0A priority patent/EP2935519A2/en
Publication of WO2014100303A2 publication Critical patent/WO2014100303A2/en
Publication of WO2014100303A3 publication Critical patent/WO2014100303A3/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/006—Pulping cellulose-containing materials with compounds not otherwise provided for
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
    • C07G1/00—Lignin; Lignin derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
    • C10G1/065—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation in the presence of a solvent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C10G3/55—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds
    • C10G3/56—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds suspended in the oil, e.g. slurries, ebullated beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

A method of hydrothermal hydrocatalytic treating biomass is provided. Lignocellulosic biomass solids is provided to a hydrothermal digestion unit in the presence of a digestive solvent, at least one of ammonia or a source of ammonia, and a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co, Ni or mixture thereof, incorporated into a suitable support. The lignocellulosic biomass solids and digestive solvent are heated in the presence of hydrogen, supported hydrogenolysis catalyst and the at least one of ammonia or a source of ammonia forming a product solution containing plurality of oxygenated hydrocarbons and ammonia. At least a portion of ammonia is separated and recycled to the hydrothermal digestion unit.
PCT/US2013/076325 2012-12-19 2013-12-19 Recyclable buffer for the hydrothermal hydrocatalytic treatment of biomass WO2014100303A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201380066742.8A CN104903425B (en) 2012-12-19 2013-12-19 What the hydro-thermal hydrogenation catalyst for biomass processed can recirculation buffer agent
EP13818620.0A EP2935519A2 (en) 2012-12-19 2013-12-19 Recyclable buffer for the hydrothermal hydrocatalytic treatment of biomass

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261739354P 2012-12-19 2012-12-19
US61/739,354 2012-12-19

Publications (2)

Publication Number Publication Date
WO2014100303A2 WO2014100303A2 (en) 2014-06-26
WO2014100303A3 true WO2014100303A3 (en) 2014-08-14

Family

ID=49920672

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/076325 WO2014100303A2 (en) 2012-12-19 2013-12-19 Recyclable buffer for the hydrothermal hydrocatalytic treatment of biomass

Country Status (4)

Country Link
US (1) US20140166221A1 (en)
EP (1) EP2935519A2 (en)
CN (1) CN104903425B (en)
WO (1) WO2014100303A2 (en)

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EP3083894A1 (en) 2013-12-18 2016-10-26 Shell Internationale Research Maatschappij B.V. Biomass treatment for hydrothermal hydrocatalytic conversion
WO2015095448A2 (en) 2013-12-18 2015-06-25 Shell Oil Company Continuous or semi-continuous biomass wash system for hydrothermal hydrocatalytic conversion
US9404217B2 (en) 2013-12-18 2016-08-02 Shell Oil Company Biomass treatment for hydrothermal hydrocatalytic conversion
BR112016014206A2 (en) 2013-12-18 2017-08-08 Shell Int Research CONTINUOUS OR SEMI-CONTINUOUS BIOMASS WASHING SYSTEM FOR HYDROTHERMIC HYDROCATALYTIC COVERSION
CN105829498A (en) 2013-12-18 2016-08-03 国际壳牌研究有限公司 Biomass treatment for hydrothermal hydrocatalytic conversion
WO2015095471A1 (en) 2013-12-18 2015-06-25 Shell Oil Company Biomass treatment for hydrothermal hydrocatalytic conversion
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BR112016013590A2 (en) 2013-12-18 2017-08-08 Shell Int Research BIOMASS TREATMENT FOR HYDROTHERMAL HYDROCATALYTIC CONVERSION
US9399837B2 (en) 2013-12-18 2016-07-26 Shell Oil Company Biomass treatment for hydrothermal hydrocatalytic conversion
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US10138428B2 (en) * 2014-05-08 2018-11-27 Reliance Industries Limited Catalyst assisted conversion of biomass to bio-oil
WO2016179133A1 (en) 2015-05-05 2016-11-10 Shell Oil Company Reduced emissions aromatics-containing jet fuels
AU2016285908B2 (en) 2015-06-30 2019-02-21 Shell Internationale Research Maatschappij B.V. Biomass conversion process using amorphous silica alumina to obtain a monooxygenated stream
EP3317377B1 (en) 2015-06-30 2019-03-06 Shell International Research Maatschappij B.V. Biomass conversion process using amorphous silica alumina to obtain a monooxygenated stream
US20170001933A1 (en) 2015-06-30 2017-01-05 Shell Oil Company Biomass conversion process to hydrocarbons
WO2017003996A1 (en) 2015-06-30 2017-01-05 Shell Oil Company Biomass conversion process using amorphous silica alumina to obtain a monooxygenated stream
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Also Published As

Publication number Publication date
US20140166221A1 (en) 2014-06-19
WO2014100303A2 (en) 2014-06-26
CN104903425A (en) 2015-09-09
CN104903425B (en) 2016-12-14
EP2935519A2 (en) 2015-10-28

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