WO2014091174A3 - Hydrocarbon polymers comprising a 2-oxo-1,3-dioxolan-4-yl end group, preparation and use thereof - Google Patents

Hydrocarbon polymers comprising a 2-oxo-1,3-dioxolan-4-yl end group, preparation and use thereof Download PDF

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Publication number
WO2014091174A3
WO2014091174A3 PCT/FR2013/053076 FR2013053076W WO2014091174A3 WO 2014091174 A3 WO2014091174 A3 WO 2014091174A3 FR 2013053076 W FR2013053076 W FR 2013053076W WO 2014091174 A3 WO2014091174 A3 WO 2014091174A3
Authority
WO
WIPO (PCT)
Prior art keywords
dioxolan
oxo
end group
preparation
hydrocarbon polymers
Prior art date
Application number
PCT/FR2013/053076
Other languages
French (fr)
Other versions
WO2014091174A2 (en
Inventor
Guillaume Michaud
Frédéric Simon
Stéphane Fouquay
Liana Annunziata
Sophie Guillaume
Jean-François Carpentier
Original Assignee
Bostik Sa
Centre National De La Recherche Scientifique (Cnrs)
Universite De Rennes 1
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bostik Sa, Centre National De La Recherche Scientifique (Cnrs), Universite De Rennes 1 filed Critical Bostik Sa
Priority to US14/650,918 priority Critical patent/US20150329666A1/en
Priority to EP13818302.5A priority patent/EP2931783A2/en
Publication of WO2014091174A2 publication Critical patent/WO2014091174A2/en
Publication of WO2014091174A3 publication Critical patent/WO2014091174A3/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J165/00Adhesives based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3324Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from norbornene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40Polymerisation processes
    • C08G2261/41Organometallic coupling reactions
    • C08G2261/418Ring opening metathesis polymerisation [ROMP]
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/70Post-treatment
    • C08G2261/75Reaction of polymer building blocks for the formation of block-copolymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

The invention relates to a method for preparing a hydrocarbon polymer comprising a 2-oxo-1,3-dioxolan-4-yl end group, by opening the cycle by metathesis in the presence of a metathesis catalyst, a vinyl ethylene carbonate chain transfer agent, and a compound including at least one C6-C16 cycle having a double carbon-carbon bond. The invention also relates to a hydrocarbon polymer that can be obtained by said method. The invention further relates to the use of said polymer as an adhesion promoter or reactive plasticiser in an adhesive composition.
PCT/FR2013/053076 2012-12-14 2013-12-13 Hydrocarbon polymers comprising a 2-oxo-1,3-dioxolan-4-yl end group, preparation and use thereof WO2014091174A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US14/650,918 US20150329666A1 (en) 2012-12-14 2013-12-13 Hydrocarbon polymers comprising a 2-oxo-1,3-dioxolan-4-yl end group, preparation and use thereof
EP13818302.5A EP2931783A2 (en) 2012-12-14 2013-12-13 Hydrocarbon polymers comprising a 2-oxo-1,3-dioxolan-4-yl end group, preparation and use thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1262052A FR2999578B1 (en) 2012-12-14 2012-12-14 HYDROCARBON POLYMERS WITH 2-OXO-1,3-DIOXOLAN-4-YL TERMINATION
FR1262052 2012-12-14

Publications (2)

Publication Number Publication Date
WO2014091174A2 WO2014091174A2 (en) 2014-06-19
WO2014091174A3 true WO2014091174A3 (en) 2015-04-30

Family

ID=48407624

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2013/053076 WO2014091174A2 (en) 2012-12-14 2013-12-13 Hydrocarbon polymers comprising a 2-oxo-1,3-dioxolan-4-yl end group, preparation and use thereof

Country Status (4)

Country Link
US (1) US20150329666A1 (en)
EP (1) EP2931783A2 (en)
FR (1) FR2999578B1 (en)
WO (1) WO2014091174A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11795315B2 (en) * 2018-05-23 2023-10-24 The University Of British Columbia Group 5 metal complexes for producing amine-functionalized polyolefins
JP7094493B2 (en) * 2018-08-03 2022-07-04 日油株式会社 Method for Producing Cyclocarbonate Group-Containing (Meta) Acrylate Monomer
US20230076090A1 (en) * 2020-01-15 2023-03-09 Nof Corporation Cyclocarbonate group-containing (meth)acrylate monomer and polymer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2511942A (en) * 1950-06-20 Vinylethylene carbonate and its
WO1997007976A1 (en) * 1995-08-28 1997-03-06 The Dow Chemical Company Adhesion promotor for linear polyolefin
JP2002317034A (en) * 2001-04-20 2002-10-31 Nippon Zeon Co Ltd Hydrogenated material of norbornene ring opening polymer having functional group at terminal and method for producing the same
WO2003028644A2 (en) * 2001-10-01 2003-04-10 Eurotech, Ltd. Preparation of oligomeric cyclocarbonates and their use in ionisocyanate or hybrid nonisocyanate polyurethanes
JP3396952B2 (en) * 1994-03-29 2003-04-14 日本ゼオン株式会社 Thermally crosslinkable cyclic olefin resin composition and crosslinked product thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2511942A (en) * 1950-06-20 Vinylethylene carbonate and its
JP3396952B2 (en) * 1994-03-29 2003-04-14 日本ゼオン株式会社 Thermally crosslinkable cyclic olefin resin composition and crosslinked product thereof
WO1997007976A1 (en) * 1995-08-28 1997-03-06 The Dow Chemical Company Adhesion promotor for linear polyolefin
JP2002317034A (en) * 2001-04-20 2002-10-31 Nippon Zeon Co Ltd Hydrogenated material of norbornene ring opening polymer having functional group at terminal and method for producing the same
WO2003028644A2 (en) * 2001-10-01 2003-04-10 Eurotech, Ltd. Preparation of oligomeric cyclocarbonates and their use in ionisocyanate or hybrid nonisocyanate polyurethanes

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; 18 January 1996 (1996-01-18), KATAOKA, HIDEAKI ET AL: "Thermally crosslinkable cyclic olefin-based compositions, their molded products, and their crosslinked molded products with good heat and water resistance", XP002713205, retrieved from STN Database accession no. 1996:35141 *
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; 31 October 2002 (2002-10-31), KURAKATA, HIROSHI ET AL: "Heat- and weather-resistant functional group-terminated hydrogenated norbornene ring-opening polymers with good adhesion to substrates, and manufacture of the polymers", XP002713206, retrieved from STN Database accession no. 2002:827489 *

Also Published As

Publication number Publication date
US20150329666A1 (en) 2015-11-19
FR2999578B1 (en) 2015-07-03
EP2931783A2 (en) 2015-10-21
WO2014091174A2 (en) 2014-06-19
FR2999578A1 (en) 2014-06-20

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