WO2014042082A1 - 2-シアノアクリレート系接着剤組成物 - Google Patents
2-シアノアクリレート系接着剤組成物 Download PDFInfo
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- WO2014042082A1 WO2014042082A1 PCT/JP2013/074035 JP2013074035W WO2014042082A1 WO 2014042082 A1 WO2014042082 A1 WO 2014042082A1 JP 2013074035 W JP2013074035 W JP 2013074035W WO 2014042082 A1 WO2014042082 A1 WO 2014042082A1
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- anion
- adhesive composition
- cyanoacrylate
- cation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
- C08F220/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/039—Macromolecular compounds which are photodegradable, e.g. positive electron resists
Definitions
- the present invention relates to a 2-cyanoacrylate adhesive composition mainly composed of 2-cyanoacrylate.
- the 2-cyanoacrylate adhesive composition is polymerized by a weak anion such as a slight amount of water adhering to the surface of the adherend due to the unique anionic polymerization property of the main component 2-cyanoacrylate.
- a weak anion such as a slight amount of water adhering to the surface of the adherend due to the unique anionic polymerization property of the main component 2-cyanoacrylate.
- Various materials can be firmly bonded in a short time. Therefore, it is used as a so-called instantaneous adhesive in a wide range of fields such as industrial use, medical use and home use.
- the curing of the 2-cyanoacrylate adhesive composition proceeds by anionic polymerization, the anionic polymerization is inhibited in the case where the adherend is an acidic wood or a metal that easily forms an oxide film. As a result, there is a problem that the bonding speed becomes slow and sufficient bonding strength cannot be obtained.
- Patent Document 1 discloses an adhesive composition containing crown ethers
- Patent Document 2 discloses an adhesive composition containing polyalkylene oxides
- Patent Documents 3 and 4 disclose adhesive compositions containing calixarenes.
- Patent Document 5 describes that a phase transfer catalyst is used as a curing accelerator for a 2-cyanoacrylate composition.
- JP-A-53-129231 Japanese Unexamined Patent Publication No. 63-128088 JP-A-60-179482 JP 2000-44891 A British Patent Application No. 2228943
- the adhesive compositions disclosed in Patent Documents 1 to 4 can reduce the bonding speed of various adherends, the adherend is made of a metal while further improvement in productivity is required. In the case of the above and the low-polarity thermoplastic elastomer, the bonding speed was not satisfactory. Moreover, even when the phase transfer catalyst specifically described in Patent Document 5 is used as a curing accelerator, the adhesion rate of the thermoplastic elastomer having a low polarity or an adherend was insufficient.
- the adhesive compositions disclosed in Patent Documents 1 and 2 containing crown ethers or polyalkylene oxides have a problem that the cured product becomes cloudy when the adherend is made of EPDM, methacrylic resin or the like. It was.
- the adhesive compositions disclosed in Patent Documents 3 to 4 containing calixarene derivatives have a problem that the cured product becomes cloudy similarly when the adherend is made of soft PVC.
- the present invention has been made in view of the above-described conventional situation, and provides an adhesive composition that exhibits an excellent adhesion rate with respect to a metal and a thermoplastic elastomer having low polarity and also has good storage stability. For the purpose.
- the present inventors By adding an onium salt having a specific structure to 2-cyanoacrylate ester, the present inventors have developed an excellent adhesion rate with respect to a metal and a thermoplastic elastomer having low polarity, and storage stability is also improved. The inventors have found that an excellent adhesive composition can be obtained, and have completed the present invention.
- a 2-cyanoacrylate-based adhesive composition characterized by containing a 1.2-cyanoacrylic acid ester (a) and an onium salt (b) represented by the following general formula (1).
- C + A - (1) [Wherein C + is an onium cation.
- a ⁇ is a hydrogen sulfate anion, a hydrogen sulfite anion, a sulfonate anion represented by R 1 SO 3 —
- R 1 is an alkyl group, a C 3-10 perfluoroalkyl group, a cycloalkyl group, a vinyl group, an aryl group , A perfluoroaryl group, an aralkyl group, or a halogen atom
- R 2 SO 2 bis (substituted sulfonyl) imide anion represented by (R 2 SO 2 ) 2 N — (R 2 is an alkyl group or a perfluoroalkyl group) Or an aryl group).
- the cation of the onium salt (b) is at least one onium cation selected from the group consisting of a quaternary ammonium cation, an imidazolium cation, a pyridinium cation, and a tertiary sulfonium cation.
- the anion of the onium salt (b) is a hydrogen sulfate anion, a hydrogen sulfite anion, and a sulfonate anion represented by R 1 SO 3 — (R 1 is an alkyl group, a cycloalkyl group, an aryl group, or an aralkyl group) .
- R 1 is an alkyl group, a cycloalkyl group, an aryl group, or an aralkyl group
- the 2-cyanoacrylate adhesive composition of the present invention contains 2-cyanoacrylate and an onium salt having a specific structure, it has an excellent adhesion rate for metals and thermoplastic elastomers with low polarity. It develops and has good storage stability. Further, when the anion of the onium salt is at least one of a hydrogen sulfate anion and a bis (perfluoroalkanesulfonyl) imide anion, a better adhesion rate is exhibited.
- the anion of the onium salt is a hydrogen sulfate anion, a hydrogen sulfite anion, and a sulfonate anion represented by R 1 SO 3 — (R 1 is an alkyl group, a cycloalkyl group, an aryl group, or an aralkyl group).
- R 1 is an alkyl group, a cycloalkyl group, an aryl group, or an aralkyl group.
- the 2-cyanoacrylate adhesive composition of the present invention contains 2-cyanoacrylate (a) and an onium salt (b) having a specific structure.
- 2-cyanoacrylate esters generally used in this type of adhesive composition can be used without any particular limitation.
- 2-cyanoacrylic acid ester include methyl, ethyl, chloroethyl, n-propyl, i-propyl, allyl, propargyl, n-butyl, i-butyl, n-pentyl, n-hexyl of 2-cyanoacrylic acid, Cyclohexyl, phenyl, tetrahydrofurfuryl, heptyl, 2-ethylhexyl, n-octyl, 2-octyl, n-nonyl, oxononyl, n-decyl, n-dodecyl, methoxyethyl, methoxypropyl, methoxyisopropyl, methoxybutyl, ethoxyethyl ,
- 2-cyanoacrylic acid esters may be used alone or in combination of two or more.
- 2-cyanoacrylates 2-cyanoacrylates having an alkyl group having 3 or less carbon atoms are preferable, and ethyl 2-cyanoacrylate is more preferable because of excellent curability.
- the adhesive composition of the present invention contains “an onium salt (b) represented by the following general formula (1)”.
- This onium salt functions as a curing accelerator for the adhesive composition, and is a compound that improves the adhesion rate particularly to metals and thermoplastic elastomers.
- C + A - (1) [Wherein C + is an onium cation.
- a ⁇ is a hydrogen sulfate anion, a hydrogen sulfite anion, a sulfonate anion represented by R 1 SO 3 —
- R 1 is an alkyl group, a C 3-10 perfluoroalkyl group, a cycloalkyl group, a vinyl group, an aryl group , A perfluoroaryl group, an aralkyl group, or a halogen atom
- R 2 SO 2 is an alkyl group or a perfluoroalkyl group
- Examples of the cation of the onium salt include an onium cation represented by the following general formula (2), an imidazolium cation, a pyridinium cation, and an onium cation represented by the general formula (3).
- R 3 to R 6 are each independently an unsubstituted or substituted alkyl group having 1 to 20 carbon atoms, a cycloalkyl group, an aryl group, an aralkyl group, an alkenyl group, or an alkynyl group;
- a part or all of R 3 to R 6 together with the atom represented by A is an unsubstituted or substituted 3- to 10-membered ring (wherein the ring contains a hetero atom such as O or S)
- R 3 to R 6 which are not involved in the formation of the ring are as defined above; and A represents a nitrogen atom or a phosphorus atom.
- Specific examples of the substituted alkyl group include an alkoxy group and an alkanoyl group.
- R 3 to R 6 when a part of R 3 to R 6 forms a ring, usually 2 or 3 of R 3 to R 6 form a ring.
- Specific examples of the compound of the formula (2) in which two of R 3 to R 6 form a ring include piperidinium cation, morpholinium cation, pyrrolidinium cation and the like.
- R 7 to R 9 are each independently an unsubstituted or substituted alkyl group having 1 to 20 carbon atoms, a cycloalkyl group, an aryl group, an aralkyl group, an alkenyl group, or an alkynyl group; A part or all of R 7 to R 9 together with a sulfur atom is an unsubstituted or substituted 3- to 10-membered ring (wherein the ring may contain a heteroatom such as O or S) R 7 to R 9 which are not involved in the formation of the ring are as defined above.
- Specific examples of the substituted alkyl group include an alkoxy group and an alkanoyl group.
- Typical examples of the onium cation represented by the general formula (2) include a quaternary ammonium cation and a quaternary phosphonium cation.
- quaternary ammonium cation examples include tetramethylammonium, ethyltrimethylammonium, diethyldimethylammonium, triethylmethylammonium, tetraethylammonium, tetra-n-butylammonium, trimethyl-n-propylammonium, trimethylisopropylammonium, n- Butyltrimethylammonium, isobutyltrimethylammonium, t-butyltrimethylammonium, n-hexyltrimethylammonium, dimethyldi-n-propylammonium, dimethyldiisopropylammonium, dimethyl-n-propylisopropylammonium, methyltri-n-propylammonium, methyltriisopropylammonium Methyldi-n-propylisopropylan Ni, methyl-n-propyldiisopropyl
- quaternary phosphonium cation examples include cations such as tetramethylphosphonium, triethylmethylphosphonium, and tetraethylphosphonium.
- imidazolium cation examples include 1,3-dimethylimidazolium, 1,2,3-trimethylimidazolium, 1-ethyl-3-methylimidazolium, 1-ethyl-2,3-dimethylimidazolium, 1 -Methyl-3-n-octylimidazolium, 1-hexyl-3-methylimidazolium, 1,3-diethylimidazolium, 1,2-diethyl-3-methylimidazolium, 1,3-diethyl-2-methyl Imidazolium, 1,2-dimethyl-3-n-propylimidazolium, 1-n-butyl-3-methylimidazolium, 1-n-butyl-2,3-methylimidazolium, 1,2,4-trimethyl -3-n-propylimidazolium, 1,2,3,4-tetramethylimidazolium, 1,2,3,4,5-pentamethy Imidazolium, 2-ethyl
- pyridinium cation examples include cations such as 1-methylpyridinium, 1-ethylpyridinium, 1-n-propylpyridinium, 1-isopropylpyridinium, 1-n-butylpyridinium, 1-n-butyl-3-methylpyridinium, and the like.
- tertiary sulfonium cation represented by the general formula (3) include cations such as trimethylsulfonium, triethylsulfonium, tripropylsulfonium, and triphenylsulfonium.
- quaternary ammonium cations, imidazolium cations, pyridinium cations are superior in terms of excellent solubility in 2-cyanoacrylate and the balance between curing acceleration ability and storage stability of the adhesive composition.
- a tertiary sulfonium cation is preferable, and a quaternary ammonium cation, an imidazolium cation, or a pyridinium cation is more preferable.
- the anion of the onium salt includes a hydrogen sulfate anion, a hydrogen sulfite anion, a sulfonate anion represented by R 1 SO 3 —
- R 1 is an alkyl group, a C 3-10 perfluoroalkyl group, a cycloalkyl Group, a vinyl group, an aryl group, a perfluoroaryl group, an aralkyl group, or a halogen atom
- R 2 SO 2 bis (substituted sulfonyl) imide anion represented by (R 2 SO 2 ) 2 N ⁇
- R 2 is An alkyl group, a perfluoroalkyl group, or an aryl group).
- the alkyl group of R 1 and R 2 preferably has 1 to 15 carbon atoms.
- sulfonic acid anion represented by R 1 SO 3 — include methanesulfonic acid, ethanesulfonic acid, propanesulfonic acid, hexanesulfonic acid, heptanesulfonic acid, octanesulfonic acid, dodecanesulfonic acid, and vinylsulfonic acid.
- anions such as benzenesulfonic acid, p-toluenesulfonic acid, dodecylbenzenesulfonic acid, 10-camphorsulfonic acid, pentafluorobenzenesulfonic acid, fluorinated sulfonic acid, chlorosulfonic acid, and brominated sulfonic acid.
- the perfluoroalkylsulfonic acid anion having 3 to 10 carbon atoms include perfluorooctanesulfonic acid anion.
- the carbon number of the perfluoroalkyl group is 3 to 10 and preferably 4 to 8 from the viewpoint of the solubility of the corresponding onium salt in 2-cyanoacrylate.
- bis (substituted sulfonyl) imide anion represented by (R 2 SO 2 ) 2 N ⁇ include bis (methanesulfonyl) imide anion, bis (ethanesulfonyl) imide anion, and bis (propanesulfonyl).
- examples thereof include an imide anion, a bis (trifluoromethanesulfonyl) imide anion, a bis (pentafluoroethanesulfonyl) imide anion, a bis (heptafluoropropanesulfonyl) imide anion, and a bis (nonafluorobutanesulfonyl) imide anion.
- a hydrogen sulfate anion and a bis (perfluoroalkanesulfonyl) imide anion are preferable because they exhibit an excellent adhesion rate to metals and thermoplastic elastomers and are excellent in storage stability of the adhesive composition.
- Hydrogen sulfate anion is more preferable, and since white turbidity of the cured product does not occur even in adhesion, filling or potting of a wide range of substrates, and an excellent curing rate is exhibited, hydrogen sulfate anion, hydrogen sulfite anion, and R 1 A sulfonate anion represented by SO 3 — (R 1 is an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group). ] Is preferable.
- the onium salt used in the present invention is not particularly limited as long as it is a combination of the cation and the anion.
- Specific examples of onium salts include tetraethylammonium hydrogensulfate, tetra-n-butylammonium hydrogensulfate, methyltri-n-octylammonium hydrogensulfate, amyltriethylammonium hydrogensulfate, cyclohexyltrimethylammonium hydrogensulfate, 1- Ethyl-3-methylimidazolium hydrogensulfate, 1-ethyl-2,3-dimethylimidazolium hydrogensulfate, 1-butyl-3-methylimidazolium hydrogensulfate, 1-butyl-2,3-dimethylimidazolium Hydrogen sulfate, 1-methyl-3-n-octylimidazolium hydrogen sulfate, 1-hexyl-3-methylimidazolium hydrogen
- the onium salt of the present invention can be produced by a known method. For example, Hiroyuki Ohno et al. Am. Chem. SOc. 2005, 27, 2398-2399, or Peter Waserscheid et al., Green Chemistry, 2002, 4, 134-138.
- the content of the onium salt (b) in the adhesive composition is preferably 10 to 20000 ppm, more preferably 25 to 15000 ppm with respect to 100 parts by mass of the 2-cyanoacrylate (a). More preferably, it is 50 to 10,000 ppm.
- the content is less than 10 ppm, the effect as a curing accelerator is not sufficiently exhibited.
- it exceeds 20000 ppm the storage stability of the adhesive composition may deteriorate.
- the onium salt can improve the adhesion rate to metals and thermoplastic elastomers without adversely affecting the storage stability of the adhesive composition. Since the conjugate acid of the low nucleophilic anion that constitutes the onium salt is a strong acid, it reacts with the salt present on the surface of the adherend and has nucleophilicity to initiate polymerization of 2-cyanoacrylate. Liberates anions that can be agents. On the other hand, during storage in the absence of such a salt, the anion exchange reaction and subsequent release of a highly reactive anion do not occur, so that the storage stability is also good. In particular, hydrogen sulfate also acts as a stabilizer during storage because it is acidic in itself.
- hydrogen sulfate ions can dissolve and remove oxides generated on the metal surface as ions, and at the same time, generate hydroxide ions with extremely high polymerization initiation, so the metal adhesion rate is thought to be greatly shortened. It is done.
- a curing accelerator other than the onium salt a curing accelerator that is conventionally used by blending with this type of adhesive composition can be blended.
- the agent include polyalkylene oxides, crown ethers, silacrown ethers, calixarenes, cyclodextrins, and pyrogallol cyclic compounds.
- polyalkylene oxides examples include polyalkylene oxides and derivatives thereof.
- polyalkylene oxides such as diethylene glycol, triethylene glycol, polyethylene glycol and polypropylene glycol
- polyethylene glycol monoalkyl ester such as diethylene glycol, triethylene glycol, polyethylene glycol and polypropylene glycol
- polyethylene glycol dialkyl ester such as polyethylene glycol dialkyl ester
- polypropylene glycol dialkyl ester diethylene glycol monoalkyl ether
- polyalkylene oxide derivatives such as dialkyl ether, dipropylene glycol monoalkyl ether, and dipropylene glycol dialkyl ether.
- crown ethers examples include those disclosed in Japanese Patent Publication No. 55-2238, Japanese Patent Laid-Open No. 3-167279, and the like. Specifically, 12-crown-4, 15-crown-5, 18-crown-6, benzo-12-crown-4, benzo-15-crown-5, benzo-18-crown-6, dibenzo-18 -Crown-6, dibenzo-24-crown-8, dibenzo-30-crown-10, tribenzo-18-crown-6, asym-dibenzo-22-crown-6, dibenzo-14-crown-4, dicyclohexyl-24 -Crown-8, cyclohexyl-12-crown-4, 1,2-decalyl-15-crown-5, 1,2-naphth-15-crown-5, 3,4,5-naphthyl-16-crown-5 1,2-methylbenzo-18-crown-6, 1,2-tert-butyl-18-crown-6, 1,2-vin
- silacrown ethers examples include those disclosed in JP-A-60-168775. Specific examples include dimethylsila-11-crown-4, dimethylsila-14-crown-5, dimethylsila-17-crown-6, and the like.
- calixarenes examples include those disclosed in JP-A-60-179482, JP-A-62-235379, JP-A-63-88152, and the like. Specifically, 5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41,42-hexahydroxycalix [6] arene, 37,38,39, 40,41,42-hexahydroxyoxycalix [6] arene, 37,38,39,40,41,42-hexa- (2-oxo-2-ethoxy) -ethoxycalix [6] arene, 25,26, 27,28-tetra- (2-oxo-2-ethoxy) -ethoxycalix [4] arene, 4-tert-butylcalix [4] arene-0,0 ', 0' ', 0' '-tetraacetic acid Tetraethyl etc.
- Examples of cyclodextrins include those disclosed in JP-T-5-505835. Specific examples include ⁇ -, ⁇ -, and ⁇ -cyclodextrin.
- Examples of pyrogallol-based cyclic compounds include compounds disclosed in JP 2000-191600 A. Specifically, 3, 4, 5, 10, 11, 12, 17, 18, 19, 24, 25, 26-dodecaethoxycarbomethoxy-C-1, C-8, C-15, C-22 And tetramethyl [14] -metacyclophane. These curing accelerators may be used alone or in combination of two or more.
- the content of the curing accelerator other than the onium salt in the adhesive composition is preferably 10 to 30000 ppm, more preferably 50 to 20000 ppm, based on 100 parts by mass of 2-cyanoacrylate. More preferably, it is ⁇ 10000 ppm.
- the content is in the range of 10 to 30000 ppm, the adhesion rate to various adherends can be improved without impairing the storage stability of the adhesive composition.
- a stabilizer in addition to the curing accelerator, a stabilizer, a plasticizer, and a thickener that are conventionally used by blending with an adhesive composition containing 2-cyanoacrylate ester.
- particles, colorants, fragrances, solvents, strength improvers, and the like can be blended in appropriate amounts within a range that does not impair the curability and adhesive strength of the adhesive composition.
- Stabilizers include (1) aliphatic sulfonic acids such as sulfur dioxide and methanesulfonic acid, aromatic sulfonic acids such as p-toluenesulfonic acid, trifluoride such as boron trifluoride methanol and boron trifluoride diethyl ether.
- Anionic polymerization inhibitors such as boron complexes, HBF 4 , and trialkylborate, and (2) radical polymerization inhibitors such as hydroquinone, hydroquinone monomethyl ether, t-butylcatechol, catechol, and pyrogallol. These stabilizers may be used alone or in combination of two or more.
- Plasticizers include triethyl acetyl citrate, tributyl acetyl citrate, dimethyl adipate, diethyl adipate, dimethyl sebacate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, diisodecyl phthalate, dihexyl phthalate, phthalate Diheptyl acid, dioctyl phthalate, bis (2-ethylhexyl) phthalate, diisononyl phthalate, diisotridecyl phthalate, dipentadecyl phthalate, dioctyl terephthalate, diisononyl isophthalate, decyl toluate, bis (2-ethylhexyl) camphorate, 2 -Ethylhexyl cyclohexyl carboxylate, diisobutyl fumarate, diisobutyl maleate, trigly
- tributyl acetyl citrate dimethyl adipate, dimethyl phthalate, 2-ethylhexyl benzoate, and dipropylene glycol have good compatibility with 2-cyanoacrylate and high plasticization efficiency.
- Dibenzoate is preferred.
- These plasticizers may be used alone or in combination of two or more.
- Thickeners include polymethyl methacrylate, copolymers of methyl methacrylate and acrylate, copolymers of methyl methacrylate and other methacrylic esters, acrylic rubber, polyvinyl chloride, polystyrene, cellulose ester And polyalkyl-2-cyanoacrylic acid ester and ethylene-vinyl acetate copolymer. These thickeners may be used alone or in combination of two or more.
- Adhesion Rate According to JIS K 6861 “Testing Method for ⁇ -Cyanoacrylate Adhesive”, the adhesion rate was measured in an environment of 23 ° C. and 60% RH.
- the test pieces used are as follows. ⁇ Aluminum: manufactured by Nippon Test Panel, aluminum test piece (material: A1050P) ⁇ Iron: manufactured by Nippon Test Panel Co., Ltd., iron test piece (material S10C) -Styrenic thermoplastic elastomer: Product name "ACTIMA A E-2060S” manufactured by Riken Technos (2) Viscosity Using an E-type viscometer, the viscosity was measured under the conditions of 25 ° C. and 100 rpm.
- ⁇ indicates that the cured product has no cloudiness / wrinkles
- x indicates that the cured product has white turbidity / wrinkles.
- the test pieces used are as follows. EPDM: manufactured by Chukyo Rubber Co., Ltd. EPDM-5065 / 3t ⁇ Soft PVC: manufactured by Nippon Wave Rock Co., Ltd., trade name “Tough Neil D Blue”
- Example 1 20 ppm sulfur dioxide and 1000 ppm hydroquinone (100 parts by mass of ethyl 2-cyanoacrylate) are added to ethyl 2-cyanoacrylate, and 1-butyl-2,3-dimethylimidazolium hydrogensulfate is added to this.
- An adhesive composition was prepared by blending 100 ppm and stirring and mixing at room temperature (15 to 30 ° C.) for 30 minutes. Using the obtained adhesive composition, the adhesion rate, viscosity, and storage stability to aluminum and iron were evaluated. The results are shown in Table 2.
- Examples 2 to 13 and Comparative Examples 1 to 5 An adhesive composition was produced and evaluated in the same manner as in Example 1 except that the onium salt or the curing accelerator to be blended in the adhesive composition was changed as shown in Tables 2 and 3. The results are shown in Tables 2 and 3.
- Example 14 20 ppm sulfur dioxide and 1000 ppm hydroquinone (100 parts by mass of ethyl 2-cyanoacrylate) are added to ethyl 2-cyanoacrylate, and 1-butyl-2,3-dimethylimidazolium hydrogensulfate is added to this.
- An adhesive composition was prepared by blending 500 ppm and stirring and mixing at room temperature (15 to 30 ° C.) for 30 minutes.
- the adhesive compositions of Examples 1 to 13 are adhesive compositions containing conventional curing accelerators (Comparative Examples 1 to 3), and out of the scope of the present invention. Compared with an adhesive composition containing an onium salt (Comparative Example 4), it exhibits an excellent adhesion rate to aluminum and iron. Moreover, the viscosity change after 50 degreeC and 95% RH x 2 weeks is also less than 2 times, and it turns out that it is excellent also in storage stability.
- the adhesive compositions of Examples 14 to 22 are superior to the thermoplastic elastomer as compared with the adhesive compositions (Comparative Examples 6 and 7) containing conventional curing accelerators. Expresses the adhesion rate. Moreover, the viscosity change after 50 degreeC and 95% RH * 1 week is also less than 1.5 times, and it turns out that it is excellent also in storage stability.
- Example 23 In 2-ethyl ethyl acrylate, 20 ppm of sulfur dioxide and 1000 ppm of hydroquinone (100 parts by mass of ethyl 2-cyanoacrylate) were added, and this was mixed with 1-butyl-3-methylpyridinium hydrogen sulfate (Table 1). 150 ppm of onium salt B) was blended and stirred and mixed at room temperature (15-30 ° C.) for 30 minutes to produce an adhesive composition. Using the obtained adhesive composition, the adhesion rate to aluminum, iron and thermoplastic elastomer, and the appearance of the cured product were evaluated. The results are shown in Table 5.
- Examples 24 to 34 and Comparative Examples 9 to 14 An adhesive composition was produced and evaluated in the same manner as in Example 23 except that the onium salt or the curing accelerator blended in the adhesive composition was changed as shown in Tables 5 and 6. The results are shown in Tables 5 and 6.
- the adhesive compositions of Examples 23 to 34 are adhesive compositions containing the conventional curing accelerators (Comparative Examples 9 and 10), and are outside the scope of the present invention. Compared with the adhesive composition containing onium salt (Comparative Examples 11 to 13), it exhibits excellent adhesion speed with respect to aluminum, iron, and low-polarity thermoplastic elastomer, and both EPDM and soft PVC. It can be seen that even on the base material, the appearance of the cured product is excellent.
- the present invention contains 2-cyanoacrylic acid ester and can be used as a so-called instantaneous adhesive in a wide range of products and technical fields such as various households in addition to general household and medical fields. In particular, it is useful for applications that require short-time adhesion of metals.
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Abstract
Description
また、クラウンエーテル類、またはポリアルキレンオキサイド類を含有する特許文献1~2に開示される接着剤組成物は、被着体をEPDM、メタクリル樹脂などとした場合、硬化物が白濁する問題があった。カリックスアレン誘導体を含有する特許文献3~4に開示される接着剤組成物は、被着体を軟質PVCとした場合には同様に硬化物が白濁する問題があった。
1.2-シアノアクリル酸エステル(a)と、下記一般式(1)で表されるオニウム塩(b)とを含有することを特徴とする2-シアノアクリレート系接着剤組成物。
C+A- (1)
[式中、C+はオニウムカチオンである。A-は硫酸水素アニオン、亜硫酸水素アニオン、R1SO3 -で表されるスルホン酸アニオン(R1はアルキル基、炭素数3~10のパーフルオロアルキル基、シクロアルキル基、ビニル基、アリール基、パーフルオロアリール基、アラルキル基、もしくはハロゲン原子である)、又は(R2SO2)2N-で表されるビス(置換スルホニル)イミドアニオンである(R2はアルキル基、パーフルオロアルキル基、もしくはアリール基である)。]
2.前記オニウム塩(b)のカチオンが、第四級アンモニウムカチオン、イミダゾリウムカチオン、ピリジニウムカチオン、及び第三級スルホニウムカチオンからなる群より選択される少なくとも一つのオニウムカチオンであることを特徴とする前記1に記載の2-シアノアクリレート系接着剤組成物。
3.前記オニウム塩(b)のアニオンが、硫酸水素アニオン及びビス(パーフルオロアルカンスルホニル)イミドアニオンの少なくとも一方であることを特徴とする前記1又は2に記載の2-シアノアクリレート系接着剤組成物。
4.前記オニウム塩(b)のアニオンが、硫酸水素アニオン、亜硫酸水素アニオン、及びR1SO3 -で表されるスルホン酸アニオン(R1はアルキル基、シクロアルキル基、アリール基又はアラルキル基である)。]からなる群より選択される少なくとも一つであることを特徴とする前記1又は2に記載の2-シアノアクリレート系接着剤組成物。
5.前記オニウム塩(b)の含有量が、前記2-シアノアクリル酸エステル(a)100質量部に対して、10~20000ppmであることを特徴とする前記1~4のいずれかに記載の2-シアノアクリレート系接着剤組成物。
本発明の接着剤組成物は、2-シアノアクリル酸エステル(a)と、特定の構造を有するオニウム塩(b)とを含有する。
C+A- (1)
[式中、C+はオニウムカチオンである。A-は硫酸水素アニオン、亜硫酸水素アニオン、R1SO3 -で表されるスルホン酸アニオン(R1はアルキル基、炭素数3~10のパーフルオロアルキル基、シクロアルキル基、ビニル基、アリール基、パーフルオロアリール基、アラルキル基、もしくはハロゲン原子である)、又は(R2SO2)2N-で表されるビス(置換スルホニル)イミドアニオンである(R2はアルキル基、パーフルオロアルキル基、もしくはアリール基である)。]
(1)接着速度
JIS K 6861「α-シアノアクリレート系接着剤の試験方法」に準じて、23℃、60%RH環境下で接着速度を測定した。使用した試験片は次のとおりである。
・アルミニウム:日本テストパネル社製、アルミニウム試験片(材質:A1050P)
・鉄:日本テストパネル社製、鉄試験片(材質S10C)
・スチレン系熱可塑性エラストマー:リケンテクノス社製 商品名「アクティマー A E-2060S」
(2)粘度
E型粘度計を用い、25℃、100rpmの条件下にて測定した。
(3)貯蔵安定性
初期の接着速度及び粘度と、50℃、95%RH環境下で1週間又は2週間保管後の接着速度及び粘度を比較して評価した。保管は、接着剤組成物1.5gを2gポリエチレン容器に密封して行った。
(4)硬化物外観
3mm×25mm×50mmのEPDM(エチレンプロピレンゴム)板、および軟質PVC(ポリ塩化ビニル)板に、接着剤を数滴垂らし、23℃、60%RH環境下で3日間放置し、硬化させた。その硬化物の外観を観察し、評価結果は○×で表した。○は、硬化物に白濁・シワがないことを、×は硬化物に白濁・シワが見られることを示す。使用した試験片は次のとおりである。
・EPDM:中京ゴム社製、EPDM-5065/3t
・軟質PVC:日本ウェーブロック社製、商品名「タフニール Dブルー」
・合成例1(1-ブチル-2,3-ジメチルイミダゾリウム硫酸水素塩)
50mlナス型フラスコに1-ブチル-2,3-ジメチルイミダゾリウムクロリド1.887g(10.00mmol)(表1参照)、陰イオン交換樹脂(オルガノ社製、商品名「アンバーライトIRA900A OH AG」、強塩基型)13.2g(20mg当量)、イオン交換水25mlを仕込み、室温下で48時間攪拌した。イオン交換樹脂をろ別後、氷冷下で49%硫酸水溶液2.002g(10.00mmol)を滴下した。氷浴を外し、室温下で更に12時間攪拌を続けた。これにトルエン25mlを加えて洗浄し、更にイオン交換樹脂で精製後、減圧下で濃縮した。得られた残渣をメタノール25mlに溶解し、不溶物をろ別した。減圧下で溶媒を留去し、淡黄色オイル2.203gを得た。
・合成例2~4
表1に示した原料と仕込み量に代えた以外は、合成例1と同様にオニウム塩を合成した。
100mlナス型フラスコにジメチルジオクチルアンモニウムブロミド2.103g(3.33mmol)(表1参照)、陰イオン交換樹脂(オルガノ社製、商品名「アンバーライトIRA900A OH AG」、強塩基型)4.40g(6.70mg当量)、メタノール50mlを仕込み、室温下で48時間攪拌した。イオン交換樹脂をろ別後、トルエン15mlに溶媒交換し、溶媒氷冷下で49%硫酸水溶液0.667g(3.33mmol)を滴下した。氷浴を外し、室温下で更に12時間攪拌を続けた。これにイオン交換水10mlを加えて3回洗浄し、無水硫酸マグネシウム上で乾燥させた。減圧下で溶媒を濃縮後、得られた残渣をメタノール25mlに再溶解し、不溶物をろ別した。再度、減圧下で溶媒を留去し、白色固体2.278gを得た。
・実施例1
2-シアノアクリル酸エチルに、二酸化硫黄を20ppm、ハイドロキノンを1000ppm(2-シアノアクリル酸エチルを100質量部とする)配合し、これに1-ブチル-2,3-ジメチルイミダゾリウム硫酸水素塩を100ppm配合して、室温(15~30℃)で30分間撹拌、混合して接着剤組成物を製造した。得られた接着剤組成物を用いて、アルミニウム及び鉄に対する接着速度、粘度並びに貯蔵安定性を評価した。結果は表2のとおりである。
・実施例2~13及び比較例1~5
接着剤組成物に配合するオニウム塩、又は硬化促進剤を表2、3のように代えた以外は、実施例1と同様にして接着剤組成物を製造して評価した。結果は表2、3のとおりである。
・実施例14
2-シアノアクリル酸エチルに、二酸化硫黄を20ppm、ハイドロキノンを1000ppm(2-シアノアクリル酸エチルを100質量部とする)配合し、これに1-ブチル-2,3-ジメチルイミダゾリウム硫酸水素塩を500ppm配合して、室温(15~30℃)で30分間撹拌、混合して接着剤組成物を製造した。得られた接着剤組成物を用いて、熱可塑性エラストマーに対する接着速度、粘度及び貯蔵安定性を評価した。結果は表4のとおりである。
・実施例15~22及び比較例6~8
接着剤組成物に配合するオニウム塩、又は添加剤を表4のように代えた以外は、実施例14と同様にして接着剤組成物を製造して評価した。結果は表4とおりである。
2-シアノアクリル酸エチルに、二酸化硫黄を20ppm、ハイドロキノンを1000ppm(2-シアノアクリル酸エチルを100質量部とする)配合し、これに1-ブチル-3-メチルピリジニウム硫酸水素塩(表1のオニウム塩B)を150ppm配合して、室温(15~30℃)で30分間撹拌、混合して接着剤組成物を製造した。得られた接着剤組成物を用いて、アルミニウム、鉄及び熱可塑性エラストマーに対する接着速度、および硬化物の外観を評価した。結果は表5のとおりである。
接着剤組成物に配合するオニウム塩、又は硬化促進剤を表5、6のように代えた以外は、実施例23と同様にして接着剤組成物を製造して評価した。結果は表5、6のとおりである。
Claims (5)
- 2-シアノアクリル酸エステル(a)と、下記一般式(1)で表されるオニウム塩(b)とを含有することを特徴とする2-シアノアクリレート系接着剤組成物。
C+A- (1)
[式中、C+はオニウムカチオンである。A-は硫酸水素アニオン、亜硫酸水素アニオン、R1SO3 -で表されるスルホン酸アニオン(R1はアルキル基、炭素数3~10のパーフルオロアルキル基、シクロアルキル基、ビニル基、アリール基、パーフルオロアリール基、アラルキル基、もしくはハロゲン原子である)、又は(R2SO2)2N-で表されるビス(置換スルホニル)イミドアニオンである(R2はアルキル基、パーフルオロアルキル基、もしくはアリール基である)。] - 前記オニウム塩(b)のカチオンが、第四級アンモニウムカチオン、イミダゾリウムカチオン、ピリジニウムカチオン、及び第三級スルホニウムカチオンからなる群より選択される少なくとも一つのオニウムカチオンであることを特徴とする請求項1に記載の2-シアノアクリレート系接着剤組成物。
- 前記オニウム塩(b)のアニオンが、硫酸水素アニオン及びビス(パーフルオロアルカンスルホニル)イミドアニオンの少なくとも一方であることを特徴とする請求項1又は2に記載の2-シアノアクリレート系接着剤組成物。
- 前記オニウム塩(b)のアニオンが、硫酸水素アニオン、亜硫酸水素アニオン、及びR1SO3 -で表されるスルホン酸アニオン(R1はアルキル基、シクロアルキル基、アリール基又はアラルキル基である)。]からなる群より選択される少なくとも一つであることを特徴とする請求項1又は2に記載の2-シアノアクリレート系接着剤組成物。
- 前記オニウム塩(b)の含有量が、前記2-シアノアクリル酸エステル(a)100質量部に対して、10~20000ppmであることを特徴とする請求項1~4のいずれか1項に記載の2-シアノアクリレート系接着剤組成物。
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WO2015137156A1 (ja) * | 2014-03-12 | 2015-09-17 | 東亞合成株式会社 | 2-シアノアクリレート系接着剤組成物 |
JP2015224277A (ja) * | 2014-05-27 | 2015-12-14 | 田岡化学工業株式会社 | 2−シアノアクリレート系接着剤用プライマー |
JP2017075110A (ja) * | 2015-10-14 | 2017-04-20 | ピアス株式会社 | 2−シアノアクリレートモノマーの重合促進剤、及び、体毛に繊維を接着させる方法 |
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TWI752043B (zh) * | 2016-06-28 | 2022-01-11 | 日商東亞合成股份有限公司 | 2-氰基丙烯酸酯系接著劑組成物 |
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JPWO2015137153A1 (ja) * | 2014-03-11 | 2017-04-06 | 東亞合成株式会社 | 2−シアノアクリレート系接着剤組成物 |
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WO2015137156A1 (ja) * | 2014-03-12 | 2015-09-17 | 東亞合成株式会社 | 2-シアノアクリレート系接着剤組成物 |
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JPWO2015137156A1 (ja) * | 2014-03-12 | 2017-04-06 | 東亞合成株式会社 | 2−シアノアクリレート系接着剤組成物 |
JP2015224277A (ja) * | 2014-05-27 | 2015-12-14 | 田岡化学工業株式会社 | 2−シアノアクリレート系接着剤用プライマー |
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JP2017075110A (ja) * | 2015-10-14 | 2017-04-20 | ピアス株式会社 | 2−シアノアクリレートモノマーの重合促進剤、及び、体毛に繊維を接着させる方法 |
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JP5556977B1 (ja) | 2014-07-23 |
TWI608069B (zh) | 2017-12-11 |
EP2896668B1 (en) | 2019-11-13 |
KR102039370B1 (ko) | 2019-11-01 |
US9353299B2 (en) | 2016-05-31 |
ES2767336T3 (es) | 2020-06-17 |
EP2896668A4 (en) | 2016-05-04 |
TW201410829A (zh) | 2014-03-16 |
CN104640947A (zh) | 2015-05-20 |
JPWO2014042082A1 (ja) | 2016-08-18 |
KR20150054823A (ko) | 2015-05-20 |
CN104640947B (zh) | 2017-10-03 |
US20150225627A1 (en) | 2015-08-13 |
EP2896668A1 (en) | 2015-07-22 |
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