WO2014032364A1

WO2014032364A1 - Fungicide composition for effectively preventing wheat fungal diseases

Info

Publication number: WO2014032364A1
Application number: PCT/CN2012/084388
Authority: WO
Inventors: 仲汉根
Original assignee: 江苏辉丰农化股份有限公司
Priority date: 2012-09-03
Filing date: 2012-11-09
Publication date: 2014-03-06
Also published as: CN102805096A

Abstract

The invention relates to a use of a fungicide composition for preventing wheat fungal diseases. The fungicide composition consists of two active components and agriculturally acceptable pesticide auxiliary agents. The component a is epoxiconazole and the component b is prochloraz (or its agriculturally acceptable metal salt compounds). In the active components, the weight ratio of epoxiconazole to prochloraz is 0.03-65, and preferably 0.05-55. The fungicide composition is capable of effectively preventing wheat rust, gibberellic disease, powdery mildew, banded sclerotial blight and full rot. The composition obtained by compounding the component a and the component b has positive effects in aspects of fungal resistance delay, and prevention effect improvement, and shows quite strong fungicidal activity.

Description

用于徹防治小麦真菌病害的杀菌剂组合物技术领域 Fungicide composition for thoroughly controlling wheat fungal diseases

本发明涉及一种具有协同增效作用的杀菌剂组合物防治小麦真菌性病害的用途。本发明属于农业植物保护领域。途 The present invention relates to the use of a synergistic fungicide composition for controlling wheat fungal diseases. The invention belongs to the field of agricultural plant protection. Way

技术背景 technical background

小麦的真菌性病害如锈病、白粉病、赤霉病、纹枯病、全蚀病等均为小麦的常见病害，这些病害目前已成为制约小麦生长和丰收的主要病害，这些病害通常使用的药剂为甲基托布津、井冈霉素、 ***酮、多菌灵等常规药剂，由于这些药剂从上个世纪 70年代就开始大面积推广，长期连续高剂量地使用品种或作用方式单一的化学杀菌剂，容易影响药剂的残留、环境污染以及抗药性真菌发展等问题。氟环唑与咪鲜胺都是农业生产上非常有效的杀菌剂。氟环唑是一种新型的重要***类含氟杀菌剂，不仅具有很好的保护、治疗和铲除活性，而且具有较佳内吸活性，可迅速被植株吸收并传导至感病部位，使病害侵染立即停止。由于该化合物导入氟离子，所以对于小麦真菌性病害具有特别高的杀菌活性，但由于氟环唑成本较高，难以大面积推广。咪鲜胺为广谱性杀菌剂，是氨基甲酰咪唑类中活性最强的品种，具有良好的传导性能，对子囊菌纲、担子菌纲、半知菌纲等引起的多种病害具有比较好的效果，对于小麦真菌性病害也有比较好的防效，而且价格适中，易于推广，但长期施用，真菌抗性问题也日益突出。对于此类问题，目前通常使用的方法是筛选出不同活性的化合物的混合物来防治有害真菌。通过此方法可延缓抗性产生，降低施用量，提高防治效果，减少防治成本。 The fungal diseases of wheat such as rust, powdery mildew, scab, sheath blight, and total eclipse are common diseases of wheat. These diseases have become the main diseases that restrict the growth and harvest of wheat. It is a conventional agent such as methyl thiophanate, jinggangmycin, triadimefon, carbendazim, etc. Since these agents have been widely promoted since the 1970s, long-term continuous high-dose use of chemical sterilization of varieties or single action modes Agents, which easily affect the residue of the drug, environmental pollution, and the development of drug-resistant fungi. Both epoxiconazole and prochloraz are very effective fungicides for agricultural production. Fluconazole is a new type of important triazole-based fluorocide, which not only has good protection, treatment and eradication activity, but also has better systemic activity, which can be quickly absorbed by plants and transmitted to susceptible parts. The disease infestation stops immediately. Since the compound introduces fluorine ions, it has a particularly high bactericidal activity against wheat fungal diseases, but since the cost of fluoxazole is high, it is difficult to promote it in a large area. Prochloraz is a broad-spectrum fungicide and is the most active of the carbamyl imidazoles. It has good conductivity and is comparable to many diseases caused by Ascomycetes, Basidiomycetes, and Deuteromycetes. Good results, also have better control effect on wheat fungal diseases, and the price is moderate, easy to promote, but long-term application, the problem of fungal resistance is also increasingly prominent. For such problems, the currently commonly used method is to screen out mixtures of compounds of different activities to prevent harmful fungi. Through this method, the generation of resistance can be delayed, the application amount can be reduced, the control effect can be improved, and the cost of prevention and control can be reduced.

发明内容 Summary of the invention

本发明的目的：针对上述不足之处，通过将氟环唑、咪鲜胺（或其农业上可接受的金属盐类化合物）有效活性成分进行组合，并辅以农药助剂，提供一种对于防治小麦真菌性病菌具有协同增效作用的杀菌剂组合物。试验结果表明，本发明的组合物对小麦真菌性病害增效作用明显，同时降低了施药量，减少了施药次数，而且氟环唑与咪鲜胺之间无交互抗性。途咪鲜胺（英文通用名称 Prochloraz ) , 化学名称（式 I ) : N-丙基 OBJECTS OF THE INVENTION: In view of the above-mentioned deficiencies, a combination of an effective active ingredient of epoxiconazole, promethamine (or an agriculturally acceptable metal salt compound thereof) and a pesticide adjuvant is provided to provide a A fungicide composition having synergistic effect against wheat fungal pathogens. The test results show that the composition of the present invention has a synergistic effect on the fungal diseases of wheat, and at the same time, the application amount is reduced, the number of application is reduced, and there is no cross-resistance between epoxiconazole and prochloraz. Prochloraz (English name Prochloraz ) , chemical name (Formula I ) : N-propyl

-N- [2-(2,4,6-三氯苯氧基)乙基] -咪唑小甲酰胺。

( I ) 延 -N-[2-(2,4,6-Trichlorophenoxy)ethyl]-imidazole small formamide.

(I) extension

适合于本发明的咪鲜胺金属盐类化合物的金属离子可以选择元素周期表中第一至第二过度族元素，尤其是锰、铁、锌、铜；还有第二主族元素，尤其是钙和镁的离子；以及第三和第四主族元素，尤其是铝离子。若合适的话，金属离子可以以它们可能呈现的各种化合价存在。例如，选择金属离子锰的盐类化合物（如式 Π )， gp，丙基嫩三氯苯氧基述乙基咪唑受甲酰胺氯化锰。延 Metal ions suitable for the prochloraz metal salt compound of the present invention may be selected from the first to second exogenous elements of the periodic table, particularly manganese, iron, zinc, copper; and a second main group element, especially Calcium and magnesium ions; and third and fourth main elements, especially aluminum ions. Metal ions may, if appropriate, be present at various valences that they may present. For example, a metal ion manganese salt compound (e.g., formula Π), gp, propyl n-trichlorophenoxyethyl imidazole is selected as the formamide manganese chloride. Delay

延 ¾ 延3⁄4

氟环唑（英文通用名称 epoxiconazole )，化学名称（式 III ) (2RS,3RS)-l-[3-(2-氯苯基 )-2,3-环氧 -2-(4-氟苯基)丙基] -1氢 -1,2,4-***。

Fluodiconazole (English name: epoxiconazole), chemical name (formula III) (2RS, 3RS)-l-[3-(2-chlorophenyl)-2,3-epoxy-2-(4-fluorophenyl) )propyl] -1 hydrogen-1,2,4-triazole.

(III) 延 (III)

本发明的具体方案为：一种防治小麦真菌性病害的杀菌剂组合物，包含下述组分：氟环唑与咪鲜胺（或农业上可接受的其金属盐类化合物）以及农药的常规助剂组成。 A specific embodiment of the present invention is: a fungicide composition for controlling fungal diseases of wheat, comprising the following components: epoxiconazole and prochloraz (or agriculturally acceptable metal salt thereof) and conventional pesticides Auxiliary composition.

适合于本发明的咪鲜胺金属盐类化合物优选咪鲜胺锰盐、咪鲜胺锌盐、咪鲜胺铜盐等其中的一种。延 The prochloraz metal salt compound suitable for the present invention is preferably one of a prochloraz manganese salt, a prolamamine zinc salt, and a prochloraz copper salt. Delay

本发明的杀菌组合物由鍾鍾量份的活性组分与量份的农药助剂组成。延 The bactericidal composition of the present invention consists of a clockwise amount of the active component and parts by weight of the pesticide adjuvant. Delay

本发明的组合物中，咪鲜胺与氟环唑重量比为髮优选为本发明的混合物以组合物的形式使用，使用时通常与其他载体、表面活性剂等常用助剂一起施用。延 In the composition of the present invention, the weight ratio of prochloraz to epoxiconazole is preferably used in the form of a composition of the present invention, usually in combination with other carriers and surfaces. A common auxiliary agent such as an active agent is applied together. Delay

合适的添加剂和载体可以是固体或液体，它们通常是剂型加工过程中常用的物质，例如天然的或再生的矿物质，溶剂、分散剂、润湿剂、胶粘剂、增稠剂、粘合剂或肥料。延 Suitable additives and carriers may be solid or liquid, they are usually materials commonly used in the processing of dosage forms, such as natural or regenerated minerals, solvents, dispersants, wetting agents, adhesives, thickeners, binders or fertilizer. Delay

应用本发明组合物的优选方法包括将本发明的组合物用于植物生长的地上部分，特别是叶部（叶面施用）。使用频率和施用量取决于病原体的生物学和气候生存条件。延 A preferred method of applying the compositions of the present invention comprises applying the compositions of the present invention to aerial parts of plants for growth, particularly foliage (foliar application). The frequency of use and the amount applied will depend on the biological and climatic conditions of the pathogen. Delay

本发明的组合物能以不变的形式使用，或者优选地与配置工艺中通常使用的添加剂一起使用，因此这些化合物能以已知的方式进行配置，例如制成可湿性粉剂、悬浮剂、水分散粒剂。根据这些组合物所具有的性质，可以根据所要达到的目的和环境情况选择如喷雾、弥雾、撒播、泼浇等之类的施用方法。延 The compositions of the present invention can be used in a constant form, or preferably together with additives commonly used in the configuration process, so that these compounds can be formulated in a known manner, for example, as wettable powders, suspending agents, water. Dispersing granules. Depending on the nature of these compositions, application methods such as spraying, misting, spreading, pouring, and the like can be selected depending on the intended purpose and environmental conditions. Delay

作为固体形式的组合物，可提及的有下列几种：水分散粒剂（其活性成分的含量一般比较高，通常在 50%-90%之间），通常是通过可湿性粉末型组合物在合适的颗粒体系中的附聚作用加以制备，制得该剂型。 As the composition in solid form, the following may be mentioned: Water-dispersible granules (the content of which is generally relatively high, usually between 50% and 90%), usually by a wettable powder type composition The dosage form is prepared by agglomeration in a suitable particle system.

可湿性粉剂一般用这样的方法制备，即以使其含有的活性成分为准，除固体载体外，它们一般含有 0-7%的湿润剂， 3-10%的分散剂，必要时，再含有 0-10%的一种或多种其它的添加剂。如染料、着色剂、渗透剂、粘合剂或抗结块剂等。 Wettable powders are generally prepared by the method of containing the active ingredients, in addition to the solid carrier, they generally contain 0-7% wetting agent, 3-10% dispersing agent, and if necessary, further 0-10% of one or more other additives. Such as dyes, colorants, penetrants, adhesives or anti-caking agents.

悬浮剂是以如下的方法来制备的，即以得到不形成沉积物的稳定的流体为准，它们一般含有 10-85%的活性成分， 0.5-45%的表面活性剂， 0-10% 适当的诸如染料、着色剂、抗泡沬剂、防蚀剂、稳定剂和渗透剂及粘合剂等的添加剂，载体可以是水或有机液体，活性成分难溶或不溶于水中，可将某些固体有机物质或无机盐溶于液体中以便有助于沉积物形成或作为水的防冻剂。 Suspending agents are prepared by the method of obtaining a stable fluid which does not form deposits, which generally contain 10-85% active ingredient, 0.5-45% surfactant, 0-10% appropriate Additives such as dyes, colorants, anti-foaming agents, corrosion inhibitors, stabilizers and penetrants, and binders, the carrier may be water or an organic liquid, the active ingredient is poorly soluble or insoluble in water, and certain The solid organic or inorganic salt is dissolved in the liquid to aid in the formation of deposits or as an antifreeze to water.

可用已知的方法制备各种剂型：例如将有效成分与填充剂，如溶剂、固体载体，需要时可以与表面活性剂一起均匀混合、研磨。延 Various dosage forms can be prepared by known methods: For example, the active ingredient and a filler such as a solvent, a solid carrier can be uniformly mixed and ground with a surfactant as needed. Delay

适合于发明的溶剂可供选择的有：芳香烃，优选含个碳原子，如二甲苯混合物或取代的苯，酞酸酯类，如酞酸二丁酯或酞酸二辛酸，脂肪烃类，如环已垸或石蜡，醇和乙二醇和它们的醚和酯，如乙醇，乙二醇，乙二醇单甲基；酮类，如环已酮，强极性的溶剂，如甲基金吡咯垸酮，二甲基亚砜或二甲基甲酰胺，和植物油或植物油，如大豆油。境适合于本发明的固体载体，如用于粉剂和可分散剂的通常是天然矿物填料，例如滑石、高岭土，蒙脱石或活性白土。为了管理物理性能也可以加入高分散性硅酸或高分散性吸附聚合物。合适的粒状吸附载体是多孔型的，如浮石、皂土或膨润土；合适的非吸附载体是例如方解石或砂。另外，可以使用大量的无机性质或有机性质的预制成粒状的材料，特别是白云石。境根据本发明两组分的化学性质，合适的表面活性剂为木质素磺酸、萘磺酸、苯酚磺酸、二丁基萘磺酸的碱金属盐、碱土金属盐和胺盐，垸基芳基磺酸盐，垸基硫酸盐，垸基磺酸盐，垸基磺酸盐，脂肪醇硫酸盐，脂肪酸和硫酸化脂肪醇乙二醇醚，还有磺化萘和萘衍生物与甲醛的缩合物，萘或萘磺酸与苯酚和甲醛的缩合物，聚氧乙烯辛基苯基醚，乙氧基化异辛基酚，辛基酚，壬基酚，垸基芳基聚乙二醇醚，三丁基苯聚乙二醇醚，三硬脂基苯基聚乙二醇醚，垸基芳基聚醚醇，乙氧基化蓖麻油，聚氧乙烯垸基醚，氧化乙烯缩合物、乙氧基化聚氧丙烯，月桂酸聚乙二醇醚缩醛，山梨醇酯，木质素亚硫酸盐废液和甲基纤维素。境 Solvents suitable for the invention are: aromatic hydrocarbons, preferably containing one carbon atom, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons, Such as ring ruthenium or paraffin, alcohols and glycols and their ethers and esters, such as ethanol, ethylene glycol, ethylene glycol monomethyl; ketones, such as cyclohexanone, a highly polar solvent such as methylpyrrolidone ketone, Dimethyl sulfoxide or dimethylformamide, and vegetable oil or vegetable oil, such as soybean oil. Solid carriers suitable for the present invention, such as for powders and dispersibles, are typically natural mineral fillers such as talc, kaolin, montmorillonite or activated clay. Highly dispersible silicic acid or highly dispersible adsorbent polymers can also be added for the management of physical properties. Suitable particulate adsorbent supports are porous, such as pumice, bentonite or bentonite; suitable non-adsorbent supports are, for example, calcite or sand. In addition, a large amount of pre-granulated materials of inorganic or organic nature, in particular dolomite, can be used. According to the chemical properties of the two components of the present invention, suitable surfactants are alkali metal salts, alkaline earth metal salts and amine salts of lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid, and mercapto groups. Aryl sulfonate, mercaptosulfate, mercaptosulfonate, mercaptosulfonate, fatty alcohol sulfate, fatty acid and sulfated fatty alcohol glycol ether, and sulfonated naphthalene and naphthalene derivatives and formaldehyde Condensate, condensate of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, mercaptoaryl polyethylene Alcohol ether, tributyl benzene polyglycol ether, tristearyl phenyl polyglycol ether, mercapto aryl polyether alcohol, ethoxylated castor oil, polyoxyethylene decyl ether, ethylene oxide condensation , ethoxylated polyoxypropylene, lauric acid polyethylene glycol ether acetal, sorbitol ester, lignin sulfite waste liquid and methyl cellulose. territory

可施用本发明的组合物中，当共同施用两组分时，出现叠加（等于增效）的效果。此组合物的活性比使用单个化合物的活性预期总和，以及单个化合物的单独活性更为显著。增效效果允许表现为施用量减少、作用效果见效快、更持久的防治效果、通过仅仅一次或少数几次施用能更好的控制植物有害真菌。 In the composition of the present invention, when two components are co-administered, an effect of superposition (equal to synergy) occurs. The activity of this composition is more significant than the expected expected activity of a single compound, as well as the individual activity of a single compound. The synergistic effect allows for a reduction in the application rate, a quick effect on the effect, and a more durable control effect, which can better control the harmful fungi of the plant by only one or a few applications.

本发明的杀菌组合物的表现出的其它特点主要表现为： 1、由于本组合物的两个单剂化学结构差异很大，不存在交互抗性，可延缓两单剂单独使用所产生的抗性问题； 2、本发明的组合物对作物安全、防效好。经试验证明，本发明杀菌剂组合物化学性质稳定，增效显著，对防治对象表现出明显的增效以及互补作用； 3、减少了用药量，从而降低了成本和减轻了对环境的污染。 The other characteristics exhibited by the bactericidal composition of the present invention are mainly as follows: 1. Since the chemical composition of the two single agents of the present composition is very different, there is no cross-resistance, and the anti-resistance generated by the two single agents can be delayed. Sexual problems; 2. The composition of the invention is safe and effective against crops. It has been proved by experiments that the bactericidal composition of the invention has stable chemical properties and remarkable synergistic effect, and exhibits obvious synergistic effect and complementary effect on the control object; 3. The dosage is reduced, thereby reducing the cost and reducing the environmental pollution.

为了使本发明的目的、技术方案及优点更加清楚明白，以下结合实施例，对本发明进行进一歩详细说明。应当理解，此处所描述的具体实施例仅用以解释本发明，并不用于限定本发明，凡在本发明的精神和原贝 J之内所做的任何修改、等同替换和改进等，均应包含在本发明的保护范围之内。 In order to make the objects, the technical solutions and the advantages of the present invention more comprehensible, the present invention will be described in detail below with reference to the embodiments. It is understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention, any modifications, etc. made within the spirit and scope of the present invention. The same substitutions, improvements, etc., are intended to be included within the scope of the present invention.

以下实施例所有配方中百分比均为重量百分比。本发明组合物各种制剂的加工工艺均为现有技术，根据不同情况可以有所变化。 The percentages in all formulations in the following examples are percentages by weight. The processing techniques for the various formulations of the compositions of the present invention are prior art and may vary depending on the circumstances.

一、剂型制备实施例 First, the dosage form preparation example

(四）水乳剂的加工及实施例 (4) Processing and examples of water emulsion

将活性成分 a与 b、 1」、助剂在机械搅拌下混合均匀，然后 SA乳化剂和稳定剂搅拌均匀，最后加入水，在 100-12000转 / 中的繊下搅拌 10-30 中，使之成为均匀乳状的产品。 The active ingredient a and b, 1", the auxiliary agent are uniformly mixed under mechanical stirring, then the SA emulsifier and the stabilizer are evenly stirred, and finally water is added, and the mixture is stirred under the armpit of 100-12000 rpm for 10-30, so that It becomes a homogeneous milky product.

雄例 1： 30%咪鲜胺 ·氟环唑水乳剂 Male 1: 1: 30% prochloraz & epoxiconazole water emulsion

咪鲜胺 5%，氟环唑 25%，聚氧乙烯嵌段共聚物 4%,丙二醇 2%，黄原胶 3%，聚异丁二酸酐-聚乙二醇共聚物 4%，有机硅消泡剂 2%，水补足至 100%。 Prochloraz 5%, flucyclazole 25%, polyoxyethylene block copolymer 4%, propylene glycol 2%, xanthan gum 3%, polyisosuccinic anhydride-polyethylene glycol copolymer 4%, silicone elimination 2% foaming agent, water to 100%.

上述实施例 1中，也可用咪鲜 JSf孟盐、咪鲜月同盐、咪鲜胺锌盐来替代咪鲜胺来制备该实施例。 In the above Example 1, the present example can also be prepared by substituting the fresh salt of Msf Meng salt, Mi Xianyue salt and prochlorazin for the prochloraz.

雄例 2： 30%咪鲜胺 ·氟环唑水乳剂 Male 2: 30% prochloraz fluorocyclazole water emulsion

咪鲜胺 25%，氟环唑 5%， N-十二； ^基吡咯；^酮 3%,蓖麻油聚氧乙烯醚 2%，丙三醇 2%，聚乙烯醇 3%，苯甲酸钠 3%，异辛醇 2%，水补足至 100%。 Prochloraz 25%, flucyclazole 5%, N-twelve; ^ pipyrrole; ketone 3%, castor oil polyoxyethylene ether 2%, glycerol 2%, polyvinyl alcohol 3%, sodium benzoate 3 %, iso-octanol 2%, water to 100%.

上述实施例 2中，也可用咪鲜孟盐、咪鲜月同盐、咪鲜胺锌盐来替代咪鲜胺来制备该实施例。 In the above Example 2, this example can also be prepared by substituting imipenem salt, imipenem salt, and prochlorazinium salt for prochloraz.

(二）悬浮剂的加工及实施例 (2) Processing and examples of suspending agents

将活性成分 a与 b、分散剂、润湿剂、增稠剂和水等各组分按配方的比例混合均匀，经砂磨禾口 /或高速剪切后，得到半成品，分析后补加水混合均匀过滤即得成品。 The active ingredients a and b, the dispersing agent, the wetting agent, the thickener and the water are mixed uniformly according to the formula, and after being sanded and/or sheared at high speed, a semi-finished product is obtained, and the water is mixed after analysis. Evenly filtered to get the finished product.

雄例 3： 42%咪鲜翻盐 ·氟环嗎孚剂 Male 3: 42% fresh salt and salt

咪鲜月同盐 40%，氟环唑 2%，木质素磺酸钠 8%,白炭黑 2%，乙二醇 5%，黄原胶 2%，水补足至 100%。 Mi Xianyue with salt 40%, epoxiconazole 2%, sodium lignin sulfonate 8%, white carbon black 2%, ethylene glycol 5%, xanthan gum 2%, water to 100%.

上述实施例 3中，也可用咪鲜胺、咪鲜胺锰盐、咪鲜辛盐来替代咪鲜胺铜盐来制备该实施例。 In the above Example 3, this example can also be prepared by replacing prochlorazinium salt with prochloraz, prochloraz, and imipenem salt.

雄例 4： 42%咪鲜翻盐 ·氟环嗎孚剂 (2:40) Male 4: 42% fresh salt and salt · Fluorocyclovir (2:40)

咪鲜月同盐 2%，氟环唑 40%，白炭黑 2%，月旨肪醇聚氧乙烯醚磷酸酯 6%,苯甲翻 3%，丙三醇 7%，水补足至 100%。 Mi Xianyue with salt 2%, flucyclazole 40%, white carbon black 2%, monthly fatty alcohol polyoxyethylene ether phosphate 6%, benzene 3%, glycerol 7%, water to 100% .

上述实施例 4中，也可用咪鲜胺、咪鲜胺锰盐、咪鲜辛盐来替代咪鲜胺铜盐来制备该实施例。 In the above Example 4, the prochloraz, the prochloraz, and the fresh salt may be used instead of the prochloraz. Salt was used to prepare this example.

(一）水分散粒剂的加工及实施例 (1) Processing and examples of water-dispersible granules

将活性成分 a与助剂和填料按配方的比例混合均匀，经气流粉碎成可湿性粉剂，再加入一定量的水混合挤压造粒，经千燥筛分后制得水分散粒剂产品。 The active ingredient a is uniformly mixed with the auxiliary agent and the filler according to the formula, and is pulverized into a wettable powder by a jet stream, and then added with a certain amount of water to be mixed and extruded, and then sieved to form a water-dispersible granule product.

雄例 5： 75%咪鲜藤盐 ·氟环唑水分散粒剂 Male 5: 75% fresh vine salt · flucyclazole water dispersible granules

咪鲜 JSf孟盐 2%，氟环唑 73%，海藻 , 4%，甲基萘磺,甲醛缩合物 2%，硫膽安 2%,有机硅酮 2%，翻土补足至 100%。 Msf JSf Meng salt 2%, epoxiconazole 73%, seaweed, 4%, methyl naphthalene sulfonate, formaldehyde condensate 2%, thiabalone 2%, organic silicone 2%, tumbling to 100%.

上述实施例 5中，也可用咪鲜月同盐、咪鲜辛盐或咪鲜胺来替代咪鲜胺锰盐来制备该实施例。 In the above Example 5, this example can also be prepared by substituting Mi Xianyue with salt, imixin salt or prochloraz.

¾ϋ例 6: 80%咪鲜辛盐 ·氟环唑水分散粒剂 3⁄4ϋExample 6: 80% fresh octyl salt · flucyclazole water dispersible granules

咪鲜辛盐 78%，氟环唑 2%，木质素磺酸钠 4%，羧甲基淀粉钠 1%，十二基磺酸钠 2%，黄原胶 4%，凹凸棒土补足至 100%。 78% of minooctyl salt, 2% of epoxiconazole, 4% of sodium lignin sulfonate, 1% of sodium carboxymethyl starch, 2% of sodium dodecyl sulfonate, 4% of xanthan gum, attapulgite to 100 %.

上述实施例 6中，也可用咪鲜月同盐、咪鲜孟盐或咪鲜胺来替代咪鲜胺锌盐来制备该实施例。 In the above Example 6, the present example can also be prepared by substituting the imide salt, the imide salt or the prochloraz in place of the prochlorazin salt.

(三）可湿性粉剂的加工及实施例 (3) Processing and examples of wettable powders

将活性成分 a与 b、各种助剂及填料等按比例充分混合，经超细粉碎机粉碎后制得可湿性粉剂。 The active ingredients a and b, various auxiliaries and fillers, etc. are thoroughly mixed in proportion, and pulverized by an ultrafine pulverizer to obtain a wettable powder.

雄例 7： 85%咪鲜翻盐 ·氟环唑可湿性粉剂 Male case 7: 85% fresh rice salt · epoxiconazole wet powder

咪鲜月同盐 78%，氟环唑 7%，木质素磺酸钙 6%,膨润土 3%，聚氧乙烯辛基苯基醚 4%,凹凸棒土补足至 100% Mi Xianyue with salt 78%, epoxiconazole 7%, calcium lignosulfonate 6%, bentonite 3%, polyoxyethylene octyl phenyl ether 4%, attapulgite to 100%

上述实施例 7中，也可用咪鲜孟盐、咪鲜胺或咪鲜辛盐来替代咪鲜胺铜盐来制备该实施例。 In the above Example 7, the present example can also be prepared by substituting the imammonium salt, prochloraz or imipenem salt for the prochlorazin copper salt.

雄例 8： 50%咪鲜翻盐 ·氟环唑可湿性粉剂 Male case 8: 50% fresh salt, fluoxazole wettable powder

咪鲜月同盐 25%，氟环唑 25%，木质素磺 , 4%,白炭黑 8%，十二； ^基苯磺 3%,凹凸棒土补足至 100% Mi Xianyue with salt 25%, epoxiconazole 25%, lignin sulfonate, 4%, white carbon black 8%, twelve; ^ benzene benzene 3%, attapulgite to 100%

上述实施例 8中，也可用咪鲜孟盐、咪鲜胺或咪鲜辛盐来替代咪鲜胺铜盐来制备该实施例。 In the above Example 8, the present example can also be prepared by substituting the imammonium salt, prochloraz or imipenem salt for the prochlorazin copper salt.

雄例 9: 55%咪鲜藤盐 ·氟环唑可湿性粉剂 Male 9: 55% fresh vine salt · epoxiconazole wettable powder

咪鲜藤盐 5%，氟环唑 50%，聚氧乙烯辛基苯基醚 6%,木质素磺酸钠 7%, 白炭黑 15%，硅¾±补足至 100%。 Fresh vine salt 5%, epoxiconazole 50%, polyoxyethylene octyl phenyl ether 6%, sodium lignin sulfonate 7%, white carbon black 15%, silicon 3⁄4 ± complement to 100%.

上述实施例 9中，也可用咪鲜月同盐、咪鲜胺或咪鲜胺来替代咪鲜孟盐来制备该实施例。 In the above-mentioned Example 9, it is also possible to replace the imammonium salt with Mi Xianyue salt, prochloraz or prochloraz. This example was prepared.

二、应用实施例 Second, the application example

(一）室内生物活性测定本发明的共毒系数脂 (I) Determination of the indoor bioactivity of the co-toxicity lipid of the present invention

将防治效果换算成几率值 ( ) ，药液浓度（ μ岭）转换成对数值 ( ) ，以最小二乘法计算毒力方程和抑制中浓度 ί¾: ，依孙云沛法计算药剂的毒力指数级共毒系数（）。毒力测定结果见表蒙月旨 The control effect is converted into the probability value ( ), the concentration of the chemical solution ( μ ridge) is converted into a logarithmic value ( ), the virulence equation and the medium concentration of inhibition are calculated by the least square method ί3⁄4: , and the virulence index of the drug is calculated by the method of Sun Yunpei. Poison coefficient ( ). Virulence measurement results are shown in the table

实测毒力指数 ( )赚醫 (搬供试药剂 ¾a«旨 Measured virulence index ( ) to make a doctor (moving test drug 3⁄4a)

理论毒力指数 ( )预药剂毒力指数混剂中的百量砜旨药剂毒力 ί 数混剂中的百分含量脂 Theoretical virulence index ( ) Pre-drug virulence index mixture of hundreds of sulfones for drug virulence ί

共毒系数（）觀剂实测毒力指数 ( )霸理论毒力指数 ( )細 ¾¾合物表现为拮抗作用 » < 组合物表现为相加作用油 ^m.组合物表现为增效作用。脂 Co-toxicity coefficient ( ) Pharmacological test virulence index ( ) tyrannical virulence index ( ) fine 3⁄43⁄4 compound showed antagonism » < composition showed additive oil ^ m. The composition showed synergy. fat

1、室内生物活性测定本发明的组合物对小麦白粉病的共毒系数测定 1. Determination of the co-toxicity coefficient of the composition of the present invention against wheat powdery mildew

测定结果（表 1 ) 表明，咪鲜胺与氟环唑在配比 50:1〜鷓鞋间对水稻白粉病的防治具有增效作用，尤其是在 30:1〜鷓之间，增效作用显著，共毒系数都在蒙 it以上，说明咪鲜胺与氟环唑复配对小麦白粉病的增效作用明显。脂 The results (Table 1) indicate that prochloraz and epoxiconazole have synergistic effects on the control of rice powdery mildew in the ratio of 50:1~ 鹧 shoes, especially between 30:1~鹧, synergistic effect. Significantly, the co-toxicity coefficient is above the level of it, indicating that the synergistic effect of prochloraz and epoxiconazole on wheat powdery mildew is obvious. fat

脱室内生物活性测定本发明的组合物对小麦赤霉病的共毒系数测定试验对象：小麦赤霉病 Determination of the co-toxicity coefficient of the composition of the invention against wheat scab Test subject: Wheat scab

表 2咪鲜胺与氟环^ ¾其不同配比复配对小麦赤霉病毒力测定结果分析 Table 2 Analysis of the results of the determination of the strain of wheat gibberellin by different ratios of prochloraz and fluorocyclohexane

测定结果（表 2) 表明，咪鲜胺与氟环唑在配比 50:1〜妻之间，对小麦赤霉病的防治具有增效作用，尤其是在 30:1〜¾ ^间，增效作用尤为显著，共毒系数都在猶系以上。具 The results of the determination (Table 2) show that prochloraz and epoxiconazole have synergistic effects on the control of wheat scab in a ratio of 50:1 to wife, especially between 30:1 and 3⁄4 ^. The effect is particularly significant, and the co-toxicity coefficient is above. With

3、室内生物活性测定本发明的组合物对小麦锈病的共毒系数具防治对象：小麦锈病（叶锈病） 3. Indoor biological activity determination The co-toxicity coefficient of the composition of the invention against wheat rust is controlled by: wheat rust (leaf rust)

表 3咪鲜胺与氟环唑及其不同配比复配对小麦锈病的毒力测定结果分析 Table 3 Analysis of virulence determination results of prochloraz and epoxiconazole and their different ratios against wheat rust

测定结果（表 3 ) 表明，咪鲜胺与氟环唑在配比 50:1〜妻 «t间，对小麦锈病的防治具有增效作用，尤其是在 30:1〜哼 »St间，增效作用尤为显著，共毒系数都在口«¾上。程 The results of the determination (Table 3) indicate that prochloraz and epoxiconazole are in a ratio of 50:1 to wife «t, small The control of wheat rust has synergistic effects, especially between 30:1 and 哼»St, the synergistic effect is particularly significant, and the co-toxicity coefficient is on the mouth «3⁄4. Cheng

4、室内生物活性测定本发明的组合物对小麦纹枯病的共毒系数程防治对象：小麦纹枯病程 4. Indoor biological activity determination The co-toxicity coefficient of the composition of the present invention on wheat sheath blight control object: wheat sheath blight course

表 4咪鲜胺与氟环^ ¾其不同配比复配对小麦纹枯病的毒力测定结果分析 Table 4 Analysis of virulence determination results of different ratios of prochloraz and fluorocyclohexanes in the treatment of wheat sheath blight

定结果（表 4) 表明，咪鲜胺与氟环唑在配比 50:1〜哼 «t间，对小麦纹枯病的防治具有增效作用，尤其是在 30:1〜哼 «之间，增效作用尤为显著，共毒系数都在叶«(上。程 The results (Table 4) indicate that prochloraz and epoxiconazole have synergistic effects on the control of wheat sheath blight in the ratio of 50:1~哼«t, especially between 30:1~哼« The synergistic effect is particularly significant, and the co-toxicity coefficient is in the leaf «(上. Cheng

5、室内生物活性测定本发明的组合物对小麦全蚀病的共毒系数程防治对象：小麦全蚀病 5. Indoor biological activity determination The co-toxicity coefficient of the composition of the present invention on wheat total erosion disease Prevention object: Wheat total erosion disease

表 5咪鲜胺与氟环唑及其不同配比复酉 S寸小麦全蚀病的毒力测定结果分析 Table 5 Analysis of virulence determination results of prochloraz and epoxiconazole and their different ratios

ECso cW mm 赫灘 ΑΉ ΤΓΙ ECso cW mm 赫滩 ΑΉ ΤΓΙ

g/ml) (CTC) 瞧安 4.72 100.000 1 1 唑 3.21 147.040 1 1 酉己比嚇翔安： W¾=50:l 3.61 130.854 100.922 129.658 酉己比嚇翔安： W^30:l 2.80 168.298 101.517 165.782 酉己比嚇翔安： W^iO:i 1.91 247.704 104.276 237.546 酉己比嚇翔安： W^i:i 2.00 235.705 123.520 190.823 酉己比嚇翔安： W^i:io 1.84 256.719 142.764 179.821 酉己比嚇羊胺： W^l:30 1.93 244.079 145.523 167.726 酉己比嚇翔安： W^l:50 2.46 191.606 146.118 131.131 测定结果（表 5 ) 表明，咪鲜胺与氟环唑在配比 50:1〜鷓鞋间，对小麦全蚀病的防治具有增效作用，尤其是在 30:1〜鷓着 t之间，增效作用尤为显著，共毒系数都在以上。月旨 g/ml) (CTC) 瞧安4.72 100.000 1 1 azole 3.21 147.040 1 1 酉己比惊翔安: W3⁄4=50:l 3.61 130.854 100.922 129.658 酉己比惊翔安: W^30:l 2.80 168.298 101.517 165.782酉己比惊翔安: W^iO:i 1.91 247.704 104.276 237.546 酉己比惊翔安: W^i:i 2.00 235.705 123.520 190.823 酉己比惊翔安: W^i:io 1.84 256.719 142.764 179.821 酉比吓 : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : 50:1 ~ 鹧 shoes, have a synergistic effect on the prevention and control of wheat total eclipse, especially between 30:1 ~ 鹧 t, the synergy is particularly significant, the co-toxicity coefficient is above. Monthly

(二）田间药效试验（采用平行试验的方法来验证本发明的组合物对小麦锈病、赤霉病、白粉病、纹枯病、全蚀病的田间试验防治效果）月旨 (II) Field efficacy test (The method of parallel test was used to verify the effect of the composition of the present invention on field control of wheat rust, scab, powdery mildew, sheath blight, and total etch disease)

试验方法：在发病初期，立即进行第一次喷雾， 7天后进行第二次施药，每个处理 4个小区，小区 20平米。于药前和第二次药后 10天调查统计发病情况，每个小区 5点随机取样，每点调查 5株小麦，调查整株小麦上每叶片或叶鞘的病斑面积占叶片面积的百分率并分级，计算病情指数和防治效果。 Test method: In the early stage of the disease, the first spray is immediately performed, and after 7 days, the second application is carried out, each treatment is 4 cells, and the plot is 20 square meters. The incidence of the disease was investigated before the drug and 10 days after the second drug. Each plot was randomly sampled at 5 points, and 5 wheats were investigated at each point. The area of the leaf area per leaf or sheath of the whole wheat was investigated and the percentage of leaf area was counted. Grading, calculating the disease index and prevention and treatment effects.

脂 fat

∑ (各級叶片发病数 *该鈒值） ∑ (number of leaves at all levels * the value of this ))

病情指數 = 100 Condition index = 100

调奎总叶片数 X最高药对照病 it指數 X药后处理病情指救 The total number of leaves in the squadron X is the highest drug, the control disease, the it index, the X drug, the post-treatment condition, the rescue

> moo > moo

药后对病情指药前处病情指数预期防效（％) =X+Y-XY/IOO (其中， X， γ为单剂防效） After the drug, the disease index refers to the disease index. Expected control effect (%) = X+Y-XY/IOO (where X, γ is a single-agent control effect)

分级标准： Grading standards:

0级：无病斑； Level 0: no lesions;

1级：叶片病斑少于 5个，长度小于 lcm; Level 1: The number of leaf lesions is less than 5, and the length is less than lcm;

3级：叶片病斑 6-10个，部分病斑长度大于 lcm; Grade 3: 6-10 leaf lesions, some lesions are longer than lcm;

5级：叶片病斑 11-25个，部分病斑连成片，病斑面积占叶面积的 10-25%; 7级：叶片病斑 26个以上，病斑连成片，病斑面积占叶面积的 26-50%; 9级: 病斑连成片，病斑面积占叶面积的 50%以上或全叶枯死。 Grade 5: 11-25 leaf lesions, some lesions are connected into pieces, the lesion area accounts for 10-25% of the leaf area; Grade 7: more than 26 leaf lesions, the lesions are connected into pieces, and the lesion area accounts for 26-50% of the leaf area; Grade 9: The lesions are connected into pieces, and the area of the lesions accounts for more than 50% of the leaf area or the whole leaves die.

( 1 ) 本发明的组合物对小麦白粉病的田间药效试验分析 (1) Field efficacy test analysis of the composition of the invention on wheat powdery mildew

表 6 咪鲜胺与氟环唑复酉寸小麦白粉病的田间防效试验结果 Table 6 Field control trial results of prochloraz and epoxiconazole retanning wheat powdery mildew

用量药第二次药后 11天序号舰續 (a.i. 鶴情病情防效 Dosage After the second drug 11 days Serial number Ships (a.i. Heqing disease condition Control effect

g/ha) 指数指数 ( ) 25%咪鲜胺乳油 25 2.99 29.15 9.3g/ha) index index ( ) 25% prochloraz cream 25 2.99 29.15 9.3

12.5%氟环唑悬浮剂 125 3.12 9.29 72.3 实施例 1 两者混合后预期防效 74.9 12.5% epoxiconazole suspension 125 3.12 9.29 72.3 Example 1 Expected control after mixing of both 74.9

30%咪鲜胺 ·氟环唑水乳剂（咪鲜胺，氟 30% prochloraz · flucyclazole water emulsion (methanol, fluoride)

150 3.43 3.61 90.2 环唑配比 =5:25) 150 3.43 3.61 90.2 Cycloazole ratio = 5:25)

25%咪鲜胺乳油 125 2.88 14.21 54.1 25% prochloraz cream 125 2.88 14.21 54.1

12.5%氟环唑悬浮剂 25 3.29 26.45 25.2 实施例 2 两者混合后预期防效 65.7 12.5% epoxiconazole suspending agent 25 3.29 26.45 25.2 Example 2 Anti-effects expected after mixing the two 65.7

150 2.98 3.36 89.5 环唑配比 =25:5) 150 2.98 3.36 89.5 Cyclicazole ratio =25:5)

25%咪鲜胺乳油 143 3.61 15.40 60.3 实施例 3 12.5%氟环唑悬浮剂 7 3.41 32.95 10.1 两者混合后预期防效 64.3 25% prochloraz cream 143 3.61 15.40 60.3 Example 3 12.5% epoxiconazole suspension 7 3.41 32.95 10.1 Expected control after mixing 64.3

42%咪鲜胺铜盐 ·氟环唑悬浮剂 (咪鲜 42% prochlorazin copper salt · epoxiconazole suspension agent

150 3.22 4.22 87.8 胺铜盐:氟环唑 =40:2) 150 3.22 4.22 87.8 Amine copper salt: epoxiconazole =40:2)

25%咪鲜胺乳油 7 3.25 33.22 4.9 25% prochloraz cream 7 3.25 33.22 4.9

12.5%氟环唑悬浮剂 143 2.78 5.65 81.1 实施例 4 两者混合后预期防效 82.0 12.5% epoxiconazole suspension 143 2.78 5.65 81.1 Example 4 Expected control after mixing the two 82.0

150 2.89 2.24 92.8 胺铜盐:氟环唑 =2:40) 150 2.89 2.24 92.8 Amine copper salt: epoxiconazole = 2:40)

25%咪鲜胺乳油 4 3.26 33.88 3.3 25% prochloraz cream 4 3.26 33.88 3.3

12.5%氟环唑悬浮剂 146 3.43 6.93 81.2 实施例 5 两者混合后预期防效 81.8 12.5% flucyclazole suspension 146 3.43 6.93 81.2 Example 5 Expected control after mixing the two 81.8

75%咪鲜胺锰盐 ·氟环唑水分散粒剂 75% prochloraz manganese salt · flucyclazole water dispersible granules

150 3.13 4.10 87.8 (咪鲜胺锰盐:氟环唑 =2:73) 150 3.13 4.10 87.8 (Mimiline manganese salt: epoxiconazole = 2:73)

25%咪鲜胺乳油 146 3.12 12.71 62.1 25% prochloraz emulsifiable concentrate 146 3.12 12.71 62.1

12.5%氟环唑悬浮剂 4 3.32 33.22 6.9 实施例 6 两者混合后预期防效 64.7 12.5% flucyclazole suspension 4 3.32 33.22 6.9 Example 6 Expected control after mixing the two 64.7

80%咪鲜胺锌盐 ·氟环唑水分散粒剂 80% prochloraz zinc salt · flucyclazole water dispersible granules

150 3.62 4.86 87.5 (咪鲜胺锰盐:氟环唑 =78:2) 150 3.62 4.86 87.5 (Mimiline manganese salt: epoxiconazole = 78:2)

实施例 Ί 25%咪鲜胺乳油 137 3.52 16.38 56.7 12.5%氟环唑悬浮剂 1 3 3.65 30.79 21.5 两者混合后预期防效 66.0Example Ί 25% prochloraz emulsifiable concentrate 137 3.52 16.38 56.7 12.5% epoxiconazole suspension 1 3 3.65 30.79 21.5 Expected control after mixing 66.0

85%咪鲜胺铜盐 ·氟环唑可湿性粉剂 85% prochloraz copper salt · flucyclazole wettable powder

150 3.78 3.70 90.9 (咪鲜胺铜盐:氟环唑 =78:7) 150 3.78 3.70 90.9 (Prochlorin copper salt: epoxiconazole = 78:7)

25%咪鲜胺乳油 75 3.45 24.66 33.5 25% prochloraz emulsifiable concentrate 75 3.45 24.66 33.5

12.5%氟环唑悬浮剂 75 3.29 19.73 44.2 实施例 8 两者混合后预期防效 62.9 12.5% epoxiconazole suspension 75 3.29 19.73 44.2 Example 8 Anti-effects expected after mixing the two 62.9

50%咪鲜胺铜盐 ·氟环唑可湿性粉剂 50% prochlorazin copper salt · epoxiconazole wettable powder

150 2.87 2.59 91.6 (咪鲜胺铜盐:氟环唑 =25:25) 150 2.87 2.59 91.6 (prochlorazide copper salt: epoxiconazole = 25:25)

25%咪鲜胺乳油 13 2.9 27.68 11.2 25% prochloraz emulsifiable concentrate 13 2.9 27.68 11.2

12.5%氟环唑悬浮剂 137 2.98 7.97 75.1 实施例 9 两者混合后预期防效 77.9 12.5% epoxiconazole suspending agent 137 2.98 7.97 75.1 Example 9 Anti-effects expected after mixing the two 77.9

55%咪鲜胺锰盐 ·氟环唑可湿性粉剂 55% prochloraz manganese salt · epoxiconazole wettable powder

150 2.85 2.91 90.5 (咪鲜胺锰盐:氟环唑 =5:50) 150 2.85 2.91 90.5 (Mimiline manganese salt: epoxiconazole = 5:50)

清水对 Clear water pair

3.21 34.5 3.21 34.5

照（CK) Photo (CK)

测定结果（表 6) 表明，咪鲜胺或咪鲜胺锰盐、咪鲜 JSf同盐、咪鲜辛盐与氟环唑复配对对防治小麦白粉病的防效明显提高，说明二者复酉 S寸白粉病有显著的增效作用。 The results of the determination (Table 6) indicate that the combination of prochloraz or prochloraz, the fresh salt of JSf, the salt of imixin and the epoxiconazole significantly improved the control effect against wheat powdery mildew, indicating that the two were reclaimed. S inch powdery mildew has a significant synergistic effect.

(2) 本发明的组合物对小麦赤霉病的田间药效试验分析 (2) Field efficacy test analysis of the composition of the present invention on wheat scab

表 7 咪鲜胺与氟环唑复酉 a寸小麦赤霉病的田间防效试验结果 Table 7 Results of field control trials of prochloraz and epoxiconazole

用量药第二次药后 11天序号舰續 (a.i.g/ 鶴情病情防效 ha) 指数指数 ( ) Dosage drug 11 days after the second drug No. Ships (a.i.g/ Heqing disease condition control ha) Index index ( )

25%咪鲜胺乳油 25 3.22 32.85 11.325% prochloraz cream 25 3.22 32.85 11.3

12.5%氟环唑悬浮剂 125 2.94 9.40 72.2 实施例 1 两者混合后预期防效 75.3 12.5% flucyclazole suspension 125 2.94 9.40 72.2 Example 1 Expected control after mixing 25.3

30%咪鲜胺 ·氟环唑水乳剂 30% prochloraz fluoxazole water emulsion

150 3.26 3.67 90.2 (咪鲜胺 ·氟环唑配比 =5:25) 150 3.26 3.67 90.2 (prochloraz & epoxiconazole = 5:25)

25%咪鲜胺乳油 125 2.91 17.70 47.1 实施例 2 25% prochloraz cream 125 2.91 17.70 47.1 Example 2

12.5%氟环唑悬浮剂 25 3.15 23.40 35.4 两者混合后预期防效 65.812.5% epoxiconazole suspension 25 3.15 23.40 35.4 Expected control effect after mixing the two 65.8

30%咪鲜胺 ·氟环唑水乳剂 30% prochloraz fluoxazole water emulsion

150 3.42 5.31 86.5 (咪鲜胺，氟环唑配比 =25:5) 150 3.42 5.31 86.5 (prochloraz, epoxiconazole = 25:5)

25%咪鲜胺乳油 143 3.26 16.46 56.1 实施例 3 12.5%氟环唑悬浮剂 7 3.14 30.04 16.8 两者混合后预期防效 63.5 25% prochloraz cream 143 3.26 16.46 56.1 Example 3 12.5% epoxiconazole suspension 7 3.14 30.04 16.8 Expected control after mixing 63.5

42%咪鲜胺铜盐 ·氟环唑悬浮剂 42% prochlorazin copper salt · epoxiconazole suspension

150 3.12 4.59 87.2 (咪鲜胺铜盐:氟环唑 =40:2) 150 3.12 4.59 87.2 (prochlorazide copper salt: epoxiconazole = 40:2)

25%咪鲜胺乳油 7 3.15 34.52 4.7 25% prochloraz emulsifiable concentrate 7 3.15 34.52 4.7

12.5%氟环唑悬浮剂 143 3.29 7.08 81.3 实施例 4 两者混合后预期防效 82.2 12.5% epoxiconazole suspending agent 143 3.29 7.08 81.3 Example 4 Anti-effects expected after mixing the two 82.2

150 3.52 4.66 88.5 (咪鲜胺铜盐:氟环唑 =2:40) 150 3.52 4.66 88.5 (prochlorazide copper salt: epoxiconazole = 2:40)

25%咪鲜胺乳油 4 3.21 35.77 3.1 25% prochloraz cream 4 3.21 35.77 3.1

12.5%氟环唑悬浮剂 146 3.32 6.83 82.1 实施例 5 两者混合后预期防效 82.7 12.5% epoxiconazole suspending agent 146 3.32 6.83 82.1 Example 5 Anti-effects expected after mixing the two 82.7

150 3.22 4.67 87.4 (咪鲜胺锰盐:氟环唑 =2:73) 150 3.22 4.67 87.4 (Mimiline manganese salt: epoxiconazole = 2:73)

25%咪鲜胺乳油 146 2.98 14.67 57.2 25% prochloraz emulsifiable concentrate 146 2.98 14.67 57.2

12.5%氟环唑悬浮剂 4 3.32 33.25 12.9 实施例 6 两者混合后预期防效 62.7 12.5% flucyclazole suspension 4 3.32 33.25 12.9 Example 6 Expected control after mixing 22.7

150 2.87 4.52 86.3 (咪鲜胺锰盐:氟环唑 =78:2) 150 2.87 4.52 86.3 (Mimiline manganese salt: epoxiconazole = 78:2)

25%咪鲜胺乳油 137 3.31 18.16 52.3 25% prochloraz emulsifiable concentrate 137 3.31 18.16 52.3

12.5%氟环唑悬浮剂 13 3.25 29.19 21.9 实施例 Ί 两者混合后预期防效 62.7 12.5% epoxiconazole suspending agent 13 3.25 29.19 21.9 Example 预期 Expected control after mixing the two 62.7

150 2.89 3.59 89.2 (咪鲜胺铜盐:氟环唑 =78:7) 150 2.89 3.59 89.2 (Prochlorin copper salt: epoxiconazole = 78:7)

25%咪鲜胺乳油 75 3.02 23.89 31.2 实施例 8 12.5%氟环唑悬浮剂 75 3.68 20.27 52.1 两者混合后预期防效 67.0 50%咪鲜胺铜盐 ·氟环唑可湿性粉剂 25% prochloraz cream 75 3.02 23.89 31.2 Example 8 12.5% epoxiconazole suspension 75 3.68 20.27 52.1 Expected control after mixing 67.0 50% prochlorazin copper salt epoxiconazole wettable powder

150 2.85 3.21 90.2 (咪鲜胺铜盐:氟环唑 =25:25) 150 2.85 3.21 90.2 (Prochlorin copper salt: epoxiconazole = 25:25)

25%咪鲜胺乳油 13 3.43 36.80 6.7 25% prochloraz emulsifiable concentrate 13 3.43 36.80 6.7

12.5%氟环唑悬浮剂 137 3.75 9.83 77.2 实施例 9 两者混合后预期防效 78.7 12.5% epoxiconazole suspending agent 137 3.75 9.83 77.2 Example 9 Anti-effects expected after mixing the two 78.7

150 3.43 4.77 87.9 (咪鲜胺锰盐:氟环唑 =5:50) 150 3.43 4.77 87.9 (Mimiline manganese salt: epoxiconazole = 5:50)

清水对 Clear water pair

3.32 38.18 3.32 38.18

照（CK) Photo (CK)

测定结果（表 7 ) 表明，咪鲜胺或咪鲜胺锰盐、咪鲜 JSf同盐、咪鲜辛盐与氟环唑复配对对防治小麦赤霉病的防效明显提高，说明二者复酉 S寸小麦赤霉病有显著的增效作用。 The results of the determination (Table 7) indicate that the combination of prochloraz or prochloraz, the JSf salt, the imipenem salt and the flucyclazole significantly improved the control effect against wheat scab, indicating that the two酉S inch wheat scab has a significant synergistic effect.

( 3 ) 本发明的组合物对小麦锈病的田间药效试验分析用量药第二次药后 11天序号舰續 (a.i.g/ 鶴情病情防效 ha) 指数指数 (%) (3) Analysis of the field efficacy test of the composition of the present invention on wheat rust. Dosage drug 11 days after the second drug No. Ship (a.i.g/ Hei disease condition control ha) Index index (%)

25%咪鲜胺乳油 25 3.92 41.56 11.225% prochloraz cream 25 3.92 41.56 11.2

12.5%氟环唑悬浮剂 125 3.92 12.54 73.2 实施例 1 两者混合后预期防效 76.2 12.5% epoxiconazole suspension 125 3.92 12.54 73.2 Example 1 Anti-effects expected after mixing the two 76.2

30%咪鲜胺 ·氟环唑水乳剂 30% prochloraz fluoxazole water emulsion

150 3.86 4.10 91.1 (咪鲜胺，氟环唑配比 =5:25) 150 3.86 4.10 91.1 (prochloraz, epoxiconazole = 5:25)

25%咪鲜胺乳油 125 3.88 21.73 53.1 25% prochloraz cream 125 3.88 21.73 53.1

12.5%氟环唑悬浮剂 25 3.39 29.83 26.3 实施例 2 两者混合后预期防效 65.4 12.5% epoxiconazole suspending agent 25 3.39 29.83 26.3 Example 2 Expected control after mixing of the two 65.4

30%咪鲜胺 ·氟环唑水乳剂 30% prochloraz fluoxazole water emulsion

150 3.98 5.27 88.9 (咪鲜胺，氟环唑配比 =25:5) 150 3.98 5.27 88.9 (prochloraz, epoxiconazole = 25:5)

25%咪鲜胺乳油 143 3.87 17.93 61.2 实施例 3 12.5%氟环唑悬浮剂 7 3.71 39.20 11.5 两者混合后预期防效 65.7 25% prochloraz cream 143 3.87 17.93 61.2 Example 3 12.5% epoxiconazole suspension 7 3.71 39.20 11.5 Expected control after mixing 65.7

42%咪鲜胺铜盐 ·氟环唑悬浮剂 150 3.82 5.88 87.1 (咪鲜胺铜盐:氟环唑 =40:2) 42% prochlorazin copper salt epoxiconazole suspending agent 150 3.82 5.88 87.1 (imipid amine copper salt: epoxiconazole = 40:2)

25%咪鲜胺乳油 7 3.75 42.76 4.5 25% prochloraz emulsifiable concentrate 7 3.75 42.76 4.5

12.5%氟环唑悬浮剂 143 2.75 5.91 82 实施例 4 两者混合后预期防效 82.8 12.5% epoxiconazole suspension 143 2.75 5.91 82 Example 4 Expected control after mixing the two 82.8

150 2.91 3.20 90.8 (咪鲜胺铜盐:氟环唑 =2:40) 150 2.91 3.20 90.8 (prochlorazide copper salt: epoxiconazole = 2:40)

25%咪鲜胺乳油 4 3.66 42.08 3.7 25% prochloraz cream 4 3.66 42.08 3.7

12.5%氟环唑悬浮剂 146 3.83 8.96 80.4 实施例 5 两者混合后预期防效 81.1 12.5% epoxiconazole suspending agent 146 3.83 8.96 80.4 Example 5 Anti-effects expected after mixing the two 81.1

150 3.73 5.75 87.1 (咪鲜胺锰盐:氟环唑 =2:73) 150 3.73 5.75 87.1 (Mimiline manganese salt: epoxiconazole = 2:73)

25%咪鲜胺乳油 146 3.82 15.64 65.7 25% prochloraz emulsifiable concentrate 146 3.82 15.64 65.7

12.5%氟环唑悬浮剂 4 3.62 39.85 7.8 实施例 6 两者混合后预期防效 68.4 12.5% epoxiconazole suspending agent 4 3.62 39.85 7.8 Example 6 Expected control after mixing of the two 68.4

150 3.61 5.82 86.5 (咪鲜胺锰盐:氟环唑 =78:2) 150 3.61 5.82 86.5 (Mimiline manganese salt: epoxiconazole = 78:2)

25%咪鲜胺乳油 137 3.98 20.15 57.6 25% prochloraz emulsifiable concentrate 137 3.98 20.15 57.6

12.5%氟环唑悬浮剂 13 3.85 35.67 22.4 实施例 Ί 两者混合后预期防效 67.1 12.5% epoxiconazole suspending agent 13 3.85 35.67 22.4 Example 预期 Expected control after mixing the two 67.1

150 3.75 5.73 87.2 (咪鲜胺铜盐:氟环唑 =78:7) 150 3.75 5.73 87.2 (Prochlorin copper salt: epoxiconazole = 78:7)

25%咪鲜胺乳油 75 3.95 30.84 34.6 25% prochloraz cream 75 3.95 30.84 34.6

12.5%氟环唑悬浮剂 75 3.54 23.20 45.1 实施例 8 两者混合后预期防效 64.1 12.5% epoxiconazole suspension 75 3.54 23.20 45.1 Example 8 Expected control after mixing of both 64.1

150 3.82 4.01 91.2 (咪鲜胺铜盐:氟环唑 =25:25) 150 3.82 4.01 91.2 (Prochlorin copper salt: epoxiconazole = 25:25)

25%咪鲜胺乳油 13 3.91 40.85 12.5 25% prochloraz emulsifiable concentrate 13 3.91 40.85 12.5

12.5%氟环唑悬浮剂 137 3.98 12.26 74.2 实施例 9 两者混合后预期防效 77.4 12.5% epoxiconazole suspension 137 3.98 12.26 74.2 Example 9 Anti-effects expected after mixing the two 77.4

150 3.82 5.38 88.2 (咪鲜胺锰盐:氟环唑 =5:50) 清水对 150 3.82 5.38 88.2 (Mimiline manganese salt: epoxiconazole = 5:50) Clear water pair

一延一延 3.65 43.58 一延照（CK) One extension and one extension 3.65 43.58 one extension (CK)

测定结果（表 8) 表明，咪鲜胺或咪鲜胺锰盐、咪鲜 JSf同盐、咪鲜辛盐与氟环唑复配对对防治小麦锈病的防效明显提高，说明二者复配对小麦锈病有显著的增效作用。延 The results of the determination (Table 8) showed that the combination of prochloraz or prochloraz, the fresh salt of Msf, the salt of imixin and the epoxiconazole significantly improved the control of wheat rust, indicating that the two were paired with wheat. Rust has a significant synergistic effect. Delay

(4) 本发明的组合物对小麦纹枯病的田间药效试验分析 (4) Field efficacy test analysis of the composition of the present invention on wheat sheath blight

表 9 咪鲜胺与氟环唑复酉 a寸小麦纹枯病的田间防效试验结果 Table 9 Results of field control trials of prochloraz and epoxiconazole in a inch of wheat sheath blight

25%咪鲜胺乳油 25 2.52 29.53 12.125% prochloraz cream 25 2.52 29.53 12.1

12.5%氟环唑悬浮剂 125 2.64 10.07 71.4 实施例 1 两者混合后预期防效一延一延一延 74.9 12.5% epoxiconazole suspending agent 125 2.64 10.07 71.4 Example 1 Expected control effect after mixing the two

30%咪鲜胺 ·氟环唑水乳剂 30% prochloraz fluoxazole water emulsion

150 2.21 3.51 88.1 (咪鲜胺 ·氟环唑配比 =5:25) 150 2.21 3.51 88.1 (prochloraz & epoxiconazole = 5:25)

25%咪鲜胺乳油 125 2.41 16.67 48.1 25% prochloraz cream 125 2.41 16.67 48.1

12.5%氟环唑悬浮剂 25 2.55 21.65 36.3 实施例 2 两者混合后预期防效一延一延一延 66.9 12.5% epoxiconazole suspending agent 25 2.55 21.65 36.3 Example 2 Expected control effect after mixing of the two

30%咪鲜胺 ·氟环唑水乳剂 30% prochloraz fluoxazole water emulsion

150 2.42 4.13 87.2 (咪鲜胺 ·氟环唑配比 =25:5) 150 2.42 4.13 87.2 (prochloraz & epoxiconazole = 25:5)

25%咪鲜胺乳油 143 2.26 13.47 55.3 实施例 3 12.5%氟环唑悬浮剂 7 2.34 25.67 17.7 两者混合后预期防效一延一延一延 63.2 25% prochloraz emulsifiable concentrate 143 2.26 13.47 55.3 Example 3 12.5% epoxiconazole suspending agent 7 2.34 25.67 17.7 Expected control effect after mixing of the two

150 2.72 4.46 87.7 (咪鲜胺铜盐:氟环唑 =40:2) 150 2.72 4.46 87.7 (prochlorazide copper salt: epoxiconazole = 40:2)

25%咪鲜胺乳油 7 2.65 33.49 5.2 25% prochloraz emulsifiable concentrate 7 2.65 33.49 5.2

12.5%氟环唑悬浮剂 143 2.25 5.97 80.1 实施例 4 两者混合后预期防效一延一延一延 81.1 12.5% epoxiconazole suspension 143 2.25 5.97 80.1 Example 4 Expected control after mixing the two.

150 2.52 3.73 88.9 (咪鲜胺铜盐:氟环唑 =2:40) 150 2.52 3.73 88.9 (Prochlorin copper salt: epoxiconazole = 2:40)

实施例 5 25%咪鲜胺乳油 4 2.41 30.97 3.6 12.5%氟环唑悬浮剂 146 2.32 5.26 83 两者混合后预期防效 83.6Example 5 25% prochloraz cream 4 2.41 30.97 3.6 12.5% epoxiconazole suspension 146 2.32 5.26 83 Expected control effect after mixing 83.6

150 2.51 3.65 89.1 (咪鲜胺锰盐:氟环唑 =2:73) 150 2.51 3.65 89.1 (Mimiline manganese salt: epoxiconazole = 2:73)

25%咪鲜胺乳油 146 2.31 13.52 56.1 25% prochloraz emulsifiable concentrate 146 2.31 13.52 56.1

12.5%氟环唑悬浮剂 4 2.32 26.72 13.6 实施例 6 两者混合后预期防效 62.1 12.5% epoxiconazole suspending agent 4 2.32 26.72 13.6 Example 6 Expected control after mixing of the two 62.1

150 2.81 5.54 85.2 (咪鲜胺锰盐:氟环唑 =78:2) 150 2.81 5.54 85.2 (Mimiline manganese salt: epoxiconazole = 78:2)

25%咪鲜胺乳油 137 2.32 14.81 52.1 25% prochloraz emulsifiable concentrate 137 2.32 14.81 52.1

12.5%氟环唑悬浮剂 13 2.25 22.35 25.5 实施例 Ί 两者混合后预期防效 64.3 12.5% epoxiconazole suspending agent 13 2.25 22.35 25.5 Example 预期 Expected control after mixing of both 64.3

150 2.39 4.11 87.1 (咪鲜胺铜盐:氟环唑 =78:7) 150 2.39 4.11 87.1 (Prochlorin copper salt: epoxiconazole = 78:7)

25%咪鲜胺乳油 75 2.22 19.56 33.9 25% prochloraz cream 75 2.22 19.56 33.9

12.5%氟环唑悬浮剂 75 2.68 16.72 53.2 实施例 8 两者混合后预期防效 69.1 12.5% epoxiconazole suspension 75 2.68 16.72 53.2 Example 8 Anti-effects expected after mixing the two 69.1

150 2.85 3.34 91.2 (咪鲜胺铜盐:氟环唑 =25:25) 150 2.85 3.34 91.2 (Prochlorin copper salt: epoxiconazole = 25:25)

25%咪鲜胺乳油 13 2.43 29.93 7.6 25% prochloraz emulsifiable concentrate 13 2.43 29.93 7.6

12.5%氟环唑悬浮剂 137 2.75 8.76 76.1 实施例 9 两者混合后预期防效 77.9 12.5% epoxiconazole suspending agent 137 2.75 8.76 76.1 Example 9 Anti-effects expected after mixing the two 77.9

150 2.41 4.40 86.3 (咪鲜胺锰盐:氟环唑 =5:50) 150 2.41 4.40 86.3 (Mimiline manganese salt: epoxiconazole = 5:50)

清水对 Clear water pair

2.42 32.26 2.42 32.26

照（CK) Photo (CK)

测定结果（表 9) 表明，咪鲜胺或咪鲜胺锰盐、咪鲜 JSf同盐、咪鲜辛盐与氟环唑复配对对防治小麦纹枯病的防效明显提高，说明二者复酉 S寸小麦纹枯病有显著的增效作用。 The results of the determination (Table 9) showed that the combination of prochloraz or prochloraz, the fresh salt of JSf, the salt of imixin and the epoxiconazole significantly improved the control effect against wheat sheath blight, indicating that the two酉S inch wheat sheath blight has a significant synergistic effect.

(4) 本发明的组合物对小麦全 t虫病的田间药效试验分析 (4) Field efficacy test analysis of the composition of the present invention on wheat whole worm disease

表 10咪鲜胺与氟环唑复酉 a寸小麦全蚀病的田间防效试验结果用量药第二次药后 11天序号舰續 (a.i.g/ 鶴情病情防效 ha) 指数指数 (%)Table 10 Field control trial results of prochloraz and epoxiconazole retanning a total wheat After the second dose of the drug, the serial number of the ship is continued for 11 days (aig/hess disease prevention effect ha) index index (%)

25%咪鲜胺乳油 25 2.64 28.41 10.225% prochloraz cream 25 2.64 28.41 10.2

12.5%氟环唑悬浮剂 125 2.12 7.27 71.4 实施例 1 两者混合后预期防效 74.3 12.5% epoxiconazole suspension 125 2.12 7.27 71.4 Example 1 Expected control after mixing of both 74.3

30%咪鲜胺 ·氟环唑水乳剂 30% prochloraz fluoxazole water emulsion

150 2.45 3.73 87.3 (咪鲜胺，氟环唑配比 =5:25) 150 2.45 3.73 87.3 (prochloraz, epoxiconazole = 5:25)

25%咪鲜胺乳油 125 2.41 13.54 53.1 25% prochloraz cream 125 2.41 13.54 53.1

12.5%氟环唑悬浮剂 25 2.29 20.22 26.3 实施例 2 两者混合后预期防效 65.4 12.5% epoxiconazole suspending agent 25 2.29 20.22 26.3 Example 2 Expected control after mixing of the two 65.4

30%咪鲜胺 ·氟环唑水乳剂 30% prochloraz fluoxazole water emulsion

150 2.98 4.93 86.2 (咪鲜胺，氟环唑配比 =25:5) 150 2.98 4.93 86.2 (prochloraz, epoxiconazole = 25:5)

25%咪鲜胺乳油 143 2.61 11.85 62.1 实施例 3 12.5%氟环唑悬浮剂 7 2.41 25.38 12.1 两者混合后预期防效 66.7 25% prochloraz cream 143 2.61 11.85 62.1 Example 3 12.5% epoxiconazole suspending agent 7 2.41 25.38 12.1 Expected control after mixing 66.7

150 2.51 4.12 86.3 (咪鲜胺铜盐:氟环唑 =40:2) 150 2.51 4.12 86.3 (Prochlorin copper salt: epoxiconazole = 40:2)

25%咪鲜胺乳油 7 2.25 25.56 5.2 25% prochloraz emulsifiable concentrate 7 2.25 25.56 5.2

12.5%氟环唑悬浮剂 143 2.62 6.18 80.3 实施例 4 两者混合后预期防效 81.3 12.5% epoxiconazole suspension 143 2.62 6.18 80.3 Example 4 Expected control after mixing the two 81.3

150 2.55 3.70 87.9 (咪鲜胺铜盐:氟环唑 =2:40) 150 2.55 3.70 87.9 (prochlorazide copper salt: epoxiconazole = 2:40)

25%咪鲜胺乳油 4 2.26 26.02 3.9 25% prochloraz cream 4 2.26 26.02 3.9

12.5%氟环唑悬浮剂 146 2.43 5.79 80.1 实施例 5 两者混合后预期防效 80.9 12.5% flucyclazole suspension 146 2.43 5.79 80.1 Example 5 Expected control after mixing of both 80.9

150 3.13 4.69 87.5 (咪鲜胺锰盐:氟环唑 =2:73) 150 3.13 4.69 87.5 (Mimiline manganese salt: epoxiconazole = 2:73)

25%咪鲜胺乳油 146 2.12 8.69 65.8 实施例 6 12.5%氟环唑悬浮剂 4 2.32 25.80 7.2 两者混合后预期防效 68.3 80%咪鲜胺锌盐 ·氟环唑水分散粒剂 25% prochloraz emulsifiable concentrate 146 2.12 8.69 65.8 Example 6 12.5% epoxiconazole suspending agent 4 2.32 25.80 7.2 Expected control effect after mixing 68.3 80% prochloraz salt · flucyclazole water dispersible granules

150 2.62 4.33 86.2 (咪鲜胺锰盐:氟环唑 =78:2) 150 2.62 4.33 86.2 (Mimiline manganese salt: epoxiconazole = 78:2)

25%咪鲜胺乳油 137 2.52 12.95 57.1 25% prochloraz emulsifiable concentrate 137 2.52 12.95 57.1

12.5%氟环唑悬浮剂 13 2.25 21.78 19.2 实施例 Ί 两者混合后预期防效 65.3 12.5% epoxiconazole suspending agent 13 2.25 21.78 19.2 Example 预期 Expected control after mixing of the two 65.3

150 2.18 2.82 89.2 (咪鲜胺铜盐:氟环唑 =78:7) 150 2.18 2.82 89.2 (Prochlorin copper salt: epoxiconazole = 78:7)

25%咪鲜胺乳油 75 2.45 19.93 32.1 25% prochloraz cream 75 2.45 19.93 32.1

12.5%氟环唑悬浮剂 75 2.22 14.55 45.3 实施例 8 两者混合后预期防效 62.9 12.5% epoxiconazole suspension 75 2.22 14.55 45.3 Example 8 Expected control after mixing the two 62.9

150 2.57 4.07 86.8 (咪鲜胺铜盐:氟环唑 =25:25) 150 2.57 4.07 86.8 (Prochlorin copper salt: epoxiconazole = 25:25)

25%咪鲜胺乳油 13 2.19 23.49 10.5 25% prochloraz emulsifiable concentrate 13 2.19 23.49 10.5

12.5%氟环唑悬浮剂 137 2.48 7.64 74.3 实施例 9 两者混合后预期防效 77.0 12.5% epoxiconazole suspension 137 2.48 7.64 74.3 Example 9 Anti-effects expected after mixing the two 77.0

150 2.35 3.32 88.2 (咪鲜胺锰盐:氟环唑 =5:50) 150 2.35 3.32 88.2 (Mimiline manganese salt: epoxiconazole = 5:50)

清水对 Clear water pair

2.32 27.8 2.32 27.8

照（CK) Photo (CK)

测定结果（表 10)表明，咪鲜胺或咪鲜胺锰盐、咪鲜 JSf同盐、咪鲜辛盐与氟环唑复配对对防治小麦全蚀病的防效明显提高，说明二者复酉 S寸小麦全蚀病有显著的增效作用。 The results of the determination (Table 10) show that the combination of prochloraz or prochloraz, the fresh salt of JSf, the salt of imixin and the epoxiconazole significantly improved the control effect against wheat all-etching disease, indicating that the two酉S inch wheat total etch has a significant synergistic effect.

Claims

权利要求书 Claim

、一种增效作用的杀菌剂组合物防治小麦真菌性病害的用途，所述的组合物包含活性组分和，其中活性组分为咪鲜胺或其在农业上可接受的金属盐类化合物，活性组分为氟环唑，两组分之间的重量比为〜。 A use of a synergistic fungicidal composition for controlling a fungal disease of wheat, said composition comprising an active ingredient and wherein the active ingredient is prochloraz or an agriculturally acceptable metal salt thereof The active component is epoxiconazole, and the weight ratio between the two components is ~.

、根据权利要求所述的用途，其特征在于所述的咪鲜胺金属盐类化合物选自咪鲜胺锰盐、咪鲜胺锌盐或咪鲜胺铜盐其中的一种化合物。 The use according to the claims, characterized in that the prochloraz metal salt compound is selected from the group consisting of a prochloraz manganese salt, a prolamamine zinc salt or a prochloraz copper salt.

、根据权利要求 1所述的用途，其特征在于所述的组合物中活性组分 a和活性组分 b的重量比为 1 :30〜。 The use according to Claim 1, characterized in that the weight ratio of the active component a to the active component b in the composition is 1:30~.

4、根据权利要求 3所述的用途，其特征在于所述的咪鲜胺金属盐类化合物为咪鲜胺铜盐。 4. Use according to claim 3, characterized in that the prochloraz metal salt compound is a prochlorazin copper salt.

5、根据权利要求 3所述的用途，其特征在于所述的咪鲜胺金属盐类化合物为咪鲜胺锰盐。 The use according to claim 3, characterized in that the prochloraz metal salt compound is a prochloraz manganese salt.

6、根据权利要求 3所述的用途，其特征在于所述的咪鲜胺金属盐类化合物为咪鲜胺锌盐。 6. Use according to claim 3, characterized in that the prochloraz metal salt compound is a prolamamine zinc salt.

7、根据权利要求 3所述的用途，其特征在于活性组分咪鲜胺铜盐和活性组分氟环唑的重量比为 1 :30〜30: 1。 7. Use according to claim 3, characterized in that the weight ratio of the active component prochlorazin salt to the active component epoxiconazole is from 1:30 to 30:1.

8、根据权利要求 3所述的用途，其特征在于活性组分咪鲜胺锰盐盐和活性组分氟环唑的重量比为 1 :30〜30:1。 8. Use according to claim 3, characterized in that the weight ratio of the active ingredient prochlorazin salt to the active ingredient epoxiconazole is from 1:30 to 30:1.

9、根据权利要求 3所述的用途，其特征在于活性组分咪鲜胺锌盐盐和活性组分氟环唑的重量比为 1 :30〜30:1。 9. Use according to claim 3, characterized in that the weight ratio of the active ingredient prochloraz salt to the active ingredient epoxiconazole is from 1:30 to 30:1.

10、根据权利要求 1-9的用途，其特征在于小麦真菌性病害为小麦锈病、白粉病、赤霉病、纹枯病、全蚀病。 10. Use according to claims 1-9, characterized in that the fungal diseases of wheat are wheat rust, powdery mildew, scab, sheath blight, total erosion.