WO2014023853A3 - Tertiary amines for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines - Google Patents

Tertiary amines for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines Download PDF

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Publication number
WO2014023853A3
WO2014023853A3 PCT/EP2013/072052 EP2013072052W WO2014023853A3 WO 2014023853 A3 WO2014023853 A3 WO 2014023853A3 EP 2013072052 W EP2013072052 W EP 2013072052W WO 2014023853 A3 WO2014023853 A3 WO 2014023853A3
Authority
WO
WIPO (PCT)
Prior art keywords
direct injection
spark ignition
injector nozzle
ignition engines
injection spark
Prior art date
Application number
PCT/EP2013/072052
Other languages
French (fr)
Other versions
WO2014023853A2 (en
Inventor
Marc Walter
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of WO2014023853A2 publication Critical patent/WO2014023853A2/en
Publication of WO2014023853A3 publication Critical patent/WO2014023853A3/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/06—Use of additives to fuels or fires for particular purposes for facilitating soot removal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/221—Organic compounds containing nitrogen compounds of uncertain formula; reaction products where mixtures of compounds are obtained
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C10L1/2387—Polyoxyalkyleneamines (poly)oxyalkylene amines and derivatives thereof (substituted by a macromolecular group containing 30C)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/0415—Light distillates, e.g. LPG, naphtha
    • C10L2200/0423—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/02—Specifically adapted fuels for internal combustion engines
    • C10L2270/023—Specifically adapted fuels for internal combustion engines for gasoline engines

Abstract

Use of a tertiary hydrocarbyl amine with C1-to C20-hydrocarbyl residues, the overall number of carbon atoms not exceeding 30, as an additive in gasoline for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines. A fuel additive composition essentially comprising nitrogen-containing dispersants, carrier oils, the above tertiary hydrocarbyl amines and optionally further friction modifiers. A fuel composition comprising a major amount of gasoline and a minor amount of the above fuel additive composition.
PCT/EP2013/072052 2012-11-06 2013-10-22 Tertiary amines for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines WO2014023853A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12191374.3 2012-11-06
EP12191374 2012-11-06

Publications (2)

Publication Number Publication Date
WO2014023853A2 WO2014023853A2 (en) 2014-02-13
WO2014023853A3 true WO2014023853A3 (en) 2014-04-10

Family

ID=47115609

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2013/072052 WO2014023853A2 (en) 2012-11-06 2013-10-22 Tertiary amines for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines

Country Status (1)

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WO (1) WO2014023853A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11201909437RA (en) 2017-04-11 2019-11-28 Basf Se Alkoxylated amines as fuel additives
CN116829684A (en) 2021-01-27 2023-09-29 巴斯夫欧洲公司 Branched primary alkylamines as additives for gasoline fuels
EP4105301A1 (en) 2021-06-15 2022-12-21 Basf Se New gasoline additive packages
WO2022263244A1 (en) 2021-06-16 2022-12-22 Basf Se Quaternized betaines as additives in fuels
DE102022131356A1 (en) 2022-11-28 2023-01-12 Basf Se Formamidines as fuel additives
DE102022132342A1 (en) 2022-12-06 2023-01-26 Basf Se Guanidinium salts as fuel additives

Citations (11)

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EP0385633A1 (en) * 1989-03-02 1990-09-05 Ethyl Petroleum Additives, Inc. Middle distillate fuel having improved storage stability
EP0869163A1 (en) * 1997-04-03 1998-10-07 Mobil Oil Corporation Method for reducing engine friction
WO2002079353A1 (en) * 2001-03-29 2002-10-10 The Lubrizol Corporation Gasoline additive concentrate composition and fuel composition and method thereof
EP1293553A2 (en) * 2001-09-14 2003-03-19 Ethyl Corporation Fuels compositions for direct injection gasoline engines
WO2003083020A2 (en) * 2002-03-28 2003-10-09 The Lubrizol Corporation Method of operating internal combustion engine by introducing detergent into combustion chamber
WO2004050806A2 (en) * 2002-12-02 2004-06-17 Basf Aktiengesellschaft Use of amines and/or mannich adducts in fuel and lubricant compositions for direct injection spark ignition engines
WO2007053787A1 (en) * 2005-11-04 2007-05-10 The Lubrizol Corporation Fuel additive concentrate composition and fuel composition and method thereof
WO2008082916A1 (en) * 2006-12-28 2008-07-10 The Lubrizol Corporation Fuel additives for use in high level alcohol-gasoline blends
WO2009074608A1 (en) * 2007-12-11 2009-06-18 Basf Se Amines as intake valve clean-up boosters
WO2013174619A1 (en) * 2012-05-25 2013-11-28 Basf Se Tertiary amines for reducing injector nozzle fouling in direct injection spark ignition engines

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GB8329082D0 (en) 1983-11-01 1983-12-07 Bp Chem Int Ltd Low molecular weight polymers of 1-olefins
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE659210C (en) * 1935-04-18 1938-04-28 I G Farbenindustrie Akt Ges Motor fuel
EP0385633A1 (en) * 1989-03-02 1990-09-05 Ethyl Petroleum Additives, Inc. Middle distillate fuel having improved storage stability
EP0869163A1 (en) * 1997-04-03 1998-10-07 Mobil Oil Corporation Method for reducing engine friction
WO2002079353A1 (en) * 2001-03-29 2002-10-10 The Lubrizol Corporation Gasoline additive concentrate composition and fuel composition and method thereof
EP1293553A2 (en) * 2001-09-14 2003-03-19 Ethyl Corporation Fuels compositions for direct injection gasoline engines
WO2003083020A2 (en) * 2002-03-28 2003-10-09 The Lubrizol Corporation Method of operating internal combustion engine by introducing detergent into combustion chamber
WO2004050806A2 (en) * 2002-12-02 2004-06-17 Basf Aktiengesellschaft Use of amines and/or mannich adducts in fuel and lubricant compositions for direct injection spark ignition engines
WO2007053787A1 (en) * 2005-11-04 2007-05-10 The Lubrizol Corporation Fuel additive concentrate composition and fuel composition and method thereof
WO2008082916A1 (en) * 2006-12-28 2008-07-10 The Lubrizol Corporation Fuel additives for use in high level alcohol-gasoline blends
WO2009074608A1 (en) * 2007-12-11 2009-06-18 Basf Se Amines as intake valve clean-up boosters
WO2013174619A1 (en) * 2012-05-25 2013-11-28 Basf Se Tertiary amines for reducing injector nozzle fouling in direct injection spark ignition engines

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Publication number Publication date
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