WO2014013440A3 - Matériau composite catalyseur-materiau a changement de phase, procédés de fabrication associés et utilisation d'un tel matériau dans des réactions catalytiques - Google Patents

Matériau composite catalyseur-materiau a changement de phase, procédés de fabrication associés et utilisation d'un tel matériau dans des réactions catalytiques Download PDF

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Publication number
WO2014013440A3
WO2014013440A3 PCT/IB2013/055861 IB2013055861W WO2014013440A3 WO 2014013440 A3 WO2014013440 A3 WO 2014013440A3 IB 2013055861 W IB2013055861 W IB 2013055861W WO 2014013440 A3 WO2014013440 A3 WO 2014013440A3
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phase
catalyst
manufacturing methods
catalytic reactions
related manufacturing
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PCT/IB2013/055861
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English (en)
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WO2014013440A2 (fr
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Laurent Bedel
Jérôme GAVILLET
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Commissariat A L'energie Atomique Et Aux Energies Alternatives
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Application filed by Commissariat A L'energie Atomique Et Aux Energies Alternatives filed Critical Commissariat A L'energie Atomique Et Aux Energies Alternatives
Priority to EP13767092.3A priority Critical patent/EP2874746A2/fr
Priority to US14/415,462 priority patent/US20150190796A1/en
Publication of WO2014013440A2 publication Critical patent/WO2014013440A2/fr
Publication of WO2014013440A3 publication Critical patent/WO2014013440A3/fr

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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0238—Impregnation, coating or precipitation via the gaseous phase-sublimation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/347—Ionic or cathodic spraying; Electric discharge
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0405—Apparatus
    • C07C1/041—Reactors
    • C07C1/0415—Reactors with moving catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/152—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
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    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/06—Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice versa
    • C09K5/063—Materials absorbing or liberating heat during crystallisation; Heat storage materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • F28D20/023—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat the latent heat storage material being enclosed in granular particles or dispersed in a porous, fibrous or cellular structure
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
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    • B01J2531/002—Materials
    • B01J2531/005—Catalytic metals
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    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
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Abstract

Matériau à particules hybrides (1) constituées chacune d'une particule (2) d'un matériau à changement de phase (MCP) en interface avec un matériau catalytique (3) sous forme solide, les dimensions des particules hybrides étant comprises entre 0,1mm et 10 mm,de préférenceentre1 mm et 5 mm.
PCT/IB2013/055861 2012-07-17 2013-07-17 Matériau composite catalyseur-materiau a changement de phase, procédés de fabrication associés et utilisation d'un tel matériau dans des réactions catalytiques WO2014013440A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP13767092.3A EP2874746A2 (fr) 2012-07-17 2013-07-17 Matériau composite catalyseur-materiau a changement de phase, procédés de fabrication associés et utilisation d'un tel matériau dans des réactions catalytiques
US14/415,462 US20150190796A1 (en) 2012-07-17 2013-07-17 Composite Material Consisting of a Catalyst/Phase-Change Material, Related Manufacturing Methods and Use of Such a Material in Catalytic Reactions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1256881A FR2993481B1 (fr) 2012-07-17 2012-07-17 Materiau composite catalyseur-materiau a changement de phase, procedes de fabrication associes et utilisation d'un tel materiau dans des reactions catalytiques
FR1256881 2012-07-17

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WO2014013440A2 WO2014013440A2 (fr) 2014-01-23
WO2014013440A3 true WO2014013440A3 (fr) 2014-04-17

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US (1) US20150190796A1 (fr)
EP (1) EP2874746A2 (fr)
FR (1) FR2993481B1 (fr)
WO (1) WO2014013440A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111013509B (zh) * 2019-12-11 2021-08-10 中国科学院化学研究所 一种无机盐类相变储能微胶囊及其制备方法与应用

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9765251B2 (en) * 2012-12-18 2017-09-19 University Of South Florida Encapsulation of thermal energy storage media
DE102014226282A1 (de) * 2014-12-17 2016-06-23 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Reaktor zur Dehydrierung von flüssigen Wasserstoffträgermaterialien
US10785839B2 (en) * 2016-06-27 2020-09-22 Kevin Joseph Hathaway Thermal ballast
WO2018226635A1 (fr) * 2017-06-05 2018-12-13 North Carolina State University Oxydes mixtes favorisés pour oxydation partielle de méthane "basse température" en l'absence d'oxydants gazeux
EP4061522A4 (fr) * 2019-11-20 2023-12-27 Lummus Technology LLC Stockage de chaleur dans des réacteurs chimiques
CN113790445A (zh) * 2021-08-16 2021-12-14 昆明理工大学 一种天然气催化燃烧蓄热型红外加热物体的方法
CN114707329B (zh) * 2022-04-02 2024-04-09 太原理工大学 一种应用于颗粒相变储能材料热力学非连续计算方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10240956A1 (de) * 2002-09-05 2004-03-18 Christian-Albrechts-Universität Zu Kiel Heterogene Kern-Schale Mikrogele mit mehrstufigem Schaltverhalten
US20080272331A1 (en) * 2006-08-21 2008-11-06 Mohapatra Satish C Hybrid nanoparticles
DE102008060259A1 (de) * 2008-12-03 2010-06-10 Bayer Technology Services Gmbh Katalysator für Oxidationsreaktionen in Gegenwart von Chlorwasserstoff und/oder Chlor und Verfahren zu dessen Herstellung, sowie dessen Verwendung

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1159685A (fr) 1956-08-10 1958-07-01 Trefileries Et Laminoirs De Pr Procédé perfectionné d'étirage sur mandrin long avec déchaussage hydraulique et dispositifs pour sa mise en oeuvre
FR2934600B1 (fr) 2008-07-31 2013-01-11 Commissariat Energie Atomique Capsules ou agglomerats gelifies de nanoobjets ou nanostructures, materiaux nanocomposites a matrice polymere les comprenant, et leurs procedes de preparation.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10240956A1 (de) * 2002-09-05 2004-03-18 Christian-Albrechts-Universität Zu Kiel Heterogene Kern-Schale Mikrogele mit mehrstufigem Schaltverhalten
US20080272331A1 (en) * 2006-08-21 2008-11-06 Mohapatra Satish C Hybrid nanoparticles
DE102008060259A1 (de) * 2008-12-03 2010-06-10 Bayer Technology Services Gmbh Katalysator für Oxidationsreaktionen in Gegenwart von Chlorwasserstoff und/oder Chlor und Verfahren zu dessen Herstellung, sowie dessen Verwendung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
MINGHUI ZHANG ET AL: "Encapsulated nano-heat-sinks for thermal management of heterogeneous chemical reactions", NANOSCALE, vol. 2, no. 12, 1 January 2010 (2010-01-01), pages 2790 - 2797, XP055058637, ISSN: 2040-3364, DOI: 10.1039/c0nr00585a *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111013509B (zh) * 2019-12-11 2021-08-10 中国科学院化学研究所 一种无机盐类相变储能微胶囊及其制备方法与应用

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EP2874746A2 (fr) 2015-05-27
US20150190796A1 (en) 2015-07-09
WO2014013440A2 (fr) 2014-01-23
FR2993481A1 (fr) 2014-01-24
FR2993481B1 (fr) 2015-07-03

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