WO2013150305A3 - Alcohol production process - Google Patents
Alcohol production process Download PDFInfo
- Publication number
- WO2013150305A3 WO2013150305A3 PCT/GB2013/050881 GB2013050881W WO2013150305A3 WO 2013150305 A3 WO2013150305 A3 WO 2013150305A3 GB 2013050881 W GB2013050881 W GB 2013050881W WO 2013150305 A3 WO2013150305 A3 WO 2013150305A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- catalyst
- precipitate
- polyhydric alcohol
- palladium
- iron
- Prior art date
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 4
- 239000002244 precipitate Substances 0.000 abstract 4
- 150000005846 sugar alcohols Polymers 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 238000001354 calcination Methods 0.000 abstract 2
- 238000007327 hydrogenolysis reaction Methods 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 239000011949 solid catalyst Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 238000000975 co-precipitation Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000002505 iron Chemical class 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000002105 nanoparticle Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
- 150000002940 palladium Chemical class 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8906—Iron and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/60—Platinum group metals with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B01J35/393—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
- B01J37/033—Using Hydrolysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
The invention provides a process for producing a monohydric alcohol by hydrogenolysis of a polyhydric alcohol, which process comprises treating a polyhydric alcohol with hydrogen in the presence of a solid catalyst, which solid catalyst comprises (a) iron oxide and (b) a metal which is a noble metal or nickel. The invention further provides a catalyst, which catalyst comprises iron oxide and nanoparticles which comprise palladium. A process for producing the catalyst is also provided, which process comprises: (1) a co-precipitation step, comprising contacting (a) a solution, which solution comprises a palladium salt and an iron salt dissolved in a solvent, with (b) a base, to produce a precipitate which comprises one or more compounds comprising said iron and said palladium; (2) a separation step, comprising separating the precipitate from the solvent; and (3) a calcination step, comprising calcining the precipitate by heating the precipitate in air. Further provided is the use of the catalyst of the invention for the hydrogenolysis of a polyhydric alcohol.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1206042.2 | 2012-04-04 | ||
GBGB1206042.2A GB201206042D0 (en) | 2012-04-04 | 2012-04-04 | Alcohol production process |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2013150305A2 WO2013150305A2 (en) | 2013-10-10 |
WO2013150305A3 true WO2013150305A3 (en) | 2013-11-28 |
Family
ID=46160329
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2013/050881 WO2013150305A2 (en) | 2012-04-04 | 2013-04-04 | Alcohol production process |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB201206042D0 (en) |
WO (1) | WO2013150305A2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107262045A (en) * | 2017-08-03 | 2017-10-20 | 中国科学院化学研究所 | Application of the fullerene MOF composites in volatile organic matter is removed |
CN107490610A (en) * | 2017-09-05 | 2017-12-19 | 济南大学 | A kind of chiral MOF graphene hybrid materials and its preparation method and application |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103922893B (en) * | 2014-04-19 | 2015-11-25 | 青岛科技大学 | A kind of composite catalyst hydrogenolysis catalysis of glycerin prepares the method for 1,2-PD |
CN104086369B (en) * | 2014-06-18 | 2017-04-05 | 华南理工大学 | The method that manioc waste hydrogenolysis prepares lower alcohol |
CN104492436B (en) * | 2014-12-12 | 2016-09-07 | 中国科学院西双版纳热带植物园 | A kind of carbon back magnetic solid base catalyst and application thereof |
CN106565393A (en) * | 2015-10-13 | 2017-04-19 | 吴倍任 | Composite material for catalysis of hydrogenolysis reaction and preparation method and application thereof |
JP2018153735A (en) * | 2017-03-16 | 2018-10-04 | 株式会社東芝 | Chemical reaction system |
CN106902842A (en) * | 2017-03-20 | 2017-06-30 | 北京工业大学 | A kind of preparation and application for deriving load type palladium catalyst of the carbon-based material as carrier with MOFs |
CN109304213B (en) * | 2017-07-28 | 2021-04-02 | 中国科学院宁波材料技术与工程研究所 | Hydrocracking catalyst, and preparation method and application thereof |
CN108579810B (en) * | 2018-03-12 | 2020-09-11 | 北京科技大学 | Method for synthesizing precious metal MOFs composite material |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1826180A1 (en) * | 2004-10-21 | 2007-08-29 | Peking University | A composite material composed of nanoparticles of transition metal and magnetic ferric oxide, a methode of preparing the same, and uses of the same |
WO2008156320A1 (en) * | 2007-06-19 | 2008-12-24 | Postech Academy-Industry Foundation | Magnetic nanocatalyst composition and method for the preparation thereof |
US20090088317A1 (en) * | 2007-09-28 | 2009-04-02 | Frye Jr John G | Multi-metal reduction catalysts and methods of producing reduction catalysts |
-
2012
- 2012-04-04 GB GBGB1206042.2A patent/GB201206042D0/en not_active Ceased
-
2013
- 2013-04-04 WO PCT/GB2013/050881 patent/WO2013150305A2/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1826180A1 (en) * | 2004-10-21 | 2007-08-29 | Peking University | A composite material composed of nanoparticles of transition metal and magnetic ferric oxide, a methode of preparing the same, and uses of the same |
WO2008156320A1 (en) * | 2007-06-19 | 2008-12-24 | Postech Academy-Industry Foundation | Magnetic nanocatalyst composition and method for the preparation thereof |
US20090088317A1 (en) * | 2007-09-28 | 2009-04-02 | Frye Jr John G | Multi-metal reduction catalysts and methods of producing reduction catalysts |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107262045A (en) * | 2017-08-03 | 2017-10-20 | 中国科学院化学研究所 | Application of the fullerene MOF composites in volatile organic matter is removed |
CN107490610A (en) * | 2017-09-05 | 2017-12-19 | 济南大学 | A kind of chiral MOF graphene hybrid materials and its preparation method and application |
CN107490610B (en) * | 2017-09-05 | 2019-09-27 | 济南大学 | A kind of chirality MOF- graphene hybrid material and its preparation method and application |
Also Published As
Publication number | Publication date |
---|---|
WO2013150305A2 (en) | 2013-10-10 |
GB201206042D0 (en) | 2012-05-16 |
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