WO2013123023A3 - Fiber reinforced polymer composite composition with aligned nanofibers - Google Patents

Fiber reinforced polymer composite composition with aligned nanofibers Download PDF

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Publication number
WO2013123023A3
WO2013123023A3 PCT/US2013/025902 US2013025902W WO2013123023A3 WO 2013123023 A3 WO2013123023 A3 WO 2013123023A3 US 2013025902 W US2013025902 W US 2013025902W WO 2013123023 A3 WO2013123023 A3 WO 2013123023A3
Authority
WO
WIPO (PCT)
Prior art keywords
adhesive composition
reinforced polymer
fiber reinforced
reinforcing fiber
polymer composite
Prior art date
Application number
PCT/US2013/025902
Other languages
French (fr)
Other versions
WO2013123023A2 (en
Inventor
Felix N. Nguyen
Kenichi Yoshioka
Swezin Than TUN
Original Assignee
Toray Industries, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries, Inc. filed Critical Toray Industries, Inc.
Publication of WO2013123023A2 publication Critical patent/WO2013123023A2/en
Publication of WO2013123023A3 publication Critical patent/WO2013123023A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/12—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B32B2260/023—Two or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/202—Conductive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/748—Releasability
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • D01F9/1273—Alkenes, alkynes
    • D01F9/1275—Acetylene

Abstract

A fiber reinforced polymer composition comprises a reinforcing fiber, an adhesive composition, and a nanofiber sheet. Nanofibers of the nanofiber sheet are spatially located in the fiber reinforced polymer composition, on a plane parallel to the reinforcing fiber, and aligned at an angle with respect to the axis of the reinforcing fiber, such that both mechanical and z-direction electrical conductivity of the composite are substantially improved. The nanofiber sheet is located spatially located between a layer of the reinforcing fibers and a layer of the adhesive composition, between two adhesive composition layers of a same or different kinds, between two reinforcing fiber layers of a same or different kinds, or on one or both surfaces of the layer of the reinforcing fibers impregnated by the adhesive composition, wherein at least one of the reinforcing fiber or the nanofiber is dry or partially or fully impregnated by the adhesive composition.
PCT/US2013/025902 2012-02-14 2013-02-13 Fiber reinforced polymer composite composition with aligned nanofibers WO2013123023A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201261598808P 2012-02-14 2012-02-14
US61/598,808 2012-02-14
US201361755910P 2013-01-23 2013-01-23
US61/755,910 2013-01-23

Publications (2)

Publication Number Publication Date
WO2013123023A2 WO2013123023A2 (en) 2013-08-22
WO2013123023A3 true WO2013123023A3 (en) 2015-07-09

Family

ID=48984880

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/025902 WO2013123023A2 (en) 2012-02-14 2013-02-13 Fiber reinforced polymer composite composition with aligned nanofibers

Country Status (1)

Country Link
WO (1) WO2013123023A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10978629B2 (en) 2014-12-05 2021-04-13 Unm Rainforest Innovations Method of dispersing nanoparticles in different mediums and methods to achieve superior thermoelectric performances in carbon nanotube polymer systems
US11633925B2 (en) 2019-08-09 2023-04-25 The Boeing Company System and method for improving thermoset-thermoplastic interface adhesion
US11479026B2 (en) * 2019-08-09 2022-10-25 The Boeing Company System and method for improving thermoset-thermoplastic interface adhesion
KR102473438B1 (en) * 2020-05-11 2022-12-02 재단법인 아산사회복지재단 Membrane for forming biomaterial structure comprising artificial blood vessel, artificial biomaterial structure comprising the membrane and method for manufacturing the same
CN114933778B (en) * 2022-04-01 2023-11-03 航天特种材料及工艺技术研究所 Automatic wire-laying prepreg with crosslinked reticular toughening structure and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060047052A1 (en) * 1999-12-07 2006-03-02 Barrera Enrique V Oriented nanofibers embedded in polymer matrix
US20060057350A1 (en) * 2002-10-23 2006-03-16 Takashi Ochi Nanofiber aggregate, polymer alloy fiber, hybrid fiber, fibrous structures, and processes for production of them
US20060110599A1 (en) * 2002-12-27 2006-05-25 Masato Honma Layered product, electromagnetic-shielding molded object, and processes for producing these
US20090220409A1 (en) * 2008-03-03 2009-09-03 Performance Polymer Solutions, Inc. Continuous process for the production of carbon nanofiber reinforced continuous fiber preforms and composites made therefrom
JP2010260891A (en) * 2009-04-30 2010-11-18 Toyobo Co Ltd Prepreg using surface-modified fiber

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060047052A1 (en) * 1999-12-07 2006-03-02 Barrera Enrique V Oriented nanofibers embedded in polymer matrix
US20060057350A1 (en) * 2002-10-23 2006-03-16 Takashi Ochi Nanofiber aggregate, polymer alloy fiber, hybrid fiber, fibrous structures, and processes for production of them
US20060110599A1 (en) * 2002-12-27 2006-05-25 Masato Honma Layered product, electromagnetic-shielding molded object, and processes for producing these
US20090220409A1 (en) * 2008-03-03 2009-09-03 Performance Polymer Solutions, Inc. Continuous process for the production of carbon nanofiber reinforced continuous fiber preforms and composites made therefrom
JP2010260891A (en) * 2009-04-30 2010-11-18 Toyobo Co Ltd Prepreg using surface-modified fiber

Also Published As

Publication number Publication date
WO2013123023A2 (en) 2013-08-22

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