WO2013106017A3 - Binder-converted aluminosilicate x-type zeolite compositions with low lta-type zeolite - Google Patents

Binder-converted aluminosilicate x-type zeolite compositions with low lta-type zeolite Download PDF

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Publication number
WO2013106017A3
WO2013106017A3 PCT/US2012/032255 US2012032255W WO2013106017A3 WO 2013106017 A3 WO2013106017 A3 WO 2013106017A3 US 2012032255 W US2012032255 W US 2012032255W WO 2013106017 A3 WO2013106017 A3 WO 2013106017A3
Authority
WO
WIPO (PCT)
Prior art keywords
zeolite
type zeolite
binder
composition
converted
Prior art date
Application number
PCT/US2012/032255
Other languages
French (fr)
Other versions
WO2013106017A2 (en
Inventor
Jack E. Hurst
Linda S. Cheng
Robert W. Broach
Original Assignee
Uop Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc filed Critical Uop Llc
Priority to CN201280013151.XA priority Critical patent/CN103517876A/en
Priority to JP2014503971A priority patent/JP2014522357A/en
Priority to SG2013057849A priority patent/SG192213A1/en
Priority to RU2013147991/05A priority patent/RU2544673C1/en
Priority to KR1020137022035A priority patent/KR101504053B1/en
Priority to BR112013021043A priority patent/BR112013021043A2/en
Priority to EP12864937.3A priority patent/EP2697166A4/en
Publication of WO2013106017A2 publication Critical patent/WO2013106017A2/en
Publication of WO2013106017A3 publication Critical patent/WO2013106017A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/22—Type X
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/08—Xylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)

Abstract

A zeolitic binder-converted composition comprising (a) a zeolite X composition having at least a first zeolite X having a mean diameter not greater than 2.7 microns, and a second zeolite X, wherein the second zeolite X is obtained by converting a binder material to the second zeolite X and the binder material is in a range from 5 to 50 wt% of the zeolite X composition; and (b) an unconverted binder material content, after conversion to the second zeolite X is complete, in a range from 0 to 3 wt% of the zeolite X composition. The zeolite X composition has an average Si/Al framework mole ratio in a range from 1.0 to 1.5, and a relative LTA intensity not greater than 1.0, as determined by x-ray diffraction (XRD). The zeolitic binder-converted composition is useful in a process for separating para-xylene from a mixture of C8 alkylaromatics.
PCT/US2012/032255 2011-04-13 2012-04-05 Binder-converted aluminosilicate x-type zeolite compositions with low lta-type zeolite WO2013106017A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CN201280013151.XA CN103517876A (en) 2011-04-13 2012-04-05 Binder-converted aluminosilicate X-type zeolite compositions with low LTA-type zeolite
JP2014503971A JP2014522357A (en) 2011-04-13 2012-04-05 Binder-converted aluminosilicate X-type zeolite composition comprising a small amount of LTA-type zeolite
SG2013057849A SG192213A1 (en) 2011-04-13 2012-04-05 Binder-converted aluminosilicate x-type zeolite compositions with low lta-type zeolite
RU2013147991/05A RU2544673C1 (en) 2011-04-13 2012-04-05 Alumosilicate zeolite compositions of x type with low content of type lta zeolite, including converted binding agent
KR1020137022035A KR101504053B1 (en) 2011-04-13 2012-04-05 Binder-converted aluminosilicate x-type zeolite compositions with low lta-type zeolite
BR112013021043A BR112013021043A2 (en) 2011-04-13 2012-04-05 zeolitic composition converted to binder, e.g. process for the separation of para-xylene from a mixture of aromatic alkyls
EP12864937.3A EP2697166A4 (en) 2011-04-13 2012-04-05 Binder-converted aluminosilicate x-type zeolite compositions with low lta-type zeolite

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201161474923P 2011-04-13 2011-04-13
US201161474927P 2011-04-13 2011-04-13
US61/474,927 2011-04-13
US61/474,923 2011-04-13

Publications (2)

Publication Number Publication Date
WO2013106017A2 WO2013106017A2 (en) 2013-07-18
WO2013106017A3 true WO2013106017A3 (en) 2013-10-10

Family

ID=48139046

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/032255 WO2013106017A2 (en) 2011-04-13 2012-04-05 Binder-converted aluminosilicate x-type zeolite compositions with low lta-type zeolite

Country Status (10)

Country Link
EP (1) EP2697166A4 (en)
JP (1) JP2014522357A (en)
KR (1) KR101504053B1 (en)
CN (1) CN103517876A (en)
BR (1) BR112013021043A2 (en)
MY (1) MY168775A (en)
RU (1) RU2544673C1 (en)
SG (2) SG10201404109YA (en)
TW (1) TWI461239B (en)
WO (1) WO2013106017A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112017020959A2 (en) * 2015-04-09 2018-07-10 Basf Corp zsm-5 zeolite microspheres, and method for forming zsm-5 zeolite microspheres
FR3059571B1 (en) 2016-12-02 2018-11-16 Arkema France ZEOLITHIC ADSORBENT MATERIAL, PROCESS FOR THE PREPARATION AND USE FOR THE NON-CRYOGENIC SEPARATION OF INDUSTRIAL GASES

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6350428B1 (en) * 1997-05-29 2002-02-26 Exxonmobil Chemical Patents Inc. Preparation of zeolite-bound FAU structure type zeolite and use thereof
EP1184067A2 (en) * 2000-08-28 2002-03-06 The Boc Group, Inc. Process and apparatus for adsorptive purification of gases
US20040029716A1 (en) * 1999-05-05 2004-02-12 Mohr Gary David Tailored zeolite bound zeolite catalyst and its use for hydrocarbon conversion
US20080138619A1 (en) * 2005-09-13 2008-06-12 Miller Stephen J Shaped binderless titanosilicate zeolite ts-1
US20100076243A1 (en) * 2008-09-22 2010-03-25 Uop Llc Binderless adsorbents with improved mass transfer properties and their use in the adsorptive separation of para-xylene
US20110011804A1 (en) * 2009-07-20 2011-01-20 Linda Shi Cheng Binderless zeolitic adsorbents, methods for producing binderless zeolitic adsorbents, and processes for adsorptive separation of para-xylene from mixed xylenes using the binderless zeolitic adsorbents

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5747713A (en) * 1980-09-05 1982-03-18 Kanto Kagaku Kk Manufacture of x-type zeolite
US4603040A (en) * 1985-03-27 1986-07-29 Air Products And Chemicals, Inc. Massive bodies of Maximum Aluminum X-type zeolite
JPS63260810A (en) * 1988-03-18 1988-10-27 Kanebo Ltd Bactericidal zeolite composition and production thereof
FR2767524B1 (en) * 1997-08-21 1999-09-24 Ceca Sa IMPROVED PROCESS FOR OBTAINING PARAXYLENE FROM AROMATIC C8 CUTS
US6478854B1 (en) * 1999-11-25 2002-11-12 Tosoh Corporation High purity, low silica X-type zeolite binderless shaped product and gas separation method employing it
JP4830185B2 (en) * 1999-11-25 2011-12-07 東ソー株式会社 High purity low silica X-type zeolite binderless molded body and gas separation method using the same
RU2273602C2 (en) * 2000-11-03 2006-04-10 Юоп Ллк Uzm-5, uzm-5p, and uzm-6: crystalline aluminosilicate zeolites and processes involving them
FR2903978B1 (en) * 2006-07-19 2010-09-24 Ceca Sa AGGLOMERATED ZEOLITIC ADSORBENTS, PROCESS FOR THEIR PREPARATION AND USES THEREOF
CN101254928B (en) * 2007-02-28 2010-06-23 中国石油化工股份有限公司 Method for preparing fine-grain low silica/alumina ratio X zeolite
CN101497022B (en) * 2008-01-31 2011-06-15 中国石油化工股份有限公司 Coalescence type zeolite sorbent and preparation method thereof
US7820869B2 (en) * 2008-06-30 2010-10-26 Uop Llc Binderless adsorbents and their use in the adsorptive separation of para-xylene

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6350428B1 (en) * 1997-05-29 2002-02-26 Exxonmobil Chemical Patents Inc. Preparation of zeolite-bound FAU structure type zeolite and use thereof
US20040029716A1 (en) * 1999-05-05 2004-02-12 Mohr Gary David Tailored zeolite bound zeolite catalyst and its use for hydrocarbon conversion
EP1184067A2 (en) * 2000-08-28 2002-03-06 The Boc Group, Inc. Process and apparatus for adsorptive purification of gases
US20080138619A1 (en) * 2005-09-13 2008-06-12 Miller Stephen J Shaped binderless titanosilicate zeolite ts-1
US20100076243A1 (en) * 2008-09-22 2010-03-25 Uop Llc Binderless adsorbents with improved mass transfer properties and their use in the adsorptive separation of para-xylene
US20110011804A1 (en) * 2009-07-20 2011-01-20 Linda Shi Cheng Binderless zeolitic adsorbents, methods for producing binderless zeolitic adsorbents, and processes for adsorptive separation of para-xylene from mixed xylenes using the binderless zeolitic adsorbents

Also Published As

Publication number Publication date
CN103517876A (en) 2014-01-15
EP2697166A2 (en) 2014-02-19
TWI461239B (en) 2014-11-21
BR112013021043A2 (en) 2016-10-18
RU2544673C1 (en) 2015-03-20
MY168775A (en) 2018-12-04
KR101504053B1 (en) 2015-03-18
TW201249532A (en) 2012-12-16
JP2014522357A (en) 2014-09-04
KR20130121162A (en) 2013-11-05
SG192213A1 (en) 2013-09-30
WO2013106017A2 (en) 2013-07-18
SG10201404109YA (en) 2014-09-26
EP2697166A4 (en) 2015-02-25

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