WO2012087690A3 - Methods for removing unsaturated aliphatic hydrocarbons from a hydrocarbon stream using clay - Google Patents

Methods for removing unsaturated aliphatic hydrocarbons from a hydrocarbon stream using clay Download PDF

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Publication number
WO2012087690A3
WO2012087690A3 PCT/US2011/064774 US2011064774W WO2012087690A3 WO 2012087690 A3 WO2012087690 A3 WO 2012087690A3 US 2011064774 W US2011064774 W US 2011064774W WO 2012087690 A3 WO2012087690 A3 WO 2012087690A3
Authority
WO
WIPO (PCT)
Prior art keywords
unsaturated aliphatic
clay
methods
feed stream
hydrocarbon feed
Prior art date
Application number
PCT/US2011/064774
Other languages
French (fr)
Other versions
WO2012087690A2 (en
Inventor
Deng-Yang Jan
Michael A. Schultz
James A. Johnson
Original Assignee
Uop Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc filed Critical Uop Llc
Priority to JP2013544719A priority Critical patent/JP5837939B2/en
Priority to EP11850572.6A priority patent/EP2655298A4/en
Priority to CN2011800597873A priority patent/CN103261128A/en
Priority to KR1020137018280A priority patent/KR101621601B1/en
Priority to SG2013047154A priority patent/SG191241A1/en
Publication of WO2012087690A2 publication Critical patent/WO2012087690A2/en
Publication of WO2012087690A3 publication Critical patent/WO2012087690A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00—Purification; Separation; Stabilisation; Use of additives
    • C07B63/04—Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Disclosed is a method for removing unsaturated aliphatic compounds from a hydrocarbon feed stream by contacting the hydrocarbon feed stream with one of an adsorbent comprising clay, an acidic molecular sieve, and activated carbon to produce a hydrocarbon effluent stream having a lower unsaturated aliphatic content relative to the hydrocarbon feed stream. The hydrocarbon feed stream comprises an aromatic compound, a nitrogen compound, and an unsaturated aliphatic compound.
PCT/US2011/064774 2010-12-20 2011-12-14 Methods for removing unsaturated aliphatic hydrocarbons from a hydrocarbon stream using clay WO2012087690A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2013544719A JP5837939B2 (en) 2010-12-20 2011-12-14 Method for removing unsaturated aliphatic hydrocarbons from hydrocarbon streams using clay
EP11850572.6A EP2655298A4 (en) 2010-12-20 2011-12-14 Methods for removing unsaturated aliphatic hydrocarbons from a hydrocarbon stream using clay
CN2011800597873A CN103261128A (en) 2010-12-20 2011-12-14 Methods for removing unsaturated aliphatic hydrocarbons from a hydrocarbon stream using clay
KR1020137018280A KR101621601B1 (en) 2010-12-20 2011-12-14 Methods for removing unsaturated aliphatic hydrocarbons from a hydrocarbon stream using clay
SG2013047154A SG191241A1 (en) 2010-12-20 2011-12-14 Methods for removing unsaturated aliphatic hydrocarbons from a hydrocarbon stream using clay

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US201061424822P 2010-12-20 2010-12-20
US201061424813P 2010-12-20 2010-12-20
US201061424831P 2010-12-20 2010-12-20
US61/424,831 2010-12-20
US61/424,822 2010-12-20
US61/424,813 2010-12-20

Publications (2)

Publication Number Publication Date
WO2012087690A2 WO2012087690A2 (en) 2012-06-28
WO2012087690A3 true WO2012087690A3 (en) 2013-01-17

Family

ID=46314761

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/064774 WO2012087690A2 (en) 2010-12-20 2011-12-14 Methods for removing unsaturated aliphatic hydrocarbons from a hydrocarbon stream using clay

Country Status (7)

Country Link
EP (1) EP2655298A4 (en)
JP (1) JP5837939B2 (en)
KR (1) KR101621601B1 (en)
CN (1) CN103261128A (en)
SG (1) SG191241A1 (en)
TW (1) TWI450753B (en)
WO (1) WO2012087690A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9744531B2 (en) * 2015-03-03 2017-08-29 Lanxess Solutions Us Inc. Regeneration of clay catalysts for alkylation of aromatic rings

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6315816B1 (en) * 1999-09-23 2001-11-13 Korea Institute Of Energy Research Adsorbents, method for the preparation and method for the separation of unsaturated hydrocarbons for gas mixtures
US6423881B1 (en) * 1998-10-22 2002-07-23 The Regents Of The University Of Michigan Selective adsorption of alkenes using supported metal compounds
US6500996B1 (en) * 1999-10-28 2002-12-31 Exxonmobil Oil Corporation Process for BTX purification
US20060270886A1 (en) * 2005-05-27 2006-11-30 Brown Stephen H Process for reducing bromine index of hydrocarbon feedstocks
US20090326291A1 (en) * 2008-06-30 2009-12-31 Uop Llc Selective hydrogenation of unsaturated aliphatic hydrocarbons in predominantly aromatic streams

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54135726A (en) * 1978-04-10 1979-10-22 Mitsubishi Petrochem Co Ltd Preparation of high-purity benzene
US6368496B1 (en) 1998-02-03 2002-04-09 Exxonmobil Oil Corporation Decreasing bi-reactive contaminants
US6894201B1 (en) * 2003-12-19 2005-05-17 Uop Llc Process and apparatus for the removal of nitrogen compounds from a fluid stream
DE102004045879B4 (en) * 2004-09-20 2007-06-14 Basf Ag Process for the purification of aromatics-containing feed streams with zeolites
US7744750B2 (en) * 2005-11-17 2010-06-29 Exxonmobil Chemical Patents Inc. Process for reducing Bromine Index of hydrocarbon feedstocks
TWI414516B (en) * 2006-08-25 2013-11-11 Basf Ag Process for removing oxygen, nitrogen oxides, acetylenes and/or dienes from hydrogen-rich olefin-comprising gas mixtures

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6423881B1 (en) * 1998-10-22 2002-07-23 The Regents Of The University Of Michigan Selective adsorption of alkenes using supported metal compounds
US6315816B1 (en) * 1999-09-23 2001-11-13 Korea Institute Of Energy Research Adsorbents, method for the preparation and method for the separation of unsaturated hydrocarbons for gas mixtures
US6500996B1 (en) * 1999-10-28 2002-12-31 Exxonmobil Oil Corporation Process for BTX purification
US20060270886A1 (en) * 2005-05-27 2006-11-30 Brown Stephen H Process for reducing bromine index of hydrocarbon feedstocks
US20090326291A1 (en) * 2008-06-30 2009-12-31 Uop Llc Selective hydrogenation of unsaturated aliphatic hydrocarbons in predominantly aromatic streams

Also Published As

Publication number Publication date
WO2012087690A2 (en) 2012-06-28
KR20130098429A (en) 2013-09-04
SG191241A1 (en) 2013-07-31
TWI450753B (en) 2014-09-01
CN103261128A (en) 2013-08-21
KR101621601B1 (en) 2016-05-16
JP2014509301A (en) 2014-04-17
TW201236742A (en) 2012-09-16
EP2655298A2 (en) 2013-10-30
JP5837939B2 (en) 2015-12-24
EP2655298A4 (en) 2014-08-13

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