WO2012076563A1 - Mélanges pesticides - Google Patents

Mélanges pesticides Download PDF

Info

Publication number
WO2012076563A1
WO2012076563A1 PCT/EP2011/071996 EP2011071996W WO2012076563A1 WO 2012076563 A1 WO2012076563 A1 WO 2012076563A1 EP 2011071996 W EP2011071996 W EP 2011071996W WO 2012076563 A1 WO2012076563 A1 WO 2012076563A1
Authority
WO
WIPO (PCT)
Prior art keywords
compound
plants
spp
plant
mixtures
Prior art date
Application number
PCT/EP2011/071996
Other languages
English (en)
Inventor
Markus Gewehr
Andreas Haase
Egon Haden
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of WO2012076563A1 publication Critical patent/WO2012076563A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines

Definitions

  • the present invention relates to synergistic mixtures comprising, as active components,
  • one fungicidal compound IA selected from the group consisting of carboxin, do- demorph, spiroxamin, procymidon, valifenalat, sulfur, 2-(4-chlorphenyl)-N-[4-(3,4- dimethoxy-phenyl)-isoxazol-5-yl]-2-prop-2-ynyloxy-acetamid; 2- ⁇ 1-[2-(5-Methyl-3- trifluormethyl-pyrazol-1 -yl)-acetyl]-piperidin-4-yl ⁇ -thiazol-4-carboxylsaure-methyl-
  • one fungicidal compound II selected from the group of azoxystrobin, coume- thoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim- methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyrametostrobin, pyraoxystrobin, pyribencarb, trifloxystrobin, 2-(ortho-((2,5-dimethylphenyl- oxymethylen)phenyl)-3-methoxy-acrylic acid methyl ester, 2-(2-(3-(2,6-dichlorophenyl)- 1-methyl-allylideneaminooxymethyl)-phenyl)-2-methoxyimino-N-methyl-acetamide in synergistic effective amounts.
  • compositions comprising such mixtures.
  • the invention relates to a method for controlling phytopathogenic harmful fungi comprising contacting the phytopathogenic harmful fungi, their habitat, breeding grounds, their locus or the plants to be protected against fungal attack, the soil or plant propagation material with an effective amount of a mixture as defined above.
  • the present invention also comprises a method for protection of plant propagation material from phytopathogenic harmful fungi comprising contacting the plant propagation materials with an inventive mixture in fungicidally effective amounts.
  • plant propagation material is to be understood to denote all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e. g. potatoes), which can be used for the multiplication of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, sprouts and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil. These young plants may also be protected before transplantation by a total or partial treatment by immersion or pouring.
  • the term propagation material denotes seeds.
  • the present invention further relates to plant-protecting active ingredient mixtures having synergistically enhanced action of improving the health of plants and to a method of applying such inventive mixtures to the plants.
  • the compounds IA and II as well as their fungicidal action and methods for producing them are generally known.
  • the commercially available compounds may be found in The Pesticide Manual, 14th Edition, British Crop Protection Council (2006) among other publications.
  • Bacillus subtilis var. amyloliquefaciens FZB24 is for example TAEGRO® (Novozyme Biologicals, Inc., USA), Chitosan for ex- ample as ARMOUR-ZEN ( BotriZen Ltd., New Zealand), Pythium oligandrum DV74 for example as POLYVERSUM® ( Remeslo SSRO, Biopreparaty, Chez Republic) and Reynoutria sachlinensis for example as Arts REGALIA® ( Marrone Biolnnovations, USA).
  • TAEGRO® Novozyme Biologicals, Inc., USA
  • Chitosan for ex- ample as ARMOUR-ZEN ( BotriZen Ltd., New Zealand
  • Pythium oligandrum DV74 for example as POLYVERSUM® ( Remeslo SSRO, Biopreparaty, Chez Republic)
  • Reynoutria sachlinensis for example as Arts REGALIA® ( Marrone Biol
  • phytopathogenic harmful fungi is hereinbelow abbreviated as "harmful fungi”.
  • harmful fungi Another problem encountered concerns the need to have available fungal control agents which are effective against a broad spectrum of harmful fungi.
  • compositions that improve plants a process which is commonly and hereinafter referred to as "plant health”.
  • plant health comprises various sorts of improvements of plants that are not connected to the control of fungi.
  • advantageous properties that may be mentioned are improved crop characteristics including: emergence, crop yields, protein content, oil content, starch content, more developed root system (improved root growth), improved stress tolerance (e.g.
  • tillering increase, increase in plant height, bigger leaf blade, less dead basal leaves, stronger tillers, greener leaf color, pigment content, photosynthetic activity, less input needed (such as fertilizers or water), less seeds needed, more productive tillers, earlier flowering, early grain maturity, less plant verse (lodging), increased shoot growth, enhanced plant vigor, increased plant stand and early and better germination; or any other advantages familiar to a person skilled in the art.
  • the mixtures as defined in the outset show markedly enhanced action against fungi compared to the control rates that are possible with the individual compounds and/or is suitable for improving the health of plants when applied to plants, parts of plants, plant propagation materials (preferably seeds), or at their locus of growth. It has been found that the action of the inventive mixtures goes far beyond the fungicidal and/or plant health improving action of the active compounds present in the mixture alone.
  • inventive mixtures comprise the active substances in synergistically effective amounts, for example in weight ratio of compound I to component II of from 500:1 to 1 :500, preferably from 100:1 to 1 :100, more preferably from 50:1 to 1 :50, even more preferably from 20: 1 to 1 :20, particularly preferably from 10: 1 to : 10, in particular from 5:1 to 1 :5.
  • the present invention relates to mixtures comprising compound I A and compound II.
  • the inventive mixtures comprise compound IA and as compound II azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, metom- inostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyribencarb or trifloxystrobin.
  • the inventive mixtures comprise compound IA and as compound II azoxystrobin, kresoxim-methyl, orysastrobin, picoxystrobin, pyraclostrobin or tri- floxystrobin.
  • the inventive mixtures comprise compound IA and as compound II azoxystrobin, pyraclostrobin or trifloxystrobin. Utmost preference is given to mixtures comprising compound IA and pyraclostrobin as compound II.
  • the inventive mixtures comprise compound IB and as compound II azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, metom- inostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyribencarb or trifloxystrobin. More preferably, the inventive mixtures comprise compound IB and as compound II azoxystrobin, kresoxim-methyl, orysastrobin, picoxystrobin, pyraclostrobin or trifloxystrobin. Most preferably, the inventive mixtures comprise compound IB and as compound II azoxystrobin, pyraclostrobin or trifloxystrobin.
  • mixtures comprising compound IB and pyraclostrobin as compound II.
  • preferred compounds IA are selected from carboxin, dodemorph, spiroxamin, procymidon, valifenalat, propineb, ziram, tolylfluanid, 5-chlor-1-(4,6-d ' imethoxy-pyrimidin-2-yl)-2-methyl-1 H- benzoimidazol, 2-(4-chlorphenyl)-N-[4-(3,4-dimethoxy-phenyl)-isoxazol-5-yl]-2-prop-2- ynyloxy-acetamid; 2- ⁇ 1 -[2-(5-Methyl-3-trifluormethyl-pyrazol-1 -yl)-acetyl]-piperidin-4-yl ⁇ - thiazol-4-carboxylsaure-methyl-(1 ,2,3,4-tetra
  • mixtures which fungicidal components are limited to sulfur and compound II, wherein in these mixtures compound II is prefereably selected from azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyribencarb or tri- floxystrobin, is prefereably selected from azoxystrobin, kresoxim-methyl, orysastrobin, picoxystrobin, pyraclostrobin or trifloxystrobin, most prefereably selected from azoxystrobin, pyraclostrobin or trifloxystrobin and utmost prefereably is pyraclostrobin.
  • compound II is prefereably selected from azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysa
  • a further preferred embodiment of the present invention relates to the compositions listed in Table A, where a row of Table A corresponds in each case to a fungicidal composition comprising one compound I A and one component II compiled in the respective row.
  • inventive mixtures comprise the active substances in synergistically effective amounts, for example in weight ratio of compound IA to component II of from 500:1 to 1 :500, preferably from 100:1 to 1 :100, more preferably from 50:1 to 1 :50, even more preferably from 20:1 to 1 :20, particularly preferably from 10:1 to 1 :10, in particular from 5:1 to 1 :5.
  • I is compound I 2- ⁇ 1 -[2-(5-Methyl-3-trifluormethyl-pyrazol-1 -yl)-acetylj-
  • T trifloxystrobin 2-(4-chlorphenyl)-N-[4-(3,4-dimethoxy-phenyl)-isoxazol-5-
  • a further embodiment of the present invention relates to the compositions listed in Table B, where a row of Table B corresponds in each case to a fungicidal composition comprising one compound IB and one component II compiled in the respective row.
  • the inventive mixtures comprise the active substances in synergistically effective amounts, for example in weight ratio of compound IB to component II of from 500:1 to 1 :500, preferably from 100:1 to 1 :100, more preferably from 10:1 to 100:1 and most preferably from 20:1 to 40:1 (IB.II).
  • mixtures of Table A and Table B are more preferred.
  • inventive mixtures can further comprise one or more insecticides, fungicides, herbicides.
  • the mixtures according to the invention can be converted into the customary formulations, for example solutions, emulsions, suspensions, dusts, powders, pastes and granules.
  • the use form depends on the particular intended purpose; in each case, it should ensure a fine and even distribution of the inventive mixtures.
  • the formulations are prepared in a known manner (cf. US 20140060600A1 ).
  • the agrochemical formulations may also comprise auxiliaries which are customary in agrochemical formulations.
  • auxiliaries depend on the particular application form and active substance, respectively.
  • auxiliaries examples include solvents, solid earners, dispersants or emulsifiers (such as further solubilizers, protective colloids, surfactants and adhesion agents), organic and anorganic thickeners, bactericides, anti-freezing agents, anti-foaming agents, if appropriate colorants and tackifiers or binders (e. g. for seed treatment formulations).
  • Suitable solvents are water, organic solvents such as mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, e. g.
  • Solid carriers are mineral earths such as silicates, silica gels, talc, kaolins, limestone, lime, chalk, bole, loess, clays, dolomite, diatomaceous earth, calcium sulfate, magnesi- urn sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, e. g., ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers.
  • mineral earths such as silicates, silica gels, talc, kaolins, limestone, lime, chalk, bole, loess, clays, dolomite, diatomaceous earth, calcium sulfate, magnesi- urn sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, e. g., ammoni
  • Suitable surfactants are alkali metal, alkaline earth metal and ammonium salts of aromatic sulfonic acids, such as ligninsoulfonic acid (Borresperse® types, Borregard, Norway) phenolsulfonic acid, naphthalenesulfonic acid (Morwet® types, Akzo Nobel, U.S.A.), dibutylnaphthalene- sulfonic acid (Nekal® types, BASF, Germany),and fatty acids, alkylsulfonates, alkyl- arylsulfonates, alkyl sulfates, laurylether sulfates, fatty alcohol sulfates, and sulfated hexa-, hepta- and octadecanolates, sulfated fatty alcohol glycol ethers, furthermore con
  • methylcellulose g. methylcellulose
  • hydrophobically modified starches polyvinyl alcohols ( owiol® types, Clariant, Switzerland), polycarboxylates (Sokolan® types, BASF, Germany), polyalkoxylates, polyvi- nylamines (Lupasol® types, BASF, Germany), polyvinylpyrrolidone and the copolymers therof.
  • thickeners i. e. compounds that impart a modified flowability to formulations, i. e. high viscosity under static conditions and low viscosity during agitation
  • thickeners are polysaccharides and organic and anorganic clays such as Xanthan gum (Kelzan®, CP Kelco, U.S.A.), Rhodopol® 23 (Rhodia, France), Veegum® (R.T. Vanderbilt, U.S.A.) or Attaclay® (Engelhard Corp., NJ, USA).
  • Bactericides may be added for preservation and stabilization of the formulation.
  • suitable bactericides are those based on dichlorophene and benzylalcohol hemi formal (Proxel® from ICI or Acticide® RS from Thor Chemie and Kathon® MK from Rohm & Haas) and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones (Acticide® MBS from Thor Chemie).
  • Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin.
  • anti-foaming agents examples include silicone emulsions (such as e. g. Silikon® SRE, Wacker, Germany or Rhodorsil®, Rhodia, France), long chain alcohols, fatty acids, salts of fatty acids, fluoroorganic compounds and mixtures thereof.
  • Suitable colorants are pigments of low water solubility and water-soluble dyes. Examples to be mentioned und the designations rhodamin B, C. I. pigment red 112, C. I. solvent red 1 , pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15:1 , pigment blue 80, pigment yellow , pigment yellow 13, pigment red 112, pigment red 48:2, pigment red 48: , pigment red 57:1 , pigment red 53: , pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51 , acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108.
  • tackifiers or binders examples include polyvinylpyrrolidons, polyvinylacetates, polyvinyl alcohols and cellulose ethers (Tylose®, Shin-Etsu, Japan).
  • Powders, materials for spreading and dusts can be prepared by mixing or concomitantly grinding the compounds the resepective active compounds present in the in- ventive mixtures and, if appropriate, further active substances, with at least one solid carrier.
  • Granules e. g. coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active substances to solid carriers.
  • solid carriers are mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, e.
  • ammonium sulfate ammonium phosphate, ammonium nitrate, ureas
  • products of vegetable origin such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers.
  • formulation types are suspensions (SC, OD, FS), emulsifiable concentrates (EC), emulsions (EW, EO, ES), pastes, pastilles, wettable powders or dusts (WP, SP, SS, WS, DP, DS) or granules (GR, FG, GG, MG), which can be water- soluble or wettable, as well as gel formulations for the treatment of plant propagation materials such as seeds (GF), herein further below exemplified in detail:
  • compositions 15 parts by weight of compounds of the inventive mixtures are dissolved in 75 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil eth- oxylate (in each case 5 parts by weight). Dilution with water gives an emulsion.
  • the composition has an active substance content of 15% by weight.
  • Emulsions (EW, EO, ES)
  • 25 parts by weight of compounds of the inventive mixtures are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil eth- oxylate (in each case 5 parts by weight).
  • This mixture is introduced into 30 parts by weight of water by means of an emulsifying machine (Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion.
  • the composition has an active substance content of 25% by weight.
  • compositions 50 parts by weight of compounds of the inventive mixtures are ground finely with addition of 50 parts by weight of dispersants and wetting agents and prepared as water- dispersible or water-soluble granules by means of technical appliances (e. g. extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance.
  • the composition has an active substance content of 50% by weight.
  • compositions of the inventive mixtures 75 parts by weight of compounds of the inventive mixtures are ground in a rotor-stator mill with addition of 25 parts by weight of dispersants, wetting agents and silica gel. Dilution with water gives a stable dispersion or solution of the active substance.
  • the active substance content of the composition is 75% by weight.
  • Dustable powders (DP, DS)
  • the agrochemical formulations generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, most preferably between 0.5 and 90%, by weight of active sub- stances.
  • the compounds of the inventive mixtures are employed in a purity of from 90% to 100%, preferably from 95% to 100% (according to NMR spectrum).
  • the compounds of the inventive mixtures can be used as such or in the form of their compositions, e. g. in the form of directly sprayable solutions, powders, suspensions, dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading, or granules, by means of spraying, atomizing, dusting, spreading, brushing, immersing or pouring.
  • the application forms depend entirely on the intended purposes; it is intended to ensure in each case the finest possible distribution of the compounds present in the inventive mixtures.
  • Aqueous application forms can be prepared from emulsion concentrates, pastes or wettable powders (sprayable powders, oil dispersions) by adding water.
  • emulsions, pastes or oil dispersions the substances, as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetter, tackifier, dispersant or emulsifier.
  • concentrates composed of active substance, wetter, tackifier, dispersant or emulsifier and, if appropriate, solvent or oil and such concentrates are suitable for dilution with water.
  • the active substance concentrations in the ready-to-use preparations can be varied within relatively wide ranges. In general, they are from 0.0001 to 10%, preferably from 0.001 to 1% by weight of compounds of the inventive mixtures .
  • the compounds of the inventive mixtures may also be used successfully in the ultra- low-volume process (ULV), it being possible to apply compositions comprising over 95% by weight of active substance, or even to apply the active substance without additives.
  • UUV ultra- low-volume process
  • oils, wetters, adjuvants, herbicides, fungicides, other pesticides, or bactericides may be added to the active compounds, if appropriate not until
  • compositions of this invention may also contain fertilizers such as ammonium nitrate, urea, potash, and superphosphate, phytotoxicants and plant growth regulators and safeners. These may be used sequentially or in combination with the above-described compositions, if appropriate also added only immediately prior to use (tank mix). For example, the plant(s) may be sprayed with a composition of this invention either before or after being treated with the fertilizers.
  • fertilizers such as ammonium nitrate, urea, potash, and superphosphate, phytotoxicants and plant growth regulators and safeners.
  • the compounds contained in the mixtures as defined above can be applied simultaneously, that is jointly or separately, or in succession, wherein the time interval be- tween the individual applications is selected to ensure that the active substance applied first still occurs at the site of action in a sufficient amount at the time of application of the further active substance(s).
  • the order of application is not essential for working of the present invention.
  • the compound I and compound II is to be understood to denote, that at least the compound I and compound II occur simultaneously at the site of action (i.e. the harmful fungi to be controlled or their habitats such as infected plants, plant propagation materials, particularly seeds, surfaces, materials or the soil as well as plants, plant propagation materials, particularly seeds, soil, surfaces, materials or rooms to be protected from fungal attack in a effective amount.
  • This can be obtained by applying the compound I and compound II simultaneously, either jointly (e. g. as tank-mix) or sperately, or in succession, wherein the time interval between the individual applications is selected to ensure that the active substance applied first still occurs at the site of action in a sufficient amount at the time of application of the further active substance(s).
  • the order of application is not essential for working of the present invention.
  • the weight ratio of the compounds generally depends from the properties of the compounds of the inventive mixtures.
  • the compounds of the inventive mixtures can be used individually or already partially or completely mixed with one another to prepare the composition according to the invention. It is also possible for them to be packaged and used further as combination composition such as a kit of parts.
  • the kits may include one or more, including all, components that may be used to prepare a subject agrochemical composition.
  • kits may include the compound I and compound II and/or an adjuvant component and/or a further pesticidal compound (e.g. insecticide or herbicide) and/or a growth regulator component).
  • a further pesticidal compound e.g. insecticide or herbicide
  • One or more of the components may already be combined to- gether or pre-formulated.
  • kits may include one or more separate containers such as vials, cans, bottles, pouches, bags or canisters, each container containing a separate component for an agrochemical composition.
  • a component of the kit may be applied separately from or together with the further components or as a component of a combination composition according to the invention for preparing the composition according to the invention.
  • the user applies the composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank or a spray plane.
  • the agrochemical composition is made up with water and/or buffer to the desired application concentration, it being possible, if appropriate, to add further auxiliaries, and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained.
  • 50 to 500 liters of the ready-to-use spray liquor are applied per hectare of agricultural useful area, preferably 100 to 400 liters.
  • individual compounds of the inventive mixtures formulated as composition (or formulation) such as parts of a kit or parts of the inventivemix- ture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate (tank mix).
  • either individual compounds of the inventive mixtures formulated as composition or partially premixed components e. g. components comprising the compound I and compound II may be mixed by the user in a spray tank and further auxiliaries and additives may be added, if appropriate (tank mix).
  • either individual components of the composition according to the invention or partially premixed components, e. g. components comprising the compound I and compound II , can be applied jointly (e. .g. after tankmix) or consecutively.
  • the present invention comprises a method for harmful fungi, wherein the fungi, their habitat, breeding grounds, their locus or the plants to be protected against fungal attack, the soil or plant propagation material (preferably seed) are treated with an fungicidally effective amount of a mixture.
  • inventive mixtures are suitable for controlling the following harmful fungi:
  • Albugo spp. (white rust) on ornamentals, vegetables (e. g. A. Candida) and sunflowers (e. g. A. tragopogon/s); Alternaria spp. (Alternaria leaf spot) on vegetables, rape ⁇ A. brassicolaox brassicae), sugar beets ⁇ A. tenuis), fruits, rice, soybeans, potatoes (e. g. A. so/an/or A. alternate), tomatoes (e. g. A. so/an/or A. alternata) and wheat; Aphano- myces spp. on sugar beets and vegetables; Ascochyta spp. on cereals and vegetables, e. g. A.
  • Botrytis cinerea (teleomorph: Botryotinia fuckeliana. grey mold) on fruits and berries (e. g. strawberries), vegetables (e. g. lettuce, carrots, celery and cabbages), rape, flowers, vines, forestry plants and wheat; Bremia lactucae (downy mildew) on lettuce; Ceratocystis (syn. Ophiostoma) spp. (rot or wilt) on broad- leaved trees and evergreens, e. g. C. ulmi (Dutch elm disease) on elms; Cercospora spp. (Cercospora leaf spots) on corn (e.g.
  • Gray leaf spot C. zeae-maydis
  • rice sugar beets (e. g. C. beticola), sugar cane, vegetables, coffee, soybeans (e. g. C. sojina or C. kikuchii and rice; Cladosporium spp. on tomatoes (e. g. C. fulvu . leaf mold) and cereals, e. g. C. herbarum (black ear) on wheat; Claviceps purpurea (ergot) on cereals; Cochliobolus ⁇ anamorph: Helminthosporium of Bipolaris) spp. (leaf spots) on corn (C. carbonum), cereals (e. g. C. sativus, anamorph: B. sorokiniana) and rice (e. g. C.
  • Colletotrichum teleomorph: Glomerella
  • spp. an- thracnose
  • cotton e. g. C. gossyp/ ⁇ '
  • corn e. g. C. graminicola: Anthracnose stalk rot
  • soft fruits e. g. C. coccodes. black dot
  • beans e. g. C. lindemuthianum
  • soybeans e. g. C. truncatum or C. gloeosporioides
  • Corticium spp. e. g. C.
  • sasa- Ay/ ' sheath blight
  • Corynespora cassiicola leaf spots
  • Cycloconium spp. e. g. C. oleaginum on olive trees
  • Cylindrocarpon spp. e. g. fruit tree canker or young vine decline, teleomorph: Nectria or Neonectria spp.
  • vines e. g. C. liriodendri, teleomorph: Neonectria liriodendri.
  • Phellinus punctata, F. mediterranea, Phaeomoniella chlamydospora (earlier Phaeo- acremonium chlamydosporum), Phaeoacremonium aleophilum and/or Botryosphaeria obtusa, Elsinoe spp. on pome fruits (E. pyn), soft fruits (E. veneta. anthracnose) and vines (E. ampelina. anthracnose); Entyloma oryzae (leaf smut) on rice; Epicoccum spp. (black mold) on wheat; Erysiphe spp.
  • Bakanae disease Glomerella cingulata on vines, pome fruits and other plants and G. gossypii or ⁇ cotton; Grain- staining complex on rice; Guignardia bidwellii (black rot) on vines; Gymnosporangium spp. on rosaceous plants and junipers, e. g. G. sabinae (rust) on pears; Helminthosporium spp. (syn. Drechslera, teleomorph: Cochliobolus) on corn, cereals and rice; Hemileia spp., e. g. H.
  • fructigena (bloom and twig blight, brown rot) on stone fruits and other rosaceous plants
  • Mycosphaerella spp. on cereals, bananas, soft fruits and ground nuts, such as e. g. M. graminico/a (anamorph: Septoria tritici, Septoria blotch) on wheat or M. fijiensis (black Sigatoka disease) on bananas
  • Peronospora spp. downy mildew) on cabbage (e. g. P. brassicae), rape (e. g. P. parasitica), onions (e. g. P. destructof), tobacco (P. tabacina) and soybeans (e. g. P.
  • Phakopsora pachyrhizi and P. meibomiae on soybeans
  • Phialo- phora spp. e. g. on vines e. g. P. tracheiphila and P. tetraspora
  • soybeans e. g. P. gregata. stem rot
  • Phoma lingam root and stem rot
  • rape and cabbage and P. betae (root rot, leaf spot and damping-off) on sugar beets
  • Phomopsis spp. on sunflowers, vines e. g. P. viticola. can and leaf spot
  • soybeans e. g.
  • stem rot P. phaseoli teleomorph: Diaporthe phaseolorum); Physoderma maydis (brown spots) on corn; Phy- tophthora spp. (wilt, root, leaf, fruit and stem root) on various plants, such as paprika and cucurbits (e. g. P. capsici), soybeans (e. g. P. megasperma, syn. P. sojae), potatoes and tomatoes (e. g. P. infestans. late blight) and broad-leaved trees (e. g. P. ra- morurrr.
  • Plasmodiophora brassicae club root
  • Plasmopara spp. e. g. P. viticola (grapevine downy mildew) on vines and P. halstedii on sunflowers
  • Podosphaera spp. powdery mildew on rosaceous plants, hop, pome and soft fruits, e. g. P. leucotricha on apples
  • Polymyxa spp. e. g. on cereals, such as barley and wheat ⁇ P. graminis) and sugar beets ⁇ P.
  • Pseudocercosporella herpotrichoides eyespot, teleomorph: Tapesia yallundae
  • Pseudoperonospora downy mildew
  • Pseudopezicula tracheiphila red fire disease or .rotbrenner', anamorph: Phialophora
  • Puccinia spp. rusts on various plants, e. g. P. triticina (brown or leaf rust), P.
  • striiformis stripe or yellow rust
  • P. horde dwarf rust
  • P. graminis seed or black rust
  • P. recondite brown or leaf rust
  • cereals such as e. g. wheat, barley or rye
  • P. kuehnii range rust
  • Pyrenophora anamorph: Drechslera
  • tritici-repentis tan spot
  • P. teres net blotch
  • oryzae (teleomorph: Magnaporthe grisea, rice blast) on rice and P. grisea on turf and cereals; Pythium spp. (damping-off) on turf, rice, corn, wheat, cotton, rape, sunflowers, soybeans, sugar beets, vegetables and various other plants (e. g. P. ultimum or P. aphanidermatum); Ramularia spp., e. g. R. collo-cygni (Ramularia leaf spots, Physiological leaf spots) on barley and R. beticola on sugar beets; Rhizoctonia spp.
  • R. solani ⁇ voot and stem rot on soy- beans
  • R. solani sheath blight
  • R. cerealis Rhizoctonia spring blight
  • Rhizopus stolonifer black mold, soft rot
  • Rhynchosporium secalis scald
  • Sarocladium oryzae and S. attenuatum sheath rot
  • seed rot or white mold on vegetables and field crops, such as rape, sunflowers (e. g. S. sclerotiorum) and soybeans (e. g. S. rolfsiior S. sclerotiorum); Septoria spp. on various plants, e. g. S. glycines (brown spot) on soybeans, S. tritici (Septoria blotch) on wheat and S. (syn. Stagonospora) nodorum (Stagonospora blotch) on cereals; Uncinula (syn.
  • S. nodorum Stagonospora blotch, teleomorph: Leptosphaeria [syn. Phaeosphaeria] nodorum
  • wheat Synchytrium endobioticumon potatoes (potato wart disease)
  • Taphrina spp. e. g. T. deformans (leaf curl disease) on peaches and T. pruni (p ⁇ um pocket) on plums
  • Thielaviopsis spp. black root rot
  • tobacco, pome fruits, vegetables, soybeans and cotton e. g. T. basicola (syn. Chalara elegans); Tilletia spp.
  • the inventive mixturs are also suitable for controlling fungal diseases occouring in the protection of materials (e. g. wood, paper, paint dispersions, fiber or fabrics) and in the protection of stored products.
  • materials e. g. wood, paper, paint dispersions, fiber or fabrics
  • protection of materials is to be understood to denote the protection of technical and non-living materials, such as adhesives, glues, wood, paper and paperboard, textiles, leather, paint dispersions, plastics, colling lubricants, fiber or fabrics, against the infestation and destruction by harmful microorganisms, such as fungi and bacteria.
  • Ascomycetes such as Ophi- ostoma spp., Ceratocystis spp., Aureobasidium pullulans, Sclerophoma spp., Chaeto- mium spp., Humicola spp., Petriella spp., Trichurus spp.; Basidiomycetes such as Co- niophora spp., Coriolus spp., Gloeophyllum spp., Lentinus spp., Pleurotus spp., Poria spp., Serpula spp.
  • Ascomycetes such as Ophi- ostoma spp., Ceratocystis spp., Aureobasidium pullulans, Sclerophoma spp., Chaeto- mium spp., Humicola spp., Petriella spp., Trichurus spp.
  • Basidiomycetes
  • yeast fungi are worthy of note: Candida spp. and Saccharomy- ces cerevisae.
  • fungicidally effective amount means the amount of the inventive mixtures or of compositions comprising the mixtures needed to achieve an observable effect on growth, including the effects of necrosis, death, retardation, prevention, and removal, destruction, or otherwise diminishing the occurrence and activity of the target organism.
  • the fungicidally effective amount can vary for the various mixtures / compositions used in the invention.
  • a fungicidally effective amount of the mixtures / compositions will also vary according to the prevailing conditions such as desired fungicidal effect and duration, weather, target species, locus, mode of application, and the like.
  • the inventive mixtures are particularly important for controlling a multitude of harmful fungi or insects on various cultivated plants, such as cereals, e. g.
  • the inventive mixtures of the present invention are used for controlling a multitude of fungi on field crops, such as potatoes sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rape, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes, beans or squashes.
  • field crops such as potatoes sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rape, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes, beans or squashes.
  • inventive mixtures of the present invention are used for controlling a multitude of fungi on field oropo, ouch as potatoos sugar booto, tobac co, wheat, ryo, borloy, oats, rico, corn, cotton, soybeans, rapo, legumes; fruits and vegetables, such as cucumbers, tomatoes, beans or squashes.
  • the treatment of plant propagation materials with the inventive mixtures is used for controlling a multitude of fungi on cereals, such as wheat, rye, barley and oats; rice, corn, cotton and soybeans.
  • the present invention comprises a method for improving the health of plants, wherein the plant, the locus where the plant is growing or is expected to grow or plant propagation material, from which the plant grows, is treated with an plant health effective amount of an inventive mixture.
  • plant health effective amount denotes an amount of the inventive mixtures, which is sufficient for achieving plant health effects as defined hereinbelow. More ex- emplary information about amounts, ways of application and suitable ratios to be used is given below. Again, the skilled artisan is well aware of the fact that such an amount can vary in a broad range and is dependent on various factors, e.g. the treated cultivated plant or material and the climatic conditions.
  • effective amount comprises the terms “plant health effective amount” and/or “fungicidally effective amount” as the case may be.
  • “Locus” means a plant, plant propagation material (preferably seed), soil, area, material or environment in which a fungi is growing or may grow.
  • the pure active compounds to which further active compounds against pests, such as insecticides, herbidices, fungicides or else herbicidal or growth-regulating active compounds or fertilizers can be added as further active components according to need.
  • the inventive mixtures are employed by treating the fungi or the plants, plant propagation materials (preferably seeds), materials or soil to be protected from fungal attack with a fungicidally effective amount of the active compounds.
  • the application can be carried out both before and after the infection of the materials, plants or plant propagation materials (preferably seeds) by the fungi.
  • the inventive mixtures are employed by treating the fungi or the plants or soil to be protected from fungicidal attack via foliar application with a fungicidally effective amount of the active compounds. Also herein, the application can be carried out both before and after the infection of the plants by the fungi.
  • the application rates of the mixtures according to the invention are from 0,1 g/ha to 10000 g/ha, preferably 2 g/ha to 2500 g/ha, more preferably from 5 to 1000 g/ha, most prefarebly from 10 to 750 g/ha, in particular from 20 to 500 g/ha.
  • the term plant refers to an entire plant, a part of the plant or the propagation material of the plant.
  • Plants and as well as the propagation material of said plants, which can be treated with the inventive mixtures include all genetically modified plants or transgenic plants, e.g. crops which tolerate the action of herbicides or fungicides or insecticides owing to breeding, including genetic engineering methods, or plants which have modified char- acteristics in comparison with existing plants, which can be generated for example by traditional breeding methods and/or the generation of mutants, or by recombinant procedures.
  • inventive mixtures can be applied (as seed treatment, spray treatment, in furrow or by any other means) also to plants which have been modified by breeding, mutagenesis or genetic engineering including but not limiting to agricultural biotech products on the market or in development (cf.
  • Genetically modified plants are plants, which genetic material has been so modified by the use of recombinant DNA techniques that under natural circumstances cannot readily be obtained by cross breeding, mutations or natural recombination. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant.
  • Such genetic modifications also include but are not limited to targeted post-transtional modification of protein(s), oligo- or polypeptides e. g. by glycosylation or polymer additions such as prenylated, acetylated or farnesylated moieties or PEG moieties.
  • herbicides e. bromoxynil or ioxynil herbicides as a result of conventional methods of breeding or genetic engineering. Furthermore, plants have been made resistant to multiple classes of herbicides through multiple genetic modifications, such as resistance to both glyphosate and glufosinate or to both glyphosate and a herbicide from another class such as ALS inhibitors, HPPD inhibitors, auxin herbicides, or ACCase inhibitors. These herbicide resistance technologies are e. g. described in Pest anagem. Sci.
  • cultivated plants have been rendered tolerant to herbicides by conventional methods of breeding (mutagenesis), e. g. Clearfield ® summer rape (Canola, BASF SE, Germany) being tolerant to imidazolinones, e. g.
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly from Bacillus thuringiensis, such as ⁇ - endotoxins, e. g. CrylA(b), CrylA(c), CrylF, CrylF(a2), CryllA(b), CrylllA, CrylllB(bl) or Cry9c; vegetative insecticidal proteins (VIP), e. g. VIP1 , VIP2, VIP3 or VIP3A; insecticidal proteins of bacteria colonizing nematodes, e. g. Photorhabdus spp.
  • VIP1 , VIP2, VIP3 or VIP3A vegetative insecticidal proteins
  • toxins produced by animals such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins
  • toxins produced by fungi such Streptomy- cetes toxins, plant lectins, such as pea or barley lectins; agglutinins
  • proteinase inhibi- tors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors
  • ribosome-inactivating proteins (RIP) such as ricin, maize-RIP, abrin, luffin, saporin or bryodin
  • steroid metabolism enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase
  • ion channel blockers such as block
  • these insecticidal proteins or toxins are to be understood expressly also as pre-toxins, hybrid proteins, truncated or otherwise modified proteins.
  • Hybrid proteins are characterized by a new combination of protein domains, (see, e. g. WO 02/015701).
  • Further examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, e. g., in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/18810 und WO 03/52073.
  • the methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, e. g.
  • The- se insecticidal proteins contained in the genetically modified plants impart to the plants producing these proteins tolerance to harmful pests from all taxonomic groups of athropods, especially to beetles (Coeloptera), two-winged insects (Diptera), and moths (Lepidoptera) and to nematodes (Nematoda).
  • Genetically modified plants capable to synthesize one or more insecticidal proteins are, e.
  • WO 03/018810 MON 863 from Monsanto Europe S.A., Belgium (corn cultivars producing the Cry3Bb1 toxin), IPC 531 from Monsanto Europe S.A., Belgium (cotton cultivars producing a modified version of the Cry1 Ac toxin) and 1507 from Pioneer Overseas Corporation, Belgium (corn cultivars producing the Cryl F toxin and PAT enzyme).
  • plants are also covered that are by the use of recombinant DNA tech- niques capable to synthesize one or more proteins to increase the resistance or tolerance of those plants to bacterial, viral or fungal pathogens.
  • proteins are the so-called "pathogenesis-related proteins" (PR proteins, see, e. g.
  • EP-A 392 225 plant disease resistance genes (e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solanum bulbocastanum) or T4-lysozym (e. g. potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Erwinia amylvora).
  • plant disease resistance genes e. g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the mexican wild potato Solanum bulbocastanum
  • T4-lysozym e. g. potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Erwinia amylvora.
  • the methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, e. g. in the publications mentioned above.
  • plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the productivity (e. g. bio mass production, grain yield, starch content, oil content or protein content), tolerance to drought, salinity or other growth-limiting environmental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants.
  • productivity e. g. bio mass production, grain yield, starch content, oil content or protein content
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve human or animal nutrition, e. g. oil crops that produce health- promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e. g. Nexera® rape, DOW Agro Sciences, Canada).
  • plants are also covered that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve raw material production, e. g. potatoes that produce increased amounts of amylopectin (e. g. Amflora® potato, BASF SE, Germany).
  • inventive mixtures are used for the protection of the seed and the seedlings' roots and shoots, preferably the seeds.
  • Seed treatment can be made into the seedbox before planting into the field.
  • the weight ration in the inventivemixtures generally depends from the properties of the compounds of the inventive mixtures.
  • compositions which are especially useful for seed treatment are e.g.: A Soluble concentrates (SL, LS)
  • compositions can be applied to plant propagation materials, particularly seeds, diluted or undiluted. These compositions can be applied to plant propagation materials, particularly seeds, diluted or undiluted.
  • the compositions in question give, after two-to- tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, prefer- ably from 0.1 to 40% by weight, in the ready-to-use preparations. Application can be carried out before or during sowing.
  • Methods for applying or treating agrochemical compounds and compositions thereof, respectively, on to plant propagation material, especially seeds are known in the art, and include dressing, coating, pelleting, dusting and soaking application methods of the propagation material (and also in furrow treat- ment).
  • the compounds or the compositions thereof, respectively are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.
  • the application rates of the inventive mixture are generally for the formulated product (which usually comprises from 10 to 750 g/l of the active(s)) .
  • the invention also relates to the propagation products of plants, and especially the seed comprising, that is, coated with and/or containing, a mixture as defined above or a composition containing the mixture of two or more active ingredients or a mixture of two or more compositions each providing one of the active ingredients.
  • the plant propagation material (preferably seed) comprises the inventive mixtures in an amount of from 0.1 g to 10 kg per 100 kg of plant propagation material (preferably seed), preferably 0.1 g to 1 kg per 100 kg of plant propagation material (preferably seed).
  • the ratio by weight for compound II is herein preferably between 0.5 - 200 g/100kg plant propagation material (preferably seed), more preferred 1 to 50 g/100kg plant propagation material (preferably seed) and most preferred 1 to 20 g/100kg plant propagation material (preferably seed).
  • the ratio by weight of compound I is herein preferably between 1 - 2000 g/100kg plant propagation material (preferably seed), more prefered 10 to 1000 g/100kg plant propagation material (preferably seed), most preferred 25 to 750 g/100kg plant propagation material (preferably seed) and utmost preferred 50-500 g/100kg plant propagation material (preferably seed).
  • the separate or joint application of the compounds of the inventive mixtures is carried out by spraying or dusting the seeds, the seedlings, the plants or the soils before or after sowing of the plants or before or after emergence of the plants.
  • the invention is further illustrated, but not limited by the following Examples
  • Example 1 Activity against the late blight pathogen Phytophthora infestans (Phytin)
  • the stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations.
  • MTP micro titer plate
  • a spore suspension of Phy- tophtora infestans containing a pea juice-based aqueous nutrient medium or DDC medium was then added.
  • the plates were placed in a water vapor-saturated chamber at a temperature of 18°C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation.
  • Example 2 Activity against leaf blotch on wheat caused by Septoria tritici (Septtr)
  • the stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations.
  • a spore suspension of Septoria tritici in an aqueous biomalt or yeast-bactopeptone-glycerine solution was then added.
  • the plates were placed in a water vapor-saturated chamber at a temperature of 18°C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation.
  • the stock solutions were mixed according to the ratio, pipetted onto a micro titer plate (MTP) and diluted with water to the stated concentrations.
  • MTP micro titer plate
  • a spore suspension of Rhizoctonia solani in an aqueous biomalt or yeast-bactopeptone-glycerine solution was then added.
  • the plates were placed in a water vapor-saturated chamber at a tempera- ture of 18°C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after the inoculation.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Cette invention concerne des mélanges synergiques comprenant, à titre de composants actifs, un composé fongicide IA choisi dans le groupe constitué par le dodémorphe, la carboxine, le propineb, le ziram, le bénodanil, le pentachlorphénol et un phtalide; ou un composé biologique IB choisi parmi Bacillus subtilis var. amyloliquefaciens FZB24, le chitosane, Pythium oligandrum DV74 et Reynoutria sachlinensis; et un composé fongicide II choisi dans le groupe des strobilurines en des quantités synergiques efficaces.
PCT/EP2011/071996 2010-12-08 2011-12-07 Mélanges pesticides WO2012076563A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP10194180 2010-12-08
EP10194180.5 2010-12-08

Publications (1)

Publication Number Publication Date
WO2012076563A1 true WO2012076563A1 (fr) 2012-06-14

Family

ID=44123410

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/IB2011/055504 WO2012077061A1 (fr) 2010-12-08 2011-12-07 Mélanges pesticides
PCT/EP2011/071996 WO2012076563A1 (fr) 2010-12-08 2011-12-07 Mélanges pesticides

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/IB2011/055504 WO2012077061A1 (fr) 2010-12-08 2011-12-07 Mélanges pesticides

Country Status (2)

Country Link
CN (1) CN103260410A (fr)
WO (2) WO2012077061A1 (fr)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103168799A (zh) * 2013-03-06 2013-06-26 广东省农业科学院植物保护研究所 一种含有吡唑醚菌酯和硫磺的杀菌剂组合物
CN103404519A (zh) * 2013-07-17 2013-11-27 山东省农业科学院植物保护研究所 一种杀菌剂组合物及其应用
WO2014079766A1 (fr) * 2012-11-22 2014-05-30 Basf Se Mélanges pesticides
WO2014079764A1 (fr) * 2012-11-22 2014-05-30 Basf Se Mélanges pesticides
WO2014079769A1 (fr) * 2012-11-23 2014-05-30 Basf Se Mélanges pesticides
CN104255756A (zh) * 2014-09-10 2015-01-07 江苏省绿盾植保农药实验有限公司 一种含有吡唑醚菌酯与几丁聚糖的杀菌组合物及其应用
WO2015028376A1 (fr) * 2013-08-28 2015-03-05 Basf Se Utilisation d'un mélange comprenant au moins une strobilurine et au moins un dithiocarbamate pour augmenter la santé de plantes sylvicoles
CN104396979A (zh) * 2014-10-24 2015-03-11 北京富力特农业科技有限责任公司 一种杀菌剂及其用途
CN104705344A (zh) * 2013-12-13 2015-06-17 上海生农生化制品有限公司 一种含有硫磺的杀菌剂组合物及其应用
CN105613540A (zh) * 2014-11-05 2016-06-01 江苏龙灯化学有限公司 一种活性成分组合物
US9622484B2 (en) 2014-12-29 2017-04-18 Fmc Corporation Microbial compositions and methods of use for benefiting plant growth and treating plant disease
WO2018001392A1 (fr) * 2016-07-01 2018-01-04 Bio Agens Research And Development - Bard, S.R.O. Préparation comprenant le micro-organisme mycoparasite pythium oligandrum à l'état viable servant au traitement de dermatophytoses et d'infections mycosiques de la peau et des muqueuses, méthode pour déterminer la viabilité cellulaire du micro-organisme pythium oligandrum, et méthode d'application de la préparation
US10076119B2 (en) 2012-11-22 2018-09-18 Basf Corporation Pesticidal mixtures
US10251400B2 (en) 2014-05-23 2019-04-09 Basf Se Mixtures comprising a Bacillus strain and a pesticide
US10537110B2 (en) 2012-11-22 2020-01-21 Basf Corporation Pesticidal mixtures
US10779536B2 (en) 2014-11-07 2020-09-22 Basf Se Pesticidal mixtures
US10905122B2 (en) 2016-03-16 2021-02-02 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on cereals
US11241012B2 (en) 2016-03-16 2022-02-08 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on soybean
US11425909B2 (en) 2016-03-16 2022-08-30 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on fruits

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PT2854547T (pt) * 2012-05-30 2018-11-16 Bayer Cropscience Ag Composição que compreende um agente de controlo biológico e trifloxistrobina
CN105265493A (zh) * 2014-06-25 2016-01-27 陕西美邦农药有限公司 一种含虎杖提取物的组合物
CN105309488A (zh) * 2014-06-25 2016-02-10 陕西美邦农药有限公司 一种含虎杖提取物与嘧菌酯或醚菌酯的杀菌组合物
CN105211118A (zh) * 2014-06-28 2016-01-06 陕西美邦农药有限公司 一种含虎杖提取物与苯醚菌酯或唑菌酯的杀菌组合物
CN105309489A (zh) * 2014-06-30 2016-02-10 陕西美邦农药有限公司 一种含虎杖提取物与吡唑醚菌酯的杀菌组合物
CN105309490A (zh) * 2014-07-03 2016-02-10 陕西美邦农药有限公司 一种含虎杖提取物与肟菌酯或苯醚菌酯的杀菌组合物
CN105309494A (zh) * 2014-07-07 2016-02-10 陕西美邦农药有限公司 一种含虎杖提取物与氟嘧菌酯或啶氧菌酯的杀菌组合物
CN104286031B (zh) * 2014-09-22 2016-12-07 江苏丘陵地区镇江农业科学研究所 一种生物复配杀菌组合物及其应用
CN104770398B (zh) * 2015-01-28 2018-04-10 中国水稻研究所 一种生防细菌和肟菌酯的组合物
CN105145602A (zh) * 2015-09-25 2015-12-16 安徽美兰农业发展股份有限公司 一种吡唑醚菌酯和丙森锌复配可湿性粉剂及其制备方法
CN106719751A (zh) * 2016-11-24 2017-05-31 山东省果树研究所 一种苹果炭疽叶枯病专用杀菌组合物及其应用

Citations (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3060084A (en) 1961-06-09 1962-10-23 Du Pont Improved homogeneous, readily dispersed, pesticidal concentrate
US3299566A (en) 1964-06-01 1967-01-24 Olin Mathieson Water soluble film containing agricultural chemicals
US3920442A (en) 1972-09-18 1975-11-18 Du Pont Water-dispersible pesticide aggregates
US4144050A (en) 1969-02-05 1979-03-13 Hoechst Aktiengesellschaft Micro granules for pesticides and process for their manufacture
US4172714A (en) 1976-12-20 1979-10-30 E. I. Du Pont De Nemours And Company Dry compactible, swellable herbicidal compositions and pellets produced therefrom
GB2095558A (en) 1981-03-30 1982-10-06 Avon Packers Ltd Formulation of agricultural chemicals
EP0374753A2 (fr) 1988-12-19 1990-06-27 American Cyanamid Company Toxines insecticides, gènes les codant, anticorps les liant, ainsi que cellules végétales et plantes transgéniques exprimant ces toxines
EP0392225A2 (fr) 1989-03-24 1990-10-17 Ciba-Geigy Ag Plantes transgéniques résistantes aux maladies
EP0427529A1 (fr) 1989-11-07 1991-05-15 Pioneer Hi-Bred International, Inc. Lectines larvicides, et résistance induite des plantes aux insectes
WO1991013546A1 (fr) 1990-03-12 1991-09-19 E.I. Du Pont De Nemours And Company Granules pesticides dispersibles ou solubles dans l'eau, obtenus a partir de liants thermo-actives
EP0451878A1 (fr) 1985-01-18 1991-10-16 Plant Genetic Systems, N.V. Modification de plantes par techniques de génie génétique pour combattre ou contrôler les insectes
US5180587A (en) 1988-06-28 1993-01-19 E. I. Du Pont De Nemours And Company Tablet formulations of pesticides
WO1993007278A1 (fr) 1991-10-04 1993-04-15 Ciba-Geigy Ag Sequence d'adn synthetique ayant une action insecticide accrue dans le mais
US5208030A (en) 1989-08-30 1993-05-04 Imperial Chemical Industries Plc Active ingredient dosage device
US5232701A (en) 1990-10-11 1993-08-03 Sumitomo Chemical Company, Limited Boron carbonate and solid acid pesticidal composition
WO1995034656A1 (fr) 1994-06-10 1995-12-21 Ciba-Geigy Ag Nouveaux genes du bacillus thuringiensis codant pour des toxines actives contre les lepidopteres
EP0707445A1 (fr) 1993-07-03 1996-04-24 Basf Ag Formulation aqueuse polyphasee et stable prete a l'emploi pour produits phytosanitaires et procede de preparation
WO1998025465A1 (fr) * 1996-12-10 1998-06-18 Bayer Aktiengesellschaft Combinaisons de principes actifs fungicides
WO2000029404A1 (fr) 1998-11-17 2000-05-25 Kumiai Chemical Industry Co., Ltd. Derives de pyrimidinylbenzimidazole et de triazinylbenzimidazole et bactericides agricoles/horticoles
WO2002015701A2 (fr) 2000-08-25 2002-02-28 Syngenta Participations Ag Nouvelles toxines insecticides derivees de proteines cristallines insecticides de $i(bacillus thuringiensis)
WO2003018810A2 (fr) 2001-08-31 2003-03-06 Syngenta Participations Ag Toxines cry3a modifiees et sequences d'acides nucleiques les codant
WO2003052073A2 (fr) 2001-12-17 2003-06-26 Syngenta Participations Ag Nouvel evenement du mais
WO2004083193A1 (fr) 2003-03-17 2004-09-30 Sumitomo Chemical Company, Limited Compose amide et composition bactericide contenant ledit compose
WO2006040123A2 (fr) * 2004-10-12 2006-04-20 Bayer Cropscience Ag Combinaisons d'agents fongicides
WO2007014290A2 (fr) 2005-07-26 2007-02-01 E. I. Du Pont De Nemours And Company Carboxamides fongicides
WO2007062765A1 (fr) * 2005-12-03 2007-06-07 Bayer Cropscience Ag Combinaisons de substances actives fongicides
WO2008013622A2 (fr) 2006-07-27 2008-01-31 E. I. Du Pont De Nemours And Company Amides azocycliques fongicides
CN101584330A (zh) * 2009-04-15 2009-11-25 陕西蒲城县美邦农药有限责任公司 一种含丙森锌与嘧菌酯的杀菌组合物
WO2010029067A2 (fr) * 2008-09-11 2010-03-18 Basf Se Procédé permettant d'augmenter le nombre de semis par rapport au nombre de graines semées
CN101703058A (zh) * 2009-11-18 2010-05-12 青岛海利尔药业有限公司 一种含有嘧菌酯和丙森锌的杀菌组合物
WO2010139653A1 (fr) * 2009-06-04 2010-12-09 Basf Se Mélanges fongicides comprenant des sulfonamides hétéroaromatiques

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PE20060801A1 (es) * 2004-12-23 2006-10-03 Basf Ag Mezclas fungicidas
US20080188530A1 (en) * 2004-12-23 2008-08-07 Markus Gewehr Fungicidal Mixtures
WO2006069700A1 (fr) * 2004-12-23 2006-07-06 Basf Aktiengesellschaft Melanges fongicides
CA2590364A1 (fr) * 2004-12-23 2006-07-06 Basf Aktiengesellschaft Melanges fongicides
CN101816305A (zh) * 2010-05-09 2010-09-01 海南正业中农高科股份有限公司 一种含有壳寡糖的杀菌剂农药组合物

Patent Citations (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3060084A (en) 1961-06-09 1962-10-23 Du Pont Improved homogeneous, readily dispersed, pesticidal concentrate
US3299566A (en) 1964-06-01 1967-01-24 Olin Mathieson Water soluble film containing agricultural chemicals
US4144050A (en) 1969-02-05 1979-03-13 Hoechst Aktiengesellschaft Micro granules for pesticides and process for their manufacture
US3920442A (en) 1972-09-18 1975-11-18 Du Pont Water-dispersible pesticide aggregates
US4172714A (en) 1976-12-20 1979-10-30 E. I. Du Pont De Nemours And Company Dry compactible, swellable herbicidal compositions and pellets produced therefrom
GB2095558A (en) 1981-03-30 1982-10-06 Avon Packers Ltd Formulation of agricultural chemicals
EP0451878A1 (fr) 1985-01-18 1991-10-16 Plant Genetic Systems, N.V. Modification de plantes par techniques de génie génétique pour combattre ou contrôler les insectes
US5180587A (en) 1988-06-28 1993-01-19 E. I. Du Pont De Nemours And Company Tablet formulations of pesticides
EP0374753A2 (fr) 1988-12-19 1990-06-27 American Cyanamid Company Toxines insecticides, gènes les codant, anticorps les liant, ainsi que cellules végétales et plantes transgéniques exprimant ces toxines
EP0392225A2 (fr) 1989-03-24 1990-10-17 Ciba-Geigy Ag Plantes transgéniques résistantes aux maladies
US5208030A (en) 1989-08-30 1993-05-04 Imperial Chemical Industries Plc Active ingredient dosage device
EP0427529A1 (fr) 1989-11-07 1991-05-15 Pioneer Hi-Bred International, Inc. Lectines larvicides, et résistance induite des plantes aux insectes
WO1991013546A1 (fr) 1990-03-12 1991-09-19 E.I. Du Pont De Nemours And Company Granules pesticides dispersibles ou solubles dans l'eau, obtenus a partir de liants thermo-actives
US5232701A (en) 1990-10-11 1993-08-03 Sumitomo Chemical Company, Limited Boron carbonate and solid acid pesticidal composition
WO1993007278A1 (fr) 1991-10-04 1993-04-15 Ciba-Geigy Ag Sequence d'adn synthetique ayant une action insecticide accrue dans le mais
EP0707445A1 (fr) 1993-07-03 1996-04-24 Basf Ag Formulation aqueuse polyphasee et stable prete a l'emploi pour produits phytosanitaires et procede de preparation
WO1995034656A1 (fr) 1994-06-10 1995-12-21 Ciba-Geigy Ag Nouveaux genes du bacillus thuringiensis codant pour des toxines actives contre les lepidopteres
WO1998025465A1 (fr) * 1996-12-10 1998-06-18 Bayer Aktiengesellschaft Combinaisons de principes actifs fungicides
WO2000029404A1 (fr) 1998-11-17 2000-05-25 Kumiai Chemical Industry Co., Ltd. Derives de pyrimidinylbenzimidazole et de triazinylbenzimidazole et bactericides agricoles/horticoles
WO2002015701A2 (fr) 2000-08-25 2002-02-28 Syngenta Participations Ag Nouvelles toxines insecticides derivees de proteines cristallines insecticides de $i(bacillus thuringiensis)
WO2003018810A2 (fr) 2001-08-31 2003-03-06 Syngenta Participations Ag Toxines cry3a modifiees et sequences d'acides nucleiques les codant
WO2003052073A2 (fr) 2001-12-17 2003-06-26 Syngenta Participations Ag Nouvel evenement du mais
WO2004083193A1 (fr) 2003-03-17 2004-09-30 Sumitomo Chemical Company, Limited Compose amide et composition bactericide contenant ledit compose
WO2006040123A2 (fr) * 2004-10-12 2006-04-20 Bayer Cropscience Ag Combinaisons d'agents fongicides
WO2007014290A2 (fr) 2005-07-26 2007-02-01 E. I. Du Pont De Nemours And Company Carboxamides fongicides
WO2007062765A1 (fr) * 2005-12-03 2007-06-07 Bayer Cropscience Ag Combinaisons de substances actives fongicides
WO2008013622A2 (fr) 2006-07-27 2008-01-31 E. I. Du Pont De Nemours And Company Amides azocycliques fongicides
WO2010029067A2 (fr) * 2008-09-11 2010-03-18 Basf Se Procédé permettant d'augmenter le nombre de semis par rapport au nombre de graines semées
CN101584330A (zh) * 2009-04-15 2009-11-25 陕西蒲城县美邦农药有限责任公司 一种含丙森锌与嘧菌酯的杀菌组合物
WO2010139653A1 (fr) * 2009-06-04 2010-12-09 Basf Se Mélanges fongicides comprenant des sulfonamides hétéroaromatiques
CN101703058A (zh) * 2009-11-18 2010-05-12 青岛海利尔药业有限公司 一种含有嘧菌酯和丙森锌的杀菌组合物

Non-Patent Citations (19)

* Cited by examiner, † Cited by third party
Title
"Perry's Chemical Engineer's Handbook", 1963, MCGRAW-HILL, pages: 8 - 57
"The Pesticide Manual", 2006, BRITISH CROP PROTECTION COUNCIL
AUSTRAL. J. AGRICULT. RES., vol. 58, 2007, pages 708
BROWNING: "Agglomeration", CHEMICAL ENGINEERING, 4 December 1967 (1967-12-04), pages 147 - 48
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; CHEN, WEIQIANG ET AL: "Fungicidal composition comprising azoxystrobin and propineb", XP002642154, retrieved from STN Database accession no. 152:585608 *
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; ZHANG, SHAOWU ET AL: "Synergistic fungicide containing propineb and azoxystrobin, its formulation and application", XP002642155, retrieved from STN Database accession no. 152:28743 *
HANCE ET AL.: "Weed Control Handbook", 1989, BLACKWELL SCIENTIFIC
KLINGMAN: "Weed Control as a Science", 1961, J. WILEY & SONS
MOLLET, H.; GRUBEMANN, A.: "Formulation technology", 2001, WILEY VCH VERLAG
PEST MANAGEM. SCI., 2008, pages 332
PEST MANAGEM. SCI., vol. 269, 2005, pages 61
PEST MANAGEM. SCI., vol. 277, 2005, pages 61
PEST MANAGEM. SCI., vol. 286, 2005, pages 64
PEST MANAGEM. SCI., vol. 326, 2008, pages 64
PEST MANAGEM. SCI., vol. 61, 2005, pages 246
PEST MANAGEM. SCI., vol. 61, 2005, pages 258
R.S. COLBY: "Calculating synergistic and antagonistic responses of herbicide combinations", WEEDS, vol. 15, 1967, pages 20 - 22, XP001112961
SCIENCE, vol. 316, 2007, pages 1185
WEED SCI., vol. 57, 2009, pages 108

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11284623B2 (en) 2012-11-22 2022-03-29 Basf Corporation Pesticidal mixtures
US10076119B2 (en) 2012-11-22 2018-09-18 Basf Corporation Pesticidal mixtures
WO2014079766A1 (fr) * 2012-11-22 2014-05-30 Basf Se Mélanges pesticides
WO2014079764A1 (fr) * 2012-11-22 2014-05-30 Basf Se Mélanges pesticides
US10537110B2 (en) 2012-11-22 2020-01-21 Basf Corporation Pesticidal mixtures
CN105101797A (zh) * 2012-11-22 2015-11-25 巴斯夫公司 农药混合物
WO2014079769A1 (fr) * 2012-11-23 2014-05-30 Basf Se Mélanges pesticides
CN103168799B (zh) * 2013-03-06 2014-12-17 广东省农业科学院植物保护研究所 一种含有吡唑醚菌酯和硫磺的杀菌剂组合物
CN103168799A (zh) * 2013-03-06 2013-06-26 广东省农业科学院植物保护研究所 一种含有吡唑醚菌酯和硫磺的杀菌剂组合物
CN103404519A (zh) * 2013-07-17 2013-11-27 山东省农业科学院植物保护研究所 一种杀菌剂组合物及其应用
CN103404519B (zh) * 2013-07-17 2016-01-27 山东省农业科学院植物保护研究所 一种杀菌剂组合物及其应用
WO2015028376A1 (fr) * 2013-08-28 2015-03-05 Basf Se Utilisation d'un mélange comprenant au moins une strobilurine et au moins un dithiocarbamate pour augmenter la santé de plantes sylvicoles
CN104705344A (zh) * 2013-12-13 2015-06-17 上海生农生化制品有限公司 一种含有硫磺的杀菌剂组合物及其应用
US11083202B2 (en) 2014-05-23 2021-08-10 Basf Se Mixtures comprising a bacillus strain and a pesticide
US10251400B2 (en) 2014-05-23 2019-04-09 Basf Se Mixtures comprising a Bacillus strain and a pesticide
CN104255756B (zh) * 2014-09-10 2016-05-18 江苏丘陵地区镇江农业科学研究所 一种含有吡唑醚菌酯与几丁聚糖的杀菌组合物及其应用
CN104255756A (zh) * 2014-09-10 2015-01-07 江苏省绿盾植保农药实验有限公司 一种含有吡唑醚菌酯与几丁聚糖的杀菌组合物及其应用
CN104396979A (zh) * 2014-10-24 2015-03-11 北京富力特农业科技有限责任公司 一种杀菌剂及其用途
CN105613540A (zh) * 2014-11-05 2016-06-01 江苏龙灯化学有限公司 一种活性成分组合物
US10779536B2 (en) 2014-11-07 2020-09-22 Basf Se Pesticidal mixtures
US9622484B2 (en) 2014-12-29 2017-04-18 Fmc Corporation Microbial compositions and methods of use for benefiting plant growth and treating plant disease
US10375964B2 (en) 2014-12-29 2019-08-13 Fmc Corporation Microbial compositions and methods of use for benefiting plant growth and treating plant disease
US10905122B2 (en) 2016-03-16 2021-02-02 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on cereals
US11241012B2 (en) 2016-03-16 2022-02-08 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on soybean
US11425909B2 (en) 2016-03-16 2022-08-30 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on fruits
WO2018001392A1 (fr) * 2016-07-01 2018-01-04 Bio Agens Research And Development - Bard, S.R.O. Préparation comprenant le micro-organisme mycoparasite pythium oligandrum à l'état viable servant au traitement de dermatophytoses et d'infections mycosiques de la peau et des muqueuses, méthode pour déterminer la viabilité cellulaire du micro-organisme pythium oligandrum, et méthode d'application de la préparation
US11331356B2 (en) 2016-07-01 2022-05-17 Bio Agens Research And Development—Bard, S.R.O. Preparation with the mycoparasitic microorganism pythium oligandrum for the treatment of dermaphytoses and yeast infections on the skin and mucouses, method of determing the cell's viability of the microorganism pythium oligandrum and method of applying the preparation

Also Published As

Publication number Publication date
WO2012077061A1 (fr) 2012-06-14
CN103260410A (zh) 2013-08-21

Similar Documents

Publication Publication Date Title
WO2012076563A1 (fr) Mélanges pesticides
WO2012076634A1 (fr) Mélanges fongicides comprenant de la pyraclostrobine
US11477984B2 (en) Fungicidal mixtures of mefentrifluconazole
EP3419423A1 (fr) Mélanges fongicides comprenant du fluxapyroxad
EP3512339A1 (fr) Mélanges pesticides
US20190246640A1 (en) Fungicidal mixtures comprising a carboxamide
WO2018189001A1 (fr) Mélanges fongicides destinés à être utilisés dans le riz
WO2020078797A1 (fr) Mélanges ternaires contenant des inhibiteurs de fenpropimorphe, de succinate déshydrogénase et un autre composé
EP3412150A1 (fr) Mélanges de meptyldinocap avec fongicides sdhi
EP4225034A1 (fr) Mélanges contenant du cyclobutrifluram
WO2019166252A1 (fr) Mélanges fongicides comprenant de la fenpropidine
EP2462807A1 (fr) Mélanges de pesticides contenant pyraclostrobin
US20190208783A1 (en) Fungicidal Mixtures Comprising a Formamidine
CA2923096C (fr) Melanges pesticides
WO2020007646A1 (fr) Mélanges pesticides
US20210251232A1 (en) Use of fungicidal active compound i derivative and mixtures thereof in seed application and treatment methods
EP3643175A1 (fr) Mélanges pesticides ternaires contenant du metyltetraprole et du fenpropimorphe
WO2022117373A1 (fr) Mélanges contenant du méarylpicoxamide
EP3817553B1 (fr) Mélanges pesticides
WO2012110439A1 (fr) Procédé de lutte contre les champignons phytopathogènes
WO2020078795A1 (fr) Mélanges ternaires contenant du fenpropimorphe, des inhibiteurs de succinate déshydrogénase et des azoles
WO2022128554A1 (fr) Mélanges contenant du n-méthoxy-n-[[4-[5-(trifluorométhyl)-1,2,4-oxadiazol-3-yl]phényl]méthyl]cyclopropanecarboxamide
EP3214937B1 (fr) Mélanges de pesticides
WO2021197885A1 (fr) Mélanges ternaires contenant du fenpropimorphe, des azoles et des strobilurines
WO2021197884A1 (fr) Mélanges ternaires contenant du fenpropimorphe, des inhibiteurs de succinate déshydrogénase et des strobilurines

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 11793432

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 11793432

Country of ref document: EP

Kind code of ref document: A1